Publications
Research Progress of Fuel Cell Technology in Marine Applications: A Review
Apr 2025
Publication
With the increasing severity of global environmental issues and the pressure from the strict pollutant emission regulations proposed by the International Maritime Or‑ ganization (IMO) the shipping industry is seeking new types of marine power systems that can replace traditional propulsion systems. Marine fuel cells as an emerging energy technology only emit water vapor or a small amount of carbon dioxide during operation and have received widespread attention in recent years. However research on their appli‑ cation in the shipping industry is relatively limited. Therefore this paper collects relevant reports and literature on the use of fuel cells on ships over the past few decades and con‑ ducts a thorough study of typical fuel cell‑powered vessels. It summarizes and proposes current design schemes and optimization measures for marine fuel cell power systems pro‑ viding directions for further improving battery performance reducing carbon emissions and minimizing environmental pollution. Additionally this paper compares and analyzes marine fuel cells with those used in automotive aviation and locomotive applications of‑ fering insights and guidance for the development of marine fuel cells. Although hydrogen fuel cell technology has made significant progress in recent years issues still exist regard‑ ing hydrogen production storage and related safety and standardization concerns. In terms of comprehensive performance and economics it still cannot effectively compete with traditional internal combustion engines. However with the continued rapid devel‑ opment of fuel cell technology marine fuel cells are expected to become a key driver for promoting green shipping and achieving carbon neutrality goals.
Optimizing Hydrogen Storage and Fuel Cell Performance Using Carbon-Based Materials: Insights into Pressure and Surface Area Effects
Mar 2025
Publication
Efficient hydrogen storage is critical for advancing hydrogen-based technologies. This study investigates the effects of pressure and surface area on hydrogen storage in three carbon-based materials: graphite graphene oxide and reduced graphene oxide. Hydrogen adsorption–desorption experiments under pressures ranging from 1 to 9 bar revealed nonlinear storage capacity responses with optimal performance at around 5 bar. The specific surface area plays a pivotal role with reduced graphene oxide and exhibiting a surface area of 70.31 m2/g outperforming graphene oxide (33.75 m2/g) and graphite (7.27 m2/g). Reduced graphene oxide achieved the highest hydrogen storage capacity with 768 sccm and a 3 wt.% increase over the other materials. In assessing proton-exchange fuel cell performance this study found that increased hydrogen storage correlates with enhanced power density with reduced graphene oxide reaching a maximum of 0.082 W/cm2 compared to 0.071 W/cm2 for graphite and 0.017 W/cm2 for graphene oxide. However desorption rates impose temporal constraints on fuel cell operation. These findings enhance our understanding of pressure–surface interactions and underscore the balance between hydrogen storage capacity surface area and practical performance in carbon-based materials offering valuable insights for hydrogen storage and fuel cell applications.
Development, Application and Optimization of Hydrogen Refueling Processes for Railway Vehicles
Apr 2025
Publication
In recent years numerous hydrogen-powered rail vehicles have been developed and their deployment within public transport is steadily increasing. To avoid disadvantages compared to diesel vehicles refueling times of 15 min are stated in the industry as target independent of climate zones or vehicle configurations. As refueling time varies with these parameters this work presents the corresponding refueling times and defines optimization potentials. A simulation model was set up and parametrized with a reference vehicle and hydrogen refueling station from the FCH2RAIL project. Measurement data from this station and vehicle were analyzed and compared to simulation results for model validation. The results show that at high ambient temperature pre-cooling reduces refueling time by 71 % and type 4 tanks increase refueling time by 20 % compared to type 3. Overall optimized tank design and thermal management reduce the refueling time for rail vehicles from over 2 h to 15 min.
Multi-scale Modeling of the Multi-phase Flow in Water Electrolyzers for Green Hydrogen Production
May 2025
Publication
Water electrolyzers play a crucial role in green hydrogen production. However their efficiency and scalability are often compromised by bubble dynamics across various scales from nanoscale to macroscale components. This review explores multi-scale modeling as a tool to visualize multi-phase flow and improve mass transport in water electrolyzers. At the nanoscale molecular dynamics (MD) simulations reveal how electrode surface features and wettability influence nanobubble nucleation and stability. Moving to the mesoscale models such as volume of fluid (VOF) and lattice Boltzmann method (LBM) shed light on bubble transport in porous transport layers (PTLs). These insights inform innovative designs including gradient porosity and hydrophilic-hydrophobic patterning aimed at minimizing gas saturation. At the macroscale VOF simulations elucidate two-phase flow regimes within channels showing how flow field geometry and wettability affect bubble discharging. Moreover artificial intelligence (AI)-driven surrogate models expedite the optimization process allowing for rapid exploration of structural parameters in channel-rib flow fields and porous flow field designs. By integrating these approaches we can bridge theoretical insights with experimental validation ultimately enhancing water electrolyzer performance reducing costs and advancing affordable highefficiency hydrogen production.
In-situ Surface Engineering of Ternary Eco-friendly QDs for Enhanced Photoelectrochemical Hydrogen Production
Oct 2025
Publication
Ternary I-III-VI quantum dots (QDs) have recently received wide attention in solar energy conversion technologies because of their non-toxicity tunable band gap and composition-dependant optical properties. However their complex non-stoichiometry induces high density of surface traps/defects which significantly affects solar energy conversion efficiencies and long-term stability. This work presents an in-situ growth passivation approach to encapsulate ternary Cu:ZnInSe with ZnSeS alloyed shell (CZISe/ZSeS QDs) as light harvesters for solar-driven photoelectrochemical (PEC) hydrogen (H2) production. The engineered CZISe/ZSeS QDs coupled with TiO2- MWCNTs hybrid photoanode exhibit a high photocurrent density of 13.15 mA/cm2 at 0.8 V vs RHE under 1 sun illumination which is 20.5 % higher than bare CZISe QDs/TiO2 photoanode based device. In addition we observed a 48 % enhancement in the long-term stability with ~88 % current retained after 6000 s. These results indicate that the effective shell passivation has mitigated the surface traps/defects leading to suppressed charge recombination and improved charge transfer efficiency as confirmed by optoelectronic carrier dynamics measurements and theoretical simulations. The findings hold great promise on improving the performance of ternary/multinary eco-friendly colloidal QDs by surface engineering for effective utilization in solar energy conversion technologies.
Hydrogen-powered Vessels in Green Maritime Decarbonization: Policy Drivers, Technological Frontiers and Challenges
May 2025
Publication
The global shipping industry is transitioning toward decarbonization with hydrogen-powered vessels emerging as a key solution to meet international emission reduction targets particularly the IMO’s goal of reducing emissions by 50% by 2050. As a zero-emission fuel hydrogen aligns with international regulations such as the IMO’s greenhouse gas reduction strategy the MARPOL Convention and regional policies like the EU’s Emissions Trading System. Despite regulatory support and advancements in hydrogen fuel cell technology challenges remain in hydrogen storage fuel cell integration and operational safety. Currently high-pressure gaseous hydrogen storage is the most viable option but its spatial and safety limitations must be addressed. Alternative storage methods including cryogenic liquid hydrogen organic liquid hydrogen carriers and metal hydride storage hold potential for application but still face technical and integration barriers. Overcoming these challenges requires continued innovation in vessel design fuel cell technology and storage systems supported by comprehensive safety standards and regulations. The successful commercialization of hydrogen-powered vessels will be instrumental in decarbonizing global shipping and achieving climate goals.
Hydrogen via Co-Electrolysis of Water and CO2: Challenge or Solution for Industrial Decarbonization?
