Poland
Evaluation of the Technical Condition of Pipes during the Transportation of Hydrogen Mixtures According to the Energy Approach
Jun 2024
Publication
In this study a theoretical–experimental methodology for determining the stress–strain state in pipeline systems taking into account the hydrogen environment was developed. A complex of theoretical and experimental studies was conducted to determine the specific energy of destruction as an invariant characteristic of the material’s resistance to strain at different hydrogen concentrations. The technique is based on the construction of complete diagrams of the destruction of the material based on the determination of true strains and stresses in the local volume using the method involving the optical–digital correlation of speckle images. A complex of research was carried out and true diagrams of material destruction were constructed depending on the previous elastic–plastic strain and the action of the hydrogen environment. The change in the concentration of hydrogen absorbed by the material was estimated depending on the value of the specific energy of destruction. A study was conducted on tubular samples and the degree of damage to the material of the inner wall under the action of hydrogen and stress from the internal pressure was evaluated according to the change in specific energy depending on the value of the true strain established with the help of an optical–digital correlator on the outer surface and the degree of damage was determined. It has been established that the specific fracture energy of 17G1S steel decreases by 70–90% under the influence of hydrogen. The effect of the change in the amount of strain energy on the thickness of the pipe wall is illustrated.
Composition Tracking of Natural Gas-Hydrogen Mixtures in Pipeline Flow Using High-resolution Schemes
Jul 2024
Publication
A transient pipeline flow model with gas composition tracking is solved for studying the operation of a natural gas pipeline under nonisothermal flow conditions in a hydrogen injection scenario. Two approaches to high-resolution pipeline flow modeling based on the WENO scheme are presented and compared with the implicit finite difference method. The high-resolution models are capable of capturing fast fluid transients and tracking the step changes in the composition of the transported mixture. The implicit method assumes the decoupling of the flow model components in order to enhance calculation efficiency. The validation of the composition tracking results against actual gas transmission pipeline indicates that both models exhibit good prediction performance with normalized root mean square errors of 0.406% and 1.48% respectively. Under nonisothermal flow conditions the prediction response of the reduced model against a high-resolution flow model with respect to the mass and energy linepack is at most 3.20%.
Techno-Economic Analysis of Hydrogen Production from Swine Manure Biogas via Steam Reforming in Pilot-Scale Installation
Sep 2023
Publication
The main purpose of this paper is the techno-economic analysis of hydrogen production from biogas via steam reforming in a pilot plant. Process flow modeling based on mass and energy balance is used to estimate the total equipment purchase and operating costs of hydrogen production. The pilot plant installation produced 250.67 kg/h hydrogen from 1260 kg/h biomethane obtained after purification of 4208 m3/h biogas using a heat and mass integration process. Despite the high investment cost the plant shows a great potential for biomethane reduction and conversion to hydrogen an attractive economic path with ecological possibilities. The conversion of waste into hydrogen is a possibility of increasing importance in the global energy economy. In the future such a plant will be expanded with a CO2 reduction module to increase economic efficiency and further reduce greenhouse gases in an economically viable manner.
Applying a 2 kW Polymer Membrane Fuel-Cell Stack to Building Hybrid Power Sources for Unmanned Ground Vehicles
Nov 2023
Publication
The novel constructions of hybrid energy sources using polymer electrolyte fuel cells (PEMFCs) and supercapacitors are developed. Studies on the energy demand and peak electrical power of unmanned ground vehicles (UGVs) weighing up to 100 kg were conducted under various conditions. It was found that the average electrical power required does not exceed ~2 kW under all conditions studied. However under the dynamic electrical load of the electric drive of mobile robots the short peak power exceeded 2 kW and the highest current load was in the range of 80–90 A. The electrical performance of a family of PEMFC stacks built in open-cathode mode was determined. A hydrogen-usage control strategy for power generation cleaning processes and humidification was analysed. The integration of a PEMFC stack with a bank of supercapacitors makes it possible to mitigate the voltage dips. These occur periodically at short time intervals as a result of short-circuit operation. In the second construction the recovery of electrical energy dissipated by a short-circuit unit (SCU) was also demonstrated in the integrated PEMFC stack and supercapacitor bank system. The concept of an energy-efficient mobile and environmentally friendly hydrogen charging unit has been proposed. It comprises (i) a hydrogen anion exchange membrane electrolyser (ii) a photovoltaic installation (iii) a battery storage (iv) a hydrogen buffer storage in a buffer tank (v) a hydrogen compression unit and (vi) composite tanks.
The Development of a Green Hydrogen Economy: Review
Jun 2024
Publication
Building a hydrogen economy is perceived as a way to achieve the decarbonization goals set out in the Paris Agreement to limit global warming as well as to meet the goals resulting from the European Green Deal for the decarbonization of Europe. This article presents a literature review of various aspects of this economy. The full added value chain of hydrogen was analyzed from its production through to storage transport distribution and use in various economic sectors. The current state of knowledge about hydrogen is presented with particular emphasis on its features that may determine the positives and negatives of its development. It was noted that although hydrogen has been known for many years its production methods are mainly related to fossil fuels which result in greenhouse gas emissions. The area of interest of modern science is limited to green hydrogen produced as a result of electrolysis from electricity produced from renewable energy sources. The development of a clean hydrogen economy is limited by many factors the most important of which are the excessive costs of producing clean hydrogen. Research and development on all elements of the hydrogen production and use chain is necessary to contribute to increasing the scale of production and use of this raw material and thus reducing costs as a result of the efficiencies of scale and experience gained. The development of the hydrogen economy will be related to the development of the hydrogen trade and the centers of this trade will differ significantly from the current centers of energy carrier trade.
