Australia
Synergy of Carbon Capture, Waste Heat Recovery and Hydrogen Production for Industrial Decarbonisation
May 2024
Publication
Industry is the biggest sector of energy consumption and greenhouse gas emissions whose decarbonisation is essential to achieve the Sustainable Development Goals. Carbon capture energy efficiency improvement and hydrogen are among the main strategies for industrial decarbonization. However novel approaches are needed to address the key requirements and differences between sectors to ensure they can work together to well integrate industrial decarbonisation with heat CO2 and hydrogen. The emerging Calcium Looping (CaL) is attracting interest in designing CO2-involved chemical processes for heat capture and storage. The reversibility relatively high-temperature (600 to 900 ◦C) and high energy capacity output as well as carbon capture function make CaL well-fit for CO2 capture and utilisation and waste heat recovery from industrial flue gases. Meanwhile methane dry reforming (MDR) is a promising technology to produce blue hydrogen via the consumption of two major greenhouse gases i.e. CO2 and CH4. It has great potential to combine the two technologies to achieve insitu CO2 utilization with multiple benefits. In this paper progresses on the reaction conditions and performance of CaL for CO2 capture and industrial waste heat recovery as well as MDR were screened. Secondly recent approaches to CaL-MDR synergy have been reviewed to identify the advantages. The major challenges in such a synergistic process include MDR catalyst deactivation CaL sorbents sintering and system integration. Thirdly the paper outlooks future work to explore a rational design of a multi-function system for the proposed synergistic process.
A Review on the Overall Performance of Metal Hydride-Based Hydrogen Storage Systems
Mar 2025
Publication
Metal hydride-based hydrogen storage (MHHS) has been used for several purposes including mobile and stationary applications. In general the overall MHHS performance for both applications depends on three main factors which are the appropriate selection of metal hydride material uses design configurations of the MHHS based on the heat exchanger and overall operating conditions. However there are different specific requirements for the two applications. The weight of the overall MHHS is the key requirement for mobile applications while hydrogen storage capacity is the key requirement for stationary applications. Based on these requirements several techniques have been recently used to enhance MHHS performance by mostly considering the faster hydrogen absorption/desorption reaction. Considering metal hydride (MH) materials their low thermal conductivity significantly impacts the hydrogen absorption/desorption reaction. For this purpose a comprehensive understanding of these three main factors and the hydrogen absorption/desorption reaction is critical and it should be up to date to obtain the suitable MHHS performance for all related applications. Therefore this article reviews the key techniques which have recently been applied for the enhancement of MHHS performance. In the review it is demonstrated that the design and layout of the heat exchanger greatly affect the performance of the internal heat exchanger. The initial temperature of the heat transfer fluid and hydrogen supply pressure are the main parameters to increase the hydrogen sorption rate and specific heating power. The higher supply pressure results in the improvement in specific heating power. For the metal hydride material selection under the consideration of mobile applications and stationary applications it is important to strike trade-offs between hydrogen storage capacity weight material cost and effective thermal conductivity.
Life Cycle Assessment of Renewable Hydrogen Transport by Ammonia
Nov 2024
Publication
Ammonia is a promising hydrogen carrier for enabling the efficient transport of hydrogen as observed by the many hydrogen transport projects using ammonia. For the clean energy future understanding environmental impacts of the transport system is important. This study conducts life cycle assessment (LCA) for the marine transport of renewable hydrogen using ammonia as the hydrogen carrier. The LCA considered renewable hydrogen produced from four systems; wind-powered electrolysis gasification of forest residue anaerobic digestion of food waste and landfill gas reforming; followed by Haber-Bosch ammonia synthesis using the renewable hydrogen and nitrogen produced from air separation. The ammonia was then transported 11000 km by sea to a destination facility where it was decomposed using either Ru or Ni catalysts to obtain hydrogen. Among the four hydrogen transport systems operated with renewable energy electrolysis-hydrogen system presented the highest global warming impact of 3.31 kg CO2 eq/kg H2 due to electricity use for the electrolysis whereas simpler processes based on a landfill gas system led to the lowest impact of 2.27 kg CO2 eq/kg H2. Process energy consumption was the major contributor to global warming impact with 27%–49.2% of contri bution. The consumption of metals and energy during wind turbine construction resulted in the most significant impact in six out of 12 midpoint impact categories for the electrolysis-hydrogen system which also led to the highest endpoint impacts. The endpoint impacts of the four systems were in the order of electrolysis > food waste > forest residue > landfill gas (from high to low) for both endpoint human health and ecosystems impacts. Ammonia decomposition using Ru catalysts exhibited slightly lower global warming impact than Ni catalysts while final purification of hydrogen by vanadium membrane presented 4.8% lower impacts than the purification by pressure swing adsorption. Large-scale hydrogen supply chains can be achieved by technological improve ment and support of policies and financial schemes.
Comparative Study of LNG, Liquid Hydrogen ,and Liquid Ammonia Post-release Evaporation and Dispersion During Bunkering
Apr 2024
Publication
The use of alternative fuels is a primary means for decarbonising the maritime industry. Liquefied natural gas (LNG) liquid hydrogen (LH2) and liquid ammonia (LNH3) are liquified gases among the alternative fuels. The safety risks associated with these fuels differ from traditional fuels. In addition to their low-temperature hazards the flammability of LNG and LH2 and the high toxicity of LNH3 present challenges in fuel handlings due to their high likelihood of fuel release during bunkering. This study aims at drawing extensive comparisons of the evaporation and vapour dispersion behaviours for the three fuels after release accidents during bunkering and discuss their safety issues. The study involved the release event of the three fuels on the main deck area of a reference bulk carrier with a deadweight of 208000 tonnes. Two release scenarios were considered: Scenario 1 involved a release of 0.3 m3 of fuel and Scenario 2 involved a release of 100 kg of fuel. An empirical equation was used to calculate the fuel evaporation process and the Computational Fluid Dynamic (CFD) code FDS was employed to simulate the dispersion of vapour clouds. The obtained results reveal that LH2 has the highest evaporation rate followed by LNG and LNH3. The vapour clouds of LNG and LNH3 spread along the main deck surface while the LH2 vapour cloud exhibits upward dispersion. The flammable vapour clouds of LNG and LH2 remain within the main deck area whereas the toxic gas cloud of LNH3 disperses towards the shore and spreads near the ground on the shore side. Based on the dispersion behaviours the hazards of LNG and LH2 are com parable while LNH3 poses significantly higher hazards. In terms of hazard mitigations effective water curtain systems can suppress the vapour dispersion.
Challenges and Opportunities in Green Hydrogen Supply Chain through Metaheuristic Optimisation
May 2023
Publication
A comprehensive analysis of the green hydrogen supply chain is presented in this paper encompassing production storage transportation and consumption with a focus on the application of metaheuristic optimization. The challenges associated with each stage are highlighted and the potential of metaheuristic optimization methods to address these challenges is discussed. The primary method of green hydrogen production water electrolysis through renewable energy is outlined along with the importance of its optimization. Various storage methods such as compressed gas liquid hydrogen and material-based storage are covered with an emphasis on the need for optimization to improve safety capacity and performance. Different transportation options including pipelines trucks and ships are explored and factors influencing the choice of transportation methods in different regions are identified. Various hydrogen consumption methods and their associated challenges such as fuel cell performance optimization hydrogen-based heating systems design and energy conversion technology choice are also discussed. The paper further investigates multi-objective approaches for the optimization of problems in this domain. The significant potential of metaheuristic optimization techniques is highlighted as a key to addressing these challenges and improving overall efficiency and sustainability with respect to future trends in this rapidly advancing area.
Towards Net Zero Aviation: Exploring Safe Hydrogen Refuelling at Airports
Nov 2024
Publication
Hydrogen flight is one important part of the way to net zero aviation. However safety challenges around refuelling are not well understood but are paramount to enable airports to be more comfortable with using hydrogen in the airport environment. This study investigates safety considerations of hydrogen aircraft refuelling at airports. Technical and human factor risks are explored as well as risk assessment models. Two focus groups were conducted in 2022. Data was analysed using NVivo revealing major themes including the mental and physical performance of refuellers technical aspects of refuelling stations environmental factors and the use of risk assessment models. These findings contribute significantly to an understanding of hydrogen refuelling challenges in busy airport environments. Recommendations help airports preparing for hydrogen as a fuel source further supporting the transition towards net zero aviation. Future research could focus on carrying out experiments analysing chemical reactions between kerosene and hydrogen vapours and testing the identified risk assessment tools in different airport environments.
