Publications
Optimization Using RSM of Combined Cycle of Power, NG, and Hydrogen Production by a Bi-geothermal Energy Resource and LNG Heat Sink
Aug 2025
Publication
This study presents a comprehensive optimization of a tri-generation system that integrates dual geothermal wells Liquefied Natural Gas (LNG) cold energy recovery and hydrogen production using an advanced Response Surface Methodology (RSM) approach. The system combines two geothermal wells with different temperature profiles power generation via an Organic Rankine Cycle (ORC) and hydrogen production through a Proton Exchange Membrane (PEM) electrolyzer enhanced by integrated LNG regasification for improved energy recovery. The primary novelty of this work lies in the first application of RSM for multi-objective optimization of geothermal-based tri-generation systems moving beyond the conventional single-objective approaches. A 40-run experimental design is employed to simultaneously optimize three critical performance indicators: exergy efficiency power-specific cost and hydrogen production rate considering six key operating parameters. The RSM framework enables systematic exploration of parameter interactions and delivers statistically validated predictive models offering a robust and computationally efficient optimization strategy. The optimized system achieves outstanding performance with an exergy efficiency of 44.60% a competitive power-specific cost of 19.70 $/GJ and a hydrogen production rate of 5.15 kg/hr. Comparative analysis against prior studies confirms the superiority of the RSM-based approach demonstrating a 1% improvement in exergy efficiency (44.60% vs. 44.16%) a significant 44.1% increase in hydrogen production rate (5.15 kg/hr vs. 3.575 kg/hr) and a 0.81% reduction in power-specific cost compared to genetic algorithm-based optimization.
Research on the Optimization Decision Method for Hydrogen Load Aggregators to Participate in Peak Shaving Market
Oct 2025
Publication
Zhenya Lei,
Libo Gu,
Zhen Hu and
Tao Shi
This article takes the perspective of Hydrogen Load Aggregator (HLA) to optimize the declaration strategy of peak shaving market improve the flexible regulation capability of power system and HLA economy as the research objectives and proposes an optimization strategy method for HLA to participate in peak shaving market. Firstly an improved Convolutional Neural Networks–Long Short-Term Memory (CNN-LSTM) time series prediction model is developed to address peak shaving demand uncertainty. Secondly a bidding strategy model incorporating dynamic pricing is constructed by comprehensively considering electrolyzer regulation costs market supply–demand relationships and system constraints. Thirdly a market clearing model for peak shaving markets with HLA participation is designed through analysis of capacity contribution and marginal costs among different regulation resources. Finally the capacity allocation model is designed with the goal of minimizing the total cost of peak shaving among various stakeholders within HLA and the capacity won by HLA in the peak shaving market is reasonably allocated. Simulations conducted on a Python3.12-based experimental platform demonstrate the following: the improved CNN-LSTM model exhibits strong adaptability and robustness the bidding model effectively enhances HLA market competitiveness and the clearing model reduces system operator costs by 5.64%.
Investigating Ammonia as an Alternative Marine Fuel: A SWOT Analysis Using the Best–Worst Method
Oct 2025
Publication
The shipping industry remains heavily dependent on heavy fuel oils which account for approximately 77% of fuel consumption and contribute significantly to greenhouse gas (GHG) emissions. In line with the IMO’s decarbonization targets ammonia has emerged as a promising carbon-free alternative. This study evaluates the strategic viability of ammonia especially green production as a marine fuel through a hybrid SWOT–Best–Worst Method (BWM) analysis combining literature insights with expert judgment. Data were collected from 17 maritime professionals with an average of 15.7 years of experience ensuring robust sectoral representation and methodological consistency. The results highlight that opportunities hold the greatest weight (0.352) particularly the criteria “mandatory carbonfree by 2050” (O3:0.106) and “ammonia–hydrogen climate solution” (O2:0.080). Weaknesses rank second (0.270) with “higher toxicity than other marine fuels” (W5:0.077) as the most critical concern. Strengths (0.242) underscore ammonia’s advantage as a “carbonfree and sulfur-free fuel” (S1:0.078) while threats (0.137) remain less influential though “costly green ammonia” (T3:0.035) and “uncertainty of green ammonia” (T1:0.034) present notable risks. Overall the analysis suggests that regulatory imperatives and environmental benefits outweigh safety technical and economic challenges. Ammonia demonstrates strong potential to serve as viable marine fuel in achieving the maritime sector’s long-term decarbonization goals.
