Institution of Gas Engineers & Managers

Today electricity & heat generation transportation and industrial sectors together produce more than 80% of energy-related CO₂ emissions. Hydrogen may be used as an energy carrier and an alternative fuel in the industrial residential and transportation sectors for either heating energy production from fuel cells or direct fueling of vehicles. In particular the use of hydrogen fuel cell vehicles (HFCVs) has the potential to virtually eliminate CO₂ emissions from tailpipes and considerably reduce overall emissions from the transportation sector. Although steam methane reforming (SMR) is the dominant industrial process for hydrogen production environmental concerns associated with CO₂ emissions along with the process intensification and energy optimization are areas that still require improvement. Metallic membrane reactors (MRs) have the potential to address both challenges. MRs operate at significantly lower pressures and temperatures compared with the conventional reactors. Hence the capital and operating expenses could be considerably lower compared with the conventional reactors. Moreover metallic membranes specifically Pd and its alloys inherently allow for only hydrogen permeation making it possible to produce a stream of up to 99.999+% purity.

For smaller and emerging hydrogen markets such as the semiconductor and fuel cell industries Pd-based membranes may be an appropriate technology based on the scales and purity requirements. In particular at lower hydrogen production rates in small-scale plants MRs with CCUS could be competitive compared to centralized H₂ production. On-site hydrogen production would also provide a self-sufficient supply and further circumvent delivery delays as well as issues with storage safety. In addition hydrogen-producing MRs are a potential avenue to alleviate carbon emissions. However material availability Pd cost and scale-up potential on the order of 1.5 million m3/day may be limiting factors preventing wider application of Pd-based membranes.

Regarding the economic production of hydrogen the benchmark by the year 2020 has been determined and set in place by the U.S. DOE at less than $2.00 per kg of produced hydrogen. While the established SMR process can easily meet the set limit by DOE other carbon-free processes such as water electrolysis electron beam radiolysis and gliding arc technologies do not presently meet this requirement. In particular it is expected that the cost of hydrogen produced from natural gas without CCUS will remain the lowest among all of the technologies while the hydrogen cost produced from an SMR plant with solvent-based carbon capture could be twice as expensive as the conventional SMR without carbon capture. Pd-based MRs have the potential to produce hydrogen at competitive prices with SMR plants equipped with carbon capture.

Despite the significant improvements in the electrolysis technologies the cost of hydrogen produced by electrolysis may remain significantly higher in most geographical locations compared with the hydrogen produced from fossil fuels. The cost of hydrogen via electrolysis may vary up to a factor of ten depending on the location and the electricity source. Nevertheless due to its modular nature the electrolysis process will likely play a significant role in the hydrogen economy when implemented in suitable geographical locations and powered by renewable electricity.

This review provides a critical overview of the opportunities and challenges associated with the use of the MRs to produce high-purity hydrogen with low carbon emissions. Moreover a technoeconomic review of the potential methods for hydrogen production is provided and the drawbacks and advantages of each method are presented and discussed.

Carbon capture and storage (CCS) technologies are expected to play a significant part in the global climate response. Following the ratification of the Paris Agreement the ability of CCS to reduce emissions from fossil fuel use in power generation and industrial processes – including from existing facilities – will be crucial to limiting future temperature increases to ""well below 2°C"" as laid out in the Agreement. CCS technology will also be needed to deliver ""negative emissions"" in the second half of the century if these ambitious goals are to be achieved.

CCS technologies are not new. This year is the 20th year of operation of the Sleipner CCS Project in Norway which has captured almost 17 million tonnes of CO2 from an offshore natural gas production facility and permanently stored them in a sandstone formation deep under the seabed. Individual applications of CCS have been used in industrial processes for decades and projects injecting CO2 for enhanced oil recovery (EOR) have been operating in the United States since the early 1970s.

This publication reviews progress with CCS technologies over the past 20 years and examines their role in achieving 2°C and well below 2°C targets. Based on the International Energy Agency’s 2°C scenario it also considers the implications for climate change if CCS was not a part of the response. And it examines opportunities to accelerate future deployment of CCS to meet the climate goals set in the Paris Agreement.

Link to Document on IEA Website

This is a transcript of the discussion session on the effects of hydrogen in the non-ferrous alloys of zirconium and titanium which are anisotropic hydride-forming metals. The four talks focus on the hydrogen embrittlement mechanisms that affect zirconium and titanium components which are respectively used in the nuclear and aerospace industries. Two specific mechanisms are delayed hydride cracking and stress corrosion cracking.

