Publications
Flexible Electricity Use for Heating in Markets with Renewable Energy
Mar 2020
Publication
Using electricity for heating can contribute to decarbonization and provide flexibility to integrate variable renewable energy. We analyze the case of electric storage heaters in German 2030 scenarios with an open-source electricity sector model. We find that flexible electric heaters generally increase the use of generation technologies with low variable costs which are not necessarily renewables. Yet making customary night-time storage heaters temporally more flexible offers only moderate benefits because renewable availability during daytime is limited in the heating season. Respective investment costs accordingly have to be very low in order to realize total system cost benefits. As storage heaters feature only short-term heat storage they also cannot reconcile the seasonal mismatch of heat demand in winter and high renewable availability in summer. Future research should evaluate the benefits of longer-term heat storage.
Enabling Low-carbon Hydrogen Supply Chains Through Use of Biomass and Carbon Capture and Storage: A Swiss Case Study
Jul 2020
Publication
This study investigates the optimal design of low-carbon hydrogen supply chains on a national scale. We consider hydrogen production based on several feedstocks and energy sources namely water with electricity natural gas and biomass. When using natural gas we couple hydrogen production with carbon capture and storage. The design of the hydrogen biomass and carbon dioxide (CO2 ) infrastructure is performed by solving an optimization problem that determines the optimal selection size and location of the hydrogen production technologies and the optimal structure of the hydrogen biomass and CO2 O2 networks. First we investigate the rationale behind the optimal design of low-carbon hydrogen supply chains by referring to an idealized system configuration and by performing a parametric analysis of the most relevant design parameters of the supply chains such as biomass availability. This allows drawing general conclusions independent of any specific geographic features about the minimum-cost and minimum-emissions system designs and network structures. Moreover we analyze the Swiss case study to derive specific guidelines concerning the design of hydrogen supply chains deploying carbon capture and storage. We assess the impact of relevant design parameters such as location of CO2 storage facilities techno-economic features of CO2 capture technologies and network losses on the optimal supply chain design and on the competition between the hydrogen and CO2 networks. Findings highlight the fundamental role of biomass (when available) and of carbon capture and storage for decarbonizing hydrogen supply chains while transitioning to a wider deployment of renewable energy sources.
SimSES: A Holistic Simulation Framework for Modeling and Analyzing Stationary Energy Storage Systems
Feb 2022
Publication
The increasing feed-in of intermittent renewable energy sources into the electricity grids worldwide is currently leading to technical challenges. Stationary energy storage systems provide a cost-effective and efficient solution in order to facilitate the growing penetration of renewable energy sources. Major technical and economical challenges for energy storage systems are related to lifetime efficiency and monetary returns. Holistic simulation tools are needed in order to address these challenges before investing in energy storage systems. One of these tools is SimSES a holistic simulation framework specialized in evaluating energy storage technologies technically and economically. With a modular approach SimSES covers various topologies system components and storage technologies embedded in an energy storage application. This contribution shows the capabilities and benefits of SimSES by providing in-depth knowledge of the implementations and models. Selected functionalities are demonstrated with two use cases showing the easy-to-use simulation framework while providing detailed technical analysis for expert users. Hybrid energy storage systems consisting of lithium-ion and redox-flow batteries are investigated in a peak shaving application while various system topologies are analyzed in a frequency containment reserve application. The results for the peak shaving case study show a benefit in favor of the hybrid system in terms of overall cost and degradation behavior in applications that have a comparatively low energy throughput during lifetime. In terms of system topology a cascaded converter approach shows significant improvements in efficiency for the frequency containment reserve application.
Power-to-Steel: Reducing CO2 through the Integration of Renewable Energy and Hydrogen into the German Steel Industry
Apr 2017
Publication
This paper analyses some possible means by which renewable power could be integrated into the steel manufacturing process with techniques such as blast furnace gas recirculation (BF-GR) furnaces that utilize carbon capture a higher share of electrical arc furnaces (EAFs) and the use of direct reduced iron with hydrogen as reduction agent (H-DR). It is demonstrated that these processes could lead to less dependence on—and ultimately complete independence from—coal. This opens the possibility of providing the steel industry with power and heat by coupling to renewable power generation (sector coupling). In this context it is shown using the example of Germany that with these technologies reductions of 47–95% of CO2 emissions against 1990 levels and 27–95% of primary energy demand against 2008 can be achieved through the integration of 12–274 TWh of renewable electrical power into the steel industry. Thereby a substantial contribution to reducing CO2 emissions and fuel demand could be made (although it would fall short of realizing the German government’s target of a 50% reduction in power consumption by 2050).
Hydrogen vs. Battery-Based Propulsion Systems in Unipersonal Vehicles—Developing Solutions to Improve the Sustainability of Urban Mobility
May 2021
Publication
The percentage of the population in urban areas has increased by ten points from 2000 (46%) to 2020 (56%); it is expected to reach up to 70% by 2050. This undoubtedly will encourage society to use alternative transports. On the other hand the widespread fear of pandemics seems to be here to stay and it is causing most people to leave public transport to use private cars and a few have chosen unipersonal electric vehicles. As a consequence the decision of using private cars negatively affects the air quality and consequently urban population health. This paper aims to demonstrate a sustainable solution for urban mobility based on a hydrogen powered unipersonal electric vehicle which as shown provides great advantages over the conventional battery powered unipersonal electric vehicle. To show this the authors have developed both vehicles in comparable versions using the same platform and ensuring that the total weight of the unipersonal electric vehicle was the same in both cases. They have been subjected to experimental tests that support the features of the hydrogen-based configuration versus the battery-based one including higher specific energy more autonomy and shorter recharge time.
Hydrogen-Based Energy Storage Systems for Large-Scale Data Center Applications
Nov 2021
Publication
Global demand for data and data access has spurred the rapid growth of the data center industry. To meet demands data centers must provide uninterrupted service even during the loss of primary power. Service providers seeking ways to eliminate their carbon footprint are increasingly looking to clean and sustainable energy solutions such as hydrogen technologies as alternatives to traditional backup generators. In this viewpoint a survey of the current state of data centers and hydrogen-based technologies is provided along with a discussion of the hydrogen storage and infrastructure requirements needed for large-scale backup power applications at data centers.
Van der Waals Heterostructures - Recent Progress in Electrode Materials for Clean Energy Applications
Jul 2021
Publication
The unique layered morphology of van der Waals (vdW) heterostructures give rise to a blended set of electrochemical properties from the 2D sheet components. Herein an overview of their potential in energy storage systems in place of precious metals is conducted. The most recent progress on vdW electrocatalysis covering the last three years of research is evaluated with an emphasis on their catalytic activity towards the oxygen reduction reaction (ORR) oxygen evolution reaction (OER) and hydrogen evolution reaction (HER). This analysis is conducted in pair with the most active Pt-based commercial catalyst currently utilized in energy systems that rely on the above-listed electrochemistry (metal–air battery fuel cells and water electrolyzers). Based on current progress in HER catalysis that employs vdW materials several recommendations can be stated. First stacking of the two types vdW materials with one being graphene or its doped derivatives results in significantly improved HER activity. The second important recommendation is to take advantage of an electronic coupling when stacking 2D materials with the metallic surface. This significantly reduces the face-to-face contact resistance and thus improves the electron transfer from the metallic surface to the vdW catalytic plane. A dual advantage can be achieved from combining the vdW heterostructure with metals containing an excess of d electrons (e.g. gold). Despite these recent and promising discoveries more studies are needed to solve the complexity of the mechanism of HER reaction in particular with respect to the electron coupling effects (metal/vdW combinations). In addition more affordable synthetic pathways allowing for a well-controlled confined HER catalysis are emerging areas.
