Denmark
Techno-economic Evaluation of Retrofitting Power-to-methanol: Grid-connected Energy Arbitrage vs Standalone Renewable Energy
Aug 2025
Publication
The power-to-methanol (PtMeOH) will play a crucial role as a form of renewable chemical energy storage. In this paper PtMeOH techno-economics are assessed using the promising configuration from the previous work (Mbatha et al. [1]). This study evaluated the effect of parameters such as the CO2 emission tax electricity price and CAPEX reduction on the product methanol economic parity with respect to a reference case. Superior to previous economic studies a scenario where an existing methanol synthesis infrastructure is 100 % retrofitted with the promising electrolyser is assessed in terms of its economics and the associated economic parity. The volatile South African electricity market is considered as a case study. The sensitivity of the PtMeOH and green H2 profitability are checked. Grid-connected and standalone renewable energy PtMeOH scenarios are assessed. Foremost generalisable effect trends of these parameters on the net present value (NPV) and the levelized cost of methanol(LCOMeOH) and H2 (LCOH2) are discussed. The results show that economic parity of H2 (LCOH2 = current selling price = 4.06 €/kg) can be reached with an electricity price of 30 €/MWh and 70 % of the CAPEX. While the LCOMeOH will still be above 2 €/kg at 80 % of the CAPEX and electricity price of 20 €/MWh. This indicates that even if the CAPEX reduces to 20 % of its original in this study and the electricity price reduces to about 20 €/MWh the LCOMEOH will still not reach economic parity (LCOMeOH > current selling price = 0.44 €/kg). The results show that to make the retrofitted plant with a minimum of 20 years of life span profitable a feasible reduction in the electricity price to below 10 €/MWh along with favourable incentives such as CO2 credit and reduction in CAPEX particularly that of the electrolyser and treatment of the PtMeOH as a multiproduct plant will be required.
Green Hydrogen Techno-economic Assessments from Simulated and Measured Solar Photovoltaic Power Profiles
Nov 2024
Publication
Studies estimating the production cost of hydrogen-based fuels known as e-fuels often use renewable power profile time series obtained from open-source simulation tools that rely on meteorological reanalysis and satellite data such as Renewables.ninja or PVGIS. These simulated time series contain errors compared to real on-site measured data which are reflected in e-fuels cost estimates plant design and operational performance increasing the risk of inaccurate plant design and business models. Focusing on solar-powered e-fuels this study aims to quantify these errors using high-quality on-site power production data. A state-of-the-art optimization techno-economic model was used to estimate e-fuel production costs by utilizing either simulated or high-quality measured PV power profiles across four sites with different climates. The results indicate that in cloudy climates relying on simulated data instead of measured data can lead to an underestimation of the fuel production costs by 36 % for a hydrogen user requiring a constant supply considering an original error of 1.2 % in the annual average capacity factor. The cost underestimation can reach 25 % for a hydrogen user operating between 40 % and 100 % load and 17.5 % for a fully flexible user. For comparison cost differences around 20 % could also result from increasing the electrolyser or PV plant costs by around 55 % which highlights the importance of using high-quality renewable power profiles. To support this an open-source collaborative repository was developed to facilitate the sharing of measured renewable power profiles and provide tools for both time series analysis and green hydrogen techno-economic assessments.
Validation of a Hydrogen Jet Fire Model in FDS
Sep 2023
Publication
Hydrogen jet fire occurs with high probability when hydrogen leaks from high-pressure equipment. The hydrogen jet fire is characterized by its high velocity and energy. Computational Fluid Dynamics (CFD) numerical analysis is a prominent way to predict the potential hazards associated with hydrogen jet fire. Validation of the CFD model is essential to ensure and quantify the accuracy of numerical results. This study focuses on the validation of the hydrogen jet fire model using Fire Dynamic Simulation (FDS). Hydrogen release is modeled using high-speed Lagrangian particles released from a virtual nozzle thus avoiding the modeling of the actual nozzle. The mesh size sensitivity analysis of the model is carried out in a container-size domain with 0.04m – 0.08m resolution of the jet. The model is validated by comparing gas temperatures and heat fluxes with test data. The promising results demonstrated that the model could predict the hazardous influence of the jet fire.
Explosion Mitigation Techniques in Tunnels and their Applicability to Scenarios of Hydrogen Tank Rupture in a Fire
Sep 2023
Publication
This paper presents a comprehensive review of existing explosion mitigation techniques for tunnels and evaluates their applicability in scenarios of hydrogen tank rupture in a fire. The study provides an overview of the current state of the art in tunnel explosion mitigation and discusses the challenges associated with hydrogen explosions in the context of fire incidents. The review shows that there are several approaches available to decrease the effects of explosions including wrapping the tunnel with a flexible and compressible barrier and introducing energy-absorbing flexible honeycomb elements. However these methods are limited to the mitigation of the action and do not consider either the mitigation of the structural response or the effects on the occupants. The study highlights how the structural response is affected by the duration of the action and the natural period of the structural elements and how an accurate design of the element stiffness can be used in order to mitigate the structural vulnerability to the explosion. The review also presents various passive and active mitigation techniques aimed at mitigating the explosion effects on the occupants. Such techniques include tunnel branching ventilation openings evacuation lanes right-angled bends drop-down perforated plates or high-performance fibre-reinforced cementitious composite (HPFRCC) panels for blast shielding. While some of these techniques can be introduced during the tunnel's construction phase others require changes to the already working tunnels. To simulate the effect of blast wave propagation and evaluate the effectiveness of these mitigation techniques a CFD-FEM study is proposed for future analysis. The study also highlights the importance of considering these mitigation techniques to ensure the safety of the public and first responders. Finally the study identifies the need for more research to understand blast wave mitigation by existing structural elements in the application for potential accidents associated with hydrogen tank rupture in a tunnel.