Artificial Intelligence for Hydrogen-Enabled Integrated Energy Systems: A Systematic Review
Aug 2024
Publication
Hydrogen-enabled Integrated Energy Systems (H-IES) stand out as a promising solution with the potential to replace current non-renewable energy systems. However their development faces challenges and has yet to achieve widespread adoption. These main challenges include the complexity of demand and supply balancing dynamic consumer demand and challenges in integrating and utilising hydrogen. Typical energy management strategies within the energy domain rely heavily on accurate models from domain experts or conventional approaches such as simulation and optimisation approaches which cannot be satisfied in the real-world operation of H-IES. Artificial Intelligence (AI) or Advanced Data Analytics (ADA) especially Machine Learning (ML) has the ability to overcome these challenges. ADA is extensively used across several industries however further investigation into the incorporation of ADA and hydrogen for the purpose of enabling H-IES needs to be investigated. This paper presents a systematic literature review to study the research gaps research directions and benefits of ADA as well as the role of hydrogen in H-IES.
Decarbonisation and Hydrogen Integration of Steel Industries: Recent Development, Challenges and Technoeconomics Analysis
Feb 2023
Publication
The steel industry is one of the major sources of greenhouse gas emissions with significant energy demand. Currently 73% of the world’s steel is manufactured through the coal-coke-based blast furnace-basic oxygen furnace route (BF-BOF) emitting about two tonnes of CO2 per tonne of steel produced. This review reports the major technologies recent developments challenges and technoeconomic comparison of steelmaking technol ogies emphasising the integration of hydrogen in emerging and established ironmaking and steelmaking pro cesses. Significant trials are underway especially in Germany to replace coal injected in the tuyeres of the blast furnace with hydrogen. However it is not clear that this approach can be extended beyond 30% replacement of coke because of the associated technical challenges. Direct smelting and fluidised bed technologies can emit 20%–30% less CO2 without carbon capture and storage utilisation. The implications of hydrogen energy in these technologies as a substitute for natural gas and coal are yet to be fully explored. A hydrogen-based direct reduction of iron ore (DRI) and steel scrap melting in an electric arc furnace (EAF) appeared to be the most mature technological routes to date capable of reducing CO2 emission by 95% but rely on the availability of rich iron concentrates as feed materials. Shaft furnace technologies are the common DRI-making process with a share of over 72% of the total production. The technology has been developed with natural gas as the main fuel and reductant. However it is now being adapted to operate predominantly on hydrogen to produce a low-carbon DRI product. Plasma and electrolysis-based iron and steelmaking are some of the other potential technologies for the application of hydrogen with a CO2 reduction potential of over 95%. However these technologies are in the preliminary stage of development with a technology readiness level of below 6. There are many technological challenges for the application of hydrogen in steel manufacturing such as challenges in distributing heat due to the endothermic H2 reduction process balancing carbon content in the product steel (particularly using zerocarbon DRI) removal of gangue materials and sourcing of cost-competitive renewable hydrogen and highquality iron ore (65>Fe). As iron ore quality degrades worldwide several companies are considering melting DRI before steelmaking possibly using submerged arc technology to eliminate gangue materials. Hence sig nificant laboratory and pilot-scale demonstrations are required to test process parameters and product qualities. Our analysis anticipates that hydrogen will play an instrumental role in decarbonising steel industries by 2035.
Hydrogen Demand Estimation for Sustainable Transport: A Comprehensive Review
Aug 2025
Publication
Hydrogen demand estimation for various transport modes supports policy and decision-making for the transition towards a sustainable low-carbon future transport system. It is one of the major factors that determine infrastructure construction production and distribution cost optimisation. Researchers have developed various methods for modelling hydrogen demand and its geographical distribution each based on different sets of predictor variables. This paper systematically reviews these methods and examines the key variables used in hydrogen demand estimation including the number of vehicles travel distance penetration rate and fuel economy. It emphasises the role of spatial analysis in uncovering the geographical distribution of hydrogen demand providing insights for strategic infrastructure planning. Furthermore the discussion underscores the significance of minimising uncertainty by incorporating multiple scenarios into the model thereby accommodating the dynamic nature of hydrogen adoption in transport. The necessity for multi-temporal estimation which accounts for the changing nature of hydrogen demand over time is also highlighted. In addition this paper advocates for a holistic approach to hydrogen demand estimation integrating spatiotemporal analysis. Future research could enhance the reliability of hydrogen demand models by addressing uncertainty through advanced modelling techniques to improve accuracy and spatial-temporal resolution.
Optimum Geological Storage Depths for Structural H2 Geo-storage
Sep 2021
Publication
H2 geo-storage has been suggested as a key technology with which large quantities of H2 can be stored and withdrawn again rapidly. One option which is currently explored is H2 storage in sedimentary geologic for mations which are geographically widespread and potentially provide large storage space. The mechanism which keeps the buoyant H2 in the subsurface is structural trapping where a caprock prevents the H2 from rising by capillary forces. It is therefore important to assess how much H2 can be stored via structural trapping under given geo-thermal conditions. This structural trapping capacity is thus assessed here and it is demonstrated that an optimum storage depth for H2 exists at a depth of 1100 m at which a maximum amount of H2 can be stored. This work therefore aids in the industrial-scale implementation of a hydrogen economy.
A Review of Type V Composite Pressure Vessels and Automated Fibre Placement Based Manufacturing
Feb 2023
Publication
Hydrogen is emerging as a promising future energy medium in a wide range of industries. For mobile applica tions it is commonly stored in a gaseous state within high-pressure composite overwrapped pressure vessels (COPVs). The current state of the art pressure vessel technology known as Type V eliminates the internal polymer gas barrier used in Type IV vessels and instead relies on carbon fibre laminate to provide structural properties and prevent gas leakage. Achieving this functionality at high pressure poses several engineering challenges that have thus far prohibited commercial application. Additionally the traditional manufacturing process for COPVs filament winding has several constraints that limit the design space. Automated fibre placement (AFP) a highly flexible robotic composites manufacturing technique has the potential to replace filament winding for composite pressure vessel manufacturing and provide pathways for further vessel optimi sation. A combination of both AFP and Type V technology could provide an avenue for a new generation of highperformance composite pressure vessels. This critical review presents key work on industry-standard Type IV vessels alongside the current state of Type V CPV technology including manufacturing developments challenges cost relevance to commercial standards and future fabrication solutions using AFP. Additionally a novel Type V CPV design concept for a two-piece AFP produced vessel is presented.
Pieces of a Jigsaw: Opportunities and Challenges in the Nascent Australian Hydrogen Mobility Market
Mar 2023
Publication
Mobility has been a prominent target for proponents of the hydrogen economy. Given the complexities involved in the mobility value chain actors hoping to participate in this nascent market must overcome a range of challenges relating to the availability of vehicles the co-procurement of supporting infrastructure a favourable regulatory environment and a supportive community among others. In this paper we present a state-of-play account of the nascent hydrogen mobility market in Victoria Australia drawing on data from a workshop (N ¼ 15) and follow-up interviews (n ¼ 10). We interpret findings through a socio-technical framework to understand the ways in which fuel cell electric vehicles (FCEVs)dand hydrogen technologies more generallydare conceptualised by different stakeholder groups and how these conceptualisations mediate engagement in this unfolding market. Findings reveal prevailing efforts to make sense of the FCEV market during a period of considerable institutional ambiguity. Discourses embed particular worldviews of FCEV technologies themselves in addition to the envisioned roles the resultant products and services will play in broader environmental and energy transition narratives. Efforts to bring together stakeholders representing different areas of the FCEV market should be seen as important enablers of success for market participants.
The Synergy Between Battery and Hydrogen Storage in Stand-alone Hybrid Systems: A Parameterised Load Approach
Jun 2025
Publication
Hydrogen is widely considered advantageous for long-duration storage applications however the conditions under which hydrogen outperforms batteries remain unclear. This study employs a novel load parameterisation approach to systematically examine the conditions under which integrating hydrogen significantly reduces the levelised cost of energy (LCOE). The study analyses a broad spectrum of 210 synthetic load profiles varying independently in duration frequency and timing at two Australian locations. This reveals that batteries dominate short frequent or wellaligned solar loads and that hydrogen becomes economically beneficial during prolonged infrequent or poorly aligned loads—achieving up to 122 % (Gladstone) and 97 % (Geelong) LCOE improvements under current fuel cell costs and even higher savings under reduced costs. This systematic method clarifies the load characteristics thresholds that define hydrogen’s advantage providing generalisable insights beyond individual case studies.