Optimal Facility Combination Set of Integrated Energy System Based on Consensus Point between Independent System Operator and Independent Power Producer
Dec 2022
Publication
In recent years the frequency of power demand imbalance and negative price phenomenon has risen due to the rapid expansion of renewable energy sources (RES). Because of this a means to reduce the curtailment of RES by utilizing surplus energy is essential. This paper focuses on reducing the curtailment of wind turbines (WT) with high output intermittency and minimizing the investment cost of IES via an integrated energy system (IES). The IES operation seeks to improve the acceptability and efficiency of the RES as it supports the integration of various energies mix such as electricity heat hydrogen. This paper proposes an optimal facility combination set (FCS) of IES that satisfies the requirements of ISO and IPP using Multi-Objective Optimization Programming (MOP). The case study is based on a wind farm in South Korea set in Aewol-eup Jeju-Island. The case study results provide the best configuration of the IES energy mix with the best economic value and efficiency while satisfying ISO and IPP perspectives.
Greenhouse Gas Emissions of Conventional and Alternative Vehicles: Predictions Based on Energy Policy Analysis in South Korea
Mar 2020
Publication
This paper compares the well-to-wheel (WTW) greenhouse gas (GHG) emissions of representative vehicle types–internal combustion engine vehicle (ICEV) hybrid electric vehicle (HEV) plug-in hybrid electric vehicle (PHEV) battery electric vehicle (BEV) and fuel cell electric vehicle (FCEV)–in the future (2030) based on a WTW analysis for the present (2017) and an analysis of various energy policies that could affect future emissions. South Korea was selected as the target region because it has detailed energy policies related to alternative vehicles. The WTW analysis for the present was performed based on three sets of subordinate analyses: (1) life cycle analyses of eight base fuels; (2) life cycle analyses of electricity and hydrogen; and (3) analyses of the fuel economies of seven vehicle types. From the WTW analysis for the present the national average WTW GHG emissions of ICEV-gasoline ICEV-diesel ICEV-liquefied petroleum gas HEV PHEV BEV and FCEV were calculated as 225 233 201 159 133 109 and 55 g-CO2-eq./km respectively. For calculating the WTW GHG emissions in the future two policies regarding electricity production and three policies regarding hydrogen production were analysed. Three cases with varying the degrees of improvements in fuel economies were considered. Six future scenarios were constructed and each scenario represented the case in which each energy policy is enacted. In the reference scenario for compact car the WTW GHG emissions of ICEVs-gasoline HEV PHEV BEV-200 mile FCEV were analysed as 161 110 97 86 and 91 g-CO2-eq./km respectively. The differences between ICEV/HEV and BEV were predicted to decrease in the future mainly due to larger improvements of ICEV/HEV in fuel economies compared to that of BEV. The future life cycle GHG emissions of electricity and hydrogen were calculated according to energy policy. Both two policies regarding power generation were confirmed to increase the benefits of utilizing BEVs but current energy policy regarding hydrogen production were confirmed to decrease the benefits of utilizing FCEVs. Based on the comprehensive results of this study a framework was proposed to evaluate the impacts of an energy policy regarding electricity and hydrogen production on the benefits of using BEVs and FCEVs compared to using HEVs and ICEVs. This framework can also be utilized in other countries when they assess and establish their energy policies.
Heat Pumps for Space Heating and Domestic Hot Water Production in Residential Buildings, an Environmental Comparison in a Present and Future Scenario
Nov 2022
Publication
The hydrogen vector stands as a potentially important tool to achieve the decarbonization of the energy sector. It represents an option to store the periodic excesses of energy generation from renewable electrical sources to be used as it is as a substitute for fossil fuels in some applications or reconverted into electricity when needed. In this context hydrogen can significantly decarbonize the building sector as an alternative fuel for gas-driven devices. Along with hydrogen the European strategic vision indicates the electrification of heat among the main energy transition pathways. The potential environmental benefits achievable from renewable hydrogen in thermally-driven appliances and the electrification of residential heat through electric heat pumps were evaluated and compared in this work. The novelty of the research consists of a consequential comparative life cycle assessment (16 impact categories) evaluation for three buildings (old old retrofitted and new) supplied by three different appliances (condensing boiler gas absorption heat pump and electric heat pump) never investigated before. The energy transition was evaluated for 2020 and 2030 scenarios considering the impact of gaseous fuels (natural gas and European green hydrogen) and electricity based on the pathway of the European electricity grid (27 European member states plus the United Kingdom). The results allowed to compare the environmental profile in deterministic and stochastic approaches and confirm if the increase of renewables reduces the impact in the operational phase of the appliances. The results demonstrate that despite the increased renewable share the use phase remains the most significant for both temporal scenarios contributing to 91% of the environmental profile. Despite the higher footprint in 2020 compared to the electric heat pump (198–200 vs. 170–196 gCO2eq/kWhth) the gas absorption heat pump offered a lower environmental profile than the others in all the scenarios analyzed.
Life Cycle Assessment of Improved High Pressure Alkaline Electrolysis
Aug 2015
Publication
This paper investigates environmental impacts of high pressure alkaline water electrolysis systems. An advanced system with membranes on polymer basis is compared to a state-of-the-art system with asbestos membranes using a Life Cycle Assessment (LCA) approach. For the advanced system a new improved membrane technology has been investigated within the EU research project “ELYGRID”. Results indicate that most environmental impacts are caused by the electricity supply necessary for operation. During the construction phase cell stacks are the main contributor to environmental impacts. New improved membranes have relatively small contributions to impacts caused by cell construction within the advanced systems. As main outcome the systems comparison illustrates a better ecological performance of the new developed system
Ex Situ Thermo-catalytic Upgrading of Biomass Pyrolysis Vapors Using a Traveling Wave Microwave Reactor
Sep 2016
Publication
Microwave heating offers a number of advantages over conventional heating methods such as rapid and volumetric heating precise temperature control energy efficiency and lower temperature gradient. In this article we demonstrate the use of 2450 MHz microwave traveling wave reactor to heat the catalyst bed for thermo-catalytic upgrading of pyrolysis vapors. HZSM-5 catalyst was tested at three different temperatures (290 330 and 370°C) at a catalyst to biomass ratio of 2. Results were compared with conventional heating and induction heating method of catalyst bed. The yields of aromatic compounds and coke deposition were dependent on temperature and method of heating. Microwave heating yielded higher aromatic compounds and lower coke deposition. Microwave heating was also energy efficient compared to conventional reactors. The rate of catalyst deterioration was lower for catalyst heated in microwave system.
Assessment of an Innovative Way to Store Hydrogen in Vehicles
May 2019
Publication
The use of hydrogen as an alternative to fossil fuels for vehicle propulsion is already a reality. However due to its physical characteristics storage is still a challenge. There is an innovative way presented in this study to store hydrogen in conventional vehicles propelled by spark-ignition reciprocating engines and fuel cells using hydrogen as fuel; the storage of hydrogen will be at high pressure within small spheres randomly packed in a tank like the conventional tank of fuel used nowadays in current vehicles. Therefore the main purpose of the present study is to assess the performance of this storage system and compare it to others already applied by car manufacturers in their cars. In order to evaluate the performance of this storage system some parameters were taken into account: The energy stored by volume and stored by weight hydrogen leakage and compliance with current standards. This system is safer than conventional storage systems since hydrogen is stored inside small spheres containing small amounts of hydrogen. Besides its gravimetric energy density (GED) is threefold and the volumetric energy density (VED) is about half when compared with homologous values for conventional systems and both exceed the targets set by the U.S. Department of Energy. Regarding the leakage of hydrogen it complies with the European Standards provided a suitable choice of materials and dimensions is made.
