Publications
A Multi-model Assessment of the Global Warming Potential of Hydrogen
Jun 2023
Publication
With increasing global interest in molecular hydrogen to replace fossil fuels more attention is being paid to potential leakages of hydrogen into the atmosphere and its environmental consequences. Hydrogen is not directly a greenhouse gas but its chemical reactions change the abundances of the greenhouse gases methane ozone and stratospheric water vapor as well as aerosols. Here we use a model ensemble of five global atmospheric chemistry models to estimate the 100-year time-horizon Global Warming Potential (GWP100) of hydrogen. We estimate a hydrogen GWP100 of 11.6 ± 2.8 (one standard deviation). The uncertainty range covers soil uptake photochemical production of hydrogen the lifetimes of hydrogen and methane and the hydroxyl radical feedback on methane and hydrogen. The hydrogeninduced changes are robust across the different models. It will be important to keep hydrogen leakages at a minimum to accomplish the benefits of switching to a hydrogen economy.
Multi-Seasonal Risk Assessment of Hydrogen Leakage, Diffusion, and Explosion in Hydrogen Refueling Station
Aug 2025
Publication
To reveal the influence mechanisms of seasonal climatic factors (wind speed wind direction temperature) and leakage direction on hydrogen dispersion and explosion behavior from single-source leaks at typical risk locations (hydrogen storage tanks compressors dispensers) in hydrogen refueling stations (HRSs) this work established a full-scale 1:1 three-dimensional numerical model using the FLACS v22.2 software based on the actual layout of an HRS in Xichang Sichuan Province. Through systematic simulations of 72 leakage scenarios (3 equipment types × 4 seasons × 6 leakage directions) the coupled effects of climatic conditions equipment layout and leakage direction on hydrogen dispersion patterns and explosion risks were quantitatively analyzed. The key findings indicate the following: (1) Downward leaks (−Z direction) from storage tanks tend to form large-area ground-hugging hydrogen clouds representing the highest explosion risk (overpressure peak: 0.25 barg; flame temperature: >2500 K). Leakage from compressors (±X/−Z directions) readily affects adjacent equipment. Dispenser leaks pose relatively lower risks but specific directions (−Y direction) coupled with wind fields may drive significant hydrogen dispersion toward station buildings. (2) Southeast/south winds during spring/summer promote outward migration of hydrogen clouds reducing overall station risk but causing localized accumulation near storage tanks. Conversely north/northwest winds in autumn/winter intensify hydrogen concentrations in compressor and station building areas. (3) An empirical formula integrating climatic parameters leakage conditions and spatial coordinates was proposed to predict hydrogen concentration (error < 20%). This model provides theoretical and data support for optimizing sensor placement dynamically adjusting ventilation strategies and enhancing safety design in HRSs.
Advances in Hydrogen Storage Technologies
Jan 2025
Publication
Gaseous hydrogen storage is the most mature technology for fuel cell vehicles. The main safety concern is the catastrophic consequences of tank rupture in a fire i.e. blast waves fireballs and projectiles. This paper sum marises research on the development and validation of the breakthrough microleaks-no-burst (μLNB) safety technology of explosion-free in any fire self-venting Type IV tanks that do not require a thermally-activate pressure relief device (TPRD). The invention implies the melting of the hydrogen-tight liner of the Type IV tank before the hydrogen-leaky double-composite wall loses load-bearing ability. Hydrogen then flows through the natural microchannels in the composites and burns in microflames or together with resin. The unattainable to competitive products feature of the technology is the ability to withstand any fire from smouldering to extreme impinging hydrogen jet fires. Innovative 70 MPa tanks made of carbon-carbon carbon-glass and carbon-basalt composites were tested in characteristic for gasoline/diesel spill fires with a specific heat release rate of HRR/A = 1 MW/m2 . Standard unprotected Type III and IV tanks will explode in such intensity fire. The technology excludes hydrogen accumulation in naturally ventilated enclosures. It reduces the risk of hydrogen vehicles to an acceptable level below that of fossil fuel cars including underground parking tunnels etc. The performance of self-venting tanks is studied for fire intervention scenarios: removal from fire and fire extinction by water. It is concluded that novel tanks allow standard fire intervention strategies and tactics. Self-venting operation of the 70 MPa tank is demonstrated in extreme jet fire conditions under impinging hydrogen jet fire (70 MPa) with huge HRR/A = 19.5 MW/m2 . This technology excludes tank rupture in fires onboard trains ships and planes where hazard distances cannot be implemented i.e. provides an unprecedented level of life safety and property protection.
