Publications
A Review of Machine Learning Applications in Hydrogen Electrochemical Devices
Jan 2025
Publication
Machine learning methods have been proven to be a useful tool for solving complex problems based on historical data in both scientific and engineering applications. Those properties make them a great candidate for providing a better insight into the operating characteristics of hydrogen electrochemical devices such as electrolyzers and fuel cells. Therefore this paper critically analyzes the current state of research on the application of machine learning methods for predicting operating parameters degradation detection with an emphasis on diagnostics and prognostics and fault detection in hydrogen electrochemical devices. The analysis includes a comparison of different methods discussion of existing challenges and exploration of future potential applications. Addition ally guidelines for future research along with recommendations and best practices for applying machine learning methods are provided.
Green Hydrogen Revolution: Advancing Electrolysis, Market Integration, and Sustainable Energy Transitions Towards a Net Zero Future
Apr 2025
Publication
Green hydrogen is emerging as a key driver in global decarbonization efforts particularly in hard-to-abate sectors such as steel manufacturing ammonia production and long-distance transportation. This study evaluates the techno-economic and environmental aspects of green hydrogen production storage and integration with renewable energy systems. Electrolysis remains the dominant production method with efficiency rates ranging from 70–80% for Alkaline Electrolyzers (AEL) 75–85% for Proton Exchange Membrane Electrolyzers (PEMEL) and up to 90% for Solid Oxide Electrolyzers (SOEL). Capital costs are steadily decreasing with AEL costs falling from $1200/kW in 2018 to $800/kW in 2024 while PEMEL costs are projected to decline to $600/kW by 2030. Green hydrogen significantly reduces carbon emissions with a footprint of 0.5–1 kg CO₂ per kg of H₂ compared to 10–12 kg for gray hydrogen and 1–3 kg for blue hydrogen. Its potential to cut global CO₂ emissions by 6 gigatons annually by 2050 underscores its role in climate action. However its high water demand—approximately 9 liters per kilogram of hydrogen—necessitates efficient management strategies such as desalination and recycling. Economically green hydrogen is becoming more competitive with its levelized cost decreasing from $6/kg in 2018 to $3–4/kg in 2024 and projections indicating a further drop to $1.50/kg by 2030. Global investments exceeding $500 billion in 2024 along with major projects like Saudi Arabia's NEOM Green Hydrogen Project and Australia's Asian Renewable Energy Hub are accelerating adoption. Policy frameworks such as the EU Hydrogen Strategy and the U.S. Inflation Reduction Act further support deployment. Despite progress challenges remain in infrastructure storage and regulatory frameworks necessitating continued innovation and international collaboration. Green hydrogen aligns with key Sustainable Development Goals (SDGs) including SDG 7 (Affordable and Clean Energy) SDG 9 (Industry Innovation and Infrastructure) and SDG 13 (Climate Action). As the world transitions to a low-carbon economy green hydrogen presents a transformative opportunity contingent on sustained technological advancements investment and policy support.
Temporal Regulation of Renewable Supply of Electrolytic Hydrogen
Feb 2024
Publication
Electrolytic hydrogen produced using renewable electricity can help lower carbon dioxide emissions in sectors where feedstocks reducing agents dense fuels or high temperatures are required. This study investigates the implications of various standards being proposed to certify that the grid electricity used is renewable. The standards vary in how strictly they match the renewable generation to the electrolyser demand in time and space. Using an energy system model we compare electricity procurement strategies to meet a constant hydrogen demand for selected European countries in 2025 and 2030. We compare cases where no additional renewable generators are procured with cases where the electrolyser demand is matched to additional supply from local renewable generators on an annual monthly or hourly basis. We show that local additionality is required to guarantee low emissions. For the annually and monthly matched case we demonstrate that baseload operation of the electrolysis leads to using fossil-fuelled generation from the grid for some hours resulting in higher emissions than the case without hydrogen demand. In the hourly matched case hydrogen production does not increase system-level emissions but baseload operation results in high costs for providing constant supply if only wind solar and short-term battery storage are available. Flexible operation or buffering hydrogen with storage either in steel tanks or underground caverns reduces the cost penalty of hourly versus annual matching to 7%–8%. Hydrogen production with monthly matching can reduce system emissions if the electrolysers operate flexibly or the renewable generation share is large. The largest emission reduction is achieved with hourly matching when surplus electricity generation can be sold to the grid. We conclude that flexible operation of the electrolysis should be supported to guarantee low emissions and low hydrogen production costs.
