Institution of Gas Engineers & Managers
The Optimization of Hybrid Power Systems with Renewable Energy and Hydrogen Generation
Jul 2018
Publication
This paper discusses the optimization of hybrid power systems which consist of solar cells wind turbines fuel cells hydrogen electrolysis chemical hydrogen generation and batteries. Because hybrid power systems have multiple energy sources and utilize different types of storage we first developed a general hybrid power model using the Matlab/SimPowerSystemTM and then tuned model parameters based on the experimental results. This model was subsequently applied to predict the responses of four different hybrid power systems for three typical loads without conducting individual experiments. Furthermore cost and reliability indexes were defined to evaluate system performance and to derive optimal system layouts. Finally the impacts of hydrogen costs on system optimization was discussed. In the future the developed method could be applied to design customized hybrid power systems.
Decarbonization in Shipping Industry: A Review of Research, Technology Development, and Innovation Proposals
Apr 2021
Publication
This review paper examines the possible pathways and possible technologies available that will help the shipping sector achieve the International Maritime Organization’s (IMO) deep decarbonization targets by 2050. There has been increased interest from important stakeholders regarding deep decarbonization evidenced by market surveys conducted by Shell and Deloitte. However deep decarbonization will require financial incentives and policies at an international and regional level given the maritime sector’s ~3% contribution to green house gas (GHG) emissions. The review paper based on research articles and grey literature discusses technoeconomic problems and/or benefits for technologies that will help the shipping sector achieve the IMO’s targets. The review presents a discussion on the recent literature regarding alternative fuels (nuclear hydrogen ammonia methanol) renewable energy sources (biofuels wind solar) the maturity of technologies (fuel cells internal combustion engines) as well as technical and operational strategies to reduce fuel consumption for new and existing ships (slow steaming cleaning and coating waste heat recovery hull and propeller design). The IMO’s 2050 targets will be achieved via radical technology shift together with the aid of social pressure financial incentives regulatory and legislative reforms at the local regional and international level.
Hydrogen Energy Vision 2060: Hydrogen as Energy Carrier in Malaysian Primary Energy Mix – Developing P2G Case
Mar 2021
Publication
The transition of Malaysia from fossil fuels to renewable energy sources provides significant challenges and opportunities for various energy sectors. Incorporation of H2 in the primary energy mix requires a deal of complexity in its relation to production transportation and end-use. The Sarawak State Government in Malaysia implemented a hydrogen energy roadmap for the year 2005–2030 on the state-level but despite the great enthusiasm and full support given by the government the development of hydrogen technology is still far from its goals. This is due to several factors that hinder its progress including (1) inability of hydrogen to be integrated with current primary energy infrastructure (2) limited technology resources to produce sustainable hydrogen and (3) lack of technical expertise in the field of hydrogen. In this paper a potential national roadmap and milestones are presented based on the power-to-gas (P2G) approach combined with its implications on the national natural gas (NG) pipeline network. Besides that the long-term and short-term strategies and implementation mechanisms are discussed in detail. Furthermore complete research schemes are formulated to be inline with the presented vision to further enhance technology development and implementation.
Hydrogen Storage Behavior of TiFe Alloy Activated by Different Methods
Feb 2021
Publication
TiFe activation for hydrogen uptake was conducted through different methods and ball milling with ethanol proved to be the most effective one. TiFe alloy after activation could absorb 1.2 wt% hydrogen at room temperature with absorption and desorption plateaus of 0.5 MPa and 0.2 MPa respectively. Investigation on microstructure and chemical state of TiFe sample after milled with ethanol suggested that the well spread metallic Ti and Fe elements helped hydrogen uptake and release. The activation of TiFe alloy by milling with ethanol was achieved at ambient conditions with ease successfully and possibly can be used for large scale production
An Optimal Fuzzy Logic-Based Energy Management Strategy for a Fuel Cell/Battery Hybrid Power Unmanned Aerial Vehicle
Feb 2022
Publication
With the development of high-altitude and long-endurance unmanned aerial vehicles (UAVs) optimization of the coordinated energy dispatch of UAVs’ energy management systems has become a key target in the research of electric UAVs. Several different energy management strategies are proposed herein for improving the overall efficiency and fuel economy of fuel cell/battery hybrid electric power systems (HEPS) of UAVs. A rule-based (RB) energy management strategy is designed as a baseline for comparison with other strategies. An energy management strategy (EMS) based on fuzzy logic (FL) for HEPS is presented. Compared with classical rule-based strategies the fuzzy logic control has better robustness to power fluctuations in the UAV. However the proposed FL strategy has an inherent defect: the optimization performances will be determined by the heuristic method and the past experiences of designers to a great extent rather than a specific cost function of the algorithm itself. Thus the paper puts forward an improved fuzzy logic-based strategy that uses particle swarm optimization (PSO) to track the optimal thresholds of membership functions and the equivalent hydrogen consumption minimization is considered as the objective function. Using a typical 30 min UAV mission profile all the proposed EMS were verified by simulations and rapid controller prototype (RCP) experiments. Comprehensive comparisons and analysis are presented by evaluating hydrogen consumption system efficiency and voltage bus stability. The results show that the PSO-FL algorithm can further improve fuel economy and achieve superior overall dynamic performance when controlling a UAV’s fuel-cell powertrain.