The Influence of the Changes in Natural Gas Supplies to Poland on the Amount of Hydrogen Produced in the SMR Reactor
Mar 2024
Publication
Thanks to investments in diversifying the supply of natural gas Poland did not encounter any gas supply issues in 2022 when gas imports from Russia were ceased due to the Russian Federation’s armed intervention in Ukraine. Over the past few years the supply of gas from routes other than the eastern route has substantially grown particularly the supplies of liquefied natural gas (LNG) via the LNG terminal in Swinouj´scie. The growing proportion of LNG in Poland’s gas supply ´ leads to a rise in ethane levels in natural gas as verified by the review of data taken at a specific location within the gas system over the years 2015 2020 and 2022. Using measurements of natural gas composition the effectiveness of the steam hydrocarbon reforming process was simulated in the Gibbs reactor via Aspen HYSYS. The simulations confirmed that as the concentration of ethane in the natural gas increased the amount of hydrogen produced and the heat required for reactions in the reformer also increased. This article aims to analyze the influence of the changes in natural gas quality in the Polish transmission network caused by changes in supply structures on the mass and heat balance of the theoretical steam reforming reactor. Nowadays the chemical composition of natural gas may be significantly different from that assumed years ago at the plant’s design stage. The consequence of such a situation may be difficulties in operating especially when controlling the quantity of incoming natural gas to the reactor based on volumetric flow without considering changes in chemical composition.
Environmental Benefits of Hydrogen-Powered Buses: A Case Study of Coke Oven Gas
Oct 2024
Publication
This study conducted a Life Cycle Assessment (LCA) of alternative (electric and hydrogen) and conventional diesel buses in a large metropolitan area. The primary focus was on hydrogen derived from coke oven gas a byproduct of the coking process which is a crucial step in the steel production value chain. The functional unit was 1000000 km traveled over 15 years. LCA analysis using SimaPro v9.3 revealed significant environmental differences between the bus types. Hydrogen buses outperformed electric buses in all 11 environmental impact categories and in 5 of 11 categories compared to conventional diesel buses. The most substantial improvements for hydrogen buses were observed in ozone depletion (8.6% of diesel buses) and global warming (29.9% of diesel buses). As a bridge to a future dominated by green hydrogen employing grey hydrogen from coke oven gas in buses provides a practical way to decrease environmental harm in regions abundant with this resource. This interim solution can significantly contribute to climate policy goals.
Spatial Succession for Degradation of Solid Multicomponent Food Waste and Purification of Toxic Leachate with the Obtaining of Biohydrogen and Biomethane
Jan 2022
Publication
A huge amount of organic waste is generated annually around the globe. The main sources of solid and liquid organic waste are municipalities and canning and food industries. Most of it is disposed of in an environmentally unfriendly way since none of the modern recycling technologies can cope with such immense volumes of waste. Microbiological and biotechnological approaches are extremely promising for solving this environmental problem. Moreover organic waste can serve as the substrate to obtain alternative energy such as biohydrogen (H2 ) and biomethane (CH4 ). This work aimed to design and test new technology for the degradation of food waste coupled with biohydrogen and biomethane production as well as liquid organic leachate purification. The effective treatment of waste was achieved due to the application of the specific granular microbial preparation. Microbiological and physicochemical methods were used to measure the fermentation parameters. As a result a four-module direct flow installation efficiently couples spatial succession of anaerobic and aerobic bacteria with other micro- and macroorganisms to simultaneously recycle organic waste remediate the resulting leachate and generate biogas.
Effect of Methane Addition on Transition to Detonation in Hydrogen-Air Mixtures Due to Shock Wave Focussing in a 90 - Degree Corner
Sep 2023
Publication
The main purpose of this work is to investigate the influence of methane addition in methane-hydrogen-air mixture (φ = 0.8 – 1.6) on the critical conditions for transition to detonation in a 90-deg wedge corner. Similar to hydrogen-air mixtures investigated previously [1] methane-hydrogen-air mixtures results showed three ignition modes weak ignition followed by deflagration with ignition delay time higher than 1 μs strong ignition with instantaneous transition to detonation and third with deflagrative ignition and delayed transition to detonation. Methane addition caused an increase in the range of 3.25 – 5.03% in the critical shock wave velocity necessary for transition to detonation for all mixtures considered. For example in stoichiometric mixture with 5% methane in fuel (95% hydrogen in fuel) in air the transition to detonation velocity was approx. 752 m/s (an increase of 37 m/s from hydrogen-air) corresponding to M = 1.89 (an increase of 0.14 from hydrogen-air) and 75.7% (an increase of 4.7% from hydrogen-air) of speed of sound in products. Also similar to hydrogen-air mixture the transition to detonation velocity increased for leaner and richer mixture. Moreover it was observed that methane addition in general increased the pressure limit at the corner necessary for transition to detonation.
