Transmission, Distribution & Storage
Altering Carbonate Wettability for Hydrogen Storage: The Role of Surfactant and CO2 Floods
Oct 2025
Publication
Underground hydrogen storage (UHS) in depleted oil and gas fields is pivotal for balancing large-scale renewable-energy systems yet the wettability of reservoir rocks in contact with hydrogen after decades of Enhanced Oil Recovery (EOR) operations remains poorly quantified. This work experimentally investigates how two common EOR legacies cationic surfactant (city-trimethyl-ammonium bromide CTAB) and supercritical carbon dioxide (SC–CO2) flooding alter rock–water–Hydrogen (H2) wettability in carbonate formations. Contact angles were measured on dolomite and limestone rock slabs at 30–75 ◦C and 3.4–17.2 MPa using a high-pressure captive-bubble cell. Crude-oil aging shifted clean dolomite from strongly water-wet (θ ~ 28–29◦) to intermediate-wet (θ ≈ 84◦). Subsequent immersion in dilute CTAB solutions (0.5–2 wt %) fully reversed this effect restoring or surpassing the original water-wetness (θ ≈ 21–28◦). Limestone samples exposed to SC-CO2 at 60–80 ◦C became more hydrophilic (θ ≈ 18–30◦) relative to untreated controls; moderate carbonate dissolution (≤6 × 103 ppm Ca2+) produced the most significant improvement in water-wetness whereas severe dissolution yielded diminishing returns. These findings show that many mature reservoirs are already water-wet (post-CO2) or can be easily re-wetted (via residual CTAB). Across all scenarios sample wettability showed little sensitivity to pressure but higher temperature consistently promoted stronger water-wetness. Future work should include dynamic core-flooding experiments with realistic reservoir.
Evaluating the Potential for Underground Hydrogen Storage (UHS) in Lithuania: A Review of Geological Viability and Storage Integrity
Feb 2025
Publication
The aim of this study is to review and identify H2 storage suitability in geological reservoirs of the Republic of Lithuania. Notably Lithuania can store clean H2 effectively and competitively because of its wealth of resources and well-established infrastructure. The storage viability in Lithuanian geological contexts is highlighted in this study. In addition when it comes to injectivity and storage capacity salt caverns and saline aquifers present less of a challenge than other kinds of storage medium. Lithuania possesses sizable subterranean reservoirs (Cambrian rocks) that can be utilized to store H2. For preliminary assessment the cyclic H2 injection and production simulation is performed. A 10-year simulation of hydrogen injection and recovery in the Syderiai saline aquifer demonstrated the feasibility of UHS though efficiency was reduced by nearly 50% when using a single well for both injection and production. The study suggests using separate wells to improve efficiency. However to guarantee economic injectivity and containment security a detailed assessment of the geological structures is required specifically at the pore scale level. The volumetric approach estimated a combined storage capacity of approximately 898.5 Gg H2 (~11 TWh) for the Syderiai and Vaskai saline aquifers significantly exceeding previous estimates. The findings underscore the importance of detailed geological data and further research on hydrogen-specific factors to optimize UHS in Lithuania. Addressing technical geological and environmental challenges through multidisciplinary research is essential for advancing UHS implementation and supporting Lithuania’s transition to a sustainable energy system. UHS makes it possible to maximize the use of clean energy reduce greenhouse gas emissions and build a more sustainable and resilient energy system. Hence intensive research and advancements are needed to optimize H2 energy for broader applications in Lithuania.