QRA of Hydrogen Vehicles in a Road Tunnel
Sep 2023
Publication
Hydrogen energy is recognized by many European governments as an important part of the development to achieve a more sustainable energy infrastructure. Great efforts are spent to build up a hydrogen supply chain to support the increasing number of hydrogen-powered vehicles. Naturally these vehicles will use the common traffic infrastructure. Thus it has to be ensured these infrastructures are capable to withstand the hazards and associated risks that may arise from these new technologies. In order to have an appropriate assessment tool for hydrogen vehicles transport through tunnels a new QRA methodology is developed and presented here. In Europe the PIARC is a very common approach. It is therefore chosen as a starting point for the new methodology. It provides data on traffic statistics accident frequencies tunnel geometries including certain prevention and protection measures. This approach is enhanced by allowing better identification of hazards and their respective sources for hydrogen vehicles. A detailed analysis of the accident scenarios that are unique for hydrogen vehicles hereunder the initiating events severity of collision types that may result in a release of hydrogen gas in a tunnel and the location of such an accident are included. QRA enables the assessment and evaluation of scenarios involving external fires or vehicles that burst into fire because of an accident or other fire sources. Event Tree Analysis is the technique used to estimate the event frequencies. The consequence analysis includes the hazards from blast waves hydrogen jet fires DDT.
A Model for Assessing the Risk of Liquid Hydrogen Transport through Road Tunnels
Sep 2023
Publication
Among the new energy carriers aimed at reducing greenhouse gas emissions the use of hydrogen is expected to grow significantly in various applications and sectors (i.e. industrial commercial transportation etc.) due to its high energy content by weight and zero carbon emissions. The increasingly widespread use of hydrogen will require massive distribution from production sites to final consumers and the delivery by means of liquid hydrogen road tankers may be a suitable cost-effective option for market penetration in the short-medium term. Liquid hydrogen (LH2) presents different hazards compared to gaseous hydrogen and an accidental release in confined spaces such as road tunnels might lead to the formation of a flammable hydrogen cloud that might deflagrate or even detonate. Nevertheless the potential negative effects on users in the event of accidental leakage of liquid hydrogen from a tanker in road tunnels so far have not been sufficiently investigated. Therefore a 3D Computational Fluid Dynamics model for the release of LH2 and its dispersion within a road tunnel was developed in this study. The proposed model was validated by a comparison with certain experimental and numerical studies found in the literature. Such modeling is demanding for long tunnels. Therefore the results of the simulations (e.g. the amount of hydrogen contained within the cloud) were combined with established simplified consequence methods to estimate the overpressures generated from a potential hydrogen deflagration. This was then used to evaluate the effects on users while evacuating from the tunnel. The findings showed that the worst scenario is when the release is in the middle of the tunnel length and the ignition occurs 90 s after the leakage.
Review on Ammonia as a Potential Fuel: From Synthesis to Economics
Feb 2021
Publication
Ammonia a molecule that is gaining more interest as a fueling vector has been considered as a candidate to power transport produce energy and support heating applications for decades. However the particular characteristics of the molecule always made it a chemical with low if any benefit once compared to conventional fossil fuels. Still the current need to decarbonize our economy makes the search of new methods crucial to use chemicals such as ammonia that can be produced and employed without incurring in the emission of carbon oxides. Therefore current efforts in this field are leading scientists industries and governments to seriously invest efforts in the development of holistic solutions capable of making ammonia a viable fuel for the transition toward a clean future. On that basis this review has approached the subject gathering inputs from scientists actively working on the topic. The review starts from the importance of ammonia as an energy vector moving through all of the steps in the production distribution utilization safety legal considerations and economic aspects of the use of such a molecule to support the future energy mix. Fundamentals of combustion and practical cases for the recovery of energy of ammonia are also addressed thus providing a complete view of what potentially could become a vector of crucial importance to the mitigation of carbon emissions. Different from other works this review seeks to provide a holistic perspective of ammonia as a chemical that presents benefits and constraints for storing energy from sustainable sources. State-of-the-art knowledge provided by academics actively engaged with the topic at various fronts also enables a clear vision of the progress in each of the branches of ammonia as an energy carrier. Further the fundamental boundaries of the use of the molecule are expanded to real technical issues for all potential technologies capable of using it for energy purposes legal barriers that will be faced to achieve its deployment safety and environmental considerations that impose a critical aspect for acceptance and wellbeing and economic implications for the use of ammonia across all aspects approached for the production and implementation of this chemical as a fueling source. Herein this work sets the principles research practicalities and future views of a transition toward a future where ammonia will be a major energy player.