This article is a transcription of the recorded discussion of the session ‘Hydrogen in non-ferrous alloys’ at the Royal Society Discussion Meeting Challenges of Hydrogen in Metals 16–18 January 2017. The text is approved by the contributors. M.P. transcribed the session. M.A.S. assisted in the preparation of the manuscript.

Link to document download on Royal Society Website 

Gas switching reforming (GSR) is a promising technology for natural gas reforming with inherent CO₂ capture. Like conventional steam methane reforming (SMR) GSR can be integrated with CO₂ -gas shift and pressure swing adsorption units for pure hydrogen production. The resulting GSR-H2 process concept was techno-economically assessed in this study. Results showed that GSR-H2 can achieve 96% CO₂ capture at a CO₂ avoidance cost of 15 $/ton (including CO₂ transport and storage). Most components of the GSR-H2 process are proven technologies but long-term oxygen carrier stability presents an important technical uncertainty that can adversely affect competitiveness when the material lifetime drops below one year. Relative to the SMR benchmark GSR-H2 replaces some fuel consumption with electricity consumption making it more suitable to regions with higher natural gas prices and lower electricity prices. Some minor alterations to the process configuration can adjust the balance between fuel and electricity consumption to match local market conditions. The most attractive commercialization pathway for the GSR-H2 technology is initial construction without CO2 capture followed by simple retrofitting for CO₂ capture when CO₂ taxes rise and CO₂ transport and storage infrastructure becomes available. These features make the GSR-H2 technology robust to almost any future energy market scenario.

HyNet North West is a significant clean growth opportunity for the UK. It is a low cost deliverable project which meets the major challenges of reducing carbon emissions from industry domestic heat and transport.<br/>HyNet North West is based on the production of hydrogen from natural gas. It includes the development of a new hydrogen pipeline; and the creation of the UK’s first carbon capture and storage (CCS) infrastructure. CCS is a vital technology to achieve the widespread emissions savings needed to meet the 2050 carbon reduction targets.<br/>Accelerating the development and deployment of hydrogen technologies and CCS through HyNet North West positions the UK strongly for skills export in a global low carbon economy.<br/>The North West is ideally placed to lead HyNet. The region has a history of bold innovation and today clean energy initiatives are thriving. On a practical level the concentration of industry existing technical skill base and unique geology means the region offers an unparalleled opportunity for a project of this kind.<br/>The new infrastructure built by HyNet is readily extendable beyond the initial project and provides a replicable model for similar programmes across the UK<br/>Contains Vision statement 2 leaflets a presentation and a summary report which are all stored as supplements.

The influence of the addition of refractory metals (molybdenum and tantalum) on the hydrogenation properties of FeTi intermetallic phase-based alloys was investigated. The suspended droplet alloying technique was applied to fabricate FeTiTa-based and FeTiMo-based alloys. The phase composition and hydrogen storage properties of the samples were investigated. The samples modified with the refractory metals exhibited lower plateau pressures and lower hydrogen storage capacities than those of the FeTi reference sample due to solid solution formation. It was observed that the equilibrium pressures decreased with the amount of molybdenum which is in good agreement with the increase in the cell parameters of the TiFe phase. Suspended droplet alloying was found to be a practical method to fabricate alloys with refractory metal additions; however it is appropriate for screening samples with desired chemical and phase compositions rather than for manufacturing purposes.

Three alternative transport options for hydrogen generated from excess renewable power to a refinery of different scales are compared to the reference case by means of hydrogen production cost overall efficiency and CO₂ emissions. The hydrogen is transported by a) the natural gas grid and reclaimed by the existing steam reformer b) an own pipeline and c) hydrogen trailers. The analysis is applied to the city of Hamburg Germany for two scenarios of installed renewable energy capacities. The annual course of excess renewable power is modelled in a coupled system approach and the replaceable hydrogen mass flow rate is determined using measurement data from an existing refinery. Dynamic simulations are performed using an open-source Modelica® library. It is found that in all three alternative hydrogen supply chains CO₂ emissions can be reduced and costs are increased compared to the reference case. Transporting hydrogen via the natural gas grid is the least efficient but achieves the highest emission reduction and is the most economical alternative for small to medium amounts of hydrogen. Using a hydrogen pipeline is the most efficient option and slightly cheaper for large amounts than employing the natural gas grid. Transporting hydrogen by trailers is not economical for single consumers and realizes the lowest CO₂ reductions.