Municipal Wastewater Reclamation: Reclaimed Water for Hydrogen Production by Electrolysis - A Case Study
Apr 2023
Publication
This paper presents an analysis of a treatment system selection for municipal wastewater stream based on the DuPont Water Solutions WAVE software. The results obtained based on an analysis of 7 different processing cases studies (ultrafiltration and reverse osmosis) confirmed that the application of 2-pass membrane systems enables the reclamation of water from municipal wastewater that fulfills the requirements concerning the quality of water intended as electrolyzer feedstock as the obtained water exhibited a conductivity of < 5 µS/cm. Depending on the analyzed case study the attainable level of water reclamation ranged from 68.8 to 84.1 % at an energy consumption of 606.1 – 2 694 kWh/d. The results of this work not only confirm that the selected pro cessing solutions make it possible to reclaim water from municipal wastewater but also confirm the necessity of using software to simulate the membrane system operation to select the most economic and cost-effective solution.
Hydrogen Storage Capacity of Salt Caverns and Deep Aquifers Versus Demand for Hydrogen Storage: A Case Study of Poland
Nov 2023
Publication
Geological structures in deep aquifers and salt caverns can play an important role in large-scale hydrogen storage. However more work needs to be done to address the hydrogen storage demand for zero-emission energy systems. Thus the aim of the article is to present the demand for hydrogen storage expressed in the number of salt caverns in bedded rock salt deposits and salt domes or the number of structures in deep aquifers. The analysis considers minimum and maximum hydrogen demand cases depending on future energy system configurations in 2050. The method used included the estimation of the storage capacity of salt caverns in bedded rock salt deposits and salt domes and selected structures in deep aquifers. An estimation showed a large hydrogen storage potential of geological structures. In the case of analyzed bedded rock salt deposits and salt domes the average storage capacity per cavern is 0.05–0.09 TWhH2 and 0.06–0.20 TWhH2 respectively. Hydrogen storage capacity in analyzed deep aquifers ranges from 0.016 to 4.46 TWhH2. These values indicate that in the case of the upper bound for storage demand there is a need for the 62 to 514 caverns depending on considered bedded rock salt deposits and salt domes or the 9 largest analyzed structures in deep aquifers. The results obtained are relevant to the discussion on the global hydrogen economy and the methodology can be used for similar considerations in other countries.
Assessment of Energy Footprint of Pure Hydrogen-Supplied Vehicles in Real Conditions of Long-Term Operation
Jul 2024
Publication
The desire to maintain CO2 concentrations in the global atmosphere implies the need to introduce ’new’ energy carriers for transport applications. Therefore the operational consumption of each such potential medium in the ’natural’ exploitation of vehicles must be assessed. A useful assessment method may be the vehicle’s energy footprint resulting from the theory of cumulative fuel consumption presented in the article. Using a (very modest) database of long-term use of hydrogen-powered cars the usefulness of this method was demonstrated. Knowing the energy footprint of vehicles of a given brand and type and the statistical characteristics of the footprint elements it is also possible to assess vehicle fleets in terms of energy demand. The database on the use of energy carriers such as hydrogen in the long-term operation of passenger vehicles is still relatively modest; however as it has been shown valuable data can be obtained to assess the energy demand of vehicles of a given brand and type. Access to a larger operational database will allow for wider use of the presented method.
Probabilistic Analysis of Low-Emission Hydrogen Production from a Photovoltaic Carport
Oct 2024
Publication
This article presents a 3D model of a yellow hydrogen generation system that uses the electricity produced by a photovoltaic carport. The 3D models of all key system components were collected and their characteristics were described. Based on the design of the 3D model of the photovoltaic carport the amount of energy produced monthly was determined. These quantities were then applied to determine the production of low-emission hydrogen. In order to increase the amount of low-emission hydrogen produced the usage of a stationary energy storage facility was proposed. The Metalog family of probability distributions was adopted to develop a strategic model for low-emission hydrogen production. The hydrogen economy of a company that uses small amounts of hydrogen can be based on such a model. The 3D modeling and calculations show that it is possible to design a compact low-emission hydrogen generation system using rapid prototyping tools including the photovoltaic carport with an electrolyzer placed in the container and an energy storage facility. This is an effective solution for the climate and energy transition of companies with low hydrogen demand. In the analytical part the Metalog probability distribution family was employed to determine the amount of monthly energy produced by 6.3 kWp photovoltaic systems located in two European countries: Poland and Italy. Calculating the probability of producing specific amounts of hydrogen in two European countries is an answer to a frequently asked question: In which European countries will the production of low-emission hydrogen from photovoltaic systems be the most profitable? As a result of the calculations for the analyzed year 2023 in Poland and Italy specific answers were obtained regarding the probability of monthly energy generation and monthly hydrogen production. Many companies from Poland and Italy are taking part in the European competition to create hydrogen banks. Only those that offer low-emission hydrogen at the lowest prices will receive EU funding.