Aug 2025
Publication
The paper investigates the potential of co-electrolysis as a viable pathway for hydrogen production and industrial decarbonization expanding on previous studies on water electrolysis. The analysis adopts a general and critical perspective aiming to assess the realistic scope of this technology with regard to current energy and environmental needs. Although co-electrolysis theoretically offers improved efficiency by simultaneously converting H2O and CO2 into syngas the practical advantages are difficult to consolidate. The study highlights that the energetic margins of the process remain relatively narrow and that several key aspects including system irreversibility and the limited availability of CO2 in many contexts significantly constrain its applicability. Despite the growing interest and promising technological developments co-electrolysis still faces substantial challenges before it can be implemented on a larger scale. The findings suggest that its success will depend on targeted integration strategies advanced thermal management and favorable boundary conditions rather than on the intrinsic efficiency of the process alone. However there are specific sectors where assessing the implementation potential of co-electrolysis could be of interest a perspective this paper aims to explore.
Hydrogen UK - Hydrogen to Power Report
Jan 2025
Publication
The UK has set an ambitious target of delivering clean power by 2030. Low carbon dispatchable power generation using hydrogen will play a key role in a clean power system by providing flexibility and other services for system operability and also by providing supply adequacy during extended periods of low renewable output decarbonising the role currently performed by an aging portfolio of unabated natural gas power generation. While some 100% hydrogen to power (H2P) commercial projects are already being deployed globally using multi megawatt fuel cells alongside blending hydrogen into existing gas turbines and new hydrogen ready turbines industrial scale 100% H2P projects face additional challenges of deploying new technology into a nascent system one which requires significant volumes of hydrogen storage with long lead times. To achieve the 2030 clean power system ambition and lay the foundations for a clean resilient and secure power system beyond 2030 it is critical that the new government takes resolute actions now to support H2P at scale. A clear strategic plan should be developed within the first 12 months of the new administration with clarity being given on policy business models and deployment rates for hydrogen to power (H2P) and its enabling infrastructure. This report produced by Hydrogen UK’s Power Generation Working Group explores the role that H2P will play in the decarbonised power system of the future the barriers to deployment and recommendations for overcoming them.
This paper can be found on their website.
This paper can be found on their website.
The Hydrogen Education and Research Landscape - Update of the October 2024 Report
Oct 2025
Publication
This report includes information on European training programmes educational materials and the trends and patterns of research and innovation activity in the hydrogen sector with data of patent registrations and publications. It is based on the information available at the European Hydrogen Observatory (EHO) website (https://observatory.cleanhydrogen.europa.eu/) the leading source of hydrogen data in Europe. The data presented in this report is based on research conducted until the end of August 2025. The training programmes section provides insights into major European training initiatives categorized by location. It allows filtering by type of training focus area and language. It covers a wide range of opportunities such as vocational and professional trainings summer schools and Bachelor's or Master's programmes. The education materials chapter summarizes the publicly accessible educational materials available online. Documents can be searched by educational level by course subject by language or by the year of release. The section referring to research and innovation activity analyses trends and patterns in the hydrogen sector using aggregated datasets of patent registrations and publications by country.
Study on Hydrogen Embrittlement Behavior in Heat-Affected Zone of X80 Welded Pipe
Apr 2025
Publication
Hydrogen as a clean energy source has gradually become an important choice for the energy transformation in the world. Utilizing existing natural gas pipelines for hydrogen-blended transportation is one of the most economical and effective ways to achieve large-scale hydrogen transportation. However hydrogen can easily penetrate into the pipe material during the hydrogen-blended transportation process causing damage to the properties of the pipe. The heat-affected zone (HAZ) of the weld being the weakest part of the pipeline is highly sensitive to hydrogen embrittlement. The microstructure and properties of the grains in the heat-affected zone undergoes changes during the welding process. Therefore this paper divides the HAZ of X80 welded pipes into three sub-HAZ namely the coarse-grained HAZ fine-grained HAZ and intercritical HAZ to study the hydrogen behavior. The results show that the degree of hydrogen damage in each sub-HAZ varies significantly at different strain rates. The coarse-grained HAZ has the highest hydrogen embrittlement sensitivity at low strain rates while the intercritical HAZ experiences the greatest hydrogen damage at high strain rates. By combining the microstructural differences within each sub-HAZ the plastic damage mechanism of hydrogen in each sub-HAZ is analyzed with the aim of providing a scientific basis for the feasibility of using X80 welded pipes in hydrogen-blended transportation.
Low-Carbon Economic Dispatch of Integrated Energy Systems for Electricity, Gas, and Heat Based on Deep Reinforcement Learning
Oct 2025
Publication
Under the background of “dual-carbon” the development of energy internet is an inevitable trend for China’s low-carbon energy transition. This paper proposes a hydrogen-coupled electrothermal integrated energy system (HCEH-IES) operation mode and optimizes the source-side structure of the system from the level of carbon trading policy combined with low-carbon technology taps the carbon reduction potential and improves the renewable energy consumption rate and system decarbonization level; in addition for the operation optimization problem of this electric–gas–heat integrated energy system a flexible energy system based on electric–gas–heat is proposed. Furthermore to address the operation optimization problem of the HCEH-IES a deep reinforcement learning method based on Soft Actor–Critic (SAC) is proposed. This method can adaptively learn control strategies through interactions between the intelligent agent and the energy system enabling continuous action control of the multi-energy flow system while solving the uncertainties associated with source-load fluctuations from wind power photovoltaics and multi-energy loads. Finally historical data are used to train the intelligent body and compare the scheduling strategies obtained by SAC and DDPG algorithms. The results show that the SAC-based algorithm has better economics is close to the CPLEX day-ahead optimal scheduling method and is more suitable for solving the dynamic optimal scheduling problem of integrated energy systems in real scenarios.
The Impact of Temporal Hydrogen Regulation on Hydrogen Exporters and their Domestic Energy Transition
Aug 2025
Publication
As global demand for green hydrogen rises potential hydrogen exporters move into the spotlight. While exports can bring countries revenue large-scale on-grid hydrogen electrolysis for export can profoundly impact domestic energy prices and energy-related emissions. Our investigation explores the interplay of hydrogen exports domestic energy transition and temporal hydrogen regulation employing a sector-coupled energy model in Morocco. We find substantial co-benefits of domestic carbon dioxide mitigation and hydrogen exports whereby exports can reduce market-based costs for domestic electricity consumers while mitigation reduces costs for hydrogen exporters. However increasing hydrogen exports in a fossil-dominated system can substantially raise market-based costs for domestic electricity consumers but surprisingly temporal matching of hydrogen production can lower these costs by up to 31% with minimal impact on exporters. Here we show that this policy instrument can steer the welfare (re-)distribution between hydrogen exporting firms hydrogen importers and domestic electricity consumers and hereby increases acceptance among actors.
Combustion Process Analysis of Secondary Jet-Guided Combustion in Hydrogen Direct-Injection Engines
Oct 2025
Publication
This study investigates the effects of secondary jet-guided combustion on the combustion and emissions of a hydrogen direct-injection engine through numerical simulations. The results show that secondary jet-guided combustion which involves injecting and igniting the hydrogen jet at the end of the compression stroke significantly shortens the delay period improves combustion stability and brings the combustion center closer to the top dead center (TDC) achieving a maximum indicative thermal efficiency (ITE) of 46.55% (λ = 2.4). However this strategy results in higher NOx emissions due to high-temperature combustion. In contrast single and double injections lead to worsened combustion and reduced thermal efficiency under lean-burn conditions but with relatively lower NOx emissions. This study demonstrates that secondary jet-guided combustion can effectively enhance hydrogen engine performance by optimizing mixture stratification and flame propagation providing theoretical support for clean and efficient combustion.