Efficient and Low-emission Approaches for Cost-effective Hydrogen, Power, and Heat Production Based on Chemical Looping Combustion
Nov 2024
Publication
Hydrogen production has recently attracted much attention as an energy carrier and sector integrator (i.e. electricity and transport) in future decarbonized smart energy systems. At the same time power production is highly valued in energy systems as other sectors like transport and heating become electrified. This work compares two different low-emission systems to produce electricity hydrogen and heat. The proposed systems are based on chemical looping combustion combined with biomass gasification (CLC-BG) and steam methane reforming (CLC-SMR) both benefiting from heat integration between chemical looping combustion and downstream processes. A full process simulation is carried out in Aspen Plus for both systems and detailed modeling is performed for chemical looping combustion. The overall thermal efficiency is calculated to be 71.1 % for CLC-BG and 76.4 % for CLC-SMR. Co-feeding methane into the biomass gasification process of CLC-BG leads to an enhanced overall efficiency. In comparison to CLC-BG CLC-SMR exhibits greater potential in terms of power and hydrogen generation resulting in a higher exergy efficiency of 58.3 % as opposed to 44.6 %. Assuming market prices of 5.2 USD/GJ for biomass and 9.1 USD/GJ for natural gas the lowest minimum hydrogen sale price is estimated to be 4 USD/kg for CLC-SMR.
Correlations between Component Size Green Hydrogen Demand and Breakeven Price for Energy Islands
Jun 2023
Publication
The topic of energy islands is currently a focal point in the push for the energy transition. An ambitious project in the North Sea aims to build an offshore wind-powered electrolyser for green hydrogen production. Power-to-X (PtX) is a process of converting renewable electricity into hydrogen-based energy carriers such as natural gas liquid fuels and chemicals. PtH2 represents a subset of PtX wherein hydrogen is the resultant green energy from the conversion process. Many uncertainties surround PtH2 plants affecting the economic success of the investment and making the price of hydrogen and the levelized cost of hydrogen (LCOH) of this technology uncompetitive. Several studies have analysed PtH2 layouts to identify the hydrogen price without considering how component capacities and external inputs affect the breakeven price. Unlike previous works this paper investigates component capacity dependencies under variables such as wind and hydrogen demand shape for dedicated/non-dedicated system layouts. To this end the techno-economic analysis finds the breakeven price optimising the components to reach the lowest selling price. Results show that the hydrogen price can reach 2.2 €/kg for a non-dedicated system for certain combinations of maximum demand and electrolyser capacity. Furthermore the LCOH analysis revealed that the offshore wind electrolyser system is currently uncompetitive with hydrogen production from carbon-based technologies but is competitive with renewable technologies. The sensitivity analysis reveals the green electricity price in the non-dedicated case for which a dedicated system has a lower optimum hydrogen price. The price limit for the dedicated case is 116 €/MWh.
Off-grid Wind/Hydrogen Systems with Multi-electrolyzers: Optimized Operational Strategies
Sep 2023
Publication
Optimized operation of wind/hydrogen systems can increase the system efficiency and further reduce the hydrogen production cost. In this regard extensive research has been done but there is a lack of detailed electrolyzer models and effective management of multiple electrolyzers considering their physical restrictions. This work proposes electrolyzer models that integrate the efficiency variation caused by load level change start–stop cycle (including hot and cold start) thermal management and degradation caused by frequent starts. Based on the proposed models three operational strategies are considered in this paper: two traditionally utilized methods simple start–stop and cycle rotation strategies and a newly proposed rolling optimizationbased strategy. The results from daily operation show that the new strategy results in a more balanced load level among the electrolyzers and a more stable temperature. Besides from a yearly operation perspective it is found that the proposed rolling optimization method results in more hydrogen production higher system efficiency and lower LCOH. The new method leads to hydrogen production of 311297 kg compared to 289278 kg and 303758 kg for simple start–stop and cycle rotation methods. Correspondingly the system efficiencies for the new simple start–stop and cycle rotation methods are 0.613 0.572 and 0.587. The resulting LCOH from the new method is 3.89 e/kg decreasing by 0.35 e/kg and 0.21 e/kg compared to the simple start–stop and cycle rotation methods. Finally the proposed model is compared with two conventional models to show its effectiveness in revealing more operational details and reliable results.
Overview of International Activities in Hydrogen System Safety in IEA Hydrogen TCP Task 43
Sep 2023
Publication
Safety and reliability have long been recognized as key issues for the development commercialization and implementation of new technologies and infrastructure and hydrogen systems are no exception to this rule. Reliability engineering quantitative risk assessment (QRA) and knowledge exchange each play a key role in proactive addressing safety – before problems happen – and help us learn from problems if they happen. Many international research activities are focusing on both reliability and risk assessment for hydrogen systems. However the element of knowledge exchange is sometimes less visible. To support international collaboration and knowledge exchange the International Energy Agency (IEA) convened a new Technology Collaboration Program “Task 43: Safety and Regulatory Aspects of Emerging Large Scale Hydrogen Energy Applications” started in June 2022. Within Task 43 Subtask E focuses on Hydrogen Systems Safety. This paper discusses the structure of the Hydrogen Systems Safety subtask and the aligned activities and introduces opportunities for future work.
