Publications
Analysis of Exergy Flow and CCUS Carbon Reduction Potential in Coal Gasification Hydrogen Production Technology in China
Nov 2025
Publication
Coal constitutes China’s most significant resource endowment at present. Utilizing coal resources for hydrogen production represents an early-stage pathway for China’s hydrogen production industry. The analysis of energy quality and carbon emissions in coal gasification-based hydrogen production holds practical significance. This paper integrates the exergy analysis methodology into the traditional LCA framework to evaluate the exergy and carbon emission scales of coal gasification-based hydrogen production in China considering the technical conditions of CCUS. This paper found that the life cycle exergic efficiency of the whole chain of gasification-based hydrogen production in China is accounted to be 38.8%. By analyzing the causes of exergic loss and energy varieties it was found that the temperature difference between the reaction of coal gasification and CO conversion unit and the pressure difference due to the compressor driven by the electricity consumption of the compression process in the variable pressure adsorption unit are the main causes of exergic loss. Corresponding countermeasures were suggested. Regarding decarbonization strategies the CCUS process can reduce CO2 emissions across the life cycle of coal gasification-based hydrogen production by 48%. This study provides an academic basis for medium-to-long-term forecasting and roadmap design of China’s hydrogen production structure.
Advancing the Energy Transition in the Steel Industry: A Game-theoretic Bilevel Approach for Green Hydrogen Supply Chains
Sep 2025
Publication
Green hydrogen is essential for advancing the energy transition as it is regarded as a CO2-neutral flexible and storable energy carrier. Particularly in steel production which is known for its high energy intensity hydrogen has great potential to replace conventional energy sources. In a game-theoretic bi-level optimization model involving a power plant operator and a steel company we investigate in which situations the production and use of green hydrogen is advantageous from an economic and ecological point of view. Through an extensive case study based on a realworld scenario we can observe that hydrogen production can serve as a profitable and flexible secondary income opportunity for the power plant operator and help avoid curtailment and spot market losses. On the other hand the steel manufacturer can reduce CO2 emissions and associated costs while also meeting the growing customer demand for low-carbon products. However our findings also highlight important trade-offs and uncertainties. While lower electricity generation costs or improved electrolyzer efficiency enhance hydrogen’s competitiveness increases in coal and CO2 emission prices do not always result in greater hydrogen adoption. This is due to the persistent reliance on a non-replaceable share of coal in steel production which raises the overall cost of both low-carbon and carbon-intensive steel. The model further shows that consumer demand elasticity plays a critical role in determining hydrogen uptake. These insights underscore the importance of not only reducing hydrogen costs but also designing supportive policies that address market acceptance and the full cost structure of green industrial products.
Process Analysis and Techno-economic Comparison of Aviation Biofuel Production via Microbial Oil and Ethanol Upgrading
Oct 2025
Publication
The transport sector is the largest source of greenhouse gases in the EU after the energy supply one contributing approximately 27% of total emissions. Although decarbonization pathways for light-duty transport are relatively well established heavy-duty transport shipping and aviation emissions are difficult to eliminate through electrification. In particular the aviation sector is strongly dependent on liquid hydrocarbons making the development of sustainable aviation fuels (SAFs) a critical priority for achieving long-term climate targets. This study evaluates four biomass-to-liquid pathways for producing jet-like SAF from lignocellulosic biomass: (1) triacylglycerides (TAGs) production from syngas fermentation (2) TAGs production from sugar fermentation (3) ethanol production from syngas fermentation and (4) ethanol production from sugar fermentation. These pathways are simulated using Aspen Plus™ and the mass and heat balances obtained are used to assess their technical performance (e.g. carbon utilization energetic fuel efficiency) and techno-economic viability (e.g. production cost capital investment). Pathway (4) demonstrated the highest jet fuel selectivity (63%) and total carbon utilization (32.5%) but at higher power demands. Pathway (1) was self-sufficient in energy due to internal syngas utilization but exhibited lower carbon efficiencies. Cost analysis revealed that microbial oil-based pathways were restrained by higher hydrogen demands and lower product selectivity compared to ethanol-based routes. However with advancements in microbial oil production efficiency and reduced water usage these pathways could become competitive.
