United Kingdom
Exploiting the Ocean Thermal Energy Conversion (OTEC) Technology for Green Hydrogen Production and Storage: Exergo-economic Analysis
Nov 2024
Publication
This study presents and analyses three plant configurations of the Ocean Thermal Energy Conversion (OTEC) technology. All the solutions are based on using the OTEC system to obtain hydrogen through an electrolyzer. The hydrogen is then compressed and stored. In the first and second layouts a Rankine cycle with ammonia and a mixture of water and ethanol is utilised respectively; in the third layout a Kalina cycle is considered. In each configuration the OTEC cycle is coupled with a polymer electrolyte membrane (PEM) electrolyzer and the compression and storage system. The water entering the electrolyzer is pre-heated to 80 ◦C by a solar collector. Energy exergy and exergo-economic studies were conducted to evaluate the cost of producing compressing and storing hydrogen. A parametric analysis examining the main design constraints was performed based on the temperature range of the condenser the mass flow ratio of hot and cold resource flows and the mass fraction. The maximum value of the overall exergy efficiency calculated is equal to 93.5% for the Kalina cycle and 0.524 €/kWh is the minimum cost of hydrogen production achieved. The results were compared with typical data from other hydrogen production systems.
Preliminary Assessment of a Hydrogen Farm Including Health and Safety and Capacity Needs
Dec 2024
Publication
The safety engineering design of hydrogen systems and infrastructure worker education and training regulatory compliance and engagement with other stakeholders are significant to the viability and public acceptance of hydrogen farms. The only way to ensure these are accomplished is for the field of hydrogen safety engineering (HSE) to grow and mature. HSE is described as the application of engineering and scientific principles to protect the environment property and human life from the harmful effects of hydrogen-related mishaps and accidents. This paper describes a whole hydrogen farm that produces hydrogen from seawater by alkaline and proton exchange membrane electrolysers then details how the hydrogen gas will be used: some will be stored for use in a combined-cycle gas turbine some will be transferred to a liquefaction plant and the rest will be exported. Moreover this paper describes the design framework and overview for ensuring hydrogen safety through these processes (production transport storage and utilisation) which include legal requirements for hydrogen safety safety management systems and equipment for hydrogen safety. Hydrogen farms are large-scale facilities used to create store and distribute hydrogen which is usually produced by electrolysis using renewable energy sources like wind or solar power. Since hydrogen is a vital energy carrier for industries transportation and power generation these farms are crucial in assisting the global shift to clean energy. A versatile fuel with zero emissions at the point of use hydrogen is essential for reaching climate objectives and decarbonising industries that are difficult to electrify. Safety is essential in hydrogen farms because hydrogen is extremely flammable odourless invisible and also has a small molecular size meaning it is prone to leaks which if not handled appropriately might cause fires or explosions. To ensure the safe and dependable functioning of hydrogen production and storage systems stringent safety procedures are required to safeguard employees infrastructure and the surrounding environment from any mishaps.
Energy Storage Strategy - Narrative
Feb 2023
Publication
This narrative document sets out the main rationale for hydrogen storage development at scale in the UK: - To meet net zero the UK will need considerable energy storage - Hydrogen storage will be a major and essential part of this - Physical hydrogen storage is needed in the UK - Only geological hydrogen storage can deliver at the scale needed within the timescales for net zero - Geological hydrogen storage should be supported through a viable business model now to ensure it comes online in the 2030s.
Green Hydrogen and its Unspoken Challenges for Energy Justice
Oct 2024
Publication
Green hydrogen is often promoted as a key facilitator for the clean energy transition but its implementation raises concerns around energy justice. This paper examines the socio-political and techno-economic challenges that green hydrogen projects may pose to the three tenets of energy justice: distributive procedural and recognition justice. From a socio-political perspective the risk of neocolonial resource extraction uneven distribution of benefits exclusion of local communities from decision-making and disregard for indigenous rights and cultures threaten all three justice tenets. Techno-economic factors such as water scarcity land disputes and resource-related conflicts in potential production hotspots further jeopardise distributive and recognition justice. The analysis framed by an adapted PEST model reveals that while green hydrogen holds promise for sustainable development its implementation must proactively address these justice challenges. Failure to do so could perpetuate injustices exploitation and marginalisation of vulnerable communities undermining the sustainability goals it aims to achieve. The paper highlights the need for inclusive and equitable approaches that respect local sovereignty integrate diverse stakeholders and ensure fair access and benefit-sharing. Only by centring justice considerations can the transition to green hydrogen catalyse positive social change and realise its full potential as a driver of sustainable energy systems.