Economic and Resilient Operation of Hydrogen-based Microgrids: An Improved MPC-based Optimal Scheduling Scheme Considering Security Constraints of Hydrogen Facilities
Feb 2023
Publication
Optimally scheduling alkaline electrolyzers (AELs) in a hydrogen-based microgrid (HBM) can greatly unleash the operational flexibility of the HBM. However existing scheduling strategies of AELs mostly utilize a simplified AEL model which ignores the nonlinear coupling of electric-hydrogen-thermal sectors violating the AEL’s security constraints thereby making the scheduling scheme infeasible. This paper proposes an improved model predictive control (MPC) based optimal scheduling framework which incorporates a scheduling correction algorithm into the basic MPC structure. This framework is utilized for implementing economic and resilient scheduling of an HBM under normal and emergency conditions respectively. With the scheduling correction algorithm this framework can be formulated into a computationally efficient mixedinteger linear programming meanwhile guaranteeing the solutions strictly satisfy the security constraints of hydrogen facilities (i.e. AEL and hydrogen tank). Case studies are conducted based on real operating data of a Danish energy island Bornholm. The results demonstrate that the proposed scheduling scheme under normal conditions can contribute to significant comprehensive benefits from the daily operation cost saving of 68% computational time saving of 98% and satisfying the security constraints of hydrogen facilities compared to previous scheduling strategies. Besides it sharply reduces load shedding under emergency conditions by proactively allocating distributed energy sources in the HBM.
Exploring Decentralized Ammonia Synthesis for Hydrogen Storage and Transport: A Comprehensive CFD Investigation with Experimental Validation and Parametric Study
Sep 2023
Publication
Hydrogen energy plays a vital role in the transition towards a carbon-neutral society but faces challenges in storage and transport as well as in production due to fluctuations in renewable electricity generation. Ammonia (NH3 ) as a carbon-neutral hydrogen carrier offers a promising solution to the energy storage and transport problem. To realize its potential and support the development of a hydrogen economy exploring NH3 synthesis in a decentralized form that integrates with distributed hydrogen production systems is highly needed. In this study a computational fluid dynamics (CFD) model for the Ruthenium (Ru) catalysts-based Haber– Bosch reactor is developed. First a state-of-the-art kinetic model comprehensively describing the complex catalytic reaction is assessed for its sensitivity and applicability to temperature pressure and conversion. Then the kinetic model is integrated into the CFD model and its accuracy is verified through comparison with experimental data obtained from different Ru-based catalysts and operation conditions. Detailed CFD results for a given case are presented offering a visual understanding of thermal gradients and species distributions inside the reactor. Finally a CFD-based parametric study is performed to reveal the impacts of key operation parameters and optimize the NH3 synthesis reactor. The results show that the NH3 production rate is predominantly influenced by temperature with a two-fold difference observed for every 30 ◦C variation while pressure primarily affects the equilibrium. Additionally the affecting mechanism of space velocity is thoroughly discussed and the best value for efficient NH3 synthesis is found to be 180000 h−1. In conclusion the CFD model and simulation results provide valuable insights for the design and control of decentralized NH3 synthesis reactor and operation contributing to the advancement of sustainable energy technologies.
Renewable Fuel Production and the Impact of Hydrogen Infrastructure - A Case Study of the Nordics
Apr 2024
Publication
Hard-to-electrify sectors will require renewable fuels to facilitate the green transition in the future. Therefore it is crucial to identify promising production locations while taking into account the local biomass resources variable renewable energy sources and the synergies between sectors. In this study investments and dispatch operations are optimised of a large catalogue of renewable fuel production technologies in the opensource software SpineOpt and this is soft-linked to the comprehensive energy system model Balmorel. We analyse future production pathways by comparing various levels of hydrogen infrastructure including large-scale hydrogen storage and assess system impacts. The results indicate that methanol may provide synergies in its multipurpose use as an early (2030-2040) shipping fuel and later as an aviation fuel through further refining if ammonia becomes more competitive (2050). We furthermore show that a hydrogen infrastructure increases the competitiveness of non-flexible hydrogen-based fuel production technologies. Offshore electrolysis hubs decrease energy system impacts in scenarios with 105 TWh of Nordic hydrogen export. However hydrogen export scenarios are much costlier compared to scenarios with no export unless a high hydrogen price is received. Finally we find that emission taxes in the range of 250-265 euro/tCO2 will be necessary for renewable fuels to become competitive.
Control and Optimization of Hydrogen Hybrid Electric Vehicles Using GPS-Based Speed Estimation
Dec 2024
Publication
This paper investigates the feasibility of hydrogen-powered hybrid electric vehicles as a solution to transportation-related pollution. It focuses on optimizing energy use to improve efficiency and reduce emissions. The study details the creation and real-time performance assessment of a hydrogen hybrid electric vehicle (HHEV)system using an STM32F407VG board. This system includes a fuel cell (FC) as the main energy source a battery (Bat) to provide energy during hydrogen supply disruptions and a supercapacitor (SC) to handle power fluctuations. A multi-agent-based artificial intelligence tool is used to model the system components and an energy management algorithm (EMA) is applied to optimize energy use and support decision-making. Real Global Positioning System (GPS) data are analyzed to estimate energy consumption based on trip and speed parameters. The EMA developed and implemented in real-time using Matlab/Simulink(2016) identifies the most energy-efficient routes. The results show that the proposed vehicle architecture and management strategy effectively select optimal routes with minimal energy use.
