Publications
Hydrogen-Based Energy Systems: Current Technology Development Status, Opportunities and Challenges
Dec 2023
Publication
The use of hydrogen as an energy carrier within the scope of the decarbonisation of the world’s energy production and utilisation is seen by many as an integral part of this endeavour. However the discussion around hydrogen technologies often lacks some perspective on the currently available technologies their Technology Readiness Level (TRL) scope of application and important performance parameters such as energy density or conversion efficiency. This makes it difficult for the policy makers and investors to evaluate the technologies that are most promising. The present study aims to provide help in this respect by assessing the available technologies in which hydrogen is used as an energy carrier including its main challenges needs and opportunities in a scenario in which fossil fuels still dominate global energy sources but in which renewables are expected to assume a progressively vital role in the future. The production of green hydrogen using water electrolysis technologies is described in detail. Various methods of hydrogen storage are referred including underground storage physical storage and material-based storage. Hydrogen transportation technologies are examined taking into account different storage methods volume requirements and transportation distances. Lastly an assessment of well-known technologies for harnessing energy from hydrogen is undertaken including gas turbines reciprocating internal combustion engines and fuel cells. It seems that the many of the technologies assessed have already achieved a satisfactory degree of development such as several solutions for high-pressure hydrogen storage while others still require some maturation such as the still limited life and/or excessive cost of the various fuel cell technologies or the suitable operation of gas turbines and reciprocating internal combustion engines operating with hydrogen. Costs below 200 USD/kWproduced lives above 50 kh and conversion efficiencies approaching 80% are being aimed at green hydrogen production or electricity production from hydrogen fuel cells. Nonetheless notable advances have been achieved in these technologies in recent years. For instance electrolysis with solid oxide cells may now sometimes reach up to 85% efficiency although with a life still in the range of 20 kh. Conversely proton exchange membrane fuel cells (PEMFCs) working as electrolysers are able to sometimes achieve a life in the range of 80 kh with efficiencies up to 68%. Regarding electricity production from hydrogen the maximum efficiencies are slightly lower (72% and 55% respectively). The combination of the energy losses due to hydrogen production compression storage and electricity production yields overall efficiencies that could be as low as 25% although smart applications such as those that can use available process or waste heat could substantially improve the overall energy efficiency figures. Despite the challenges the foreseeable future seems to hold significant potential for hydrogen as a clean energy carrier as the demand for hydrogen continues to grow particularly in transportation building heating and power generation new business prospects emerge. However this should be done with careful regard to the fact that many of these technologies still need to increase their technological readiness level before they become viable options. For this an emphasis needs to be put on research innovation and collaboration among industry academia and policymakers to unlock the full potential of hydrogen as an energy vector in the sustainable economy.
OIES Podcast - Key Energy Themes for 2024
Jan 2024
Publication
In this latest OIES podcast James Henderson talks to Bill Farren-Price the new Head of the Gas Programme about some of Key Themes identified by OIES research fellows for 2024. After a review of the outcomes from 2023 we look at the oil and gas markets and discuss a common theme around the contrast between the fundamental tightness in both markets compared with the relative softness of prices. We then move onto a number of energy transition issues starting with some of the key actions from COP28 that need to be implemented in 2024 and following with a review of the outlook for carbon markets hydrogen developments and offshore wind. We also consider the impact of emerging competition between regions over green industrial policy. Finally we consider some of the key geopolitical drivers for 2024 with the influence of China being the most critical. However in an election year for so many countries it will be critical to follow the key policy announcements of the main candidates and of most critically the outcome of the US election in November.
The podcast can be found on their website
The podcast can be found on their website
Component and System Levels Limitations in Power-Hydrogen Systems: Analytical Review
Jun 2024
Publication
This study identifies limitations and research and development (R&D) gaps at both the component and system levels for hydrogen energy systems (HESs) and specifies how these limitations impact HES adoption within the electric power system (EPS) decarbonization roadmap. To trace these limitations and potential solutions an analytical review is conducted in electrification and integration of HESs renewable energy sources (RESs) and multi-carrier energy systems (MCESs) in sequence. The study also innovatively categorizes HES integration challenges into component and system levels. At the component level technological aspects of hydrogen generation storage transportation and refueling are explored. At the system level HES coordination hydrogen market frameworks and adoption challenges are evaluated. Findings highlight R&D gaps including misalignment between HES operational targets and techno-economic development integration insufficiency model deficiencies and challenges in operational complexity. This study provides insights for sustainable energy integration by supporting the transition to a decarbonized energy system.
Thermo-economic Analysis of Green Hydrogen Production Onboard LNG Carriers through Solid Oxide Electrolysis Powered by Organic Rankine Cycles
Nov 2024
Publication
LNG carriers play a crucial role in the shipping industry meeting the global demand for natural gas (NG). However the energy losses resulting from the propulsion system and the excess boil-off gas (BOG) cannot be overlooked. The present article investigates the H2 production on board LNG carriers employing both the engine's waste heat (WH) and the excess BOG. Conventional (ORC) and dual-pressure (2P-ORC) organic Rankine cycles coupled separately with a solid oxide electrolysis (SOEC) have been simulated and compared. The hydrogen (H2) produced is then compressed at 150 bar for subsequent use as required. According to the results the 2P-ORC generates 14.79 % more power compared to ORC allowing for an increased energy supply to the SOEC; hence producing more H2 (34.47 kg/h compared to 31.14 kg/h). Including the 2P-ORC in the H2 production plant results in a cheaper H2 cost by 0.04 $/kgH2 compared to ORC a 1.13 %LHV higher system efficiency when leveraging all the available waste heat. The plant including 2P-ORC exploits more than 86 % of the of the available waste compared to 70 % when using ORC. Excluding the compression system decreases the capital cost by almost the half regardless of the WH recovery system used yet it plays in favour of the plant with ORC making the cost of H2 cheaper by 0.29 $/kgH2 in this case. Onboard H2 production is a versatile process independent from the propulsion system ensuring the ship's safety and availability throughout a sea journey.
Hazard Identification of Hydrogen-Based Alternative Fuels Onboard Ships
Dec 2023
Publication
It is essential to use alternative fuels if we are to reach the emission reduction targets set by the IMO. Hydrogen carriers are classified as zero-emission while having a higher energy density (including packing factor) than pure hydrogen. They are often considered as safe alternative fuels. The exact definition of what safety entails is often lacking both for hydrogen carriers as well as for ship safety. The aim of this study is to review the safety of hydrogen carriers from two perspectives investigating potential connections between the chemical and maritime approaches to safety. This enables a reasoned consideration between safety aspects and other design drivers in ship design and operation. The hydrogen carriers AB NaBH4 KBH4 and two LOHCs (NEC and DBT) are taken into consideration together with a couple reference fuels (ammonia methanol and MDO). After the evaluation of chemical properties related to safety and the scope of the current IMO safety framework it can be concluded that safety remains a vague and non-explicit concept from both perspectives. Therefore further research is required to prove the safe application of hydrogen carriers onboard ships.
Integration of Hydrogen Compressors and Turbines into Current and Future Hydrogen Infrastructure
Dec 2024
Publication
Fuel cell-based systems are emerging as the future focus for global adaptation and hydrogen compressors and turbines as economically critical versions are at the technological edge of product development of hydrogen-based energy systems in sustainable energy initiatives. As a novelty the paper deals with the issues behind implementing hydrogen machinery technologies to bring about a resilient hydrogen infrastructure also powered by fuel cells and it aims at strengthening the argument for evolving policies and comprehensive approaches that can cope with the technical infrastructural and market-related hurdles.<br/>More specifically the present paper analyzes several hydrogen compressor technologies with their unique advantages and disadvantages. Among them centrifugal compressors are seen to become their most efficient on the large-scale manufacture of hydrogen and allow compression ratios up to 30:1 with isentropic efficiencies between 70 and 90 %. On the other hand electrochemical hydrogen compressors exhibit operation with no vibration reduced noise and level of hydrogen purification among others and offer a plus in a module with lower energy consumption up to half value compared to mechanical compressors. Meanwhile hydrogen turbines are evolving to accommodate hydrogen mixes with the current technological activity in the turbine sector allowing for a blend of 30 % hydrogen and 70 % methane. In comparison prototypes have been already tested using 100 % hydrogen. Within this context this paper describes ongoing work related to efficiency improvements and cost reduction of hydrogen machinery.