Safety Equipment Planning Through Experimental Analysis of Hydrogen Leakage and Ventilation in Enclosed Spaces
Aug 2025
Publication
In South Korea securing ground space for installing hydrogen refueling stations in urban areas is challenging due to limited ground space and high-density development. Safety concerns for hydrogen systems in enclosed urban environments also require careful consideration. To address this issue this study explored a method of undergrounding hydrogen infrastructure as a solution for urban hydrogen charging stations. This study examined the characteristics of hydrogen diffusion and concentration reduction under leakage conditions within a confined hydrogen infrastructure focusing on key safety systems including emergency shut-off valves (ESVs) and ventilation fans. We discovered that the ESV reduced hydrogen concentration by over 80%. Installing two or more ventilation fans arranged horizontally improves airflow and enhances ventilation efficiency. Moreover increasing the number of fans reduces stagnant zones within the space effectively lowering the average hydrogen concentration.
Retrofitted Hydrogen-Electric Propulsion Aircraft: Performance Simulation of Critical Operating Conditions
Jan 2025
Publication
Retrofitting regional turboprop aircraft with hydrogen (H2)-electric powertrains using fuel cell systems (FCSs) has gained interest in the last decade. This type of powertrain eliminates CO2 NOx and fine particle emissions during flight as FCSs only emit water. In this context the “Hydrogen Aircraft Powertrain and Storage Systems” (HAPSS) project targets the development of a H2-electric propulsion system for retrofitting Dash 8- 300 series aircraft. The purpose of the study described in this paper is to analyze the performance of the retrofitted H2-electric aircraft during critical operating conditions. Takeoff as well as climb cruise and go-around performances are addressed. The NLR in-house tool MASS (Mission Aircraft and Systems Simulation) was used for the performance analyses. The results show that the retrofitted H2-electric aircraft has a slightly increased takeoff distance compared to the Dash 8-300 and it requires a maximum rated shaft power of 1.9 MW per propeller. A total rated FCS output power of 3.1 MW is sufficient to satisfy the takeoff requirements at the cost of lower cruise altitude and reduced cruise speed as compared to the Dash 8-300. Furthermore a higher-rated FCS is required to achieve the climb performance required for the typical climb profile of the Dash 8-300.
A Techno-economic Analysis of Hydrogen Refuelling and Electric Fast-charging Stations: Effects on Cost-competitiveness of Zero-emission Trucks
Jun 2025
Publication
Hydrogen fuel cell electric trucks and battery electric trucks can significantly contribute to the decarbonisation of the heavy-duty vehicles transport segment. Nonetheless a paucity of hydrogen refuelling and fast-charging stations can represent a hindrance to the development of zero-emission vehicles. This work aims to provide a techno-economic analysis with a view to comparing the costs of hydrogen refuelling and electric charging and evaluating their effects on the total cost of ownership of zero-emission trucks. Thus a comprehensive analysis has been conducted on off-site compressed (CH2) cryo-compressed subcooled hydrogen refuelling stations in conjunction with a fast-charging station. The resulting levelized costs of hydrogen and charging have been incorporated into the total cost of ownership analysis. Thus it has been demonstrated that battery electric trucks are more costeffective than hydrogen-fuel cell electric trucks. The findings of this study indicate that the costs associated with electric charging and hydrogen refuelling are comparable and the economic profitability is contingent upon a number of techno-economic variables. Therefore it is not possible to determine a priori whether one solution is more economically competitive than the other. A mixed infrastructure can represent an opportunity for the transport sector decarbonisation whereby electric-charging and hydrogen-refuelling are not mutually exclusive.