CO2 Emissions Reduction Measures for RO-RO Vessels on Non-Profitable Coastal Liner Passenger Transport
Jun 2021
Publication
Reducing CO2 emissions from ships in unprofitable coastline transport using electricity and hydrogen has potential for island development to improve transport and protect biodiversity and nature. New technologies are a challenge for shipping companies and their introduction should be accompanied by a system of state aid for alternative energy sources. The energy requirements of an electric ferry for a route of up to 6 km were considered as well as the amount of hydrogen needed to generate the electricity required to charge the ferry batteries to enable a state aid scheme. For a daily ferry operation a specific fuel consumption of 60.6 g/kWh of liquid hydrogen is required in the system fuel cell with a total of 342.69 kg of hydrogen. Compared to marine diesel the use of electric ferries leads to a reduction of CO2 emissions by up to 90% including significantly lower NOx Sox and particulate matter (PM) emissions and operating costs by up to 80%.
A New Model For Hydrogen-Induced Crack (HIC) Growth in Metal Alloy Pipelines Under Extreme Pressure
Dec 2020
Publication
Pipeline failure caused by Hydrogen-Induced Cracking (HIC) also known as Hydrogen Embrittlement (HE) is a pressing issue for the oil and natural gas industry. Bursts in pipelines are devastating and extremely costly. The explosive force of a bursting pipe can inflict fatal injuries to workers while the combined loss of product and effort to repair are highly costly to producers. Further pipeline failures due to HIC have a long lasting impact on the surrounding environment. Safe use and operation of such pipelines depend on a good understanding of the underlying forces that cause HIC. Specifically a reliable way to predict the growth rate of hydrogen-induced cracks is needed to establish a safe duration of service for each length of pipeline. Pipes that have exceeded or are near the end of their service life can then be retired before the risk of HIC-related failures becomes too high. However little is known about the mechanisms that drive HIC. To date no model has been put forth that accurately predicts the growth rate of fractures due to HIC under extreme pressures such as in the context of natural gas and petroleum pipelines. Herein a mathematical model for the growth of fractures by HIC under extreme pressures is presented. This model is derived from first principles and the results are compared with other models. The implications of these findings are discussed and a description of future work based on these findings is presented.
Evaluation of a New Combined Energy System Performance to Produce Electricity and Hydrogen with Energy Storage Option
Mar 2021
Publication
According to new findings the use of alternative energy sources such as wind energy is needed to supply the energy demand of future generations. On the other hand combined renewable energy systems can be more efficient than their stand-alone systems. Therefore clean energy-based hybrid energy systems can be a suitable solution for fossil fuels. However for their widespread commercialization more detailed and powerful studies are needed. On the other hand in order to attain sustainable development for the use of renewable energy sources due to their nature energy storage is required. The motivation of this study is introduce and examine a new energy system performance for the production of electricity and hydrogen fuel as well as energy storage. So this paper presents the energy and exergy operation of a hybrid wind turbine water electrolyzer and Pumped-hydro-compressed air system. The electricity produced by the wind turbine is used to produce hydrogen fuel in electrolyzer and the excess energy is stored using the storage system. It was found that the electrolyzer needed 512.6 W of electricity to generate 5 mol/h of hydrogen fuel which was supplied by a 10 kW-wind turbine. In such a context the efficiency of the process was 74.93%. Furthermore on average the isothermal process requires 17.53% less storage capacity than the isentropic process. The effect of key parameters such as rate of hydrogen fuel production operating pressures wind speed and components efficiency on the process operation is also examined.