Hydrogen is essential to the UK meeting its net zero emissions target. We must act now to scale hydrogen solutions and achieve cost effective deep decarbonisation. With the support of Government UK industry is ready to deliver.

The potential to deploy hydrogen at scale as an energy vector has risen rapidly in the political and industrial consciousness in recent years as the benefits and opportunities have become better understood. Early stage projects across the globe have demonstrated the potential of hydrogen to deliver deep decarbonisation reduce the cost of renewable power and balance energy supply and demand. Governments and major industrial and commercial organisations across the world have set out their ambition to deploy hydrogen technologies at scale. This has created a growing confidence that hydrogen will present both a viable decarbonisation pathway and a global market opportunity. Hydrogen will have an important role to play in meeting the global climate goals set out in the Paris Climate Agreement and due to be discussed later this year at COP26.

The UK’s commitment to a net zero greenhouse gas emissions target has sharpened the conversation around hydrogen. Most experts agree that net zero by 2050 cannot be achieved through electrification alone and as such there is a need for a clean molecule to complement the electron. Hydrogen has properties which lend themselves to the decarbonisation of parts of the energy system which are less well suited to electrification such as industrial processes heating and heavy and highly utilised vehicles. Hydrogen solutions can be scaled meaning that the contribution of hydrogen to meeting net zero could be substantial.

A steady start has been made to exploring the hydrogen opportunity. Partnerships between policymakers and industry exist on several projects which are spread out right across the country from London to many industrial areas in the north east and north west. Existing projects include the early stage roll out of transport infrastructure and vehicles feasibility studies focused on large scale hydrogen production technologies projects exploring the decarbonisation of the gas grid and the development of hydrogen appliances.

The Government recently announced new funding for hydrogen through the Hydrogen Supply Programme and Industrial Fuel Switching Competition. These programmes are excellent examples of collaboration between Government and industry in driving UK leadership in hydrogen and developing solutions that will be critical for meeting net zero.

If the UK is going to meet net zero and capitalise on the economic growth opportunities presented by domestic and global markets for hydrogen solutions and expertise it is critical that the 2020s deliver a step change in hydrogen activity building on the unique strengths and expertise developed during early stage technology development.

The Hydrogen Taskforce brings together leading companies pushing hydrogen into the mainstream in the UK to offer a shared view of the opportunity and a collective position on the next steps that must be taken to ensure that the UK capitalises on this opportunity. There are questions to be answered and challenges that must be overcome as hydrogen technologies develop yet by focusing on what can be done today the benefits of hydrogen can be immediately realised whilst industry expertise and knowledge is built.

You can download the whole document from the Hydrogen Taskforce website here

Metal fuels as recyclable carriers of clean energy are promising alternatives to fossil fuels in a future low-carbon economy. Fossil fuels are a convenient and widely-available source of stored solar energy that have enabled our modern society; however fossil-fuel production cannot perpetually keep up with increasing energy demand while carbon dioxide emissions from fossil-fuel combustion cause climate change. Low-carbon energy carriers with high energy density are needed to replace the multiple indispensable roles of fossil fuels including for electrical and thermal power generation for powering transportation fleets and for global energy trade. Metals have high energy densities and metals are therefore fuels within many batteries energetic materials and propellants. Metal fuels can be burned with air or reacted with water to release their chemical energy at a range of power-generation scales. The metal-oxide combustion products are solids that can be captured and then be recycled using zero-carbon electrolysis processes powered by clean energy enabling metals to be used as recyclable zero-carbon solar fuels or electrofuels. A key technological barrier to the increased use of metal fuels is the current lack of clean and efficient combustor/reactor/engine technologies to convert the chemical energy in metal fuels into motive or electrical power (energy). This paper overviews the concept of low-carbon metal fuels and summarizes the current state of our knowledge regarding the reaction of metal fuels with water to produce hot hydrogen on demand and the combustion of metal fuels with air in laminar and turbulent flames. Many important questions regarding metal-fuel combustion processes remain unanswered as do questions concerning the energy-cycle efficiency and life-cycle environmental impacts and economics of metals as recyclable fuels. Metal fuels can be an important technology option within a future low-carbon society and deserve focused attention to address these open questions.