Publications
In the Green? Perceptions of Hydrogen Production Methods Among the Norwegian Public
Feb 2023
Publication
This article presents findings from a representative survey fielded through the Norwegian Citizen Panel examining public perceptions of hydrogen fuel and its different production methods. Although several countries including Norway have strategies to increase the production of hydrogen fuel our results indicate that hydrogen as an energy carrier and its different production methods are still unknown to a large part of the public. A common misunderstanding seems to be confusing ‘hydrogen fuel’ in general with environmentally friendly ‘green hydrogen’. Results from a survey experiment (N = 1906) show that production method is important for public acceptance. On a five-point acceptance scale respondents score on average 3.9 for ‘green’ hydrogen which is produced from renewable energy sources. The level of acceptance is significantly lower for ‘blue’ (3.2) and ‘grey’ (2.3) hydrogen when respondents are informed that these are produced from coal oil or natural gas. Public support for hydrogen fuel in general as well as the different production methods is also related to their level of worry about climate change gender and political affiliation. Widespread misunderstandings regarding ‘green’ hydrogen production could potentially fuel public resistance as new ‘blue’ or ‘grey’ projects develop. Our results indicate a need for clearer communication from the government and developers regarding production methods to avoid distrust and potential public backfire.
Solar Water Splitting by Photovoltaic-electrolysis with a Solar-to-hydrogen Efficiency over 30%
Oct 2016
Publication
Hydrogen production via electrochemical water splitting is a promising approach for storing solar energy. For this technology to be economically competitive it is critical to develop water splitting systems with high solar-to-hydrogen (STH) efficiencies. Here we report a photovoltaic-electrolysis system with the highest STH efficiency for any water splitting technology to date to the best of our knowledge. Our system consists of two polymer electrolyte membrane electrolysers in series with one InGaP/GaAs/GaInNAsSb triple-junction solar cell which produces a large-enough voltage to drive both electrolysers with no additional energy input. The solar concentration is adjusted such that the maximum power point of the photovoltaic is well matched to the operating capacity of the electrolysers to optimize the system efficiency. The system achieves a 48-h average STH efficiency of 30%. These results demonstrate the potential of photovoltaic-electrolysis systems for cost-effective solar energy storage.
Hydrogen Energy as Future of Sustainable Mobility
May 2022
Publication
Conventional fuels for vehicular applications generate hazardous pollutants which have an adverse effect on the environment. Therefore there is a high demand to shift towards environment-friendly vehicles for the present mobility sector. This paper highlights sustainable mobility and specifically sustainable transportation as a solution to reduce GHG emissions. Thus hydrogen fuel-based vehicular technologies have started blooming and have gained significance following the zero-emission policy focusing on various types of sustainable motilities and their limitations. Serving an incredible deliverance of energy by hydrogen fuel combustion engines hydrogen can revolution various transportation sectors. In this study the aspects of hydrogen as a fuel for sustainable mobility sectors have been investigated. In order to reduce the GHG (Green House Gas) emission from fossil fuel vehicles researchers have paid their focus for research and development on hydrogen fuel vehicles and proton exchange fuel cells. Also its development and progress in all mobility sectors in various countries have been scrutinized to measure the feasibility of sustainable mobility as a future. This paper is an inclusive review of hydrogen-based mobility in various sectors of transportation in particular fuel cell cars that provides information on various technologies adapted with time to add more towards perfection. When compared to electric vehicles with a 200-mile range fuel cell cars have a lower driving cost in all of the 2035 and 2050 scenarios. To stimulate the use of hydrogen as a passenger automobile fuel the cost of a hydrogen fuel cell vehicle (FCV) must be brought down to at least the same level as an electric vehicle. Compared to gasoline cars fuel cell vehicles use 43% less energy and generate 40% less CO2.
