Sweden
Towards Electrochemical Hydrogen Storage in Liquid Organic Hydrogen Carriers via Proton-coupled Electron Transfers
Jun 2022
Publication
Green hydrogen is identified as one of the prime clean energy carriers due to its high energy density and a zero emission of CO2. A possible solution for the transport of H2 in a safe and low-cost way is in the form of liquid organic hydrogen carriers (LOHCs). As an alternative to loading LOHC with H2 via a two-step procedure involving preliminary electrolytic production of H2 and subsequent chemical hydrogenation of the LOHC we explore here the possibility of electrochemical hydrogen storage (EHS) via conversion of proton of a proton donor into a hydrogen atom involved in covalent bonds with the LOHC (R) via a proton-coupled electron transfer (PCET) reaction: . 2 + +2 ― + ox↔ 0 2red We chose 9-fluorenone/fluorenol (Fnone/Fnol) conversion as such a model PCET reaction. The electrochemical activation of Fnone via two sequential electron transfers was monitored with in-situ and operando spectroscopies in absence and in presence of different alcohols as proton donors of different reactivity which enabled us to both quantify and get the mechanistic insight on PCET. The possibility of hydrogen extraction from the loaded carrier molecule was illustrated by chemical activation.
A 1000 MWth Boiler for Chemical-looping Combustion of Solid Fuels – Discussion of Design and Costs
May 2015
Publication
More than 2000 h of solid-fuel CLC operation in a number of smaller pilot units clearly indicate that the concept works. A scale-up of the technology to 1000 MWth is investigated in terms of mass and heat balances flows solids inventories boiler dimensions and the major differences between a full-scale Circulating Fluidized-Bed (CFB) boiler and a Chemical-Looping Combustion CFB (CLC–CFB). Furthermore the additional cost of CLC–CFB relative to CFB technology is analysed and found to be 20 €/tonne CO2. The largest cost is made up of compression of CO2 which is common to all capture technologies. Although the need for oxygen to manage incomplete conversion is estimated to be only a tenth of that of oxy-fuel combustion oxygen production is nonetheless the second largest cost. Other significant costs include oxygen-carrier material increased boiler cost and steam for fluidization of the fuel reactor.
The Potential Role of Ammonia as Marine Fuel—Based on Energy Systems Modeling and Multi-Criteria Decision Analysis
Apr 2020
Publication
To reduce the climate impact of shipping the introduction of alternative fuels is required. There is a range of different marine fuel options but ammonia a potential zero carbon fuel has recently received a lot of attention. The purpose of this paper is to assess the prospects for ammonia as a future fuel for the shipping sector in relation to other marine fuels. The assessment is based on a synthesis of knowledge in combination with: (i) energy systems modeling including the cost-effectiveness of ammonia as marine fuel in relation to other fuels for reaching global climate targets; and (ii) a multi-criteria decision analysis (MCDA) approach ranking marine fuel options while considering estimated fuel performance and the importance of criteria based on maritime stakeholder preferences. In the long-term and to reach global GHG reduction the energy systems modeled indicate that the use of hydrogen represents a more cost-effective marine fuel option than ammonia. However in the MCDA covering more aspects we find that ammonia may be almost as interesting for shipping related stakeholders as hydrogen and various biomass-based fuels. Ammonia may to some extent be an interesting future marine fuel option but many issues remain to be solved before large-scale introduction.
Progress and Challenges on the Thermal Management of Electrochemical Energy Conversion and Storage Technologies: Fuel Cells, Electrolysers, and Supercapacitors
Oct 2021
Publication
It is now well established that electrochemical systems can optimally perform only within a narrow range of temperature. Exposure to temperatures outside this range adversely affects the performance and lifetime of these systems. As a result thermal management is an essential consideration during the design and operation of electrochemical equipment and can heavily influence the success of electrochemical energy technologies. Recently significant attempts have been placed on the maturity of cooling technologies for electrochemical devices. Nonetheless the existing reviews on the subject have been primarily focused on battery cooling. Conversely heat transfer in other electrochemical systems commonly used for energy conversion and storage has not been subjected to critical reviews. To address this issue the current study gives an overview of the progress and challenges on the thermal management of different electrochemical energy devices including fuel cells electrolysers and supercapacitors. The physicochemical mechanisms of heat generation in these electrochemical devices are discussed in-depth. Physics of the heat transfer techniques currently employed for temperature control are then exposed and some directions for future studies are provided.