Emerging Perovskite-based Catalysts for Sustainable and Green Ammonia Production: A Promosing Hydrogen Energy Carrier
Feb 2025
Publication
Ammonia (NH₃) presents a comprehensive energy storage solution for future energy demands. Its synthesis plays a pivotal role in the chemical industry acting as a fundamental precursor for fertilizers explosives and a wide range of industrial applications. In recent years there has been a growing interest in exploring novel catalyst materials to enhance the efficiency selectivity and sustainability of NH3 production technologies. Among these materials perovskite-based catalysts have emerged as promising candidates due to their unique properties. This review article aims to provide a sharp and short understanding of the role of perovskite-based catalysts in emerging NH3 production technologies and to stimulate further research and innovation in this rapidly evolving field. It provides an overview of recent advances in the synthesis and characterisation of perovskite-based cat alysts for NH3 production in terms of structural properties and catalytic performance of perovskite catalysts in NH3 synthesis. The review also discusses the underlying mechanisms involved in NH3 production on perovskite surfaces highlighting the role of surface chemistry and electronic structure. Furthermore the review examines the potential applications and prospects of perovskite-based catalysts in NH3 production technologies. It explores opportunities for integrating perovskite catalysts into existing NH3 synthesis processes as well as the develop ment of process configurations to maximise the efficiency and sustainability of NH3 production.
Increasing the Efficiency of Water Electrolysis with the Application of Pulsing Electric Fields
Mar 2025
Publication
Due to hydrogen’s beneficial characteristics as a sustainable energy carrier the application of pulsing electric fields has been researched for its effectiveness during water electrolysis. Although there have been conflicting findings on the benefits of the application of pulsing electric fields this research highlights the potential it has to enhance the efficiency of water electrolysis while providing clarity on past discrepancies. This research achieves this by identifying distinctive energy flow profiles that result from various power input waveforms along with subsequent hydrogen production rates and efficiencies while also utilising a novel method of measuring the capacitance of the electrolyte to detect shifts in the molecular energy. The results indicate that pulsing electric fields can increase efficiency by up to 20 % or decrease efficiency by over 40 % depending on the energy flow profiles of the electrical molecular and electrochemical dynamics. Furthermore the use of pulsing electric fields also enabled load adaptability by allowing the electrolyser to operate effectively throughout a range of power inputs. For example the power input could be increased to cause a 279 % increase in hydrogen production without compromising efficiency; while conversely enabling electrolysis at >65 % efficiency using power input levels which were otherwise too low to drive electrochemical reactions. This study provides another step towards making renewable hydrogen viable as a sustainable energy carrier by identifying factors which influence and are influenced by changing electrical molecular and electrochemical dynamics while also providing a foundation for further research into more efficient use of energy to produce hydrogen gas.
Explosions of Hydrogen Storages and the Safety Considerations in Hydrogen-Powered Railway Applications—A Review
Nov 2024
Publication
As one of the most promising clean energy sources hydrogen power has gradually emerged as a viable alternative to traditional energy sources. However hydrogen safety remains a significant concern due to the potential for explosions and the associated risks. This review systematically examines hydrogen explosions with a focus on high-pressure and low-temperature storage transportation and usage processes mostly based on the published papers from 2020. The fundamental principles of hydrogen explosions classifications and analysis methods including experimental testing and numerical simulations are explored. Key factors influencing hydrogen explosions are also discussed. The safety issues of hydrogen power on railway applications are focused and finally recommendations are provided for the safe application of hydrogen power in railway transportation particularly for long-distance travel and heavy-duty freight trains with an emphasis on storage safety considerations.
Uncovering an Emerging Policy Direction for Australian Energy and Future Fuels Using a "Participatory Decision-Making" Framework
Aug 2024
Publication
Introduction: An online deliberative engagement process was undertaken with members of the general public to understand what they value or would like to change about the energy system within the broader context of decarbonizing Australia's energy networks identifying a role for future fuels (hydrogen and biogas). Citizens developed a set of principles that could guide Australia's path toward a low-carbon energy future reflecting on expectations they place upon energy transition. Next citizens' principles were shared with policy-makers in government and policy-influencers from the energy industry using an online interactive workshop.<br/>Methods: This study analyses policy-makers and -influencers response to citizens' guiding principles using the 'diamond of participatory decision-making' framework for analysis. Convergence and divergence in diverse complex and rich views across cohorts and implications thereupon energy policy were identified.<br/>Results: Although considerable alignment between multi-stakeholders' views was noted key areas of divergence or what is called the “groan zone” were easily identified in relation to social and environmental justice issues. This groan zone highlights the struggles that energy policy-makers face -the need to listen and respond to citizens' voices vs. the need for practical and workable policies that also support overarching government or industry objectives.<br/>Discussion: Policy making when the views of different stakeholders align is relatively straightforward. However this is not the case where the expectations diverge. More creative measures will be needed to address divergent views and expectations whilst maintaining procedural fairness in this case using democratic deliberative engagement processes. While the use of deliberative processes is gaining momentum worldwide particularly concerning climate change and energy transition policies this paper also highlights the benefits of conducting a robust post facto analysis of the content of the processes. Areas of alignment where policy can be made and implemented relatively easily without contention are identified. Other areas (such as making electrification mandatory) might be more complex or have unwanted negative social and environmental justice effects. Overall this paper bridges an analytical gap between “expectation studies” and participatory research. By borrowing terminology from a participatory research framework we sharpen the concepts in “expectation studies” from a consensus inclusion and diversity standpoint.
Gas Storage in Geological Formations: A Comparative Review on Carbon Dioxide and Hydrogen Storage
Feb 2024
Publication
Carbon dioxide and hydrogen storage in geological formations at Gt scale are two promising strategies toward net-zero carbon emissions. To date investigations into underground hydrogen storage (UHS) remain relatively limited in comparison to the more established knowledge body of underground carbon dioxide storage (UCS). Despite their analogous physical processes can be used for accelerating the advancements in UHS technology the existing distinctions possibly may hinder direct applicability. This review therefore contributes to advancing our fundamental understanding on the key differences between UCS and UHS through multi-scale comparisons. These comparisons encompass key factors influencing underground gas storage including storage media trapping mechanisms and respective fluid properties geochemical and biochemical reactions and injection scenarios. They provide guidance for the conversion of our existing knowledge from UCS to UHS emphasizing the necessity of incorporating these factors relevant to their trapping and loss mechanisms. The article also outlines future directions to address the crucial knowledge gaps identified aiming to enhance the utilisation of geological formations for hydrogen and carbon dioxide storage.
Hydrogen Diffusion into Water and Cushion Gases - Relevance for Hydrogen Geo-storage
Dec 2024
Publication
Hydrogen (H2) has been recognized as a promising solution to reduce carbon dioxide (CO2) emissions. H2 is considered a green energy carrier for energy storage transport and usage and it can be produced from renewable energy resources (such as solar hydropower and wind energy). However H2 is a highly diffusive compound compared to other natural gases raising concerns about the possibility of H2 loss in geo-storage (e.g. in underground geological formations such as depleted oil/gas reservoirs aquifers or shale formations) or H2 leak via pipelines when blending H2 with natural gas in existing pipeline systems. Thus understanding H2 diffusion in subsurface formations and pipeline systems is vital. However despite its importance only limited data is available to assess the above situations. Therefore in this study molecular dynamics simulations were used to predict the self-diffusion coefficients of H2 in water and cushion gases (CH4 and N2) at relevant geothermal conditions (i.e. 300 K–373 K and pressures up to 50 MPa). The findings showed that H2 self-diffusion in methane and nitrogen increases with increasing temperature but decreases with increasing pressure. However H2 selfdiffusion in water increases with increasing temperature but is not impacted by increasing or decreasing pres sure. The results also indicated that the rate of H2 self-diffusion in cushion gas is faster than in water about exceeding two-digit times. Furthermore the outcomes reported extended or new data on H2 self-diffusion for the binary system of H2–H2O H2–CH4 and H2–N2. This study is beneficial and contributes to assessing efficiency and safety for executing H2 transportation and underground hydrogen storage (UHS) schemes.