Hydrogen Storage Potential of Unlined Granite Rock Caverns: Experimental and Numerical Investigations on Geochemical Interactions
Jun 2025
Publication
Underground Hydrogen Storage (UHS) offers a promising solution for large-scale energy storage yet suitable geological formations are often scarce. Unlined rock caverns (URCs) constructed in crystalline rocks like granite present a novel alternative particularly in regions where salt caverns or porous media are unsuitable. Despite their potential URCs remain largely unexplored for hydrogen storage. This study addresses this gap by providing one of the first comprehensive investigations into the geochemical interactions between hydrogen and granite host rock using a combined experimental and numerical approach. Granite powder samples were exposed to hydrogen and inert gas (N₂) in brine at room temperature and 5 MPa pressure for 14 weeks. Results showed minimal reactivity of silicate minerals with hydrogen indicated by negligible differences in elemental concentrations between H₂ and N₂ atmospheres. A validated geochemical model demonstrated that existing thermodynamic databases can accurately predict silicate‑hydrogen interactions. Additionally a kinetic batch model was developed to simulate long-term hydrogen storage under commercial URC conditions at Haje. The model predicts a modest 0.65 % increase in mineral volume over 100 years due to mineral precipitation which decreases net porosity and potentially enhances hydrogen containment by limiting leakage pathways. These findings support the feasibility of granite URCs for UHS providing a stable long-term storage option in regions lacking traditional geological formations. By filling a critical knowledge gap this study advances scalable hydrogen storage solutions contributing to the development of resilient renewable energy infrastructure.
A Cost-Optimizing Analysis of Energy Storage Technologies and Transmission Lines for Decarbonizing the UK Power System by 2035
Mar 2025
Publication
The UK net zero strategy aims to fully decarbonize the power system by 2035 anticipating a 40–60% increase in demand due to the growing electrification of the transport and heating sectors over the next thirteen years. This paper provides a detailed technical and economic analysis of the role of energy storage technologies and transmission lines in balancing the power system amidst large shares of intermittent renewable energy generation. The analysis is conducted using the cost-optimizing energy system modelling framework REMix developed by the German Aerospace Center (DLR). The obtained results of multiple optimization scenarios indicate that achieving the lowest system cost with a 73% share of electricity generated by renewable energy sources is feasible only if planning rules in England and Wales are flexible enough to allow the construction of 53 GW of onshore wind capacity. This flexibility would enable the UK to become a net electricity exporter assuming an electricity trading market with neighbouring countries. Depending on the scenario 2.4–11.8 TWh of energy storage supplies an average of 11% of the electricity feed-in with underground hydrogen storage representing more than 80% of that total capacity. In terms of storage converter capacity the optimal mix ranges from 32 to 34 GW of lithium-ion batteries 13 to 22 GW of adiabatic compressed air energy storage 4 to 24 GW of underground hydrogen storage and 6 GW of pumped hydro. Decarbonizing the UK power system by 2035 is estimated to cost $37–56 billion USD with energy storage accounting for 38% of the total system cost. Transmission lines supply 10–17% of the total electricity feed-in demonstrating that when coupled with energy storage it is possible to reduce the installed capacity of conventional power plants by increasing the utilization of remote renewable generation assets and avoiding curtailment during peak generation times.
A Multi-objective Decision-making Framework for Renewable Energy Transportation
Aug 2025
Publication
The mismatch in renewable energy generation potential levelized cost and demand across different geographies highlight the potential of a future global green energy economy through the trade of green fuels. This potential and need call for modeling frameworks to make informed decisions on energy investments operations and regulations. In this work we present a multi-objective optimization framework for modeling and optimizing energy transmission strategies considering different generation locations transportation modes and often conflicting objectives of cost environmental impact and transportation risk. An illustrative case study on supplying renewable energy to Germany demonstrates the utility of the framework across diverse options and trade-offs. Sensitivity analysis reveals that the optimal energy carrier and transmission strategy depend on distance demand and existing infrastructure that can be re-purposed. The framework is adaptable across geographies and scales to offer actionable insights to guide investment operational and regulatory decisions in renewable energy and hydrogen supply chains.
