Italy
Optimal Integration of Hydrogen-Based Energy Storage Systems in Photovoltaic Microgrids: A Techno-Economic Assessment
Aug 2020
Publication
The feasibility and cost-effectiveness of hydrogen-based microgrids in facilities such as public buildings and small- and medium-sized enterprises provided by photovoltaic (PV) plants and characterized by low electric demand during weekends were investigated in this paper. Starting from the experience of the microgrid being built at the Renewable Energy Facility of Sardegna Ricerche (Italy) which among various energy production and storage systems includes a hydrogen storage system a modeling of the hydrogen-based microgrid was developed. The model was used to analyze the expected performance of the microgrid considering different load profiles and equipment sizes. Finally the microgrid cost-effectiveness was evaluated using a preliminary economic analysis. The results demonstrate that an effective design can be achieved with a PV system sized for an annual energy production 20% higher than the annual energy requested by the user and a hydrogen generator size 60% of the PV nominal power size. This configuration leads to a self-sufficiency rate of about 80% and without public grants a levelized cost of energy comparable with the cost of electricity in Italy can be achieved with a reduction of at least 25–40% of the current initial costs charged for the whole plant depending on the load profile shape.
Combustion of Hydrogen Enriched Methane and Biogases Containing Hydrogen in a Controlled Auto-Ignition Engine
Dec 2018
Publication
The paper describes a numerical study of the combustion of hydrogen enriched methane and biogases containing hydrogen in a Controlled Auto Ignition engine (CAI). A single cylinder CAI engine is modelled with Chemkin to predict engine performance comparing the fuels in terms of indicated mean effective pressure engine efficiency and pollutant emissions. The effects of hydrogen and carbon dioxide on the combustion process are evaluated using the GRI-Mech 3.0 detailed radical chain reactions mechanism. A parametric study performed by varying the temperature at the start of compression and the equivalence ratio allows evaluating the temperature requirements for all fuels; moreover the effect of hydrogen enrichment on the auto-ignition process is investigated. The results show that at constant initial temperature hydrogen promotes the ignition which then occurs earlier as a consequence of higher chemical reactivity. At a fixed indicated mean effective pressure hydrogen presence shifts the operating range towards lower initial gas temperature and lower equivalence ratio and reduces NOx emissions. Such reduction somewhat counter-intuitive if compared with similar studies on spark-ignition engines is the result of operating the engine at lower initial gas temperatures.
Optimized Design of a H2-Powered Moped for Urban Mobility
Mar 2024
Publication
Micro-mobility plays an increasingly important role in the current energy transition thanks to its low energy consumption and reduced contribution to urban congestion. In this scenario fuel cell hybrid electric vehicles have several advantages over state-of-the-art battery electric vehicles such as increased driving ranges and reduced recharge times. In this paper we study the conversion of a commercial electric moped (Askoll eS3 ®) into a fuel cell hybrid electric vehicle by finding the optimal design of the components through an optimization methodology based on backward dynamic programming. This optimal design and operation strategy can also be implemented with a rulesbased approach. The results show that a system composed of a 1 kW proton exchange membrane fuel cell a 2000 Sl metal hydride hydrogen tank and a 240 Wh buffer battery can cover the same driving range as the batteries in an electric moped (119 km). Such a hybrid system occupies considerably less volume (almost 40 L) and has a negligibly higher mass. The free volume can be used to extend the driving range up to almost three times the nominal value. Moreover by using a high-pressure composite tank it is possible to increase the mass energy density of the onboard energy storage (although compression can require up to 10% of the hydrogen’s chemical energy). The fuel cell hybrid electric vehicle can be recharged with green hydrogen that is locally produced. In detail we analyze a residential scenario and a shared mobility scenario in the small Italian city of Viterbo.
Dynamic Electric Simulation Model of a Proton Exchange Membrane Electrolyzer System for Hydrogen Production
Sep 2022
Publication
An energy storage system based on a Proton Exchange Membrane (PEM) electrolyzer system which could be managed by a nanoGrid for Home Applications (nGfHA) is able to convert the surplus of electric energy produced by renewable sources into hydrogen which can be stored in pressurized tanks. The PEM electrolyzer system must be able to operate at variable feeding power for converting all the surplus of renewable electric energy into hydrogen in reasonable time. In this article the dynamic electric simulation model of a PEM electrolyzer system with its pressurized hydrogen tanks is developed in a proper calculation environment. Through the calculation code the stack voltage and current peaks to a supply power variation from the minimum value (about 56 W) to the maximum value (about 440 W) are controlled and zeroed to preserve the stack the best range of the operating stack current is evaluated and hydrogen production is monitored.