National Gas FutureGrid Phase 1 Closure Report
Jul 2024
Publication
This project an essential part of the National Gas HyNTS programme endeavours to align the NTS with GB’s net zero ambitions by demonstrating the operational viability of the system with varying hydrogen blends using decommissioned assets typical of the natural gas network today ultimately aiming for 100% hydrogen conveyance. Several desktop studies were undertaken within the HyNTS programme to confirm the theoretical potential of the NTS to transport hydrogen safely and reliably. Further to these studies practical demonstration was deemed necessary to bridge the knowledge gaps and ensure the system’s transition maintains the utmost safety and reliability standards. A range of tests on decommissioned assets were conducted offline in a controlled environment to ensure robust outcomes that will ultimately start to build the safety case for a hydrogen network. The key deliverables and testing achievements of FutureGrid included: • Operational testing with natural gas and 2% 5% 20% and 100% hydrogen to verify the network’s ability to transport hydrogen and varying blends. • Standalone offline testing modules complementing evidence gathered on the main test facility. These address specific areas of concern including material permeation flange integrity asset leakage and rupture consequence which are essential for risk mitigation and safety assurance. FutureGrid is a global first facility and a critical part of National Gas’ hydrogen programme providing physical evidence of the capability of our network to transport hydrogen. It provides key evidence for hydrogen blending alongside 100% hydrogen pipelines which are planned under Project Union our Hydrogen Backbone across GB. FutureGrid is pivotal in the journey to reaching Net Zero by 2050 and is a fully operational proven technical demonstrator. FutureGrid’s repurposed assets are representative of today’s live high pressure gas network and have been subjected to testing at different blends of natural gas with hydrogen and 100% hydrogen; this was achieved with no major findings in differences in terms of how the assets interact with hydrogen. The overall project completion date was delayed from November 2023 to February 2024 due to technical issues with the newly built hydrogen re‑compressor. There were no changes made to the project costs.
Overview and Prospects of Low-emissions Hydrogen (H2) Energy Systems: Roadmap for a Sustainable H2 Economy
Jul 2024
Publication
Hydrogen (2 ) has a big role to play in energy transition to achieve net-zero carbon emissions by 2050. For 2 to compete with other fuels in the energy market more research is required to mitigate key issues like greenhouse gas (GHG) emissions safety and end-use costs. For these reasons a software-supported technical overview of 2 production storage transportation and utilisation is introduced. Drawbacks and mitigation approaches for 2 technologies were highlighted. The recommended areas include solar thermal or renewable-powered plasma systems for feedstock preheating and oxy-hydrogen combustion to meet operating temperatures and heat duties due to losses; integration of electrolysis of 2 into hydrocarbon reforming methods to replace air separation unit (ASU); use of renewable power sources for electrical units and the introduction of thermoelectric units to maximise the overall efficiency. Furthermore a battolyser system for small-scale energy storage; new synthetic hydrides with lower absorption and desorption energy; controlled parameters and steam addition to the combustor/cylinder and combustors with fitted heat exchangers to reduce emissions and improve the overall efficiency are also required. This work also provided detailed information on any of these systems implementations based on location factors and established a roadmap for 2 production and utilisation. The proposed 2 production technologies are hybrid pyrolysis-electrolysis and integrated AD-MEC and DR systems using renewable bioelectrochemical and low-carbon energy systems. Production and utilisation of synthetic natural gas (NG) using renewablepowered electrolysis of 2 oxy-fuel and direct air capture (DAC) is another proposed 2 energy system for a sustainable 2 economy. By providing these factors and information researchers can work towards pilot development and further efficiency enhancement.