Decarbonizing the Future for the Transportation and Aviation Industries: Green Hydrogen as the Sustainable Fuel Solution
Jun 2025
Publication
The pressure to move to sustainable energy sources is obvious in today's fast changing energy environment. In this context green hydrogen appears as a beacon of hope with the potential to reinvent the paradigms of energy consumption particularly in the transportation and aviation sectors. Hydrogen has long been intriguing owing to its unique characteristics. It is not only an energy transporter; it has the power to alter the game. Its growing significance is due to its capacity to decarbonize energy generation. Traditional hydrogen generation techniques have contributed considerably to world CO2 emissions accounting for over 2% of total emissions. This environmental problem is successfully addressed by the development of green hydrogen which is created from renewable energy sources. The International Energy Agency (IEA) predicts a 25 to 30 percent increase in global energy consumption by 2040 which is a very grim scenario. If continue to rely on coal and oil this growing demand will result in greater CO2 emissions exacerbating climate change's consequences. In this situation green hydrogen is not only an option but a need. Because green hydrogen has properties with conventional fuels it can be simply integrated into current infrastructure. This harmonic integration ensures that the shift to hydrogen-based solutions in these sectors would not demand a complete redesign of the present systems assuring cost-effectiveness and practicality. However like with any energy source green hydrogen has obstacles. Its combustibility and probable explosiveness have been cited as causes for concern. However developments in safety measures have successfully mitigated these dangers ensuring that hydrogen may be used safely and efficiently across various applications. A further difficulty is its energy density particularly in comparison to conventional fuels. While its energy-to-weight ratio may be good its bulk poses challenges particularly in the aviation industry where space is at a premium. Beyond its direct use as a fuel green hydrogen has potential in auxiliary capacities. It may be used as a dependable backup energy source during power outages as well as in a variety of different sectors and uses ranging from manufacturing to residential. Green hydrogen's adaptability demonstrates its potential to infiltrate all sectors of our economy. Storage is an important enabler for broad hydrogen use. Effective hydrogen storage technologies guarantee not only its availability but also its viability as a source of energy. Current research and advancements in this field are encouraging which strengthens the argument for green hydrogen. At conclusion green hydrogen is in the vanguard of sustainable energy solutions particularly for the transportation and aviation industries. In our collaborative quest of a sustainable future its unique features and environmental advantages make it a vital asset. As we explore further into the complexities of green hydrogen in this publication we want to shed light on its potential obstacles and future route.
Multilateral Governance in a Global Hydrogen Economy: An Overview of Main Actors and Institutions, Key Challenges and Future Pathways
Nov 2024
Publication
This paper explores the current scope and direction of the emerging global governance of hydrogen within the broader context of the energy transition where technological innovation and institutional change intersect. Hydrogen as a critical yet complex energy vector requires coordinated governance efforts to navigate its development effectively. To this end we critically engage with key challenges facing the hydrogen sector and examine how institutional frameworks are addressing these issues. Departing from the broader scholarship on global energy governance we conceptually leverage the socio-technical transition and innovation system liter ature to understand the complexities underpinning the development of the global hydrogen economy. We identify three overarching issue areas pertaining to the nature and role of hydrogen in the global energy system: end-use sector development infrastructure and trade and environmental and socio-economic sustainability. Each of these areas presents distinct challenges to hydrogen’s global governance from stimulating supply and demand to managing geo-economic challenges and establishing comprehensive certification and standards. Through mapping multilateral institutions at the global and regional levels and their main objectives we offer insights into the emerging institutional architecture related to hydrogen and identify potential gaps in current governance. Our findings suggest that while newer hydrogen-specific institutions complement the broader agenda of the main established international organizations the overall global hydrogen structure remains a patchwork of diverse actors and frameworks each addressing hydrogen-related challenges to varying degrees. Our research contributes to a nuanced understanding of global governance in the hydrogen sector and advances scholarly discussions on how institutional and actor dynamics shape the emergence and development of new technologies.
Stability, Change, Formation: Insights into the Media's Role in Shaping Attitudes Toward Green Hydrogen in Germany
Nov 2024
Publication
This study uses a multi-method design to investigate the media’s role in shaping Germans’ attitudes toward green hydrogen. It combines an automatized content analysis of 7649 German newspaper articles published between July 2021 and June 2024 and a three-wave panel survey of the German population conducted between June 2023 and June 2024 with an initial sample of 2701 participants. The findings show that the intensity of media reporting on hydrogen was low compared to other energy-related topics. Nevertheless participants’ assessments of relative topic presence are rather accurate (rho: 0.50–0.80). A considerable number of participants were unable to position themselves toward the potential and challenges of hydrogen (23%–35%). Overall the results indicate that media and communication tend to stabilize or change existing attitudes rather than contribute to the formation or loss of attitudes leading to implications for the communication of relevant stakeholders.
Hydrogen Import and Export: Unlocking the UK's Hydrogen Trade Potential
May 2024
Publication
Hydrogen trade is an emerging area of interest for hydrogen developers end-users traders and governments around the world. It can enhance system flexibility energy security and clean growth enabling decarbonisation at a lower cost and faster pace. Thanks to its competitive advantage in existing ports terminals and interconnectors the UK is well placed to be the European trade hub for hydrogen and its carriers. With its access to world leading offshore wind generation capacity and geological storage the UK will almost certainly be a net exporter of hydrogen in the future delivering economic value and creating jobs. However hydrogen trade will not be a one-way process. In order to best position the UK as a future hydrogen trade hub there could be value in investing in small scale hydrogen imports and exports to ‘wet the pipes’ and stimulate investment in infrastructure. Imports could also enhance our energy security as a part of a diverse energy mix and support demand whilst domestic production gets up to speed. Both imports and exports will be key to build supply chains and skills and enhance clean growth. With major European economies having established their hydrogen trade strategy there is growing uncertainty as to how the United Kingdom will capitalise on its competitive advantage and position itself in the global hydrogen market. This is the first qualitative report released by Hydrogen UK’s Import and Export Taskforce. This report aims to provide a high-level overview of Hydrogen UK’s vision and recommendations with subsequent reports exploring this topic in further detail.
This report can be found on Hydrogen UK's website.
This report can be found on Hydrogen UK's website.
Comparative Techno-Economic Analysis of Gray Hydrogen Production Costs: A Case Study
Jan 2025
Publication
Despite Iran’s considerable renewable energy (RE) potential and excellent wind capacity and high solar radiation levels these sources contribute only a small fraction of the country’s total energy production. This paper addresses the techno-economic viability of gray hydrogen production by these renewables with a particular focus on solar energy. Given the considerable potential of solar energy and the strategic location of Shahrekord it would be an optimal site for a hydrogen generation plant integrated with a solar field. HOMER Pro 3.18.3 software was utilized to model and optimize the levelized cost of hydrogen (LCOH) of steam reforming using different hydrocarbons in various scenarios. The results of this study indicate that natural gas (NG) reforming represents the most cost-effective method of gray hydrogen production in this city with an LCOH of −0.423 USD/kg. Other hydrocarbons such as diesel gasoline propane methanol and ethanol have a price per kilogram of produced hydrogen as follows: USD −0.4 USD −0.293 USD 1.17 USD 1.48 and USD 2.15. In addition integrating RE sources into hydrogen production was found to be viable. Moreover by implementing RE technologies CO2 emissions can be significantly reduced and energy security can be achieved.
The Impact of Hydrogen on Decarbonisation and Resilience in Integrated Energy Systems
Nov 2024
Publication
The lack of clarity and uncertainty about hydrogen’s role demand applications and economics has been a barrier to the development of the hydrogen economy. In this paper an optimisation model for the integrated planning and operation of hydrogen and electricity systems is presented to identify the role of hydrogen technologies and linepack in decarbonising energy systems improving system flexibility and enhancing energy system security and resilience against extreme weather events. The studies are conducted on Great Britain’s (GB) 2050 net-zero electricity and gas transmission systems to analyse the hydrogen transport and capacity requirements within the existing infrastructure under different scenarios. This includes sensitivities on the level of flexibility high gas prices hydrogen production mixes enabled reversibility of electrolysers electricity generation cost and hydrogen storage facilities. In all sensitivity scenarios efficient hydrogen transport within the existing infrastructure is enabled by the optimal allocation of green and blue hydrogen sources distributed storage facilities and the intra-day flexibility provided by linepack. The findings highlight that increased renewable deployment transfers intermittency to the hydrogen network requiring greater linepack flexibility compared to the current paradigm (up to 83%). Furthermore the necessity of synergy between different gas and electricity systems components in providing flexibility security and resilience is quantified.