The Role of Direct Air Capture in EU’s Decarbonisation and Associated Carbon Intensity for Synthetic Fuels Production
May 2023
Publication
Direct air capture (DAC) is considered one of the mitigation strategies in most of the future scenarios trying to limit global temperature to 1.5 ◦C. Given the high expectations placed on DAC for future decarbonisation this study presents an extensive review of DAC technologies exploring a number of techno-economic aspects including an updated collection of the current and planned DAC projects around the world. A dedicated analysis focused on the production of synthetic methane methanol and diesel from DAC and electrolytic hydrogen in the European Union (EU) is also performed where the carbon footprint is analysed for different scenarios and energy sources. The results show that the maximum grid carbon intensity to obtain negative emissions with DAC is estimated at 468 gCO2e/kWh which is compliant with most of the EU countries’ current grid mix. Using only photovoltaics (PV) and wind negative emissions of at least −0.81 tCO2e/tCO2 captured can be achieved. The maximum grid intensities allowing a reduction of the synthetic fuels carbon footprint compared with their fossil-fuels counterparts range between 96 and 151 gCO2e/kWh. However to comply with the Renewable Energy Directive II (REDII) sustainability criteria to produce renewable fuels of non-biological origin the maximum stays between 30.2 to 38.8 gCO2e/kWh. Only when using PV and wind is the EU average able to comply with the REDII threshold for all scenarios and fuels with fuel emissions ranging from 19.3 to 25.8 gCO2e/MJ. These results highlight the importance of using renewable energies for the production of synthetic fuels compliant with the EU regulations that can help reduce emissions from difficult-to-decarbonise sectors.
Numerical Investigation of a Fuel Cell-Powered Agricultural Tractor
Nov 2022
Publication
In recent years growing awareness about environmental issues is pushing humankind to explore innovative technologies to reduce the anthropogenic sources of pollutants. Among these sources internal combustion engines in non-road mobile machinery (NRMM) such as agricultural tractors are one of the most important. The aim of this work is to explore the possibility of replacing the conventional diesel engine with an electric powertrain powered by a hybrid storage system consisting of a small battery pack and a fuel-cell system. The battery pack (BP) is necessary to help the fuel cell manage sudden peaks in power demands. Numerical models of the conventional powertrain and a fuel-cell tractor were carried out. To compare the two powertrains work cycles derived from data collected during real operative conditions were exploited and simulated. For the fuel-cell tractor a control strategy to split the electric power between the battery pack and the fuel cell was explored. The powertrains were compared in terms of greenhouse gas emissions (GHG) according to well-to-wheel (WTW) equivalent CO2 emission factors available in the literature. Considering the actual state-of-the-art hydrogen production methods the simulation results showed that the fuel-cell/battery powertrain was able to accomplish the tasks with a reduction of about 50% of the equivalent CO2 emissions compared to traditional diesel-powered vehicles.
Strategic Overview on Fuel Cell-Based Systems for Mobility and Electrolytic Cells for Hydrogen Production
Mar 2022
Publication
Given the global effort to embrace research actions and technology enhancement for the energy transition innovative sustainable systems are needed both for energy production and for those sectors that are responsible for high pollution and CO2 emissions. In this context electrolytic cells and fuel cells in their variety and flexibility are energy systems characterized by high efficiency and important performance guaranteeing a sustainable solution for future energy systems and for the circular economy. The scope of this paper is therefore to present the state of the art of such systems. An overview of the electrolyzers for hydrogen production is presented by detailing the level of applications for their different technologies from low-temperature units to high-temperature units the fuel flexibility the electrolysis and co-electrolysis mode and the potential coupling with renewable sources. Fuel cell-based systems are also presented and their application in the mobility sector is investigated by considering road transport with light-duty and heavy-duty applications and marine transport. A comparison with conventional technologies will be also presented providing some hints on the potential applications of electrolytic cells and fuel cell systems given their important contribution to the sustainable and circular economy.