Assistance in the Development of an Auction Design and Necessary Pre-conditions for a European Import Auction for Renewable Hydrogen under the European Hydrogen Bank: Final Report
Aug 2025
Publication
This report supports the European Commission (DG ENER) in the design and implementation of a European import auction for renewable hydrogen and its derivatives under the European Hydrogen Bank (EHB). The EHB aims to contribute to the EU's climate neutrality goal by 2050. While domestic auctions have already been launched under the EHB its international leg focusing on renewable fuels of non-biological origin (RFNBO) imports from third countries remains to be designed. This report offers strategic recommendations based on hydrogen market analyses the assessment of existing and planned hydrogen auction schemes in Europe and beyond as well as preliminary considerations on auction design. The analysis highlights the potential for hydrogen imports from regions like North America Australia Latin America and the MENA region. It includes concrete case studies on both pipeline-based imports of pure hydrogen and ship-based imports of key derivatives (ammonia methanol and synthetic aviation fuels (eSAF) to reflect Member State preferences and provides a concrete starting point for further defining import auctions. Priority considerations for auction design include ensuring fair competition between domestic production and imports addressing geopolitical risks and achieving cost efficiency. The case studies serve as a flexible blueprint for implementing EHB import auctions considering Member State interests and aligning with the EU's broader objectives.
Hydrogen UK - Driving Demand
Jul 2025
Publication
Low carbon hydrogen has a fundamental role to play in not one but two of the UK Government’s core missions. First it can help grow the economy - with thousands of new jobs and opportunities breathing new life into our industrial heartlands. Second it can help the UK become a clean energy superpower by using clean secure energy that we control. Third it can future-proof the UK’s foundational industries delivering decarbonisation and energy security to the hard-to-abate sectors which underpin the UK economy. Hydrogen developers across our membership report growing interest from customers in a wide range of sectors. Whilst current government policy has helped start the hydrogen economy industry wants this to accelerate and become more holistic so that interest is translated into demand allowing the sector to fully develop and the UK to meet its decarbonisation targets. With growing international competition the UK Government should prioritise the growth of hydrogen technology implementation leveraging the nation’s natural geological and geographical advantages. Although £20 billion in private capital investment is estimated to be ready to support the UK Government’s hydrogen ambitions persistent delays and market uncertainty risk this funding being lost to other markets. This report outlines the importance of Driving Demand for offtakers complementing the strong market foundation built from Government’s early hydrogen production focus. For effective policy implementation industry stakeholders have highlighted the importance of finding balance: retaining low-carbon technology optionality alongside certainty and support for investment with the adoption of a clear ‘vision’ and ‘market creation’ supported by a tailored mix of ‘carrots and sticks’ to support the market. From the research conducted by HUK it is clear that the choice of decarbonisation options is not done on a sector-by-sector basis that even within companies the decision-making process is site-by-site. This reflects the sensitivity of numerous factors that will ultimately determine the best solution for their site and re-enforces the view that customers must be allowed the choice of decarbonisation options. Hydrogen will play a significant role in decarbonising some of the hardest to abate sectors of the UK economy complimenting the role of electrification CCUS and other decarbonisation technologies. These sectors represent the hardest and therefore most expensive to decarbonise. However hydrogen also provides an opportunity to deliver significant economic growth through a thriving domestic supply chain and so a holistic approach should be applied.
The paper can be found on their website.
The paper can be found on their website.
Comparative Risk Assessment of Gaseous and Liquid Hydrogen Fuel Gas Supply Systems for Hydrogen-fueled Vessels
Aug 2025
Publication
This study compares qualitative risk analyses of compressed hydrogen gas (GH2) and liquid hydrogen (LH2) fuel gas supply systems (FGSSs) for eco-friendly marine vessels. Using hazard identification (HAZID) and hazard and operability (HAZOP) methodologies the study systematically identifies and compares the unique risks and safety strategies for GH2 and LH2 FGSS. For GH2-FGSS HAZID identifies 22 hazards with one unacceptable risk related to potential explosions from high-pressure hydrogen accumulation due to ventilation failure. HAZOP identifies 27 hazards all categorized as acceptable or ALARP. Recommended safety measures include pressure protection devices real-time alarms and enhanced piping durability. For LH2-FGSS HAZID identifies 38 hazards without any unacceptable risks though cryogenic icing and overpressure remain significant concerns. HAZOP reveals 43 hazards with one unacceptable risk involving thermal contraction and piping damage from repeated operations posing fire hazards. Suggested mitigations include improved cooling and purge gas procedures along with rigorous insulation management. Primary differences in safety management focus on high explosion risk of GH2-FGSS from high-pressure storage and the piping damage risk of LH2-FGSS from icing and thermal contraction. To enhance risk management for each system future research implements an operational simulation-based quantitative risk assessment. This study provides foundational safety strategies and guidelines for future vessels supporting the adoption of eco-friendly fuels in the maritime industry.
Numerical Investigation of Marine Dual-Fuel Engine Operating with High Shares of Premixed Hydrogen Fuel Using LES
Oct 2025
Publication
Hydrogen fuel presents a promising pathway for achieving long-term decarbonization in the maritime sector. However its use in diesel engines introduces challenges due to high reactivity leading to increased NOx emissions and combustion instability. The aim of this study is to identify settings so that the investigated engine operates with 60% hydrogen energy fraction at high load through CFD modelling. The model is utilized to simulate a four-stroke 10.5 MW marine engine at 90% load incorporating 60% hydrogen injection by energy at the engine intake port. The CFD model is verified using experimental data from diesel operation of the marine engine and hydrogen operation of a light-duty engine. The engine performance was determined and detailed emissions analysis was conducted including NO NO2 HO2 and OH. The findings indicate a substantial rise in NOx emissions as opposed to diesel operation due to elevated combustion temperatures and increased residence time at elevated temperature of the mixture in-cylinder. The presence of HO2 and OH highlights critical zones of combustion which contribute to operational stability. The novelty of this study is supported by the examination of the high hydrogen energy fraction the advanced emissions analysis and the insights into the emissions–performance trade-offs in hydrogen-fueled dual-fuel marine engines. The results offer guidance for the development of sustainable hydrogen-based marine propulsion systems.
The Lack of Systems Thinking and Interdisciplinarity is Killing the Hydrogen Economy
Sep 2025
Publication
Hydrogen’s promise as a transformative energy solution has been consistently unfulfilled. This perspective article suggests that the primary barrier is not necessarily technological but a systemic failure to apply holistic systems thinking and genuine interdisciplinary collaboration. Through historical analysis and contemporary case studies we argue that only by integrating technical economic policy and social expertise within a holistic systems framework across the entire value chain can hydrogen overcome its boom-and-bust cycles and become a foundational component of the low-carbon energy future.
Decarbonising European Heavy-duty Transport: A Stakeholder Analysis of Technology Readiness and Future R&I Priorities for Zero-emission Vehicles and Infrastructure
Sep 2025
Publication
This report identifies the critical research and innovation (R&I) priorities for decarbonising Europe's heavy-duty vehicles based on direct feedback from industry stakeholders. The findings reveal a consensus: battery electric technology is the primary pathway forward with significant stakeholder support for R&I focused on its improvement. While battery electric technology is perceived as more mature hydrogen is considered a complementary solution for the most demanding long-haul routes. Large-scale demonstrations are suggested for de-risking operations and evaluating integration with the transport and energy system. The analysis confirms that achieving TCO parity or better compared to diesel is the most important factor for market uptake. This study provides direct evidence-based guidance for EU transport R&I policy helping to chart the road ahead and orient R&I call programming to meet the ambitious CO₂ emission standards for heavy-duty vehicles.
Plasma-Assisted Hydrogen Production: Technologies, Challenges, and Future Prospects
Apr 2025
Publication
As global demand for clean energy continues to rise hydrogen as an ideal energy carrier plays a crucial role in the energy transition. Traditional hydrogen production methods predominantly rely on fossil fuels leading to environmental pollution and energy inefficiency. In contrast plasma-assisted hydrogen production as an emerging technology has gained significant attention due to its high efficiency environmental friendliness and flexibility. Plasma technology generates high-energy electrons or ions by exciting gas molecules which under specific conditions effectively decompose water vapor or hydrocarbon gases to produce hydrogen. This review systematically summarizes the basic principles technological routes research progress and potential applications of plasmaassisted hydrogen production. It focuses on various plasma-based hydrogen production methods such as water vapor decomposition hydrocarbon cracking arc discharge and microwave discharge highlighting their advantages and challenges. Additionally it addresses key issues facing plasma-assisted hydrogen production including energy efficiency improvement reactor stability and cost optimization and discusses the future prospects of these technologies. With ongoing advancements plasma-assisted hydrogen production is expected to become a mainstream technology for hydrogen production contributing to global goals of zero carbon emissions and sustainable energy development.