UK Hydrogen Roadmap: Financial and Strategic Insights into Oil and Gas Industry’s Transition
Dec 2024
Publication
Inspired by the announcement of the new Hydrogen Strategy for the UK in 2021 this study aimed to determine how the oil and gas industry responds and adapts to the changes. This paper analyses qualitative and quantitative data from the companies’ annual and energy reports. Four oil and gas companies involved in hydrogen projects in the UK were selected as case studies. The responses from the companies were collected using the content analysis research strategy in 2019–2021. A steady increase was observed based on the code frequency reflecting the increasing discussions and actions the companies took regarding this hydrogen pathway. Although only one company appears to be at the forefront of this transition progress with a score of almost 90% based on the strategy management analysis other companies continue to demonstrate their commitment to supporting the national target.
An Experimental Investigation of Hydrogen Production through Biomass Electrolysis
Jan 2024
Publication
This work investigated hydrogen production from biomass feedstocks (i.e. glucose starch lignin and cellulose) using a 100 mL h-type proton exchange membrane electrolysis cell. Biomass electrolysis is a promising process for hydrogen production although low in technology readiness level but with a series of recognised advantages: (i) lower-temperature conditions (compared to thermochemical processes) (ii) minimal energy consumption and low-cost post-production (iii) potential to synthesise high-volume H2 and (iv) smaller carbon footprint compared to thermochemical processes. A Lewis acid (FeCl3 ) was employed as a charge carrier and redox medium to aid in the depolymerisation/oxidation of biomass components. A comprehensive analysis was conducted measuring the H2 and CO2 emission volume and performing electrochemical analysis (i.e. linear sweep voltammetry and chronoamperometry) to better understand the process. For the first time the influence of temperature on current density and H2 evolution was studied at temperatures ranging from ambient temperature (i.e. 19 ◦C) to 80 ◦C. The highest H2 volume was 12.1 mL which was produced by FeCl3 -mediated electrolysis of glucose at ambient temperature which was up to two times higher than starch lignin and cellulose at 1.20 V. Of the substrates examined glucose also showed a maximum power-to-H2 -yield ratio of 30.99 kWh/kg. The results showed that hydrogen can be produced from biomass feedstock at ambient temperature when a Lewis acid (FeCl3 ) is employed and with a higher yield rate and a lower electricity consumption compared to water electrolysis.
Optimization of the Joint Operation of an Electricity–Heat– Hydrogen–Gas Multi-Energy System Containing Hybrid Energy Storage and Power-to-Gas–Combined Heat and Power
Jun 2024
Publication
With the continuous development of hydrogen storage systems power-to-gas (P2G) and combined heat and power (CHP) the coupling between electricity–heat–hydrogen–gas has been promoted and energy conversion equipment has been transformed from an independent operation with low energy utilization efficiency to a joint operation with high efficiency. This study proposes a low-carbon optimization strategy for a multi-energy coupled IES containing hydrogen energy storage operating jointly with a two-stage P2G adjustable thermoelectric ratio CHP. Firstly the hydrogen energy storage system is analyzed to enhance the wind power consumption ability of the system by dynamically absorbing and releasing energy at the right time through electricity–hydrogen coupling. Then the two-stage P2G operation process is refined and combined with the CHP operation with an adjustable thermoelectric ratio to further improve the low-carbon and economic performance of the system. Finally multiple scenarios are set up and the comparative analysis shows that the addition of a hydrogen storage system can increase the wind power consumption capacity of the system by 4.6%; considering the adjustable thermoelectric ratio CHP and the twostage P2G the system emissions reduction can be 5.97% and 23.07% respectively and the total cost of operation can be reduced by 7.5% and 14.5% respectively.
Thermodynamic and Techno-Economic Performance Comparison of Methanol Aqueous Phase Reforming and Steam Reforming for Hydrogen Production
Dec 2024
Publication
Methanol which can be derived from sustainable energy sources such as biomass solar power and wind power is widely considered an ideal hydrogen carrier for distributed and mobile hydrogen production. In this study a comprehensive comparison of the thermodynamic and techno-economic performance of the aqueous phase reforming (APR) and steam reforming (SR) of methanol was conducted using Aspen Plus and CAPCOST software to evaluate the commercial feasibility of the APR process. Thermodynamic analysis based on the Gibbs free energy minimization method reveals that while APR and SR have similar energy demands APR achieves higher energy efficiency by avoiding losses from evaporation and compression. APR typically operates at higher pressures and lower temperatures compared to SR suppressing CO formation and increasing hydrogen fraction but reducing methanol single-pass conversion. A techno-economic comparison of APR and SR for a distributed hydrogen production system with a 50 kg/h hydrogen output shows that although APR requires higher fixed operating costs and annual capital charges it benefits from lower variable operating costs. The minimum hydrogen selling price for APR was calculated to be 7.07 USD/kg compared to 7.20 USD/kg for SR. These results suggest that APR is a more economically viable alternative to SR for hydrogen production.
Numerical Simulation and Field Experimental Study of Combustion Characteristics of Hydrogen-Enriched Natural Gas
Jun 2024
Publication
For the safe and efficient utilization of hydrogen-enriched natural gas combustion in industrial gas-fired boilers the present study adopted a combination of numerical simulation and field tests to investigate its adaptability. Firstly the combustion characteristics of hydrogen-enriched natural gas with different hydrogen blending ratios and equivalence ratios were evaluated by using the Chemkin Pro platform. Secondly a field experimental study was carried out based on the WNS2- 1.25-Q gas-fired boiler to investigate the boiler’s thermal efficiency heat loss and pollutant emissions after hydrogen addition. The results show that at the same equivalence ratio with the hydrogen blending ratio increasing from 0% to 25% the laminar flame propagation speed of the fuel increases the extinction strain rate rises and the combustion limit expands. The laminar flame propagation speed of premixed methane/air gas reaches the maximum value when the equivalence ratio is 1.0 and the combustion intensity of the flame is the highest at this time. In the field tests as the hydrogen blending ratio increases from 0% to nearly 10% with the increasing excess air ratio the boiler’s thermal efficiency decreases as well as the NOx emission. This indicates that there exists a tradeoff between the boiler thermal efficiency and NOx emission in practice.
Sustainable E-Fuels: Green Hydrogen, Methanol and Ammonia for Carbon-Neutral Transportation
Dec 2023
Publication
Increasingly stringent sustainability and decarbonization objectives drive investments in adopting environmentally friendly low and zero-carbon fuels. This study presents a comparative framework of green hydrogen green ammonia and green methanol production and application in a clear context. By harnessing publicly available data sources including from the literature this research delves into the evaluation of green fuels. Building on these insights this study outlines the production process application and strategic pathways to transition into a greener economy by 2050. This envisioned transformation unfolds in three progressive steps: the utilization of green hydrogen green ammonia and green methanol as a sustainable fuel source for transport applications; the integration of these green fuels in industries; and the establishment of mechanisms for achieving the net zero. However this research also reveals the formidable challenges of producing green hydrogen green ammonia and green methanol. These challenges encompass technological intricacies economic barriers societal considerations and far-reaching policy implications necessitating collaborative efforts and innovative solutions to successfully develop and deploy green hydrogen green ammonia and green methanol. The findings unequivocally demonstrate that renewable energy sources play a pivotal role in enabling the production of these green fuels positioning the global transition in the landscape of sustainable energy.