Enabling Large-scale Enhanced Hydrogen Production in Deep Underground Coal Gasification in the Context of a Hydrogen Economy
Dec 2024
Publication
Underground coal gasification (UCG) is an emerging clean energy technology with significant potential for enhanced hydrogen production especially when coupled with water injection. Previous lab-scale studies have explored this potential but the mechanisms driving water-assisted hydrogen enhancement in large-scale deep UCG settings remain unclear. This study addresses this gap using numerical simulations of a large-scale deep coal model designed for hydrogen-oriented UCG. We investigated single-point and multipoint water injection stra tegies to optimize hydrogen production. Additionally we developed a retractable water injection technique to ensure sustained hydrogen output and effective cavity control. Our results indicate that the water–gas shift re action is crucial for increasing hydrogen production. Multipoint injection has been proven to be more effective than single-point injection increasing hydrogen production by 11% with an equal amount of steam. The introduction of retractable injection allows for continuous and efficient hydrogen generation with daily hydrogen production rates of approximately five times that of a conventional injection scheme and an increase in cumulative hydrogen production of approximately 105% over the same time period. Importantly the mul tipoint injection method also helped limit vertical cavity growth mitigating the risk of aquifer contamination. These findings support the potential of UCG as a low-carbon energy source in the transition to a hydrogen economy
A Review on Liquid Hydrogen Fuel Systems in Aircraft Applications for Gas Turbine Engines
Oct 2024
Publication
The transition from traditional aviation fuels to low-emission alternatives such as hydrogen is a crucial step towards a sustainable future for aviation. Conventional jet fuels substantially contribute to greenhouse gas emissions and climate change. Hydrogen fuel especially "green" hydrogen offers great potential for achieving full sustainability in aviation. Hybrid/electric/fuel cell technologies may be used for shorter flights while longrange aircraft are more likely to combust hydrogen in gas turbines. Liquid hydrogen is necessary to minimize storage tank weight but the required fuel systems are at a low technology readiness level and differ significantly from Jet A-1 systems in architecture operation and performance. This paper provides an in-depth review covering the development of liquid hydrogen fuel system design concepts for gas turbines since the 1950s compares insights from key projects such as NASA studies and ENABLEH2 alongside an analysis of recent publications and patent applications and identifies the technological advancements required for achieving zeroemission targets through hydrogen-fuelled propulsion.
Local and Global Sensitivity Analysis for Railway Upgrading Between Hydrogen Fuel Cell and Electrification
Nov 2024
Publication
In the field of rail transit the UK Department of Transport stated that it will realize a comprehensive transformation of UK railways by 2050 abandoning traditional diesel trains and upgrading them to new environmentally friendly trains. The current mainstream upgrade methods are electrification and hydrogen fuel cells. Comprehensive upgrades are costly and choosing the optimal upgrade method for trams and mainline railways is critical. Without a sensitivity analysis it is difficult for us to determine the influence relationship between each parameter and cost resulting in a waste of cost when choosing a line reconstruction method. In addition by analyzing the sensitivity of different parameters to the cost the primary optimization direction can be determined to reduce the cost. Global higher-order sensitivity analysis enables quantification of parameter interactions showing non-additive effects between parameters. This paper selects the main parameters that affect the retrofit cost and analyzes the retrofit cost of the two upgrade methods in the case of trams and mainline railways through local and global sensitivity analysis methods. The results of the analysis show that given the current UK rail system it is more economical to choose electric trams and hydrogen mainline trains. For trams the speed at which the train travels has the greatest impact on the final cost. Through the sensitivity analysis this paper provides an effective data reference for the current railway upgrading and reconstruction plan and provides a theoretical basis for the next step of train parameter optimization.