Hydrogen Storage Potential of Salado Formation in the Permian Basin of West Texas, United States
Jun 2025
Publication
Hydrogen (H2) has the potential to become a cleaner fuel alternative to increase energy mix versatility as part of a low-carbon economy. Geological H2 storage represents a key component of the emerging H2 value chain since large-scale energy generation linked to energy generation and large-scale industrial applications will require significant upscaling of geological storage. Geological H2 storage can take place in both salt domes and bedded salt formations. Bedded salt formations offer a significant advantage for H2 storage over salt domes because of their widespread availability. This research focuses on evaluating the H2 storage potential of the Salado Formation a bedded salt deposit in the Permian Basin of West Texas in the United States. Using data from 3268 well logs this study analyzes an area of 136100 km2 to identify suitable depth and net halite thickness for H2 storage in salt caverns. In addition this work applies a novel geostatistical workflow to quantify the uncertainty in the formation’s storage potential. The H2 working gas potential of the Salado Formation ranges from 0.62 to 17.53 Tsm3 (1.75–49.68 PWh of stored energy) across low-risk to high-risk scenarios with a median potential of 1.19 Tsm3 (3.37 PWh). The counties with the largest storage potential are: Lea in New Mexico and Gaines and Andrews in Texas. These three counties account for more than 75 % of the formation’s total storage potential. This is the first study to quantify uncertainty in H2 storage estimates for a bedded salt formation while providing a detailed breakdown of results by county and 1 km2 grid sections. The findings of this work offer critical insights for developing H2 infrastructure in the Permian Basin. The Permian Basin of West Texas has the potential to become an important hub for H2 production from both natural gas and/or renewable energy. Estimating H2 storage potential is an important contribution to assess the feasibility of the entire H2 value chain in Texas. An interactive map accompanies this work allowing the readers to explore the results visually.
Above-ground Hydrogen Storage: A State-of-the-art Review
Oct 2024
Publication
Hydrogen is increasingly recognized as a clean energy alternative offering effective storage solutions for widespread adoption. Advancements in storage electrolysis and fuel cell technologies position hydrogen as a pathway toward cleaner more efficient and resilient energy solutions across various sectors. However challenges like infrastructure development cost-effectiveness and system integration must be addressed. This review comprehensively examines above-ground hydrogen storage technologies and their applications. It highlights the importance of established hydrogen fuel cell infrastructure particularly in gaseous and LH2 systems. The review favors material-based storage for medium- and long-term needs addressing challenges like adverse thermodynamics and kinetics for metal hydrides. It explores hydrogen storage applications in mobile and stationary sectors including fuel-cell electric vehicles aviation maritime power generation systems off-grid stations power backups and combined renewable energy systems. The paper underscores hydrogen’s potential to revolutionize stationary applications and co-generation systems highlighting its significant role in future energy landscapes.
Optimizing Storage Parameters for Underground Hydrogen Storage in Aquifers: Cushion Gas Selection, Well Pattern Design, and Purity Control
Oct 2025
Publication
Underground hydrogen storage in aquifers is a promising solution to address the imbalance between energy supply and demand yet its practical implementation requires optimized strategies to ensure high efficiency and economic viability. To improve the storage and production efficiency of hydrogen it is essential to select the appropriate cushion gas and to study the influence of reservoir and process parameters. Based on the conceptual model of aquifer with single-well injection and production three potential cushion gas (carbon dioxide nitrogen and methane) were studied and the changes in hydrogen recovery for each cushion gas were compared. The effects of temperature initial pressure porosity horizontal permeability vertical to horizontal permeability ratio permeability gradient hydrogen injection rate and hydrogen production rate on the purity of recovered hydrogen were investigated. Additionally the impact of different well pattern on the purity of recovered hydrogen was studied. The results indicate that methane is the most effective cushion gas for improving hydrogen recovery in UHS. Different well patterns have significant impacts on the purity of recovered hydrogen. The mole fractions of methane in the produced gas for the single-well line-drive pattern and five-spot pattern were 16.8% 5% and 3.05% respectively. Considering the economic constraints the five-spot well pattern is most suitable for hydrogen storage in aquifers. Reverse rhythm reservoirs with smaller permeability differences should be chosen to achieve relatively high hydrogen recovery and purity of recovered hydrogen. An increase in hydrogen production rate leads to a significant decrease in the purity of the recovered hydrogen. In contrast hydrogen injection rate has only a minor effect. These findings provide actionable guidance for the selection of cushion gas site selection and operational design of aquifer-based hydrogen storage systems contributing to the large-scale seasonal storage of hydrogen and the balance of energy supply and demand.