Impact of Large-scale Hydrogen Electrification and Retrofitting of Natural Gas Infrastructure on the European Power System
Nov 2023
Publication
In this paper we aim to analyse the impact of hydrogen production decarbonisation and electrification scenarios on the infrastructure development generation mix CO2 emissions and system costs of the European power system considering the retrofit of the natural gas infrastructure. We define a reference scenario for the European power system in 2050 and use scenario variants to obtain additional insights by breaking down the effects of different assumptions. The scenarios were analysed using the European electricity market model COMPETES including a proposed formulation to consider retrofitting existing natural gas networks to transport hydrogen instead of methane. According to the results 60% of the EU’s hydrogen demand is electrified and approximately 30% of the total electricity demand will be to cover that hydrogen demand. The primary source of this electricity would be non-polluting technologies. Moreover hydrogen flexibility significantly increases variable renewable energy investment and production and reduces CO2 emissions. In contrast relying on only electricity transmission increases costs and CO2 emissions emphasising the importance of investing in an H2 network through retrofitting or new pipelines. In conclusion this paper shows that electrifying hydrogen is necessary and cost-effective to achieve the EU’s objective of reducing long-term emissions.
Liquid Hydrogen Pool Evaporation Above Four Different Substrates
Sep 2023
Publication
In the frame of the EC-funded project PRESLHY ten experiments on LH2-pool evaporation above four different substrates have been performed with the POOL-facility on a free field test site. Substrates to be investigated comprised concrete sand water and gravel. Four of the experiments were made with artificial side wind of known direction and known velocity to investigate the influence of side wind on hydrogen evaporation and cloud formation above the LH2-pool. The POOL-facility mainly consists of an insulated stainless-steel box with the dimensions 0.5 x 0.5 x 0.2 m³ that is filled up to half the height (0.1 m) with the respective substrate and LH2. The height of the LH2-pool that forms above the substrate can be determined using the weight of the complete facility which is positioned on a scale. Additionally six thermocouples are located in different heights above the substrate surface to indicate the LH2-level as soon as they are covered with LH2. Further measurement equipment used in the tests comprises temperature measurements inside the substrate and several thermocouples in the unconfined space above the pool where also H2-concentration measurements were performed. Using the sensor information pool evaporation rates for the different substrates were determined. The temperature and concentration measurements above the pool were mainly used to define promising ignition positions for subsequent combustion experiments in which the LH2-spills above the different substrates were ignited.
Numerical Investigations of Hydrogen Release and Dispersion Due to Silane Decomposition in a Ventilated Container
Sep 2023
Publication
In recent years new chemical release agents based on silane are being used in the tire industry. Silane is an inorganic chemical compound consisting of a silicon backbone and hydrogen. Silanes can be thermally decomposed into high-purity silicon and hydrogen. If silane is stored and transported in Intermediate Bulk Containers (IBCs) equipped with safety valves in vented semi-confined spaces such as ISO-Containers hydrogen can be accumulated and become explosive mixture with air. A conservative CFD analysis using the GASFLOW-MPI code has been carried out to assess the hydrogen risk inside the vented containers. Two types of containers with different natural ventilation systems were investigated under various hypothetical accident scenarios. A continuous release of hydrogen due to the chemical decomposition of silane from IBCs was studied as the reference case. The effect of the safety valves on hydrogen accumulation in the container which results in small pulsed releases of hydrogen was investigated. The external effects of the sun and wind on hydrogen distribution and ventilation were also evaluated. The results can provide detailed information on hydrogen dispersion and mixing within the vented enclosures and used to evaluate the hydrogen risks such as flammability. Based on the assumptions used in this study it indicates that the geometry of ventilation openings plays a key role in the efficiency of the indoor air exchange process. In addition the use of safety valves makes it possible to reduce the concentration of hydrogen by volume in air compared to the reference case. The effect of the sun which results in a temperature difference between two container walls allows a strong mixing of hydrogen and air which helps to obtain a concentration lower than both the base case and the case of the pulsed releases. But the best results for the venting process are obtained with the wind that can drive the mixture to the downwind wall vent holes.
A SWOT Analysis of the Green Hydrogen Market
Jun 2024
Publication
Since the Industrial Revolution humanity has heavily depended on fossil fuels. Recognizing the negative environmental impacts of the unmoderated consumption of fossil fuels including global warming and consequent climate change new plans and initiatives have been established to implement renewable and sustainable energy sources worldwide. This has led to a rapid increase in the installed solar and wind energy capacity. However considering the fluctuating nature of these renewable energy sources green hydrogen has been proposed as a suitable energy carrier to improve the efficiency of energy production and storage. Thus green hydrogen produced by water electrolysis using renewable electricity is a promising solution for the future energy market. Moreover it has the potential to be used for the decarbonization of the heavy industry and transportation sectors. Research and development (R&D) on green hydrogen has grown considerably over the past few decades aiming to maximize production and expand its market share. The present work uses a SWOT (strengths weaknesses opportunities and threats) analysis to evaluate the current status of the green hydrogen market. The external and internal factors that affect its market position are assessed. The results show that green hydrogen is on the right track to becoming a competitive alternative to fossil fuels soon. Supported by environmental benefits government incentives and carbon taxes roadmaps to position green hydrogen on the energy map have been outlined. Nevertheless increased investments are required for further R&D as costs must be reduced and policies enforced. These measures will gradually decrease global dependency on fossil fuels and ensure that roadmaps are followed through.
Country Risks Analysis for the Development of Green Hydrogen and Synthetic Fuel Sectors in the MENA Region
Nov 2024
Publication
Hydrogen plays a pivotal role in global efforts to decarbonize energy and industrial sectors. The European Union particularly Germany anticipate a significant reliance on hydrogen imports in the medium to long term identifying the Middle East and North Africa (MENA) region as a key potential producer and exporter of green hydrogen and its downstream products. Yet investment risks pose significant challenges to advancing the region’s green hydrogen and synthetic fuel industries. However systematic comparative risk analyses for these sectors across MENA countries remain limited. This study addresses the research gap by conducting a comparative risk assessment for renewable energy and green hydrogen and synthetic fuel development in 17 MENA countries. A comprehensive framework evaluating macro and micro risks was applied along with two contrasting risk scenarios to explore future developments under different risk conditions. The findings reveal that while MENA countries hold promise most face at least moderate risks underscoring the complexity of fostering these industries regionally.
Cooperative Boron and Vanadium Doping of Nickel Phosphides for Hydrogen Evolution in Alkaline and AnionExchange Membrane Water/Seawater Electrolyzers
Mar 2023
Publication
Developing low-cost and high-performance transition metal-based electro-catalysts is crucial for realizing sustainable hydrogen evolution reaction (HER)in alkaline media. Here a cooperative boron and vanadium co-doped nickelphosphide electrode (B V-Ni2P) is developed to regulate the intrinsic elec-tronic configuration of Ni2P and promote HER processes. Experimental andtheoretical results reveal that V dopants in B V-Ni2P greatly facilitate the dis-sociation of water and the synergistic effect of B and V dopants promotes thesubsequent desorption of the adsorbed hydrogen intermediates. Benefitingfrom the cooperativity of both dopants the B V-Ni2P electrocatalyst requires alow overpotential of 148 mV to attain a current density of −100 mA cm−2 withexcellent durability. The B V-Ni2P is applied as the cathode in both alkalinewater electrolyzers (AWEs) and anion exchange membrane water electrolyzers(AEMWEs). Remarkably the AEMWE delivers a stable performance to achieve500 and 1000 mA cm−2 current densities at a cell voltage of 1.78 and 1.92 Vrespectively. Furthermore the developed AWEs and AEMWEs also demon-strate excellent performance for overall seawater electrolysis.
Seawater Treatment Technologies for Hydrogen Production by Electrolysis—A Review
Dec 2024
Publication
Green hydrogen produced by water electrolysis using renewable energy sources (RES) is an emerging technology that aligns with sustainable development goals and efforts to address climate change. In addition to energy electrolyzers require ultrapure water to operate. Although seawater is abundant on the Earth it must be desalinated and further purified to meet the electrolyzer’s feeding water quality requirements. This paper reviews seawater purification processes for electrolysis. Three mature and commercially available desalination technologies (reverse osmosis multiple-effect distillation and multi-stage flash) were examined in terms of working principles performance parameters produced water quality footprint and capital and operating expenditures. Additionally pretreatment and post-treatment techniques were explored and the brine management methods were investigated. The findings of this study can help guide the selection and design of water treatment systems for electrolysis.