Environmental Implications of Solid Oxide Fuel Cell System for Hydrogen Sustainability
Jan 2025
Publication
Hydrogen known for its high energy content and clean combustion is promising in the energy transition. This study explores the environmental impact of a solid oxide fuel cell (SOFC) system. 1 kg of hydrogen production at 1 bar serves as the functional unit. The SOFC system generates hydrogen electricity and heat across five modes. Results indicate that the SOFC system achieves a global warming potential of 0.17–9.50 kg CO2 -eq/FU using the system expansion method. Regional analysis shows that areas with high renewable electricity shares experience increased CO2 emissions due to functional unit decision. The exergy allocation method is less sensitive to electricity sources and seasonal emission profiles than system expansion. Comparing eight production routes the SOFC system using biomethane (−5.46 kg CO2 -eq/FU) outperforms steam methane reforming (11 kg CO2 -eq/FU) and biomass gasification (1.49 kg CO2 -eq/FU). These insights are valuable for advancing renewable energy initiatives and effectively mitigating climate change.
Numerical Study on the Characteristics of Hydrogen Leakage, Diffusion and Ventilation in Ships
Jan 2025
Publication
Hydrogen is a promising environmentally friendly fuel with the potential for zero-carbon emissions particularly in maritime applications. However owing to its wide flammability range (4–75%) significant safety concerns persist. In confined spaces hydrogen leaks can lead to explosions posing a risk to both lives and assets. This study conducts a numerical analysis to investigate hydrogen flow within hydrogen storage rooms aboard ships with the goal of developing efficient ventilation strategies. Through simulations performed using ANSYS-CFX this research evaluates hydrogen diffusion stratification and ventilation performance. A vertex angle of 120◦ at the ceiling demonstrated superior ventilation efficiency compared to that at 177◦ while air inlets positioned on side-wall floors or mid-sections proved more effective than those located near the ceiling. The most efficient ventilation occurred at a velocity of 1.82 m/s achieving 20 air exchanges per hour. These findings provide valuable insights for the design of safer hydrogen vessel operations.
Post-mortem Analysis as a Method to Identify Degradation of PEM Fuel Cells Affecting their Durability in Maritime Applications
Sep 2025
Publication
Proton exchange membrane fuel cells (PEMFCs) present great potential for the decarbonization of the maritime sector but their durability in harsh marine environments remains a critical challenge. This review focuses on post-mortem analysis techniques as a tool to understand the degradation mechanisms of PEMFCs under stressors relevant to marine applications. In further detail the application of various imaging (SEM TEM) structural (XRD) electrochemical (CV) and elemental analysis (EDS) methods to characterize the effects of key stressors such as salt spray mechanical vibration and operational cycling was examined. By analyzing degraded PEMFC components post-mortem analysis reveals critical insights into catalyst layer degradation membrane damage and the impact of impurities enabling the identification of failure modes and the development of effective mitigation strategies for the establishment of PEMFCs in the maritime sector.
Will Hydrogen and Synthetic Fuels Energize our Future? Their Role in Europe's Climate-neutral Energy System and Power System Dynamics
Aug 2024
Publication
This study evaluates the technoeconomic impacts of direct and indirect electrification on the EU's net-zero emissions target by 2050. By linking the JRC-EU-TIMES long-term energy system model with PLEXOS hourly resolution power system model this research offers a detailed analysis of the interactions between electricity hydrogen and synthetic fuel demand production technologies and their effects on the power sector. It highlights the importance of high temporal resolution power system analysis to capture the synergistic effects of these components often overlooked in isolated studies. Results indicate that direct electrification increases significantly and unimpacted by biomass CCS and nuclear energy assumptions. However indirect electrification in the form of hydrogen varies significantly between 1400 and 2200 TWhH2 by 2050. Synthetic fuels are essential for sector coupling making up 6–12% of total energy consumption by 2050 with the power sector supplying most hydrogen and CO2 for their production. Varying levels of indirect electrification impact electrolysers renewable energy and firm capacities. Higher indirect electrification increases electrolyser capacity factors by 8% leading to more renewable energy curtailment but improves system reliability by reducing 11 TWh unserved energy and increasing flexibility options. These insights inform EU energy policies stressing the need for a balanced approach to electrification biomass use and CCS to achieve a sustainable and reliable net-zero energy system by 2050. We also explore limitations and sensitivities.