Reforming Processes for Syngas Production: A Mini-review on the Current Status, Challenges, and Prospects for Biomass Conversion to Fuels
Mar 2022
Publication
Dedicated bioenergy combined with carbon capture and storage are important elements for the mitigation scenarios to limit the global temperature rise within 1.5 °C. Thus the productions of carbon-negative fuels and chemicals from biomass is a key for accelerating global decarbonisation. The conversion of biomass into syngas has a crucial role in the biomass-based decarbonisation routes. Syngas is an intermediate product for a variety of chemical syntheses to produce hydrogen methanol dimethyl ether jet fuels alkenes etc. The use of biomass-derived syngas has also been seen as promising for the productions of carbon negative metal products. This paper reviews several possible technologies for the production of syngas from biomass especially related to the technological options and challenges of reforming processes. The scope of the review includes partial oxidation (POX) autothermal reforming (ATR) catalytic partial oxidation (CPO) catalytic steam reforming (CSR) and membrane reforming (MR). Special attention is given to the progress of CSR for biomass-derived vapours as it has gained significant interest in recent years. Heat demand and efficiency together with properties of the reformer catalyst were reviewed more deeply in order to understand and propose solutions to the problems that arise by the reforming of biomass-derived vapours and that need to be addressed in order to implement the technology on a big scale.
Detection of Contaminants in Hydrogen Fuel for Fuel Cell Electrical Vehicles with Sensors—Available Technology, Testing Protocols and Implementation Challenges
Dec 2021
Publication
Europe’s low-carbon energy policy favors a greater use of fuel cells and technologies based on hydrogen used as a fuel. Hydrogen delivered at the hydrogen refueling station must be compliant with requirements stated in different standards. Currently the quality control process is performed by offline analysis of the hydrogen fuel. It is however beneficial to continuously monitor at least some of the contaminants onsite using chemical sensors. For hydrogen quality control with regard to contaminants high sensitivity integration parameters and low cost are the most important requirements. In this study we have reviewed the existing sensor technologies to detect contaminants in hydrogen then discussed the implementation of sensors at a hydrogen refueling stations described the state-of-art in protocols to perform assessment of these sensor technologies and finally identified the gaps and needs in these areas. It was clear that sensors are not yet commercially available for all gaseous contaminants mentioned in ISO14687:2019. The development of standardized testing protocols is required to go hand in hand with the development of chemical sensors for this application following a similar approach to the one undertaken for air sensors.
Achieving Carbon-neutral Iron and Steelmaking in Europe Through the Deployment of Bioenergy with Carbon Capture and Storage
Jan 2019
Publication
The 30 integrated steel plants operating in the European Union (EU) are among the largest single-point CO2 emitters in the region. The deployment of bioenergy with carbon capture and storage (bio-CCS) could significantly reduce their emission intensities. In detail the results demonstrate that CO2 emission reduction targets of up to 20% can be met entirely by biomass deployment. A slow CCS technology introduction on top of biomass deployment is expected as the requirement for emission reduction increases further. Bio-CCS could then be a key technology particularly in terms of meeting targets above 50% with CO2 avoidance costs ranging between €60 and €100 tCO2−1 at full-scale deployment. The future of bio-CCS and its utilisation on a larger scale would therefore only be viable if such CO2 avoidance cost were to become economically appealing. Small and medium plants in particular would economically benefit from sharing CO2 pipeline networks. CO2 transport however makes a relatively small contribution to the total CO2 avoidance cost. In the future the role of bio-CCS in the European iron and steelmaking industry will also be influenced by non-economic conditions such as regulations public acceptance realistic CO2 storage capacity and the progress of other mitigation technologies.