Sorption-enhanced Steam Methane Reforming for Combined CO2 Capture and Hydrogen Production: A State-of-the-Art Review
Oct 2021
Publication
The European Commission have just stated that hydrogen would play a major role in the economic recovery of post-COVID-19 EU countries. Hydrogen is recognised as one of the key players in a fossil fuel-free world in decades to come. However commercially practiced pathways to hydrogen production todays are associated with a considerable amount of carbon emissions. The Paris Climate Change Agreement has set out plans for an international commitment to reduce carbon emissions within the forthcoming decades. A sustainable hydrogen future would only be achievable if hydrogen production is “designed” to capture such emissions. Today nearly 98% of global hydrogen production relies on the utilisation of fossil fuels. Among these steam methane reforming (SMR) boasts the biggest share of nearly 3 50% of the global generation. SMR processes correspond to a significant amount of carbon emissions at various points throughout the process. Despite the dark side of the SMR processes they are projected to play a major role in hydrogen production by the first half of this century. This that a sustainable yet clean short/medium-term hydrogen production is only possible by devising a plan to efficiently capture this co-produced carbon as stated in the latest International Energy Agency (IEA) reports. Here we have carried out an in-depth technical review of the processes employed in sorption-enhanced steam methane reforming (SE-SMR) an emerging technology in low-carbon SMR for combined carbon capture and hydrogen production. This paper aims to provide an in-depth review on two key challenging elements of SE-SMR i.e. the advancements in catalysts/adsorbents preparation and current approaches in process synthesis and optimisation including the employment of artificial intelligence in SE-SMR processes. To the best of the authors‟ knowledge there is a clear gap in the literature where the above areas have been scrutinised in a systematic and coherent fashion. The gap is even more pronounced in the application of AI in SE-SMR technologies. As a result this work aims to fill this gap within the scientific literature.
Integrating a Hydrogen Fuel Cell Electric Vehicle with Vehicle-to-grid Technology, Photovoltaic Power and a Residential Building
Feb 2018
Publication
This paper presents the results of a demonstration project including building-integrated photovoltaic (BIPV) solar panels a residential building and a hydrogen fuel cell electric vehicle (FCEV) for combined mobility and power generation aiming to achieve a net zero-energy residential building target. The experiment was conducted as part of the Car as Power Plant project at The Green Village in the Netherlands. The main objective was to assess the end-user’s potential of implementing FCEVs in vehicle-to-grid operation (FCEV2G) to act as a local energy source. FCEV2G field test performance with a Hyundai ix35 FCEV are presented. The car was adapted using a power output socket capable of delivering up to 10 kW direct current (DC) to the alternating current (AC) national grid when parked via an off-board (grid-tie) inverter. A Tank-To-AC-Grid efficiency (analogous to Tank- To-Wheel efficiency when driving) of 44% (measured on a Higher Heating Value basis) was obtained when the car was operating in vehicle-to-grid (V2G) mode at the maximum power output. By collecting and analysing real data on the FCEV power production in V2G mode and on BIPV production and household consumption two different operating modes for the FCEV offering balanced services to a residential microgrid were identified namely fixed power output and load following. Based on the data collected one-year simulations of a microgrid consisting of 10 all-electric dwellings and 5 cars with the different FCEV2G modes of operation were performed. Simulation results were evaluated on the factors of autonomy self-consumption of locally produced energy and net-energy consumption by implementing different energy indicators. The results show that utilizing an FCEV working in V2G mode can reduce the annual imported electricity from the grid by approximately 71% over one year and aiding the buildings in the microgrid to achieve a net zero-energy building target. Furthermore the simulation results show that utilizing the FCEV2G setup in both modes analysed could be economically beneficial for the end-user if hydrogen prices at the pump fall below 8.24 €/kg.
Fuel Cell Electric Vehicle as a Power Plant and SOFC as a Natural Gas Reformer: An Exergy Analysis of Different System Designs
Apr 2016
Publication
Delft University of Technology under its ‘‘Green Village” programme has an initiative to build a power plant (car parking lot) based on the fuel cells used in vehicles for motive power. It is a trigeneration system capable of producing electricity heat and hydrogen. It comprises three main zones: a hydrogen production zone a parking zone and a pump station zone. This study focuses mainly on the hydrogen production zone which assesses four different system designs in two different operation modes of the facility: Car as Power Plant (CaPP) mode corresponding to the open period of the facility which uses fuel cell electric vehicles (FCEVs) as energy and water producers while parked; and Pump mode corresponding to the closed period which compresses the hydrogen and pumps to the vehicle’s fuel tank. These system designs differ by the reforming technology: the existing catalytic reformer (CR) and a solid oxide fuel cell operating as reformer (SOFCR); and the option of integrating a carbon capture and storage (CCS). Results reveal that the SOFCR unit significantly reduces the exergy destruction resulting in an improvement of efficiency over 20% in SOFCR-based system designs compared to CR-based system designs in both operation modes. It also mitigates the reduction in system efficiency by integration of a CCS unit achieving a value of 2% whereas in CR-based systems is 7–8%. The SOFCR-based system running in Pump mode achieves a trigeneration efficiency of 60%.
Safety Standard for Hydrogen and Hydrogen Systems Guidelines for Hydrogen System Design, Materials Selection, Operations, Storage and Transportation
Jan 1997
Publication
The NASA Safety Standard which establishes a uniform process for hydrogen system design materials selection operation storage and transportation is presented. The guidelines include suggestions for safely storing handling and using hydrogen in gaseous (GH2) liquid (LH2) or slush (SLH2) form whether used as a propellant or non-propellant. The handbook contains 9 chapters detailing properties and hazards facility design design of components materials compatibility detection and transportation. Chapter 10 serves as a reference and the appendices contained therein include: assessment examples; scaling laws explosions blast effects and fragmentation; codes standards and NASA directives; and relief devices along with a list of tables and figures abbreviations a glossary and an index for ease of use. The intent of the handbook is to provide enough information that it can be used alone but at the same time reference data sources that can provide much more detail if required.
Modeling Photovoltaic-electrochemical Water Splitting Devices for the Production of Hydrogen Under Real Working Conditions
Jan 2022
Publication
Photoelectrochemical splitting of water is potentially a sustainable and affordable solution to produce hydrogen from sun light. Given the infancy stage of technology development it is important to compare the different experimental concepts and identify the most promising routes. The performance of photoelectrochemical devices is typically measured and reported under ideal irradiation conditions i.e. 1 sun. However real-life operating conditions are very different and are varying in time according to daily and seasonal cycles. In this work we present an equivalent circuit model for computing the steady state performance of photoelectrochemical cells. The model allows for a computationally efficient yet precise prediction of the system performance and a comparison of different devices working in real operating conditions. To this end five different photo-electrochemical devices are modeled using experimental results from literature. The calculated performance shows good agreement with experimental data of the different devices. Furthermore the model is extended to include the effect of illumination and tilt angle on the hydrogen production efficiency. The resulting model is used to compare the devices for different locations with high and low average illumination and different tilt angles. The results show that including real illumination data has a considerable impact on the efficiency of the PV-EC device. The yearly average solar-to-hydrogen efficiency is significantly lower than the ideal one. Moreover it is dependent on the tilt angle whose optimal value for European-like latitude is around 40. Notably we also show that the most performing device through the whole year might not necessarily be the one with highest sun-to-hydrogen efficiency for one-sun illumination.
Life Cycle Environmental and Cost Comparison of Current and Future Passenger Cars under Different Energy Scenarios
Apr 2020
Publication
In this analysis life cycle environmental burdens and total costs of ownership (TCO) of current (2017) and future (2040) passenger cars with different powertrain configurations are compared. For all vehicle configurations probability distributions are defined for all performance parameters. Using these a Monte Carlo based global sensitivity analysis is performed to determine the input parameters that contribute most to overall variability of results. To capture the systematic effects of the energy transition future electricity scenarios are deeply integrated into the ecoinvent life cycle assessment background database. With this integration not only the way how future electric vehicles are charged is captured but also how future vehicles and batteries are produced. If electricity has a life cycle carbon content similar to or better than a modern natural gas combined cycle powerplant full powertrain electrification makes sense from a climate point of view and in many cases also provides reductions in TCO. In general vehicles with smaller batteries and longer lifetime distances have the best cost and climate performance. If a very large driving range is required or clean electricity is not available hybrid powertrain and compressed natural gas vehicles are good options in terms of both costs and climate change impacts. Alternative powertrains containing large batteries or fuel cells are the most sensitive to changes in the future electricity system as their life cycles are more electricity intensive. The benefits of these alternative drivetrains are strongly linked to the success of the energy transition: the more the electricity sector is decarbonized the greater the benefit of electrifying passenger vehicles.