Modeling and Technical-Economic Analysis of a Hydrogen Transport Network for France
Feb 2025
Publication
This work aims to study the technical and economical feasibility of a new hydrogen transport network by 2035 in France. The goal is to furnish charging stations for fuel cell electrical vehicles with hydrogen produced by electrolysis of water using low-carbon energy. Contrary to previous research works on hydrogen transport for road transport we assume a more realistic assumption of the demand side: we assume that only drivers driving more than 20000 km per year will switch to fuel cell electrical vehicles. This corresponds to a total demand of 100 TWh of electricity for the production of hydrogen by electrolysis. To meet this demand we primarily use surplus electricity production from wind power. This surplus will satisfy approximately 10% of the demand. We assume that the rest of the demand will be produced using surplus from nuclear power plants disseminated in regions. We also assume a decentralized production namely that 100 MW electrolyzers will be placed near electricity production plants. Using an optimization model we define the hydrogen transport network by considering decentralized production. Then we compare it with more centralized production. Our main conclusion is that decentralized production makes it possible to significantly reduce distribution costs particularly due to significantly shorter transport distances.
Advancing Nickel-based Catalysts for Enhanced Hydrogen Production: Innovations in Electrolysis and Catalyst Design
Feb 2025
Publication
Nickel-based catalysts recognized for their cost-efficiency and availability play a critical role in advancing hydrogen production technologies. This study evaluates their optimization in water electrolysis to improve efficiency and system stability. Key findings highlight the enhancement of these catalysts with nickel-iron oxyhydroxide and nickel-molybdenum co-catalysts. Technological innovations such as Perovskite Solar Cells integration for solar-to-hydrogen conversion are explored. The use of nickel foam enhances electrode durability offering valuable insights into designing sustainable and efficient hydrogen production systems.
Electric-thermal Collaborative System and Control for Hydrogen-fuel Cell Passenger Trains in the UK's Winter
Feb 2025
Publication
This paper presents a quantitative study on electric-thermal collaborative system for hydrogen-powered train reutilising the waste heat from fuel cell system for Heating Ventilation and Air Conditioning (HVAC). Firstly a hybrid train simulator is developed to simulate the train’s motion state. Heat generation from fuel cell is estimated using a fuel cell model while a detailed thermodynamic model for railway passenger coach is established to predict the heat demand. Furthermore an electric-thermal collaborative energy management strategy (ETCEMS) is proposed for the system to comprehensively optimise the on-train power distribution considering traction and auxiliary power. Finally comparative analysis is performed among the train with electric heater (EH) heat pump (HP) and heat pump-heat reuse (HP-HR). The results demonstrate that over a round trip the proposed HP-HR with ETC-EMS recovers over 22.88% residual heat and saves 16.17% of hydrogen consumption. For the daily operation it reduces hydrogen and energy consumption by 12.06% and 12.82 % respectively. The findings indicate that collaborative optimisation brings significant improvements on the global energy utilisation. The proposed design with ETC-EMS is potential to further enhance the economic viability of hydrail and contributes to the rail decarbonisation.
Optimizing Hydrogen Production for Sustainable Fuel Cell Electric Vehicles: Grid Impacts in the WECC Region
Jan 2025
Publication
The fuel cell electric vehicle (FCEV) is a promising transportation technology for resolving the air pollution and climate change issues in the United States. However a large-scale penetration of FCEVs would require a sustained supply of hydrogen which does not exist now. Water electrolysis can produce hydrogen reliably and sustainably if the electricity grid is clean but the impacts of FCEVs on the electricity grid are unknown. In this paper we develop a comprehensive framework to model FCEV-driving and -refueling behaviors the water electrolysis process and electricity grid operation. We chose the Western Electricity Coordinating Council (WECC) region for this case study. We modeled the existing WECC electricity grids and accounted for the additional electricity loads from FCEVs using a Production Cost Model (PCM). Additionally the hydrogen need for five million FCEVs leads to a 3% increase in electricity load for WECC. Our results show that an inflexible hydrogen-producing process leads to a 1.55% increase to the average cost of electricity while a flexible scenario leads to only a 0.9% increase. On the other hand oversized electrolyzers could take advantage of cheaper electricity generation opportunities thus lowering total system costs.