Underground Hydrogen Storage in Salt Cavern: A Review of Advantages, Challenges, and Prospects
Jun 2025
Publication
The transition to a sustainable energy future hinges on the development of reliable large-scale hydrogen storage solutions to balance the intermittency of renewable energy and decarbonize hard-to-abate industries. Underground hydrogen storage (UHS) in salt caverns emerged as a technically and economically viable strategy leveraging the unique geomechanical properties of salt formations—including low permeability self-healing capabilities and chemical inertness—to ensure safe and high-purity hydrogen storage under cyclic loading conditions. This review provides a comprehensive analysis of the advantages of salt cavern hydrogen storage such as rapid injection and extraction capabilities cost-effectiveness compared to other storage methods (e.g. hydrogen storage in depleted oil and gas reservoirs aquifers and aboveground tanks) and minimal environmental impact. It also addresses critical challenges including hydrogen embrittlement microbial activity and regulatory fragmentation. Through global case studies best operational practices for risk mitigation in real-world applications are highlighted such as adaptive solution mining techniques and microbial monitoring. Focusing on China’s regional potential this study evaluates the hydrogen storage feasibility of stratified salt areas such as Jiangsu Jintan Hubei Yunying and Henan Pingdingshan. By integrating technological innovation policy coordination and cross-sector collaboration salt cavern hydrogen storage is poised to play a pivotal role in realizing a resilient hydrogen economy bridging the gap between renewable energy production and industrial decarbonization.
Evaluation of Passenger Train Safety in the Event of a Liquid Hydrogen Release from a Freight Train in a Tunnel Along an Italian High-Speed/High-Capacity Rail Line
Oct 2025
Publication
The global shift towards cleaner energy sources is driving the adoption of hydrogen as an environmentally friendly alternative to fossil fuels. Among the forms currently available Liquid Hydrogen (LH2) offers high energy density and efficient storage making it suitable for large-scale transport by rail. However the flammability of hydrogen poses serious safety concerns especially when transported through confined spaces such as railway tunnels. In case of an accidental LH2 release from a freight train the rapid accumulation and potential ignition of hydrogen could cause catastrophic consequences especially if freight and passenger trains are present simultaneously in the same tunnel tube. In this study a three-dimensional computational fluid dynamics model was developed to simulate the dispersion and explosion of LH2 following an accidental leak from a freight train’s cryo-container in a single-tube double-track railway tunnel when a passenger train queues behind it on the same track. The overpressure results were analyzed using probit functions to estimate the fatality probabilities for the passenger train’s occupants. The analysis suggests that a significant number of fatalities could be expected among the passengers. However shorter users’ evacuation times from the passenger train’s wagons and/or longer distances between the two types of trains might reduce the number of potential fatalities. The findings by providing additional insight into the risks associated with LH2 transport in railway tunnels indicate the need for risk mitigation measures and/or traffic management strategies.
Economic and Environmental Assessment of Different Energy Storage Methods for Hybrid Energy Systems
Jul 2025
Publication
Due to the environmental impact of fossil fuels renewable energy such as wind and solar energy is rapidly developed. In energy systems energy storage units are important which can regulate the safe and stable operation of the power system. However different energy storage methods have different environmental and economic impacts in renewable energy systems. This paper proposed three different energy storage methods for hybrid energy systems containing different renewable energy including wind solar bioenergy and hydropower meanwhile. Based on Homer Pro software this paper compared and analyzed the economic and environmental results of different methods in the energy system through the case of a residential community in Baotou City. The result showed that (1) the use of batteries as energy storage in communities posed the lowest energy costs whose NPC was $197396 and LCOE was $0.159 consisting of 20 batteries 19.3 kW PV 6 wind turbines a 12.6 kW converter. (2) Lower fuel cell prices mean lower NPC and the increase in the Electric Load Scaled Average implied a decrease in LCOE and the increase of the NPC. (3) The use of fuel cells also had impacts on the environment such as resulting CO2 and SO2.