GB Energy Networks: Experts' Views on Future Pathways and Multi-vector Energy Networks Approach
Jul 2025
Publication
The decarbonization of energy systems poses significant challenges to energy networks due to the introduction of new energy vectors and changes in the pattern of energy demand. However this is currently an under-researched area. This paper addresses a gap in the literature by drawing on the socio-technological transitions and multi-system interactions literature to explore the views of experts from industry academia and other sectors about the challenges facing UK energy networks and the possible solutions including taking a more wholistic approach to the planning and operation of dierent networks. Using these frameworks we have demonstrated that systems can be deliberately integrated to interact and solve particular system challenges and have identified the nature of these interactions. The empirical results identify areas of consensus and disagreement about the future development of network infrastructure and regulation. They also highlight how government policy responds to the challenges and opportunities presented by the UK climate targets. The findings show widespread agreement that the UK energy system will become more electrified and decentralized as it incorporates more renewable energy. However the role of gaseous fuels in the energy system is more uncertain with some experts seeing a move from natural gas to hydrogen as being key to maintaining the security of supply while others see little or no role for hydrogen. There is also widespread agreement that the regulatory structure should change to address the challenges facing energy networks with much less agreement on whether this could happen quickly enough. Recent developments indicate the UK Government recognizes the need for regulatory change but it is premature to foresee their success in helping networks be a driver of rather than a barrier to a net-zero energy system.
From Natural Gas to Hydrogen: Climate Impacts of Current and Future Gas Transmission Networks in Germany
May 2025
Publication
Hydrogen emissions arise from leakage during its production transport storage and use leading to an increase in atmospheric hydrogen concentrations. These emissions also cause an indirect climate effect which has been quantified in the literature with a global warming potential over 100 years (GWP100) of about 11.6 placing hydrogen between carbon dioxide (1) and methane (29.8). There is increasing debate about the climate impact of an energy transition based on hydrogen. As a case study we have therefore evaluated the expected climate impact of switching from the long-distance natural gas transmission network to the outlined future “hydrogen core network” in Germany. Our analysis focuses on the relevant sources and network components of emissions. Our results show that the emissions from the network itself represent only about 1.8% of total emissions from the transmission of hydrogen with 98% attributed to energy-related compressor emissions and only 2% to fugitive and operational hydrogen leakage. Compared to the current natural gas transmission network we calculate a 99% reduction in total network emissions and a 97% reduction in specific emissions per transported unit of energy. In the discussion we show that when considering the entire life cycle which also includes emissions from the upstream and end-use phases the switch to hydrogen reduces the overall climate impact by almost 90%. However while our results show a significantly lower climate impact of hydrogen compared to natural gas minimising any remaining emissions remains crucial to achieve carbon neutrality by 2045 as set in Germany’s Federal Climate Action Act. Hence we recommend further reducing the emissions intensity of hydrogen supply and minimising the indirect emissions associated with the energy supply of compressors.
Thermo-economic Analysis of Blending Hydrogen into Natural Gas Pipeline with Gaseous Inhibitors for Sustainable Hydrogen Transportation
Apr 2025
Publication
Hydrogen transportation through a new pipeline poses significant economic barriers and blending hydrogen into existing natural gas pipelines offers promising alternative. However hydrogen’s low energy density and potential material compatibility challenges necessitate modifications to existing infrastructure. This study conducts a comprehensive thermo-economic analysis of natural gas and hydrogen mixtures with and without gaseous inhibitors evaluating the impact on thermophysical properties (Wobbe index density viscosity energy density higher and lower heating values) compression power economic feasibility and storage volume requirement. A pipeline transmission model was developed in Aspen HYSYS to assess these properties considering major and minor infrastructure modifications. The findings suggest that the addition of 5% carbon monoxide and 2% ethylene as gaseous inhibitors in maintaining desired properties ensuring compatibility with existing infrastructure and operational processes. The findings also indicate that blending 30% hydrogen increases storage volume by 30–55% while reducing higher and lower heating values by 20–25%. However the addition of 5% carbon monoxide and 2% ethylene improves the pipeline performance and reduces the carbon emissions by 23–26% supporting the transition to low-carbon energy systems. The results suggest that hydrogen blending is viable under specific infrastructure modifications providing critical insights for optimizing pipeline repurposing for sustainable hydrogen transportation.
Forward Osmosis Membrane Bioreactor for Sustainable Hydrogen Production from Waste Molasses
Oct 2025
Publication
The current study evaluates the feasibility of a forward osmosis membrane bioreactor (FO-MBR) for dark fermentation aiming at simultaneous biohydrogen production and wastewater treatment. Optimal microbial inoculation was achieved via heat-treated activated sludge enriching Clostridium sensu stricto 1 and yielding up to 2.21 mol H2.(mol hexose)− 1 in batch mode. In continuous operation a substrate concentration of 4.4 g L− 1 and a hydraulic retention time (HRT) of 12 h delivered the best results producing 1.51 mol H2.(mol hexosesupplied) − 1 . The FO-MBR configured with a 1.1 m2 hollow fiber side-stream membrane module and operated under dynamic HRT (2.5–12 h) dependent on membrane flux was integrated with intermittent CSTR (Continuous stirred tank reactor) operation to counter metabolite accumulation. This system outperformed a conventional CSTR achieving a hydrogen yield of 1.78 mol H2.(mol hexosesupplied) − 1 . Remarkable treatment efficiencies were observed with BOD5 COD and TOC removal rates of 95.32 % 99.02 % and 99.10 % respectively and an 83.8 % reduction in total waste volume. Additionally the FO-MBR demonstrated strong antifouling performance with 96.14 % water flux recovery achieved after a brief 5 min hydraulic rinse following 47.5 h of continuous highstrength broth exposure. These results highlight the FO-MBR system’s ability as a sustainable and highperformance alternative for integrated hydrogen production and effluent treatment. Further studies are recommended to address long-term fouling control and metabolite management for industrial scalability.
Hydrogen UK - Splitting the Difference: Reducing the Cost of Electrolytic Hydrogen to Accelerate Deployment
Jan 2025
Publication
The UK is set to build on its world leading position of renewables deployment targeting as much as 50GW of offshore wind 27GW of onshore wind and 47GW of solar by 2030 as part of the Clean Power 2030 mission. As we move towards a net zero power system driven by renewables and away from unabated gas the UK will need greater capability to manage periods of low and excess renewable generation. Electrolytic hydrogen is a critical solution to this challenge as the Clean Power Plan and the advice from NESO make clear. Firstly because hydrogen can be stored for long periods of time and in large volumes and because curtailed power can be very low cost. Therefore electrolytic hydrogen can provide cost-effective long duration energy storage which can then be used as a low carbon alternative to natural gas for dispatchable power generation and for a wide variety of uses essential to the full decarbonisation of other sectors including industry and heavy transport. Secondly electrolytic hydrogen can be produced using the renewable power in places such as Scotland that would otherwise go to waste due to the lack of network capacity or demand. Building electrolytic hydrogen production capacity in areas with high renewables and behind grid constraints has a wide range of benefits. Providing electricity demand for the increasing levels of onshore and offshore wind that is in the pipeline in Scotland is going to be critical for renewable deployment while reducing constraint costs paid by consumers. Thus by providing a source of firm power and demand for excess renewable generation electrolytic hydrogen is fundamental to ensuring security of supply in a low carbon power system.
This paper can be found on their website.
This paper can be found on their website.