CFD Simulations of Large Scale LH2 Dispersion in Open Environment
Sep 2021
Publication
An inter-comparison among partners’ CFD simulations has been carried out within the EU-funded project PRESLHY to investigate the dispersion of the mixture cloud formed from large scale liquid hydrogen release. Rainout experiments performed by Health and Safety Executive (HSE) have been chosen for the work. From the HSE experimental series trial-11 was selected forsimulation due to its conditions where only liquid flow at the nozzle was achieved. During trial-11 liquid hydrogen is spilled horizontally 0.5 m above a concrete pad from a 5 barg tank pressure through a 12 mm (1/2 inch) nozzle. The dispersion takes place outdoors and thus it is imposed to variant wind conditions. Comparison of the CFD results with the measurements at several sensors is presented and useful conclusions are drawn.
A Model-based Parametric and Optimal Sizing of a Battery/Hydrogen Storage of a Real Hybrid Microgrid Supplying a Residential Load: Towards Island Operation
Jun 2021
Publication
In this study the optimal sizing of a hybrid battery/hydrogen Energy Storage System “ESS” is assessed via a model-based parametric analysis in the context of a real hybrid renewable microgrid located in Huelva Spain supplying a real-time monitored residential load (3.5 kW; 5.6 MWh/year) in island mode. Four storage configurations (battery-only H2-only hybrid battery priority and hybrid H2 priority) are assessed under different Energy Management Strategies analysing system performance parameters such as Loss of Load “LL” (kWh;%) Over Production “OP” (kWh;%) round-trip storage efficiency ESS (%) and total storage cost (€) depending on the ESS sizing characteristics. A parallel approach to the storage optimal sizing via both multi-dimensional sensitivity analysis and PSO is carried out in order to address both sub-optimal and optimal regions respectively. Results show that a hybridised ESS capacity is beneficial from an energy security and efficiency point of view but can represent a substantial additional total cost (between 100 and 300 k€) to the hybrid energy system especially for the H2 ESS which presents higher costs. Reaching 100% supply from renewables is challenging and introducing a LL threshold induces a substantial relaxation of the sizing and cost requirements. Increase in battery capacity is more beneficial for the LL abatement while increasing H2 capacity is more useful to absorb large quantities of excess energy. The optimal design via PSO technique is complemented to the parametric study.
Role of Hydrogen-Charging on Nucleation and Growth of Ductile Damage in Austenitic Stainless Steels
May 2019
Publication
Hydrogen energy is a possible solution for storage in the future. The resistance of packaging materials such as stainless steels has to be guaranteed for a possible use of these materials as containers for highly pressurized hydrogen. The effect of hydrogen charging on the nucleation and growth of microdamage in two different austenitic stainless steels AISI316 and AISI316L was studied using in situ tensile tests in synchrotron X-ray tomography. Information about damage nucleation void growth and void shape were obtained. AISI316 was found to be more sensitive to hydrogen compared to AISI316L in terms of ductility loss. It was measured that void nucleation and growth are not affected by hydrogen charging. The effect of hydrogen was however found to change the morphology of nucleated voids from spherical cavities to micro-cracks being oriented perpendicular to the tensile axis.
Advanced Polymeric/inorganic Nanohybrids: An Integrated Platform for Gas Sensing Applications
Jan 2022
Publication
Rapid industrial development vehicles domestic activities and mishandling of garbage are the main sources of pollutants which are destroying the atmosphere. There is a need to continuously monitor these pollutants for the safety of the environment and human beings. Conventional instruments for monitoring of toxic gases are expensive bigger in size and time-consuming. Hybrid materials containing organic and inorganic components are considered potential candidates for diverse applications including gas sensing. Gas sensors convert the information regarding the analyte into signals. Various polymeric/inorganic nanohybrids have been used for the sensing of toxic gases. Composites of different polymeric materials like polyaniline (PANI) poly (4-styrene sulfonate) (PSS) poly (34-ethylene dioxythiophene) (PEDOT) etc. with various metal/metal oxide nanoparticles have been reported as sensing materials for gas sensors because of their unique redox features conductivity and facile operation at room temperature. Polymeric nanohybrids showed better performance because of the larger surface area of nanohybrids and the synergistic effect between polymeric and inorganic materials. This review article focuses on the recent developments of emerging polymeric/inorganic nanohybrids for sensing various toxic gases including ammonia hydrogen nitrogen dioxide carbon oxides and liquefied petroleum gas. Advantages disadvantages operating conditions and prospects of hybrid composites have also been discussed.
Phase Field Modelling of Formation and Fracture of Expanding Precipitates
May 2017
Publication
It is a common belief that embedded expanding inclusions are subjected to an internal homogeneous compressive hydrostatic stress. Still cracks that appear in precipitates that occupy a larger volume than the original material are frequently observed. The appearance of cracks has since long been regarded as a paradox. In the present study it is shown that matrix materials that increases its volume even several percent during the precipitation process develop a tensile hydrostatic stress in the centre of the precipitate. This is the result of a complicated mechanical-chemical phase transformation process. The process is here studied using a Landau phase feld model. Before the material is transformed and incorporated in a precipitate it undergoes stretching beyond the elastic strain limit because of the presence of already expanded material. During the phase transformation the accompanying volumetric expansion cannot be fully accommodated which instead creates an internal compressive stress and adds tension in the surrounding material. As the growth of the precipitate proceeds a region with increasing tensile stress develops in the interior of the precipitate. This is suggested to be the most probable cause of the observed cracks. First the mechanics that lead to the tension is computed. The infuence of elastic-plastic properties is studied both for cases both with and without cracks. The growth history from microscopic to macroscopic precipitates is followed and the result is compared with observations of so called hydride blisters that are formed on surfaces of zirconium alloys in the presence of hydrogen. A common practical situation is when the zirconium is in contact with an object of lower temperature. Then the cooled spot attracts hydrogen that make the zirconium transform to a metal hydride with the shape of a blister. The simulations predicts a final size and position of the growing crack that compares well with the experimental observations.
Brittle Fracture Manifestation in Gas Pipeline Steels after Long-term Operation
Dec 2020
Publication
Gas pipelines are exposed to operational loads combined with corrosive environment action during their long-term service. Complicated service conditions lead to a worsening of steel properties a reduction of serviceability of the whole object therefore a risk of its premature failure rises. Aware of the importance of the existing problem the aim of this study is the analysis of various mechanical properties of steels after their long-term operation on gas pipelines and detecting and evaluating fractographic signs of this degradation.<br/>Mechanical properties of operated pipe steels characterizing their brittle fracture resistance were significantly decreased. Delamination areas as one of a feature of brittle fracture were identified on the fracture surfaces of specimens after SSRT of the operated steels in corrosive environment. Fracture was initiated from the outer surface of the specimens along the boundaries of ferrite and pearlite grains with significant secondary cracking.<br/>The obvious texture in the steels affects noticeably the results of the impact tests. Higher KCV values for the specimens cut in the longitudinal direction relative to the pipe axis comparing with the specimens of transversal orientation were obtained. This was explained by different length of narrow pearlite strips alternated by wide ferrite bands and interrupted by individual ferrite grains depending on the orientation of the specimen fracture surface relative to the pipe axis. Thus a proper direction of specimen cutting to achieve the maximum sensitivity of KCV parameter to operational degradation of steels is discussed. The effect of specimen orientation on the results of the Charpy testing becomes much more pronounced with steel operation. Defects accumulated in steels during their service are preferentially oriented in the pipe axial direction along the boundaries between ferrite and pearlite strips. Analyzing the fracture surfaces of the Charpy specimens after their impact testing certain signs of embrittlement were found for long term operated steels in the form of delaminations varying in size and shape and some cleavage fragments. Furthermore their percentage of total fracture surface (generally formed by dimples) correlates well with a drop in the impact toughness. The established relationship could be the basis for the introduction of fractographic criteria of the steel serviceability.