Effect of Relative Permeability Hysteresis on Reservoir Simulation of Underground Hydrogen Storage in an Offshore Aquifer
Mar 2023
Publication
Underground hydrogen storage (UHS) in porous media is proposed to balance seasonal fluctuations between demand and supply in an emerging hydrogen economy. Despite increasing focus on the topic worldwide the understanding of hydrogen flow in porous media is still not adequate. In particular relative permeability hys teresis and its impact on the storage performance require detailed investigations due to the cyclic nature of H2 injection and withdrawal. We focus our analysis on reservoir simulation of an offshore aquifer setting where we use history matched relative permeability to study the effect of hysteresis and gas type on the storage efficiency. We find that omission of relative permeability hysteresis overestimates the annual working gas capacity by 34 % and the recovered hydrogen volume by 85 %. The UHS performance is similar to natural gas storage when using hysteretic hydrogen relative permeability. Nitrogen relative permeability can be used to model the UHS when hysteresis is ignored but at the cost of the accuracy of the bottom-hole pressure predictions. Our results advance the understanding of the UHS reservoir modeling approaches.
Recent Advances of Metal Borohydrides for Hydrogen Storage
Aug 2022
Publication
Hydrogen energy is an excellent carrier for connecting various renewable energy sources and has many advantages. However hydrogen is flammable and explosive and its density is low and easy to escape which brings inconvenience to the storage and transportation of hydrogen. Therefore hydrogen storage technology has become one of the key steps in the application of hydrogen energy. Solid-state hydrogen storage method has a very high volumetric hydrogen density compared to the traditional compressed hydrogen method. The main issue of solid-state hydrogen storage method is the development of advanced hydrogen storage materials. Metal borohydrides have very high hydrogen density and have received much attention over the past two decades. However high hydrogen sorption temperature slow kinetics and poor reversibility still severely restrict its practical applications. This paper mainly discusses the research progress and problems to be solved of metal borohydride hydrogen storage materials for solid-state hydrogen storage.
Coal Decarbonization: A State-of-the-art Review of Enhanced Hydrogen Production in Underground Coal Gasification
Aug 2022
Publication
The world is endowed with a tremendous amount of coal resources which are unevenly distributed in a few nations. While sustainable energy resources are being developed and deployed fossil fuels dominate the current world energy consumption. Thus low-carbon clean technologies like underground coal gasification (UCG) ought to play a vital role in energy supply and ensuring energy security in the foreseeable future. This paper provides a state-of-the-art review of the world's development of UCG for enhanced hydrogen production. It is revealed that the world has an active interest in decarbonizing the coal industry for hydrogen-oriented research in the context of UCG. While research is ongoing in multiple coal-rich nations China dominates the world's efforts in both industrial-scale UCG pilots and laboratory experiments. A variety of coal ranks were tested in UCG for enhanced hydrogen output and the possibilities of linking UCG with other prospective technologies had been proposed and critically scrutinized. Moreover it is found that transborder collaborations are in dire need to propel a faster commercialization of UCG in an ever-more carbon-conscious world. Furthermore governmental and financial support is necessary to incentivize further UCG development for large-scale hydrogen production.
Sustainable Ammonia Production Processes
Mar 2021
Publication
Due to the important role of ammonia as a fertilizer in the agricultural industry and its promising prospects as an energy carrier many studies have recently attempted to find the most environmentally benign energy efficient and economically viable production process for ammonia synthesis. The most commonly utilized ammonia production method is the Haber-Bosch process. The downside to this technology is the high greenhouse gas emissions surpassing 2.16 kgCO2-eq/kg NH3 and high amounts of energy usage of over 30 GJ/tonne NH3 mainly due to the strict operational conditions at high temperature and pressure. The most widely adopted technology for sustainable hydrogen production used for ammonia synthesis is water electrolysis coupled with renewable technologies such as wind and solar. In general a water electrolyzer requires a continuous supply of pretreated water with high purity levels for its operation. Moreover for production of 1 tonne of hydrogen 9 tonnes of water is required. Based on this data for the production of the same amount of ammonia through water electrolysis 233.6 million tonnes/yr of water is required. In this paper a critical review of different sustainable hydrogen production processes and emerging technologies for sustainable ammonia synthesis along with a comparative life cycle assessment of various ammonia production methods has been carried out. We find that through the review of each of the studied technologies either large amounts of GHG emissions are produced or high volumes of pretreated water is required or a combination of both these factors occur.