A Computational Analysis of Cryogenic Hydrogen Release Under Various Conditions
Dec 2023
Publication
Cryogenic liquid hydrogen offers a promising solution for achieving high-density hydrogen storage and efficient on-site distribution. However the potential hazards associated with hydrogen leakages necessitate thorough investigations. This research aims to model cryogenic hydrogen release from circular and high aspect ratio (HAR) nozzles tested by Sandia. The test conditions cover reservoir pressures and temperatures corresponding to cryogenic hydrogen storage. The study conducts computational simulations using OpenFOAM to examine hydrogen concentration temperature fields mass fraction and temperature distributions achieving good agreement with the experimental data. To further explore the study of velocity variations shows a consistent decay rate with room-temperature jets. The numerical data reveals comparable inverse centreline hydrogen mass fractions (0.254 for HAR and 0.26 for circular) and normalised centreline temperature decay rates (0.031 for HAR and 0.032 for circular). The present computational model holds the potential for further analysis of cryogenic hydrogen in large-scale facilities.
A Theoretical Study on Reversible Solid Oxide Cells as Key Enablers of Cyclic Conversion between Electrical Energy and Fuel
Jul 2021
Publication
Reversible solid oxide cells (rSOC) enable the efficient cyclic conversion between electrical and chemical energy in the form of fuels and chemicals thereby providing a pathway for longterm and high-capacity energy storage. Amongst the different fuels under investigation hydrogen methane and ammonia have gained immense attention as carbon-neutral energy vectors. Here we have compared the energy efficiency and the energy demand of rSOC based on these three fuels. In the fuel cell mode of operation (energy generation) two different routes have been considered for both methane and ammonia; Routes 1 and 2 involve internal reforming (in the case of methane) or cracking (in the case of ammonia) and external reforming or cracking respectively. The use of hydrogen as fuel provides the highest round-trip efficiency (62.1%) followed by methane by Route 1 (43.4%) ammonia by Route 2 (41.1%) methane by Route 2 (40.4%) and ammonia by Route 1 (39.2%). The lower efficiency of internal ammonia cracking as opposed to its external counterpart can be attributed to the insufficient catalytic activity and stability of the state-of-the-art fuel electrode materials which is a major hindrance to the scale-up of this technology. A preliminary cost estimate showed that the price of hydrogen methane and ammonia produced in SOEC mode would be ~1.91 3.63 and 0.48 $/kg respectively. In SOFC mode the cost of electricity generation using hydrogen internally reformed methane and internally cracked ammonia would be ~52.34 46.30 and 47.11 $/MWh respectively.
Evaluation and Outlook for Australian Renewable Energy Export via Circular Liquid Hydrogen Carriers
Oct 2023
Publication
To combat global temperature rise we need affordable clean and renewable energy that does not add carbon to the atmosphere. Hydrogen is a promising option because it can be used as a carbon-free energy source. However storing and transporting pure hydrogen in liquid or gaseous forms is challenging. To overcome the limitations associated with conventional compressed and liquefied hydrogen or physio-chemical adsorbents for bulk storage and transport hydrogen can be attached to other molecules known as hydrogen carriers. Circular carriers which involve the production of CO2 or nitrogen during the hydrogen recovery process include substances such as methanol ammonia or synthetic natural gas. These carriers possess higher gravimetric and volumetric hydrogen densities (i.e. 12.5 wt% and 11.88 MJ/L for methanol) than cyclic carriers (i.e. 6.1 wt% and 5.66 MJ/L for methylcyclohexane (MCH)) which produce cyclic organic chemicals during dehydrogenation. This makes circular carriers particularly appealing for the Australian energy export market. Furthermore the production-decomposition cycle of circular carriers can be made carbon-neutral if they are derived from renewable H2 sources and combined with atmospheric or biomass-based CO2 or nitrogen. The key parameters are investigated in this study focusing on circular hydrogen carriers relevant to Australia. The parameters are ranked from 0 (worst) to 10 (best) depending on the bandwidth of the parameter in this review. Methanol shows great potential as a cost-effective solution for long-distance transport of renewable energy being a liquid at standard conditions with a boiling point of 64.7 °C. Methane is also an important hydrogen carrier due to the availability of natural gas infrastructure and its role as a significant export product for Australia.
Modulating Selectivity and Stability of the Direct Seawater Electrolysis for Sustainable Green Hydrogen Production
Feb 2025
Publication
Direct seawater electrolysis (DSE) has emerged as a compelling route to sustainable hydrogen production leveraging the vast global reserves of seawater. However the inherently complex composition of seawater—laden with halide ions multivalent cations (Mg2+ Ca2+) and organic/biological impurities—presents formidable challenges in maintaining both selectivity and durability. Chief among these obstacles is mitigating chloride corrosion and suppressing chlorine evolution reaction (ClER) at the anode while also preventing the precipitation of magnesium and calcium hydroxides at the cathode. This review consolidates recent advances in material engineering and cell design strategies aimed at controlling undesired side reactions enhancing electrode stability and maximizing energy efficiency in DSE. We first outline the fundamental thermodynamic and kinetic hurdles introduced by Cl⁻ and other impurities. This discussion highlights how these factors accelerate catalyst degradation and drive suboptimal reaction pathways. We then delve into innovative approaches to improve selectivity and durability of DSE—such as engineering protective barrier layers tuning electrolyte interfaces developing corrosion-resistant materials and techniques to minimize Mg/Ca-related precipitations. Finally we explore emerging reactor configurations including asymmetric and membrane-free electrolyzers which address some barriers for DSE commercialization. Collectively these insights provide a framework for designing next-generation DSE systems which can achieve large-scale cost-effective and environmentally benign hydrogen production.
Transient-state Behaviours of Blast Furnace Ironmaking: The Role of Shaft-injected Hydrogen
Aug 2025
Publication
Hydrogen shaft injection into blast furnaces (BFs) has a large potential to eliminate carbon dioxide emissions yet the temporal evolution of thermal and chemical states following shaft-injected hydrogen utilisation has not been reported in the open literature. In this research a recently developed transient-state multifluid BF model is applied to elucidate the temporal evolution of in-furnace phenomena. Besides a domain-average method is adopted to analyse the extensive simulation data to determine the time required to attain the next steady-like state. The results show that the evolution of thermal and chemical conditions varies across different regions with distinct characteristics near the furnace wall. The shifts in iron oxide reduction behaviour are completed within 10 to 20 h after the new operation and the transition time points to the next steady-like states of thermal and chemical conditions are different. As the hydrogen flow rate increases the average transition time decreases. However 2 to 4 days are required for the studied BF to reach a new steady-like state in the considered scenarios. The model offers a cost-effective approach to investigating the transient smelting characteristics of an ironmaking BF with hydrogen injection.
Sustainable Aviation Fuels: Addressing Barriers to Global Adoption
Oct 2025
Publication
The aviation industry is responsible for approximately 2–3% of worldwide CO2 emissions and is increasingly subjected to demands for the attainment of net-zero emissions targets by the year 2050. Traditional fossil jet fuels which exhibit lifecycle emissions of approximately 89 kg CO2-eq/GJ play a substantial role in exacerbating climate change contributing to local air pollution and fostering energy insecurity. In contrast Sustainable Aviation Fuels (SAFs) derived from renewable feedstocks including biomass municipal solid waste algae or through CO2- and H2-based power-to-liquid (PtL) represent a pivotal solution for the immediate future. SAFs generally accomplish lifecycle greenhouse gas (GHG) reductions of 50–80% (≈20–30 kg CO2-eq/GJ) possess reduced sulfur and aromatic content and markedly diminish particulate emissions thus alleviating both climatic and health-related repercussions. In addition to their environmental advantages SAFs promote energy diversification lessen reliance on unstable fossil fuel markets and invigorate regional economies with projections indicating the creation of up to one million green jobs by 2030. This comprehensive review synthesizes current knowledge on SAF sustainability advantages compared to conventional aviation fuels identifying critical barriers to large-scale deployment and proposing integrated solutions that combine technological innovation supportive policy frameworks and international collaboration to accelerate the aviation industry’s sustainable transformation.