Investigating Hydrogen-Based Non-Conventional Storage for PV Power in Eco-Energetic Optimization of a Multi-Energy System
Dec 2021
Publication
Through the integration of multiple energy carriers with related technologies multi-energy systems (MES) can exploit the synergies coming from their interplay for several benefits towards decarbonization. In such a context inclusion of Power-to-X technologies in periods of excess renewable electricity supply removes the need for curtailment of renewable electricity generation. In order to achieve the environmental benefits of MES without neglecting their economic feasibility the optimal design problem is as crucial as challenging and requires the adoption of a multi-objective approach. This paper extends the results of a previous work by investigating hydrogen-based non-conventional storage for PV power in the eco-energetic optimization of an MES. The system under study consists of a reversible fuel cell (r-SOC) photovoltaic (PV) electric heat pump absorption chiller and thermal storage and allows satisfying the multi-energy needs of a residential end-user. A multi-objective linear problem is established to find the optimal MES configuration including the sizes of the involved technologies with the goal of reducing the total annual cost and the fossil primary energy input. Simulation results are compared with those obtained in previous work with a conventional nanogrid where a combined heat and power (CHP) system with gas-fired internal combustion engine and a battery were present instead of an r-SOC. The optimized configuration of the non-conventional nanogrid allows achieving a maximum primary energy reduction amounting to 66.3% compared to the conventional nanogrid. In the face of the environmental benefits the non-conventional nanogrid leads to an increase in total annual costs which compared to the conventional nanogrid is in the range of 41–65%.
Enhanced Performance and Durability of Low Catalyst Loading PEM Water Electrolyser Based on a Short-side Chain Perfluorosulfonic Ionomer
Sep 2016
Publication
Water electrolysis supplied by renewable energy is the foremost technology for producing ‘‘green” hydrogen for fuel cell vehicles. In addition the ability to rapidly follow an intermittent load makes electrolysis an ideal solution for grid-balancing caused by differences in supply and demand for energy generation and consumption. Membrane-electrode assemblies (MEAs) designed for polymer electrolyte membrane (PEM) water electrolysis based on a novel short-side chain (SSC) perfluorosulfonic acid (PFSA) membrane Aquivion with various cathode and anode noble metal loadings were investigated in terms of both performance and durability. Utilizing a nanosized Ir0.7Ru0.3O solid solution anode catalyst and a supported Pt/C cathode catalyst in combination with the Aquivion membrane gave excellent electrolysis performances exceeding 3.2 A cm-2 at 1.8 V terminal cell voltage ( 80% efficiency) at 90 ºC in the presence of a total catalyst loading of 1.6 mg cm−2. A very small loss of efficiency corresponding to 30 mV voltage increase was recorded at 3 A cm 2 using a total noble metal catalyst loading of less than 0.5 mg cm−2 (compared to the industry standard of 2 mg cm−2). Steady-state durability tests carried out for 1000 h at 1 A cm -2 showed excellent stability for the MEA with total noble metal catalyst loading of 1.6 mg cm−2 (cell voltage increase 5 lV/h). Moderate degradation rate (cell voltage increase 15 lV/h) was recorded for the low loading 0.5 mg cm-2 MEA. Similar stability characteristics were observed in durability tests at 3 A cm−2. These high performance and stability characteristics were attributed to the enhanced proton conductivity and good stability of the novel membrane the optimized structural properties of the the enhanced proton conductivity and good stability of the novel membrane the optimized structural properties of the the enhanced proton conductivity and good stability of the novel membrane the optimized structural properties of the Ir and Ru oxide solid solution and the enrichment of Ir species on the surface for the anodic catalyst.
Water Electrolysis for the Production of Hydrogen to Be Employed in the Ironmaking and Steelmaking Industry
Nov 2021
Publication
The way to decarbonization will be characterized by the huge production of hydrogen through sustainable routes. Thus the basic production way is water electrolysis sustained by renewable energy sources allowing for obtaining “green hydrogen”. The present paper reviews the main available technologies for the water electrolysis finalized to the hydrogen production. We describe the fundamental of water electrolysis and the problems related to purification and/or desalinization of water before electrolysis. As a matter of fact we describe the energy efficiency issues with particular attention to the potential application in the steel industry. The fundamental aspects related to the choice of high-temperature or low-temperature technologies are analyzed.