Photoelectrochemical Water Splitting under Concentrated Sunlight: Best Practices and Protocols
Mar 2025
Publication
Photoelectrochemical (PEC) water splitting is a promising technology for green hydrogen production by harnessing solar energy. Traditionally this sustainable approach is studied under light intensity of 100 mW/cm2 mimicking the natural solar irradiation at the Earth’s surface. Sunlight can be easily concentrated using simple optical systems like Fresnel lens to enhance charge carrier generation and hydrogen production in PEC water splitting. Despite the great potentials this strategy has not been extensively studied and faces challenges related to the stability of photoelectrodes. To prompt the investigations and applications this work outlines the best practices and protocols for conducting PEC solar water splitting under concentrated sunlight illumination incorporating our recent advancements and providing some experimental guidelines. The key factors such as light source calibration photoelectrode preparation PEC cell configuration and long-term stability test are discussed to ensure reproducible and high performance. Additionally the challenges of the expected photothermal effect and the heat energy utilization strategy are discussed.
Comparative Electrochemical Performance of Solid Oxide Fuel Cells: Hydrogen vs. Ammonia Fuels—A Mini Review
Apr 2025
Publication
Solid oxide fuel cells (SOFCs) have garnered significant attention as a promising technology for clean and efficient power generation due to their ability to utilise renewable fuels such as hydrogen and ammonia. As carbon-free energy carriers hydrogen and ammonia are expected to play a pivotal role in achieving net-zero emissions. However a critical research question remains: how does the electrochemical performance of SOFCs compare when fuelled by hydrogen vs. ammonia and what are the implications for their practical application in power generation? This mini-review paper is premised on the hypothesis that while hydrogen-fuelled SOFCs currently demonstrate superior stability and performance at low and high temperatures ammonia-fuelled SOFCs offer unique advantages such as higher electrical efficiencies and improved fuel utilisation. These benefits make ammonia a viable alternative fuel source for SOFCs particularly at elevated temperatures. To address this the mini-review paper provides a comprehensive comparative analysis of the electrochemical performance of SOFCs under direct hydrogen and ammonia fuels focusing on key parameters such as open-circuit voltage (OCV) power density electrochemical impedance spectroscopy fuel utilisation stability and electrical efficiency. Recent advances in electrode materials electrolytes fabrication techniques and cell structures are also highlighted. Through an extensive literature survey it is found that hydrogen-fuelled SOFCs exhibit higher stability and are less affected by temperature cycling. In contrast ammonia-fuelled SOFCs achieve higher OCVs (by 7%) and power densities (1880 mW/cm2 vs. 1330 mW/cm2 for hydrogen) at 650 °C along with 6% higher electrical efficiency. Despite these advantages ammonia-fuelled SOFCs face challenges such as NOx emissions nitride formation environmental impact and OCV stabilisation which are discussed alongside potential solutions. This mini review aims to provide insights into the future direction of SOFC research emphasising the need for further exploration of ammonia as a sustainable fuel alternative.
Hydrogen Production Plant Retrofit for Green H2: Experimental Validation of a High-Efficiency Retrofit of an Alkaline Hydrogen Plant Using an Isolated DC Microgrid
Oct 2025
Publication
Given the climate change observed in the past few decades sustainable development and the use of renewable energy sources are urgent. In this scenario hydrogen production through electrolyzers is a promising renewable source and energy vector because of its ultralow greenhouse emissions and high energy content. Hydrogen can be used in a variety of applications from transportation to electricity generation contributing to the diversification of the energy matrix. In this context this paper presents an autonomous isolated DC microgrid system for generating and storing electrical energy to be exclusively used for feeding an electrolyzer hydrogen production plant which has been retrofitted for green hydrogen production. Experimental verification was performed at Itaipu Parquetec which consists of an alkaline electrolysis unit directly integrated with a battery energy storage system and renewable sources (e.g. photovoltaic and wind) by using an isolated DC microgrid concept based on DC/DC and AC/DC converters. Experimental results revealed that the new electrolyzer DC microgrid increases the system’s overall efficiency in comparison to the legacy thyristor-based power supply system by 26% and it autonomously controls the energy supply to the electrolyzer under optimized conditions with an extremely low output current ripple. Another advantage of the proposed DC microgrid is its ability to properly manage the startup and shutdown process of the electrolyzer plant under power generation outages. This paper is the result of activities carried out under the R&D project of ANEEL program No. PD-10381-0221/2021 entitled “Multiport DC-DC Converter and IoT System for Intelligent Energy Management” which was conducted in partnership with CTG-Brazil.
Boosting Green Hydrogen Production—Energy Savings in Alkaline Water Electrolysis Using Synergy of Magnetic Field and In Situ Activation of Electrodes
Oct 2025
Publication
This study focuses on enhancing the efficiency of alkaline water electrolysis technology a key process in green hydrogen production by leveraging the synergy of magnetic fields and in situ electrode activation. Optimizing AWE efficiency is essential to meet increasing demands for sustainable energy solutions. In this research nickel mesh electrodes were modified through the application of magnetic fields and the addition of hypo-hyper d-metal (cobalt complexes and molybdenum salt) to the electrolyte. These enhancements improve mass transfer facilitate bubble detachment and create a high-surface-area catalytic layer on the electrodes all of which lead to improved hydrogen evolution rates. The integration of magnetic fields and in situ activation achieved over 35% energy savings offering a cost-effective and scalable pathway for industrial green hydrogen production.
Biohydrogen Production from Industrial Wastewater: An Overview
Jun 2019
Publication
Biohydrogen production from industrial wastewater has been a focus of interest in recent years. The in depth knowledge in lab scale parameters and emerging strategies are needed to be investigated in order to implement the biohydrogen production process at large scale. The operating parameters have great influence on biohydrogen productivity. With the aim to gain major insight into biohydrogen production process this review summarizes recent updates on dark fermentation inoculum pretreatment methods operating parameters (hydraulic retention time organic loading rate pH temperature volatile fatty acids bioreactor configuration nutrient availability partial pressure etc.). The challenges and limitations associated with the biohydrogen production are lack of biohydrogen producers biomass washout and accumulation of metabolites are discussed in detail. The advancement strategies to overcome these limitations are also briefly discussed.
Hydrogen-Blended Natural Gas Leakage and Diffusion Characteristics Simulation and Ventilation Strategy in Utility Tunnels
Aug 2025
Publication
To ensure the safe and reliable operation of hydrogen-blended natural gas (HBNG) pipelines in urban utility tunnels this study conducted a comprehensive CFD simulation of the leakage and diffusion characteristics of HBNG in confined underground environments. Utilizing ANSYS CFD software (2024R1) a three-dimensional physical model of a utility tunnel was developed to investigate the influence of key parameters such as leak sizes (4 mm 6 mm and 8 mm)—selected based on common small-orifice defects in utility tunnel pipelines (e.g. corrosion-induced pinholes and minor mechanical damage) and hydrogen blending ratios (HBR) ranging from 0% to 20%—a range aligned with current global HBNG demonstration projects (e.g. China’s “Medium-Term and Long-Term Plan for Hydrogen Energy Industry Development”) and ISO standards prioritizing 20% as a technically feasible upper limit for existing infrastructure on HBNG diffusion behavior. The study also evaluated the adequacy of current accident ventilation standards. The findings show that as leak orifice size increases the diffusion range of HBNG expands significantly with a 31.5% increase in diffusion distance and an 18.5% reduction in alarm time as the orifice diameter grows from 4 mm to 8 mm. Furthermore hydrogen blending accelerates gas diffusion with each 5% increase in HBR shortening the alarm time by approximately 1.6 s and increasing equilibrium concentrations by 0.4% vol. The current ventilation standard (12 h−1 ) was found to be insufficient to suppress concentrations below the 1% safety threshold when the HBR exceeds 5% or the orifice diameter exceeds 4 mm—thresholds derived from simulations showing that under 12 h−1 ventilation equilibrium concentrations exceed the 1% safety threshold under these conditions. To address these gaps this study proposes an adaptive ventilation strategy that uses variable-frequency drives to adjust ventilation rates in real time based on sensor feedback of gas concentrations ensuring alignment with leakage conditions thereby ensuring enhanced safety. These results provide crucial theoretical insights for the safe design of HBNG pipelines and ventilation optimization in utility tunnels.
