Publications
An Overview of the Hydrogen Value Chain in Energy Transitioning Economies: A Focus on India
Oct 2025
Publication
India’s energy sector is undergoing a major transformation as the nation targets energy independence by 2047 and net-zero emissions by 2070. With a high dependency on energy imports a strategic shift toward renewable energy and decarbonisation is crucial. Hydrogen has emerged as a promising solution to address energy storage and sustainability challenges prompting emerging countries to develop strong hydrogen infrastructures. This paper examines various methods involved in the hydrogen value chain from production to utilisation from the perspective of transitioning economies. By identifying key parameters and existing gaps this paper aims to support policymakers and stakeholders in designing effective strategies to accelerate the development of a sustainable and secure hydrogen economy. India currently relies on carbon-intensive hydrogen from fossil fuels. Green hydrogen faces high costs and infrastructure gaps. Despite storage and safety concerns hydrogen shows strong potential for clean energy and industry transformation.
Assessing Hydrogen Supply and Demand in the Liverpool City Region: A Regional Development Review from Stakeholders' Perspective
Oct 2025
Publication
Under the UK’s carbon neutrality goals for 2050 the Liverpool City Region’s (LCR) strategic positioning with its rich industrial heritage and infrastructure assets such as extensive port facilities and proximity to vast renewable energy resources positions it as a potential leader in the UK’s shift towards a hydrogen economy. Given this the regional hydrogen industry and stakeholders in decarbonisation initiatives intend to undertake a critical review of the opportunities challenges and uncertainties to local hydrogen supply and demand systems to assist in their decision-making. To achieve this goal this study reviews the readiness of the hydrogen supply chain infrastructure within the LCR which highlights four sectors in the hydrogen economy i.e. production storage transportation and utilisation. Subsequently to offer the first-hand data in practice a multi-faceted approach that incorporates a broad array of stakeholders through the Triple Helix (TH) model is adopted. Special attention is given to hydrogen’s role in transforming heavy industry transportation and heating sectors supported by significant local projects like HyNet North West. During a roundtable discussion industry-academia-government stakeholders identify challenges in scaling up infrastructure and assess the economic and technological landscape for hydrogen adoption. To the best of our knowledge this will be the first regional academic endeavour to comprehensively examine the alignment between hydrogen supply and demand theory and practice. Based on a detailed SWOT analysis this study outlines the region’s strengths including established industrial clusters and technological capabilities in manufacturing. It also highlights weaknesses such as the high costs associated with emerging hydrogen technologies technological immaturity and gaps in necessary infrastructure. The opportunities presented by national policy incentives and growing global demand for sustainable energy solutions are considered alongside threats including regulatory complexities and the slow pace of public acceptance. This comprehensive examination not only maps the current landscape but also sets the stage for strategic interventions needed to realise hydrogen’s full potential within the LCR aiming to guide policymakers industry leaders and researchers in their efforts to foster a viable hydrogen economy. Moreover the findings offer valuable insights that can inform the development of hydrogen strategies in other regions and cities.
Enhancing Hydrogen Production from Biomass Steam Gasification: The Role of Chemical Variability of Industrial Biomass Fly Ash Catalysts
Oct 2025
Publication
This study examines the influence of industrial biomass fly ash (BFA) composition variability on its catalytic performance in biomass steam gasification particularly regarding producer gas quality and hydrogen production. BFA samples collected over two years from a bubbling fluidised bed combustion system were granulated and calcined to remove CO2. Water-gas shift (WGS) reaction tests identified temperature as a key factor in H2 production with BFA promoting CO conversion and increasing H2 yield by over 26-fold. Bench-scale gasification experiments confirmed BFA’s catalytic potential with alkali and alkaline earth metals (AAEM) enhancing H2 yield up to two-fold and improving tar conversion. BFA-A granules richest in CaO achieved the highest H2 concentration (exceeding 50 % vol.dry and inert (N2 Ar) free gas). Despite slight variations all BFA samples demonstrated strong catalytic performance supporting their effective repurposing as waste-derived catalysts within industrial applications aligning with circular economy principles.