Modeling the Long-term Evolution of the Italian Power Sector: The Role of Renewable Resources and Energy Storage Facilities
Feb 2024
Publication
The aim of this study is to investigate the long-term planning of the Italian power sector from 2021 to 2050. The key role of photovoltaic and wind technologies in combination with power-to-power systems based on hydrogen and batteries is investigated. An updated version of the OSeMOSYS tool is used which employs a clustering method for the representation of time-varying input data. First the potential of variable renewable energy sources (VRES) is assessed. A sensitivity analysis is also performed on the temporal resolution of the model to determine an adequate trade-off between the computation time and the accuracy of the results. Then a technoeconomic optimization scenario is carried out resulting in a total net present cost of about 233.7 B€. A high penetration of VRES technologies is foreseen by 2050 with a total VRES installed capacity of 272.9 GW (mainly photovoltaic and onshore wind). Batteries are found to be the preferable energy storage solution in the first part of the energy transition while the hydrogen storage starts to be convenient from about the year 2040. Indeed the role of hydrogen storage becomes fundamental as the VRES penetration increases thanks to its cost-effective long-term storage capability. By 2050 74.6 % of electricity generation will be based on VRES which will also enable a significant reduction in CO2 emissions of about 87 %.
Standalone and System-level Perspectives on Hydrogen-based Sustainable Aviation Fuel Pathways for Denmark
Mar 2025
Publication
Aviation is one of the most challenging sectors to electrify directly due to its high energy density demands. Hydrogen offers a pathway for indirect electrification in such sectors enabling sustainable aviation fuels (SAF) production when combined with a carbon source. SAF produced via methanol or Fischer-Tropsch (FT) synthesis (e-SAF) has higher volumetric density than hydrogen remains liquid under standard conditions and can be used as a direct drop-in fuel. Certain FT-based e-SAF pathways are already certified for use in blends enhancing their appeal for sustainable aviation. This study evaluates e-SAF pathways in terms of resource efficiency and costs for different carbon sources. The results from both a standalone and system-level perspective indicate that biomass gasification-sourced carbon is the most energy-efficient pathway given biomass availability. For point-source and direct air capture pathways electricity costs for renewable hydrogen dominate the overall costs comprising about 70 % of total e-SAF costs. Given cheap renewable electricity and by-product revenues e-SAF can achieve price levels of 0.5–1.1 €/litre which is cost-competitive with their fossil-based counterparts. A breakeven electricity price of 9–29 €/MWh is needed for e-SAF made via a point source-based CO2 pathway compared with a moderate aviation fossil fuel price of 0.5 €/litre.
Review of Electrofuel Feasibility - Cost and Environmental Impact
Jun 2022
Publication
Electrofuels fuels produced from electricity water and carbon or nitrogen are of interest as substitutes for fossil fuels in all energy and chemical sectors. This paper focuses on electrofuels for transportation where some can be used in existing vehicle/vessel/aircraft fleets and fueling infrastructure. The aim of this study is to review publications on electrofuels and summarize costs and environmental performance. A special case denoted as bio-electrofuels involves hydrogen supplementing existing biomethane production (e.g. anaerobic digestion) to generate additional or different fuels. We use costs identified in the literature to calculate harmonized production costs for a range of electrofuels and bio-electrofuels. Results from the harmonized calculations show that bio-electrofuels generally have lower costs than electrofuels produced using captured carbon. Lowest costs are found for liquefied bio-electro-methane bio-electro-methanol and bio-electro-dimethyl ether. The highest cost is for electro-jet fuel. All analyzed fuels have the potential for long-term production costs in the range 90–160 € MWh−1 . Dominant factors impacting production costs are electrolyzer and electricity costs the latter connected to capacity factors (CFs) and cost for hydrogen storage. Electrofuel production costs also depend on regional conditions for renewable electricity generation which are analyzed in sensitivity analyses using corresponding CFs in four European regions. Results show a production cost range for electro-methanol of 76–118 € MWh−1 depending on scenario and region assuming an electrolyzer CAPEX of 300–450 € kWelec −1 and CFs of 45%–65%. Lowest production costs are found in regions with good conditions for renewable electricity such as Ireland and western Spain. The choice of system boundary has a large impact on the environmental assessments. The literature is not consistent regarding the environmental impact from different CO2 sources. The literature however points to the fact that renewable energy sources are required to achieve low global warming impact over the electrofuel life cycle.