Hydrogen Production in the Swedish Power Sector: Considering Operational Volatilities and Long-term Uncertainties
Nov 2020
Publication
With more renewables on the Swedish electricity market while decommissioning nuclear power plants electricity supply increasingly fluctuates and electricity prices are more volatile. There is hence a need for securing the electricity supply before energy storage solutions become widespread. Electricity price fluctuations moreover affect operating income of nuclear power plants due to their inherent operational inflexibility. Since the anticipated new applications of hydrogen in fuel cell vehicles and steel production producing hydrogen has become a potential source of income particularly when there is a surplus supply of electricity at low prices. The feasibility of investing in hydrogen production was investigated in a nuclear power plant applying Swedish energy policy as background. The analysis applies a system dynamics approach incorporating the stochastic feature of electricity supply and prices. The study revealed that hydrogen production brings alternative opportunities for large-scale electricity production facilities in Sweden. Factors such as hydrogen price will be influential and require in-depth investigation. This study provides guidelines for power sector policymakers and managers who plan to engage in hydrogen production for industrial applications. Although this study was focused upon nuclear power sources it can be extended to hydrogen production from renewable energy sources such as wind and solar.
Transient Numerical Modeling and Model Predictive Control of an Industrial-scale Steam Methane Reforming Reactor
Mar 2021
Publication
A steam methane reforming reactor is a key equipment in hydrogen production and numerical analysis and process control can provide a critical insight into its reforming mechanisms and flexible operation in real engineering applications. The present paper firstly studies the transport phenomena in an industrial-scale steam methane reforming reactor by transient numerical simulations. Wall effect and local non thermal equilibrium is considered in the simulations. A temperature profile of the tube outer wall is given by user defined functions integrated into the ANSYS FLUENT software. Dynamic simulations show that the species distribution is closely related to the temperature distribution which makes the temperature of the reactor tube wall an important factor for the hydrogen production of the reformer and the thermal conductivity of the catalyst network is crucial in the heat transfer in the reactor. Besides there exists a delay of the reformer's hydrogen production when the temperature profile of the tube wall changes. Among inlet temperature inlet mass flow rate and inlet steam-to-carbon (S/C) ratio the mass flow rate is the most influencing factor for the hydrogen production. The dynamic matrix control (DMC) scheme is subsequently designed to manipulate the mole fraction of hydrogen of the outlet to the target value by setting the temperature profile trajectory of the reforming tube with time. The proportional-integral control strategy is also studied for comparison. The closed-loop simulation results show that the proposed DMC control strategy can reduce the overshoot and have a small change of the input variable. In addition the disturbances of feed disturbance can also be well rejected to assure the tracking performance indicating the superiority of the DMC controller. All the results give insight to the theoretical analysis and controller design of a steam methane reformer and demonstrate the potential of the CFD modeling in study the transport mechanism and the idea of combining CFD modelling with controller design for the real application.
Levelized Cost of Hydrogen for Refueling Stations with Solar PV and Wind in Sweden: On-grid or Off-grid?
Dec 2021
Publication
The European Union expects that hydrogen will play a vital role in future energy systems. Fuel cell electric vehicles currently present a key development path for electrification of the transport sector which requires infrastructure investments of hydrogen refueling stations preferably powered by renewables such as solar and wind energy. The economic feasibility of refueling stations depends on geographical locations. This study introduces a model to identify the key cost components of renewable hydrogen for refueling stations and simulates the performance using solar radiation wind speed and electricity price data in a selection of Swedish cities. The study demonstrates the importance of integrating the electricity grid in green hydrogen production. Wind speed is crucial in reducing the cost whereas solar radiation has less influence. In addition a combination of solar and wind brings better performance in an off-grid scenario. The most encouraging finding is the cost of 35e72 SEK/kg (3.5e7.2 V/kg) which is competitive with reported costs in other EUcountries especially since this cost excludes any government support scheme. The study provides a reference for investors and policy makers foreseeing the industrial landscape for hydrogen energy development.
Roadmap to Hybrid Offshore System with Hydrogen and Power Co-generation
Sep 2021
Publication
Constrained by the expansion of the power grid the development of offshore wind farms may be hindered and begin to experience severe curtailment or restriction. The combination of hydrogen production through electrolysis and hydrogen-to-power is considered to be a potential option to achieve the goal of low-carbon and energy security. This work investigates the competitiveness of different system configurations to export hydrogen and/or electricity from offshore plants with particular emphasis on unloading the mixture of hydrogen and electricity to end-users on land. Including the levelized energy cost and net present value a comprehensive techno-economic assessment method is proposed to analyze the offshore system for five scenarios. Assuming that the baseline distance is 10 km the results show that exporting hydrogen to land through pipelines shows the best economic performance with the levelized energy cost of 3.40 $/kg. For every 10 km increase in offshore distance the net present value of the project will be reduced by 5.69 MU$ and the project benefit will be positive only when the offshore distance is less than 53.5 km. An important finding is that the hybrid system under ship transportation mode is not greatly affected by the offshore distance. Every 10% increase in the proportion of hydrogen in the range of 70%–100% can increase the net present value by 1.43–1.70 MU$ which will increase by 7.36–7.37 MU$ under pipeline transportation mode. Finally a sensitivity analysis was carried out to analyze the wind speed electricity and hydrogen prices on the economic performance of these systems.