Techno-economic Analysis of Underground Hydrogen Storage in Europe
Dec 2023
Publication
Hydrogen storage is crucial to developing secure renewable energy systems to meet the European Union’s 2050 carbon neutrality objectives. However a knowledge gap exists concerning the site-specific performance and economic viability of utilizing underground gas storage (UGS) sites for hydrogen storage in Europe. We compile information on European UGS sites to assess potential hydrogen storage capacity and evaluate the associated current and future costs. The total hydrogen storage potential in Europe is 349 TWh of working gas energy (WGE) with site-specific capital costs ranging from $10 million to $1 billion. Porous media and salt caverns boasting a minimum storage capacity of 0.5 TWh WGE exhibit levelized costs of $1.5 and $0.8 per kilogram of hydrogen respectively. It is estimated that future levelized costs associated with hydrogen storage can potentially decrease to as low as $0.4 per kilogram after three experience cycles. Leveraging these techno-economic considerations we identify suitable storage sites.
Offshore Green Hydrogen Production from Wind Energy: Critical Review and Perspective
Feb 2024
Publication
Hydrogen is envisaged to play a major role in decarbonizing our future energy systems. Hydrogen is ideal for storing renewable energy over longer durations strengthening energy security. It can be used to provide electricity renewable heat power long-haul transport shipping and aviation and in decarbonizing several industrial processes. The cost of green hydrogen produced from renewable via electrolysis is dominated by the cost of electricity used. Operating electrolyzers only during periods of low electricity prices will limit production capacity and underutilize high investment costs in electrolyzer plants. Hydrogen production from deep offshore wind energy is a promising solution to unlock affordable electrolytic hydrogen at scale. Deep offshore locations can result in an increased capacity factor of generated wind power to 60–70% 4–5 times that of onshore locations. Dedicated wind farms for electrolysis can use the majority >80% of the produced energy to generate economical hydrogen. In some scenarios hydrogen can be the optimal carrier to transport the generated energy onshore. This review discusses the opportunities and challenges in offshore hydrogen production using electrolysis from wind energy and seawater. This includes the impact of site selection size of the electrolyzer and direct use of seawater without deionization. The review compares overall electrolysis system efficiency cost and lifetime when operating with direct seawater feed and deionized water feed using reverse osmosis and flash evaporation systems. In the short to medium term it is advised to install a reverse osmosis plant with an ion exchanger to feed the electrolysis instead of using seawater directly.
Blue Hydrogen in the United Kingdom - A Policy & Environmental Case Study
Feb 2025
Publication
Blue hydrogen is one of the energy carriers to be adopted by the United Kingdom to reduce emissions to net Zero by 2050 and its use is majorly influenced by policy and technological innovations. With more than 10 blue hydrogen facilities planning productive offtake from 2025 there is an urgent need to confirm the viability of these proposed facilities to aid decarbonisation and the path to conformity to policy regulation. This study discovers that the Acorn blue hydrogen facility can produce blue hydrogen within the low carbon hydrogen standard set by the United Kingdom’s government. In this study a detailed examination of hydrogen production techniques is conducted using lifecycle assessment (LCA) approach aimed to understand the environmental impact of producing 144 tons of hydrogen per day using Acorn hydrogen facility as a case study. This was followed on with sensitive analysis embracing steam and oxygen consumption and methane leakages the ability of the facility meeting the low carbon hydrogen standard economics and the externality-priced production costs that embody the environmental impact. A gate-to-gate LCA shows that the Acorn hydrogen plant must aim at carbon capture rates of >90% to meet the set UK target of 20 gCO2e/MJLHV. The study further identifies from literature that the autothermal reforming (ATR) system with integrated carbon capture and storage (CCS) production technology as the most environmentally sustainable technology at present in comparison to commercially available options studied. This assessment helps to appraise potentially unintended causes and effects of the production of blue hydrogen that should aid future policy guidance and investments.
IEA TCP Task 43 - Subtask Safety Distances: State of the Art
Sep 2023
Publication
The large deployment of hydrogen technologies for new applications such as heat power mobility and other emerging industrial utilizations is essential to meet targets for CO2 reduction. This will lead to an increase in the number of hydrogen installations nearby local populations that will handle hydrogen technologies. Local regulations differ and provide different safety and/or separation distances in different geographies. The purpose of this work is to give an insight on different methodologies and recommendations developed for hydrogen (mainly) risk management and consequences assessment of accidental scenarios. The first objective is to review available methodologies and to identify the divergent points on the methodology. For this purpose a survey has been launched to obtain the needed inputs from the subtask participants. The current work presents the outcomes of this survey highlighting the gaps and suggesting the prioritization of the actions to take to bridge these gaps.
