Publications
Macroeconomic Analysis of a New Green Hydrogen Industry using Input-output Analysis: The Case of Switzerland
Sep 2023
Publication
Hydrogen is receiving increasing attention to decarbonize hard-to-abate sectors such as carbon intensive industries and long-distance transport with the ultimate goal of reducing greenhouse gas (GHG) emissions to net-zero. However limited knowledge exists so far on the socio-economic and environmental impacts for countries moving towards green hydrogen. Here we analyse the macroeconomic impacts both direct and indirect in terms of GDP growth employment generation and GHG emissions of green hydrogen production in Switzerland. The results are first presented in gross terms for the construction and operation of a new green hydrogen industry considering that all the produced hydrogen is allocated to passenger cars (final demand). We find that for each kg of green hydrogen produced the operational phase creates 6.0 5.9 and 9.5 times more GDP employment and GHG emissions respectively compared to the construction phase (all values in gross terms). Additionally the net impacts are calculated by assuming replacement of diesel by green hydrogen as fuel for passenger cars. We find that green hydrogen contributes to a higher GDP and employment compared to diesel while reducing GHG emissions. For instance in all the three cases namely ‘Equal Cost’ ‘Equal Energy’ and ‘Equal Service’ we find that a green hydrogen industry generates around 106% 28% and 45% higher GDP respectively; 163% 43% and 65% more full-time equivalent jobs respectively; and finally 45% 18% and 29% lower GHG emissions respectively compared to diesel and other industries. Finally the methodology developed in this study can be extended to other countries using country-specific data.
Design and Implementation of the Safety System of a Solar-driven Smart Micro-grid Comprising Hydrogen Production for Electricity & Cooling Co-generation
Sep 2023
Publication
This article presents a comprehensive description of the safety system of a real installation that comprises PV panels lithium-ion batteries an electrolyzer H2 storage a fuel cell and a barium chloride/ammonia thermochemical prototype for heat recovery and cooling production. Such a system allows for the increase of the overall efficiency of the H2 chain by exploiting the waste heat and transforming it into a cooling effect particularly useful in tropical regions like French Polynesia. The study provides a great deal of detail regarding practical aspects of the system implementation and a consistent reference to the relevant standards and regulations applicable to the subject matter. More specifically the study covers the ATEX classification of the site the safety features of each component the electrical power distribution the main safety instrumented system fire safety and the force ventilation system. The study also includes safety assessment and a section on lessons learned that could serve as guidance for future installations. In addition an extensive amount of technical data is readily available to the reader in repository (P&ID electrical diagrams etc.).
Mitigating Risks in Hydrogen-powered Transportation: A Comprehensive Risk Assessment for Hydrogen Refuelling Stations, Vehicles, and Garages
Oct 2024
Publication
Hydrogen is increasingly seen as a viable alternative to fossil fuels in transportation crucial to achieving net-zero energy goals. However the rapid expansion of hydrogen-powered transportation is outpacing safety standards posing significant risks due to limited operational experience involvement of new actors and lack of targeted guidelines. This study addresses the urgent need for a tailored comprehensive risk assessment framework. Using Structured What-If (SWIFT) and bowtie barrier analysis the research evaluates a hypothetical pilot project focusing on hydrogen refuelling stations vehicles and garages. The study identifies critical hazards and assesses the adequacy of current risk mitigation measures. Key findings reveal gaps in safety practices leading to 41 actionable steps and 5 key activities to help new actors manage hydrogen risks effectively. By introducing novel safety guidelines this research contributes to the development of safe hydrogen use and advances the understanding of hydrogen risks ensuring its sustainable integration into transportation systems.
Suitability and Energy Sustainability of Atmospheric Water Generation Technology for Green Hydrogen Production
Sep 2023
Publication
This research investigated the suitability of air-to-water generator (AWG) technology to address one of the main concerns in green hydrogen production namely water supply. This study specifically addresses water quality and energy sustainability issues which are crucial research questions when AWG technology is intended for electrolysis. To this scope a reasoned summary of the main findings related to atmospheric water quality has been provided. Moreover several experimental chemical analyses specifically focused on meeting electrolysis process requirements on water produced using a real integrated AWG system equipped with certified materials for food contact were discussed. To assess the energy sustainability of AWGs in green hydrogen production a case study was presented regarding an electrolyzer plant intended to serve as energy storage for a 2 MW photovoltaic field on Iriomote Island. The integrated AWG used for the water quality analyses was studied in order to determine its performance in the specific island climate conditions. The production exceeded the needs of the electrolyzer; thus the overproduction was considered for the panels cleaning due to the high purity of the water. Due to such an operation the efficiency recovery was more than enough to cover the AWG energy consumption. This paper on the basis of the quantity results provides the first answers to the said research questions concerning water quality and energy consumption establishing the potential of AWG as a viable solution for addressing water scarcity and enhancing the sustainability of electrolysis processes in green hydrogen production.
Carbon Footprint of Hydrogen-powered Inland Shipping: Impacts and Hotspots
Aug 2023
Publication
The shipping sector is facing increasing pressure to implement clean fuels and drivetrains. Especially hydrogen fuel cell drivetrains seem attractive. Although several studies have been conducted to assess the carbon footprint of hydrogen and its application in ships their results remain hard to interpret and compare. Namely it is necessary to include a variety of drivetrain solutions and different studies are based on various assumptions and are expressed in other units. This paper addresses this problem by offering a three-step meta-review of life cycle assessment studies. First a literature review was conducted. Second results from the literature were harmonized to make the different analyses comparable serving cross-examination. The entire life cycle of both the fuels and drivetrains were included. The results showed that the dominant impact was fuel use and related fuel production. And finally life-cycle hot spots have been identified by looking at the effect of specific configurations in more detail. Hydrogen production by electrolysis powered by wind has the most negligible impact. For this ultra-low carbon pathway the modes of hydrogen transport and the use of specific materials and components become relevant.
Towards a Future Hydrogen Supply Chain: A Review of Technologies and Challenges
Feb 2024
Publication
The overuse of fossil fuels has caused a serious energy crisis and environmental pollution. Due to these challenges the search for alternative energy sources that can replace fossil fuels is necessary. Hydrogen is a widely acknowledged future energy carrier because of its nonpolluting properties and high energy density. To realize a hydrogen economy in the future it is essential to construct a comprehensive hydrogen supply chain that can make hydrogen a key energy carrier. This paper reviews the various technologies involved in the hydrogen supply chain encompassing hydrogen production storage transportation and utilization technologies. Then the challenges of constructing a hydrogen supply chain are discussed from techno-economic social and policy perspectives and prospects for the future development of a hydrogen supply chain are presented in light of these challenges.
The Impact of Water Injection and Hydrogen Fuel on Performance and Emissions in a Hydrogen/Diesel Dual-Fuel Engine
Nov 2024
Publication
As the need for alternative energy sources and reduced emissions grows proven technologies are often sidelined in favour of emerging solutions that lack the infrastructure for mass adoption. This study explores a transitional approach by modifying existing compression ignition engines to run on a hydrogen/diesel mixture for performance improvement utilising water injection to mitigate the drawbacks associated with hydrogen combustion. This approach can yield favourable results with current technology. In this modelling study ten hydrogen energy ratios (0–90%) and nine water injection rates (0–700 mg/cycle) were tested in a turbocharged Cummins ISBe 220 31 six-cylinder diesel engine. An engine experiment was conducted to validate the model. Key performance indicators such as power mechanical efficiency thermal efficiency indicated mean effective pressure (IMEP) and brake-specific fuel consumption (BSFC) were measured. Both water injection and hydrogen injection led to slight improvements in all performance metrics except BSFC due to hydrogen’s lower energy density. In terms of emissions CO and CO2 levels significantly decreased as hydrogen content increased with reductions of 94% and 96% respectively at 90% hydrogen compared to the baseline diesel. Water injection at peak rates further reduced CO emissions by approximately 40% though it had minimal effect on CO2 . As expected NOx (which is a typical challenge with hydrogen combustion and also with diesel engines in general) increased with hydrogen fuelling resulting in an approximately 70% increase in total NOx emissions over the range of 0–90% hydrogen energy. Similar increases were observed in NO and NO2 e.g. 90% and 57% increases with 90% hydrogen respectively. However water injection reduced NO and NO2 levels by up to 16% and 83% respectively resulting in a net decrease in NOX emissions in many combined cases not only with hydrogen injection but also when compared to baseline diesel.