Review of Environmental Life Cycle Assessment for Fuel Cell Electric Vehicles in Road Transport
Mar 2025
Publication
This article summarizes current research on the life cycle assessment (LCA) of fuel cell electric vehicles (FCEVs) in road transport. Increasing greenhouse gas emissions and climate change are pushing the transport sector to intensify efforts toward decarbonization. One promising solution is the adoption of hydrogen technologies whose development is supported by European Union regulations such as the “Fit for 55” package. FCEVs are characterized by zero emissions during operation but their environmental impact largely depends on the methods of hydrogen production. The use of renewable energy sources in hydrogen production can significantly reduce greenhouse gas emissions while hydrogen produced from fossil fuels can even result in higher emissions compared to internal combustion engine vehicles. This article also discusses the importance of hydrogen refueling infrastructure and the efficiency of fuel storage and transportation systems. In conclusion LCA shows that FCEVs can support the achievement of climate goals provided that the development of hydrogen production technologies based on renewable sources and the corresponding infrastructure is ensured. The authors also highlight the potential of hybrid technologies as a transitional solution in the process of transforming the transport sector.
Hydrogen in Natural Gas Grids: Prospects and Recommendations About Gas Flow Meters
Aug 2024
Publication
To inject green hydrogen (H2) into the existing natural gas (NG) infrastructure is one way to decarbonize the European energy system. However asset readiness is necessary to be successful. Preliminary analysis and experimental results about the compatibility of hydrogen and natural gas mixtures (H2NG) with the actual gas grids make the scientific community confident about the feasibility. Nevertheless specific technical questions need more research. A significant topic of debate is the impact of H2NG mixtures on the performance of state-ofthe-art fiscal measuring devices which are essential for accurate billing. Identifying and addressing any potential degradation in their metrological performance due to H2NG is critical for decision-making. However the literature lacks data about the gas meters’ technologies currently installed in the NG grids such as a comprehensive overview of their readiness at different concentrations while data are fragmented among different sources. This paper addresses these gaps by analyzing the main characteristics and categorizing more than 20000 gas meters installed in THOTH2 project partners’ grids and by summarizing the performance of traditional technologies with H2NG mixtures and pure H2 based on literature review operators experience and manufacturers knowledge. Based on these insights recommendations are given to stakeholders on overcoming the identified barriers to facilitate a smooth transition.
Green Energy Fuelling Stations in Road Transport: Poland in the European and Global Context
Aug 2025
Publication
The transition to green energy in the transport sector is becoming a priority in the context of global climate challenges and the European Green Deal. This paper investigates the development of alternative fuelling stations particularly electric vehicle (EV) charging infrastructure and hydrogen stations across EU countries with a focus on Poland. It combines a policy and technology overview with a quantitative scientific analysis offering a multidimensional perspective on green infrastructure deployment. A Pearson correlation analysis reveals significant links between charging station density and both GDP per capita and the share of renewable energy. The study introduces an original Infrastructure Accessibility Index (IAI) to compare infrastructure availability across EU member states and models Poland’s EV charging station demand up to 2030 under multiple growth scenarios. Furthermore the article provides a comprehensive overview of biofuels including first- second- and third-generation technologies and highlights recent advances in hydrogen and renewable electricity integration. Emphasis is placed on life cycle considerations energy source sustainability and economic implications. The findings support policy development toward zero-emission mobility and the decarbonisation of transport systems offering recommendations for infrastructure expansion and energy diversification strategies.
Experimental Investigation on Knock Characteristics from Pre-Chamber Gas Engine Fueled by Hydrogen
Feb 2024
Publication
Hydrogen-fueled engines require large values of the excess air ratio in order to achieve high thermal efficiency. A low value of this coefficient promotes knocking combustion. This paper analyzes the conditions for the occurrence of knocking combustion in an engine with a turbulent jet ignition (TJI) system with a passive pre-chamber. A single-cylinder engine equipped with a TJI system was running with an air-to-fuel equivalence ratio λ in the range of 1.25–2.00 and the center of combustion (CoC) was regulated in the range of 2–14 deg aTDC (top dead center). Such process conditions made it possible to fully analyze the ascension of knock combustion until its disappearance with the increase in lambda and CoC. Measures of knock in the form of maximum amplitude pressure oscillation (MAPO) and integral modulus of pressure oscillation (IMPO) were used. The absolute values of these indices were pointed out which can provide the basis for the definition of knock combustion. Based on our own work the MAPO index > 1 bar was defined determining the occurrence of knocking (without indicating its quality). In addition taking into account MAPO it was concluded that IMPO > 0.13 bar·deg is the quantity responsible for knocking combustion.
Hydrogen Materials and Technologies in the Aspect of Utilization in the Polish Energy Sector
Nov 2024
Publication
Currently modern hydrogen technologies due to their low or zero emissions constitute one of the key elements of energy transformation and sustainable development. The growing interest in hydrogen is driven by the European climate policy aimed at limiting the use of fossil fuels for energy purposes. Although not all opinions regarding the technical and economic potential of hydrogen energy are positive many prepared forecasts and analyses show its prospective importance in several areas of the economy. The aim of this article is to provide a comprehensive review of modern materials current hydrogen technologies and strategies and show the opportunities problems and challenges Poland faces in the context of necessary energy transformation. The work describes the latest trends in the production transportation storage and use of hydrogen. The environmental social and economic aspects of the use of green hydrogen were discussed in addition to the challenges and expectations for the future in the field of hydrogen technologies. The main goals of the development of the hydrogen economy in Poland and the directions of actions necessary to achieve them were also presented. It was found that the existence of the EU CO2 emissions allowance trading system has a significant impact on the costs of hydrogen production. Furthermore the production of green hydrogen will become economically justified as the costs of energy obtained from renewable sources decrease and the costs of electrolysers decline. However the realisation of this vision depends on the progress of scientific research and technical innovations that will reduce the costs of hydrogen production. Government support mechanisms for the development of hydrogen infrastructure and technologies will also be of key importance.