LES Analysis of the DLR F400S.3 mGT Burner Operating with 100% Hydrogen Fuel
Oct 2025
Publication
The paper approaches a computational evaluation of the 100% hydrogen fueled DLR micro-Gas Turbine (mGT) burner F400S.3 through high-fidelity Large Eddy Simulations (LES). Sensitivity analyses on the thermal boundary conditions of the burner walls and the turbulent combustion model were conducted. The experimental OH*-Chemiluminescence distribution was compared with numerical results obtained using the Partially Stirred Reactor (PaSR) and the Extended Flamelet Generated Manifold (ExtFGM) combustion models. The results showed good agreement regarding the flame shape and reactivity prediction when non-adiabatic thermal boundary conditions were applied at the burner walls and the PaSR model was implemented. On the contrary the ExtFGM model exhibited underprediction in flame length and flame lift-off overestimating flame reactivity. Finally after selecting the combustion model that best retrieved the experimental data a pressurized LES was performed on the combustor domain to evaluate its performance under real operating conditions for mGT.
Decentralized Use Case Integration of Chemical Hydrogen Carriers: The Cost Saving Potential in Domestic Supply Chains
Oct 2025
Publication
The use of chemical hydrogen carriers such as ammonia (NH3) methanol (MeOH) dimethyl ether (DME) and liquid organic hydrogen carriers (LOHC) is considered as a potential option for hydrogen imports. Following import the carriers are either converted centrally into hydrogen or transported further to the point of use. This study evaluates various domestic transport options – truck rail inland waterway and pipeline – as unimodal or intermodal transport for hydrogen and chemical hydrogen carriers. Based on this the potential of transport and decentralized integration of carriers for various locations is assessed. A cost comparison is used to determine the maximum specific costs that a decentralized conversion plant can incur while remaining competitive with a centralized conversion plant in the port. The analysis shows that the specific costs of decentralized conversion plants at numerous locations can be significantly higher than those of centralized plants indicating considerable cost-saving potential.
Towards Sustainable Blue Hydrogen: Integrating Membrane-based Carbon Capture and Oxygen-enriched Combustion
Oct 2025
Publication
Blue hydrogen production typically achieved by combining steam methane reforming with amine-based CO2 capture is widely considered an economical route towards clean hydrogen. However it suffers from high energy demands associated with solvent regeneration. To overcome this limitation we propose a novel hybrid approach integrating steam methane reforming with membrane-based CO2 capture and O2-enriched combustion. Using process simulations we conducted comprehensive techno-economic and environmental analyses to assess critical parameters affecting the levelised cost of hydrogen (LCOH) and CO2 emissions. Optimal results were obtained at an enriched oxygen level of 30% using vacuum pumping and CO2 capture via feed compression at 11 bar. This configuration achieved an LCOH of ~$1.8/kg H2 and total specific CO2 emissions of ~4.9 kg CO2/kg H2. This aligns closely with conventional blue hydrogen benchmarks with direct emissions significantly reduced to around 1 kg CO2/kg H2. Additionally sensitivity analysis showed robust economic performance despite variations in energy prices. Anticipated advancements in membrane technology could reduce the LCOH further to approximately $1.5/kg H2. Thus this hybrid membrane-based process presents a competitive and sustainable strategy supporting the achievement of the 2050 net-zero emissions goals in hydrogen production.