Market Dynamics and Power Risks in Green Technology Materials: Platinum under the EU 2030 Hydrogen Target
Jan 2025
Publication
The central role of hydrogen in the EU’s decarbonization strategy has increased the importance of critical raw materials. To address this the EU has taken legislative steps including the 2023 Critical Raw Materials Act (CRMA) to ensure a stable supply. Using a leader–follower Stackelberg game framework this study analyzes CRM market dynamics integrating CRMA compliance through rules on sourcing and stockpiling value chain resilience via the inclusion of supply diversification strategies and geopolitical influences by modeling exporter behaviors and trade dependencies. Results highlight the potential for strategic behavior by major exporters stressing the benefits of diversifying export sources and maintaining strategic stockpiles to stabilize supply. The findings provide insights into the EU’s efforts to secure CRM supplies key to achieving decarbonization goals and fostering a sustainable energy transition. Future research should explore alternative cost-reduction strategies mitigate exporter market power and evaluate the implications for pricing mechanisms market outcomes and consumer welfare
Green Hydrogen Transformation of the Iron and Steel Production System: An Integrated Operating Concept for System-internal Balance, Lower Emissions, and Support for Power System Stability
Dec 2024
Publication
The green hydrogen transformation of the iron and steel industry is considered a technically viable option. Concretely large-scale renewable energy generation and water electrolyzer capacity are to be added to the production system. Given that renewables are intermittent and H2 demand is high there is continued reliance on the CO2 emitting upstream power system. This paper introduces a novel operating concept that regards an extended production system that includes not only the renewables and water electrolyzer but also a dedicated conventional generator and onsite customer and prioritizes loads with the aim to create an internal balance. The paper studies different production system configurations and load prioritization strategies evaluating technoeconomic properties CO2 emissions the internal balance and the support for the stability of the upstream power system. It finds that local emission-free production of H2 is not only techno-economically viable but that the integrated operating concept leads to lower Scope I and II emissions and to significant reduction of electrical loads on the upstream power system.
Everything About Hydrogen Podcast: Decarbonizing Shipping
Mar 2024
Publication
On this episode of EAH Patrick Molloy Alicia Eastman and Chris Jackson are delighted to speak with Arsenio Dominguez the newly appointed Secretary General of the International Maritime Organization (IMO). Recorded before the highly successful MEPC81 Arsenio describes his vision for the IMO and his confidence in solutions that will reduce emissions from shipping without penalizing member states.
The podcast can be found on their website.
The podcast can be found on their website.
An Ageing Test Standards Analysis on Thermoplastic Liners of Type IV Composite Hydrogen Storage Tanks
Mar 2023
Publication
The liner of a carbon fiber fully reinforced composite tank with thermoplastic liner (type IV) works in a hydrogen environment with varying temperature and pressure profiles. The ageing performance of the thermoplastic liner may affect hydrogen permeability and the consequent storage capacity degrade the mechanical properties and even increase the leakage risks of type IV tanks. In this paper both testing procedures and evaluation parameters of an ageing test in a hydrogen environment required in several standards are compared and analyzed. Hydrogen static exposure in a high-temperature condition with a constant temperature and pressure is suggested to be a reasonable way to accelerate the ageing reaction of thermoplastic materials. A total of 192 h is considered a superior ageing test duration to balance the test economy and safety. The ageing test temperature in the high-temperature condition is suggested as no lower than 85 ◦C while the upper limit of test pressure is suggested to be 1.25 NWP. In addition the hydrogen permeation coefficient and mechanical properties are recognized as important parameters in ageing performance evaluation. Considering the actual service conditions the influence of temperature/pressure cycling depressurization rate and humidity on the ageing performance of thermoplastics in hydrogen are advised to be investigated experimentally.