Quantifying Natural Hydrogen Generation Rates and Volumetric Potential in Onshore Serpentinization
Mar 2025
Publication
This study explores the generation of natural hydrogen through the serpentinization of onshore ultramafic rocks highlighting its potential as a clean energy resource. By investigating critical factors such as mineral composition temperature and pressure the research develops an empirical model using multiple regression analysis to predict hydrogen generation rates under varying geological conditions. A novel five-stage volumetric calculation methodology is introduced to estimate hydrogen production from ultramafic rock bodies. The application of this framework to the Giles Complex an ultramafic-mafic intrusion in Australia suggests a hydrogen generation potential of approximately 2.24 × 1013 kg of hydrogen through partial serpentinization. This estimate is based on the assumed mineral composition depth and temperature conditions within the intrusion which influence the extent of serpentinization reactions. The findings demonstrate the significant potential of ultramafic complexes for natural hydrogen production and provide a foundation for advancing natural hydrogen exploration refining predictive models and supporting sustainable energy development.
Hydrogen Storage Potential of Unlined Granite Rock Caverns: Experimental and Numerical Investigations on Geochemical Interactions
Jun 2025
Publication
Underground Hydrogen Storage (UHS) offers a promising solution for large-scale energy storage yet suitable geological formations are often scarce. Unlined rock caverns (URCs) constructed in crystalline rocks like granite present a novel alternative particularly in regions where salt caverns or porous media are unsuitable. Despite their potential URCs remain largely unexplored for hydrogen storage. This study addresses this gap by providing one of the first comprehensive investigations into the geochemical interactions between hydrogen and granite host rock using a combined experimental and numerical approach. Granite powder samples were exposed to hydrogen and inert gas (N₂) in brine at room temperature and 5 MPa pressure for 14 weeks. Results showed minimal reactivity of silicate minerals with hydrogen indicated by negligible differences in elemental concentrations between H₂ and N₂ atmospheres. A validated geochemical model demonstrated that existing thermodynamic databases can accurately predict silicate‑hydrogen interactions. Additionally a kinetic batch model was developed to simulate long-term hydrogen storage under commercial URC conditions at Haje. The model predicts a modest 0.65 % increase in mineral volume over 100 years due to mineral precipitation which decreases net porosity and potentially enhances hydrogen containment by limiting leakage pathways. These findings support the feasibility of granite URCs for UHS providing a stable long-term storage option in regions lacking traditional geological formations. By filling a critical knowledge gap this study advances scalable hydrogen storage solutions contributing to the development of resilient renewable energy infrastructure.
Feasibility Assessment and Response Surface Optimisation of a Fuel Cell-integrated Sustainable Wind Farm in Italy
Sep 2025
Publication
This study explores the design and feasibility of a novel fuel cell-powered wind farm for residential electricity hydrogen/oxygen production and cooling/heating via a compression chiller. Wind turbine energy powers Proton Exchange Membrane (PEM) electrolyzers and a compression chiller unit. The proposed system was modeled using EES thermodynamic software and its economic viability was assessed. A case study across seven Italian regions with varying wind potentials evaluated the system’s feasibility in diverse weather conditions. Multi-objective optimization using Response Surface Methodology (RSM) determined the number of wind turbines as optimum number of electrolyzers & fuel cell units. Optimization results indicated that 37 wind turbines 1 fuel cell unit and 2 electrolyzer units yielded an exergy efficiency of 27.98 % and a cost rate of 619.9 $/h. TOPSIS analysis suggested 32 wind turbines 2 electrolyzers and 2 reverse osmosis units as an alternative configuration. Further twelve different scenarios were examined to enhance the distribution of wind farmgenerated electricity among the grid electrolyzers and reverse osmosis systems. revealing that directing 25 % to reverse osmosis 20 % to electrolyzers and 55 % to grid sales was optimal. Performance analysis across seven Italian cities (Turin Bologna Florence Palermo Genoa Milan and Rome) identified Genoa Palermo and Bologna as the most suitable locations due to favorable wind conditions. Implementing the system in Genoa the optimal site could produce 28435 MWh of electricity annually prevent 5801 tons of CO2 emissions (equivalent to 139218 $). Moreover selling this clean electricity to the grid could meet the annual clean electricity needs of approximately 5770 people in Italy
Towards Decarbonizing Gas: A Generic Optimal Gas Flow Model with Linepack Constraints for Assessing the Feasibility of Hydrogen Blending in Existing Gas Networks
Aug 2025
Publication
Hydrogen blending into natural gas networks is a promising pathway to decarbonize the gas sector but requires bespoke fluid-dynamic models to accurately capture the properties of hydrogen and assess its feasibility. This paper introduces a generalizable optimal transient gas flow model for transporting homogeneous natural gashydrogen mixtures in large-scale networks. Designed for preliminary planning the model assesses whether a network can operate under a given hydrogen blending ratio without violating existing constraints such as pressure limits pipeline and compressor capacity. A distinguishing feature of the model is a multi-day linepack management strategy that engenders realistic linepack profiles by precluding mathematically feasible but operationally unrealistic solutions thereby accurately reflecting the flexibility of the gas system. The model is demonstrated on Western Australia’s 7560 km transmission network using real system topology and demand data from several representative days in 2022. Findings reveal that the system can accommodate up to 20 % mol hydrogen potentially decarbonizing 7.80 % of gas demand.
Sustainable Aviation Fuels: A Review of Current Techno Economic Viability and Life Cycle Impacts
Oct 2025
Publication
Australia has set a new climate target of reducing emissions by 62–70% below 2005 levels by 2035 with sustainable aviation fuel (SAF) central to achieving this goal. This review critically examines techno-economic analysis (TEA) and life cycle assessment (LCA) of Powerto-Liquid (PtL) electrofuels (e-fuels) which synthesize atmospheric CO2 and renewable hydrogen (H2) via Fischer-Tropsch (FT) synthesis. Present PtL pathways require ~0.8 kg of H2 and 3.1 kg of CO2 per kg SAF with ~75% kerosene yield. While third-generation feedstocks could cut greenhouse gas emissions by up to 93% (as low as 8 gCO2e/MJ) real world reductions have been limited (~1.5%) due to variability in technology rollout and feedstock variability. Integrated TEA–LCA studies demonstrate up to 20% energy efficiency improvements and 40% cost reductions but economic viability demands costs below $3/kg. In Australia abundant solar resources vast transport networks and supportive policy frameworks present both opportunities and challenges. This review provides the first comprehensive assessment of PtL-FT SAF for Australian conditions highlighting that large-scale development will require technological advancement feedstock development infrastructure investment and coordinated policy support.
Influence of Hydrogen-Based Direct Reduction Shaft Furnace Interior Structure on Shaft Furnace Performance
Oct 2025
Publication
Hydrogen-based direct reduction of iron ore is a promising route to reduce CO2 emissions in steelmaking where uniform particle flow inside shaft furnaces is essential for efficient operation. In this study a full-scale three-dimensional Discrete Element Method (DEM) model of a shaft furnace was developed to investigate the effects of a diverter device on granular flow. By systematically varying the radial width and top/bottom diameters of the diverter particle descent velocity residence time compressive force distribution and collision energy dissipation were analyzed. The results demonstrate that introducing a diverter effectively suppresses funnel flow prolongs residence time and improves radial flow uniformity. Among the tested configurations the smaller central diameter diverter showed the most favorable performance achieving a faster and more uniform descent reduced compressive force concentration and lower collision energy dissipation. These findings highlight the critical role of diverter design in regulating particle dynamics and provide theoretical guidance for optimizing shaft furnace structures to enhance the efficiency of hydrogen-based direct reduction processes.
Zero-emission Traction for Rail
Jul 2025
Publication
Replacing the energy density and convenience of diesel fuel for all forms of fossil fuel-powered trains presents significant challenges. Unlike the traditional evolutions of rail which has largely self-optimised to different fuels and cost structures over 150 years the challenges now present with a timeline of just a few decades. Fortunately unlike the mid-1800s simulation and modelling tools are now quite advanced and a full range of scenarios of operations and train trips can be simulated before new traction systems are designed. Full trip simulations of large heavy haul trains or high speed passenger trains are routinely completed controlled by emulations of human drivers or automated control systems providing controls of the “virtual train”. Recent developments in digital twins can be used to develop flexible and dynamic models of passenger and freight rail systems to support the new complexities of decarbonisation efforts. Interactions between many different traction components and the train multibody system can be considered as a system of systems. Adopting this multi-modelling paradigm enables the secure and integrated interfacing of diverse models. This paper demonstrates the application of the multi-modelling approach to develop digital twins for rail decarbonisation traction and it presents physics-based multi-models that include key components required for studying rail decarbonisation problems. Specifically the challenge of evaluating zero-emission options is addressed by adding further layers of modelling to the existing fully detailed multibody dynamics simulations. The additional layers detail control options energy storage the alternate traction system components and energy management systems. These traction system components may include both electrical system and inertia dynamics models to accurately represent the driveline and control systems. This paper presents case study examples of full trip scenarios of both long haul freight trains and higher speed passenger trains. These results demonstrate the many complex scenarios that are difficult to anticipate. Flowing on from this risks can be assessed and practical designs of zero-emission systems can be proposed along with the required recharging or refuelling systems.