‘Greening’ an Oil Exporting Country: A Hydrogen, Wind and Gas Turbine Case Study
Feb 2024
Publication
In the quest for achieving decarbonisation it is essential for different sectors of the economy to collaborate and invest significantly. This study presents an innovative approach that merges technological insights with philosophical considerations at a national scale with the intention of shaping the national policy and practice. The aim of this research is to assist in formulating decarbonisation strategies for intricate economies. Libya a major oil exporter that can diversify its energy revenue sources is used as the case study. However the principles can be applied to develop decarbonisation strategies across the globe. The decarbonisation framework evaluated in this study encompasses wind-based renewable electricity hydrogen and gas turbine combined cycles. A comprehensive set of both official and unofficial national data was assembled integrated and analysed to conduct this study. The developed analytical model considers a variety of factors including consumption in different sectors geographical data weather patterns wind potential and consumption trends amongst others. When gaps and inconsistencies were encountered reasonable assumptions and projections were used to bridge them. This model is seen as a valuable foundation for developing replacement scenarios that can realistically guide production and user engagement towards decarbonisation. The aim of this model is to maintain the advantages of the current energy consumption level assuming a 2% growth rate and to assess changes in energy consumption in a fully green economy. While some level of speculation is present in the results important qualitative and quantitative insights emerge with the key takeaway being the use of hydrogen and the anticipated considerable increase in electricity demand. Two scenarios were evaluated: achieving energy self-sufficiency and replacing current oil exports with hydrogen exports on an energy content basis. This study offers for the first time a quantitative perspective on the wind-based infrastructure needs resulting from the evaluation of the two scenarios. In the first scenario energy requirements were based on replacing fossil fuels with renewable sources. In contrast the second scenario included maintaining energy exports at levels like the past substituting oil with hydrogen. The findings clearly demonstrate that this transition will demand great changes and substantial investments. The primary requirements identified are 20529 or 34199 km2 of land for wind turbine installations (for self-sufficiency and exports) and 44 single-shaft 600 MW combined-cycle hydrogen-fired gas turbines. This foundational analysis represents the commencement of the research investment and political agenda regarding the journey to achieving decarbonisation for a country.
Innovations in Hydrogen Storage Materials: Synthesis, Applications, and Prospects
Jul 2024
Publication
Hydrogen globally recognized as the most efficient and clean energy carrier holds the potential to transform future energy systems through its use as a fuel and chemical resource. Although progress has been made in reversible hydrogen adsorption and release challenges in storage continue to impede widespread adoption. This review explores recent advancements in hydrogen storage materials and synthesis methods emphasizing the role of nanotechnology and innovative synthesis techniques in enhancing storage performance and addressing these challenges to drive progress in the field. The review provides a comprehensive overview of various material classes including metal hydrides complex hydrides carbon materials metal-organic frameworks (MOFs) and porous materials. Over 60 % of reviewed studies focused on metal hydrides and alloys for hydrogen storage. Additionally the impact of nanotechnology on storage performance and the importance of optimizing synthesis parameters to tailor material properties for specific applications are summarized. Various synthesis methods are evaluated with a special emphasis on the role of nanotechnology in improving storage performance. Mechanical milling emerges as a commonly used and cost-effective method for fabricating intermetallic hydrides capable of adjusting hydrogen storage properties. The review also explores hydrogen storage tank embrittlement mechanisms particularly subcritical crack growth and examines the advantages and limitations of different materials for various applications supported by case studies showcasing real-world implementations. The challenges underscore current limitations in hydrogen storage materials highlighting the need for improved storage capacity and kinetics. The review also explores prospects for developing materials with enhanced performance and safety providing a roadmap for ongoing advancements in the field. Key findings and directions for future research in hydrogen storage materials emphasize their critical role in shaping future energy systems.