Environmental and Economic Assessment of Large-scale Hydrogen Supply Chains across Europe: LOHC vs Other Hydrogen Technologies
Oct 2025
Publication
The transition to decarbonized energy systems positions hydrogen as a critical vector for achieving climate neutrality yet its large-scale transportation and storage remain key challenges. This study presents a comprehensive life cycle assessment (LCA) and economic analysis of large-scale H2 supply chains evaluating the liquid organic hydrogen carrier (LOHC) system based on benzyltoluene/perhydro-benzyltoluene (H0-BT/H12-BT) against conventional technologies: compressed gaseous hydrogen (CGH2) liquid hydrogen (LH2) and liquid ammonia (LNH3). The analysis includes multiple H2 transportation scenarios across Europe considering the steps: conditioning sea transportation post-processing and land distribution by truck or pipeline. Environmentally LOHC currently faces higher environmental impacts than CGH2 driven by energy-intensive dehydrogenation process. Truck-based distribution further amplifies impacts particularly over long distances while pipeline-based distribution significantly reduces the environmental burdens where infrastructure exists. Sensitivity analysis reveals that using H2 for dehydrogenation heat lowers process-level impacts but increases overall supply chain impacts questioning its net environmental benefit. Economically LOHC remains competitive despite high dehydrogenation costs benefiting from low sea transportation expenses compatibility with existing fossil fuel infrastructure and potential for future CAPEX and OPEX improvements. While CGH2 outperforms LH2 and LNH3 avoiding energy-intensive liquefaction and cracking its storage requirements add considerable costs. For land distribution LOHC trucks are optimal at lower capacities whereas repurposed natural gas pipelines favour CGH2 at higher scale reducing costs by up to 84 %. Despite current trade-offs the scalability flexibility and synergies with existing infrastructure position LOHC as a promising solution for long-distance H2 transport contingent on technological maturation to mitigate dehydrogenation impacts.
Fractal Fuzzy‑Based Multi‑criteria Assessment of Sustainability in Rare Earth Use for Hydrogen Storage
Aug 2025
Publication
The use of rare earth elements in hydrogen storage processes offers significant advantages in terms of increasing technological efficiency and ensuring system security. However this process also creates some serious problems in terms of environmental and economic sustainability. It is necessary to determine the most critical indicators affecting the sustainable use of these elements. Studies on this subject in the literature are quite limited and this may lead to wrong investment decisions. The main purpose of this study is to determine the most important indicators to increase the sustainable use of rare earth elements in hydrogen storage processes. An original decision-making model in which Siamese network logarithmic percentage-change driven objective weighting (LOPCOW) fractal fuzzy numbers and weighted influence super matrix with precedence (WISP) approaches are integrated in the study. This study provides an original contribution to the literature by identifying the most critical indicators affecting the sustainable use of rare earths in hydrogen storage processes by presenting an innovative model. Fractal structures such as Koch Snowflake Cantor Dust and Sierpinski Triangle can model complex uncertainties more successfully. Fractal structures are particularly effective in modeling linguistic fuzziness because their recursive nature closely mirrors the layered and imprecise way humans often express subjective judgments. Unlike linear fuzzy sets fractals can capture the patterns of ambiguity found in expert evaluations. Hydrogen storage capacity and government supports are determined as the most vital criteria affecting sustainability in rare earth use.