Preliminary Analysis of Refilling Cold-adsorbed Hydrogen Tanks
Sep 2023
Publication
The effective storage of hydrogen is a critical challenge that needs to be overcome for it to become a widely used and clean energy source. Various methods exist for storing hydrogen including compression at high pressures liquefaction through extreme cooling (i.e. -253 °C) and storage with chemical compounds. Each method has its own advantages and disadvantages. MAST3RBoost (Maturing the Production Standards of Ultraporous Structures for High Density Hydrogen Storage Bank Operating on Swinging Temperatures and Low Compression) is a European funded Project aiming to establish a reliable benchmark for cold-adsorbed H2 storage (CAH2) at low compression levels (100 bar or below). This is achieved through the development of advanced ultraporous materials suitable for mobility applications such as hydrogen-powered vehicles used in road railway air and water transportation. The MAST3RBoost Project utilizes cutting-edge materials including Activated Carbons (ACs) and high-density MOFs (Metalorganic Frameworks) which are enhanced by Machine Learning techniques. By harnessing these materials the project seeks to create a groundbreaking path towards meeting industry goals. The project aims to develop the world's first adsorption-based demonstrator at a significant kg-scale. To support the design of the storage tank the project employs Computational Fluid Dynamics (CFD) software which allows for numerical investigations. In this paper a preliminary analysis of the tank refilling process is presented with a focus on the impact of the effect of the tank and hydrogen temperatures on quantity of hydrogen adsorbed.
Evaluating the Economic Influence of Water Sources on Green Hydrogen Production: A Cost Analysis Approach
Sep 2024
Publication
The production of green hydrogen requires significant water usage making the economic evaluation of different water sources crucial for optimizing the Levelized Cost of Hydrogen (LCOH). This study examines the economic impact of using seawater groundwater grid water industrial wastewater and rainwater for hydrogen production through PEM electrolysis considering the water abstraction transport treatment and storage costs across various plant sizes (1 MW 10 MW 20 MW 50 MW and 100 MW) were assessed and a sensitivity analysis on electricity prices was conducted. Findings reveal that while water-related costs are minimal.
Operation Optimization of Wind/Battery Storage/Alkaline Electrolyzer System Considering Dynamic Hydrogen Production Efficiency
Aug 2023
Publication
Hydrogen energy is regarded as a key path to combat climate change and promote sustainable economic and social development. The fluctuation of renewable energy leads to frequent start/stop cycles in hydrogen electrolysis equipment. However electrochemical energy storage with its fast response characteristics helps regulate the power of hydrogen electrolysis enabling smooth operation. In this study a multi-objective constrained operation optimization model for a wind/battery storage/alkaline electrolyzer system is constructed. Both profit maximization and power abandonment rate minimization are considered. In addition some constraints such as minimum start/stop times upper and lower power limits and input fluctuation limits are also taken into account. Then the non-dominated sorting genetic algorithm II (NSGA-II) algorithm and the entropy method are used to optimize the operation strategy of the hybrid energy system by considering dynamic hydrogen production efficiency and through optimization to obtain the best hydrogen production power of the system under the two objectives. The change in dynamic hydrogen production efficiency is mainly related to the change in electrolyzer power and the system can be better adjusted according to the actual supply of renewable energy to avoid the waste of renewable energy. Our results show that the distribution of Pareto solutions is uniform which indicates the suitability of the NSGA-II algorithm. In addition the optimal solution indicates that the battery storage and alkaline electrolyzer can complement each other in operation and achieve the absorption of wind power. The dynamic hydrogen production efficiency can make the electrolyzer operate more efficiently which paves the way for system optimization. A sensitivity analysis reveals that the profit is sensitive to the price of hydrogen energy.