Potential-risk and No-regret Options for Urban Energy System Design - A Sensitivity Analysis
Jan 2024
Publication
This study identifies supply options for sustainable urban energy systems which are robust to external system changes. A multi-criteria optimization model is used to minimize greenhouse gas (GHG) emissions and financial costs of a reference system. Sensitivity analyses examine the impact of changing boundary conditions related to GHG emissions energy prices energy demands and population density. Options that align with both financial and emission reduction and are robust to system changes are called “no-regret” options. Options sensitive to system changes are labeled as “potential-risk” options.<br/>There is a conflict between minimizing GHG emissions and financial costs. In the reference case the emission-optimized scenario enables a reduction of GHG emissions (-93%) but involves higher costs (+160%) compared to the financially-optimized scenario.<br/>No-regret options include photovoltaic systems decentralized heat pumps thermal storages electricity exchange between sub-systems and with higher-level systems and reducing energy demands through building insulation behavioral changes or the decrease of living space per inhabitant. Potential-risk options include solar thermal systems natural gas technologies high-capacity battery storages and hydrogen for buildiing energy supply.<br/>When energy prices rise financially-optimized systems approach the least-emission system design. The maximum profitability of natural gas technologies was already reached before the 2022 European energy crisis.
Numerical Simulations of the Critical Diameter and Flame Stability for the Hydrogen Jet Flames
Sep 2023
Publication
This study focuses on development of a CFD model able to simulate the experimentally observed critical nozzle diameter for hydrogen non-premixed flames. The critical diameter represents the minimum nozzle size through which a free jet flame will remain stable at all driving pressures. Hydrogen non-premixed flames will not blow-out at diameters equal to or greater than the critical diameter. Accurate simulation of this parameter is important for assessment of thermally activated pressure relief device (TPRD) performance during hydrogen blowdown from a storage tank. At TPRD diameters below the critical value there is potential for a hydrogen jet flame to blow-out as the storage tank vents potentially leading to hydrogen accumulation in an indoor release scenario. Previous experimental studies have indicated that the critical diameter for hydrogen is approximately 1 mm. In this study flame stability is considered across a range of diameters and overpressures from 0.1 mm to 2 mm and from 0.2 MPa to 20 MPa respectively. The impact of turbulent Schmidt number Sct which is the ratio of momentum diffusivity (kinematic viscosity) and mass diffusivity on the hydrogen concentration profile in the region near the nozzle exit and subsequent influence on critical diameter was investigated and discussed. For lower Sct values the enhanced mass mixing resulted in smaller predicted critical diameters. The use of value Sct=0.61 in the model demonstrated the best agreement with experimental values of the critical diameter. The model reproduced the critical diameter of 1 mm and then was applied to predict flame stability for under-expanded hydrogen jets.
Hopes and Fears for a Sustainable Energy Future: Enter the Hydrogen Acceptance Matrix
Feb 2024
Publication
Hydrogen-fuelled technologies for home heating and cooking may provide a low-carbon solution for decarbonising parts of the global housing stock. For the transition to transpire the attitudes and perceptions of consumers must be factored into policy making efforts. However empirical studies are yet to explore potential levels of consumer heterogeneity regarding domestic hydrogen acceptance. In response this study explores a wide spectrum of consumer responses towards the prospect of hydrogen homes. The proposed spectrum is conceptualised in terms of the ‘domestic hydrogen acceptance matrix’ which is examined through a nationally representative online survey conducted in the United Kingdom. The results draw attention to the importance of interest and engagement in environmental issues knowledge and awareness of renewable energy technologies and early adoption potential as key drivers of domestic hydrogen acceptance. Critically strategic measures should be taken to convert hydrogen scepticism and pessimism into hope and optimism by recognising the multidimensional nature of consumer acceptance. To this end resources should be dedicated towards increasing the observability and trialability of hydrogen homes in proximity to industrial clusters and hubs where the stakes for consumer acceptance are highest. Progress towards realising a net-zero society can be supported by early stakeholder engagement with the domestic hydrogen acceptance matrix.
Experimental Study of Cycle-by-cycle Variations in a Spark Ignition Internal Combustion Engine Fueled with Hydrogen
Feb 2024
Publication
High fluctuations in the combustion process from one cycle to another referred to as cycle-by-cycle variations can have adverse effects on internal combustion engine performances particularly in spark ignition (SI) engines. These effects encompass incomplete combustion the potential for misfires and adverse impacts on fuel economy. Furthermore the cycle-by-cycle variations can also affect a vehicle’s drivability and overall comfort especially when operating under lean-burn conditions. Although many cycle-by-cycle analyses have been investigated extensively in the past there is limited in-depth knowledge available regarding the causes of cycle-by-cycle (CbC) variations in hydrogen lean-burn SI engines. Trying to contribute to this topic the current study presents a comprehensive analysis of the CbC variations based on the cylinder pressure data. The study was carried out employing a hydrogen single-cylinder research SI engine. The experiments were performed by varying more than fifty operating conditions including the variations in lambda spark advance boost pressure and exhaust gas recirculation however the load and speed were kept constant throughout the experimental campaign. The results indicate that pressure exhibits significant variations during the combustion process and minor variations during non-combustion processes. In the period from the inlet valve close till the start of combustion pressure exhibits the least variations. The coefficient of variation of pressure (COVP) curve depicts three important points in H2-ICE as well: global minima global maxima and second local minima. The magnitude of the COVP curve changes across all the operating conditions however the shape of the COVP curve remains unchanged across all the operating conditions indicating its independence from the operating condition in an H2-ICE. This study presents an alternative approach for a quick combustion analysis of hydrogen engines. Without the need for more complex methodologies like heat release rate analysis the presented cylinder pressure cycle-by-cycle analysis enables a quick and precise identification of primary combustion features (start of combustion center of combustion end of combustion and operation condition stability). Additionally the engine control unit could implement these procedures to automatically adjust cycle-by-cycle variations therefore increasing engine efficiency.
Socio-environmental and Technical Factors Assessment of Photovoltaic Hydrogen Production in Antofagasta, Chile
Apr 2024
Publication
This study introduces a method for identifying territories ideal for establishing photovoltaic (PV) plants for green hydrogen (GH2 ) production in the Antofagasta region of northern Chile a location celebrated for its outstanding solar energy potential. Assessing the viability of PV plant installation necessitates a balanced consideration of technical aspects and socio-environmental constraints such as the proximity to areas of ecological importance and indigenous communities to identify potential zones for solar and non-conventional renewable energy (NCRE)-based hydrogen production. To tackle this challenge we propose a methodology that utilizes geospatial analysis integrating Geographic Information System (GIS) tools with sensitivity analysis to determine the most suitable sites for PV plant installation in the Antofagasta region. Our geospatial analysis employs the QGIS software to identify these optimal locations while sensitivity analysis uses the Sørensen–Dice coefficient method to assess the similarity among chosen socio-environmental variables. Applying this methodology to the Antofagasta region reveals that a significant area within a 15 km radius of existing road networks and electrical substations is favorable for photovoltaic projects. Our sensitivity analysis further highlights the limiting effects of socio-environmental factors and their interactions. Moreover our research finds that enlarging areas of socio-environmental importance could increase the total hydrogen production by about 10% per commune indicating the impact of these factors on the potential for renewable energy production.
A Perspective on Broad Deployment of Hydrogen-fueled Vehicles for Ground Freight Transportation with a Comparison to Electric Vehicles
Oct 2024
Publication
The pressing global challenge of climate change necessitates a concerted effort to limit greenhouse gas emissions particularly carbon dioxide. A critical pathway is to replace fossil fuel sources by electrification including transportation. While electrification of light-duty vehicles is rapidly expanding the heavy-duty vehicle sector is subject to challenges notably the logistical drawbacks of the size and weight of high-capacity batteries required for range as well as the time for battery charging. This Perspective highlights the potential of hydrogen fuel-cell vehicles as a viable alternative for heavy-duty road transportation. We evaluate the implications of hydrogen integration into the freight economy energy dynamics and CO2 mitigation and envision a roadmap for a holistic energy transition. Our critical opinion presented in this Perspective is that federal incentives to produce hydrogen could foster growth in the nascent hydrogen economy. The pathway that we propose is that initial focus on operators of large fleets that could control their own fueling infrastructure. This opinion was formed from private discussions with numerous stakeholders during the formation of one of the awarded hydrogen hubs if they focus on early adopters that could leverage the hydrogen supply chain.