Fatigue Behavior of AA2198 in Liquid Hydrogen
Aug 2019
Publication
Tensile and fatigue tests were performed on an AA2198 aluminum alloy in the T851 condition in ambient air and liquid hydrogen (LH2). All fatigue tests were performed under load control at a frequency of 20 Hz and a stress ratio of R=0.1. The Gecks-Och-Function [1] was fitted on the measured cyclic lifetimes.<br/><br/>The tensile strength in LH2 was measured to be 46 % higher compared to the value determined at ambient conditions and the fatigue limit was increased by approximately 60 %. Both S-N curves show a distinct S-shape but also significant differences. Under LH2 environment the transition from LCF- to HCF-region as well as the transition to the fatigue limit is shifted to higher cyclic lifetimes compared to ambient test results. The investigation of the crack surfaces showed distinct differences between ambient and LH2 conditions. These observed differences are important factors in the fatigue behavior change.
Hollow Cobalt Sulfide Nanocapsules for Electrocatalytic Selective Transfer Hydrogenation of Cinnamaldehyde with Water
Feb 2021
Publication
Designing nanostructured electrocatalysts for selective transfer hydrogenation of α β-unsaturated aldehydes with water as the hydrogen source is highly desirable. Here a facile self-templating strategy is designed for the synthesis of CoS2 and CoS2-x nanocapsules (NCs) as efficient cathodes for selective transfer hydrogenation of cinnamaldehyde a model α β-unsaturated aldehyde. The hollow porous structures of NCs are rich in active sites and improve mass transfer resulting in high turnover frequency. The specific adsorption of the styryl block on pristine CoS2 NCs is conducive to the selective formation of half-hydrogenated hydrocinnamaldehyde with 91.7% selectivity and the preferential adsorption of the C = O group induced by sulfur vacancies on defective CoS2-x NCs leads to the full-hydrogenated hydrocinnamyl alcohol with 92.1% selectivity. A cross-coupling of carbon and hydrogen radicals may be involved in this electrochemical hydrogenation reaction. Furthermore this selective hydrogenation method is also effective for other α β-unsaturated aldehydes illustrating the universality of the method.
Hydrogen Assisted Cracking in Pearlitic Steel Rods: The Role of Residual Stresses Generated by Fatigue Precracking
May 2017
Publication
Stress corrosion cracking (SCC) of metals is an issue of major concern in engineering since this phenomenon causes many catastrophic failures of structural components in aggressive environments. SCC is even more harmful under cathodic conditions promoting the phenomenon known as hydrogen assisted cracking (HAC) hydrogen assisted fracture (HAF) or hydrogen embrittlement (HE). A common way to assess the susceptibility of a given material to HAC HAF or HE is to subject a cracked rod to a constant extension rate tension (CERT) test until it fractures in this harsh environment. This paper analyzes the influence of a residual stress field generated by fatigue precracking on the sample’s posterior susceptibility to HAC. To achieve this goal numerical simulations were carried out of hydrogen diffusion assisted by the stress field. Firstly a mechanical simulation of the fatigue precracking was developed for revealing the residual stress field after diverse cyclic loading scenarios and posterior stress field evolution during CERT loading. Afterwards a simulation of hydrogen diffusion assisted by stress was carried out considering the residual stresses after fatigue and the superposed rising stresses caused by CERT loading. Results reveal the key role of the residual stress field after fatigue precracking in the HAC phenomena in cracked steel rods as well as the beneficial effect of compressive residual stress.
Evaluation of Hydrogen Permeation Characteristics in Rubbery Polymers
Oct 2020
Publication
To find suitable sealing material with low permeability against hydrogen the elaborated evaluation techniques for hydrogen transport properties are necessary. We developed two techniques determining the permeability of hydrogen including software for diffusion behavior analysis. The techniques contain gas chromatography and volumetric collection of hydrogen gas. By measuring the hydrogen released from polymer samples with respect to the elapsed time after being decompressed from the high pressure total amount of adsorption and diffusivity (D) of hydrogen are evaluated with self-developed program of Fick's diffusion equation specified to a sample shape. The solubility (S) and permeability (P) of the polymers are determined through Henry's law and a relation of P=SD respectively. Developed techniques were applied to three kinds of spherical-shaped sealing rubbers NBR EPDM and FKM. The D S and P have been measured as function of pressure. The permeability obtained by both methods are discussed with Comsol simulation.