Process Integration and Exergy-based Assessment of High-temperature Solid Oxide Electrolysis Configurations
Sep 2025
Publication
Solid oxide electrolysis (SOEL) is considered an efficient option for largely emission-free hydrogen production and thus for supporting the decarbonization of the process industry. The thermodynamic advantages of high-temperature operation can be utilized particularly when heat integration from subsequent processes is realized. As the produced hydrogen is usually required at a higher pressure level the operating pressure of the electrolysis is a relevant design parameter. The study compares pressurized and near-atmospheric designs of 126 MW SOEL systems with and without the integration of process heat from a downstream ammonia synthesis and the inefficiencies that occur in the processes. Furthermore process improvements by sweep-air utilization are investigated. Pinch analysis is applied to determine the potential of internal heat recovery and the minimum external heating and cooling demand. It is shown that pressurized SOEL operation does not necessarily decrease the overall power consumption for compression due to the high power requirement of the sweep-air compressor. The exergetic efficiencies of the standalone SOEL processes achieve similar values of = 81 %. Results further show that integrating the heat of reaction from ammonia synthesis can replace almost the entire electrically supplied thermal energy thereby improving the overall exergetic efficiency by up to 3.5 percentage points. However the exergetic efficiency strongly depends on the applied air ratio. The highest exergetic efficiency of 86 % can be achieved by employing sweep-air utilization with an expander. The results demonstrate that integrating downstream process heat and applying sweep-air utilization can significantly enhance overall efficiency and thus reduce external energy requirements.
Design and Assessment of an Integrated PV-based Hydrogen Production Facility
Jun 2025
Publication
This study develops a photovoltaic (PV)-based hydrogen production system specifically designed for university campuses which is expected to lead in sustainability efforts. The proposed system aims to meet the electricity demand of a Hydrogen Research Center while supplying energy to an electric charging station and a hydrogen refueling station for battery-electric and fuel-cell electric vehicles operating within the campus. In this integrated system the electricity generation capacity of PV panels installed on the research center’s roof is determined and the surplus electricity after meeting the energy demand is allocated to cover the varying proportions needed for both electric charging station and hydrogen production system. The green hydrogen produced by the system is compressed to 100 350 and 700 bar with intermediate cooling stages where the heat generated at the compressor outlet is absorbed by a cooling fluid and repurposed in a condenser for domestic hot water production. A full thermodynamic analysis of this entirely renewable energy-powered system is conducted by considering a 9-hour daily operational period from 8:00 AM to 5:00 PM. The average incoming solar radiation is determined to be 484.63 W/m2 resulting in an annual electricity generation capacity of 494.86 MWh. Based on the assumptions and data considered the energy and exergy efficiencies of the proposed system are calculated as 17.71 % and 17.01 % respectively with an annual hydrogen production capacity of 3.642 tons. Various parametric studies are performed for varying solar intensity values and PV surface areas to investigate how the overall system capacities and efficiencies are affected. The results show that an integration of hydrogen production systems with solar energy offers significant advantages including mitigating intermittency issues found in standalone renewable systems reducing carbon emissions compared to fossil-based alternatives and enhancing the flexibility of energy systems.
Grid Infrastructure and Renewables Integration for Singapore Energy Transition
Oct 2025
Publication
Considering rising environmental concerns and the energy transition towards sustainable energy Singapore’s power sector stands at a crucial juncture. This study explores the integration of grid infrastructure with both generated and imported renewable energy (RE) sources as a strategic pathway for the city-state’s energy transition to reach net-zero carbon emissions by 2050. Employing a combination of simulation modeling and data analysis for energy trading and advanced energy management technologies we examine the current and new grid infrastructure’s capacity to assimilate RE sources particularly solar photovoltaic and energy storage systems. The findings reveal that with strategic upgrades and smart grid technologies; Singapore’s grid can efficiently manage the variability and intermittency of RE sources. This integration is pivotal in achieving a higher penetration of renewables as well as contributing significantly to Singapore’s commitment to the Paris Agreement and sustainable development goals. While the Singapore’s power system has links to the Malay Peninsula the planned ASEAN regional interconnection might alter the grid operation in Singapore and possibly make Singapore a new green energy hub. The study also highlights the key challenges and opportunities associated with cross-border energy trade with ASEAN countries including the need for harmonized regulatory frameworks and incentives to foster public–private partnerships. The insights from this study could guide policymakers industry stakeholders and researchers offering a roadmap for a sustainable energy transition in Singapore towards meeting its 2050 carbon emission goals.