Use of Hydrogen as Fuel: A Trend of the 21st Century
Jan 2022
Publication
The unbridled use of fossil fuels is a serious problem that has become increasingly evident over the years. As such fuels contribute considerably to environmental pollution there is a need to find new sustainable sources of energy with low emissions of greenhouse gases. Climate change poses a substantial challenge for the scientific community. Thus the use of renewable energy through technologies that offer maximum efficiency with minimal pollution and carbon emissions has become a major goal. Technology related to the use of hydrogen as a fuel is one of the most promising solutions for future systems of clean energy. The aim of the present review was to provide an overview of elements related to the potential use of hydrogen as an alternative energy source considering its specific chemical and physical characteristics as well as prospects for an increase in the participation of hydrogen fuel in the world energy matrix.
Optimal Design of Multi-energy Systems with Seasonal Storage
Oct 2017
Publication
Optimal design and operation of multi-energy systems involving seasonal energy storage are often hindered by the complexity of the optimization problem. Indeed the description of seasonal cycles requires a year-long time horizon while the system operation calls for hourly resolution; this turns into a large number of decision variables including binary variables when large systems are analyzed. This work presents novel mixed integer linear program methodologies that allow considering a year time horizon with hour resolution while significantly reducing the complexity of the optimization problem. First the validity of the proposed techniques is tested by considering a simple system that can be solved in a reasonable computational time without resorting to design days. Findings show that the results of the proposed approaches are in good agreement with the full-scale optimization thus allowing to correctly size the energy storage and to operate the system with a long-term policy while significantly simplifying the optimization problem. Furthermore the developed methodology is adopted to design a multi-energy system based on a neighborhood in Zurich Switzerland which is optimized in terms of total annual costs and carbon dioxide emissions. Finally the system behavior is revealed by performing a sensitivity analysis on different features of the energy system and by looking at the topology of the energy hub along the Pareto sets.
Renewable Energy, Carbon Capture & Sequestration and Hydrogen Solutions as Enabling Technologies for Reduced CO2 Energy Transition at a National Level: An Application to the 2030 Italian National Energy Scenarios
Dec 2022
Publication
Globally climate change fossil fuel depletion and greenhouse emissions are fundamental problems requiring massive effort from the international scientific community to be addressed and solved. Following the Clean Energy for all Europeans Package (CEP) guidelines the Italian Government has established challenging and tight objectives both on energy and climate matter to be targeted by 2030. Accordingly research activities on different topics are carried out in Italy looking at the installation of intermittent renewable energy systems (IRES) implementation of carbon capture and sequestration (CCS) on existing power plants and hydrogen technology and infrastructure penetration for accomplishing the end-users demands. The optimal integration of the above-mentioned technologies is one of the most effective weapons to address these objectives. The paper investigates different energy scenarios for meeting the Italian National Energy and Climate Plan (NECP) 2030 targets showing how the combined implementation of around +12 GW of IRES and +6 GW of electrolyzers compared to the national estimates simultaneously with the CCS of around 10 Mt of CO2 per year can reduce the CO2 emissions up to about 247 Mt/year. Thanks to the adoption of the well-established software platform EnergyPlan the integration of IRES plants CCS and hydrogen-based technologies have been explored and the most successful results for concurrently reducing the impact of industrial transport residential and energy sectors and mitigating the greenhouse emissions substantially relies on the diversifications. Results show both the technical and economic convenience of a 2030 energy scenario which implements properly hydrogen IRES and CCS penetration in the energy system meeting the NECP 2030 targets and maintaining both the over-generation of the power plants below 5 TWh and the initial capital expenditure to be sustained for this scenario to occur below +80% compared to the 2019 energy scenario.