Hydrogen Adsorbents in the Vacuum Layer of Liquid Hydrogen Containers: Materials and Applications
Oct 2025
Publication
Hydrogen serves as a key clean-energy carrier with the main hurdles lying in safe efficient transport and storage (gas or liquid) and in end-use energy conversion. Liquid hydrogen (LH) as a high-density method of storage and transportation presents cryogenic insulation as its key technical issues. In LH storage tanks the performance of high vacuum multilayer insulation (HVMLI) will decline due to hydrogen release and leakage from the microscopic pores of steel which significantly destroy the vacuum layer. The accumulation of residual gases will accelerate thermal failure shorten the service life of storage tanks and increase safety risks. Adsorption is the most effective strategy for removing residual gases. This review aims to elucidate materials methods and design approaches related to hydrogen storage. First it summarizes adsorbents used in liquid hydrogen storage tanks including cryogenic adsorbents metal oxides zeolite molecular sieves and non-volatile compounds. Second it explores experimental testing methods and applications of hydrogen adsorbents in storage tanks analyzing key challenges faced in practical applications and corresponding countermeasures. Finally it proposes research prospects for exploring novel adsorbents and developing integrated systems.
Optimization of Interfacial Bonding between Graphene-enhanced Polyethylene Liners and CFRP Composites using Plasma Treatment for Hydrogen Storage Applications
Oct 2025
Publication
As the need for sustainable hydrogen storage solutions increases enhancing the bonding interface between polymer liners and carbon fiber-reinforced polymer (CFRP) in Type IV hydrogen tanks is essential to ensure tank integrity and safety. This study investigates the effect of plasma treatment on polyethylene (PE) and PE/graphene nanoplatelets (GNP) composites to optimize bonding with CFRP simulating the liner-CFRP interface in hydrogen tanks. Initially plasma treatment effects on PE surfaces were assessed focusing on plasma energy and exposure time with key surface modifications characterized and bonding performance being evaluated. Plasma treatment on PE/GNP composites with increasing GNP content was then examined comparing the bonding effectiveness of untreated and plasma-treated samples. Wedge peel tests revealed that plasma treatment significantly enhanced PE-CFRP bonding with optimal conditions at 510 W and 180 s resulting in 212 % and 165 % increases in the wedge peel strength and fracture energy respectively. Plasma-treated PE/GNP composites with 0.75 wt.% GNP achieved a notable bonding enhancement with CFRP showing 528 % and 269 % improvements in strength and fracture energy over untreated neat PE-CFRP samples. These findings offer practical implications for improving the mechanical performance of hydrogen storage tanks contributing to safer and more efficient hydrogen storage systems for a sustainable energy future.
Optimization Scheduling of Hydrogen-Integrated Energy Systems Considering Multi-Timescale Carbon Trading Mechanisms
Mar 2025
Publication
Amidst the escalating global challenges presented by climate change carbon trading mechanisms have become critical tools for driving reductions in carbon emissions and optimizing energy systems. However existing carbon trading models constrained by fixed settlement cycles face difficulties in addressing the scheduling needs of energy systems that operate across multiple time scales. To address this challenge this paper proposes an optimal scheduling methodology for hydrogen-encompassing integrated energy systems that incorporates a multi-time-scale carbon trading mechanism. The proposed approach dynamically optimizes the scheduling and conversion of hydrogen energy electricity thermal energy and other energy forms by flexibly adjusting the carbon trading cycle. It accounts for fluctuations in energy demand and carbon emissions occurring both before and during the operational day. In the day-ahead scheduling phase a tiered carbon transaction cost model is employed to optimize the initial scheduling framework. During the day scheduling phase real-time data are utilized to dynamically adjust carbon quotas and emission ranges further refining the system’s operational strategy. Through the analysis of typical case studies this method demonstrates significant benefits in reducing carbon emission costs enhancing energy efficiency and improving system flexibility.
On the Relationship Between Pressure Collapse Rate and Nusselt Number During Sloshing in Cryogenic Liquid Hydrogen Tanks
Oct 2025
Publication
Pressure collapse in sloshing cryogenic liquid hydrogen tanks is a challenge for existing models which often diverge from experimental data. This paper presents a novel lumped-parameter model that overcomes these limitations. Based on a control volume analysis our approach simplifies the complex non-equilibrium physics into a single dimensionless ordinary differential equation governing the liquid’s temperature. We demonstrate this evolution is controlled by one key parameter: the interfacial Nusselt number (). A method for estimating directly from pressure data is also provided. Validated against literature data the model predicts final tank temperatures with deviation of 0.88K (<5% relative error) from measurements thereby explaining the associated pressure collapse. Furthermore our analysis reveals that the Nusselt number varies significantly during a single sloshing event—with calculated values ranging from a peak of 5.81 × 105 down to 7.58 × 103—reflecting the transient nature of the phenomenon.
Chemical Kinetics Properties and the Influences of Different Hydrogen Blending Ratios on Reactions of Natural Gas
Dec 2022
Publication
Hydrogen is blended with natural gas to form hydrogenated natural gas (HCNG) which is a new efficient and clean energy. CHEMKIN-PRO 19.0 software was combined with the GRI-Mech 3.0 mechanism to evaluate the capacity of H2 blending in reducing CO and CO2 emissions. Influences of H2 blending on combustion reactions of the CH4-air mixture were investigated. The results showed that the main reactants and products (CH4 CO and CO2) decreased in gradient with increasing H2 blending ratio accompanied by a shorter reaction duration and a faster reaction rate. After adding H2 important key radicals H O and OH increase significantly so that the combustion reactions become more violent. Sensitivity analysis reveals that among relevant elementary reactions of CO and CO2 R38 (with its promotional effect) and R158 (with its inhibitory effect) show the greatest sensitivity. As the H2 concentration increases the sensitivity of the two reactions (separately with promotional and inhibitory effects) decreases. Blending H2 in the natural gas can improve the combustion rate and reduce the generation of emissions CO and CO2 which is of important significance for realizing low-carbon goals and reducing air pollution.
Photocatalytic Generation of Hydrogen from a Non-carbon Source, Ammonia in Aqueous Solutions
Aug 2025
Publication
This review investigates hydrogen production via photocatalysis using ammonia a carbon-free source potentially present in wastewater. Photocatalysis offers low energy requirements and high conversion efficiency compared to electrocatalysis thermocatalysis and plasma catalysis. However challenges such as complex material synthesis low stability spectral inefficiency high costs and integration barriers hinder industrial scalability. The review addresses thermodynamic requirements reaction mechanisms and the role of pH in optimizing photocatalysis. By leveraging ammonia’s potential and advancing photocatalyst development this study provides a framework for scalable sustainable hydrogen production and simultaneous ammonia decomposition paving the way for innovative energy solutions and wastewater management.
Facilitating India’s Deep Decarbonisation Through Sector Coupling of Electricity with Green Hydrogen and Ammonia
Mar 2025
Publication
Green hydrogen and ammonia are forecast to play key roles in the deep decarbonization of the global economy. Here we explore the potential of using green hydrogen and ammonia to couple the energy agriculture and industrial sectors with India’s nationalscale electricity grid. India is an ideal test case as it currently has one of the most ambitious hydrogen programs in the world with projected electricity demands for hydrogen and ammonia production accounting for over 1500 TWh/yr or nearly 25% of India’s total electricity demand by 2050. We model the ambitious deep decarbonization of India’s electricity grid and half of its steel and fertilizer industries by 2050. We uncover modest risks for India from such a strategy with many benefits and opportunities. Our analysis suggests that a renewables-based energy system coupled with ammonia off-take sectors has the potential to dramatically reduce India’s greenhouse emissions reduce requirements for expensive long-duration energy storage or firm generating capacity reduce the curtailment of renewable energy provide valuable short-duration and long-duration load-shifting and system resilience to inter-annual weather variations and replace tens of billions of USD in ammonia and fuel imports each year. All this while potentially powering new multi-billion USD green steel and maritime fuel export industries. The key risk for India in relation to such a strategy lies in the potential for higher costs and reduced benefits if the rest of the world does not match their ambitious investment in renewables electrolyzers and clean storage technologies. We show that such a pessimistic outcome could result in the costs of green hydrogen and ammonia staying high for India through 2050 although still within the range of their gray counterparts. If on the other hand renewable and storage costs continue to decline further with continued global deployment all the above benefits could be achieved with a reduced levelized cost of hydrogen and ammonia (10–25%) potentially with a modest reduction in total energy system costs (5%). Such an outcome would have profound global implications given India’s central role in the future global energy economy establishing India’s global leadership in green shipping fuel agriculture and steel while creating an affordable sustainable and secure domestic energy supply.