An Empirical Study of Kingdom of Saudi Arabia Citizens' Intentions about the Adoption of Hydrogen Fuel Cell Vehicles
Oct 2025
Publication
A comprehensive understanding of consumer preferences and demand factors is essential for successfully implementing demand-side strategies for alternative energy solutions such as hydrogen. This study aims to identify the key determinants influencing the adoption propensity for Hydrogen fuel cell vehicles (HFCVs) in the Kingdom of Saudi Arabia (KSA). Developing a conceptual framework to organise the key factors influencing consumers’ decisions to adopt or reject this technology. Using data from an online survey of 384 prospective customers we employed structural equation modelling (SEM) via Smart-PLS 4.1 to analyze consumer intent. The findings reveal that perceived benefits barriers opinions and governmental initiatives have a significant impact on the likelihood of HFCV adoption. The study emphasises the significance of collaborative efforts among key stakeholders including manufacturers hydrogen producers research institutions and financial entities in addressing challenges and advancing the development of the hydrogen transportation ecosystem in KSA. Financial incentives and subsidies such as purchasing subsidies awareness and reduced registration costs for HFCVs may be instituted.
Towards Green and Smart Ports: A Review of Digital Twin and Hydrogen Applications in Maritime Management
Oct 2025
Publication
Modern ports are pivotal to global trade facing increasing pressures from operational demands resource optimization complexities and urgent decarbonization needs. This study highlights the critical importance of digital model adoption within the maritime industry particularly in the port sector while integrating sustainability principles. Despite a growing body of research on digital models industrial simulation and green transition a specific gap persists regarding the intersection of port management hydrogen energy integration and Digital Twin (DT) applications. Specifically a bibliometric analysis provides an overview of the current research landscape through a study of the most used keywords while the document analysis highlights three primary areas of advancement: optimization of hydrogen storage and integrated energy systems hydrogen use in propulsion and auxiliary engines and DT for management and validation in maritime operations. The main outcome of this research work is that while significant individual advancements have been made across critical domains such as optimizing hydrogen systems enhancing engine performance and developing robust DT applications for smart ports a major challenge persists due to the limited simultaneous and integrated exploration of them. This gap notably limits the realization of their full combined benefits for green ports. By mapping current research and proposing interdisciplinary directions this work contributes to the scientific debate on future port development underscoring the need for integrated approaches that simultaneously address technological environmental and operational dimensions.
Nodal Marginal Price Decomposition Mechanism for the Hydrogen Energy Market Considering Hydrogen Transportation Characteristics
Oct 2025
Publication
With the growing significance of hydrogen in the global energy transition research on its pricing mechanisms has become increasingly crucial. Focusing on hydrogen markets predominantly supplied by electrolytic production this study proposes a nodal marginal hydrogen price decomposition algorithm that explicitly incorporates the time-delay dynamics inherent in hydrogen transmission. A four-dimensional price formation framework is established comprising the energy component network loss component congestion component and time-delay component. To address the nonconvex optimization challenges arising in the market-clearing model an improved second-order cone programming method is introduced. This method effectively reduces computational complexity through the reconstruction of time-coupled constraints and reformulation of the Weymouth equation. On this basis the analytical expression of the nodal marginal hydrogen price is rigorously derived elucidating how transmission dynamics influence each price component. Empirical studies using a modified Belgian 20-node system demonstrate that the proposed pricing mechanism dynamically adapts to load variations with hydrogen prices exhibiting a strong correlation with electricity cost fluctuations. The results validate the efficacy and superiority of the proposed approach in hydrogen energy market applications. This study provides a theoretical foundation for designing efficient and transparent pricing mechanisms in emerging hydrogen markets.
Optimization of Novel Variable-Channel-Width Solid Oxide Electrolysis Cell (SOEC) Design for Enhanced Hydrogen Production
Oct 2025
Publication
This study presents a novel solid oxide electrolysis cell (SOEC) design with variable channel widths to optimize thermal management and electrochemical performance for enhanced hydrogen production. Using high-fidelity computational modeling in COMSOL Multiphysics 6.1 five distinct channel width configurations were analyzed with a baseline model validated against experimental data. The simulations showed that modifying the channel geometry particularly in Scenario 2 significantly improved hydrogen production rates by 6.8% to 29% compared to a uniform channel design with the effect becoming more pronounced at higher voltages. The performance enhancement was found to be primarily due to improved fluid velocity regulation which increased reactant residence time and enhanced mass transport rather than a significant thermal effect as temperature distribution remained largely uniform across the cell. Additionally the inclusion of a dedicated heat transfer channel was shown to improve current density and overall efficiency particularly at lower voltages. While a small increase in voltage raised internal cell pressure the variable-width designs especially those with widening channels led to greater hydrogen output albeit with a corresponding increase in system energy consumption due to higher pressure. Overall the findings demonstrate that strategically designed variable-width channels offer a promising approach to optimizing SOEC performance for industrial-scale hydrogen production.