Dynamic Simulation and Thermoeconomic Analysis of a Hybrid Renewable System Based on PV and Fuel Cell Coupled with Hydrogen Storage
Nov 2021
Publication
The production of “green hydrogen” is currently one of the hottest topics in the field of renewable energy systems research. Hydrogen storage is also becoming more and more attractive as a flexible solution to mitigate the power fluctuations of solar energy systems. The most promising technology for electricity-to-hydrogen conversion and vice versa is the reversible solid-oxide cell (SOC). This device is still very expensive but it exhibits excellent performance under dynamic operating conditions compared to the competing devices. This work presents the dynamic simulation of a prototypal renewable plant combining a 50 kW photovoltaic (PV) field with a 50 kW solid-oxide electrolyzer cell (SOEC) and a compressed hydrogen tank. The electricity is used to meet the energy demand of a dwelling located in the area of Campi Flegrei (Naples). The SOC efficiency is simulated by developing a mathematical model in MATLAB®. The model also calculates the cell operating temperature as a function of the input current. Once the optimal values of the operating parameters of the SOC are calculated the model is integrated in the transient system simulation tool (TRNSYS) for dynamic analysis. Furthermore this work presents a parametric analysis of the hydrogen storage system (HSS). The results of the energy and environmental analyses show that the proposed system can reach a primary energy saving by 70% and an amount of saved CO2 of 28 tons/year. Some possible future market scenarios are considered for the economic analysis. In the most realistic case the optimal configuration shows a simple pay back lower than 10 years and a profit index of 46%.
Main Hydrogen Production Processes: An Overview
May 2021
Publication
Due to its characteristics hydrogen is considered the energy carrier of the future. Its use as a fuel generates reduced pollution as if burned it almost exclusively produces water vapor. Hydrogen can be produced from numerous sources both of fossil and renewable origin and with as many production processes which can use renewable or non-renewable energy sources. To achieve carbon neutrality the sources must necessarily be renewable and the production processes themselves must use renewable energy sources. In this review article the main characteristics of the most used hydrogen production methods are summarized mainly focusing on renewable feedstocks furthermore a series of relevant articles published in the last year are reviewed. The production methods are grouped according to the type of energy they use; and at the end of each section the strengths and limitations of the processes are highlighted. The conclusions compare the main characteristics of the production processes studied and contextualize their possible use.
Electrolyzer Performance Analysis of an Integrated Hydrogen Power System for Greenhouse Heating. A Case Study
Jul 2016
Publication
A greenhouse containing an integrated system of photovoltaic panels a water electrolyzer fuel cells and a geothermal heat pump was set up to investigate suitable solutions for a power system based on solar energy and hydrogen feeding a self-sufficient geothermal-heated greenhouse. The electricity produced by the photovoltaic source supplies the electrolyzer; the manufactured hydrogen gas is held in a pressure tank. In these systems the electrolyzer is a crucial component; the technical challenge is to make it work regularly despite the irregularity of the solar source. The focus of this paper is to study the performance and the real energy efficiency of the electrolyzer analyzing its operational data collected under different operating conditions affected by the changeable solar radiant energy characterizing the site where the experimental plant was located. The analysis of the measured values allowed evaluation of its suitability for the agricultural requirements such as greenhouse heating. On the strength of the obtained result a new layout of the battery bank has been designed and exemplified to improve the performance of the electrolyzer. The evaluations resulting from this case study may have a genuine value therefore assisting in further studies to better understand these devices and their associated technologies.
Recent Progress and New Perspectives on Metal Amide and Imide Systems for Solid-State Hydrogen Storage
Apr 2018
Publication
Hydrogen storage in the solid state represents one of the most attractive and challenging ways to supply hydrogen to a proton exchange membrane (PEM) fuel cell. Although in the last 15 years a large variety of material systems have been identified as possible candidates for storing hydrogen further efforts have to be made in the development of systems which meet the strict targets of the Fuel Cells and Hydrogen Joint Undertaking (FCH JU) and U.S. Department of Energy (DOE). Recent projections indicate that a system possessing: (i) an ideal enthalpy in the range of 20–50 kJ/mol H2 to use the heat produced by PEM fuel cell for providing the energy necessary for desorption; (ii) a gravimetric hydrogen density of 5 wt. % H2 and (iii) fast sorption kinetics below 110 ◦C is strongly recommended. Among the known hydrogen storage materials amide and imide-based mixtures represent the most promising class of compounds for on-board applications; however some barriers still have to be overcome before considering this class of material mature for real applications. In this review the most relevant progresses made in the recent years as well as the kinetic and thermodynamic properties experimentally measured for the most promising systems are reported and properly discussed.