HyDeploy2: Quantitative Risk Assessment
Jul 2021
Publication
A consortiumcomprising Cadent Gas Health and Safety Executive – Science Division ITMPower Keele University Northern Gas Networks and Progressive Energy is undertaking the second phase of the research project HyDeploy. The project the first two phase ofwhich are funded under the UK Network Innovation Competition scheme aims to demonstrate that natural gas containing levels of hydrogen beyond the upper limit set out in Schedule 3 of in the Gas Safety (Management) Regulations (GSMR) can be distributed and utilised safely and efficiently in the UK gas distribution networks.<br/>The first phase of the HyDeploy project concludes with a 10-month field trial in which hydrogen will be injected into part of a private gas distribution system owned and operated by Keele University.<br/>The second phase of the HyDeploy project (HyDeploy2) continues on from the work of the first phase and is scheduled to conclude with two 12-month field trials in which hydrogen will be injected into public gas networks owned and operated by Northern Gas Networks and Cadent Gas.<br/>Dave Lander Consulting Limited is providing technical support to the HyDeploy project and this report presents the results of Quantified Risk Assessment (QRA) for the proposed field trial of hydrogen injection into part of a gas distribution system owned and operated by Northern Gas Networks (NGN) near the town of Winlaton in Gateshead Tyne and Wear. The QRA is intended to support an application by NGN for exemption from the legal requirement to only convey gas that is compliant with the requirements of Schedule 3 of the GSMR. The QRA estimates the risk to persons within the trial area affected by the proposed injection. A similar QRA1 was developed for the original HyDeploy field trial at Keele University.<br/>Click on the supplement tab to see the other documents from this report
Internal and Surface Damage after Electrochemical Hydrogen Charging for Ultra Low Carbon Steel with Various Degrees of Recrystallization
Jul 2016
Publication
An ultra low carbon (ULC) steel was subjected to electrochemical hydrogen charging to provoke hydrogen induced damage in the material. The damage characteristics were analyzed for recrystallized partially recrystallized and cold deformed material. The goal of the study is to understand the effect of cold deformation on the hydrogen induced cracking behavior of a material which is subjected to cathodic hydrogen charging. Additionally charging conditions i.e. charging time and current density were varied in order to identify correlations between on the one hand crack initiation and propagation and on the other hand the charging conditions. The obtained hydrogen induced cracks were studied by optical microscopy scanning electron microscopy (SEM) and electron backscatter diffraction (EBSD). Hydrogen induced cracks were observed to propagate transgranularly independently of the state of the material. Deformed samples were considerably more sensitive to hydrogen induced cracking which implies the important role of dislocations in hydrogen induced damage mechanisms.
HyDeploy2 Report: Exemption
Jun 2021
Publication
Exemption is requested by Northern Gas Networks Ltd (NGN) from the obligation set out in Regulation 8(1) of the Gas Safety (Management) Regulations 1996 (GSMR) to convey only natural gas that is compliant with the Interchangeability requirements of Part I of Schedule 3 of the GSMR within a section of the NGN gas distribution network near Winlaton (the “field trial area”). The field trial area is owned and operated by Northern Gas Networks Ltd. The proposed conveyance of non-compliant gas (hereafter called the “Winlaton Field Trial”) will last for one year and is part of the Network Innovation Competition Project “HyDeploy2”.<br/>The project the first two phases of which are funded under the UK Network Innovation Competition scheme aims to demonstrate that natural gas containing levels of hydrogen beyond the upper limit set out in Schedule 3 of in the Gas Safety (Management) Regulations (GSMR) can be distributed and utilised safely and efficiently in the UK gas distribution networks. The first phase of the HyDeploy project is currently underway and includes a 10-month field trial that of hydrogen injection into part of a private gas distribution system owned and operated by Keele University. The second phase of the HyDeploy project (HyDeploy2) continues on from the work of the first phase and is scheduled to conclude with two 12-month field trials in which hydrogen will be injected into public gas networks owned and operated by NGN and Cadent Gas.<br/>Click on the supplements tab to view the other documents from this report
Laser Induced Hydrogen Emission from Ethanol with Dispersed Graphene Particles
Apr 2021
Publication
Efficient hydrogen emission from ethanol with disperse graphene foam particles by using a continuous wave infrared laser diode is reported. The products of ethanol dissociation - hydrogen methane and carbon oxide were measured using mass spectrometry. It was found that the most efficient generation of hydrogen was observed when graphene particles were irradiated by a focused laser beam proceeded at the surface of ethanol solution. The process was assisted by intense white light emission resulting from the laser induced multiphoton ionization of graphene combined with the simultaneous emission of hot electrons. The hot electron emission enables the efficient dissociation of ethanol molecules located close to the solution surface with graphene foam particles.