Numerical Modelling of Hydrogen Release and Dispersion in Under-deck Compressed Hydrogen Storage of Marine Ships
Feb 2024
Publication
There is growing interest in using hydrogen (H2) as a marine fuel. Fire and explosion risks depend on hydrogen release and dispersion characteristics. Based on a validated Computational Fluid Dynamics (CFD) model this study performed hydrogen release and dispersion analysis on an under-deck compressed H2 storage system for a Live-Fish Carrier. A realistic under-deck H2 storage room was modelled based on the ship’s main dimensions and operational profile. Det Norske Veritas (DNV) Rules and Regulations for natural gas storage as a marine fuel were employed as base design guidelines. Case studies were developed to study the effect of two ceiling types (flat and slanted) in terms of flammable cloud formation and dissipation. During the leak’s duration it was found that the recommended ventilation rate was insufficient to dilute the average H2 concentration below 25% of the flammable range as required by DNV (1.2% required against 1.3% slanted and 1.4% flat). However after 35 s of gas extraction the H2 concentration was reduced to 0.5% and 0.6% in the slanted and flat cases respectively. The proposed methodology remains valid to improve the ventilation system and assess mitigation alternatives or other leakage scenarios in confined or semi-confined spaces containing compressed hydrogen gas.
Hydrogen Propulsion Systems for Aircraft, a Review on Recent Advances and Ongoing Challenges
Oct 2024
Publication
Air transportation contributes significantly to harmful and greenhouse gas emissions. To combat these issues there has been a recent emergence of aircraft electrification as a potential solution to mitigate environmental concerns and address fuel shortages. However current technologies related to batteries electric machinery and power systems are still in the developmental phase to meet the requirements for power and energy density weight safety and reliability. In the interim there is a focus on the more electric and hybrid electric propulsion systems for aircraft. Hydrogen with its high specific energy and carbon-free characteristics stands out as a promising alternative fuel for aviation. This paper is centred on the application of hydrogen in aircraft propulsion mainly fuel cell hybrid electric (FCHE) propulsion systems. Furthermore application of hydrogen as a fuel for the aircraft propulsion systems is considered. A comprehensive overview of the hydrogen propulsion systems in aviation is presented with an emphasis on the technical aspects crucial for creating a more sustainable and efficient air transportation sector. Additionally the paper acknowledges the technical and regulatory challenges that must be addressed to attain these goals.
Magnesium-Based Hydrogen Storage Alloys: Advances, Strategies, and Future Outlook for Clean Energy Applications
May 2024
Publication
Magnesium-based hydrogen storage alloys have attracted significant attention as promising materials for solid-state hydrogen storage due to their high hydrogen storage capacity abundant reserves low cost and reversibility. However the widespread application of these alloys is hindered by several challenges including slow hydrogen absorption/desorption kinetics high thermodynamic stability of magnesium hydride and limited cycle life. This comprehensive review provides an in-depth overview of the recent advances in magnesium-based hydrogen storage alloys covering their fundamental properties synthesis methods modification strategies hydrogen storage performance and potential applications. The review discusses the thermodynamic and kinetic properties of magnesium-based alloys as well as the effects of alloying nanostructuring and surface modification on their hydrogen storage performance. The hydrogen absorption/desorption properties of different magnesium-based alloy systems are compared and the influence of various modification strategies on these properties is examined. The review also explores the potential applications of magnesium-based hydrogen storage alloys including mobile and stationary hydrogen storage rechargeable batteries and thermal energy storage. Finally the current challenges and future research directions in this field are discussed highlighting the need for fundamental understanding of hydrogen storage mechanisms development of novel alloy compositions optimization of modification strategies integration of magnesium-based alloys into hydrogen storage systems and collaboration between academia and industry.
Numerical Study on a Diesel/Dissociated Methanol Gas Compression Ignition Engine with Exhaust Gas Recirculation
Aug 2023
Publication
Bo Li,
Yihua Chen,
Fei Zhong and
Xu Hao
Hydrogen is the most promising alternative fuel in the field of engines. Exhaust heat assisted methanol dissociation is an attractive approach for generating hydrogen. In this work simulations are conducted on a compression ignition engine fueled with different proportions of diesel-dissociated methanol gas (DMG) blends at intermediate engine speed full load and 0% EGR ratio. The results reveal that the indicated thermal efficiency and indicated mean effective pressure are greatly enhanced combustion efficiency is increased and regular emissions of CO HC and soot are reduced while NOx emissions are reduced with increased DMG substitution. In addition a simulation is conducted at an intermediate engine speed full load 15% DMG substitution ratio and varying EGR ratios of 0–20%. The results indicate that the dual-fuel engine outperforms the original engine with respect to power fuel economy and regular emissions once an optimal EGR rate is adopted.