Techno-economic and Environmental Optimization of Hydrogen-based Hybrid Energy Systems for Remote Off-grid Australian Communities
Jun 2025
Publication
This study presents a techno-economic and environmental optimization of hydrogen-based hybrid energy systems (HESs) for Broken Hill City Council in New South Wales Australia. Two configurations are evaluated: Configuration 1 includes solar PV battery fuel cell electrolyzer and hydrogen storage while Configuration 2 includes solar PV fuel cell electrolyzer and hydrogen storage but excludes the battery. The system is optimized using advanced metaheuristic algorithms such as Harris Hawks Algorithm (HHA) Red-Tailed Hawk Algorithm and Non-Dominated Sorting Genetic Algorithm-II while ensuring real-time supply–demand balance and system stability through a robust energy management strategy. This integrated approach simultaneously determines the optimal sizes of PV arrays battery storage (where applicable) fuel cells electrolyzers and hydrogen storage units and maintains reliable energy supply. Results show that HHA Configuration 1 achieves the lowest net present cost of $338111 a levelized cost of electricity of $0.185/kWh and a levelized cost of hydrogen of $4.60/kg. Sensitivity analysis reveals that PV module and hydrogen storage costs significantly impact system economics while improving fuel cell efficiency from 40% to 60% can reduce costs by up to 40%. Beyond cost-effectiveness life cycle analysis demonstrates annual CO2 emission reductions exceeding 500000 kg compared to an equivalent diesel generator system meeting the same load demand. Socio-economic assessments further indicate that the HES can support improvements in the Human Development Index by enhancing access to healthcare education and economic opportunities while also creating local jobs in PV installation battery maintenance and hydrogen infrastructure. These findings establish hydrogen-based HES as a scalable cost-effective and environmentally sustainable solution for energy access in remote areas.
Opportunities for Emission Reduction in the Transformation of Petroleum Refining
Sep 2025
Publication
Crude oil accounts for approximately 40% of global energy consumption and the refining sector is a major contributor to greenhouse gas (GHG) emissions particularly through the production of hard-to-abate fuels such as aviation fuel and fuel oil. This study disaggregates the refinery into its key process units to identify decarbonization opportunities along the entire production chain. Units are categorized into combustion-based processes— including crude and vacuum distillation hydrogen production coking and fluid catalytic cracking—and non-combustion processes which exhibit lower emission intensities. The analysis reveals that GHG emissions can be reduced by up to 60% with currently available technologies without requiring major structural changes. Electrification residual heat recovery renewable hydrogen for desulfurization and process optimization through digital twins are identified as priority measures many of which are also economically viable in the short term. However achieving full decarbonization and alignment with net-zero targets will require the deployment of carbon capture technologies. These results highlight the significant potential for emission reduction in refineries and reinforce their strategic role in enabling the transition toward low-carbon fuels.
Optimal Configuration of Hydrogen Energy Storage Systems Considering the Operational Efficiency Characteristics of Multi-Stack Electrolyzers
Sep 2025
Publication
Enhancing the economics of microgrid systems and achieving a balance between energy supply and demand are critical challenges in capacity allocation research. Existing studies often neglect the optimization of electrolyzer efficiency and multi-stack operation leading to inaccurate assessments of system benefits. This paper proposes a capacity allocation model for wind-PV-hydrogen integrated microgrid systems that incorporates hydrogen production efficiency optimization. This paper analyzes the relationship between the operating efficiency of the electrolyzer and the output power regulates power generation-load mismatches through a renewable energy optimization model and establishes a double-layer optimal configuration framework. The inner layer optimizes electrolyzer power allocation across periods to maximize operational efficiency while the outer layer determines configuration to maximize daily system revenue. Based on the data from a demonstration project in Jiangsu Province China a case study is conducted to verify that the proposed method can improve system benefits and reduce hydrogen production costs.
Numerical Simulation of Natural Gas/Hydrogen Combustion in a Novel Laboratory Combustor
Jun 2025
Publication
Hydrogen is a promising fuel in the current transition to zero-net CO2 emissions. However most practical combustion equipment is not yet ready to burn pure hydrogen without adaptation. In the meantime blending hydrogen with natural gas is an interesting option. This work reports a computational study of the performance of swirl-stabilized natural gas/hydrogen flames in a novel combustion chamber design. The combustor employs an air-staging strategy introducing secondary air through a top-mounted plenum in a direction opposite to the fuel jet. The thermal load is fixed at 5 kW and the effects of fuel composition (hydrogen molar fraction ranging from zero to one) excess air coefficient (λ = 1.3 1.5 or 1.7) and primary air fraction (α = 50–100%) on the velocity temperature and emissions are analysed. The results show that secondary air changes the flow pattern reducing the central recirculation zone and lowering the temperature in the primary reaction zone while increasing it further downstream. Secondary air improves the performance of the combustor for pure hydrogen flames reducing NO emissions to less than 50 ppm for λ = 1.3 and 50% primary air. For natural gas/hydrogen blends a sufficiently high excess air level is required to keep CO emissions within acceptable limits.