Hydrogen Production via Steam Reforming: A Critical Analysis of MR and RMM Technologies
Jan 2020
Publication
Hydrogen as the energy carrier of the future’ has been a topic discussed for decades and is today the subject of a new revival especially driven by the investments in renewable electricity and the technological efforts done by high-developed industrial powers such as Northern Europe and Japan. Although hydrogen production from renewable resources is still limited to small scale local solutions and R&D projects; steam reforming (SR) of natural gas at industrial scale is the cheapest and most used technology and generates around 8 kg CO2 per kg H2. This paper is focused on the process optimization and decarbonization of H2 production from fossil fuels to promote more efficient approaches based on membrane separation. In this work two emerging configurations have been compared from the numerical point of view: the membrane reactor (MR) and the reformer and membrane module (RMM) proposed and tested by this research group. The rate of hydrogen production by SR has been calculated according to other literature works a one-dimensional model has been developed for mass heat and momentum balances. For the membrane modules the rate of hydrogen permeation has been estimated according to mass transfer correlation previously reported by this research group and based on previous experimental tests carried on in the first RMM Pilot Plant. The methane conversion carbon dioxide yield temperature and pressure profile are compared for each configuration: SR MR and RMM. By decoupling the reaction and separation section such as in the RMM the overall methane conversion can be increased of about 30% improving the efficiency of the system.
Current Status of Automotive Fuel Cells for Sustainable Transport
May 2019
Publication
Automotive proton-exchange membrane fuel cells (PEMFCs) have finally reached a state of technological readiness where several major automotive companies are commercially leasing and selling fuel cell electric vehicles including Toyota Honda and Hyundai. These now claim vehicle speed and acceleration refueling time driving range and durability that rival conventional internal combustion engines and in most cases outperform battery electric vehicles. The residual challenges and areas of improvement which remain for PEMFCs are performance at high current density durability and cost. These are expected to be resolved over the coming decade while hydrogen infrastructure needs to become widely available. Here we briefly discuss the status of automotive PEMFCs misconceptions about the barriers that platinum usage creates and the remaining hurdles for the technology to become broadly accepted and implemented.
Environmental and Socio-Economic Analysis of Naphtha Reforming Hydrogen Energy Using Input-Output Tables: A Case Study from Japan
Aug 2017
Publication
Comprehensive risk assessment across multiple fields is required to assess the potential utility of hydrogen energy technology. In this research we analyzed environmental and socio-economic effects during the entire life cycle of a hydrogen energy system using input-output tables. The target system included hydrogen production by naphtha reforming transportation to hydrogen stations and FCV (Fuel Cell Vehicle) refilling. The results indicated that 31% 44% and 9% of the production employment and greenhouse gas (GHG) emission effects respectively during the manufacturing and construction stages were temporary. During the continuous operation and maintenance stages these values were found to be 69% 56% and 91% respectively. The effect of naphtha reforming was dominant in GHG emissions and the effect of electrical power input on the entire system was significant. Production and employment had notable effects in both the direct and indirect sectors including manufacturing (pumps compressors and chemical machinery) and services (equipment maintenance and trade). This study used data to introduce a life cycle perspective to environmental and socio-economic analysis of hydrogen energy systems and the results will contribute to their comprehensive risk assessment in the future.
Prospects and Obstacles for Green Hydrogen Production in Russia
Jan 2021
Publication
Renewable energy is considered the one of the most promising solutions to meet sustainable development goals in terms of climate change mitigation. Today we face the problem of further scaling up renewable energy infrastructure which requires the creation of reliable energy storages environmentally friendly carriers like hydrogen and competitive international markets. These issues provoke the involvement of resource-based countries in the energy transition which is questionable in terms of economic efficiency compared to conventional hydrocarbon resources. To shed a light on the possible efficiency of green hydrogen production in such countries this study is aimed at: (1) comparing key Russian trends of green hydrogen development with global trends (2) presenting strategic scenarios for the Russian energy sector development (3) presenting a case study of Russian hydrogen energy project «Dyakov Ust-Srednekanskaya HPP» in Magadan region. We argue that without significant changes in strategic planning and without focus on sustainable solutions support the further development of Russian power industry will be halted in a conservative scenario with the limited presence of innovative solutions in renewable energy industries. Our case study showed that despite the closeness to Japan hydrogen market economic efficiency is on the edge of zero with payback period around 17 years. The decrease in project capacity below 543.6 MW will immediately lead to a negative NPV. The key reason for that is the low average market price of hydrogen ($14/kg) which is only a bit higher than its production cost ($12.5/kg) while transportation requires about $0.96/kg more. Despite the discouraging results it should be taken into account that such strategic projects are at the edge of energy development. We see them as an opportunity to lead transnational energy trade of green hydrogen which could be competitive in the medium term especially with state support.
Charge Carrier Mapping for Z-scheme Photocatalytic Water-splitting Sheet via Categorization of Microscopic Time-resolved Image Sequences
Jun 2021
Publication
Photocatalytic water splitting system using particulate semiconductor materials is a promising strategy for converting solar energy into hydrogen and oxygen. In particular visible-light-driven ‘Z-scheme’ printable photocatalyst sheets are cost-effective and scalable. However little is known about the fundamental photophysical processes which are key to explaining and promoting the photoactivity. Here we applied the pattern-illumination time-resolved phase microscopy for a photocatalyst sheet composed of Mo-doped BiVO4 and Rh-doped SrTiO3 with indium tin oxide as the electron mediator to investigate photo-generated charge carrier dynamics. Using this method we successfully observed the position- and structure-dependent charge carrier behavior and visualized the active/inactive sites in the sheets under the light irradiation via the time sequence images and the clustering analysis. This combination methodology could provide the material/synthesis optimization methods for the maximum performance of the photocatalyst sheets.
Assessing the Environmental Impacts of Wind-based Hydrogen Production in the Netherlands Using Ex-ante LCA and Scenarios Analysis
Mar 2021
Publication
Two electrolysis technologies fed with renewable energy sources are promising for the production of CO2-free hydrogen and enabling the transition to a hydrogen society: Alkaline Electrolyte (AE) and Polymer Electrolyte Membrane (PEM). However limited information exists on the potential environmental impacts of these promising sustainable innovations when operating on a large-scale. To fill this gap the performance of AE and PEM systems is compared using ex-ante Life Cycle Assessment (LCA) technology analysis and exploratory scenarios for which a refined methodology has been developed to study the effects of implementing large-scale sustainable hydrogen production systems. Ex-ante LCA allows modelling the environmental impacts of hydrogen production exploratory scenario analysis allows modelling possible upscaling effects at potential future states of hydrogen production and use in vehicles in the Netherlands in 2050. A bridging tool for mapping the technological field has been created enabling the combination of quantitative LCAs with qualitative scenarios. This tool also enables diversity for exploring multiple sets of visions. The main results from the paper show with an exception for the “ozone depletion” impact category (1) that large-scale AE and PEM systems have similar environmental impacts with variations lower than 7% in all impact categories (2) that the contribution of the electrolyser is limited to 10% of all impact categories results and (3) that the origin of the electricity is the largest contributor to the environmental impact contributing to more than 90% in all impact categories even when renewable energy sources are used. It is concluded that the methodology was applied successfully and provides a solid basis for an ex-ante assessment framework that can be applied to emerging technological systems.