Overview of International Activities in Hydrogen System Safety in IEA Hydrogen TCP Task 43
Sep 2023
Publication
Safety and reliability have long been recognized as key issues for the development commercialization and implementation of new technologies and infrastructure and hydrogen systems are no exception to this rule. Reliability engineering quantitative risk assessment (QRA) and knowledge exchange each play a key role in proactive addressing safety – before problems happen – and help us learn from problems if they happen. Many international research activities are focusing on both reliability and risk assessment for hydrogen systems. However the element of knowledge exchange is sometimes less visible. To support international collaboration and knowledge exchange the International Energy Agency (IEA) convened a new Technology Collaboration Program “Task 43: Safety and Regulatory Aspects of Emerging Large Scale Hydrogen Energy Applications” started in June 2022. Within Task 43 Subtask E focuses on Hydrogen Systems Safety. This paper discusses the structure of the Hydrogen Systems Safety subtask and the aligned activities and introduces opportunities for future work.
Nuclear Enabled Hydrogen CO-generation: Safety and Regulatory Insight
Sep 2023
Publication
National Nuclear Laboratory (NNL) is aiming to demonstrate through a research and development programme that nuclear enabled hydrogen can be used to support future clean energy systems. Demonstrating the safe operation of hydrogen facilities co-generating with a nuclear reactor will be key to enabling the deployment and success of nuclear enabled hydrogen technologies in the future. During the deployment continuity of supply will be paramount and possibly requires inter-seasonal storage. Co-generation is a means of using a source of energy in this case a nuclear reactor to efficiently produce power and thermal energy. Since a great deal of the heat energy is lost to the environment in a power plant making use of wasted energy for other useful output like the production of hydrogen and direct heating would be advantageous to plant economics and energy system flexibility. The civil nuclear industry is regulated around the world. This approach ensures that all the activities related to the production of power from nuclear and the hazards associated with ionising radiation are controlled in a manner which protects workers members of the public property and the environment. Nuclear safety assessments follow a rigorous process and are required as part of the Nuclear Site Licence. A fundamental requirement which is cited in the UK legislation is that the risks associated with all activities at the licensed site be reduced to As Low As Reasonably Practicable (ALARP). The principle places a requirement on duty holders to implement measures to reduce risk where doing so is considered reasonable and proportionate. The inclusion of risks for hazardous materials associated with the hydrogen production facilities need to be considered and this requires harmonisation of two different safety and regulatory governance regimes which have not previously interacted in this way. The safety demonstration for nuclear facilities is provided through the Safety Case.
Methodology for Consequence-based Setback Distance Calculations for Bulk Liquid Hydrogen Storage Systems
Sep 2023
Publication
Updates to the separation distances between different exposures and bulk liquid hydrogen systems are included in the 2023 version of NFPA 2: Hydrogen Technologies Code. This work details the models and calculations leading to those distances. The specific models used including the flow of liquid hydrogen through an orifice within the Hydrogen Plus Other Alternative Fuels Risk Assessment Models (HyRAM+) toolkit are described and discussed to emphasize challenges specific to liquid hydrogen systems. Potential hazards and harm affecting individual exposures (e.g. ignition sources air intakes) for different unignited concentrations overpressures and heat flux levels were considered and exposures were grouped into three bins. For each group the distances to a specific hazard criteria (e.g. heat flux level) for a characteristic leak size informed by a risk-analysis led to a hazard distance. The maximum hazard distance within each group was selected to determine a table of separation distances based on internal pressure and pipe size rather than storage volume similar to the bulk gaseous separation distance tables in NFPA 2. The new separation distances are compared to the previous distances and some implications of the updated distances are given.
Production of Hydrogen Energy from Graphene-based Catalytic Technologies
Jul 2025
Publication
This comprehensive review aims at investigating graphene-based technologies in boosting hydrogen production via three methods including electrocatalysis photocatalysis and plasma-assisted reforming. Graphene stands out as an excellent catalytic material due to its exceptional attributes which include large surface area exceptional electrical and thermal conductivity adjustable electronic properties and outstanding mechanical strength. The research explores graphene’s contributions to hydrogen evolution through three main strategies including lowering energy barriers escalation of active sites and enhanced electrical charge transport. The study also focuses on graphene’s performance when functionalized with metal catalysts and heteroatoms enhancing its capability in charge separation and absorption of light during photocatalysis. The application of plasma to graphene improves catalytic reaction in hydrogen production with improved resistance to energy consumption. Large-scale industrial adoption of this technology remains restricted in terms production cost synthesis scalability and environmental safety issues. The research suggests an outlook for enhancing production technologies improving process sustainability and tackling scale-up technology to boost graphene’s incorporation into green and effective hydrogen energy production.
Lifetime Design, Operation, and Cost Analysis for the Energy System of a Retrofitted Cargo Vessel with Fuel Cells and Batteries
Oct 2024
Publication
Fuel cell-battery electric drivetrains are attractive alternatives to reduce the shipping emissions. This research focuses on emission-free cargo vessels and provides insight on the design lifetime operation and costs of hydrogen-hybrid systems which require further research for increased utilization. A representative round trip is created by analysing one-year operational data based on load ramps and power frequency. A low-pass filter controller is employed for power distribution. For the lifetime cost analysis 14 scenarios with varying capital and operational expenses were considered. The Net Present Value of the retrofitted fuel cell-battery propulsion system can be up to $ 2.2 million lower or up to $ 18.8 million higher than the original diesel mechanical configuration highly dependent on the costs of green hydrogen and carbon taxes. The main propulsion system weights and volumes of the two versions are comparable but the hydrogen tank (68 tons 193 m3 ) poses significant design and safety challenges.
A New Dimensionless Number for Type IV Composite Pressure Vessel Designer to Increase Efficiency and Reduce Cost
Sep 2023
Publication
A new dimensionless number (DN) is proposed in order to evaluate the performance of a high-pressure vessel composite structure. It shows that very few composite part is used at its maximum loading potential during bursting. Today for 70 MPa on-board type IV composite tanks DN values close to 20%. The suggested DN will be a useful indicator for an industrial application. By maximizing the DN at the design phase it is possible to minimize the mass of the composite structure of a CPV to reduce the manufacturing time and cost. To increase the DN as close as possible to 100% it is necessary to succeed in increasing the overall loading of the composite structure to have better oriented fibre. For this it seems necessary to find new processes which make it possible to better orient the fibre.
Effect of Wall Friction on Shock-flame Interactions in a Hydrogen-air Mixture
Sep 2023
Publication
Shock-flame interactions (SFI) occur in a variety of combustion scenarios of scientific and engineering interest which can distort the flame extend the flame surface area and subsequently enhance heat release. This process is dominated by Richtmyer-Meshkov instability (RMI) that features the perturbation growth of a density-difference interface (flame) after the shock passage. The main mechanism of RMI is the vorticity deposition results from a misalignment between pressure and density gradients. This paper focuses on the multi-dimensional interactions between shock wave and flame in a hydrogen-air mixture. The simulations of this work were conducted by solving three-dimensional fully-compressible reactive Navier-Stokes equations using a high-order numerical method on a dynamically adapting mesh. The effect of wall friction on the SFI was examined by varying wall boundary condition (free-slip/no-slip) on sidewall. The results show that the global flame perturbation grows faster with the effect of wall friction in the no-slip case than that in the free-slip case in the process of SFI. Two effects of wall friction on SFI were found: (1) flame stretching close to the no-slip wall and (2) damping of local flame perturbation at the no-slip wall. The flame stretch effect leads to a significantly higher growth rate in the global flame perturbation. By contrast the damping effect locally moderates the flame perturbation induced by RMI in close proximity to the no-slip wall because less vorticity is deposited on this part of flame during SFI.
Hydrogen in Energy Transition: The Problem of Economic Efficiency, Environmental Safety, and Technological Readiness of Transportation and Storage
Jul 2024
Publication
The circular economy and the clean-energy transition are inextricably linked and interdependent. One of the most important areas of the energy transition is the development of hydrogen energy. This study aims to review and systematize the data available in the literature on the environmental and economic parameters of hydrogen storage and transportation technologies (both mature and at high technological readiness levels). The study concluded that salt caverns and pipeline transportation are the most promising methods of hydrogen storage and transportation today in terms of a combination of all parameters. These methods are the most competitive in terms of price especially when transporting hydrogen over short distances. Thus the average price of storage will be 0.35 USD/kg and transportation at a distance of up to 100 km is 0.3 USD/kg. Hydrogen storage underground in a gaseous state and its transportation by pipelines have the least consequences for the environment: emissions and leaks are insignificant and there is no environmental pollution. The study identifies these methods as particularly viable given their lower environmental impact and potential for seamless integration into existing energy systems therefore supporting the transition to a more sustainable and circular economy.