Modelling and Experimental Analysis of a Polymer Electrolyte Membrane Water Electrolysis Cell at Different Operating Temperatures
Nov 2018
Publication
In this paper a simplified model of a Polymer Electrolyte Membrane (PEM) water electrolysis cell is presented and compared with experimental data at 60 ◦C and 80 ◦C. The model utilizes the same modelling approach used in previous work where the electrolyzer cell is divided in four subsections: cathode anode membrane and voltage. The model of the electrodes includes key electrochemical reactions and gas transport mechanism (i.e. H2 O2 and H2O) whereas the model of the membrane includes physical mechanisms such as water diffusion electro osmotic drag and hydraulic pressure. Voltage was modelled including main overpotentials (i.e. activation ohmic concentration). First and second law efficiencies were defined. Key empirical parameters depending on temperature were identified in the activation and ohmic overpotentials. The electrodes reference exchange current densities and change transfer coefficients were related to activation overpotentials whereas hydrogen ion diffusion to Ohmic overvoltages. These model parameters were empirically fitted so that polarization curve obtained by the model predicted well the voltage at different current found by the experimental results. Finally from the efficiency calculation it was shown that at low current densities the electrolyzer cell absorbs heat from the surroundings. The model is not able to describe the transients involved during the cell electrochemical reactions however these processes are assumed relatively fast. For this reason the model can be implemented in system dynamic modelling for hydrogen production and storage where components dynamic is generally slower compared to the cell electrochemical reactions dynamics.
Finding Synergy Between Renewables and Coal: Flexible Power and Hydrogen Production from Advanced IGCC Plants with Integrated CO2 Capture
Feb 2021
Publication
Variable renewable energy (VRE) has seen rapid growth in recent years. However VRE deployment requires a fleet of dispatchable power plants to supply electricity during periods with limited wind and sunlight. These plants will operate at reduced utilization rates that pose serious economic challenges. To address this challenge this paper presents the techno-economic assessment of flexible power and hydrogen production from integrated gasification combined cycles (IGCC) employing the gas switching combustion (GSC) technology for CO2 capture and membrane assisted water gas shift (MAWGS) reactors for hydrogen production. Three GSC-MAWGS-IGCC plants are evaluated based on different gasification technologies: Shell High Temperature Winkler and GE. These advanced plants are compared to two benchmark IGCC plants one without and one with CO2 capture. All plants utilize state-of-the-art H-class gas turbines and hot gas clean-up for maximum efficiency. Under baseload operation the GSC plants returned CO2 avoidance costs in the range of 24.9–36.9 €/ton compared to 44.3 €/ton for the benchmark. However the major advantage of these plants is evident in the more realistic mid-load scenario. Due to the ability to keep operating and sell hydrogen to the market during times of abundant wind and sun the best GSC plants offer a 6–11%-point higher annual rate of return than the benchmark plant with CO2 capture. This large economic advantage shows that the flexible GSC plants are a promising option for balancing VRE provided a market for the generated clean hydrogen exists.
On the Climate Impacts of Blue Hydrogen Production
Nov 2021
Publication
Natural gas based hydrogen production with carbon capture and storage is referred to as blue hydrogen. If substantial amounts of CO2 from natural gas reforming are captured and permanently stored such hydrogen could be a low-carbon energy carrier. However recent research raises questions about the effective climate impacts of blue hydrogen from a life cycle perspective. Our analysis sheds light on the relevant issues and provides a balanced perspective on the impacts on climate change associated with blue hydrogen. We show that such impacts may indeed vary over large ranges and depend on only a few key parameters: the methane emission rate of the natural gas supply chain the CO2 removal rate at the hydrogen production plant and the global warming metric applied. State-of-the-art reforming with high CO2 capture rates combined with natural gas supply featuring low methane emissions does indeed allow for substantial reduction of greenhouse gas emissions compared to both conventional natural gas reforming and direct combustion of natural gas. Under such conditions blue hydrogen is compatible with low-carbon economies and exhibits climate change impacts at the upper end of the range of those caused by hydrogen production from renewable-based electricity. However neither current blue nor green hydrogen production pathways render fully “net-zero” hydrogen without additional CO2 removal.
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