Analysis of Hydrogen Value Chain Events: Implications for Hydrogen Refueling Stations’ Safety
Apr 2024
Publication
Renewable hydrogen is emerging as the key to a sustainable energy transition with multiple applications and uses. In the field of transport in addition to fuel cell vehicles it is necessary to develop an extensive network of hydrogen refueling stations (hereafter HRSs). The characteristics and properties of hydrogen make ensuring the safe operation of these facilities a crucial element for their successful deployment and implementation. This paper shows the outcomes of an analysis of hydrogen incidents and accidents considering their potential application to HRSs. For this purpose the HIAD 2.0 was reviewed and a total of 224 events that could be repeated in any of the major industrial processes related to hydrogen refueling stations were analyzed. This analysis was carried out using a mixed methodology of quantitative and qualitative techniques considering the following hydrogen value chain: production storage delivery and industrial use. The results provide general information segmented by event frequency damage classes and failure typology. The analysis shows the main processes of the value chain allow the identification of key aspects for the safety management of refueling facilities.
Origin and Evolution of Hydrogen-rich Gas Discharges from a Hot Spring in the Eastern Coastal Area of China
Jan 2020
Publication
Unlike the typical low-temperature (< 150 °C) continental geothermal systems usually characterized by high N2 CH4 and CO2 concentrations but a trace H2 concentration the sandstone-dominated Jimo hot spring on China's eastern coast exhibits: (1) abnormally high H2 concentrations (2.4–12.5 vol%) and H2/CH4 (up to 46.5); (2) depleted δD-H2 (−822 to −709‰) comparable to the Kansas hot springs near the Mid-Continent rift system with the most depleted δD-H2 (−836 to −740‰) recorded in nature; and (3) dramatic gas concentration and isotope ratio variations within an area of 0.2 km2 . Gas chemistry and H-C-He-Ne isotope ratios are studied with reference to published H2 isotope data from various systems. The origin of the gas is most likely attributed to: (a) allochthonous abiotic H2 generated by the reduction of water and oxidation of FeII-rich pyroxene and olivine (serpentinization) in the basalt located 2 km away under near-surface conditions and migration to the deep sandstone reservoir; (b) primary thermogenic CH4 produced in the sandstone; (c) mixing with a considerable amount of microbial H2 from shallow fresh and marine sediments; and (d) biotic CH4 with typical abiotic signatures resulting from isotope exchanges with fluids high in H2/CH4 and CO2/CH4 ratios. Allochthonous abiotic H2 in a sandstone-dominated continental geothermal system and massive microbial fermentation-based H2 production in shallow fresh and residual marine sediments with insignificant but differential consumption activity are highlighted. The published hydrogen isotope ratios for H2 produced under various natural geological environmental and experimental conditions have been collected systematically to provide a fundamental framework and an initial tool for restricting the dominant origin of H2.
The Hydrogen-water Collision: Assessing Water and Cooling Demands for Large-scale Green Hydrogen Production in a Warming Climate
Dec 2024
Publication
Hydrogen is expected to play a critical role in future energy systems projected to have an annual demand of 401–660 Mt by 2050. With large-scale green hydrogen projects advancing in water-scarce regions like Australia Chile and the Middle East and North Africa understanding water requirements for large-scale green hydrogen production is crucial. Meeting this future hydrogen demand will necessitate 4010 to 6600 GL of demineralised water annually for electrolyser feedwater if dry cooling is employed or an additional 6015 to 19800 GL for cooling water per year if evaporative cooling is employed. Using International Panel of Climate Change 2050 climate projections this work evaluated the techno-economic implications of dry vs. evaporative cooling for large-scale electrolyser facilities under anticipated higher ambient temperatures. The study quantifies water demands costs and potential operational constraints showing that evaporative cooling is up to 8 times cheaper to implement than dry cooling meaning that evaporative cooling can be oversized to accommodate increased cooling demand of high temperature events at a lower cost. Furthermore of the nations analysed herein Chile emerged as having the lowest cost of hydrogen owing to the lower projected ambient temperatures and frequency of high temperature events.
Renewable Hydrogen for the Energy Transition in Australia - Current Trends, Challenges and Future Directions
Sep 2024
Publication
Hydrogen is viewed as a potential energy solution for the 21st century with capabilities to tackle issues relating to environmental emissions sustainability energy shortages and security. Even though there are potential benefits of renewable hydrogen towards transitioning to net-zero emissions there is a limited study on the current use ongoing development and future directions of renewable hydrogen in Australia. Thus this study conducts a systematic review of studies for exploring Australia’s renewable hydrogen energy transition current trends strategies developments and future directions. By using the Preferred Reporting Items for Systematic Reviews and Meta-Analyses (PRISMA) guidelines earlier studies from 2005 to 2024 from two major databases such as ProQuest and Web of Science are gathered and analyzed. The study highlights significant issues relating to hydrogen energy technologies and opportunities/challenges in production storage distribution utilization and environmental impacts. The study found that Australia’s ambition for a strong hydrogen economy is made apparent with its clear strategic actions to develop a clean technology-based hydrogen production storage and distribution system. This study provides several practical insights on Australia’s hydrogen energy transition hydrogen energy technologies investments and innovation as well as strategies/recommendations for achieving a more environment friendly secure affordable and sustainable energy future.
A Review on the Environmental Performance of Various Hydrogen Production Technologies: An Approach Towards Hydrogen Economy
Nov 2023
Publication
Demand for hydrogen has grown and continues to rise as a versatile energy carrier. Hydrogen can be produced from renewable and non-renewable energy sources. A wide range of technologies to produce hydrogen in an environmentally friendly way have been developed. As the life cycle assessment (LCA) approach has become popular recently including in the hydrogen energy system this paper comprehensively reviews the LCA of hydrogen production technology. A subdivision based on the trends in the LCA studies hydrogen production technology goal and scope definition system boundary and environmental performance of hydrogen production is discussed in this review. Thermochemical hydrogen production is the most studied technology in LCA. However utilizing natural resources especially wind power in the electrolysis process stands out as an environmentally preferable solution when compared to alternative production processes. It is crucial to rethink reactors and other production-related equipment to improve environmental performance and increase hydrogen production efficiency. Since most of the previous LCA studies were conducted in developed countries and only a few were from developing countries a way forward for LCA application on hydrogen in developing countries was also highlighted and discussed. This review provides a comprehensive insight for further research on hydrogen production technology from an LCA perspective.
Design of Energy Management Strategy for Integrated Energy System Including Multi-Component Electric–Thermal–Hydrogen Energy Storage
Dec 2024
Publication
To address the challenges of multi-energy coupling decision-making caused by the complex interactions and significant conflicts of interest among multiple entities in integrated energy systems an energy management strategy for integrated energy systems with electricity heat and hydrogen multi-energy storage is proposed. First based on the coupling relationship of electricity heat and hydrogen multi-energy flows the architecture of the integrated energy system is designed and the mathematical model of the main components of the system is established. Second evaluation indexes in three dimensions including energy storage device life load satisfaction rate and new energy utilization rate are designed to fully characterize the economy stability and environmental protection of the system during operation. Then an improved radar chart model considering multi-evaluation index comprehensive optimization is established and an adaptability function is constructed based on the sector area and perimeter. Combined with the operation requirements of the electric–thermal–hydrogen integrated energy system constraint conditions are determined. Finally the effectiveness and adaptability of the strategy are verified by examples. The proposed strategy can obtain the optimal decision instructions under different operation objectives by changing the weight of evaluation indexes while avoiding the huge decision space and secondary optimization problems caused by multiple non-inferior solutions in conventional optimization and has multiscenario adaptability.