Green Hydrogen Production and Liquefaction Using Offshore Wind Power, Liquid Air, and LNG Cold Energy
Sep 2023
Publication
Coastal regions have abundant off-shore wind energy resources and surrounding areas have large-scale liquefied natural gas (LNG) receiving stations. From the engineering perspectives there are limitations in unstable off-shore wind energy and fluctuating LNG loads. This article offers a new energy scheme to combine these 2 energy units which uses surplus wind energy to produce hydrogen and use LNG cold energy to liquefy and store hydrogen. In addition in order to improve the efficiency of utilizing LNG cold energy and reduce electricity consumption for liquid hydrogen (LH2) production at coastal regions this article introduces the liquid air energy storage (LAES) technology as the intermediate stage which can stably store the cold energy from LNG gasification. A new scheme for LNG-LAES-LH2 hybrid LH2 production is built. The case study is based on a real LNG receiving station at Hainan province China and this article presents the design of hydrogen production/liquefaction process and carries out the optimizations at key nodes and proves the feasibility using specific energy consumption and exergy analysis. In a 100 MW system the liquid air storage round-trip efficiency is 71.0% and the specific energy consumption is 0.189 kWh/kg and the liquid hydrogen specific energy consumption is 7.87 kWh/kg and the exergy efficiency is 46.44%. Meanwhile the corresponding techno-economic model is built and for a LNGLAES-LH2 system with LH2 daily production 140.4 tons the shortest dynamic payback period is 9.56 years. Overall this novel hybrid energy scheme can produce green hydrogen using a more efficient and economical method and also can make full use of surplus off-shore wind energy and coastal LNG cold energy.
Multi-criteria Site Selection Workflow for Geological Storage of Hydrogen in Depleted Gas Fields: A Case for the UK
Oct 2023
Publication
Underground hydrogen storage (UHS) plays a critical role in ensuring the stability and security of the future clean energy supply. However the efficiency and reliability of UHS technology depend heavily on the careful and criteria-driven selection of suitable storage sites. This study presents a hybrid multi-criteria decision-making framework integrating the Analytical Hierarchy Process (AHP) and Preference Ranking Organisation Method for Enrichment of Evaluations (PROMETHEE) to identify and select the best hydrogen storage sites among depleted gas reservoirs in the UK. To achieve this a new set of site selection criteria is proposed in light of the technical and economic aspects of UHS including location reservoir rock quality and tectonic characteristics maximum achievable hydrogen well deliverability rate working gas capacity cushion gas volume requirement distance to future potential hydrogen clusters and access to intermittent renewable energy sources (RESs). The framework is implemented to rank 71 reservoirs based on their potential and suitability for UHS. Firstly the reservoirs are thoroughly evaluated for each proposed criterion and then the AHP-PROMETHEE technique is employed to prioritise the criteria and rank the storage sites. The study reveals that the total calculated working gas capacity based on single-well plateau withdrawal rates is around 881 TWh across all evaluated reservoirs. The maximum well deliverability rates for hydrogen withdrawal are found to vary considerably among the sites; however 22 % are estimated to have deliverability rates exceeding 100 sm3 /d and 63 % are located within a distance of 100 km from a major hydrogen cluster. Moreover 70 % have access to nearby RESs developments with an estimated cumulative RESs capacity of approximately 181 GW. The results highlight the efficacy of the proposed multicriteria site selection framework. The top five highest-ranked sites for UHS based on the evaluated criteria are the Cygnus Hamilton Saltfleetby Corvette and Hatfield Moors gas fields. The insights provided by this study can contribute to informed decision-making sustainable development and the overall progress of future UHS projects within the UK and globally.