Chile and its Potential Role Among the Most Affordable Green Hydrogen Producers in the World
Jul 2022
Publication
As result of the adverse effects caused by climate change the nations have decided to accelerate the transition of the energy matrix through the use of non-conventional sources free of polluting emissions. One of these alternatives is green hydrogen. In this context Chile stands out for the exceptional climate that makes it a country with a lot of renewable resources. Such availability of resources gives the nation clear advantages for hydrogen production strong gusts of wind throughout the country the most increased solar radiation in the world lower cost of production of electrical supplies among others. Due to this the nation would be between the lowest estimated cost for hydrogen production i.e. 1.5 USD/kg H2 approximately scenario that would place it as one of the cheapest green hydrogen producer in the world.
Assessing the Social Acceptance of Key Technologies for the German Energy Transition
Jan 2022
Publication
Background: The widespread use of sustainable energy technologies is a key element in the transformation of the energy system from fossil-based to zero-carbon. In line with this technology acceptance is of great importance as resistance from the public can slow down or hinder the construction of energy technology projects. The current study assesses the social acceptance of three energy technologies relevant for the German energy transition: stationary battery storage biofuel production plants and hydrogen fuel station. Methods: An online survey was conducted to examine the public’s general and local acceptance of energy technologies. Explored factors included general and local acceptance public concerns trust in relevant stakeholders and attitudes towards financial support. Results: The results indicate that general acceptance for all technologies is slightly higher than local acceptance. In addition we discuss which public concerns exist with regard to the respective technologies and how they are more strongly associated with local than general acceptance. Further we show that trust in stakeholders and attitudes towards fnancial support is relatively high across the technologies discussed. Conclusions: Taken together the study provides evidence for the existence of a “general–local” gap despite measuring general and local acceptance at the same level of specifcity using a public sample. In addition the collected data can provide stakeholders with an overview of worries that might need to be addressed when planning to implement a certain energy project.
The Effects of Fuel Type and Cathode Off-gas Recirculation on Combined Heat and Power Generation of Marine SOFC Systems
Dec 2022
Publication
An increasing demand in the marine industry to reduce emissions led to investigations into more efficient power conversion using fuels with sustainable production pathways. Solid Oxide Fuel Cells (SOFCs) are under consideration for long-range shipping because of its high efficiency low pollutant emissions and fuel flexibility. SOFC systems also have great potential to cater for the heat demand in ships but the heat integration is not often considered when assessing its feasibility. This study evaluates the electrical and heat efficiency of a 100 kW SOFC system for marine applications fuelled with methane methanol diesel ammonia or hydrogen. In addition cathode off-gas recirculation (COGR) is investigated to tackle low oxygen utilisation and thus improve heat regeneration. The software Cycle Tempo is used to simulate the power plant which uses a 1D model for the SOFCs. At nominal conditions the highest net electrical efficiency (LHV) was found for methane (58.1%) followed by diesel (57.6%) and ammonia (55.1%). The highest heat efficiency was found for ammonia (27.4%) followed by hydrogen (25.6%). COGR resulted in similar electrical efficiencies but increased the heat efficiency by 11.9% to 105.0% for the different fuels. The model was verified with a sensitivity analysis and validated by comparison with similar studies. It is concluded that COGR is a promising method to increase the heat efficiency of marine SOFC systems.