Total Cost of Ownership Analysis of Fuel Cell Electric Bus with Different Hydrogen Supply Alternatives
Dec 2023
Publication
In the transition to sustainable public transportation with zero-emission buses hydrogen fuel cell electric buses have emerged as a promising alternative to traditional diesel buses. However assessing their economic viability is crucial for widespread adoption. This study carries out a comprehensive examination encompassing both sensitivity and probabilistic analyses to assess the total cost of ownership (TCO) for the bus fleet and its corresponding infrastructure. It considers various hydrogen supply options encompassing on-site electrolysis on-site steam methane reforming and off-site hydrogen procurement with both gaseous and liquid delivery methods. The analysis covers critical cost elements encompassing bus acquisition costs infrastructure capital expenses and operational and maintenance costs for both buses and infrastructure. This paper conducted two distinct case studies: one involving a current small bus fleet of five buses and another focusing on a larger fleet set to launch in 2028. For the current small fleet the off-site gray hydrogen purchase with a gaseous delivery option is the most cost-effective among hydrogen alternatives but it still incurs a 26.97% higher TCO compared to diesel buses. However in the case of the expanded 2028 fleet the steam methane-reforming method without carbon capture emerges as the most likely option to attain the lowest TCO with a high probability of 99.5%. Additionally carbon emission costs were incorporated in response to the growing emphasis on environmental sustainability. The findings indicate that although diesel buses currently represent the most economical option in terms of TCO for the existing small fleet steam methane reforming with carbon capture presents a 69.2% likelihood of being the most cost-effective solution suggesting it is a strong candidate for cost efficiency for the expanded 2028 fleet. Notably substantial investments are required to increase renewable energy integration in the power grid and to enhance electrolyzer efficiency. These improvements are essential to make the electrolyzer a more competitive alternative to steam methane reforming. Overall the findings in this paper underscore the substantial impact of the hydrogen supply chain and carbon emission costs on the TCO of zero-emission buses.
A Multi-Zone Model for Hydrogen Accumulation and Ventilation in Enclosures
Sep 2023
Publication
Due to the small characteristic molecular size of hydrogen small leaks are more common in hydrogen systems compared to similar systems with hydrocarbons. This together with the high reactivity makes an efficient ventilation system very important in hydrogen applications. There are several models available for ventilation sizing that are based on either a well-mixed assumption or a fully stratified situation. However experiments show that many realistic releases will be neither and therefore additional models are needed. One possibility is to use CFD-models but the small release sizes for pinhole releases (<<1 mm) make it difficult to find an appropriate mesh without excessive computational time (especially since the simulations need to be iterated to find the optimum ventilation size). An alternative approach which is described and benchmarked in the current paper is to use a multi-zone model where the domain is divided into several large cells where the mass exchange is simplified compared to CFD and thus simulation time is reduced. The flow in the model is governed by mass conservation and density differences due to concentration gradients using the Bernoulli equation. The release of gas generates a plume which is modelled based on an empirical plume model which gives the entrainment and hydrogen source term for each cell. The model has a short run time and will therefore allow optimization in a short time frame. The model is benchmarked against five experiments with helium at the Canadian Nuclear Laboratories (CNL) in Canada and one hydrogen experiment performed at Lodz University of Technology in Poland. The result shows that the model can reasonably well reproduce accumulation in the experiments with small release without ventilation but appears to slightly underestimate the level of stratification and the interface height for ventilated cases where the source is elevated from the floor level.
HyPLANT100: Industrialization from Assembly to the Construction Site for Gigawatt Electrolysis
Apr 2024
Publication
The global push for sustainable energy has heightened the demand for green hydrogen which is crucial for decarbonizing heavy industry. However current electrolysis plant capacities are insufficient. This research addresses the challenge through optimizing large-scale electrolysis construction via standardization modularization process optimization and automation. This paper introduces H2Giga a project for mass-producing electrolyzers and HyPLANT100 investigating largescale electrolysis plant structure and construction processes. Modularizing electrolyzers enhances production efficiency and scalability. The integration of AutomationML facilitates seamless information exchange. A digital twin concept enables simulations optimizations and error identification before assembly. While construction site automation provides advantages tasks like connection technologies and handling cables tubes and hoses require pre-assembly. This study identifies key tasks suitable for automation and estimating required components. The Enapter Multicore electrolyzer serves as a case study showcasing robotic technology for tube fittings. In conclusion this research underscores the significance of standardization modularization and automation in boosting the electrolysis production capacity for green hydrogen contributing to ongoing efforts in decarbonizing the industrial sector and advancing the global energy transition.
Mitigating Emissions in the Global Steel Industry: Representing CCS and Hydrogen Technologies in Integrated Assessment Modelling
Dec 2023
Publication
We conduct a techno-economic assessment of two low-emissions steel production technologies and evaluate their deployment in emissions mitigation scenarios utilizing the MIT Economic Projection and Policy Analysis (EPPA) model. Specifically we assess direct reduced iron-electric arc furnace with carbon capture and storage (DRI-EAF with CCS) and H2-based direct reduced iron-electric arc furnace (H2 DRI-EAF) which utilizes low carbon hydrogen to reduce CO2 emissions. Our techno-economic analysis based on the current state of technologies found that DRI-EAF with CCS increased costs ~7% relative to the conventional steel technology. H2 DRI-EAF increased costs by ~18% when utilizing Blue hydrogen and ~79% when using Green hydrogen. The exact pathways for hydrogen production in different world regions including the extent of CCS and hydrogen deployment in steelmaking are highly speculative at this point. In illustrative scenarios using EPPA we find that using base cost assumptions switching from BF-BOF to DRI-EAF or scrap EAF can provide significant emissions mitigation within steelmaking. With further reductions in the cost of advanced steelmaking we find a greater role for DRI-EAF with CCS whereas reductions in both the cost of advanced steelmaking and hydrogen production lead to a greater role for H2 DRI-EAF. Our findings can be used to help decision-makers assess various decarbonization options and design economically efficient pathways to reduce emissions in the steel industry. Our cost evaluation can also be used to inform other energy-economic and integrated assessment models designed to provide insights about future decarbonization pathways.
High-Entropy Alloys: Innovative Materials with Unique Properties for Hydrogen Storage and Technologies for Their Production
Jan 2025
Publication
This paper presents a review of a number of works devoted to the studies of high-entropy alloys (HEAs). As is known HEAs represent a new class of materials that have attracted the attention of scientists due to their unique properties and prospects of application in hydrogen power engineering. The peculiarity of HEAs is their high entropy of mixing which provides phase stability and flexibility in developing materials with given characteristics. The main focus of this paper is on the application of HEAs for solid-state hydrogen storage their physicochemical and mechanical properties and synthesis technologies. Recent advances in the hydrogen absorption properties of HEAs are analyzed including their ability to efficiently absorb and desorb hydrogen at moderate temperatures and pressures. Prospects for their use in the development of environmentally safe and efficient hydrogen storage systems are considered. The work also includes a review of synthesis methods aimed at optimizing the properties of HEAs for hydrogen energy applications.
The NREL Sensor Laboratory: Hydrogen Leak Detection for Large Scale Deployments
Sep 2023
Publication
The NREL Hydrogen Sensor Laboratory was commissioned in 2010 as a resource for sensor developers end-users and regulatory agencies within the national and international hydrogen community. The Laboratory continues to provide as its core capability the unbiased verification of hydrogen sensor performance to assure sensor availability and their proper use. However the mission and strategy of the NREL Sensor Laboratory has evolved to meet the needs of the growing hydrogen market. The Sensor Laboratory program has expanded to support research in conventional and alternative detection methods as hydrogen use expands to large-scale markets as envisioned by the DOE National Clean Hydrogen Strategy and Roadmap. Current research encompasses advanced methods of hydrogen leak detection including stand-off and wide area monitoring approaches for large scale and distributed applications. In addition to safety applications low-level detection strategies to support the potential environmental impacts of hydrogen and hydrogen product losses along the value chain are being explored. Many of these applications utilize detection strategies that supplement and may supplant the use of traditional point sensors. The latest results of the hydrogen detection strategy research at NREL will be presented.