The Impact of the Configuration of a Hydrogen Refueling Station on Risk Level
Nov 2024
Publication
The paper discusses potential hazards at hydrogen refueling stations for transportation vehicles: cars and trucks. The main hazard analyzed here is an uncontrolled gas release due to a failure in one of the structures in the station: storage tanks of different pressure levels or a dispenser. This may lead to a hydrogen cloud occurring near the source of the release or at a given distance. The range of the cloud was analyzed in connection to the amount of the released gas and the wind velocity. The results of the calculations were compared for chosen structures in the station. Then potential fires and explosions were investigated. The hazard zones were calculated with respect to heat fluxes generated in the fires and the overpressure generated in explosions. The maximum ranges of these zones vary from about 14 to 30 m and from about 9 to 14 m for a fires and an explosions of hydrogen respectively. Finally human death probabilities are presented as functions of the distance from the sources of the uncontrolled hydrogen releases. These are shown for different amounts and pressures of the released gas. In addition the risk of human death is determined along with the area where it reaches the highest value in the whole station. The risk of human death in this area is 1.63 × 10−5 [1/year]. The area is approximately 8 square meters.
Carbon Dioxide Emission in Hydrogen Production Technology from Coke Oven Gas with Life Cycle Approach
Oct 2016
Publication
The analysis of Carbon Footprint (CF) for technology of hydrogen production from cleaned coke oven gas was performed. On the basis of real data and simulation calculations of the production process of hydrogen from coke gas emission indicators of carbon dioxide (CF) were calculated. These indicators are associated with net production of electricity and thermal energy and direct emission of carbon dioxide throughout a whole product life cycle. Product life cycle includes: coal extraction and its transportation to a coking plant the process of coking coal purification and reforming of coke oven gas carbon capture and storage. The values were related to 1 Mg of coking blend and to 1 Mg of the hydrogen produced. The calculation is based on the configuration of hydrogen production from coke oven gas for coking technology available on a commercial scale that uses a technology of coke dry quenching (CDQ). The calculations were made using ChemCAD v.6.0.2 simulator for a steady state of technological process. The analysis of carbon footprint was conducted in accordance with the Life Cycle Assessment (LCA).
Hydrogen Storage Technology, and Its Challenges: A Review
Mar 2025
Publication
This paper aims to present an overview of the current state of hydrogen storage methods and materials assess the potential benefits and challenges of various storage techniques and outline future research directions towards achieving effective economical safe and scalable storage solutions. Hydrogen is recognized as a clean secure and costeffective green energy carrier with zero emissions at the point of use offering significant contributions to reaching carbon neutrality goals by 2050. Hydrogen as an energy vector bridges the gap between fossil fuels which produce greenhouse gas emissions global climate change and negatively impact health and renewable energy sources which are often intermittent and lack sustainability. However widespread acceptance of hydrogen as a fuel source is hindered by storage challenges. Crucially the development of compact lightweight safe and cost-effective storage solutions is vital for realizing a hydrogen economy. Various storage methods including compressed gas liquefied hydrogen cryocompressed storage underground storage and solid-state storage (material-based) each present unique advantages and challenges. Literature suggests that compressed hydrogen storage holds promise for mobile applications. However further optimization is desired to resolve concerns such as low volumetric density safety worries and cost. Cryo-compressed hydrogen storage also is seen as optimal for storing hydrogen onboard and offers notable benefits for storage due to its combination of benefits from compressed gas and liquefied hydrogen storage by tackling issues related to slow refueling boil-off and high energy consumption. Material-based storage methods offer advantages in terms of energy densities safety and weight reduction but challenges remain in achieving optimal stability and capacities. Both physical and material-based storage approaches are being researched in parallel to meet diverse hydrogen application needs. Currently no single storage method is universally efficient robust and economical for every sector especially for transportation to use hydrogen as a fuel with each method having its own advantages and limitations. Moreover future research should focus on developing novel materials and engineering approaches in order to overcome existing limitations provide higher energy density than compressed hydrogen and cryo-compressed hydrogen storage at 70 MPa enhance costeffectiveness and accelerate the deployment of hydrogen as a clean energy vector.