Public Perception of Hydrogen: Response to an Open-ended Questions
Sep 2023
Publication
Widespread use of hydrogen and hydrogen-based fuels as energy carriers in society may enable the gradual replacement of fossil fuels by renewable energy sources. Although the development and deployment of the associated technologies and infrastructures represent a considerable bottleneck it is generally acknowledged that neither the technical feasibility nor the economic viability alone will determine the extent of the future use of hydrogen as an energy carrier. Public perception beliefs awareness and knowledge about hydrogen will play a significant role in the further development of the hydrogen economy. To this end the present study examines public perception and awareness of hydrogen in Norway. The approach adopted entailed an open-ended question examining spontaneous associations with the term ‘hydrogen’. The question was fielded to 2276 participants in Wave 25 of the Norwegian Citizen Panel (NCP) an on-line panel that derives random samples from the general population registry. The analysis focused on classifying the responses into negative associations (i.e. barriers towards widespread implementation of hydrogen in society) neutral associations (e.g. basic facts) and positive associations (i.e. drivers towards widespread implementation of hydrogen in society). Each of the 2194 responses were individually assessed by five researchers. The majority of the responses highlighted neutral associations using words such as ‘gas’ ‘water’ and ‘element’. When considering barriers vs. drivers the overall responses tend towards positive associations. Many respondents perceive hydrogen as a clean and environmentally friendly fuel and hydrogen technologies are often associated with the future. The negative sentiments were typically associated with words such as ‘explosive’ ‘hazardous’ and ‘expensive’. Despite an increase in the mentioning of safety-related properties relative to a previous study in the same region the frequency of such references was rather low (4%). The responses also reveal various misconceptions such as hydrogen as a prospective ‘source’ of clean energy.
Economics of Renewable Hydrogen Production Using Wind and Solar Energy: A Case Study for Queensland, Australia
Dec 2023
Publication
This study presents a technoeconomic analysis of renewables-based hydrogen production in Queensland Australia under Optimistic Reference and Pessimistic scenarios to address uncertainty in cost predictions. The goal of the work was to ascertain if the target fam-gate cost of AUD 3/kg (approx. USD 2/kg) could be reached. Economies of scale and the learning rate concept were factored into the economic model to account for the effect of scale-up and cost reductions as electrolyser manufacturing capacity grows. The model assumes that small-scale to large-scale wind turbine (WT)-based and photovoltaic (PV)-based power generation plants are directly coupled with an electrolyser array and utilises hourly generation data for the Gladstone hydrogen-hub region. Employing first a commonly used simplified approach the electrolyser array was sized based on the maximum hourly power available for hydrogen production. The initial results indicated that scale-up is very beneficial: the levelised cost of green hydrogen (LCOH) could decrease by 49% from $6.1/kg to $3.1/kg when scaling PV-based plant from 10 MW to 1 GW and for WT-based plant by 36% from $5.8/kg to $3.7/kg. Then impacts on the LCOH of incorporating curtailment of ineffective peak power and electrolyser overload capacity were investigated and shown to be significant. Also significant was the beneficial effect of recognising that electrolyser efficiency depends on input power. The latter two factors have mostly been overlooked in the literature. Incorporating in the model the influence on the LCOH of real-world electrolyser operational characteristics overcomes a shortcoming of the simplified sizing method namely that a large portion of electrolyser capacity is under-utilised leading to unnecessarily high values of the LCOH. It was found that AUD 3/kg is achievable if the electrolyser array is properly sized which should help to incentivise large-scale renewable hydrogen projects in Australia and elsewhere.
Conceptual Design of a Hydrogen-Hybrid Dual-Fuel Regional Aircraft Retrofit
Jan 2024
Publication
A wide range of aircraft propulsion technologies is being investigated in current research to reduce the environmental impact of commercial aviation. As the implementation of purely hydrogenpowered aircraft may encounter various challenges on the airport and vehicle side combined hydrogen and kerosene energy sources may act as an enabler for the first operations with liquid hydrogen propulsion technologies. The presented studies describe the conceptual design of such a dual-fuel regional aircraft featuring a retrofit derived from the D328eco under development by Deutsche Aircraft. By electrically assisting the sustainable aviation fuel (SAF) burning conventional turboprop engines with the power of high-temperature polymer-electrolyte fuel cells the powertrain architecture enables a reduction of SAF consumption. All aircraft were modeled and investigated using the Bauhaus Luftfahrt Aircraft Design Environment. A description of this design platform and the incorporated methods to model the hydrogen-hybrid powertrain is given. Special emphasis was laid on the implications of the hydrogen and SAF dual-fuel system design to be able to assess the potential benefits and drawbacks of various configurations with the required level of detail. Retrofit assumptions were applied particularly retaining the maximum takeoff mass while reducing payload to account for the propulsion system mass increase. A fuel cell power allocation of 20% led to a substantial 12.9% SAF consumption decrease. Nonetheless this enhancement necessitated an 18.1% payload reduction accompanied by a 34.5% increment in propulsion system mass. Various additional studies were performed to assess the influence of the power split. Under the given assumptions the design of such a retrofit was deemed viable.
Techno-economic Analysis of Territorial Case Studies for the Integration of Biorefineries and Green Hydrogen
Nov 2024
Publication
To achieve sustainable development the transition from a fossil-based economy to a circular economy is essential. The use of renewable energy sources to make the overall carbon foot print more favorable is an important pre-requisite. In this context it is crucial to valorize all renewable resources through an optimized local integration. One opportunity arises through the synergy between bioresources and green hydrogen. Through techno-economic assessments this work analyzes four local case studies that integrate bio-based processes with green hydrogen produced via electrolysis using renewable energy sources. An analysis of the use of webGIS tools (i.e. Atlas of Biorefineries of IEA Bioenergy) to identify existing biorefineries that require hydrogen in relation to territories with a potential availability of green hydrogen has never been conducted before. This paper provides an evaluation of the production costs of the target products as a function of the local green hydrogen supply costs. The results revealed that the impact of green hydrogen costs could vary widely ranging from 1% to 95% of the total production costs depending on the bio-based target product evaluated. Additionally hydrogen demand in the target area could require an installed variable renewable energy capacity of 20 MW and 500 MW. On the whole the local integration of biorefineries and green hydrogen could represent an optimal opportunity to make hydrogenated bio-based products 100% renewable.
H2-powered Aviation - Design and Economics of Green LH2 Supply for Airports
Aug 2023
Publication
The economic competitiveness of hydrogen-powered aviation highly depends on the supply costs of green liquid hydrogen to enable true-zero CO2 flying. This study uses non-linear energy system optimization to analyze three main liquid hydrogen (LH2) supply pathways for five locations. Final liquid hydrogen costs at the dispenser supply costs could reach 2.04 USD/kgLH2 in a 2050 base case scenario for locations with strong renewable energy source conditions. This could lead to cost-competitive flying with hydrogen. Reflecting techno-economic uncertainties in two additional scenarios the liquid hydrogen cost span at all five airport locations ranges between 1.37–3.48 USD/kgLH2 if hydrogen import options from larger hydrogen markets are also available. Import setups are of special importance for airports with a weaker renewable energy source situation e.g. selected Central European airports. There on-site supply might not only be too expensive but space requirements for renewable energy sources could be too large for feasible implementation in densely populated regions. Furthermore main costs for liquid hydrogen are caused by renewable energy sources electrolysis systems and liquefaction plants. Seven detailed design rules are derived for optimized energy systems for these and the storage components. This and the cost results should help infrastructure planners and general industry and policy players prioritize research and development needs
The Development of a Green Hydrogen Economy: Review
Jun 2024
Publication
Building a hydrogen economy is perceived as a way to achieve the decarbonization goals set out in the Paris Agreement to limit global warming as well as to meet the goals resulting from the European Green Deal for the decarbonization of Europe. This article presents a literature review of various aspects of this economy. The full added value chain of hydrogen was analyzed from its production through to storage transport distribution and use in various economic sectors. The current state of knowledge about hydrogen is presented with particular emphasis on its features that may determine the positives and negatives of its development. It was noted that although hydrogen has been known for many years its production methods are mainly related to fossil fuels which result in greenhouse gas emissions. The area of interest of modern science is limited to green hydrogen produced as a result of electrolysis from electricity produced from renewable energy sources. The development of a clean hydrogen economy is limited by many factors the most important of which are the excessive costs of producing clean hydrogen. Research and development on all elements of the hydrogen production and use chain is necessary to contribute to increasing the scale of production and use of this raw material and thus reducing costs as a result of the efficiencies of scale and experience gained. The development of the hydrogen economy will be related to the development of the hydrogen trade and the centers of this trade will differ significantly from the current centers of energy carrier trade.