Techno-economic and Environmental Optimization of Hydrogen-based Hybrid Energy Systems for Remote Off-grid Australian Communities
Jun 2025
Publication
This study presents a techno-economic and environmental optimization of hydrogen-based hybrid energy systems (HESs) for Broken Hill City Council in New South Wales Australia. Two configurations are evaluated: Configuration 1 includes solar PV battery fuel cell electrolyzer and hydrogen storage while Configuration 2 includes solar PV fuel cell electrolyzer and hydrogen storage but excludes the battery. The system is optimized using advanced metaheuristic algorithms such as Harris Hawks Algorithm (HHA) Red-Tailed Hawk Algorithm and Non-Dominated Sorting Genetic Algorithm-II while ensuring real-time supply–demand balance and system stability through a robust energy management strategy. This integrated approach simultaneously determines the optimal sizes of PV arrays battery storage (where applicable) fuel cells electrolyzers and hydrogen storage units and maintains reliable energy supply. Results show that HHA Configuration 1 achieves the lowest net present cost of $338111 a levelized cost of electricity of $0.185/kWh and a levelized cost of hydrogen of $4.60/kg. Sensitivity analysis reveals that PV module and hydrogen storage costs significantly impact system economics while improving fuel cell efficiency from 40% to 60% can reduce costs by up to 40%. Beyond cost-effectiveness life cycle analysis demonstrates annual CO2 emission reductions exceeding 500000 kg compared to an equivalent diesel generator system meeting the same load demand. Socio-economic assessments further indicate that the HES can support improvements in the Human Development Index by enhancing access to healthcare education and economic opportunities while also creating local jobs in PV installation battery maintenance and hydrogen infrastructure. These findings establish hydrogen-based HES as a scalable cost-effective and environmentally sustainable solution for energy access in remote areas.
Catalytic Hydrogen Combustion as Heat Source for the Dehydrogenation of Liquid Organic Hydrogen Carriers using a Novel Compact Autothermal Reactor
Sep 2025
Publication
The experimental performance of an autothermal hydrogen release unit comprising a perhydro benzyltoluene (H12-BT) dehydrogenation chamber and a catalytic hydrogen combustion (CHC) chamber in thermal contact is discussed. In detail the applied set-up comprised a multi-tubular CHC heating based on seven parallel tubes with the reactor shell containing a commercial dehydrogenation catalyst. In this way the CHC heated the endothermal LOHC dehydrogenation using a part of the hydrogen generated in the dehydrogenation. The proposed heating concept for autothermal LOHC dehydrogenation offers several advantages over state-of-the-art heating concepts including minimized space consumption high efficiency and zero NOx emissions. During performance tests the process reached a minimum hydrogen combustion fraction of 37 % while the minimum heat requirement for the dehydrogenation reaction for industrial scale plants is 33 %. The reactor orientation (vertical vs horizontal) and the flow configuration (counter-current vs. co-current) showed very little influence on the performance demonstrating the robustness of the proposed reactor design.
Artificial Intelligence-based Multi-objective Optimization of a Solar-driven System for Hydrogen Production with Integrated Oxygen and Power Co-generation Across Different Climates
Oct 2025
Publication
This study develops and optimizes a solar-powered system for hydrogen generation with oxygen and power coproducts addressing the need for efficient scalable carbon-free energy solutions. The system combines a linear parabolic collector a Steam Rankine cycle and a Proton Exchange Membrane Electrolyzer (PEME) to produce electricity for electrolysis. Thermodynamic modeling was accomplished in Engineering Equation Solver while a hybrid Artificial Intelligence (AI) framework combining Artificial Neural Networks and Genetic Algorithms in Statistica coupled with Technique for Order Preference by Similarity to Ideal Solution (TOPSIS) decision support optimized technical and economic performance. Optimization considered seven key decision variables covering collector design thermodynamic inputs and component efficiencies. The optimization achieved energy and exergy efficiencies of 30.83 % and 26.32 % costing 47.02 USD/h and avoiding CO2 emissions equivalent to 190 USD/ton. Economic and exergy analyses showed the solar and hydrogen units had the highest costs (38.17 USD/h and 9.61 USD/h) with 4503 kWh of exergy destruction to generate 575 kWh of electricity. A case study across six cities suggested that Perth Bunbury and Adelaide with higher solar irradiance delivered the highest annual power and hydrogen outputs consistent with irradiance–electrolyzer correlation. Unlike conventional single-site studies this work delivers a climate-responsive multi-city analysis integrating solar thermal and PEME within an AI-driven framework. By linking techno-economic performance with quantified environmental value and co-production synergies of hydrogen oxygen and electricity the study highlights a novel pathway for scalable clean hydrogen measurable CO2 reductions and global decarbonization with future work focused on digital twins and dynamic uncertainty-aware optimization.
Overcoming Hurdles and Harnessing the Potential of the Hydrogen Transition in Germany
Jun 2025
Publication
Green hydrogen has become a core element of Europe’s energy transition to assist in lowering carbon emissions. However the transition to green hydrogen faces challenges including the cost of production availability of renewable energy sources public opposition and the need for supportive government policies and financial initiatives. While there are other alternatives for producing low-carbon hydrogen for example blue hydrogen German funding favours projects that involve hydrogen production via electrolysis. Beyond climate goals it is anticipated that a green hydrogen industry will create economic benefits and a wide-range of collaborative opportunities with key international partnerships increasing energy security if done appropriately. Germany a leader in green hydrogen technology will need to rely on imports to meet long-term demand due to limited renewable energy capacity. Despite the current obstacles to transitioning to green hydrogen it is felt that ultimately the benefits of this industry and reducing emissions will outweigh the associated costs of production. This study analyses the hydrogen transition in Germany by interviewing 37 European experts guided by the research question: What are the key perceived barriers and opportunities influencing the successful adoption and integration of hydrogen technologies in Germany’s hydrogen transition?
Effect of Injection Timing on Gas Jet Developments in a Hydrogen Low-pressure Direct-injection Spark-ignition Engine
Sep 2025
Publication
Injection timing in low-pressure hydrogen direct injection (H2LPDI) engines plays a critical role in optimising gas jet structure and mixture formation due to the complex and transient nature of ambient air flow and density inside the cylinder. This study systematically investigates the macroscopic characteristics of gas jet development at five distinct injection timings from 210 to 120 ◦CA bTDC with the intake valve closure (IVC) as a reference point in a motored inline four-cylinder spark-ignition engine at 2000 rpm and 160 Nm load using low-pressure injection of 3.5 MPa. Optical access was made with two endoscopes: one for high-speed imaging and the other for laser insertion to realise laser shadowgraph imaging of the gas jet delivered using a side-mounted outwardopening pintle nozzle injector. The experimental results reveal spatial and temporal variations in jet morphology penetration spreading angle and mixture dispersion as a function of injection timing. Pre-IVC injection (210 ◦CA bTDC) produced a narrow mean cone angle of ~40◦ and the highest penetration-rate proxy (0.49) whereas postIVC injection (120 ◦CA bTDC) retained a wider ~53◦ cone yet reduced the penetration rate to 0.28 while increasing the sheet-based mixing index from − 0.084 to − 0.106. Pre-IVC injection occurring under low ambient pressure and with active intake airflow was found to produce elongated jets with enhanced penetration and mixing rates though accompanied by substantial cyclic variations. Conversely post-IVC injection was strongly influenced by a fully developed tumble flow which redirected the jet trajectory towards the pent-roof and facilitated mixing through increased turbulence. However the elevated air density constrained the jet penetration. At-IVC injection resulted in a more uniform and stable jet structure. However the lack of convective flow constrained the overall mixing effectiveness. Quantitative analysis of jet spreading angle pixel intensity gradient and centroid movement using 100 consecutive cycles confirms the critical role of injection timing in shaping the gas jet development as suggested by the images.