Cost Modelling-based Route Applicablity Analysis of United Kingdom Pasenger Railway Decarbonization Options
Jun 2024
Publication
The UK government plans to phase out pure diesel trains by 2040 and fully decarbonize railways by 2050. Hydrogen fuel cell (HFC) trains electrified trains using pantographs (Electrified Trains) and battery electric multiple unit (BEMU) trains are considered the main solutions for decarbonizing railways. However the range of these decarbonization options’ line upgrade cost advantages is unclear. This paper analyzes the upgrade costs of three types of trains on different lines by constructing a cost model and using particle swarm optimization (PSO) including operating costs and fixed investment costs. For the case of decarbonization of the London St. Pancras to Leicester line the electrified train option is more cost-effective than the other two options under the condition that the service period is 30 years. Then the traffic density range in which three new energy trains have cost advantages on different line lengths is calculated. For route distances under 100 km and with a traffic density of less than 52 trips/day BEMU trains have the lowest average cost while electrified trains are the most costeffective in other ranges. For route distances over 100 km the average cost of HFC trains is lower than that of electrified trains at traffic densities below about 45 trips/day. In addition if hydrogen prices fall by 26 % the cost advantage range of HFC trains will increase to 70 trips per day. For route distances under 100 km BEMU trains still maintain their advantages in terms of lower traffic density.
An Assessment of Current Hydrogen Supply Chains in the Gulf Cooperation Council (GCC)
May 2024
Publication
The Gulf Cooperation Council (GCC) comprising: Saudi Arabia United Arab Emirates Kuwait Qatar Oman and Bahrain is home to an abundant number of resources including natural gas and solar and wind energy (renewables). Because of this the region is favourably positioned to become a significant player in both blue and green hydrogen production and their export. Current dependence on fossil fuels and ambitious national targets for decarbonisation have led the region and world to research the feasibility of switching to a hydrogen economy. This literature review critically examines the current advantages and strategies adopted by the GCC to expedite the implementation of hydrogen supply chains as well as investigation into the methodologies employed in current research for the modelling and optimisation of hydrogen supply chains. Insight into these endeavours is critical for stakeholders to assess the inherent challenges and opportunities in establishing a sustainable hydrogen economy. Despite a substantial global effort establishing a solid hydrogen supply chain presently faces various obstacles including the costs of clean hydrogen production. Scaling-up storage and transport methods is an issue that affects all types of hydrogen including carbon-intensive (grey) hydrogen. However the current costs of green hydrogen production mostly via the process of electrolysis is a major obstacle hindering the widescale deployment of clean hydrogen. Research in this literature review found that compressed gas and cryogenic liquid options have the highest storage capacities for hydrogen of 39.2 and 70.9 kg/m3 respectively. Meanwhile for hydrogen transportation pipelines and cryogenic tankers are the most conventional and efficient options with an efficiency of over 99 %. Cryogenic ships to carry liquid hydrogen also show potential due to their large storage capacities of 10000 tonnes per shipment However costs per vessel are currently still very expensive ranging between $ 465 and $620 million.
Research on the Technical Scheme of Multi-stack Common Rail Fuel Cell Engine Based on the Demand of Commercial Vehicle
Feb 2024
Publication
At present most fuel cell engines are single-stack systems and high-power single-stack systems have bottlenecks in meeting the power requirements of heavy-duty trucks mainly because the increase in the single active area and the excessive number of cells will lead to poor distribution uniformity of water gas and heat in the stack which will cause local attenuation and reduce the performance of the stack. This paper introduces the design concept of internal combustion engine takes three-stack fuel cell engine as an example designs multi-stack fuel cell system scheme and serialized high-voltage scheme. Through Intelligent control technology of independent hydrogen injection based on multi-stack coupling the hydrogen injection inflow of each stack is controlled online according to the real-time anode pressure to achieve accurate fuel injection of a single stack and ensure the consistency between multiple stacks. proves the performance advantage of multi-stack fuel cell engine through theoretical designintelligent control and test verification and focuses on analyzing the key technical problems that may exist in multi-stack consistency. The research results provide a reference for the design of multi-stack fuel cell engines and have important reference value for the powertrain design of long-distance heavy-duty and high-power fuel cell trucks.
Safety of Cryogenic Liquid Hydrogen Bunkering Operations - The Gaps Between Existing Knowhow and Industry Needs
Sep 2023
Publication
Hydrogen plays an important role in the global transition towards Net-Zero emission. While pipelines are a viable option to transport large quantities of compressed hydrogen over long distances it is not always practical in many applications. In such situations a viable option is to transport and deliver large quantities of hydrogen as cryogenic liquid. The liquefaction process cools hydrogen to cryogenic temperatures below its boiling point of -259.2 0C. Such extreme low temperature implies specific hazards and risks which are different from those associated with the relatively well-known compressed gaseous hydrogen. Managing these specific issues brings new challenges for the stakeholders.<br/>Furthermore the transfer of liquid hydrogen (LH2) and its technical handling is relatively well known for industrial gas or space applications. Experience with LH2 in public and populated areas such as truck and aircraft refuelling stations or port bunkering stations for example is limited or non-existent. Safety requirements in these applications which involve or are in proximity of untrained public are different from rocket/aerospace industry.<br/>The manuscript reviews knowhow already gained by the international hydrogen safety community; and on such basis elucidate the gaps which are yet to be filled to meet industry needs to design and operate inherently safe LH2 operations including the implications for regulations codes and standards (RCS). Where relevant the associated gaps in some underpinning sciences will be mentioned; and the need to contextualise the information and safety practices from NASA1/ESA2/JAXA3 to inform risk adoption will be summarised.
Comparative Study of Different Alternative Fuel Options for Shipowners Based on Carbon Intensity Index Model Under the Background of Green Shipping Development
Nov 2024
Publication
The International Maritime Organization (IMO)’s annual operational carbon intensity index (CII) rating requires that from 1 January 2023 all applicable ships meet both technical and operational energy efficiency requirements. In this paper we conduct a comparative study of different alternative fuel options based on a CII model from the perspective of shipowners. The advantages and disadvantages of alternative fuel options such as liquefied natural gas (LNG) methanol ammonia and hydrogen are presented. A numerical example using data from three China Ocean Shipping (Group) shipping lines is analyzed. It was found that the overall attained CII of different ship types showed a decreasing trend with the increase of the ship’s deadweight tonnage. A larger ship size choice can obtain better carbon emission reduction for the carbon emission reduction investment program using alternative fuels. The recommended options of using LNG fuel and zero-carbon fuel (ammonia and hydrogen) on Route 1 and Route 3 during the study period were analyzed for the shipowners. Carbon reduction scenarios using low-carbon fuels (LNG and methanol) and zero-carbon fuels (ammonia and hydrogen) on Route 2 are in line with IMO requirements for CII.
Evaluating the Offshore Wind Business Case and Green Hydrogen Production: A Case Study of a Future North Sea Offshore Grid
Jun 2024
Publication
The European Union aims to increase its climate ambition and achieve climate neutrality by 2050. This necessitates expanding offshore wind energy and green hydrogen production especially for hard-to-abate industrial sectors. A study examines the impact of green hydrogen on offshore wind projects specifically focusing on a potential future North Sea offshore grid. The study utilizes data from the TYNDP 2020 Global Ambition scenario 2040 considering several European countries. It aims to assess new transmission and generation capacity utilization and understand the influencing factors. The findings show that incorporating green hydrogen production increases offshore wind utilization and capture prices. The study estimates that by 2040 the levelized cost of hydrogen could potentially decrease to e1.2-1.6/kg H2 assuming low-cost electricity supply and declining capital costs of electrolysers. These results demonstrate the potential benefits and cost reductions of integrating green hydrogen production into North Sea offshore wind projects.
Advancing Renewable Energy: Strategic Modeling and Optimization of Flywheel and Hydrogen-based Energy System
Sep 2024
Publication
This study introduces a hybrid energy storage system that combines advanced flywheel technology with hydrogen fuel cells and electrolyzers to address the variability inherent in renewable energy sources like solar and wind. Flywheels provide quick energy dispatch to meet peak demand while hydrogen fuel cells offer sustained power over extended periods. The research explores the strategic integration of these technologies within a hybrid photovoltaic (PV)-flywheel‑hydrogen framework aiming to stabilize the power supply. To evaluate the impact of flywheel integration on system sizing and load fluctuations simulations were conducted both before and after the flywheel integration. The inclusion of the flywheel resulted in a more balanced energy production and consumption profile across different seasons notably reducing the required fuel cell capacity from 100 kW to 30 kW. Additionally the integration significantly enhanced system stability enabling the fuel cell and electrolyzer to operate at consistent power during load fluctuations. The system achieved efficiencies of 71.42 % for the PEM electrolyzer and 62.14 % for the PEM fuel cell. However the introduction of the flywheel requires a higher capacity of PV modules and a larger electrolyzer. The overall flywheel's efficiency was impacted by parasitic energy losses resulting in an overall efficiency of 46.41 %. The minimum efficiency observed across various scenarios of the model studied was 3.14 % highlighting the importance of considering these losses in the overall system design. Despite these challenges the hybrid model demonstrated a substantial improvement in the reliability and stability of renewable energy systems effectively bridging short-term and long-term energy storage solutions.