Hydrogen—An Alternative Fuel for Automotive Diesel Engines Used in Transportation
Nov 2020
Publication
Considering the current environmental restrictions particularly those imposed on fossil fuel exploitation hydrogen stands out as a very promising alternative for the power and transportation sectors. This paper investigates the effects of the employment of hydrogen in a K9K automotive diesel engine. Experiments were conducted at a speed of 2000 min−1 with various engine load levels of 40% 55% 70% and 85%; several quantities were monitored to evaluate the performance with hydrogen use in terms of brake-specific energetic consumption (BSEC) fuel economy maximum pressure and heat-release characteristics. It was found that at 55% engine load the engine efficiency increased by 5.3% with hydrogen addition achieving a diesel fuel economy of 1.32 kg/h. The rate of increase of the peak pressure and maximum pressure started to increase as a consequence of the higher fuel quantity that burned in the premixed combustion phase while still remaining within reliable operational limits. The accelerated combustion and augmented heat release rate resulted in a combustion duration that was reduced by 3◦ CA (crank angle degree) achieving a mass fraction burned percentage of 10% to 90% earlier in the cycle and the combustion variability was also influenced. Hydrogen use assured the decrease of CO2 HC NOx and smoke emission levels in comparison with classic fueling.
Fuel Cells and Hydrogen Observatory Technology and Market Report
Sep 2021
Publication
The information in this report covers the period January 2019 – December 2019. The technology and market module of the FCHO presents a range of statistical data as an indicator of the health of the sector and the progress in market development over time. This includes statistical information on the size of the global fuel cell market including number and capacity of fuel cell systems shipped in a calendar year. For this first edition data to the end of 2019 is presented where possible alongside analysis of key sector developments. Fuel cell system shipments for each calendar year are presented both as numbers of units and total system megawatts. The data are further divided and subdivided by: • Application: Total system shipments are divided into Transport Stationary and Portable applications • Fuel cell type: Numbers are provided for each of the different fuel cell chemistry types • Region of integration: Region where the final manufacturer – usually the system integrator – integrates the fuel cell into the final product • Region of deployment: Region where the final product was shipped to for deployment The data is sourced directly from industry players as well as other relevant sources including press releases associations and other industry bodies.
A Fundamental Viewpoint on the Hydrogen Spillover Phenomenon of Electrocatalytic Hydrogen Evolution
Jun 2021
Publication
Hydrogen spillover phenomenon of metal-supported electrocatalysts can significantly impact their activity in hydrogen evolution reaction (HER). However design of active electrocatalysts faces grand challenges due to the insufficient understandings on how to overcome this thermodynamically and kinetically adverse process. Here we theoretically profile that the interfacial charge accumulation induces by the large work function difference between metal and support (∆Φ) and sequentially strong interfacial proton adsorption construct a high energy barrier for hydrogen transfer. Theoretical simulations and control experiments rationalize that small ∆Φ induces interfacial charge dilution and relocation thereby weakening interfacial proton adsorption and enabling efficient hydrogen spillover for HER. Experimentally a series of Pt alloys-CoP catalysts with tailorable ∆Φ show a strong ∆Φ-dependent HER activity in which PtIr/CoP with the smallest ∆Φ = 0.02 eV delivers the best HER performance. These findings have conclusively identified ∆Φ as the criterion in guiding the design of hydrogen spillover-based binary HER electrocatalysts
Recent Research Progress in Hybrid Photovoltaic–Regenerative Hydrogen Fuel Cell Microgrid Systems
May 2022
Publication
Hybrid photovoltaic–regenerative hydrogen fuel cell (PV-RHFC) microgrid systems are considered to have a high future potential in the effort to increase the renewable energy share in the form of solar PV technology with hydrogen generation storage and reutilization. The current study provides a comprehensive review of the recent research progress of hybrid PV-RHFC microgrid systems to extract conclusions on their characteristics and future prospects. The different components that can be integrated (PV modules electrolyzer and fuel cell stacks energy storage units power electronics and controllers) are analyzed in terms of available technology options. The main modeling and optimization methods and control strategies are discussed. Additionally various application options are provided which differentiate in terms of scale purpose and further integration with other power generating and energy storage technologies. Finally critical analysis and discussion of hybrid PV-RHFC microgrid systems were conducted based on their current status. Overall the commercialization of hybrid PV-RHFC microgrid systems requires a significant drop in the RHFC subsystem capital cost. In addition it will be necessary to produce complete hybrid PV-RHFC microgrid systems with integrated energy management control capabilities to avoid operational issues and ensure flexibility and reliability of the energy flow in relation to supply storage and demand.
A Numerical and Graphical Review of Energy Storage Technologies
Dec 2014
Publication
More effective energy production requires a greater penetration of storage technologies. This paper takes a looks at and compares the landscape of energy storage devices. Solutions across four categories of storage namely: mechanical chemical electromagnetic and thermal storage are compared on the basis of energy/power density specific energy/power efficiency lifespan cycle life self-discharge rates capital energy/power costs scale application technical maturity as well as environmental impact. It’s noted that virtually every storage technology is seeing improvements. This paper provides an overview of some of the problems with existing storage systems and identifies some key technologies that hold promise.
Risk-adjusted Preferences of Utility Companies and Institutional Investors for Battery Storage and Green Hydrogen Investment
Feb 2022
Publication
Achieving climate-neutrality requires considerable investment in energy storage systems (ESS) to integrate variable renewable energy sources into the grid. However investments into ESS are often unprofitable in particular for grid-scale battery storage and green hydrogen technologies prompting many actors to call for policy intervention. This study investigates investor-specific risk-return preferences for ESS investment and derives policy recommendations. Insights are drawn from 1605 experimental investment-related decisions obtained from 42 high-level institutional investors and utility representatives. Results reveal that both investor groups view revenue stacking as key to making ESS investment viable. While the expected return on investment is the most important project characteristic risk-return preferences for other features diverge between groups. Institutional investors appear more open to exploring new technological ventures (20% of utility respondents would not consider making investments into solar photovoltaic-hydrogen) whereas utilities seem to prefer greenfield projects (23% of surveyed institutional investors rejected such projects). Interestingly both groups show strong aversion towards energy market price risk. Institutional investors require a premium of 6.87 percentage points and utilities 5.54 percentage points for moving from a position of fully hedged against market price risk to a scenario where only 20% of revenue is fixed underlining the need for policy support.
Calibration of Hydrogen Coriolis Flow Meters Using Nitrogen and Air and Investigation of the Influence of Temperature on Measurement Accuracy
Feb 2021
Publication
The performance of four Coriolis flow meters designed for use in hydrogen refuelling stations was evaluated with air and nitrogen by three members of the MetroHyVe JRP consortium; NEL METAS and CESAME EXADEBIT.<br/>A wide range of conditions were tested overall with gas flow rates ranging from (0.05–2) kg/min and pressures ranging from (20–86) bar. The majority of tests were conducted at nominal pressures of either 20 bar or 40 bar in order to match the density of hydrogen at 350 bar and 20 °C or 700 bar and −40 °C. For the conditions tested pressure did not have a noticeable influence on meter performance.<br/>When the flow meters were operated at ambient temperatures and within the manufacturer's recommended flow rate ranges errors were generally within ±1%. Errors within ±0.5% were achievable for the medium to high flow rates.<br/>The influence of temperature on meter performance was also studied with testing under both stable and transient conditions and temperatures as low as −40 °C.<br/>When the tested flow meters were allowed sufficient time to reach thermal equilibrium with the incoming gas temperature effects were limited. The magnitude and spread of errors increased but errors within ±2% were achievable at moderate to high flow rates. Conversely errors as high as 15% were observed in tests where logging began before temperatures stabilised and there was a large difference in temperature between the flow meter and the incoming gas.<br/>One of the flow meters tested with nitrogen was later installed in a hydrogen refuelling station and tested against the METAS Hydrogen Field Test Standard (HFTS). Under these conditions errors ranged from 0.47% to 0.91%. Testing with nitrogen at the same flow rates yielded errors of −0.61% to −0.82%.