Machine Learning Models for the Prediction of Hydrogen Solubility in Aqueous Systems
Aug 2025
Publication
Hydrogen storage is integral to reducing CO2 emissions particularly in the oil and gas industry. However a primary challenge involves the solubility of hydrogen in subsurface environments particularly saline aquifers. The dissolution of hydrogen in saline water can impact the efficiency and stability of storage reservoirs necessitating detailed studies of fluid dynamics in such settings. Beyond its role as a clean energy carrier and precursor for synthetic fuels and chemicals understanding hydrogen’s solubility in subsurface conditions can significantly enhance storage technologies. When hydrogen solubility is high it can reduce reservoir pressure and alter the chemical composition of the storage medium undermining process efficiency. Machine learning techniques have gained prominence in predicting physical and chemical properties across various systems. One of the most complex challenges in hydrogen storage is predicting its solubility in saline water influenced by factors such as pressure temperature and salinity. Machine learning models offer substantial promise in improving hydrogen storage by identifying intricate nonlinear relationships among these parameters. This study uses machine learning algorithms to predict hydrogen solubility in saline aquifers employing techniques such as Bayesian inference linear regression random forest artificial neural networks (ANN) support vector machines (SVM) and least squares boosting (LSBoost). Trained on experimental data and numerical simulations these models provide precise predictions of hydrogen solubility which is strongly influenced by pressure temperature and salinity under a wide range of thermodynamic conditions. Among these methods RF outperformed the others achieving an R2 of 0.9810 for test data and 0.9915 for training data with RMSE values of 0.048 and 0.032 respectively. These findings emphasize the potential of machine learning to significantly optimize hydrogen storage and reservoir management in saline aquifers.
Polymers and Composites for Hydrogen Economy: A Perspective
Oct 2025
Publication
This paper provides authors’ perspective on the current advances and challenges in utilising polymers and composites in hydrogen economy. It has originated from ‘Polymers and Composites for Hydrogen Economy’ symposium organised in March 2025 at the University of Warwick. This paper presents views from the event and thus provides a perspective from academia and industry on the ongoing advances and challenges for those materials in hydrogen applications.
Proactive Regulation for Hydrogen Supply Chains: Enhancing Logistics Frameworks in Australia
Jun 2025
Publication
The rapid growth of Australia’s hydrogen economy highlights the pressing need for innovative regulatory strategies that address the distinct characteristics of hydrogen supply chains. This study focuses on the supply-side dynamics of the hydrogen energy sector emphasizing the importance of tailored frameworks to ensure the safe efficient and reliable movement of hydrogen across the supply chain. Key areas of analysis include the regulatory challenges associated with various transportation and storage methods particularly during long-distance transport and extended storage periods. The research identifies notable gaps and inconsistencies within the current regulatory systems across Australian states which inhibit the development of a unified hydrogen economy. To address these challenges the concept of Proactive Regulation for Hydrogen Supply (PRHS) is introduced. PRHS emphasizes anticipatory governance that adapts alongside technological advancements to effectively manage hydrogen transportation and storage. The study advocates for harmonizing fragmented state frameworks into a cohesive national regulatory system to support the sustainable and scalable expansion of hydrogen logistics. Furthermore the paper examines the potential of blockchain technology to enhance safety accountability and traceability across the hydrogen supply chain offering practical solutions to current regulatory and operational barriers.
Investigation of Erosion Behavior and Life Prediction of Stainless Steel Tube Under Hydrogen Gas with High Velocity
Sep 2025
Publication
The erosion behavior and the service life of a hydrogen transmission tube with high velocity suitable for a hydrogen fuel aviation engine are not clear which is the bottleneck for its application. In this study a coupled model considering the fluid flow field of hydrogen and discrete motion of particles was established. The effects of the geometry parameters and erosion parameters on the hydrogen erosion behavior were investigated. The maximum erosion rate increased exponentially with the increased hydrogen velocity and increased linearly with the increased erosion time. The large bend radius and inner diameter of the bend tube contributed to the decreased erosion rate. There was an optimized window of the bend angle for a small erosion rate. The relationship between the accumulated thickness loss and maximum erosion rate was established. The prediction model of the service life was established using fourth strength theory. The service life of the tube was sensitive to the hydrogen velocity and erosion time. The experiments were conducted and the variations in thickness and hardness were measured. The simulated models agreed with the experiments and could provide guidance for the parameter selection and prediction of the service life of a bend tube.