Thermocatalytic Hydrogen Production Through Decomposition of Methane-A Review
Oct 2021
Publication
Consumption of fossil fuels especially in transport and energy-dependent sectors has led to large greenhouse gas production. Hydrogen is an exciting energy source that can serve our energy purposes and decrease toxic waste production. Decomposition of methane yields hydrogen devoid of COx components thereby aiding as an eco-friendly approach towards large-scale hydrogen production. This review article is focused on hydrogen production through thermocatalytic methane decomposition (TMD) for hydrogen production. The thermodynamics of this approach has been highlighted. Various methods of hydrogen production from fossil fuels and renewable resources were discussed. Methods including steam methane reforming partial oxidation of methane auto thermal reforming direct biomass gasification thermal water splitting methane pyrolysis aqueous reforming and coal gasification have been reported in this article. A detailed overview of the different types of catalysts available the reasons behind their deactivation and their possible regeneration methods were discussed. Finally we presented the challenges and future perspectives for hydrogen production via TMD. This review concluded that among all catalysts nickel ruthenium and platinum-based catalysts show the highest activity and catalytic efficiency and gave carbon-free hydrogen products during the TMD process. However their rapid deactivation at high temperatures still needs the attention of the scientific community.
The Hydrogen Bike: Communicating the Production and Safety of Green Hydrogen
Mar 2021
Publication
As the international community aims to reduce its reliance on fossil fuels green hydrogen has great potential to replace methane as a clean source of fuel. A novel public engagement activity The Hydrogen Bike has been developed to demonstrate the production and use of green hydrogen from water. The aim of the activity is to educate entertain and inform young people and adults so that they have an opportunity to form an opinion about the use of hydrogen as a fuel. Using a novel two-part data collection system participants are briefly surveyed for their opinion on hydrogen before and after participating in The Hydrogen Bike activity. Through this we have found that most participants (73%) are considered to have no opinion or a neutral opinion on hydrogen before participating in The Hydrogen Bike activity. After participation 88% of those who were originally neutral or had no opinion on hydrogen self-reported a positive feeling about hydrogen. The method of data collection was quick intuitive and suitable for an audience attracted from passing footfall.
Risk Perception of an Emergent Technology: The Case of Hydrogen Energy
Jan 2006
Publication
Although hydrogen has been used in industry for many years as a chemical commodity its use as a fuel or energy carrier is relatively new and expert knowledge about its associated risks is neither complete nor consensual. Public awareness of hydrogen energy and attitudes towards a future hydrogen economy are yet to be systematically investigated. This paper opens by discussing alternative conceptualisations of risk then focuses on issues surrounding the use of emerging technologies based on hydrogen energy. It summarises expert assessments of risks associated with hydrogen. It goes on to review debates about public perceptions of risk and in doing so makes comparisons with public perceptions of other emergent technologies—Carbon Capture and Storage (CCS) Genetically Modified Organisms and Food (GM) and Nanotechnology (NT)—for which there is considerable scientific uncertainty and relatively little public awareness. The paper finally examines arguments about public engagement and "upstream" consultation in the development of new technologies. It is argued that scientific and technological uncertainties are perceived in varying ways and different stakeholders and different publics focus on different aspects or types of risk. Attempting to move public consultation further "upstream" may not avoid this because the framing of risks and benefits is necessarily embedded in a cultural and ideological context and is subject to change as experience of the emergent technology unfolds.