Whole System Impacts of Decarbonising Transport with Hydrogen: A Swedish Case Study
Oct 2024
Publication
This study aims to carry out a techno-economic analysis of different hydrogen supply chain designs coupled with the Swedish electricity system to study the inter-dependencies between them. Both the hydrogen supply chain designs and the electricity system were parameterized with data for 2030. The supply chain designs comprehend centralised production decentralised production a combination of both and with/without seasonal variation in hydrogen demand. The supply chain design is modelled to minimize the overall cost while meeting the hydrogen demands. The outputs of the supply chain model include the hydrogen refuelling stations’ locations the electrolyser’s locations and their respective sizes as well as the operational schedule. The electricity system model shows that the average electricity prices in Sweden for zones SE1 SE2 SE3 and SE4 will be 4.28 1.88 8.21 and 8.19 €/MWh respectively. The electricity is mainly generated from wind and hydropower (around 42% each) followed by nuclear (14%) solar (2%) and then bio-energy (0.3%). In addition the hydrogen supply chain design that leads to a lower overall cost is the decentralised design with a cost of 1.48 and 1.68 €/kgH2 in scenarios without and with seasonal variation respectively. The seasonal variation in hydrogen demand increases the cost of hydrogen regardless of the supply chain design.
Energy-exergy Evaluation of Liquefied Hydrogen Production System Based on Steam Methane Reforming and LNG Revaporization
Jul 2023
Publication
The research motivation of this paper is to utilize the large amount of energy wasted during the LNG (liquefied natural gas) gasification process and proposes a synergistic liquefied hydrogen (LH2) production and storage process scheme for LNG receiving station and methane reforming hydrogen production process - SMR-LNG combined liquefied hydrogen production system which uses the cold energy from LNG to pre-cool the hydrogen and subsequently uses an expander to complete the liquefaction of hydrogen. The proposed process is modeled and simulated by Aspen HYSYS software and its efficiency is evaluated and sensitivity analysis is carried out. The simulation results show that the system can produce liquefied hydrogen with a flow rate of 5.89t/h with 99.99% purity when the LNG supply rate is 50t/h. The power consumption of liquefied hydrogen is 46.6kWh/kg LH2; meanwhile the energy consumption of the HL subsystem is 15.9kWh/kg LH2 lower than traditional value of 17~19kWh/kg LH2. The efficiency of the hydrogen production subsystem was 16.9%; the efficiency of the hydrogen liquefaction (HL) subsystem was 29.61% which was significantly higher than the conventional industrial value of 21%; the overall energy efficiency (EE1) of the system was 56.52% with the exergy efficiency (EE2) of 22.2% reflecting a relatively good thermodynamic perfection. The energy consumption of liquefied hydrogen per unit product is 98.71 GJ/kg LH2.
Analysis of the Combustion Speed in a Spark Ignition Engine Fuelled with Hydrogen and Gasoline Blends at Different Air Fuel Ratios
Nov 2024
Publication
The use of hydrogen in internal combustion engines is a promising solution for the decarbonisation of the transport sector. The current transition scenario is marked by the unavailability and storage challenges of hydrogen. Dual fuel combustion of hydrogen and gasoline in current spark ignition engines is a feasible solution in the short and medium term as it can improve engine efficiency reduce pollutant emissions and contribute significantly in tank to wheel decarbonisation without major engine modification. However new research is needed to understand how the incorporation of hydrogen affects existing engines to effectively implement gasoline-hydrogen dual fuel option. Understanding the impact of hydrogen on the combustion process (e.g. combustion speed) will guide and optimize the operation of engines under dual fuel combustion conditions. In this work a commercial gasoline direct injection engine has been modified to operate with gasolinehydrogen fuels. The experiments have been carried out at various air–fuel ratios ranging from stoichiometric to lean combustion conditions at constant engine speed and torque. At each one of the 14 experimental points 200-cycle in-cylinder pressure traces were recorded and processed with a quasi-dimensional diagnostic model and a combustion speed analysis was then carried out. It has been understood that hydrogen mainly reduces the duration of the first combustion phase. Hydrogen also enables to increase air excess ratios (lean in fuel combustion) without significantly increasing combustion duration. Furthermore a correlation is proposed to predict combustion speed as a function of the fuel and air mixture properties. This correlation can be incorporated to calculate combustion duration in predictive models of engines operating under different fuel mixtures and different geometries of the combustion chamber with pent-roof cylinder head and flat piston head.
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