Effects of Operating Parameters on Combustion Characteristics of Hydrogen-Doped Natural Gas
Oct 2025
Publication
The operational optimization of industrial boilers utilizing hydrogen-enriched natural gas is constrained by two critical gaps: insufficient understanding of the coupled effects of hydrogen blending ratio equivalence ratio and boiler load on combustion performance— compounded by unresolved challenges of combustion instability flashback and elevated NOx emissions—and a lack of systematic investigations combining these parameters in industrial-scale systems (prior studies often focus on single variables like hydrogen fraction). To address this a comprehensive computational fluid dynamics (CFD) analysis was conducted on a 2.1 MW industrial boiler employing the Steady Laminar Flamelet Model (SLFM) with a modified k-ε turbulence model and the GRI-Mech 3.0 mechanism. Simulations covered hydrogen fractions (f(H2) = 0–25%) equivalence ratios (Φ = 0.8–1.2) and load conditions (15–100%). All NOx emissions reported herein are normalized to 3.5% O2 (mg/Nm3 ) for regulatory comparison. Results show that increasing the hydrogen content raises the flame temperature and NOx emissions while reducing CO and unburned hydrocarbons; a higher equivalence ratio elevates temperature and NOx with Φ = 0.8 balancing efficiency and emission control; and reducing load significantly lowers furnace temperature and NO emissions. Notably the boiler’s unique staged-combustion configuration (81% fuel supply to the central rich-combustion nozzle 19% to the concentric lean-combustion nozzle) was found to mitigate NOx formation by 15–20% compared to single-inlet burner designs and its integrated cyclone blades (generating maximum swirling velocity of 14.2 m/s at full load) enhanced fuel–air mixing which became particularly critical for maintaining combustion stability at low loads (≤20%) and high hydrogen blending ratios (≥20%). This study provides quantitative trade-off insights between combustion efficiency and pollutant formation offering actionable guidance for the safe efficient operation of hydrogen-enriched natural gas in industrial boilers.
Simulation of the Hydrogen Railway Engine Performance Under Different Load Conditions and Control Parameters
Oct 2025
Publication
The article examines the use of hydrogen fuel as an alternative to traditional diesel fuel for internal combustion engines (ICE) in railway applications. The main objective of the study is to analyze the operational consumption of hydrogen fuel based on the mathematical modeling of the working cycle of the EMD 12-645E3C engine installed on CIE 071 locomotives used in freight and passenger service. The article provides information on the design features of the EMD 12-645E3C engine its technical parameters and the results of bench tests. The indicator parameters of the engine at various controller positions are determined and analyzed and the results of mathematical modeling of its operation on hydrogen fuel are presented. Particular attention is paid to changes in indicator parameters including the maximum combustion pressure and the peak gas temperature in the cylinder as well as comparing the mass consumption of diesel and hydrogen fuel. The study results demonstrate that the use of hydrogen allows the engine to maintain effective power across all operational modes while simultaneously reducing energy costs up to 8%. In this case the pressure and temperature of the gases in the cylinder increased by 3–6% and 5–8%. Recommendations are also provided regarding technical challenges associated with transitioning to hydrogen fuel including the modernization of the combustion chamber fuel system and safety system.
Assessment of the Use of a Passive Pre-Chamber in a Marine Engine Fueled with Ammonia–Hydrogen Mixtures
Oct 2025
Publication
This study investigates the combustion process in a marine spark-ignition engine fueled with an ammonia–hydrogen blend (15% hydrogen by volume) using a passive pre-chamber. A 3D-CFD model supported by a 1D engine model was employed to analyze equivalence ratios between 0.7 and 0.9 and pre-chamber nozzle diameters from 7 to 3 mm. Results indicate that combustion is consistently initiated by turbulent jets but at an equivalence ratio of 0.7 the charge combustion is incomplete. For lean mixtures reducing nozzle size improves flame propagation although not sufficiently to ensure stable operation. At an equivalence ratio of 0.8 reducing the nozzle diameter from 7 to 5 mm advances CA50 by about 6 CAD while further reduction causes minor variations. At richer conditions nozzle diameter plays a negligible role. Optimal performance was achieved with a 7 mm nozzle at equivalence ratio 0.8 delivering about 43% efficiency and 1.17 MW per cylinder.