Fuel Cell-based Hybrid Electric Vehicles: An Integrated Review of Current Status, Key Challenges, Recommended Policies, and Future Prospects
Aug 2023
Publication
Battery electric vehicles (BEVs) and fuel cell electric vehicles (FCEVs) whose exhaust pipes emit nothing are examples of zero-emission automobiles. FCEVs should be considered an additional technology that will help battery-powered vehicles to reach the aspirational goal of zero-emissions electric mobility particularly in situations where the customers demand for longer driving ranges and where using batteries would be insufficient due to bulky battery trays and time-consuming recharging. This study stipulates a current evaluation of the status of development and challenges related to (i) research gap to promote fuel-cell based HEVs (ii) key barriers of fuel-cell based HEVs (iii) advancement of electric mobility and their power drive (iv) electrochemistry of fuel cell technology for FCEVs (v) power transformation topologies communication protocols and advanced charging methods (vi) recommendations and future prospects of fuel-cell HEVs and (vii) current research trends of EVs and FCEVs. This article discusses key challenges with fuel cell electric mobility such as low fuel cell performance cold starts problems with hydrogen storage cost-reduction safety concerns and traction systems. The operating characteristics and applications of several fuel-cell technologies are investigated for FCEVs and FCHEVs. An overview of the fuel cell is provided which serves as the primary source of energy for FCHEVs along with comparisons and its electrochemistry. The study of power transformation topologies communication protocols and enhanced charging techniques for FCHEVs has been studied analytically. Recent technology advancements and the prospects for FCHEVs are discussed in order to influence the future vehicle market and to attain the aim of zero emissions.
The Influence of the Changes in Natural Gas Supplies to Poland on the Amount of Hydrogen Produced in the SMR Reactor
Mar 2024
Publication
Thanks to investments in diversifying the supply of natural gas Poland did not encounter any gas supply issues in 2022 when gas imports from Russia were ceased due to the Russian Federation’s armed intervention in Ukraine. Over the past few years the supply of gas from routes other than the eastern route has substantially grown particularly the supplies of liquefied natural gas (LNG) via the LNG terminal in Swinouj´scie. The growing proportion of LNG in Poland’s gas supply ´ leads to a rise in ethane levels in natural gas as verified by the review of data taken at a specific location within the gas system over the years 2015 2020 and 2022. Using measurements of natural gas composition the effectiveness of the steam hydrocarbon reforming process was simulated in the Gibbs reactor via Aspen HYSYS. The simulations confirmed that as the concentration of ethane in the natural gas increased the amount of hydrogen produced and the heat required for reactions in the reformer also increased. This article aims to analyze the influence of the changes in natural gas quality in the Polish transmission network caused by changes in supply structures on the mass and heat balance of the theoretical steam reforming reactor. Nowadays the chemical composition of natural gas may be significantly different from that assumed years ago at the plant’s design stage. The consequence of such a situation may be difficulties in operating especially when controlling the quantity of incoming natural gas to the reactor based on volumetric flow without considering changes in chemical composition.
Analysis for the Implementation of Surplus Hydropower for Green Hydrogen Production in Ecuador
Dec 2024
Publication
This study investigates the feasibility of utilizing surplus hydropower from Ecuador’s major hydroelectric plants to produce green hydrogen a clean energy source that can be used to meet a large percentage of energy needs. Given Ecuador’s significant hydropower infrastructure this approach leverages untapped energy resources for hydrogen production with potential impacts on decarbonization strategies. A Pareto analysis identified five key hydroelectric plants that contribute the most to the national surplus. Using historical data from 2019 to 2023 a stochastic model was applied to estimate future surplus availability through 2030. The findings indicate that although Ecuador’s surplus hydropower peaked in 2021 the general trend shows a decline suggesting an urgent need to capitalize on these resources efficiently. The results indicate a projected annual surplus of hydroelectric energy in Ecuador ranging from 7475 to 3445 GWh over the next five years which could be utilized for green hydrogen production. Ecuador thus has promising potential to become a green hydrogen producer enhancing both regional energy security and carbon reduction goals. The reduction in energy availability for hydrogen production is attributed to the increasing energy demand and variable climatic conditions.
Analysis and Comparison of Hydrogen Generators Safety Measures According to International Regulations, Codes and Standards (RCS)
Sep 2023
Publication
Climate change has prompted the international community to invest heavily in renewable energy sources in order to gradually replace fossil fuels. Whilst energy systems will be increasingly based on non-programmable renewable sources hydrogen is the main player when it comes to the role of energy reserve. This change has triggered a fast development of hydrogen production technologies with increasing use and installation of hydrogen generators (electrolyzers) in both the civil and industrial sector. The implementation of such investments requires the need for accurate design and verification of hydrogen systems with particular attention on fire safety. Due to its chemical-physical characteristics hydrogen is highly flammable and is often stored at very high-pressure levels. ISO 22734 and NFPA 2 are the main international standards which are currently available for the design of hydrogen generators and systems both of which include fire safety requirements. This paper analyses the main existing Regulations Codes and Standards (RCS) for hydrogen generators with the purpose of evaluating and comparing fire safety measures with focus on both active protection (detection systems extinguishing systems) and passive protection (safety distances separation walls). The scope of the paper is to identify safety measures which can be considered generally applicable and provide a reference for further fire safety regulations. The analysis carried out identifies potential gaps in RCS and suggests areas for potential future research.
Power-to-gas and Power-to-liquid Systems in Emerging Hydrogen Valleys: Techno-economic Assessment of Alternative Fuels
Feb 2025
Publication
This study presents a techno-economic assessment of power-to-gas and power-to-liquid pathways within the Hydrogen Valley concept to support the decarbonization of local energy systems. Using the EnergyPLAN software both business-as-usual and Hydrogen Valley scenarios were analyzed by varying renewable energy electrolyzer capacity and hydrogen storage. The levelized costs of green hydrogen electrofuels and synthetic natural gas were estimated for both scenarios. A sensitivity analysis was conducted to assess the impact of cost parameters on the levelized costs of hydrogen and alternative fuel production. The findings indicate that the Hydrogen Valley scenario results in a 5.9% increase in total annual costs but achieves a 29.5% reduction in CO2 emissions compared to the business-as-usual scenario. Additionally utilizing excess energy for power-to-gas and power-to-liquid conversion in the Hydrogen Valley scenario lowers the levelized cost of electrofuels from 0.28 €·kWh−1 to 0.21 €·kWh−1 . Similarly the levelized cost of synthetic natural gas decreases from 0.33 €·kWh−1 to 0.25 €·kWh−1 when transitioning from the businessas-usual scenario to the Hydrogen Valley scenario. The results highlight that Hydrogen Valleys enable low-emission energy systems with cost-effective alternative fuels underscoring the tradeoffs between deep decarbonization and cost optimization in the transition to clean energy systems.
Simulation of DDT in Obstructed Channels: Wavy Channels vs. Fence-type Obstacles
Sep 2023
Publication
The capabilities of an OpenFOAM solver to reproduce the transition of stoichiometric H2-air mixtures to detonation in obstructed 2-D channels were tested. The process is challenging numerically as it involves the ignition of a flame kernel its subsequent propagation and acceleration interaction with obstacles formation of shock waves ahead and detonation onset (DO). Two different obstacle configurations were considered in 10-mm high × 1-m long channels: (i) wavy walls (WW) that mimic the behavior of fencetype obstacles but prevent abrupt area changes. In this case flame acceleration (FA) is strongly affected by shock-flame interactions and DO often results from the compression of the gas present between the accelerating flame front and a converging section of the channel. (ii) Fence-type (FT) obstacles. In this case FA is driven by the increase in flame surface area as a result of the interaction of the flame front with the unburned gas flow field ahead particularly downstream of obstacles; shock-flame interactions play a role at the later stages of FA and DO takes place upon reflection of precursor shocks from obstacles. The effect of initial pressure p0 = 25 50 and 100 kPa at constant blockage ratio (BR = 0.6) was investigated and compared for both configurations. Results show that for the same initial pressure (p0 = 50 kPa) the obstacle configurations could lead to different final propagation regimes: a quasi-detonation for WW and a choked-flame for FT due to the increased losses for the latter. At p0 = 25 kPa however while both configurations result in choked flames WW seem to exhibit larger velocity deficits than FT due to longer flame-precursor shock distances during quasi-steady propagation and to the increased presence of unburnt mixture downstream of the tip of the flame that homogeneously explodes providing additional support to the propagation of the flame.