HyDeploy2: Appliance Testing Summary and Interpretation
Apr 2021
Publication
In order to inform the Quantified Risk Assessment (QRA) and procedures for the Winlaton trial the HyDeploy 2 project has undertaken a second programme of work focused on assessing the safe operation of gas appliances with hydrogen blended gas. This work extends the initial programme of work undertaken in HyDeploy 1 in 2018. Collectively these two projects provide an evidence base to support the project objective to demonstrate that there are no overarching safety concerns for the addition of up to 20 % mol/mol hydrogen to the GB natural gas distribution network.<br/>Click on the supplements tab to view the other documents from this report
Potentials of Hydrogen Technologies for Sustainable Factory Systems
Mar 2021
Publication
The industrial sector is the world’s second largest emitter of greenhouse gases hence a methodology for decarbonizing factory systems is crucial for achieving global climate goals. Hydrogen is an important medium for the transition towards carbon neutral factories due to its broad applicability within the factory including its use in electricity and heat generation and as a process gas or fuel. One of the main challenges is the identification of economically and environmentally suitable design scenarios such as for the entire value chain for hydrogen generation and application. For example the infrastructure for renewable electricity hydrogen generation hydrogen conversion (e.g. into synthetic fuels) storage and transport systems as well as application in the factory. Due to the high volatility of energy generation and the related dynamic interdependencies within a factory system a valid technical economic and environmental evaluation of benefits induced by hydrogen technologies can only be achieved using digital factory models. In this paper we present a framework to integrate hydrogen technologies into factory systems. This enables decision makers to identify promising measures according to their expected impact and collect data for appropriate factory modelling. Furthermore a concept for factory modelling and simulation is presented and demonstrated in a case study from the electronics industry assessing the use of hydrogen for decentralized power and heat generation.
Towards a CO2-neutral Steel Industry: Justice Aspects of CO2 Capture and Storage, Biomass- and Green Hydrogen-based Emission Reductions
Apr 2022
Publication
A rapid transition towards a CO2-neutral steel industry is required to limit climate change. Such a transition raises questions of justice as it entails positive and negative impacts unevenly distributed across societal stakeholders. To enable stakeholders to address such concerns this paper assesses the justice implications of three options that reduce emissions: CO2 capture and storage (CCS) on steel (up to 70%) bio-based steelmaking (up to 50%) and green hydrogen-based steel production (up to 100%). We select justice indicators from the energy climate labour and environmental justice literature and assess these indicators qualitatively for each of the technological routes based on literature and desk research. We find context-dependent differences in justness between the different technological routes. The impact on stakeholders varies across regions. There are justice concerns for local communities because of economic dependence on and environmental impact of the industry. Communities elsewhere are impacted through the siting of infrastructure and feedstock production. CCS and bio-based steelmaking routes can help retain industry and associated economic benefits on location while hydrogen-based steelmaking may deal better with environmental concerns. We conclude that besides techno-economic and environmental information transparency on sector-specific justice implications of transforming steel industries is essential for decision-making on technological routes
Deep Decarbonisation Pathways for Scottish Industries: Research Report
Dec 2020
Publication
The following report is a research piece outlining the potential pathways for decarbonisation of Scottish Industries. Two main pathways are considered hydrogen and electrification with both resulting in similar costs and levels of carbon reduction.
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