Brief Review of Hydrocarbon-reforming Catalysts Map for Hydrogen Production
Jun 2023
Publication
Hydrogen energy the cleanest fuel presents extensive applications in renewable energy technologies such as fuel cells. However the transition process from carbon-based (fossil fuel) energy to desired hydrogen energy is usually hindered by inevitable scientific technological and economic obstacles which mainly involves complex hydrocarbon reforming reactions. Hence this paper provides a systematic and comprehensive analysis focusing on the hydrocarbon reforming mechanism. Accordingly recent related studies are summarized to clarify the intrinsic difference among the reforming mechanism. Aiming to objectively assess the activated catalyst and deactivation mechanism the rate-determining steps of reforming process have been emphasized summarized and analyzed. Specifically the effect of metals and supports on individual reaction processes is discussed followed by the metalsupport interaction. Current tendency and research map could be established to promote the technology development and expansion of hydrocarbon reforming field. This review could be considered as the guideline for academics and industry designing appropriate catalysts.
Freshwater Supply for Hydrogen Production: An Underestimated Challenges
Jun 2024
Publication
This paper presents a thorough critical literature review aimed at understanding the challenges associated with freshwater supply associated with rapidly growing global hydrogen economies. The review has been prompted by the fact that the hydrogen production projected for 2030 will create at least an additional demand of 2.1 billion cubic meters for freshwater which needs to be addressed to support sustainable development of emerging hydrogen economies. The key solutions explored by this study include seawater and wastewater treatment methods for large-scale freshwater generation along with the newly introduced technique of direct seawater-fed electrolysis. Prior research indicates that desalination technologies including reverse osmosis and membrane distillation also offer promising avenues for large-scale freshwater production at costs comparable to other desalination techniques. Additionally low-temperature desalination methods such as membrane distillation could play a significant role in freshwater production for electrolysis underscoring the importance of exploring waste recovery opportunities within the system (e.g. fuel cell heat recovery). This review also identifies research gaps that need to be addressed to overcome freshwater supply challenges and enhance the sustainability and techno-economic viability of large-scale hydrogen energy systems.
Prospects of Low and Zero-carbon Renewable Fuels in 1.5-degree Net Zero Emission Actualisation by 2050: A Critical Review
Sep 2022
Publication
The Paris Climate Agreement seeks to keep global temperature increases under 2° Celsius ideally 1.5° Celsius. This goal necessitates significant emission reductions. By 2030 emissions are expected to range between 52 and 58 GtCO2e from their 2016 level of approximately 52 GtCO2e. This review paper explores a number of low and zero-carbon renewable fuels such as hydrogen green ammonia green methanol biomethane natural gas and synthetic methane (with natural gas and synthetic methane subject to CCUS both at processing and at final use) as alternative solutions for providing a way to rebalance transition paths in order to achieve the goals of the Paris Agreement while also reaping the benefits of other sustainability targets. The results show renewables will need to account for approximately 90% of total electricity generation by 2050 and approximately 25% of non-electric energy usage in buildings and industry. However low and zero-carbon renewable fuels currently only contributes about 15% to the global energy shares and it will take about 10% more capacity to reach the 2050 goal. The transportation industry will need to take important steps toward energy efficiency and fuel switching in order to achieve the 20% emission reduction. Therefore significant new commitments to efficient low-carbon alternatives will be necessary to make this enormous change. According to this paper investing in energy efficiency and lowcarbon alternative energy must rise by a factor of about five by 2050 in comparison to 2015 levels if the 1.5 °C target is to be realised.
New Flow Simulation Framework for Underground Hydrogen Storage Modelling Considering Microbial and Geochemical Reactions
Jul 2025
Publication
The widespread use of hydrogen as an energy source relies on efficient large-scale storage techniques. Underground Hydrogen Storage (UHS) is a promising solution to balance the gap between renewable energy production and constant energy demand. UHS employs geological structures like salt caverns depleted reservoirs or aquifers for hydrogen storage enabling long-term and scalable storage capacity. Therefore robust and reliable predictive tools are essential to assess the risks associated with geological hydrogen storage. This paper presents a novel reactive transport model called “Underground Gas Flow simulAtions with Coupled bio-geochemical reacTions” or “UGFACT” designed for various gas injection processes accounting for geochemical and microbial reactions. The flow module and geochemical reactions in the UGFACT model were verified against two commercial reservoir simulators E300 and CMG-GEM showing excellent agreement in fluid flow variables and geochemical behaviour. A major step forward of this model is to integrate flow dynamics geochemical reactions and microbial activity. UGFACT was used to conduct a simple storage cycle in a 1D geometry across three different reservoirs each with different mineralogies and water compositions: Bentheimer sandstone Berea sandstone and Grey Berea sandstone under three microbial conditions (“No Reaction” “Moderate Rate” “High Rate”). The findings suggest that Bentheimer sandstone and Berea sandstone sites may experience severe effects from ongoing microbial and geochemical reactions whereas Grey Berea sandstone shows no significant H2 loss. Additionally the model predicts that under the high-rate microbial conditions the hydrogen consumption rate can reach to as much as 11 mmol of H2 per kilogram of water per day (mmol / kg⋅day) driven by methanogenesis and acetogenesis.
Hydrogen Underground Storage in Silica-Clay Shales: Experimental and Density Functional Theory Investigation
Nov 2023
Publication
In the context of reducing the global emissions of greenhouse gaseshydrogen (H2) has become an attractive alternative to substitute the current fossil fuels.However its properties seasonal fluctuations and the lack of extended energy stabilitymade it extremely difficult to be economically and safely stored for a long term in recentyears. Therefore this paper investigated the potential of shale gas reservoirs (rich andlow clay−rich silica minerals) to store hydrogen upon demand. Density functional theorymolecular simulation was employed to explore hydrogen adsorption on the silica−kaolinite interface and the physisorption of hydrogen on the shale surface is revealed.This is supported by low adsorption energies on different adsorption configurations(0.01 to −0.21 eV) and the lack of charge transfer showed by Bader charge analysis.Moreover the experimental investigation was employed to consider the temperature(50−100 °C) and pressure (up to 20 bar) impact on hydrogen uptake on Midra shalespecifically palygorskite (100%) which is rich in silicate clay minerals (58.83% SiO2).The results showed that these formations do not chemically or physically maintainhydrogen; hence hydrogen can be reversibly stored. The results highlight the potential of shale gas reservoirs to store hydrogen asno hydrogen is adsorbed on the shale surface so there will be no hydrogen loss and no adverse effect on the shale’s structuralintegrity and it can be safely stored in shale reservoirs and recovered upon demand.
Gas Leak Detection Using Acoustics and Artificial Intelligence
Sep 2023
Publication
Gas leak detection on a production site is a major challenge for the safety and health of workers for environmental considerations and from an economic point of view. In addition flammable gas leaks are a safety risk because if ignited they can cause serious fires or explosions. For these reasons Acoem Metravib in collaboration with TotalEnergies One Tech R&D Safety has developed for the past four years a system called AGLED for the early detection localization and classification of such leaks exploiting acoustics and artificial intelligence driven by physics. Numerous tests have been conducted on a theater representative of gas production facilities created by TotalEnergies in Lacq (France) to build a robust learning database of leaks varying in flowrates exhaust diameters and also types (hole nozzle flange...). Moreover to limit the number of false alarms a relearning strategy has been implemented to handle unexpected disturbances (wildlife human activities meteorological events...). The presented paper describes the global architecture of the system from noise acquisition to the gas leak probability and coordinates. It gives a more in-depth look at the relearning algorithm and its performance in various environments. Finally thanks to a complementary collaboration with Air Liquide an example of test campaign in a real industrial environment is presented with an emphasis on the improvement obtained through relearning.
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