Ammonia Marine Engine Design for Enhanced Efficiency and Reduced Greenhouse Gas Emissions
Mar 2024
Publication
Pilot-diesel-ignition ammonia combustion engines have attracted widespread attentions from the maritime sector but there are still bottleneck problems such as high unburned NH3 and N2O emissions as well as low thermal efficiency that need to be solved before further applications. In this study a concept termed as in-cylinder reforming gas recirculation is initiated to simultaneously improve the thermal efficiency and reduce the unburned NH3 NOx N2O and greenhouse gas emissions of pilot-diesel-ignition ammonia combustion engine. For this concept one cylinder of the multi-cylinder engine operates rich of stoichiometric and the excess ammonia in the cylinder is partially decomposed into hydrogen then the exhaust of this dedicated reforming cylinder is recirculated into the other cylinders and therefore the advantages of hydrogen-enriched combustion and exhaust gas recirculation can be combined. The results show that at 3% diesel energetic ratio and 1000 rpm the engine can increase the indicated thermal efficiency by 15.8% and reduce the unburned NH3 by 89.3% N2O by 91.2% compared to the base/traditional ammonia engine without the proposed method. At the same time it is able to reduce carbon footprint by 97.0% and greenhouse gases by 94.0% compared to the traditional pure diesel mode.
Techno-economic Analysis and Dynamic Operation of Green Hydrogen-integrated Microgrid: An Application Study
Aug 2025
Publication
The shift to renewable energy sources requires systems that are not only environmentally sustainable but also cost-effective and reliable. Mitigating the inherent intermittency of renewable energy optimally managing the hybrid energy storage efficiently integrating the microgrid with the power grid and maximizing the lifespan of system components are the significant challenges that need to be addressed. With this aim the paper proposes an economic viability assessment framework with an optimized dynamic operation approach to determine the most stable cost-effective and environmentally sound system for a specific location and demand. The green integrated hybrid microgrid combines photovoltaic (PV) generation battery storage an electrolyzer a hydrogen tank and a fuel cell tailored for deployment in remote areas with limited access to conventional infrastructure. The study’s control strategy focuses on managing energy flows between the renewable energy resources battery and hydrogen storage systems to maximize autonomy considering real-time changes in weather conditions load variations and the state of charge of both the battery and hydrogen storage units. The core system’s components include the interlinking converter which transfers power between AC and DC grids and the decentralized droop control approach which adjusts the converter’s output to ensure balanced and efficient power sharing particularly during overload conditions. A cloud-based Internet of Things (IoT) platform has been employed allowing continuous monitoring and data analysis of the green integrated microgrid to provide insights into the system's health and performance during the dynamic operation. The results presented in this paper confirmed that the proposed framework enabled the strategic use of energy storage particularly hydrogen systems. The optimal operational control of green hydrogen-integrated microgrid can indeed mitigate voltage and frequency fluctuations caused by variable solar input ensuring stable power delivery without reliance on the main grid or fossil fuel backups.
Optimization of the Design of Underground Hydrogen Storage in Salt Caverns in Southern Ontario, Canada
Jan 2025
Publication
With the issue of energy shortages becoming increasingly serious the need to shift to sustainable and clean energy sources has become urgent. However due to the intermittent nature of most renewable energy sources developing underground hydrogen storage (UHS) systems as backup energy solutions offers a promising solution. The thick and regionally extensive salt deposits in Unit B of Southern Ontario Canada have demonstrated significant potential for supporting such storage systems. Based on the stratigraphy statistics of unit B this study investigates the feasibility and stability of underground hydrogen storage (UHS) in salt caverns focusing on the effects of cavern shape geometric parameters and operating pressures. Three cavern shapes—cylindrical cone-shaped and ellipsoid-shaped—were analyzed using numerical simulations. Results indicate that cylindrical caverns with a diameter-to-height ratio of 1.5 provide the best balance between storage capacity and structural stability while ellipsoid-shaped caverns offer reduced stress concentration but have less storage space posing practical challenges during leaching. The results also indicate that the optimal pressure range for maintaining stability and minimizing leakage lies between 0.4 and 0.7 times the vertical in situ stress. Higher pressures increase storage capacity but lead to greater stress displacements and potential leakage risks while lower pressure leads to internal extrusion tendency for cavern walls. Additionally hydrogen leakage rate drops with the maximum working pressure yet total leakage mass keeps a growing trend.