A Comparison of Two Hydrogen Storages in a Fossil Free Direct Reduced Iron Process
Jul 2021
Publication
Hydrogen direct reduction has been proposed as a means to decarbonize primary steelmaking. Preferably the hydrogen necessary for this process is produced via water electrolysis. A downside to electrolysis is the large electricity demand. The electricity cost of water electrolysis may be reduced by using a hydrogen storage to exploit variations in electricity price i.e. producing more hydrogen when the electricity price is low and vice versa. In this paper we compare two kinds of hydrogen storages in the context of a hydrogen direct reduction process via simulations based on historic Swedish electricity prices: the storage of gaseous hydrogen in an underground lined rock cavern and the storage of hydrogen chemically bound in methanol. We find the methanol-based storages to be economically advantageous to lined rock caverns in several scenarios. The main advantages of methanol-based storage are the low investment cost of storage capacity and the possibility to decouple storage capacity from rate capacity. Nevertheless no storage option is found to be profitable for historic Swedish electricity prices. For the storages to be profitable electricity prices must be volatile with relatively frequent high peaks which has happened rarely in Sweden in recent years. However such scenarios may become more common with the expected increase of intermittent renewable power in the Swedish electricity system.
Sustainable Offshore Oil and Gas Fields Development: Techno-economic Feasibility Analysis of Wind–hydrogen–natural Gas Nexus
Jul 2021
Publication
Offshore oil and gas field development consumes quantities of electricity which is usually provided by gas turbines. In order to alleviate the emission reduction pressure and the increasing pressure of energy saving governments of the world have been promoting the reform of oil and gas fields for years. Nowadays environmentally friendly alternatives to provide electricity are hotspots such as the integration of traditional energy and renewable energy. However the determination of system with great environmental and economic benefits is still controversial. This paper proposed a wind– hydrogen–natural gas nexus (WHNGN) system for sustainable offshore oil and gas fields development. Combining the optimization model with the techno-economic evaluation model a comprehensive evaluation framework is established for techno-economic feasibility analysis. In addition to WHNGN system another two systems are designed for comparison including the traditional energy supply (TES) system and wind–natural gas nexus (WNGN) system. An offshore production platforms in Bohai Bay in China is taken as a case and the results indicate that: (i) WNGN and WHNGN systems have significant economic benefits total investment is decreased by 5190 and 5020 million $ respectively and the WHNGN system increases 4174 million $ profit; (ii) WNGN and WHNGN systems have significant environmental benefits annual carbon emission is decreased by 15 and 40.2 million kg respectively; (iii) the system can be ranked by economic benefits as follows: WHNGN >WNGN > TES; and (iV) the WHNGN system is more advantageous in areas with high hydrogen and natural gas sales prices such as China Kazakhstan Turkey India Malaysia and Indonesia.
Numerical Modeling for Rapid Charging of Hydrogen Gas Vessel in Fuel Cell Vehicle
Feb 2023
Publication
As a fuel for power generation high-pressure hydrogen gas is widely used for transportation and its efficient storage promotes the development of fuel cell vehicles (FCVs). However as the filling process takes such a short time the maximum temperature in the storage tank usually undergoes a rapid increase which has become a thorny problem and poses great technical challenges to the steady operation of hydrogen FCVs. For security reasons SAE J2601/ISO 15869 regulates a maximum temperature limit of 85 ◦C in the specifications for refillable hydrogen tanks. In this paper a two-dimensional axisymmetric and a three-dimensional numerical model for fast charging of Type III 35 MPa and 70 MPa hydrogen vehicle cylinders are proposed in order to effectively evaluate the temperature rise within vehicle tanks. A modified standard k-ε turbulence model is utilized to simulate hydrogen gas charging. The equation of state for hydrogen gas is adopted with the thermodynamic properties taken from the National Institute of Standards and Technology (NIST) database taking into account the impact of hydrogen gas’ compressibility. To validate the numerical model three groups of hydrogen rapid refueling experimental data are chosen. After a detailed comparison it is found that the simulated results calculated by the developed numerical model are in good agreement with the experimental results with average temperature differences at the end time of 2.56 K 4.08 K and 4.3 K. The present study provides a foundation for in-depth investigations on the structural mechanics analysis of hydrogen gas vessels during fast refueling and may supply some technical guidance on the design of charging experiments.