Development of DC-DC Converters for Fuel-Cell Hybrid Power Systems in a Lift-Cruise Unmanned Aerial Vehicle
Oct 2025
Publication
Lift–cruise-type unmanned aerial vehicles (UAVs) powered by hydrogen fuel cells often integrate secondary energy storage devices to improve responsiveness to load fluctuations during different flight phases which necessitates an efficient energy management strategy that optimizes power allocation among multiple power sources. This paper presents an innovative fuel cell DC–DC converter (FDC) design for the hybrid power system of a lift–cruise-type UAV comprising a multi-stack fuel cell system and a battery. The novelty of this work lies in the development of an FDC suitable for a multi-stack fuel cell system through a dual-input single-output converter structure and a control algorithm. To integrate inputs supplied from two hydrogen fuel cell stacks into a single output a controller with a single voltage controller–dual current controller structure was applied and its performance was verified through simulations and experiments. Load balancing was maintained even under input asymmetry and fault-tolerant performance was evaluated by analyzing the FDC output waveform under a simulated single-stack input failure. Furthermore under the assumed flight scenarios the results demonstrate that stable and efficient power supply is achieved through power-supply mode switching and application of a power distribution algorithm.
Application and Research Progress of Mechanical Hydrogen Compressors in Hydrogen Refueling Stations: Structure, Performance, and Challenges
Nov 2025
Publication
The hydrogen energy industry is rapidly developing positioning hydrogen refueling stations (HRSs) as critical infrastructure for hydrogen fuel cell vehicles. Within these stations hydrogen compressors serve as the core equipment whose performance and reliability directly determine the overall system’s economy and safety. This article systematically reviews the working principles structural features and application status of mechanical hydrogen compressors with a focus on three prominent types based on reciprocating motion principles: the diaphragm compressor the hydraulically driven piston compressor and the ionic liquid compressor. The study provides a detailed analysis of performance bottlenecks material challenges thermal management issues and volumetric efficiency loss mechanisms for each compressor type. Furthermore it summarizes recent technical optimizations and innovations. Finally the paper identifies current research gaps particularly in reliability hydrogen embrittlement and intelligent control under high-temperature and high-pressure conditions. It also proposes future technology development pathways and standardization recommendations aiming to serve as a reference for further R&D and the industrialization of hydrogen compression technology.
Addressing Spatiotemporal Mismatch via Hourly Pipeline Scheduling: Regional Hydrogen Energy Supply Optimization
Nov 2025
Publication
The rapid adoption of hydrogen fuel cell vehicles (HFCVs) in the Beijing–Tianjin–Hebei (BTH) hub accentuates the mismatch between renewable-based hydrogen supply in Hebei and concentrated demand in Beijing and Tianjin. We develop a mixed-integer linear model that co-configures a hydrogen pipeline network and optimizes hourly flow schedules to minimize annualized cost and CO2 emissions simultaneously. For 15000 HFCVs expected in 2025 (137 t d−1 demand) the Pareto-optimal design consists of 13 production plants 43 pipelines and 38 refueling stations delivering 50767 t yr−1 at 68% pipeline utilization. Hebei provides 88% of the hydrogen 70% of which is consumed in the two megacities. Hourly profiles reveal that 65% of electrolytic output coincides with local wind–solar peaks whereas refueling surges arise during morning and evening rush hours; the proposed schedule offsets the 4–6 h mismatch without additional storage. Transport distances are 40% < 50 km 35% 50–200 km and 25% > 200 km. Raising the green hydrogen share from 10% to 70% increases total system cost from USD 1.56 bn to USD 2.73 bn but cuts annual CO2 emissions from 142 kt to 51 kt demonstrating the trade-off between cost and decarbonization. The model quantifies the value of sub-day pipeline scheduling in resolving spatial–temporal imbalances for large-scale low-carbon hydrogen supply.