Increasing Public Acceptance of Fuel Cell Vehicles in Germany: A Perspective on Pioneer Users
Jun 2025
Publication
Fuel cell vehicles (FCVs) represent an intriguing alternative to battery electric vehicles (BEVs). While the acceptance of BEVs has been widely discussed acceptance-based recommendations for promoting adoption of FCVs remain ambiguous. This paper aims to improve our understanding by reporting results from a pioneer study based on the standardized Unified Theory of Acceptance and Use of Technology 2 (UTAUT2). The sample consists of n1 = 258 registered customers of H2mobility in Germany. For effect control another n2 = 294 participant sample was drawn from the baseline population. Data were analyzed using SmartPLS 4 and importance-performance mapping (IPMA). Results demonstrate that FCV acceptance primarily relies on Perceived Usefulness Perceived Conditions and Normative Influence while surprisingly hypotheses involving Perceived Risk and Green Attitude are rejected. Finally a discussion reveals ways to increase the level of public acceptance. Three practical strategies emerge. For future acceptance analyses the authors suggest incorporating the young concept of ‘societal readiness’.
A Comprehensive Review of Advances in Bioenergy including Emerging Trends and Future Directions
Aug 2025
Publication
Bioenergy is a promising alternative to fossil fuels-based energy with significant potential to transform global energy systems and promote environmental sustainability. This review provides a comprehensive overview of the evolution of bioenergy emphasizing its role in the global transition to sustainable energy. It explores a diverse range of biomass sources including forest and agricultural residues algae and industrial by-products and their conversion into energy via thermochemical biochemical and physicochemical pathways. The paper also highlights recent technological advancements and assesses the environmental sustainability of bioenergy systems. Additionally it examines key challenges hindering bioenergy development such as feedstock logistics technological limitations economic viability and policy gaps that need resolution to fully realise its potential. By synthesizing literature from 2010 to 2025 the review identifies strategic priorities for research and deployment aiming to inform efforts that align bioenergy utilization with global decarbonization goals.
Optimizing Vietnam's Hydrogen Strategy: A Life-cycle Perspective on Technology Choices, Environmental Impacts, and Cost Trade-offs
Sep 2025
Publication
Vietnam recognizes hydrogen as a key fuel for decarbonization under its National Hydrogen Strategy. Here we quantified the environmental and economic performance of Vietnam’s optimal hydrogen-production pathways by evaluating combinations of green and blue hydrogen under varying demand scenarios using life-cycle assessment and optimization modeling techniques. The environmental performance of hydrogen production proved highly sensitive to the electricity source with water electrolysis powered by renewable energy offering the most favorable outcomes. Although green hydrogen production reduced carbon emissions it shifted environmental burdens toward increased resource extraction. Producing 20 Mt of hydrogen by 2050 would require 741.56 TWh of electricity 178 Mt of water and USD 294 billion in investment and it would emit 50.48 Mt CO2. These findings highlight the importance of strategic hydrogen planning and resource strategy aligned with national priorities for energy transition to navigate trade-offs among technology selection emissions costs and resource consumption.
Investigating the Effects of Flow Regime on Hydrogen Transport in Salt Rock
Jun 2025
Publication
Underground hydrogen storage (UHS) in salt caverns is emerging as a promising solution for the transition to a sustainable energy future. However a thorough understanding of hydrogen flow mechanisms through salt rock is essential to ensure safe and efficient storage operations. In this study we conducted hydrogen flow experiments in salt rocks using the pressure pulse decay (PPD) method covering a range of hydrogen pore pressures from 0.4 MPa to 7.5 MPa within the slip and transitional flow regimes (Knudsen numbers between 0.04 and 1.5). The Knudsen numbers were determined by measuring the pore size distribution (PSD) of the salt rock samples and assigning an average pore size to each sample based on the measured PSD. Our results indicate that the intrinsic permeability of the tested salt rock samples ranges from 5 × 10− 21 m2 to 1.0 × 10− 20 m2 . However a significant enhancement in apparent permeability up to 10 times the intrinsic permeability was observed particularly at lower pressures. This permeability enhancement is attributed to the nanoscale pore structure of salt rocks where the mean free path of hydrogen becomes comparable to the pore sizes leading to a shift from slip flow to the transitional flow regime. The results further reveal that the first-order slip model underestimates the apparent permeability in the transitional flow regime despite its satisfactory accuracy in the slip region. Moreover the higher-order slip model demonstrates acceptable accuracy across both the slip and transitional flow regimes.