Development of a Hydrogen Fuel Cell Hybrid Urban Air Mobility System Model Using a Hydrogen Metal Hydride Tank
Dec 2024
Publication
Hydrogen fuel cell-based UAM (urban air mobility) systems are gaining significant attention due to their advantages of higher energy density and longer flight durations compared to conventional battery-based UAM systems. To further improve the flight times of current UAM systems various hydrogen storage methods such as liquid hydrogen and hydrogen metal hydrides are being utilized. Among these hydrogen metal hydrides offer the advantage of high safety as they do not require the additional technologies needed for high-pressure gaseous hydrogen storage or the maintenance of cryogenic temperatures for liquid hydrogen. Furthermore because of the relatively slower dynamic response of hydrogen fuel cell systems compared to batteries they are often integrated into hybrid configurations with batteries necessitating an efficient power management system. In this study a UAM system was developed by integrating a hydrogen fuel cell system with hydrogen metal hydrides and batteries in a hybrid configuration. Additionally a state machine control approach was applied to a distribution valve for the endothermic reaction required for hydrogen desorption from the hydrogen metal hydrides. This design utilized waste heat generated by the fuel cell stack to facilitate hydrogen release. Furthermore a fuzzy logic control-based power management system was implemented to ensure efficient power distribution during flight. The results show that approximately 43% of the waste heat generated by the stack was recovered through the tank system.
Designing an Inherently Safe H2 Infrastructure: Combining Analytical, Experimental, and Numerical Investigations to Optimize H2 Refuelling Stations Safety by Passive Mitigation
Sep 2023
Publication
Natural ventilation is a well-known passive mitigation method to limit hydrogen build-up in confined spaces in case of accidental release [1-3]. In most cases a basic design of H2 infrastructure is adopted and vents installed for natural ventilation are adjusted according to safety targets and constraints of the considered structure. With the growing H2 mobility market the demand for H2 refueling infrastructure in our urban environment is on the rise. In order to meet both safety requirements and societal acceptance the design of such infrastructure is becoming more important. In this study a novel design concept is proposed for the hydrogen refueling station (HRS) by modifying physical structure while keeping safety consideration as the top priority of the concept. In this collaborative project between Air Liquide and the University of Delaware an extensive evaluation was performed on new structures of the processing container and dispenser of HRS by integrating safety protocols via passive means. Through a SWOT analysis combined with the most relevant approaches including analytical engineering models numerical simulations [4] and dedicated experimental trials an optimized design was obtained and its safety enhancement was fully evaluated. A small-scale processing container and an almost full-scale dispenser were built and tested to validate the design concepts by simulating accidental H2 release scenarios and assessing the associated consequences in terms of accumulation and potential flammable volumes formation. A conical dispenser and a V-shaped roof-top processing container which were easy to build and implement were designed and tested for this proof-of-concept study. This unique methodology from conception fundamental analysis investigation and validation through experimental design execution and evaluation is fully described in this study.
Environmental Benefits of Hydrogen-Powered Buses: A Case Study of Coke Oven Gas
Oct 2024
Publication
This study conducted a Life Cycle Assessment (LCA) of alternative (electric and hydrogen) and conventional diesel buses in a large metropolitan area. The primary focus was on hydrogen derived from coke oven gas a byproduct of the coking process which is a crucial step in the steel production value chain. The functional unit was 1000000 km traveled over 15 years. LCA analysis using SimaPro v9.3 revealed significant environmental differences between the bus types. Hydrogen buses outperformed electric buses in all 11 environmental impact categories and in 5 of 11 categories compared to conventional diesel buses. The most substantial improvements for hydrogen buses were observed in ozone depletion (8.6% of diesel buses) and global warming (29.9% of diesel buses). As a bridge to a future dominated by green hydrogen employing grey hydrogen from coke oven gas in buses provides a practical way to decrease environmental harm in regions abundant with this resource. This interim solution can significantly contribute to climate policy goals.