Deep Low-Carbon Economic Optimization Using CCUS and Two-Stage P2G with Multiple Hydrogen Utilizations for an Integrated Energy System with a High Penetration Level of Renewables
Jul 2024
Publication
Integrating carbon capture and storage (CCS) technology into an integrated energy system (IES) can reduce its carbon emissions and enhance its low-carbon performance. However the full CCS of flue gas displays a strong coupling between lean and rich liquor as carbon dioxide liquid absorbents. Its integration into IESs with a high penetration level of renewables results in insufficient flexibility and renewable curtailment. In addition integrating split-flow CCS of flue gas facilitates a short capture time giving priority to renewable energy. To address these limitations this paper develops a carbon capture utilization and storage (CCUS) method into which storage tanks for lean and rich liquor and a two-stage power-to-gas (P2G) system with multiple utilizations of hydrogen including a fuel cell and a hydrogen-blended CHP unit are introduced. The CCUS is integrated into an IES to build an electricity–heat–hydrogen–gas IES. Accordingly a deep low-carbon economic optimization strategy for this IES which considers stepwise carbon trading coal consumption renewable curtailment penalties and gas purchasing costs is proposed. The effects of CCUS the twostage P2G system and stepwise carbon trading on the performance of this IES are analyzed through a case-comparative analysis. The results show that the proposed method allows for a significant reduction in both carbon emissions and total operational costs. It outperforms the IES without CCUS with an 8.8% cost reduction and a 70.11% reduction in carbon emissions. Compared to the IES integrating full CCS the proposed method yields reductions of 6.5% in costs and 24.7% in emissions. Furthermore the addition of a two-stage P2G system with multiple utilizations of hydrogen further amplifies these benefits cutting costs by 13.97% and emissions by 12.32%. In addition integrating CCUS into IESs enables the full consumption of renewables and expands hydrogen utilization and the renewable consumption proportion in IESs can reach 69.23%.
Optimizing Maritime Energy Efficiency: A Machine Learning Approach Using Deep Reinforcement Learning for EEXI and CII Compliance
Nov 2024
Publication
The International Maritime Organization (IMO) has set stringent regulations to reduce the carbon footprint of maritime transport using metrics such as the Energy Efficiency Existing Ship Index (EEXI) and Carbon Intensity Indicator (CII) to track progress. This study introduces a novel approach using deep reinforcement learning (DRL) to optimize energy efficiency across five types of vessels: cruise ships car carriers oil tankers bulk carriers and container ships under six different operational scenarios such as varying cargo loads and weather conditions. Traditional fuels like marine gas oil (MGO) and intermediate fuel oil (IFO) challenge compliance with these standards unless engine power restrictions are applied. This approach combines DRL with alternative fuels—bio-LNG and hydrogen—to address these challenges. The DRL algorithm which dynamically adjusts engine parameters demonstrated substantial improvements in optimizing fuel consumption and performance. Results revealed that while using DRL fuel efficiency increased by up to 10% while EEXI values decreased by 8% to 15% and CII ratings improved by 10% to 30% across different scenarios. Specifically under heavy cargo loads the DRL-optimized system achieved a fuel efficiency of 7.2 nmi/ton compared to 6.5 nmi/ton with traditional methods and reduced the EEXI value from 4.2 to 3.86. Additionally the DRL approach consistently outperformed traditional optimization methods demonstrating superior efficiency and lower emissions across all tested scenarios. This study highlights the potential of DRL in advancing maritime energy efficiency and suggests that further research could explore DRL applications to other vessel types and alternative fuels integrating additional machine learning techniques to enhance optimization.
Storage Integrity During Underground Hydrogen Storage in Depleted Gas Reservoirs
Nov 2023
Publication
The transition from fossil fuels to renewable energy sources particularly hydrogen has emerged as a central strategy for decarbonization and the pursuit of net-zero carbon emissions. Meeting the demand for large-scale hydrogen storage a crucial component of the hydrogen supply chain has led to the exploration of underground hydrogen storage as an economically viable solution to global energy needs. In contrast to other subsurface storage options such as salt caverns and aquifers which are geographically limited depleted gas reservoirs have garnered increasing attention due to their broader distribution and higher storage capacity. However the safe storage and cycling of hydrogen in depleted gas reservoirs require the preservation of high stability and integrity in the caprock reservoir and wellbore. Nevertheless there exists a significant gap in the current research concerning storage integrity in underground hydrogen storage within depleted gas reservoirs and a systematic approach is lacking. This paper aims to address this gap by reviewing the primary challenges associated with storage integrity including geochemical reactions microbial activities faults and fractures and perspectives on hydrogen cycling. The study comprehensively reviews the processes and impacts such as abiotic and biotic mineral dissolution/precipitation reactivation and propagation of faults and fractures in caprock and host-rock wellbore instability due to cement degradation and casing corrosion and stress changes during hydrogen cycling. To provide a practical solution a technical screening tool has been developed considering controlling variables risks and consequences affecting storage integrity. Finally this paper highlights knowledge gaps and suggests feasible methods and pathways to mitigate these risks facilitating the development of large-scale underground hydrogen storage in depleted gas reservoirs.
Towards a Sustainable Future: Bio-hydrogen Production from Food Waste for Clean Energy Generation
Jan 2024
Publication
To address climate change energy security and waste management new sustainable energy sources must be developed. This study uses Aspen Plus software to extract bio-H2 from food waste with the goal of efficiency and environmental sustainability. Anaerobic digestion optimised to operate at 20-25°C and keep ammonia at 3% greatly boosted biogas production. The solvent [Emim][FAP] which is based on imidazolium had excellent performance in purifying biogas. It achieved a high level of methane purity while consuming a minimal amount of energy with a solvent flow rate of 13.415 m³/h. Moreover the utilization of higher temperatures (600-700°C) during the bio-H2 generation phase significantly enhanced both the amount and quality of hydrogen produced. Parametric and sensitivity assessments were methodically performed at every stage. This integrated method was practicable and environmentally friendly according to the economic assessment. H2 generation using steam reforming results in a TCC of 1.92×106 USD. The CO2 separation step has higher costs (TCC of 2.15×107 USD) due to ionic liquid washing and CO2 liquefaction. Compressor electricity consumption significantly impacts total operating cost (TOC) totaling 4.73×108 USD. showing its ability to reduce greenhouse gas emissions optimize resource utilization and promote energy sustainability. This study presents a sustainable energy solution that addresses climate and waste challenges.
Energy Use and Greenhouse Gas Emissions of Traction Alternatives for Regional Railways
Feb 2024
Publication
This paper presents a method for estimating Well-to-Wheel (WTW) energy use and greenhouse gas (GHG) emissions attributed to the advanced railway propulsion systems implemented in conjunction with different energy carriers and their production pathways. The analysis encompasses diesel-electric multiple unit vehicles converted to their hybrid-electric plug-in hybrid-electric fuel cell hybrid-electric or battery-electric counterparts combined with biodiesel or hydrotreated vegetable oil (HVO) as the first and second generation biofuels liquefied natural gas (LNG) hydrogen and/or electricity. The method is demonstrated using non-electrified regional railway network with heterogeneous vehicle fleet in the Netherlands as a case. Battery-electric system utilizing green electricity is identified as the only configuration leading to emission-free transport while offering the highest energy use reduction by 65–71% compared to the current diesel-powered hybrid-electric system. When using grey electricity based on the EU2030 production mix these savings are reduced to about 27–39% in WTW energy use and around 68–73% in WTW GHG emissions. Significant reductions in overall energy use and emissions are obtained for the plug-in hybrid-electric concept when combining diesel LNG or waste cooking oil-based HVO with electricity. The remaining configurations that reduce energy use and GHG emissions are hybrid-electric systems running on LNG or HVO from waste cooking oil. The latter led to approximately 88% lower WTW emissions than the baseline for each vehicle type. When produced from natural gas or EU2030-mix-based electrolysis hydrogen negatively affected both aspects irrespective of the prime mover technology. However when produced via green electricity it offers a GHG reduction of approximately 90% for hybrid-electric and fuel cell hybrid-electric configurations with a further reduction of up to 92–93% if combined with green electricity in plug-in hybrid-electric systems. The results indicate that HVO from waste cooking oil could be an effective and instantly implementable transition solution towards carbon–neutral regional trains allowing for a smooth transition and development of supporting infrastructure required for more energy-efficient and environment-friendly technologies.