Electrospun Metal Hydride-polymer Nanocomposite Fibers for Enhanced Hydrogen Storage and Kinetics
Oct 2025
Publication
One of the key elements in the advancement of hydrogen (H2) and fuel cell technologies is to store H2 effectively for use in various industries such as transportation defense portable electronics and energy. Because of its highest energy density availability and environmental and health benefits H2 stands as a promising future energy carrier. Currently enterprises are searching for a solution for energy distribution management and H2 gas storage. Thus there is a need to develop an innovative solution to H2 storage that might be considered for later use in aviation applications. This study aims to synthesize an electrospun nanocomposite fiber (NCF) for an H2 storage application and to understand the absorption kinetics of the resultant highly porous NCF mats. This study incorporates functional NCFs with H2-sensitive inclusions to increase the storage capacity and absorption/desorption kinetics of H2 gas at lower temperatures and pressures. Here the electrospinning technique is utilized to produce NCFs with various nanoscale metal hydrides (MHs) and conductive particles which support enhancing H2 storage capacity and kinetics. These NCFs enable controlled H2 storage and improve thermal properties. Selected polymeric materials for H2 storage that have been investigated are polyacrylonitrile (PAN) polymethyl methacrylate (PMMA) and sulfonated polyether ether ketone (SPEEK) in combination with MHs and multiwalled carbon nanotubes (MWCNTs). On testing it was observed that H2 capacity with SPEEK which includes 4 wt% MWCNTs and 4 wt% MH MmNi4.5Fe0.5 shows significant H2 uptake compared to a PAN/PMMA polymer.
A Game Theory Approach in Hydrogen Supply Chain Resilience: Focus on Pricing, Sourcing, and Transmission Security
Jun 2025
Publication
This study examines the pricing and assesses resilience methods in hydrogen supply chains by thoroughly analyzing two main disruption scenarios. The model examines a scenario in which a hydrogen production company depends on a Renewable Power plant (RP) for its electricity supply. Ensuring a steady and efficient hydrogen supply chain is crucial but outages at renewable power sources provide substantial obstacles to sustainability and operational continuity. Therefore in the event of disruptions at the RP the company has two options for maintaining resilience: either sourcing electricity from a Fossil fuel Power plant (FP) through a grid network to continue hydrogen production or purchasing hydrogen directly from another company and utilizing third-party transportation for delivery. Using a game theoretic approach we examine how different methods affect demand satisfaction cost implications and environmental sustainability. The study employs sensitivity analysis to evaluate the impact of different disruption probabilities on each scenario. In addition a unique sensitivity analysis is performed to examine the resilience of transmission security to withstand disruptions. This study evaluates how investments in security measures affect the strength and stability of the supply chain in various scenarios of disruption. Our research suggests that the first scenario offers greater reliability and cost-effectiveness along with a higher resilience rate compared to the second scenario. Furthermore the examination of the environmental impact shows that the first scenario has a smaller amount of CO2 emissions per kg of hydrogen. This study offers important insights for supply chain managers to optimize resilience measures hence improving reliability reducing costs and minimizing environmental effects.
Dimensions, Structure, and Morphology Variations of Carbon-based Materials for Hydrogen Storage: A Review
Jul 2025
Publication
The swift and far-reaching evolution of advanced nanostructures and nanotechnologies has accelerated the research rate and extent which has a huge prospect for the benefit of the practical demands of solid-state hydrogen storage implementation. Carbonaceous materials are of paramount importance capable of forming versatile structures and morphology. This review aims to highlight the influence of the carbon material structure dimension and morphology on the hydrogen storage ability. An extensive range of synthesis routes and methods produces diverse micro/nanostructured materials with superb hydrogen-storing properties. The structures of carbon materials used for hydrogen adsorption from 0 to 3D and fabrication methods and techniques are discussed. Besides highlighting the striking merits of nanostructured materials for hydrogen storage remaining challenges and new research avenues are also considered.