Liquid Air Energy Storage (LAES) Integrated into the Hydrogen Economy - Techno-economic Optimization of Waste Cold Recovery from Liquid Hydrogen Regasification
Jul 2025
Publication
A liquid air energy storage (LAES) system is a promising Carnot battery configuration capable of efficiently recovering waste heat and cold energy carriers. Among these liquid hydrogen (LH₂) regasification presents a significant opportunity due to its high exergy content and its regasification temperature which aligns well with the liquid air liquefaction process. While most existing studies focus on integrating LAES with liquid natural gas (LNG) regasification or improving hydrogen liquefaction via liquid air regasification this work takes a novel approach by enhancing liquid air liquefaction through the utilization of waste cold from LH₂ regasification. Additionally this study explores an economic innovation the valorization of clean dry air discharged by LAES which has not been extensively examined in prior literature. A novel LAES configuration is proposed and subjected to a techno-economic analysis comparing its performance with a stand-alone LAES system. Results show that the proposed integration increases round-trip efficiency by 15 % reduces the levelized cost of storage by 60 % and achieves a payback period of under 10 years. These findings provide valuable insights for both academia and industry advancing the development of more efficient and economically viable LAES systems.
Optimal Expansion of a Multi-domain Virtual Power Plant for Green Hydrogen Production to Decarbonise Seaborne Passenger Transportation
Nov 2023
Publication
Many industrialised nations recently concentrated their focus on hydrogen as a viable option for the decarbonisation of fossil-intensive sectors including maritime transportation. A sustainable alternative to the conventional production of hydrogen based on fossil hydrocarbons is water electrolysis powered by renewable energy sources. This paper presents a detailed techno-economic optimisation model for sizing an electrolyser and a hydrogen storage embedded in a multi-domain virtual power plant to produce green hydrogen for seaborne passenger transportation. We base our numerical analysis on three years of historical data from a renewable-dominated 60/10 kV substation on the Danish island of Bornholm and on data for ferries to the mainland of Sweden. Our analysis shows that an electrolyser system serves as a valuable flexibility asset on the electrical demand side while supporting the thermal management of the district heating system and contributing to meeting the ferries hydrogen demand. With a sized electrolyser of 9.63 MW and a hydrogen storage of 1.45 t the hydrogen assets are able to take up a large share of the local excess electricity generation. The waste heat of the electrolyser delivers a significant share of 21.4% of the annual district heating demand. Moreover the substation can supply 26% of the hydrogen demand of the ferries from local resources. We further examine the sensitivity of the asset sizing towards investment costs electrolyser efficiency and hydrogen market prices.
European Maritime Transport Environmental Report 2025
Jan 2025
Publication
This second edition of the European Maritime Transport Environmental Report (EMTER 2025) examines the progress made towards achieving Europe′s decarbonisation targets and environmental goals for the maritime sector while indicating the most important trends key challenges and opportunities. The objective was to update the indicators developed for the first report analyse new datasets and fill existing gaps to provide a data and knowledge-based assessment of the maritime transport sector′s transition to sustainability.
Multiphysics Modeling of Electrolyzers under Dynamic Converter Operation
Sep 2025
Publication
The integration of electrolyzers into modern power systems is a critical step toward sustainable hydrogen production. However their dynamic power consumption and stringent operational constraints present considerable challenges. This article proposes a comprehensive multiphysics model of an alkaline electrolyzer emphasizing its interaction with a power electronic converter to ensure efficient and reliable power delivery. The study incorporates electrochemical principles to develop mathematical models that accurately represent the alkaline electrolyzer’s electrical behavior and dynamic response. A single-stage active front-end (AFE) rectifier based on SiC MOSFETs is employed as the power electronic interface offering improved energy efficiency enhanced system stability and reduced power quality issues compared to conventional approaches. Experimental results validate the performance of the proposed alkaline electrolyzer and converter models highlighting the potential for effective integration of alkaline electrolyzers into converter-based systems within renewable energy environments.
Sustainability Assessment of Alternative Energy Fuels for Aircrafts—A Life Cycle Analysis Approach
Nov 2024
Publication
Aviation is of crucial importance for the transportation sector and fundamental for the economy as it facilitates trade and private travel. Nonetheless this sector is responsible for a great amount of global carbon dioxide emissions exceeding 920 million tonnes annually. Alternative energy fuels (AEFs) can be considered as a promising solution to tackle this issue with the potential to lower greenhouse gas emissions and reduce reliance on fossil fuels in the aviation industry. A life cycle analysis is performed considering an aircraft running on conventional jet fuel and various alternative fuels (biojet methanol and DME) including hydrogen and ammonia. The comparative assessment investigates different fuel production pathways including the following: JETA-1 and biojet fuels via hydrotreated esters and fatty acids (HEFAs) as well as hydrogen and ammonia employing water electrolysis using wind and solar photovoltaic collectors. The outputs of the assessment are quantified in terms of carbon dioxide equivalent emissions acidification eutrophication eco-toxicity human toxicity and carcinogens. The life cycle phases included the following: (i) the construction maintenance and disposal of airports; (ii) the operation and maintenance of aircrafts; and (iii) the production transportation and utilisation of aviation fuel in aircrafts. The results suggest that hydrogen is a more environmentally benign alternative compared to JETA-1 biojet fuel methanol DME and ammonia.