Mitigating Microbial Artifacts in Laboratory Research on Underground Hydrogen Storage
Jul 2025
Publication
The global energy sector is aiming to substantially reduce CO2 emissions to meet the UN climate goals. Among the proposed strategies underground storage solutions such as radioactive disposal CO2 NH3 and underground H2 storage (UHS) have emerged as promising options for mitigating anthropogenic emissions. These approaches require rigorous research and development (R&D) often involving laboratory-scale experiments to establish their feasibility before being scaled up to pilot plant operations. Microorganisms which are ubiquitous in laboratory environments can significantly influence geochemical reactions under variable experimental conditions of porous media and a salt cavern. We have selected a consortium composed of Bacillus sp. Enterobacter sp. and Cronobacter sp. bacteria which are typically present in the laboratory environment. These microorganisms can contaminate the rock sample and develop experimental artifacts in UHS experiments. Hence it is pivotal to sterilize the rock prior to conduct experimental research related to effects of microorganisms in the porous media and the salt cavern for the investigation of UHS. This study investigated the efficacy of various disinfection and sterilization methods including ultraviolet irradiation autoclaving oven heating ethanol treatments and gamma irradiation in removing the microorganisms from silica sand. Additionally the consideration of their effects on mineral properties are reviewed. A total of 567 vials each filled with 9 mL of acid-producing bacteria (APB) media were used to test killing efficacy of the cleaning methods. We conducted serial dilutions up to 10−8 and repeated them three times to determine whether any deviation occurred. Our findings revealed that gamma irradiation and autoclaving were the most effective techniques for eradicating microbial contaminants achieving sterilization without significantly altering the mineral characteristics. These findings underscore the necessity of robust cleaning protocols in hydrogeochemical research to ensure reliable reproducible data particularly in future studies where microbial contamination could induce artifacts in laboratory research.
Modeling Porosity Distribution Strategies in PEM Water Electrolyzers: A Comparative Analytical and Numerical Study
Jun 2025
Publication
Proton exchange membrane water electrolyzers (PEMWEs) are a promising technology for green hydrogen production. However the adoption of PEMWE-based hydrogen production systems remains limited due to several challenges including high material costs limited performance and durability and difficulties in scaling the technology. Computational modeling serves as a powerful tool to address these challenges by optimizing system design improving material performance and reducing overall costs thereby accelerating the commercial rollout of PEMWE technology. Despite this conventional models often oversimplify key components such as porous transport and catalyst layers by assuming constant porosity and neglecting the spatial heterogeneity found in real electrodes. This simplification can significantly impact the accuracy of performance predictions and the overall efficiency of electrolyzers. This study develops a mathematical framework for modeling variable porosity distributions—including constant linearly graded and stepwise profiles—and derives analytical expressions for permeability effective diffusivity and electrical conductivity. These functions are integrated into a three-dimensional multi-domain COMSOL simulation to assess their impact on electrochemical performance and transport behavior. The results reveal that although porosity variations have minimal effect on polarization at low voltages they significantly influence internal pressure species distribution and gas evacuation at higher loads. A notable finding is that reversing stepwise porosity—placing high porosity near the membrane rather than the channel—can alleviate oxygen accumulation and improve current density. A multi-factor comparison highlights this reversed configuration as the most favorable among the tested strategies. The proposed modeling approach effectively connects porous media theory and systemlevel electrochemical analysis offering a flexible platform for the future design of porous electrodes in PEMWE and other energy conversion systems.
Machine Learning-driven Stochastic Bidding for Hydrogen Refueling Station-integrated Virtual Power Plants in Energy Market
Aug 2025
Publication
Virtual power plants (VPPs) are gaining significance in the energy sector due to their capacity to aggregate distributed energy resources (DERs) and optimize energy trading. However their effectiveness largely depends on accurately modeling the uncertain parameters influencing optimal bidding strategies. This paper proposes a deep learning-based forecasting method to predict these uncertain parameters including solar irradiation temperature wind speed market prices and load demand. A stochastic programming approach is introduced to mitigate forecasting errors and enhance accuracy. Additionally this research assesses the flexibility of VPPs by mapping the flexible regions to determine their operational capabilities in response to market dynamics. The study also incorporates power-to‑hydrogen (P2H) and hydrogen-to-power (H2P) conversion processes to facilitate the integration of hydrogen fuel cell vehicles (HFCVs) into VPPs enhancing both technical and economic aspects. A network-aware VPP connected to generation resources storage facilities demand response programming (DRP) vehicle-to-grid technology (V2G) P2H and H2P is used to evaluate the proposed method. The problem is formulated as a convex model and solved using the GUROBI optimizer. Results indicate that a hydrogen refueling station can increase profits by approximately 49 % compared to the base case of directly selling surplus generation from renewable energy sources (RESs) to the market and profits can further increase to roughly 86 % when other DERs are incorporated alongside the hydrogen refueling station.
Early Transition to Near-zero Emissions Electricity and Carbon Dioxide Removal is Essential to Achieve Net-zero Emissions at a Low Cost in Australia
Aug 2025
Publication
Achieving net-zero emissions requires major changes across a nation’s economy energy and land systems particularly due to sectors where emissions are difficult to eliminate. Here we adapt two global scenarios from the International Energy Agency—the net-zero emissions by 2050 and the Stated Policies Scenario—using an integrated numerical economic-energy model tailored to Australia. We explore how emissions may evolve by sector and identify key technologies for decarbonisation. Our results show that a rapid shift to near-zero emissions electricity is central to reducing costs and enabling wider emissions reductions. From 2030 onwards carbon removal through land management and engineered solutions such as direct air capture and bioenergy with carbon capture and storage becomes critical. Australia is also well-positioned to become a global supplier of clean energy such as hydrogen made using renewable electricity helping reduce emissions beyond its borders.
Hydrogen Energy Systems for Decarbonizing Smart Cities and Industrial Applications: A Review
Oct 2025
Publication
Hydrogen is increasingly recognized as a key energy vector for achieving deep decarbonization across urban and industrial sectors. Supporting global efforts to reduce greenhouse gas (GHG) emissions and achieve the Sustainable Development Goals (SDGs) it is essential to understand the multi-sectoral role of the hydrogen value chain spanning production storage and end-use applications with particular emphasis on smart city systems and industrial processes. Green hydrogen production technologies including alkaline water electrolysis (AWE) proton exchange membrane (PEM) electrolysis anion exchange membrane (AEM) electrolysis and solid oxide electrolysis cells (SOECs) are evaluated in terms of efficiency scalability and integration potential. Storage pathways are examined across physical storage (compressed gas cryo-compressed and liquid hydrogen) material-based storage (solid-state absorption in metal hydrides and chemical carriers such as LOHCs and ammonia) and geological storage (salt caverns depleted gas reservoirs and deep saline aquifers) highlighting their suitability for urban and industrial contexts. In the smart city domain hydrogen is analyzed as an enabler of zero-emission transportation low-carbon residential and commercial heating and renewable-integrated smart grids with long-duration storage capabilities. System-level studies demonstrate that coordinated integration of these applications can deliver higher overall energy efficiency deeper reductions in life-cycle GHG emissions and improved resilience of urban energy systems compared with sector-specific approaches. Policy frameworks safety standards and digitalization strategies are reviewed to illustrate how hydrogen infrastructure can be embedded into interconnected urban energy systems. Furthermore industrial applications focus on hydrogen’s potential to decarbonize energy-intensive processes and enable sector coupling between electricity heat and manufacturing. The environmental implications of hydrogen deployment are also considered including resource efficiency life-cycle emissions and ecosystem impacts. In contrast to reviews addressing isolated aspects of hydrogen technologies this study synthesizes technological infrastructural and policy dimensions integrating insights from over 400 studies to highlight the multifaceted role of hydrogen in sustainable urban development and industrial decarbonization and the added benefits achievable through coordinated cross-sector deployment strategies.
AI Predictive Simulation for Low-Cost Hydrogen Production
Jul 2025
Publication
Green hydrogen produced through renewable-powered electrolysis has the potential to revolutionize energy systems; however its widespread adoption hinges on achieving competitive production costs. A critical challenge lies in optimising the hydrogen production process to address solar and wind energy’s high variability and intermittency. This paper explores the role of artificial intelligence (AI) in reducing and streamlining hydrogen production costs by enabling advanced process optimisation focusing on electricity cost management and system-wide efficiency improvements.