Renewable Hydrogen Supply Chains: A Planning Matrix and an Agenda for Future Research
Oct 2022
Publication
Worldwide energy systems are experiencing a transition to more sustainable systems. According to the Hydrogen Roadmap Europe (FCH EU 2019) hydrogen will play an important role in future energy systems due to its ability to support sustainability goals and will account for approximately 13% of the total energy mix in the coming future. Correct hydrogen supply chain (HSC) planning is therefore vital to enable a sustainable transition. However due to the operational characteristics of the HSC its planning is complicated. Renewable hydrogen supply can be diverse: Hydrogen can be produced de-centrally with renewables such as wind and solar energy or centrally by using electricity generated from a hydro power plant with a large volume. Similarly demand for hydrogen can also be diverse with many new applications such as fuels for fuel cell electrical vehicles and electricity generation feedstocks in industrial processes and heating for buildings. The HSC consists of various stages (production storage distribution and applications) in different forms with strong interdependencies which further increase HSC complexity. Finally planning of an HSC depends on the status of hydrogen adoption and market development and on how mature technologies are and both factors are characterised by high uncertainties. Directly adapting the traditional approaches of supply chain planning for HSCs is insufficient. Therefore in this study we develop a planning matrix with related planning tasks leveraging a systematic literature review to cope with the characteristics of HSCs. We focus only on renewable hydrogen due to its relevance to the future low-carbon economy. Furthermore we outline an agenda for future research from the supply chain management perspective in order to support HSC development considering the different phases of HSCs adoption and market development.
Power-to-hydrogen Storage Integrated with Rooftop Photovoltaic Systems and Combined Heat and Power Plants
Jul 2020
Publication
The growing share of intermittent renewable energy sources for power generation indicates an increasing demand for flexibility in the energy system. Energy storage technologies ensure a balance between demand and supply and increase the system flexibility. This study investigates increased application of renewable energy resources at a regional scale. Power-to-gas storage that interacts with a large-scale rooftop photovoltaic system is added to a regional energy system dominated by combined heat and power plants. The study addresses the influence of the storage system on the production planning of the combined heat and power plants and the system flexibility. The system is modeled and the product costs are optimized using the Mixed Integer Linear Programming method as well as considering the effects on CO2 emissions and power import into the regional system. The optimization model is investigated by developing different scenarios for the capacity and cost of the storage system. The results indicate that the proposed storage system increases the system flexibility and can reduce power imports and the marginal emissions by around 53% compared with the current energy system. There is a potential to convert a large amount of excess power to hydrogen and store it in the system. However because of low efficiency a fuel cell cannot significantly contribute to power regeneration from the stored hydrogen. Therefore for about 70% of the year the power is imported to the optimized system to compensate the power shortfalls rather than to use the fuel cell.
Pathways for Low-Carbon Transition of the Steel Industry—A Swedish Case Study
Jul 2020
Publication
The concept of techno-economic pathways is used to investigate the potential implementation of CO2 abatement measures over time towards zero-emission steelmaking in Sweden. The following mitigation measures are investigated and combined in three pathways: top gas recycling blast furnace (TGRBF); carbon capture and storage (CCS); substitution of pulverized coal injection (PCI) with biomass; hydrogen direct reduction of iron ore (H-DR); and electric arc furnace (EAF) where fossil fuels are replaced with biomass. The results show that CCS in combination with biomass substitution in the blast furnace and a replacement primary steel production plant with EAF with biomass (Pathway 1) yield CO2 emission reductions of 83% in 2045 compared to CO2 emissions with current steel process configurations. Electrification of the primary steel production in terms of H-DR/EAF process (Pathway 2) could result in almost fossil-free steel production and Sweden could achieve a 10% reduction in total CO2 emissions. Finally (Pathway 3) we show that increased production of hot briquetted iron pellets (HBI) could lead to decarbonization of the steel industry outside Sweden assuming that the exported HBI will be converted via EAF and the receiving country has a decarbonized power sector.