Comparing Sustainable Fuel Adoption in the Energy Transition for Maritime and Aviation Transport
Jul 2025
Publication
Maritime and aviation transport are widely recognised as sectors where reducing greenhouse gas emissions is particularly challenging due to their reliance on energy-dense fuels and the challenges associated with direct electrification. These sectors face increasing pressure to defossilise and reduce emissions in line with global climate goals while simultaneously facing unique technological operational and economic uncertainties. This study addresses a key research gap by comparing the maritime and aviation sectors for common factors and sector-specific differences in their transition to green e-fuels produced from renewable electricity and sustainable CO2. A techno-economic assessment is conducted to evaluate alternative fuel and propulsion options using the levelised cost of mobility framework. The analysis also incorporates the pricing of non-CO2 greenhouse gases and air pollutant emissions. Results show that e-ammonia or e-LNG combustion is the most cost-effective option for maritime transport when emission costs are excluded whereas hydrogen fuel cells become more economical when these costs are internalised. In aviation e-kerosene use in conventional aircraft presents the lowest costs regardless of the year or emission pricing. The findings highlight the importance of considering unique characteristics of each sector and tailored defossilisation and decarbonisation strategies that consider sector-specific constraints. To sustainably meet the growing demand for transport fuels rapid investments in renewable electricity generation electrolysers and e-fuel synthesis are essential. Development of strong regulatory frameworks and financial instruments will be critical to support early deployment of e-fuels and minimise the risks.
An Efficient Renewable Hybridization Based on Hydrogen Storage for Peak Demand Reduction: A Rule-based Energy Control and Optimisation Using Machine Learning Techniques
Dec 2022
Publication
The present study proposes and thoroughly examines a novel approach for the effective hybridization of solar and wind sources based on hydrogen storage to increase grid stability and lower peak load. The parabolic trough collector vanadium chloride thermochemical cycle hydrogen storage tank alkaline fuel cells thermal energy storage and absorption chiller make up the suggested smart system. Additionally the proposed system includes a wind turbine to power the electrolyzer unit and minimize the size of the solar system. A rule-based control technique establishes an intelligent two-way connection with energy networks to compensate for the energy expenses throughout the year. The transient system simulation (TRNSYS) tool and the engineering equation solver program are used to conduct a comprehensive techno-economic-environmental assessment of a Swedish residential building. A four-objective optimization utilizing MATLAB based on the grey wolf algorithm coupled with an artificial neural network is used to determine the best trade-off between the indicators. According to the results the primary energy saving carbon dioxide reduction rate overall cost and purchased energy are 80.6 % 219 % 14.8 $/h and 24.9 MWh at optimal conditions. From the scatter distribution it can be concluded that fuel cell voltage and collector length should be maintained at their lowest domain and the electrode area is an ineffective parameter. The suggested renewable-driven smart system can provide for the building’s needs for 70 % of the year and sell excess production to the local energy network making it a feasible alternative. Solar energy is far less effective in storing hydrogen over the winter than wind energy demonstrating the benefits of combining renewable energy sources to fulfill demand. By lowering CO2 emissions by 61758 kg it is predicted that the recommended smart renewable system might save 7719 $ in environmental costs equivalent to 6.9 ha of new reforestation.
Enhancing Safety and Operation of Hydrogen Fueling Stations: A Model-based Method for Complex Failure Scenario Analysis
Jun 2025
Publication
As a zero-emission fuel hydrogen provides a promising solution with significant potential to meet the increasing demand for clean energy alternatives. Hydrogen fueling stations are essential infrastructure for the commercialization of hydrogen fuel cells but the flammability of hydrogen poses safety challenges throughout its lifecycle. Past incidents highlight the need for robust risk assessments starting with comprehensive hazard identification and failure scenario analysis.<br/>This paper proposes using Multilevel Flow Modelling (MFM) a functional modeling method integrated with reasoning capability to support safety evaluations. MFM enables the structured representation of system functions and supports tasks such as fault diagnosis and hazard analysis. Previously applied in nuclear offshore and chemical systems MFM is here used to model a liquid hydrogen fueling station. This paper demonstrates that a developed MFM model identifies failure scenarios related to hydrogen leaks overpressure and operational reliability issues.<br/>This paper conducts a comparison between MFM and traditional methods FMEA and FTA and demonstrates MFM's strength in handling the key challenges rooted from complex failure interactions. Results suggest MFM is complementary to traditional methods and can enhance risk assessments. MFM also contributes to digitalization in safety assessment and monitoring systems ultimately improving hydrogen fueling station reliability and safety.
Exploring European Hydrogen Demand Variations under Tactical Uncertainty with Season Hydrogen Storage
Aug 2025
Publication
Achieving a net-zero energy system in Europe by 2050 will likely require large-scale deployment of hydrogen and seasonal energy storage to manage variability in renewable supply and demand. This study addresses two key objectives: (1) to develop a modeling framework that integrates seasonal storage into a stochastic multihorizon capacity expansion model explicitly capturing tactical uncertainty across timescales; and (2) to assess the impact of seasonal hydrogen storage on long-term investment decisions in European power and hydrogen infrastructure under three hydrogen demand scenarios. To this end the multi-horizon stochastic programming model EMPIRE is extended with tactical stages within each investment period enabling operational decisions to be modeled as a multi-stage stochastic program. This approach captures short-term uncertainty while preserving long-term investment foresight. Results show that seasonal hydrogen storage considerably enhances system flexibility displacing the need for up to 600 TWh/yr of dispatchable generation in Europe after 2040 and sizing down cross-border hydrogen transmission capacities by up to 12%. Storage investments increase by factors of 5–14 which increases the investments in variable renewables and improve utilization particularly solar. Scenarios with seasonal storage also show up to 6% lower total system costs and more balanced infrastructure deployment across regions. These findings underline the importance of modeling temporal uncertainty and seasonal dynamics in long-term energy system planning.