High Performance of Biohydrogen Production in Packed-Filter Bioreactor via Optimizing Packed-Filter Position
Jul 2021
Publication
In this present investigation a packed-filter bioreactor was employed to produce hydrogen utilizing an expired soft drink as a substrate. The effects of feeding substrate concentrations ranging from 19.51 10.19 5.34 3.48 to 2.51 g total sugar/L were examined and the position of the packed filter installed in the bioreactor at dimensionless heights (h/H) of 1/4 2/4 3/4 and 4/4 was studied. The results revealed that with a substrate concentration of 20 g total sugar/L and a hydraulic retention time (HRT) of 1 h a packed filter placed at the half-height position of the bioreactor (h/H 2/4) has the optimal hydrogen production rate hydrogen yield and average biomass concentration in the bioreactor resulting in 55.70 ± 2.42 L/L/d 0.90 ± 0.06 mol H2/mol hexose and 17.86 ± 1.09 g VSS/L. When feeding substrate concentrations varied from 20 10 to 5 g total sugar/L with the packed-filter position at h/H 2/4 Clostridium sp. Clostridium tyrobutyricum and Bifidobacterium crudilactis were the predominant bacteria community. Finally it was discovered that the packed-filter bioreactor can produce stable hydrogen in high-strength organic effluent.
Controlled Biosynthesis of ZnCdS Quantum Dots with Visible-Light-Driven Photocatalytic Hydrogen Production Activity
May 2021
Publication
The development of visible-light-responsive photocatalysts with high efficiency stability and eco-friendly nature is beneficial to the large-scale application of solar hydrogen production. In this work the production of biosynthetic ternary ZnCdS photocatalysts (Eg = 2.35–2.72 eV) by sulfate-reducing bacteria (SRB) under mild conditions was carried out for the first time. The huge amount of biogenic S2− and inherent extracellular proteins (EPs) secreted by SRB are important components of rapid extracellular biosynthesis. The ternary ZnCdS QDs at different molar ratios of Zn2+and Cd2+ from 15:1 to 1:1 were monodisperse spheres with good crystallinity and average crystallite size of 6.12 nm independent of the molar ratio of Cd2+ to Zn2+. All the ZnCdS QDs had remarkable photocatalytic activity and stability for hydrogen evolution under visible light without noble metal cocatalysts. Especially ZnCdS QDs at Zn/Cd = 3:1 showed the highest H2 production activity of 3.752 mmol·h−1·g−1. This excellent performance was due to the high absorption of visible light the high specific surface area and the lower recombination rate between photoexcited electrons and holes. The adhered inherent EPs on the ZnCdS QDs slowed down the photocorrosion and improved the stability in photocatalytic hydrogen evolution. This study provides a new direction for solar hydrogen production.
Renewable Hydrogen Potential for Low-carbon Retrofit of the Building Stocks
Dec 2015
Publication
Energy-related GHG emissions mainly from fossil fuels combustion account for around 70% of total emissions. Those emissions are the target of the recent sustainability policies. Indeed renewables exploitation is considered widely the weapon to deal with this challenge thanks to their carbon neutrality. But the biggest drawback is represented by the mismatching between their production and users consumption. The storage would be a possible solution but its viability consists of economic sustainability and energy process efficiency as well. The cutting edge technologies of batteries have not still solved these issues at the same time. So a paradigm shift towards the identification of an energy carrier as storage option the so called Power-to-Gas could be the viable solution. From viability to feasibility a mandatory step is required: the opportunity to integrate the new solution in the proven infrastructures system. Thus the recent studies on Hydrogen (H2) enrichment in Natural Gas demonstrating a lower environmental impact and an increase in energy performance are the base to build the hydrogen transition in the urban environment. The aim of this paper is to evaluate the environmental benefits at building and district scale.
Life Cycle Assessment of Hydrogen from Proton Exchange Membrane Water Electrolysis in Future Energy Systems
Jan 2019
Publication
This study discusses the potential of H2 production by proton exchange membrane water electrolysis as an effective option to reduce greenhouse gas emissions in the hydrogen sector. To address this topic a life cycle assessment is conducted to compare proton exchange membrane water electrolysis versus the reference process - steam methane reforming. As a relevant result we show that hydrogen production via proton exchange membrane water electrolysis is a promising technology to reduce CO2 emissions of the hydrogen sector by up to 75% if the electrolysis system runs exclusively on electricity generated from renewable energy sources. In a future (2050) base-load operation mode emissions are comparable to the reference system.
The results for the global warming potential show a strong reduction of greenhouse gas emissions by 2050. The thoroughly and in-depth modelled components of the electrolyser have negligible influence on impact categories; thus emissions are mainly determined by the electricity mix. With 2017 electricity mix of Germany the global warming potential corresponds to 29.5 kg CO2 eq. for each kg of produced hydrogen. Referring to the electricity mix we received from an energy model emissions can be reduced to 11.5 kg CO2 eq. in base-load operation by the year 2050. Using only the 3000 h of excess power from renewables in a year will allow for the reduction of the global warming potential to 3.3 kg CO2 eq. From this result we see that an environmentally friendly electricity mix is crucial for reducing the global warming impact of electrolytic hydrogen.
The results for the global warming potential show a strong reduction of greenhouse gas emissions by 2050. The thoroughly and in-depth modelled components of the electrolyser have negligible influence on impact categories; thus emissions are mainly determined by the electricity mix. With 2017 electricity mix of Germany the global warming potential corresponds to 29.5 kg CO2 eq. for each kg of produced hydrogen. Referring to the electricity mix we received from an energy model emissions can be reduced to 11.5 kg CO2 eq. in base-load operation by the year 2050. Using only the 3000 h of excess power from renewables in a year will allow for the reduction of the global warming potential to 3.3 kg CO2 eq. From this result we see that an environmentally friendly electricity mix is crucial for reducing the global warming impact of electrolytic hydrogen.
A Review on Recent Advances in Hydrogen Energy, Fuel Cell, Biofuel and Fuel Refining via Ultrasound Process Intensification
Mar 2021
Publication
Hydrogen energy is one of the most suitable green substitutes for harmful fossil fuels and has been investigated widely. This review extensively compiles and compares various methodologies used in the production storage and usage of hydrogen. Sonochemistry is an emerging synthesis process and intensification technique adapted for the synthesis of novel materials. It manifests acoustic cavitation phenomena caused by ultrasound where higher rates of reactions occur locally. The review discusses the effectiveness of sonochemical routes in developing fuel cell catalysts fuel refining biofuel production chemical processes for hydrogen production and the physical chemical and electrochemical hydrogen storage techniques. The operational parameters and environmental conditions used during ultrasonication also influence the production rates which have been elucidated in detail. Hence this review's major focus addresses sonochemical methods that can contribute to the technical challenges involved in hydrogen usage for energy.
Hydrogen Fuel Cell Aircraft for the Nordic Market
Mar 2024
Publication
A model for a fuel cell propelled 50 PAX hydrogen aircraft is developed. In terms of year 2045 Nordic air travel demand this aircraft is expected to cover 97% of travel distances and 58% of daily passenger volume. Using an ATR 42 as a baseline cryogenic tanks and fuel cell stacks are sized and propulsion system masses updated. Fuselage and wing resizing are required which increases mass and wetted area. Sizing methods for the multi-stack fuel cell and the cryogenic tanks are implemented. The dynamic aircraft model is updated with models for hydrogen consumption and tank pressure control. For the Multi-layer insulation (MLI) tank a trade study is performed. A ventilation pressure of 1.76 bar and 15 MLI layers are found to be optimal for the design mission. A return-without-refuel mission is explored where for a 10-hour ground hold 38.4% of the design range is retained out of the theoretically achievable 50%.