Optimal Design and Dispatch of Hydrogen Systems Inegrated in Combined Heat and Power Plants for Improving Hydrogen Economy through Excess Heat and Electricity Grid Services
Jul 2025
Publication
Renewable hydrogen is a promising energy carrier that facilitates greater renewable energy integration while supporting the decarbonization of the industrial and transportation sectors. This study investigates the optimal design and operation of two hydrogen-based energy systems. The first energy system comprises an electrolyser compressor and hydrogen storage system. It aims to supply hydrogen as a drop-in fuel for a future potential hydrogen fleet. The electrolyser provides excess heat and oxygen for a combined heat and power (CHP) plantand ancillary services to the grid for frequency support. In the second energy system the hydrogen stored in the hydrogen tank is used by a fuel cell or gas turbine to sell electricity to the grid following price signals. The optimisation algorithm developed in this study finds the optimal capacities for the hydrogen production and storage systems and optimizes the hourly dispatch of the electrolyser. The profitability of the first investigated hydrogen-based energy system is closely connected to the hydrogen production cost which fluctuates depending on the average electricity price. The profitability is also affected by the average compensation of the ancillary services and to a lesser extent by the value of excess heat and oxygen produced during the electrolysis. Only 2020 marked out by the lowest average electricity price among the investigated years could lead to a profitable investment for the first studied energy system. The breakeven hydrogen selling price varied between 24.13 SEK/kg in 2020 to 65.63 SEK/kg in 2022 while considering the extra revenues of the grid service compensation and heat and oxygen sale. If only hydrogen sale was considered the breakeven hydrogen selling prices varied between 31.28 SEK/kg in 2020 to 86.08 SEK/kg in 2022. For the second investigated hydrogen-based energy system if the threshold electricity price for activating the hydrogen consumption system is the 90th percentile of the electricity prices every week the profitability is never attained. The fuel cell system leads to lower electrolyser and hydrogen tank capacities to meet the targeted power supply given the higher assumed efficiency as compared to the gas turbine. Nevertheless the fuel cell system shows in all the investigated subcases lower net present values as compared to the gas turbine subcases due to the higher investment and running costs. The fuel cell system shows better performances in terms of net present values than the gas turbine only in an optimistic sub case marked out by higher conversion efficiencies and lower investment and running costs for the fuel cell. The profitability of the second investigated hydrogen-based energy system is guaranteed only at an annual average electricity price above 2.7 SEK/kWh.
Hydrogen Storage with Gravel and Pipes in Lakes and Reservoirs
Sep 2024
Publication
Climate change is projected to have substantial economic social and environmental impacts worldwide. Currently the leading solutions for hydrogen storage are in salt caverns and depleted natural gas reservoirs. However the required geological formations are limited to certain regions. To increase alternatives for hydrogen storage this paper proposes storing hydrogen in pipes filled with gravel in lakes hydropower and pumped hydro storage reservoirs. Hydrogen is insoluble in water non-toxic and does not threaten aquatic life. Results show the levelized cost of hydrogen storage to be 0.17 USD kg−1 at 200 m depth which is competitive with other large scale hydrogen storage options. Storing hydrogen in lakes hydropower and pumped hydro storage reservoirs increases the alternatives for storing hydrogen and might support the development of a hydrogen economy in the future. The global potential for hydrogen storage in reservoirs and lakes is 3 and 12 PWh respectively. Hydrogen storage in lakes and reservoirs can support the development of a hydrogen economy in the future by providing abundant and cheap hydrogen storage.
Comparing Sustainable Fuel Adoption in the Energy Transition for Maritime and Aviation Transport
Jul 2025
Publication
Maritime and aviation transport are widely recognised as sectors where reducing greenhouse gas emissions is particularly challenging due to their reliance on energy-dense fuels and the challenges associated with direct electrification. These sectors face increasing pressure to defossilise and reduce emissions in line with global climate goals while simultaneously facing unique technological operational and economic uncertainties. This study addresses a key research gap by comparing the maritime and aviation sectors for common factors and sector-specific differences in their transition to green e-fuels produced from renewable electricity and sustainable CO2. A techno-economic assessment is conducted to evaluate alternative fuel and propulsion options using the levelised cost of mobility framework. The analysis also incorporates the pricing of non-CO2 greenhouse gases and air pollutant emissions. Results show that e-ammonia or e-LNG combustion is the most cost-effective option for maritime transport when emission costs are excluded whereas hydrogen fuel cells become more economical when these costs are internalised. In aviation e-kerosene use in conventional aircraft presents the lowest costs regardless of the year or emission pricing. The findings highlight the importance of considering unique characteristics of each sector and tailored defossilisation and decarbonisation strategies that consider sector-specific constraints. To sustainably meet the growing demand for transport fuels rapid investments in renewable electricity generation electrolysers and e-fuel synthesis are essential. Development of strong regulatory frameworks and financial instruments will be critical to support early deployment of e-fuels and minimise the risks.
The Emerging Role of Artificial Intelligence in Enhancing Energy Efficiency and Reducing GHG Emissions in Transport Systems
Dec 2024
Publication
The global transport sector a significant contributor to energy consumption and greenhouse gas (GHG) emissions requires innovative solutions to meet sustainability goals. Artificial intelligence (AI) has emerged as a transformative technology offering opportunities to enhance energy efficiency and reduce GHG emissions in transport systems. This study provides a comprehensive review of AI’s role in optimizing vehicle energy management traffic flow and alternative fuel technologies such as hydrogen fuel cells and biofuels. It explores AI’s potential to drive advancements in electric and autonomous vehicles shared mobility and smart transportation systems. The economic analysis demonstrates the viability of AI-enhanced transport considering Total Cost of Ownership (TCO) and cost-benefit outcomes. However challenges such as data quality computational demands system integration and ethical concerns must be addressed to fully harness AI’s potential. The study also highlights the policy implications of AI adoption underscoring the need for supportive regulatory frameworks and energy policies that promote innovation while ensuring safety and fairness.