Green Hydrogen Production: Integrating Environmental and Social Criteria to Ensure Sustainability
Jul 2023
Publication
Hydrogen is experiencing an unprecedented global hype. Hydrogen is globally discussed as a possible future energy carrier and regarded as the urgently needed building block for the much needed carbon-neutral energy transition of hard-to-abate sectors to mitigate the effects of global warming. This article provides synthesised measurable sustainability criteria for analysing green hydrogen production proposals and strategies. Drawn from expert interviews and an extensive literature review this article proposes that a sustainable hydrogen production should consider six impact categories; Energy transition Environment Basic needs Socio-economy Electricity supply and Project planning. The categories are broken down into sixteen measurable sustainability criteria which are determined with related indicators. The article concludes that low economic costs can never be the only decisive criterion for the hydrogen production; social aspects must be integrated along the entire value chain. The compliance with the criteria may avoid social and ecological injustices in the planning of green hydrogen projects and increases inter alia the social welfare of the affected population.
Safety Challenges Related to the Use of Hydrogen-Natural Gas Blends in Gas Turbines
Sep 2023
Publication
In a context of the decarbonization of the power sector the gas turbine manufacturers are expected tohandle and burn hydrogen or hydrogen/natural gas mixtures. This evolution is conceptually simple in order to displace CO2 emissions by H2O in the combustion exhaust but raises potential engineering andsafety related questions. Concerning the safety aspect the flammability domain is wider and the laminar flame speed is higher for hydrogen than for natural gas. As a result handling fuels with increased hydrogen concentration should a priori lead to an increased the risk of flammable cloud formation with air and also increase the potential explosion violence.<br/>A central topic for the gas turbine manufacturer is the quantification of the hydrogen fuel content from which the explosion risk increases significantly when compared with the use of natural gas. This work will be focused on a risk study of the fuel supply piping of a gas turbine in a scenario where mixing between fuel and air would occur. The pipes are a few dozens of meters long and show singularities: elbows connections with other lines … They are operated at high temperature and atmospheric or high pressure.<br/>The paper will first highlight through CFD modelling the impact of increasing hydrogen content in the fuel on the explosion risk based on a geometry representative of a realistic system. Second the quantification of the explosion effects will be addressed. Some elements of the bibliography relative to flame propagation in pipes will be recalled and put in sight of the characteristics of the industrial case. Finally a CFD model proposed recently for accounting for methane or hydrogen flames propagating in long open steel tubes was used to assess a hydrogen fuel content from which the flame can strongly accelerate and generate significative pressure effects for a flammable mixture initially at atmospheric conditions.
Review of the Status and Prospects of Fiber Optic Hydrogen Sensing Technology
Aug 2023
Publication
With the unprecedented development of green and renewable energy sources the proportion of clean hydrogen (H2 ) applications grows rapidly. Since H2 has physicochemical properties of being highly permeable and combustible high-performance H2 sensors to detect and monitor hydrogen concentration are essential. This review discusses a variety of fiber-optic-based H2 sensor technologies since the year 1984 including: interferometer technology fiber grating technology surface plasma resonance (SPR) technology micro lens technology evanescent field technology integrated optical waveguide technology direct transmission/reflection detection technology etc. These technologies have been evolving from simply pursuing high sensitivity and low detection limits (LDL) to focusing on multiple performance parameters to match various application demands such as: high temperature resistance fast response speed fast recovery speed large concentration range low cross sensitivity excellent long-term stability etc. On the basis of palladium (Pd)-sensitive material alloy metals catalysts or nanoparticles are proposed to improve the performance of fiberoptic-based H2 sensors including gold (Au) silver (Ag) platinum (Pt) zinc oxide (ZnO) titanium oxide (TiO2 ) tungsten oxide (WO3 ) Mg70Ti30 polydimethylsiloxane (PDMS) graphene oxide (GO) etc. Various microstructure processes of the side and end of optical fiber H2 sensors are also discussed in this review.
No more items...