Performance Assessment and Economic Perspectives of Integrated PEM Fuel Cell and PEM Electrolyzer for Electric Power Generation
Mar 2021
Publication
The study presents a complete one-dimensional model to evaluate the parameters that describe the operation of a Proton Exchange Membrane (PEM) electrolyzer and PEM fuel cell. The mathematical modeling is implemented in Matlab/Simulink® software to evaluate the influence of parameters such as temperature pressure and overpotentials on the overall performance. The models are further merged into an integrated electrolyzer-fuel cell system for electrical power generation. The operational description of the integrated system focuses on estimating the overall efficiency as a novel indicator. Additionally the study presents an economic assessment to evaluate the cost-effectiveness based on different economic metrics such as capital cost electricity cost and payback period. The parametric analysis showed that as the temperature rises from 30 to 70 C in both devices the efficiency is improved between 5-20%. In contrast pressure differences feature less relevance on the overall performance. Ohmic and activation overpotentials are highlighted for the highest impact on the generated and required voltage. Overall the current density exhibited an inverse relation with the efficiency of both devices. The economic evaluation revealed that the integrated system can operate at variable load conditions while maintaining an electricity cost between 0.3-0.45 $/kWh. Also the capital cost can be reduced up to 25% while operating at a low current density and maximum temperature. The payback period varies between 6-10 years for an operational temperature of 70 C which reinforces the viability of the system. Overall hydrogen-powered systems stand as a promising technology to overcome energy transition as they provide robust operation from both energetic and economic viewpoints.
Performance and Emissions Characteristics of Hydrogen-diesel Dual-fuel Combustion for Heavy-duty Engines
Jan 2025
Publication
This study investigates hydrogen-diesel dual-fuelling specifically for a modern 4.4L 4-cylinder heavy-duty diesel engine using extensive one-dimensional combustion modelling in Ricardo WAVE. Parametric analyses from 900 to 2200 rpm speeds and 0 to 17.5% hydrogen fractions introduced via port injection are undertaken to assess the effect of exhaust gas recirculation (EGR) for controlling NOx. Moreover impacts on key indicators like brake power torque thermal efficiency and emissions are also evaluated. Results revealed that the benefits of hydrogen enrichment are highly dependent on operating conditions. At speeds above 1700 rpm and hydrogen mass fraction of 17.5% remarkable gains were attained increasing brake power and torque by up to 17% and 16.5% respectively. Brake-specific diesel consumption (BSDC) improves by 29% at higher speeds due to hy drogen’s larger energy content. NOx emissions display a trade-off decreasing substantially by 96% at lower speeds but increasing by 43% at 2200 rpm with 17.5% hydrogen.
Minimizing the Environmental Impact of Aircraft Engines with the Use of Sustainable Aviation Fuel (SAF) and Hydrogen
Jan 2025
Publication
Adverse climate change has forced a deeper reflection on the scale of pollution related to human activity including in the aviation industry. As a result fundamental questions have arisen about the characteristics of these pollutants the mechanisms of their formation and potential strategies for reducing them. This paper provides a comprehensive overview of key technical solutions to minimize the environmental impact of aircraft engines. The solutions presented range from fuel innovations to advanced design changes and drive concepts. Particular attention was paid to sustainable aviation fuels (SAFs) which are currently an important element of the environmental strategy regulated by the European Union. It also discusses the potential use of hydrogen as a potential alternative fuel to replace traditional aviation fuels in the long term. The analysis in the article made it possible to characterize in detail possible modifications in the functioning of aircraft engines based both on the current state of technical knowledge and on the anticipated directions of its development which has not been a frequent issue in comprehensive research so far. The analysis shows that the type of raw material used to create SAF has a strong impact on its physical and chemical parameters and the degree of greenhouse gas emissions. This necessitates a broader analysis of the legitimacy of using a given type of fuel from the SAF group in the direction of selected air operations and areas with a higher risk of severe atmospheric pollution. These results provide the basis for further research into sustainable solutions in the aviation sector that can contribute to significantly reducing its impact on climate change.
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