Probabilistic Analysis of Green Hydrogen Production from a Mix of Solar and Wind Energy
Sep 2024
Publication
This article describes an example of using the measurement data from photovoltaic systems and wind turbines to perform practical probabilistic calculations around green hydrogen generation. First the power generated in one month by a ground-mounted photovoltaic system with a peak power of 3 MWp is described. Using the Metalog family of probability distributions the probability of generating selected power levels corresponding to the amount of green hydrogen produced is calculated. Identical calculations are performed for the simulation data allowing us to determine the power produced by a wind turbine with a maximum power of 3.45 MW. After interpolating both time series of the power generated by the renewable energy sources to a common sampling time they are summed. For the sum of the power produced by the photovoltaic system and the wind turbine the probability of generating selected power levels corresponding to the amount of green hydrogen produced is again calculated. The presented calculations allow us to determine with probability distribution accuracy the amount of hydrogen generated from the energy sources constituting a mix of photovoltaics and wind. The green hydrogen production model includes the hardware and the geographic context. It can be used to determine the preliminary assumptions related to the production of large amounts of green hydrogen in selected locations. The calculations presented in this article are a practical example of Business Intelligence.
A Review of Green Hydrogen Production Based on Solar Energy; Techniques and Methods
Feb 2023
Publication
The study examines the methods for producing hydrogen using solar energy as a catalyst. The two commonly recognised categories of processes are direct and indirect. Due to the indirect processes low efficiency excessive heat dissipation and dearth of readily available heat-resistant materials they are ranked lower than the direct procedures despite the direct procedures superior thermal performance. Electrolysis bio photosynthesis and thermoelectric photodegradation are a few examples of indirect approaches. It appears that indirect approaches have certain advantages. The heterogeneous photocatalytic process minimises the quantity of emissions released into the environment; thermochemical reactions stand out for having low energy requirements due to the high temperatures generated; and electrolysis is efficient while having very little pollution created. Electrolysis has the highest exergy and energy efficiency when compared to other methods of creating hydrogen according to the evaluation.
The Financial Results of Energy Sector Companies in Europe and Their Involvement in Hydrogen Production
Jun 2025
Publication
In response to growing environmental concerns hydrogen production has emerged as a critical element in the transition to a sustainable global economy. We evaluate the impact of hydrogen production on both the financial performance and market value of energy sector companies using balanced panel data from 288 European-listed firms over the period of 2018 to 2022. The findings reveal a paradox. While hydrogen production imposes significant financial constraints it is positively recognized by market participants. Despite short-term financial challenges companies engaged in hydrogen production experience higher market value as investors view these activities as a long-term growth opportunity aligned with global sustainability goals. We contribute to the literature by offering empirical evidence on the financial outcomes and market valuation of hydrogen engagement distinguishing between production and storage activities and further categorizing production into green blue and gray hydrogen. By examining these nuances we highlight the complex relationship between financial market results. While hydrogen production may negatively impact short-term financial performance its potential for long-term value creation driven by decarbonization efforts and sustainability targets makes it attractive to investors. Ultimately this study provides valuable insights into how hydrogen engagement shapes corporate strategies within the evolving European energy landscape.
Biohydrogen Production from Industrial Waste: The Role of Pretreatment Methods
Oct 2025
Publication
This study aimed to investigate the effectiveness of dark fermentation in biohydrogen production from agro-industrial wastes including apple pomace brewer’s grains molasses and potato powder subjected to different pretreatment methods. The experiments were conducted at a laboratory scale using 1000 cm3 anaerobic reactors at a temperature of 35 ◦C and anaerobic sludge as the inoculum. The highest yield of hydrogen was obtained from pre-treated apple pomace (101 cm3/g VS). Molasses a less complex substrate compared to the other raw materials produced 25% more hydrogen yield following pretreatment. Methanogens are sensitive to high temperatures and low-pH conditions. Nevertheless methane constituted 1–6% of the total biogas under these conditions. The key factor was appropriate treatment of the inoculum to limit competition from methanogens. Increasing the inoculum dose from 150 cm3/dm3 to 250 cm3/dm3 had no further effect on biogas production. The physicochemical parameters and VFA data confirmed the stability and usefulness of activated sludge as a source of microbial cultures for H2 production via dark fermentation.
Scaling of Automotive Fuel Cells in Terms of Operating Indicators
Oct 2025
Publication
The search for alternatives to fossil fuels has led to hydrogen becoming an important factor in the powering means of transportation. Its most effective application is in fuel cells. A single fuel cell is not a sufficient source of power which is why a stack of fuel cells is the more common solution. Fuel cells are tested using single units as this allows all cell parameters (the current density flow rates and efficiency) to be evaluated. Therefore the scalability of fuel cells is an essential factor. This paper analyses the scalability of fuel cells with a power of approximately 100 kW and 1.2 kW. Road tests of the fuel cells were compared with stationary tests which allowed the load to be reproduced and scaled. This provided a representation of the scaled current and the scalable power of the fuel cell. The research provided voltage–current characteristics of fuel cell stacks and their individual equivalents. It was concluded that regardless of the power scaling or current values the characteristics obtain similar patterns. A very important element of the research is the awareness of the properties of these cells (the number of cells and active charge exchange area) in order to compare the unit characteristics of fuel cells.