Organic Oxidation-assisted Hydrogen Production: Glycerol Electroreforming to Formate on Nickel Diselenide Nanoparticles
Jul 2025
Publication
The energy efficiency of water electrolysis is limited by the sluggish kinetics of the anodic oxygen evolution reaction (OER) which simultaneously produces a low-value product oxygen. A promising strategy to address this challenge is to replace OER with a more favorable oxidation reaction that yields a valuable co-product. In this study we investigate the electrochemical reforming of glycerol in alkaline media to simultaneously produce hydrogen at a Pt cathode and formate at a NiSe₂ anode. The NiSe₂ electrode achieves a glycerol oxidation reaction (GOR) current density of up to 100 mA cm−2 in a 1 M KOH solution containing 1 M glycerol significantly outperforming a reference elemental Ni electrode. Both electrodes exhibit high Faradaic efficiencies (FE) achieving around 93 % for formate production at an applied potential of 1.6 V vs. RHE. To rationalize this exceptional performance density functional theory (DFT) calculations were conducted revealing that the incorporation of Se into NiSe₂ enhances the glycerol adsorption and modulates the electron density thereby lowering the energy barrier for the initial dehydrogenation step in the formate formation pathway. These findings provide valuable insights for the design of cost-effective high-performance electrocatalysts for organic oxidation-assisted hydrogen production advancing a more sustainable and economically attractive route for hydrogen generation and chemical valorization.
Research of the Impact of Hydrogen Metallurgy Technology on the Reduction of the Chinese Steel Industry’s Carbon Dioxide Emissions
Feb 2024
Publication
The steel industry which relies heavily on primary energy is one of the industries with the highest CO2 emissions in China. It is urgent for the industry to identify ways to embark on the path to “green steel”. Hydrogen metallurgy technology uses hydrogen as a reducing agent and its use is an important way to reduce CO2 emissions from long-term steelmaking and ensure the green and sustainable development of the steel industry. Previous research has demonstrated the feasibility and emission reduction effects of hydrogen metallurgy technology; however further research is needed to dynamically analyze the overall impact of the large-scale development of hydrogen metallurgy technology on future CO2 emissions from the steel industry. This article selects the integrated MARKAL-EFOM system (TIMES) model as its analysis model constructs a China steel industry hydrogen metallurgy model (TIMES-CSHM) and analyzes the resulting impact of hydrogen metallurgy technology on CO2 emissions. The results indicate that in the business-as-usual scenario (BAU scenario) applying hydrogen metallurgy technology in the period from 2020 to 2050 is expected to reduce emissions by 203 million tons and make an average 39.85% contribution to reducing the steel industry’s CO2 emissions. In the carbon emission reduction scenario applying hydrogen metallurgy technology in the period from 2020 to 2050 is expected to reduce emissions by 353 million tons contributing an average of 41.32% to steel industry CO2 reduction. This study provides an assessment of how hydrogen metallurgy can reduce CO2 emissions in the steel industry and also provides a reference for the development of hydrogen metallurgy technology.
Social Risk Approach for Assessing Public Safety of Large-scale Hydrogen Systems
Sep 2023
Publication
Social risk is a comprehensive concept that considers not only internal/external physical risks but also risks (which are multiple varied and diverse) associated with social activity. It should be considered from diverse perspectives and requires a comprehensive evaluation framework that takes into account the synergistic impact of each element on others rather than evaluating each risk individually. Social risk assessment is an approach that is not limited to internal system risk from an engineering perspective but also considers the stakeholders development stage and societal readiness and resilience to change. This study aimed to introduce a social risk approach to assess the public safety of large-scale hydrogen systems. Guidelines for comprehensive social risk assessment were developed to conduct appropriate risk assessments for advanced science and technology activities with high uncertainties to predict major impacts on society before an accident occurs and to take measures to mitigate the damage and to ensure good governance are in place to facilitate emergency response and recovery in addition to preventive measures. In a case study this approach was applied to a hydrogen refueling station in Japan and risk-based multidisciplinary approaches were introduced. These approaches can be an effective supporting tool for social implementation with respect to large-scale hydrogen systems such as liquefied hydrogen storage tanks. The guidelines for social risk assessment of large-scale hydrogen systems are under the International Energy Agency Technology Collaboration Program Hydrogen Safety Task 43. This study presents potential case studies of social risk assessment for large-scale hydrogen systems for future.
An Overview of Application-orientated Multifunctional Large-scale Stationary Battery and Hydrogen Hybrid Energy Storage System
Dec 2023
Publication
The imperative to address traditional energy crises and environmental concerns has accelerated the need for energy structure transformation. However the variable nature of renewable energy poses challenges in meeting complex practical energy requirements. To address this issue the construction of a multifunctional large-scale stationary energy storage system is considered an effective solution. This paper critically examines the battery and hydrogen hybrid energy storage systems. Both technologies face limitations hindering them from fully meeting future energy storage needs such as large storage capacity in limited space frequent storage with rapid response and continuous storage without loss. Batteries with their rapid response (90%) excel in frequent short-duration energy storage. However limitations such as a selfdischarge rate (>1%) and capacity loss (~20%) restrict their use for long-duration energy storage. Hydrogen as a potential energy carrier is suitable for large-scale long-duration energy storage due to its high energy density steady state and low loss. Nevertheless it is less efficient for frequent energy storage due to its low storage efficiency (~50%). Ongoing research suggests that a battery and hydrogen hybrid energy storage system could combine the strengths of both technologies to meet the growing demand for large-scale long-duration energy storage. To assess their applied potentials this paper provides a detailed analysis of the research status of both energy storage technologies using proposed key performance indices. Additionally application-oriented future directions and challenges of the battery and hydrogen hybrid energy storage system are outlined from multiple perspectives offering guidance for the development of advanced energy storage systems.
Grid-neutral Hydrogen Mobility: Dynamic Modelling and Techno-economic Assessment of a Renewable-powered Hydrogen Plant
Jun 2024
Publication
The seasonally varying potential to produce electricity from renewable sources such as wind PV and hydropower is a challenge for the continuous supply of hydrogen for transport and mobility. Seasonal storage of energy allows to avoid the use of grid electricity when it is scarce; storage systems can thus increase the resilience of the energy system. For grid-neutral and renewable hydrogen production an electrolyser is considered together with a Power-to-Gas seasonal storage system which consists of a methanation the gas grid as intermediate storage and a steam reformer. As feed stream electricity from an own photovoltaic (PV) system is considered and for some cases additional electricity from the grid or from a wind turbine. The dynamic operation of the plant during a year is simulated. It is possible to safely supply fuel cell vehicles with hydrogen from the grid-neutral plant without using electricity when it is scarce and expensive. To supply 135 kgH2/day unit sizes of 1 MW–2.9 MW for the PV system and 0.9 MW–2.6 MW for the electrolysis are required depending on the amount of available grid-electricity. The usage of grid-electricity increases the capacity factor of the electrolysis which results in decreased unit sizes and in a better economic performance. Seasonal storage of energy is required which results in an increased hydrogen production in summer of approximately 50% more than directly needed by the fuel cell vehicles. The overall efficiency from electricity to hydrogen is decreased due to the storage path by 10%-points to 56% based on the higher heating value. Assuming a cost-equivalent hydrogen price per driven kilometre in comparison to the actual diesel price and electricity costs of 10 Ct/kWhel from the grid the revenues of the system are higher than the operating costs.