Effects of the Size and Cost Reduction on a Discounted Payback Period and Levelised Cost of Energy of a Zero-export Photovoltaic System with Green Hydrogen Storage
May 2023
Publication
Zero-export photovoltaic systems are an option to transition to Smart Grids. They decarbonize the sector without affecting third parties. This paper proposes the analysis of a zero-export PVS with a green hydrogen generation and storage system. This configuration is feasible to apply by any selfgeneration entity; it allows the user to increase their resilience and independence from the electrical network. The technical issue is simplified because the grid supplies no power. The main challenge is finding an economic balance between the savings in electricity billing proportional to the local electricity rate and the complete system’s investment operation and maintenance expenses. This manuscript presents the effects of the power sizing on the efficacy of economic savings in billing (ηSaving ) and the effects of the cost reduction on the levelized cost of energy (LCOE) and a discounted payback period (DPP) based on net present value. In addition this study established an analytical relationship between LCOE and DPP. The designed methodology pro poses to size and selects systems to use and store green hydrogen from the zero-export photo voltaic system. The input data in the case study are obtained experimentally from the Autonomous University of the State of Quintana Roo located on Mexico’s southern border. The maximum power of the load is LPmax = 500 kW and the average power is LPmean = 250 kW; the tariff of the electricity network operator has hourly conditions for a medium voltage demand. A suggested semi-empirical equation allows for determining the efficiency of the fuel cell and electrolyzer as a function of the local operating conditions and the nominal power of the com ponents. The analytical strategy the energy balance equations and the identity functions that delimit the operating conditions are detailed to be generalized to other case studies. The results are obtained by a computer code programmed in C++ language. According to our boundary conditions results show no significant savings generated by the installation of the hydrogen system when the zero-export photovoltaic system Power ≤ LPmax and DPP ≤ 20 years is possible only with LCOE ≤ 0.1 $/kWh. Specifically for the Mexico University case study zero-export photovoltaic system cost must be less than 310 $/kW fuel cell cost less than 395 $/kW and electrolyzer cost less than 460 $/kW.
A Review of the Enhancement of Bio-Hydrogen Generation by Chemicals Addition
Apr 2019
Publication
Bio-hydrogen production (BHP) produced from renewable bio-resources is an attractive route for green energy production due to its compelling advantages of relative high efficiency cost-effectiveness and lower ecological impact. This study reviewed different BHP pathways and the most important enzymes involved in these pathways to identify technological gaps and effective approaches for process intensification in industrial applications. Among the various approaches reviewed in this study a particular focus was set on the latest methods of chemicals/metal addition for improving hydrogen generation during dark fermentation (DF) processes; the up-to-date findings of different chemicals/metal addition methods have been quantitatively evaluated and thoroughly compared in this paper. A new efficiency evaluation criterion is also proposed allowing different BHP processes to be compared with greater simplicity and validity
Performance Analysis of Yellow Hydrogen Production in the UAE
Jan 2025
Publication
This study offers a novel techno-economic evaluation of a small hydrogen generation system included into a residential villa in Sharjah. The system is designed to utilize solar energy for hydrogen production using an electrolyzer. The study assesses two scenarios: one lacking a fuel cell and the other incorporating a fuel cell stack for backup power. The initial scenario employs a solar-powered electrolyzer for hydrogen production attaining a competitive levelized cost of energy (LCOE) of $0.1846 per kWh and a hydrogen cost of $4.65 per kg. These data underscore the economic viability of utilizing electrolyzers for hydrogen generation. The system produces around 1230 kg of hydrogen per annum rendering it appropriate for many uses. Nevertheless the original investment expenditure of $73980 necessitates more optimization. The second scenario includes a 10 kW fuel cell for energy autonomy. This scenario has a marginally reduced LCOE of 0.1811 $/kWh and a cumulative net present cost of $72600. The fuel cell runs largely at night proving the efficiency of the downsizing option in decreasing capital expense. The system generates electricity from solar panels (66.1 MWh/year) and the fuel cell (16.9 MWh/year) exhibiting a multi-source power generating technique. The results indicate that scaled-down hydrogen generation systems both with and without fuel cells may offer sustainable and possibly lucrative renewable energy options for household use especially in areas with ample solar resources such as Sharjah.
The Role of Power-to-X and Domestic eFuel Production for Energy Transition and Energy Independence in Europe
Jan 2025
Publication
The ongoing global energy transition spurred by ecological concerns and by evolving political dynamics is necessitating a significant expansion of renewable energy sources. This shift towards renewables is introducing the challenge of heightened energy supply volatility and it underscores the imperative for large-scale storage solutions in order to mitigate fluctuations in demand and supply. This study investigates the potential of Power-to-X (P2X) technologies to address this challenge and it evaluates their technical and socioeconomic implications. Using scenario simulations that leverage the maximum estimated potentials of renewable energy sources relative to demand profiles across different countries we explore the role of P2X integration in the enhancement of energy production. Our analysis highlights the pivotal role of hydrogen in the decarbonization of key industrial sectors such as steel production and heavyduty transportation in the near term. For Germany we observe a reduction in CO2 emissions from 306.26 Mt to 232.28 Mt (-24.15%) and an increase in energy independence as measured by the reduction in primary energy imports from 1150.37 TWh to 887.86 TWh (-22.82%) when comparing the baseline scenario to the most socio-economically favorable scenario. France demonstrates even greater reductions with CO2 emissions decreasing by 37.69% and primary energy imports by 40.46%. Portugal achieves similar reductions with CO2 emissions falling by 38.71% and primary energy imports by 41.81%. However none of the three countries investigated in this study (Germany France and Portugal) achieve full decarbonization and energy independence simultaneously since their respective potential for renewable energy is not sufficiently large. Drawing from these insights and accounting for the unique contexts of each of the three countries we offer tailored policy recommendations for optimizing P2X utilization and enhancing energy production efficiency.
Ensuring Southern Spain’s Energy Future: A LEAP-Based Scenario for Meeting 2030 and 2050 Goals
Aug 2025
Publication
The transition towards a low-carbon energy system remains a critical challenge for regions heavily dependent on fossil fuels such as Andalusia. This study proposes an energy planning framework based on the Low Emissions Analysis Platform (LEAP) to model alternative scenarios and assess the feasibility of meeting the 2030 and 2050 decarbonisation targets. Three scenarios are evaluated the Tendential Scenario (TS01) the Efficient Scenario (ES01) and the Efficient UJA (EEUJA) Scenario with this last being specifically designed to ensure full compliance with regional energy goals. The results indicate that while the Tendential Scenario falls short in reducing primary energy consumption and greenhouse gas (GHG) emissions the Efficient Scenario achieves significant progress though it is still insufficient to meet renewable energy integration targets. The proposed EEUJA Scenario introduces more ambitious measures including large-scale electrification smart grids energy storage and green hydrogen deployment resulting in a 39.5% reduction in primary energy demand by 2030 and 97% renewable energy penetration by 2050. Furthermore by implementing sector-specific decarbonisation strategies for the industry transport residential and services sectors Andalusia could position itself as a frontrunner in the energy transition while minimising economic and environmental risks. These findings underscore the importance of policy enforcement technological innovation and financial incentives in securing a sustainable energy future. The methodology developed in this study is replicable for other regions aiming for carbon neutrality and energy resilience through strategic planning and scenario analysis.