An Overview of Development and Challenges in the Use of Hydrogen as a Fuel for a Dual-Fuel Diesel Engine
Nov 2025
Publication
The gradual exhaustion of fossil fuel reserves along with the adverse effects of their consumption on global climate drives the need for research into alternative energy sources that can meet the growing demand in a sustainable and eco-friendly way. Among these hydrogen stands out as one of the most promising options for the automotive sector being the cleanest available fuel and capable of being produced from renewable resources. This paper reviews the existing literature on compression ignition engines operating in a dualfuel configuration where diesel serves as the ignition source and hydrogen is used to enhance the combustion process. The reviewed studies focus on engine systems with hydrogen injection into the intake manifold. The investigations analyzed the influence of hydrogen energy fraction on combustion characteristics engine performance combustion stability and exhaust emissions in diesel/hydrogen dual-fuel engines operating under full or near-full-load conditions. The paper identifies the main challenges hindering the widespread and commercial application of hydrogen in diesel/hydrogen dual-fuel engines and discusses potential methods to overcome the existing barriers in this area.
Techno-Economic Analysis of Green Hydrogen Energy Production in West Africa
Nov 2025
Publication
The United Nations has set a global vision towards emissions reduction and green growth through the Sustainable Development Goals (SDGs). Towards the realisation of SDGS 7 9 and 13 we focus on green hydrogen production as a potential pathway to achievement. Green hydrogen produced via water electrolysis powered by renewable energy sources represents a pivotal solution towards climate change mitigation. Energy access in West Africa remains a challenge and dependency on fossil fuels persists. So green hydrogen offers an opportunity to harness abundant solar resources reduce carbon emissions and foster economic development. This study evaluates the techno-economic feasibility of green hydrogen production in five West African countries: Ghana Nigeria Mali Niger and Senegal. The analyses cover the solar energy potential hydrogen production capacities and economic viability using the Levelised Cost of Hydrogen (LCOH) and Net Present Value (NPV). Results indicate substantial annual hydrogen production potential with LCOH values competitive with global benchmarks amidst the EU’s Carbon Border Adjustment Mechanism (CBAM). Despite this potential several barriers exist including high initial capital costs policy and regulatory gaps limited technical capacity and water resource constraints. We recommend targeted strategies for strengthening policy frameworks fostering international partnerships enhancing regional infrastructure integration and investing in capacity-building initiatives. By addressing these barriers West Africa can be a key player in the global green hydrogen market.
Life Cycle of Fuel Cells: From Raw Materials to End-of-Life Management
Nov 2025
Publication
Fuel cells are highly efficient electrochemical devices that convert the chemical energy of fuel directly into electrical energy while generating minimal pollutant emissions. In recent decades they have established themselves as a key technology for sustainable energy supply in the transport sector stationary systems and portable applications. In order to assess their real contribution to environmental protection and energy efficiency a comprehensive analysis of their life cycle Life Cycle Assessment (LCA) is necessary covering all stages from the extraction of raw materials and the production of components through operation and maintenance to decommissioning and recycling. Particular attention is paid to the environmental challenges associated with the extraction of platinum catalysts the production of membranes and waste management. Economic aspects such as capital costs the price of hydrogen and maintenance costs also have a significant impact on their widespread implementation. This manuscript presents detailed mathematical models that describe the electrochemical characteristics energy and mass balances degradation dynamics and cost structures over the life cycle of fuel cells. The models focus on proton exchange membrane fuel cells (PEMFCs) with possible extensions to other types. LCA is applied to quantify environmental impacts such as global warming potential (GWP) while the levelized cost of electricity (LCOE) is used to assess economic viability. Particular attention is paid to the sustainability challenges of platinum catalyst extraction membrane production and end-of-life material recovery. By integrating technical environmental and economic modeling the paper provides a systematic perspective for optimizing fuel cell deployment within a circular economy.
Cost-Optimal Design of a Stand-Alone PV-Driven Hydrogen Production and Refueling Station Using Genetic Algorithms
Nov 2025
Publication
Driven by the growing availability of funding opportunities electrolyzers have become increasingly accessible unlocking significant potential for large-scale green hydrogen production. The goal of this investigation is to develop a techno-economic optimization framework for the design of a stand-alone photovoltaic (PV)-driven hydrogen production and refueling station with the explicit objective of minimizing the levelized cost of hydrogen (LCOH). The system integrates PV generation a proton-exchange-membrane electrolyzer battery energy storage compression and high-pressure hydrogen storage to meet the daily demand of a fleet of fuel cell buses. Results show that the optimal configuration achieves an LCOH of 11 €/kg when only fleet demand is considered whereas if surplus hydrogen sales are accounted for the LCOH reduces to 7.98 €/kg. The analysis highlights that more than 75% of total investment costs are attributable to PV and electrolysis underscoring the importance of capital incentives. Financial modeling indicates that a subsidy of about 58.4% of initial CAPEX is required to ensure a 10% internal rate of return under EU market conditions. The proposed methodology provides a reproducible decision-support tool for optimizing off-grid hydrogen refueling infrastructure and assessing policy instruments to accelerate hydrogen adoption in heavy-duty transport.