Fuel Cell Electric Vehicle (FCEV) Energy Flow Analysis in Real Driving Conditions (RDC)
Aug 2021
Publication
The search for fossil fuels substitutes forces the use of new propulsion technologies applied to means of transportation. Already widespread hybrid vehicles are beginning to share the market with hydrogen-powered propulsion systems. These systems are fuel cells or internal combustion engines powered by hydrogen fuel. In this context road tests of a hydrogen fuel cell drive were conducted under typical traffic conditions according to the requirements of the RDE test. As a result of the carried-out work energy flow conditions were presented for three driving phases (urban rural and motorway). The different contributions to the vehicle propulsion of the hydrogen system and the electric system in each phase of the driving route are indicated. The characteristic interaction of power train components during varying driving conditions was presented. A wide variation in the contribution of the fuel cell and the battery to the vehicle’s propulsion was identified. In urban conditions the share of the fuel cell in the vehicle’s propulsion is more than three times that contributed by the battery suburban—7 times highway—28 times. In the entire test the ratio of FC/BATT use was more than seven while the energy consumption was more than 22 kWh/100 km. The amounts of battery energy used and recovered were found to be very close to each other under RDE test conditions.
Narratives for Natural Gas in a Decarbonising European Energy Market
Feb 2019
Publication
The advocacy narrative of the European Union gas community which focused on coal to gas switching and backing up renewables has failed to convince governments NGOs and media commentators that it can achieve post-2030 decarbonisation targets. The gas community therefore needs to develop decarbonisation narratives showing how it will develop commercial scale projects for biogas biomethane and hydrogen from power to gas (electrolysis) and reformed methane. COP21 carbon targets require an accelerating decline in EU methane demand starting around 2030. In 2050 the maximum projected availability of renewable gas is equivalent to 25 per cent of current EU gas demand. Maintaining current demand levels will therefore require very substantial volumes of hydrogen from reformed methane with carbon capture and storage (CCS). Pipeline gas and LNG suppliers will need to progressively decarbonise their product if it is to remain saleable in Europe. However networks face an existential threat unless they can maintain existing throughput while simultaneously adapting to a decarbonised product. Significant threats and challenges to these narratives include: short term geopolitical concerns stemming from dependence on Russian gas ‘hydrocarbon rejectionism’ and an inability of companies to invest for a post-2030 decarbonised future. Governments will need to shift current policy and regulatory frameworks from competition to decarbonisation which will require a ‘regulatory revolution’. In addition to government funding and regulatory support there will need to be very substantial corporate investment in projects for which there is currently no business case. Failure of the gas community to create and deliver credible decarbonisation narratives is likely to result in the adoption of electrification rather than gas decarbonisation options.
Research on Carbide Characteristics and Their Influence on the Properties of Welding Joints for 2.25Cr1Mo0.25V Steel
Feb 2021
Publication
The carbide characteristics of 2.25Cr1Mo0.25V steel have an extremely important influence on the mechanical properties of welding joints. In addition hydrogen resistance behavior is crucial for steel applied in hydrogenation reactors. The carbide morphology was observed by scanning electron microscopy (SEM) and the carbide microstructure was characterized by transmission electron microscopy (TEM). Tensile and impact tests were carried out and the influence of carbides on properties was studied. A hydrogen diffusion test was carried out and the hydrogen brittleness resistance of welding metal and base metal was studied by tensile testing of hydrogenated samples to evaluate the influence of hydrogen on the mechanical properties. The research results show that the strength of the welding metal was slightly higher and the Charpy impact value was significantly lower compared to the base metal. The hydrogen embrittlement resistance of the welding metal was stronger than that of the base metal. The presence of more carbides and inclusions was the main cause of the decreased impact property and hydrogen brittleness resistance of the welding metal. These conclusions have certain reference value for designing and manufacturing hydrogenation reactors. View Full-Text
Advancing Hydrogen: Learning from 19 Plans to Advance Hydrogen from Across the Globe
Jul 2019
Publication
Hydrogen as the International Energy Agency (IEA 2019) notes has experienced a number of ‘false dawns’ - in the 1970s 1990s and early 2000s - which subsequently faded. However this time there is reason to think that hydrogen will play a substantial role in the global energy system. The most important factor driving this renewed focus is the ability of hydrogen to support deep carbon abatement by assisting in those sectors where abatement with non-carbon electricity has so far proven difficult. Hydrogen can also address poor urban air quality energy security and provides a good means of shifting energy supply between regions and between seasons.
In response to these changed conditions many countries states and even cities have developed hydrogen strategies while various interest groups have developed industry roadmaps which fulfil a similar role.
This report summarises 19 hydrogen strategies and aims to help readers understand how nations regions and industries are thinking about opportunities to become involved in this emerging industry. Its prime purpose is to act as a resource to assist those involved in long-term energy policy planning in Australia including those involved in the development of Australia’s hydrogen strategy
The full report can be read on the Energy Network website at this link here
In response to these changed conditions many countries states and even cities have developed hydrogen strategies while various interest groups have developed industry roadmaps which fulfil a similar role.
This report summarises 19 hydrogen strategies and aims to help readers understand how nations regions and industries are thinking about opportunities to become involved in this emerging industry. Its prime purpose is to act as a resource to assist those involved in long-term energy policy planning in Australia including those involved in the development of Australia’s hydrogen strategy
The full report can be read on the Energy Network website at this link here
Challenges to the Future of LNG: Decarbonisation, Affordability, and Profitability
Oct 2019
Publication
Decarbonisation should be very much on the radar of new LNG projects currently taking FID commissioning around 2024-25 and planning to operate up to 2050. The LNG community needs to replace an `advocacy’ message – based on the generality of emissions from combustion of natural gas being lower than from other fossil fuels – with certified data on carbon and methane emissions from specific elements of the value chain for individual projects. As carbon reduction targets tighten over the coming decade LNG cargoes which do not have value chain emissions certified by accredited authorities or which fail to meet defined emission levels run the risk of progressively being deemed to have a lower commercial value and eventually being excluded from jurisdictions with the strictest standards. There will be no place in this process for confidentiality; nothing less than complete transparency of data and methodologies will be acceptable.<br/>In relation to affordability prospects for new projects look much better than they did three years ago. Cost estimates for most new projects suggest that they will be able to deliver profitably to most established and anticipated import markets at or below the wholesale prices prevailing in those markets over the past decade although affordability in south Asian countries may be challenging. But new projects need to factor in costs related to future decarbonisation requirements in both exporting and importing countries. To the extent that LNG suppliers can meet standards through relatively low-cost offsets – forest projects low-cost biogas and biomethane – this may not greatly impact their commercial viability. However any requirement to transform methane into hydrogen with CCS in either the exporting or importing country would substantially impact project economics and the affordability of LNG relative to other energy choices.
A Mountain to Climb? Tracking Progress in Scaling Up Renewable Gas Production in Europe
Oct 2019
Publication
In the last couple of years there has been increasing recognition by key players in the European gas industry that to mitigate the risk of terminal decline in the context of a decarbonising energy system there will need to be rapid scale up of decarbonised gas. This has led to several projections of the scale of decarbonised gas which could potentially be supplied by 2030 2040 or 2050. This paper joint with the Sustainable Gas Institute at Imperial College London considers the very significant rate of scale up and the significant cost reductions contemplated by such projections. Based on a database of actual announced projects (both committed and in earlier stages of development) for production of decarbonised gas it then considers the extent to which project activity is consistent with meeting the ambitious projections. It identifies a significant gap in current levels of activity largely because there is not yet sufficient economic incentive for investors to develop the required projects. It is intended that this paper will form the basis of continued tracking of the level of activity over the coming years to help inform industry players of further actions which may be required.
No more items...