Fundamentals of Innovative Aircraft Heat Exchanger Integration for Hydrogen–Electric Propulsion
Apr 2025
Publication
The potential of utilizing the rejected heat of a fuel cell system to improve the aircraft propulsive efficiency is discussed for various flight conditions. The thermodynamic background of the process and the connection of power consumption in the fan of the ducted propulsor and fuel cell heat are given and a link between these two components is presented. A concept that goes beyond the known ram heat exchanger is discussed which outlines the potential benefits of integrating a fan upstream of the heat exchanger. The influence of the fan pressure ratio flight speed and altitude as well as the temperature level of the available fuel cell heat on the propulsive efficiency is presented. A correlation between the fan pressure ratio flight speed and exchangeable fuel cell heat is established providing a simplified computational approach for evaluating feasible operating conditions within this process. This paper identifies the challenges of heat exchanger integration at International Standard Atmosphere sea level conditions and its benefits for cruise flight conditions. The results show that for a flight Mach number of 0.8 and a fan pressure ratio of 1.5 at a cruising altitude of 11000 m the propulsion efficiency increases by approximately 8 percentage points compared to a ducted propulsor without heat utilization. Under sealevel conditions the concept does not offer any performance advantages over a ducted propulsor. Instead it exhibits either comparable or reduced propulsive efficiency.
Socio-Economic Impact Assessment of Hydrogen Injection in the Natural Gas Network
Feb 2025
Publication
This study explores the feasibility parameters of a potential investment plan for injecting “green” hydrogen into the existing natural gas supply network in Greece. To this end a preliminary profitability optimization analysis was conducted through key performance indicators such as the cost of hydrogen and the socio-environmental benefit of carbon savings followed by break-even and sensitivity analyses. The identification of the major impact drivers of the assessment was based on the examination of a set of operational scenarios of varying hydrogen and natural gas flow rates. The results show that high natural gas capacities with a 5% hydrogen content by volume are the optimal case in terms of socio-economic viability but the overall profitability is too sensitive to hydrogen pricing rendering it unfeasible without additional motives measures and pricing strategies. The results feed into the main challenge of implementing commercial “green” hydrogen infrastructures in the market in a sustainable and feasible manner.
Hydrogen Purity: Influence of Production Methods, Purification Techniques, and Analytical Approaches
Feb 2025
Publication
Hydrogen purity plays a crucial role in the expanding hydrogen economy particularly in applications such as fuel cells and industrial processes. This review investigates the relationship between hydrogen production methods and resulting purity levels emphasizing the differences between reforming electrolysis and biomass-based techniques. Furthermore it explores state-of-the-art purification technologies including pressure swing adsorption (PSA) membrane separation and cryogenic distillation highlighting their effectiveness and limitations in achieving ultra-pure hydrogen. Analytical methods such as gas chromatography mass spectrometry and cavity ring-down spectroscopy are also discussed in terms of their accuracy and application scope for hydrogen quality assessment. By integrating findings from global and domestic studies this paper aims to provide a comprehensive understanding of the challenges and advancements in hydrogen purity offering insights into optimizing hydrogen for a sustainable energy future.
Simulation and Feasibility Assessment of a Green Hydrogen Supply Chain: A Case Study in Oman
Feb 2024
Publication
The transition to sustainable energy is crucial for mitigating climate change impacts. This study addresses this imperative by simulating a green hydrogen supply chain tailored for residential cooking in Oman. The supply chain encompasses solar energy production underground storage pipeline transportation and residential application aiming to curtail greenhouse gas emissions and reduce the levelized cost of hydrogen (LCOH). The simulation results suggest leveraging a robust 7 GW solar plant. Oman achieves an impressive annual production of 9.78 TWh of green hydrogen equivalent to 147808 tonnes of H2 perfectly aligning with the ambitious goals of Oman Vision 2040. The overall LCOH for the green hydrogen supply chain is estimated at a highly competitive 6.826 USD/kg demonstrating cost competitiveness when benchmarked against analogous studies. A sensitivity analysis highlights Oman’s potential for cost-efective investments in green hydrogen infrastructure propelling the nation towards a sustainable energy future. This study not only addresses the pressing issue of reducing carbon emissions in the residential sector but also serves as a model for other regions pursuing sustainable energy transitions. The developed simulation models are publicly accessible at https://hychain.co.uk providing a valuable resource for further research and development in the feld of green hydrogen supply chains.
Configuring Hydrogen Lancing to Reduce Carbon and Nitrogen Oxides Emissions from Coal-fire Rotary Kilns
Mar 2025
Publication
Coal replacement with hydrogen is a strategy for reducing carbon emissions from high-temperature industrial processes. Hydrogen lancing is a direct way for introducing hydrogen to existing coal-fired kilns. This work investigates the effects of hydrogen lancing on nitrogen oxides (NOx) emissions and ignition behaviour in a pilotscale furnace that employs a 30 % coal replacement with hydrogen lancing. The investigation encompasses the impacts of lancing distance angling and velocity. Advanced measurement techniques including spectrometry and monochromatic digital cameras characterise the flame and assess emissions. The results indicate that the 30 % coal replacement by hydrogen lancing enhances combustion and reduces the emissions of carbon monoxides (CO). The flame characteristics vary with the location of the hydrogen injection generally becoming more-intense than during coal combustion. NOx emissions during lancing are similar or up to double the emissions observed for pure coal combustion depending on the lancing configuration. Increasing the distance between the hydrogen lance and coal burner increases NOx emissions.
Natural Hydrogen in Uruguay: Catalog of H2-Generating Rocks, Prospective Exploration Areas, and Potential Systems
Feb 2025
Publication
The increasing demand for carbon-free energy in recent years has positioned hydrogen as a viable option. However its current production remains largely dependent on carbon-emitting sources. In this context natural hydrogen generated through geological processes in the Earth’s subsurface has emerged as a promising alternative. The present study provides the first national-scale assessment of natural dihydrogen (H2) potential in Uruguay by developing a catalog of potential H2-generating rocks identifying prospective exploration areas and proposing H2 systems there. The analysis includes a review of geological and geophysical data from basement rocks and onshore sedimentary basins. Uruguay stands out as a promising region for natural H2 exploration due to the significant presence of potential H2-generating rocks in its basement such as large iron formations (BIFs) radioactive rocks and basic and ultrabasic rocks. Additionally the Norte Basin exhibits potential efficient cap rocks including basalts and dolerites with geological analogies to the Mali field. Indirect evidence of H2 in a free gas phase has been observed in the western Norte Basin. This suggests the presence of a potential H2 system in this area linked to the Arapey Formation basalts (seal) and Mesozoic sandstones (reservoir). Furthermore the proposed H2 system could expand exploration opportunities in northeastern Argentina and southern Brazil given the potential presence of similar play/tramp.
Integrated Design and Construction of a 50 kW Flexible Hybrid Renewable Power Hydrogen System Testbed
Mar 2025
Publication
We report on the first stage of an energy systems integration project to develop hybrid renewable energy generation and storage of hydrogen for subsequent use via research-based low regret system testbeds. This study details the design and construction of a flexible plug-and-play hybrid renewable power and hydrogen system testbed with up to 50 kW capacity aimed at addressing and benchmarking the operational parameters of the system as well as key components when commissioned. The system testbed configuration includes three different solar technologies three different battery technologies two different electrolyser technologies hydrogen storage and a fuel cell for regenerative renewable power. Design constraints include the current limit of an AC microgrid regulations for grid-connected inverters power connection inefficiencies and regulated hazardous area approval. We identify and show the resolution of systems integration challenges encountered during construction that may benefit planning for the emerging pilot or testbed configurations at other sites. These testbed systems offer the opportunity for informed decisions on economic viability for commercial-scale industry applications.
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