Development of an Experimental Setup for Testing X52 Steel SENT Specimens in Electrolytic Hydrogen to Explore Repurposing Potential of Pipelines
Apr 2025
Publication
Hydrogen is considered a key alternative to fossil fuels in the broader context of ecological transition. Repurposing natural gas pipelines for hydrogen transport is one of the challenges of this approach. However hydrogen can diffuse into metallic lattices leading to hydrogen embrittlement (HE). For this reason typically ductile materials can experience unexpected brittle fractures and it is therefore necessary to assess the HE propensity of the current pipeline network to ensure its fitness for hydrogen transport. This study examines the relationship between the microstructure of the circumferential weld joint in X52 pipeline steel and hydrogen concentration introduced electrolytically. Base material heat affected zone and fused zone were subjected to 1800 3600 7200 and 14400 s of continuous charging with a current density J = − 10 mA/cm2 in an acid solution. Results showed that the fusion zone absorbed the most hydrogen across all charging times while the base material absorbed more hydrogen than the heat-affected zone due to the presence of non-metallic inclusions. Fracture toughness was assessed using single edge notch tension specimens (SENT) in air and electrolytic hydrogen. Results indicate that the base material is particularly vulnerable to hydrogen environments exhibiting the greatest reduction in toughness when exposed to hydrogen compared to air.
Hydrogen Storage Potential in Underground Coal Gasification Cavities: A MD Simulation of Hydrogen Adsorption and Desorption Behavior in Coal Nanopores
May 2025
Publication
Underground hydrogen storage (UHS) in geological formations presents a viable option for long-term large-scale H2 storage. A physical coal model was constructed based on experimental tests and a MD simulation was used to investigate the potential of UHS in underground coal gasification (UCG) cavities. We investigated H2 behavior under various conditions including temperatures ranging from 278.15 to 348.15 K pressures in the range of 5–20 MPa pore sizes ranging from 1 to 20 nm and varying water content. We also examined the competitive adsorption dynamics of H2 in the presence of CH4 and CO2 . The findings indicate that the optimal UHS conditions for pure H2 involve low temperatures and high pressures. We found that coal nanopores larger than 7.5 nm optimize H2 diffusion. Additionally higher water content creates barriers to hydrogen diffusion due to water molecule clusters on coal surfaces. The preferential adsorption of CO2 and CH4 over H2 reduces H2 -coal interactions. This work provides a significant understanding of the microscopic behaviors of hydrogen in coal nanopores at UCG cavity boundaries under various environmental factors. It also confirms the feasibility of underground hydrogen storage (UHS) in UCG cavities.
The Link Between Microstructural Heterogeneity and Hydrogen Redistribution
Jul 2025
Publication
Green hydrogen is likely to play a major role in decarbonising the aviation industry. It is crucial to understand the effects of microstructure on hydrogen redistribution which may be implicated in the embrittlement of candidate fuel system metals. We have developed a multiscale finite element modelling framework that integrates micromechanical and hydrogen transport models such that the dominant microstructural effects can be efficiently accounted for at millimetre length scales. Our results show that microstructure has a significant effect on hydrogen localisation in elastically anisotropic materials which exhibit an interesting interplay between microstructure and millimetre-scale hydrogen redistribution at various loading rates. Considering 316L stainless steel and nickel a direct comparison of model predictions against experimental hydrogen embrittlement data reveals that the reported sensitivity to loading rate may be strongly linked with rate-dependent grain scale diffusion. These findings highlight the need to incorporate microstructural characteristics in hydrogen embrittlement models.
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