Alternative Fuels in Aero Engine Performance Calculations
Oct 2025
Publication
This paper presents a method for gas turbine performance calculations with alternative fuels with a particular focus on their use in aircraft engines. The effects of various alternative aviation fuels on fuel consumption CO2 emissions and contrail formation are examined in a comparative study. We use the GasTurb performance software and calculate heat release and hot section gas properties using a chemical equilibrium solver. Fuels with complex compositions are included in the calculation via surrogates of a limited number of known species that mimic the relevant properties of the real fuel. An automated method is used for the fuel surrogate formulation. We compare the results of this rigorous approach with the simplified approach of calculating the heat release using an alternative fuel’s heating value while still using the gas properties of conventional Jet A-1. The results show that the latter approach systematically overpredicts fuel consumption by up to 0.2% for aromaticsfree synthetic kerosene (e.g. “biofuels”). Overall aircraft engines running on alternative fuels tend to be more fuel efficient due to their often higher hydrogen contents and thus fuel heating values. We find reductions in fuel consumption of up to 2.8% during cruise when using aromatics-free synthetic kerosene. We further assess how alternative fuels affect contrail formation based on the Schmidt-Appleman criterion. Contrails can form 200 m lower under cruise conditions when burning aromatics-free synthetic kerosene instead of Jet A-1 with identical thrust requirements and under the same atmospheric conditions mainly due to their higher hydrogen content. In summary we present a flexible yet easy-to-use method for studying fuel effects in performance calculations that avoids small but systematic errors by rigorously calculating the heat release and hot section gas properties for each fuel.
Numerical Investigation of Hydrogen Leakage Quantification and Dispersion Characteristics in Buried Pipelines
Sep 2025
Publication
As a clean energy carrier hydrogen is essential for global low-carbon energy transitions due to its unique combination of safe transport properties and energy density. This investigation employs computational fluid dynamics (ANSYS Fluent) to systematically characterize hydrogen dispersion through soil media from buried pipelines. The research reveals three fundamental insights: First leakage orifices smaller than 2 mm demonstrate restricted hydrogen migration regardless of directional orientation. Second dispersion patterns remain stable under both low-pressure conditions (below 1 MPa) and minimal thermal gradients with pipeline temperature variations limited to 63 K and soil fluctuations under 40 K. Third dispersion intensity increases proportionally with higher leakage pressures (exceeding 1 MPa) greater soil porosity and larger particle sizes while inversely correlating with burial depth. The study develops a predictive model through Sequential Quadratic Programming (SQP) optimization demonstrating exceptional accuracy (mean absolute error below 10%) for modeling continuous hydrogen flow through moderateporosity soils under medium-to-high pressure conditions with weak inertial effects. These findings provide critical scientific foundations for designing safer hydrogen transmission infrastructure establishing robust risk quantification frameworks and developing effective early-warning systems thereby facilitating the practical implementation of hydrogen energy systems.
Efficiently Coupling Water Electrolysis with Solar PV for Green Hydrogen Production
Aug 2025
Publication
Solar-driven water electrolysis has emerged as a prominent technology for the production of green hydrogen facilitated by advancements in both water electrolyzers and solar cells. Nevertheless the majority of integrated solar-to-hydrogen systems still struggle to exceed 20% efficiency particularly in large-scale applications. This limitation arises from suboptimal coupling methodologies and system-level inefficiencies that have rarely been analyzed. To address these challenges this study investigates the fundamental principles of solar hydrogen production and examines key energy losses in photovoltaic-electrolyzer systems. Subsequently it systematically discusses optimization strategies across three dimensions: (1) enhancing photovoltaic (PV) system output under variable irradiance (2) tailoring electrocatalysts and electrolyzer architectures for high-performance operation and (3) minimizing coupling losses through voltage-matching technologies and energy storage devices. Finally we review existing large-scale solar hydrogen infrastructure and propose strategies to overcome barriers related to cost durability and scalability. By integrating material innovation with system engineering this work offers insights to advance solar-powered electrolysis toward industrial applications.
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