Optimal Dispatch Model for Hybrid Energy Storage in Low-Carbon Integrated Energy Systems
Nov 2025
Publication
Integrated Energy Systems (IESs) which leverage the synergistic coordination of electricity heat and gas networks serve as crucial enablers for a low-carbon transition. Current research predominantly treats energy storage as a subordinate resource in dispatch schemes failing to simultaneously optimise IES economic efficiency and storage operators’ profit maximisation thereby overlooking their potential value as independent market entities. To address these limitations this study establishes an operator-autonomous management framework incorporating electrical thermal and hydrogen storage in IESs. We propose a joint optimal dispatch model for hybrid energy storage systems in low-carbon IES operation. The upper-level model minimises total system operation costs for IES operators while the lower-level model maximises net profits for independent storage operators managing various storage assets. These two levels are interconnected through power price and carbon signals. The effectiveness of the proposed model is verified by setting up multiple scenarios for example analysis.
Hydrogen-Rich Gaseous Mixture for Enhanced Combustion in a Flex-Fuel Engine: An Experimental Analysis
Nov 2025
Publication
This experimental study examines the effect of adding a hydrogen-enriched synthetic gaseous mixture (HGM’) on the combustion and fuel conversion efficiency of a singlecylinder research engine (SCRE). The work assesses the viability of using this mixture as a supplemental fuel for flex-fuel engines operating under urban driving cycling conditions. An SCRE the AVL 5405 model was employed operating with ethanol and gasoline as primary fuels through direct injection (DI) and a volumetric compression ratio of 11.5:1. The HGM’ was added in the engine’s intake via fumigation (FS) with volumetric proportions ranging from 5% to 20%. The tests were executed at 1900 rpm and 2500 rpm engine speeds with indicated mean effective pressures (IMEPs) of 3 and 5 bar. When HGM’s 5% v/v was applied at 2500 rpm the mean indicated effective pressure of 3 bar was observed. A decrease of 21% and 16.5% in the ISFC was observed when using gasoline and ethanol as primary fuels respectively. The usage of an HGM’ combined with gasoline or ethanol proved to be a relevant and economically accessible strategy in the improvement of the conversion efficiency of combustion fuels once this gaseous mixture could be obtained through the vapor-catalytic reforming of ethanol giving up the use of turbochargers or lean and ultra-lean burn strategies. These results demonstrated the potential of using HGM’ as an effective alternative to increase the efficiency of flex-fuel engines.
Hydrogen Diffusivity and Hydrogen Traps Behavior of a Tempered and Untempered Martensitic Steel
Nov 2025
Publication
The effect of tempering temperature and tempering time on the density of hydrogen traps hydrogen diffusivity and microhardness in a vanadium-modified AISI 4140 martensitic steel was determined. Tempering parameters were selected to activate the second third and fourth tempering stages. These conditions were intended to promote specific microstructural transformations. Permeability tests were performed using the electrochemical method developed by Devanathan and Stachurski and microhardness was measured before and after these tests. It was observed that hydrogen diffusivity is inversely proportional to microhardness while the density of hydrogen traps is directly proportional to microhardness. The lowest hydrogen diffusivity the highest trap density and the highest microhardness were obtained in the as-quenched condition and the tempering at 286 ◦C for 0.25 h. In contrast tempering at a temperature corresponding to the fourth tempering stage increases hydrogen diffusivity and decreases the density of hydrogen traps and microhardness. However as the tempering time or temperature increases the opposite occurs which is attributed to the formation of alloy carbides. Finally hydrogen has a softening effect for tempering temperatures corresponding to the fourth tempering stage tempering times of 0.25 h and in the as-quenched condition. However with increasing tempering time hydrogen has a hardening effect.
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