Improving the Economics of Fossil-free Steelmaking via Co-production of Methanol
Mar 2022
Publication
Steelmaking is responsible for 7% of the global net emissions of carbon dioxide and heavily reducing emissions from currently dominating steelmaking processes is difficult and costly. Recently new steelmaking processes based on the reduction of iron ore with hydrogen (H2) produced via water electrolysis have been suggested. If the electricity input to such processes is fossil-free near-zero carbon dioxide emissions steelmaking is achievable. However the high electricity demand of electrolysis is a significant implementation barrier. A H2 storage may alleviate this via allowing a larger share of H2 to be produced at low electricity prices. However accurately forecasting the dynamics of electricity markets is challenging. This increases the risk of investment in a H2 storage. Here we evaluate a novel methanol-based H2 storage concept for a H2-based steelmaking process that also allows for the coproduction of methanol. During electricity price peaks the methanol can be reformed to produce H2 for the steelmaking process. During prolonged periods of low electricity prices excess methanol can be produced and sold off thus improving the prospects of storage profitability. We use historical electricity prices and a process model to evaluate methanol-fossil-free steel co-production schemes. Methanol coproduction has the potential to improve the economics of H2 supply to a fossil-free steelmaking process by up to an average of 0.40 €/kg H2 across considered scenarios equivalent to a reduction in H2 production electricity costs of 25.0%
Contribution of Potential Clean Trucks in Carbon Peak Pathway of Road Freight Based on Scenario Analysis: A Case Study of China
Oct 2022
Publication
Reducing the carbon emissions from trucks is critical to achieving the carbon peak of road freight. Based on the prediction of truck population and well-to-wheel (WTW) emission analysis of traditional diesel trucks and potential clean trucks including natural gas battery-electric plug-in hybrid electric and hydrogen fuel cell the paper analyzed the total greenhouse gas (GHG) emissions of China's road freight under four scenarios including baseline policy facilitation (PF) technology breakthrough (TB) and PF-TB. The truck population from 2021 to 2035 is predicted based on regression analysis by selecting the data from 2002 to 2020 of the main variables such as the GDP scale road freight turnover road freight volume and the number of trucks. The study forecasts the truck population of different segments such as mini-duty trucks (MiDT) light-duty trucks (LDT) medium-duty trucks (MDT) and heavy-duty trucks (HDT). Relevant WTW emissions data are collected and adopted based on the popular truck in China's market PHEVs have better emission intensity especially in the HDT field which reduces by 51% compared with ICEVs. Results show that the scenario of TB and PF-TB can reach the carbon peak with 0.13% and 1.5% total GHG emissions reduction per year. In contrast the baseline and PF scenario fail the carbon peak due to only focusing on the number of clean trucks while lacking the restrictions on the GHG emission factors of energy and ignoring the improvement of trucks' energy efficiency and the total emissions increased by 29.76% and 16.69% respectively compared with 2020. As the insights adopting clean trucks has an important but limited effect which should coordinate with the transition to low carbon energy and the melioration of clean trucks to reach the carbon peak of road freight in China.
A Multi-period Sustainable Hydrogen Supply Chain Model Considering Pipeline Routing and Carbon Emissions: The Case Study of Oman
Nov 2022
Publication
This paper presents a mathematical model for a multi-period hydrogen supply chain design problem considering several design features not addressed in other studies. The model is formulated as a mixed-integer program allowing the production and storage facilities to be extended over time. Pipeline and tube trailer transport modes are considered for carrying hydrogen. The model also allows finding the optimal pipeline routes and the number of transport units. The objective is to obtain an efficient supply chain design within a given time frame in a way that the demand and carbon dioxide emissions constraints are satisfied and the total cost is minimized. A computer program is developed to ease the problem-solving process. The computer program extracts the geographical information from Google Maps and solves the problem using an optimization solver. Finally the applicability of the proposed model is demonstrated in a case study from Oman.
No more items...