Analysis of the Efficiency of Hydrogen Fuel Cell Vehicle (HFCV) Applications in Manufacturing Processes Using Computer Simulation
Oct 2025
Publication
Implementing innovative solutions in the internal transport of manufacturing enterprises is becoming an important element of improving operational efficiency and reducing greenhouse gas emissions. This article assesses the potential of hydrogen fuel cell (HFCV) forklifts in a steel products manufacturing plant. The verification was carried out using a computer simulation which enabled the comparison of electric combustion and HFCV fleets under identical logistical conditions. The results showed that the HFCV fleet allowed for shorter process execution times and higher utilization compared to electric and combustion variants mainly due to the elimination of charging and refueling interruptions. Additionally when powered by green hydrogen the HFCV fleet offered clear environmental benefits and lower operating costs. The study confirms that HFCV technology can improve the efficiency of internal transport and reduce energy-related operating expenses although the costs of hydrogen refueling infrastructure were not included and should be addressed in future research.
The Concept of an Infrastructure Location to Supply Buses with Hydrogen: A Case Study of the West Pomeranian Voivodeship in Poland
Jun 2025
Publication
The growing energy crisis and increasing threat of climate change are driving the need to take action regarding the use of alternative fuels in transport including public transport. Hydrogen is undoubtedly a fuel which is environmentally friendly and constitutes an alternative to fossil fuels. The wider deployment of hydrogen-powered vehicles involves the need to adapt infrastructure to support the operation of these vehicles. Such infrastructure includes refuelling stations for hydrogen-powered vehicles. The widespread use of hydrogen-powered vehicles is dependent on the development of a network of hydrogen refuelling stations. The aim of this article is to propose the conceptual location of infrastructure for fuelling public transport vehicles with hydrogen in selected cities of the West Pomeranian Voivodeship in particular the cities of Szczecin and Koszalin. The methodology used to determine the number of refuelling stations is described and the concept of the location for the refuelling stations has been proposed. Based on a set assumptions it was stated that two stations may be located in the Voivodeship in 2025 and seven stations in 2040. The research results will be of interest to infrastructure developers public transport companies and municipalities involved in making decisions related to the purchase and operation of hydrogen-powered buses.
Potential of P-Type Cooper Oxides, N-type Titanium Oxides and their Mixtures as Resistive Hydrogen Gas Sensors - A Review
Oct 2025
Publication
Metal oxides (e.g. SnO2 ZnO TiO2) have been widely investigated materials for gas sensing applications including hydrogen detection. However the potential for hydrogen sensing of metal oxides such as CuO In2O3 NiO exhibiting p-type conduction has been largely overlooked. Over the last 15 years structures based on TiO2 and CuO have gained increasing interest as a promising system for hydrogen detection. Therefore this article aims to: 1) provide an overview of the performance of TiO2 as a reference material and discuss methods to enhance its sensing performance 2) summarize and highlight the role of copper oxides in hydrogen gas detection as the materials that have predominantly been studied for H2S detection 3) review efforts made to improve the sensing performance of heterostructures of CuTiOx from structures with charge compensation effect to those successfully sensing hydrogen 4) present the potential of CuTiOx for H2 detection.
Numerical Modelling of Gas Mixing in Salt Caverns During Cyclic Hydrogen Storage
Oct 2025
Publication
This study presents the development of a robust numerical model for simulating underground hydrogen storage (UHS) in salt caverns with a particular focus on the interactions between original gas-methane (CH4) and injected gas represented by hydrogen (H2). Using the Schlumberger Eclipse 300 compositional reservoir simulator the cavern was modelled as a highly permeable porous medium to accurately represent gas flow dynamics. Two principal mixing mechanisms were investigated: physical dispersion modelled by numerical dispersion and molecular diffusion. Multiple cavern configurations and a range of dispersion–diffusion coefficients were assessed. The results indicate that physical dispersion is the primary factor affecting hydrogen purity during storage cycles while molecular diffusion becomes more significant during long-term gas storage. Gas mixing was shown to directly impact the calorific value and quality of withdrawn hydrogen. This work demonstrates the effectiveness of commercial reservoir simulators for UHS analysis and proposes a methodological framework for evaluating hydrogen purity in salt cavern storage operations.
Hydrogen Direct Reduced Iron Melting in an Electric Arc Furnace: Benefits of In Situ Monitoring
Oct 2025
Publication
The transition toward environmentally friendly steelmaking using hydrogen direct reduced iron as feed material in electric arc furnaces will eventually require process adjustments due to changes in the pellet properties when compared to e.g. blast furnace pellets. To this end the melting of hydrogen direct reduced iron pellets with 68 and 100% reduction degrees and Fe content of 67.24% was investigated in a laboratory-scale electric arc furnace. The presence of iron oxide-rich slag had a significant effect on the arc movement on the melt and an inhibiting effect on iron evaporation. The melting was monitored with video recording and optical emission spectroscopy. The videos were used to monitor the melting behavior whereas optical emissions revealed iron gangue elements and hydrogen from the pellets radiating in the plasma. Furthermore the flow of the melt is well seen in the videos as well as the movement of slag droplets on the melt surface. After the experiments the metal had silica-rich inclusions whereas slag had mostly penetrated into the crucible. The most notable differences in melting behavior can be attributed to the iron oxide-rich slag its interaction with the arc and penetration into the crucible and how it affects the arc movement and heat transfer.
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