Analysis of the Implementation of Functional Hydrogen Assumptions in Poland and Germany
Nov 2022
Publication
The use of hydrogen exists in various sectors in Poland and Germany. Hydrogen can be used in industry transport decarbonisation of the Polish steel industry and as one of the low-emission alternatives to the existing coal applications in this sector. Limiting climate change requires efforts on a global scale from all countries of the world. Significant economic benefits will be realized by stimulating the development of new technologies to deal with climate change. The scenarios show an increasing demand for industrial hydrogen in the future. The key is to replace gray hydrogen with green and to convert industrial processes which will create additional hydrogen demand. The condition for the development of a green hydrogen economy is access to adequate installed capacity in renewable energy. Germany will become the leading market in the era of energy transformation in the coming years. The implementation of the hydrogen assumptions in Poland is possible to a greater extent by the efforts of entrepreneurs
Evidence Base Utilised to Justify a Hydrogen Blend Gas Network Safety Case
Sep 2021
Publication
Blending hydrogen with natural gas up to 20 % mol/mol has been identified as a key enabler of hydrogen deployment within the UK gas network. This work outlines the evidence base generated to form the basis of safety submitted to the Health and Safety Executive (HSE) to justify a demonstration of hydrogen blending on a live public gas network within the UK supplying a hydrogen blend to 668homes over the course of 10 months. An evidence base to demonstrate that gas users are not prejudiced by the addition of hydrogen is required by the Gas Safety (Management) Regulations [1] to allow hydrogen distribution above the 0.1 mol% limit specified within the regulations. The technical evidence generated to support the safety case presented to the HSE concerned the implications of introducing a hydrogen blend on appliance operation materials gas characteristics and operational procedures. The outputs of the technical evidence workstreams provided input data to a Quantitative Risk Assessment (QRA) of the GB gas distribution network. The QRA was developed in support of the safety case to allow a causal understanding of public risk to be understood where harm due to gas usage was defined as risk to life caused either by carbon monoxide poisoning or as a result of fires/explosions. Public records were used to calibrate and validate the base risk model to understand the dynamics of public risk due to natural gas usage. The experimental and analytical results of the technical workstreams were then used to derive risk model inputs relating to a hydrogen blend. This allowed a quantified comparison of risk to be understood to demonstrate parity of safety between natural gas and a hydrogen blend. This demonstration of risk parity is a condition precedent of allowing the distribution and utilisation of hydrogen blends within the GB gas network.
Greenhouse Gas Emission Dynamics of Saudi Arabia: Potential of Hydrogen Fuel for Emission Footprint Reduction
Mar 2023
Publication
The growth of population gross domestic product (GDP) and urbanization have led to an increase in greenhouse gas (GHG) emissions in the Kingdom of Saudi Arabia (KSA). The leading GHG-emitting sectors are electricity generation road transportation cement chemicals refinery iron and steel. However the KSA is working to lead the global energy sustainability campaign to reach net zero GHG emissions by 2060. In addition the country is working to establish a framework for the circular carbon economy (CCE) in which hydrogen acts as a transversal facilitator. To cut down on greenhouse gas emissions the Kingdom is also building several facilities such as the NEOM green hydrogen project. The main objective of the article is to critically review the current GHG emission dynamics of the KSA including major GHG emission driving forces and prominent emission sectors. Then the role of hydrogen in GHG emission reduction will be explored. Finally the researchers and decision makers will find the helpful discussions and recommendations in deciding on appropriate mitigation measures and technologies.
Analysis of Hydrogen Gas Injection at Various Compositions in an Existing Natural Gas Pipeline
Jul 2021
Publication
The lack of hydrogen (H2) transportation infrastructure restricts the development of the H2 industry. Owing to the high investment of building specific facilities using existing natural gas (NG) pipelines to transport a blend of H2 and NG (H2NG) is a viable means of transportation and approach for large-scale long-time storage. However variation in the thermo-physical properties of an H2NG blend will impact the performance of pipeline appliances. To address the gaps in H2 transmission via an NG system in the context of energy consumption in the present paper a one-dimensional pipeline model is proposed to predict the blended flow in a real existing pipeline (Shan–Jing I China). The data of NG components were derived from real gas fields. Furthermore the influence of H2 fractions on pipeline energy coefficient and the layout of pressurization stations are comprehensively analyzed. In addition the case of intermediate gas injection is investigated and the effects of injection positions are studied. This study serves as a useful reference for the design of an H2NG pipeline system. The present study reveals that with the increasing in H2 fraction the distance between pressure stations increases. Furthermore when the arrangement of original pressure stations is maintained overpressure occur. Intermediate gas injection results in the inlet pressure of subsequent pressurization stations reducing. Using existing pipeline network to transport H2NG it is necessary to make appropriate adjustment.