Opportunities and Challenges of Latent Thermal Energy Usage in the Hydrogen Economy
Aug 2025
Publication
Hydrogen plays a key role in decarbonising hard-to-abate sectors like aviation steel and shipping. However producing pure hydrogen requires significant energy to break chemical bonds from its sources such as gas and water. Ideally the energy used for this process should match the energy output from hydrogen but in reality energy losses occur at various stages of the hydrogen economy—production packaging delivery and use. This results in needing more energy to operate the hydrogen economy than it can ultimately provide. To address this passive power sources like latent thermal energy storage systems can help reduce costs and improve efficiency. These systems can enable passive cooling or electricity generation from waste heat cutting down on the extra energy needed for compression liquefaction and distribution. This study explores integrating latent thermal energy storage into all stages of the hydrogen economy offering a cost and sizing approach for such systems. The integration could reduce costs close the waste-heat recycling loop and support green hydrogen production for achieving NetZero by 2050.
Offshore Renewable Hydrogen Potential in Australia: A Techno-economic and Legal Review
Jun 2025
Publication
Hydrogen is increasingly recognised as a potential critical energy carrier in decarbonising global energy systems. Australia is positioning itself as a potential leader in offshore renewable hydrogen production by leveraging existing liquified natural gas export infrastructure activating its abundant renewable energy resources and harnessing its extensive offshore marine acreage. Despite this there is limited research on the techno-economic and regulatory pathways for offshore hydrogen development in Australia as an enabler of its net zero manufacturing and export ambitions. This study offers a multidisciplinary assessment and review of Australia’s offshore renewable hydrogen potential. It aims to examine the technical legal and economic challenges and opportunities to enable and adapt the existing Australian offshore electricity regulatory regime and enable policy to facilitate future renewable offshore hydrogen licensing and production. Overall the findings provide practical insights for advancing Australia’s offshore hydrogen transition including technical innovations needed to scale offshore wind development. The study demonstrates how a specific offshore hydrogen licensing framework could reduce legal uncertainties to create economies of scale and reduce hydrogen investment risk to unlock the full potential of developing offshore renewable hydrogen projects.
Proactive Regulation for Hydrogen Supply Chains: Enhancing Logistics Frameworks in Australia
Jun 2025
Publication
The rapid growth of Australia’s hydrogen economy highlights the pressing need for innovative regulatory strategies that address the distinct characteristics of hydrogen supply chains. This study focuses on the supply-side dynamics of the hydrogen energy sector emphasizing the importance of tailored frameworks to ensure the safe efficient and reliable movement of hydrogen across the supply chain. Key areas of analysis include the regulatory challenges associated with various transportation and storage methods particularly during long-distance transport and extended storage periods. The research identifies notable gaps and inconsistencies within the current regulatory systems across Australian states which inhibit the development of a unified hydrogen economy. To address these challenges the concept of Proactive Regulation for Hydrogen Supply (PRHS) is introduced. PRHS emphasizes anticipatory governance that adapts alongside technological advancements to effectively manage hydrogen transportation and storage. The study advocates for harmonizing fragmented state frameworks into a cohesive national regulatory system to support the sustainable and scalable expansion of hydrogen logistics. Furthermore the paper examines the potential of blockchain technology to enhance safety accountability and traceability across the hydrogen supply chain offering practical solutions to current regulatory and operational barriers.
Hydrogen Production from Dry Reforming in Australia: Applications, Opportunities, Challenges
Aug 2025
Publication
Australia’s path to net-zero emissions by 2050 depends heavily on the development and commercialisation of hydrogen as a substitute for hydrocarbons across transport power generation and industrial heat sectors. With hydrocarbons currently supplying over 90% of national energy needs hydrogen must scale rapidly to fill the gap. Existing low-carbon hydrogen production methods blue hydrogen via steam methane reforming and green hydrogen via electrolysis are constrained by high water requirements posing a challenge in water-scarce regions targeted for hydrogen development. This paper investigates dry reforming of methane (DRM) as a water-independent alternative using CO₂ as a reactant. DRM offers dual benefits: reduced reliance on freshwater resources and the utilisation of CO₂ supporting broader emissions reduction goals. Recent improvements in nickel-copper catalyst performance enhance the viability of DRM for industrial-scale hydrogen production. The Middle Arm Precinct in the Northern Territory is highlighted as an ideal site for implementation given its access to offshore gas fields containing both methane and CO₂ presenting a unique opportunity for resource-integrated low-emission hydrogen production.
Preliminary Feasibility Study of Using Hydrogen as a Fuel for an Aquaculture Vessel in Tasmania, Australia
Oct 2025
Publication
Decarbonising aquaculture support vessels is pivotal to reducing greenhouse gas (GHG) emissions across both the aquaculture and maritime sectors. This study evaluates the technical and economic feasibility of deploying hydrogen as a marine fuel for a 14.95 m net cleaning vessel (NCV) operating in Tasmania Australia. The analysis retains the vessel’s original layout and subdivision to enable a like-for-like comparison between conventional diesel and hydrogen-based systems. Two options are evaluated: (i) replacing both the main propulsion engines and auxiliary generator sets with hydrogen-based systems— either proton exchange membrane fuel cells (PEMFCs) or internal combustion engines (ICEs); and (ii) replacing only the diesel generator sets with hydrogen power systems. The assessment covers system sizing onboard hydrogen storage integration operational constraints lifecycle cost and GHG abatement. Option (i) is constrained by the sizes and weights of PEMFC systems and hydrogen-fuelled ICEs rendering full conversion unfeasible within current spatial and technological limits. Option (ii) is technically feasible: sixteen 700 bar cylinders (131.2 kg H2 total) meet one day of onboard power demand for net-cleaning operations with bunkering via swap-and-go skids at the berth. The annualised total cost of ownership for the PEMFC systems is 1.98 times that of diesel generator sets while enabling annual CO2 reductions of 433 t. The findings provide a practical decarbonisation pathway for small- to medium-sized service vessels in niche maritime sectors such as aquaculture while clarifying near-term trade-offs between cost and emissions.
Carbon Emission Reduction Capability Analysis of Electricity–Hydrogen Integrated Energy Storage Systems
Oct 2025
Publication
Against the dual backdrop of intensifying carbon emission constraints and the large-scale integration of renewable energy integrated electricity–hydrogen energy systems (EH-ESs) have emerged as a crucial technological pathway for decarbonising energy systems owing to their multi-energy complementarity and cross-scale regulation capabilities. This paper proposes an operational optimisation and carbon reduction capability assessment framework for EH-ESs focusing on revealing their operational response mechanisms and emission reduction potential under multi-disturbance conditions. A comprehensive model encompassing an electrolyser (EL) a fuel cell (FC) hydrogen storage tanks and battery energy storage was constructed. Three optimisation objectives—cost minimisation carbon emission minimisation and energy loss minimisation—were introduced to systematically characterise the trade-offs between economic viability environmental performance and energy efficiency. Case study validation demonstrates the proposed model’s strong adaptability and robustness across varying output and load conditions. EL and FC efficiencies and costs emerge as critical bottlenecks influencing system carbon emissions and overall expenditure. Further analysis reveals that direct hydrogen utilisation outperforms the ‘electricity–hydrogen–electricity’ cycle in carbon reduction providing data support and methodological foundations for low-carbon optimisation and widespread adoption of electricity–hydrogen systems.
Mapping Hydrogen Demand for Heavy-duty Vehicles: A Spatial Disaggregation Approach
Jul 2025
Publication
Hydrogen is the key to decarbonising heavy-duty transport. Understanding the distribution of hydrogen demand is crucial for effective planning and development of infrastructure. However current data on future hydrogen demand is often coarse and aggregated limiting its utility for detailed analysis and decision-making. This study developed a spatial disaggregation approach to estimating hydrogen demand for heavy-duty trucks and mapping the spatial distribution of hydrogen demand across multiple scales in Australia. By integrating spatial datasets with economic factors market penetration rates and technical specifications of hydrogen fuel cell vehicles the approach disaggregates the projected demand into specific demand centres allowing for the mapping of regional hydrogen demand patterns and the identification of key centres of hydrogen demand based on heavy-duty truck traffic flow projections under different scenarios. This approach was applied to Australia and the findings offered valuable insights that can help policymakers and stakeholders plan and develop hydrogen infrastructure such as optimising hydrogen refuelling station locations and support the transition to a low-carbon heavy-duty transport sector.
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