Above-ground Hydrogen Storage: A State-of-the-art Review
Oct 2024
Publication
Hydrogen is increasingly recognized as a clean energy alternative offering effective storage solutions for widespread adoption. Advancements in storage electrolysis and fuel cell technologies position hydrogen as a pathway toward cleaner more efficient and resilient energy solutions across various sectors. However challenges like infrastructure development cost-effectiveness and system integration must be addressed. This review comprehensively examines above-ground hydrogen storage technologies and their applications. It highlights the importance of established hydrogen fuel cell infrastructure particularly in gaseous and LH2 systems. The review favors material-based storage for medium- and long-term needs addressing challenges like adverse thermodynamics and kinetics for metal hydrides. It explores hydrogen storage applications in mobile and stationary sectors including fuel-cell electric vehicles aviation maritime power generation systems off-grid stations power backups and combined renewable energy systems. The paper underscores hydrogen’s potential to revolutionize stationary applications and co-generation systems highlighting its significant role in future energy landscapes.
Hydrogen Production from Winery Wastewater Through a Dual-Chamber Microbial Electrolysis Cell
Jun 2025
Publication
This study explores the feasibility of producing biohydrogen from winery wastewater using a dual-chamber microbial electrolysis cell (MEC). A mixed microbial consortium pre-adapted to heavy-metal environments and enriched with Geobacter sulfurreducens was anaerobically cultivated from diverse waste streams. Over 5000 h of development the MEC system was progressively adapted to winery wastewater enabling long-term electrochemical stability and high organic matter degradation. Upon winery wastewater addition (5% v/v) the system achieved a sustained hydrogen production rate of (0.7 ± 0.3) L H2 L −1 d −1 with an average current density of (60 ± 4) A m−3 and COD removal efficiency exceeding 55% highlighting the system’s resilience despite the presence of inhibitory compounds. Coulombic efficiency and cathodic hydrogen recovery reached (75 ± 4)% and (87 ± 5)% respectively. Electrochemical impedance spectroscopy provided mechanistic insight into charge transfer and biofilm development correlating resistive parameters with biological adaptation. These findings demonstrate the potential of MECs to simultaneously treat agro-industrial wastewaters and recover energy in the form of hydrogen supporting circular resource management strategies.
Europe's Environment 2025 - Main Report, Europe's Environment and Climate: Knowledge for Resilience, Prosperity and Sustainability
Jan 2025
Publication
Every five years as mandated in its founding regulation the European Environment Agency (EEA) publishes a state of the environment report. Europe's environment 2025 provides decision makers at European and national levels as well as the general public with a comprehensive and cross-cutting assessment on environment climate and sustainability in Europe. Europe's environment 2025 is the 7th state of the environment report published by the EEA since 1995. Europe's environment 2025 has been prepared in close collaboration with the EEA’s European Environment Information and Observation Network (Eionet). The report draws on the Eionet’s vast expertise of leading experts and scientists in the environmental field across the EEA’s 32 member countries and six cooperating countries.
Can Hydrogen-powered Air Travel Grow within the Planetary Limits?
Aug 2025
Publication
Air travel demand is rising rapidly and the aviation sector is relying on technology to decouple environmental impacts from its growth. Using Sweden as a case study we assessed the absolute environmental sustainability of medium-distance air travel in 2050 positioning the aviation sector's environmental impacts in relation to the planetary limits. We employed a novel framework that integrates prospective life cycle assessment and absolute environmental sustainability assessment methodologies. Our findings suggest that projected medium-distance air travel powered by e-kerosene or liquid hydrogen could have life cycle environmental impacts that overshoot global climate change and biodiversity loss thresholds by several orders of magnitude. Based on our case results for Sweden for aviation to develop within the planetary limits we recommend cross-sector collaboration to address environmental impacts from fossil-free energy supplies and the establishment of integrated targets that incorporate broader environmental issues. Given the unlikelihood of decoupling growth from environmental impacts policymakers and the aviation sector should consider concurrently supporting technological development and implementing measures to manage air travel demand.
The Role of Financial Mechanisms in Advancing Renewable Energy and Green Hydrogen
Jun 2025
Publication
Europe’s transition toward a low-carbon energy system relies on the deployment of hydrogen produced with minimized carbon emissions; however regulatory requirements increase system costs and create financial barriers. This study investigates the financial implications of enforcing European Commission rules for renewable hydrogen production from 2024 to 2048. Using a scenario-based modeling approach that draws on European power system investments in renewable energy the results show that immediate compliance leads to an additional cost of approximately eighty billion euros over twenty-four years corresponding to a 3.6 percent increase in total system costs. To address this investment gap the study employs a segmentation analysis of support mechanisms based on existing policies and market practices identifying seven categories that range from investment incentives and production subsidies to infrastructure and financial instruments. Among these hydrogen offtake support and infrastructure funding are identified as the most effective measures for reducing risk and enabling private investment. These findings provide strategic insights for policymakers seeking to align their regulatory ambitions with financially viable pathways for integrating renewable energy.
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