Techno Environmental Assessment of Flettner Rotor as Assistance Propulsion System for LH2 Tanker Ship Fuelled by Hydrogen
Nov 2022
Publication
This study presents a novel design and development of a 280000 m3 liquefied hydrogen tanker ship by implementing a set of 6 Flettner rotors as an assistance propulsion system in conjunction with a combined-cycle gas turbine fuelled by hydrogen as a prime mover. The study includes assessment of the technical and environmental aspects of the developed design. Furthermore an established method was applied to simulate the LH2 tanker in different voyages and conditions to investigate the benefits of harnessing wind energy to assist combined-cycle gas turbine in terms of performance and emission reduction based on engine behaviour for different voyages under loaded and unloaded normal as well as 6 % degraded engine and varying ambient conditions. The results indicate that implementing a set of 6 Flettner rotors for the LH2 tanker ship has the potential to positively impact the performance and lead to environmental benefits. A maximum contribution power of around 1.8 MW was achieved in the winter season owing to high wind speed and favourable wind direction. This power could save approximately 3.6 % of the combined-cycle gas turbine total output power (50 MW) and cause a 3.5 % reduction in NOx emissions.
Hydrogen Compatability of Structural Materials in Natural Gas Networks
Sep 2021
Publication
There is growing interest in utilizing existing infrastructure for storage and distribution of hydrogen. Gaseous hydrogen for example could be added to natural gas in the short-term whereas entire systems can be converted to transmission and distribution networks for hydrogen. Many active programs around the world are exploring the safety and feasibility of adding hydrogen to these networks. Concerns have been raised about the structural integrity of materials in these systems when exposed to hydrogen. In general the effects of hydrogen on these materials are grossly misunderstood. Hydrogen unequivocally degrades fatigue and fracture resistance of structural steels in these systems even for low hydrogen partial pressure (-l bar). In most systems however hydrogen effects will not be apparent because the stresses in these systems remain very low. Another misunderstanding results from the kinetics of the hydrogen effects: hydrogen degrades fatigue and fracture properties immediately upon exposure to gaseous hydrogen and those effects disappear when the hydrogen environment is removed even after prolonged exposure. There is also a misperception that materials selection can mitigate hydrogen effects. While some classes of materials perform better in hydrogen environments than other classes for most practical circumstances the range of response for a given class of material in gaseous hydrogen environments is rather narrow. These observations can be systematically characterized by considering the intersection of materials environmental and mechanical variables associated with the service application. Indeed any safety assessment of a hydrogen pressure system must quantitatively consider these aspects. In this report we quantitatively evaluate the importance of the materials environmental and mechanical variables in the context of hydrogen additions to natural gas piping and pipeline systems with the aim of providing an informed perspective on parameters relevant for assessing structural integrity of natural gas systems in the presence of gaseous hydrogen.
Review and Harmonization of the Life-Cycle Global Warming Impact of PV-Powered Hydrogen Production by Electrolysis
Sep 2021
Publication
This work presents a review of life-cycle assessment (LCA) studies of hydrogen electrolysis using power from photovoltaic (PV) systems. The paper discusses the assumptions strengths and weaknesses of 13 LCA studies and identifies the causes of the environmental impact. Differences in assumptions of system boundaries system sizes evaluation methods and functional units make it challenging to directly compare the Global Warming Potential (GWP) resulting from different studies. To simplify this process 13 selected LCA studies on PV-powered hydrogen production have been harmonized following a consistent framework described by this paper. The harmonized GWP values vary from 0.7 to 6.6 kg CO2-eq/kg H2 which can be considered a wide range. The maximum absolute difference between the original and harmonized GWP results of a study is 1.5 kg CO2-eq/kg H2. Yet even the highest GWP of this study is over four times lower than the GWP of grid-powered electrolysis in Germany. Due to the lack of transparency of most LCAs included in this review full identification of the sources of discrepancies (methods applied assumed production conditions) is not possible. Overall it can be concluded that the environmental impact of the electrolytic hydrogen production process is mainly caused by the GWP of the electricity supply. For future environmental impact studies on hydrogen production systems it is highly recommended to 1) divide the whole system into well-defined subsystems using compression as the final stage of the LCA and 2) to provide energy inputs/GWP results for the different subsystems.
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