Artificial Neural Networks as a Tool for High-Accuracy Prediction of In-Cylinder Pressure and Equivalent Flame Radius in Hydrogen-Fueled Internal Combustion Engines
Jan 2025
Publication
The automotive industry is under increasing pressure to develop cleaner and more efficient technologies in response to stringent emission regulations. Hydrogenpowered internal combustion engines represent a promising alternative offering the potential to reduce carbon-based emissions while improving efficiency. However the accurate estimation of in-cylinder pressure is crucial for optimizing the performance and emissions of these engines. While traditional simulation tools such as GT-POWER are widely utilized for these purposes recent advancements in artificial intelligence provide new opportunities for achieving faster and more accurate predictions. This study presents a comparative evaluation of the predictive capabilities of GT-POWER and an artificial neural network model in estimating in-cylinder pressure with a particular focus on improvements in computational efficiency. Additionally the artificial neural network is employed to predict the equivalent flame radius thereby obviating the need for repeated tests using dedicated high-speed cameras in optical access research engines due to the resource-intensive nature of data acquisition and post-processing. Experiments were conducted on a single-cylinder research engine operating at low-speed and low-load conditions across three distinct relative air–fuel ratio values with a range of ignition timing settings applied for each air excess coefficient. The findings demonstrate that the artificial neural network model surpasses GT-POWER in predicting in-cylinder pressure with higher accuracy achieving an RMSE consistently below 0.44% across various conditions. In comparison GT-POWER exhibits an RMSE ranging from 0.92% to 1.57%. Additionally the neural network effectively estimates the equivalent flame radius maintaining an RMSE of less than 3% ranging from 2.21% to 2.90%. This underscores the potential of artificial neural network-based approaches to not only significantly reduce computational time but also enhance predictive precision. Furthermore this methodology could subsequently be applied to conventional road engines exhibiting characteristics and performance similar to those of a specific optical engine used as the basis for the machine learning analysis offering a practical advantage in real-time diagnostics.
Advances and Challenges in Thermoacoustic Network Modeling for Hydrogen and Ammonia Combustors
Jan 2025
Publication
The transition to low-carbon energy systems has heightened interest in hydrogen and ammonia as sustainable alternatives to traditional hydrocarbon fuels. However the development and operation of combustors utilizing these fuels like other combustion systems are challenged by thermoacoustic instabilities arising from the interaction between unsteady heat release and acoustic wave oscillations. Among many different methods for studying thermoacoustic instabilities thermoacoustic network models have played an important role in analyzing the essential dynamics of these instabilities in combustors operating with low-carbon fuels. This paper provides a comprehensive review of thermoacoustic network modeling techniques focusing specifically on their application to hydrogen- and ammonia-based combustion systems. We outline the key mathematical frameworks derived from fundamental equations of motion along with experimental validations and practical applications documented in existing studies. Furthermore current research gaps are identified and future directions are proposed to improve the reliability and effectiveness of thermoacoustic network models contributing to the advancement of efficient and stable low-carbon combustors.
Empowering Fuel Cell Electric Vehicles Towards Sustainable Transportation: An Analytical Assessment, Emerging Energy Management, Key Issues, and Future Research Opportunities
Oct 2024
Publication
Fuel cell electric vehicles (FCEVs) have received significant attention in recent times due to various advantageous features such as high energy efficiency zero emissions and extended driving range. However FCEVs have some drawbacks including high production costs; limited hydrogen refueling infrastructure; and the complexity of converters controllers and method execution. To address these challenges smart energy management involving appropriate converters controllers intelligent algorithms and optimizations is essential for enhancing the effectiveness of FCEVs towards sustainable transportation. Therefore this paper presents emerging energy management strategies for FCEVs to improve energy efficiency system reliability and overall performance. In this context a comprehensive analytical assessment is conducted to examine several factors including research trends types of publications citation analysis keyword occurrences collaborations influential authors and the countries conducting research in this area. Moreover emerging energy management schemes are investigated with a focus on intelligent algorithms optimization techniques and control strategies highlighting contributions key findings issues and research gaps. Furthermore the state-of-the-art research domains of FCEVs are thoroughly discussed in order to explore various research domains relevant outcomes and existing challenges. Additionally this paper addresses open issues and challenges and offers valuable future research opportunities for advancing FCEVs emphasizing the importance of suitable algorithms controllers and optimization techniques to enhance their performance. The outcomes and key findings of this review will be helpful for researchers and automotive engineers in developing advanced methods control schemes and optimization strategies for FCEVs towards greener transportation.
Hydrogen Energy Systems: Technologies, Trends, and Future Prospects
May 2024
Publication
This review critically examines hydrogen energy systems highlighting their capacity to transform the global energy framework and mitigate climate change. Hydrogen showcases a high energy density of 120 MJ/kg providing a robust alternative to fossil fuels. Adoption at scale could decrease global CO2 emissions by up to 830 million tonnes annually. Despite its potential the expansion of hydrogen technology is curtailed by the inefficiency of current electrolysis methods and high production costs. Presently electrolysis efficiencies range between 60 % and 80 % with hydrogen production costs around $5 per kilogram. Strategic advancements are necessary to reduce these costs below $2 per kilogram and push efficiencies above 80 %. Additionally hydrogen storage poses its own challenges requiring conditions of up to 700 bar or temperatures below −253 °C. These storage conditions necessitate the development of advanced materials and infrastructure improvements. The findings of this study emphasize the need for comprehensive strategic planning and interdisciplinary efforts to maximize hydrogen's role as a sustainable energy source. Enhancing the economic viability and market integration of hydrogen will depend critically on overcoming these technological and infrastructural challenges supported by robust regulatory frameworks. This comprehensive approach will ensure that hydrogen energy can significantly contribute to a sustainable and low-carbon future.
Economic and Resilient Operation of Hydrogen-based Microgrids: An Improved MPC-based Optimal Scheduling Scheme Considering Security Constraints of Hydrogen Facilities
Feb 2023
Publication
Optimally scheduling alkaline electrolyzers (AELs) in a hydrogen-based microgrid (HBM) can greatly unleash the operational flexibility of the HBM. However existing scheduling strategies of AELs mostly utilize a simplified AEL model which ignores the nonlinear coupling of electric-hydrogen-thermal sectors violating the AEL’s security constraints thereby making the scheduling scheme infeasible. This paper proposes an improved model predictive control (MPC) based optimal scheduling framework which incorporates a scheduling correction algorithm into the basic MPC structure. This framework is utilized for implementing economic and resilient scheduling of an HBM under normal and emergency conditions respectively. With the scheduling correction algorithm this framework can be formulated into a computationally efficient mixedinteger linear programming meanwhile guaranteeing the solutions strictly satisfy the security constraints of hydrogen facilities (i.e. AEL and hydrogen tank). Case studies are conducted based on real operating data of a Danish energy island Bornholm. The results demonstrate that the proposed scheduling scheme under normal conditions can contribute to significant comprehensive benefits from the daily operation cost saving of 68% computational time saving of 98% and satisfying the security constraints of hydrogen facilities compared to previous scheduling strategies. Besides it sharply reduces load shedding under emergency conditions by proactively allocating distributed energy sources in the HBM.
Paving the Way for Renewable Energy and Hydrogen Adoption in Southern Africa
Jun 2025
Publication
Rising population and rapid development in Africa have led to growing energy demands that exceed current supply underscoring the urgent need for expanded and reliable energy access. As the global agenda shifts toward sustainability integrating renewable energy sources presents a viable pathway to address these shortages. This study explores the energy landscape policies and transition strategies of five Southern African countries using Multi-Level Perspective theory and energy systems analysis to examine the dynamics of their energy transitions. Findings highlight the significant potential of green hydrogen solar wind and hydropower to supplement conventional fuels especially in energy-intensive sectors while reducing reliance on fossil fuels and mitigating climate impacts. The application of Multi-Level Perspective theory underscores the importance of managing interactions between niche innovations existing socio-technical regimes and broader landscape pressures to support systemic transformation. The transition to renewable energy will also impact the future of coal mining shaped by policy frameworks resource distribution technological developments and market trends. However several persistent barriers must be overcome these include limited access to energy high capital costs poverty political and economic instability regulatory inefficiencies and gaps in technical expertise. Achieving a successful and inclusive energy transition in Southern Africa will require strategic planning policy alignment stakeholder engagement and targeted support for vulnerable sectors. Ensuring that the process is sustainable equitable and just is essential to realizing long-term regional energy security and economic resilience.
Storage and Transportation Technology Solutions Selection for Large-scale Hydrogen Energy Utilization Scenarios under the Trend of Carbon Neutralization
Apr 2021
Publication
This paper mainly introduces the main pain point of China's civil hydrogen energy supply chain - the problem of storage and transportation and analyzes the safety economy and scale effect and other issues of the existing hydrogen energy storage and transportation compares with other storage and transportation technology solutions and comprehensively screens out the storage and transportation technology solution mainly based on liquid hydrogen technology. The liquid hydrogen technology solution has significant advantages over the existing compressed hydrogen system in terms of safety economy and scale effect especially for future large-scale hydrogen energy application scenarios. In addition the future hydrogen energy storage and transportation system based on liquid hydrogen technology can help improve the overall utilization efficiency of country’s renewable energy promote the country's energy transition promote the electrification of the country's transportation sector and help achieve China's carbon emission reduction 2030/2060 target.
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