Ground Testing and Analysis of Liquid-hydrogen Propulsion System for UAVs
Oct 2025
Publication
This paper presents an experimental campaign on a complete liquid hydrogen (LH2 ) propulsion system for small uncrewed aerial vehicles. The first part investigates the boil-off performance of five 12 L (0.85 kg) LH2 reservoirs with different internal designs. Results show average evaporation rates of 17–37 g/h and total evaporation times of 23–50 h corresponding to endurance of up to 50 h depending on fabrication technique and insulation design. The second part examines the integrated propulsion chain from the LH2 reservoir to the fuel cell including hydrogen transfer through an instrumented line and heat exchanger. The system delivers over 14000 Wh of electrical energy enabling ranges up to 4400 km for a 4 m fixed-wing UAV with flight speeds of 24–27 m/s. A first-order theoretical model is introduced to support preliminary sizing mass estimation and boil-off prediction. These results demonstrate clear endurance advantages of LH2 storage over compressed hydrogen systems.
Molten Metal Methane Pyrolysis for Distributed Hydrogen Production: Reactor Design, Hydrodynamics, and Technoeconomic Insights
Oct 2025
Publication
Methane pyrolysis offers a compelling pathway for low-carbon hydrogen production by avoiding CO2 emissions and enabling distributed deployment in locations with natural gas supply thereby eliminating the need for costly hydrogen transport. While promising the commercial deployment is constrained by the lack of detailed reactor modeling and technoeconomic assessment at small production scales. This study addresses these gaps by designing and modeling a small-scale (1–10 t-H2/day) bubble column reactor employing molten Ni–Bi alloy catalyst for methane pyrolysis. A coupled kinetic–hydrodynamic model was developed to simulate gas holdup bubble behavior and conversion under different operating conditions. The reactor design was integrated into an Aspen Plus simulation of the full process including heat recovery and hydrogen purification. Optimization of pressure temperature and single-pass conversion revealed that operation at 1100 ◦C 15 bar and 70–75 % conversion minimized reactor volume and cost. The lowest levelized cost of hydrogen (LCOH) achieved was $3.06/kg-H2 without sale of carbon significantly lower than green H2 produced from water electrolysis and competitive with blue H2 produced via centralized reforming when transportation costs are included. Sensitivity analysis reveals that carbon byproduct is a key economic lever; carbon sale at $250/t-C reduces LCOH by 25 % while a price of $700/t-C would meet U.S. DOE $1/kg-H₂ target. These results demonstrate the technoeconomic viability of molten metal methane pyrolysis and highlight future opportunities.
Dynamic Pressure Characteristics of Multi-mode Combustion Instability in a Model Gas Turbine Combustor under Simulated Hydrogen-methane Co-firing Conditions
Oct 2025
Publication
The adoption of H2 fuel in gas turbine systems is steadily increasing as part of the transition toward cleaner energy sources. However its unique combustion characteristics pose significant challenges in managing combustion instability. This study examines the acoustic behavior of H2-CH4 mixed-fuel combustion instability using a model gas turbine combustor. To simulate instability situation of mixed fuel multi-mode acoustic excitation experiments are performed with the fixed fundamental forcing at the combustor's resonance frequency (∼160 Hz) together with additional variable forcing at 250 Hz and 1000 Hz which are the representative instability modes of CH4 and H2 flames respectively. In some cases highly risky signal amplification is observed. For example when the amplitude ratios of forcing at 160 250 and 1000 Hz are 1:9:0 the response reaches up to 106.15 kPa at the other frequency of 1750 Hz. This phenomenon is confirmed by attribution of the interaction of the overlapping mode frequencies and the node and antinode position of standing wave with no such amplification observed at other experimental conditions. Consequently the optimal sensor location is expected to vary with changes in the co-firing ratio and conditions and identifying these optimal positions is essential for reliable monitoring and successful implementation of H2 co-firing technology.
Certification Gap Analysis for Normal-Category and Large Hydrogen-Powered Airplanes
Mar 2025
Publication
The transition to hydrogen as an aviation fuel as outlined in current decarbonization roadmaps is expected to result in the entry into service of hydrogen-powered aircraft in 2035. To achieve this evolution certification regulations are key enablers. Due to the disruptive nature of hydrogen aircraft technologies and their associated hazards it is essential to assess the maturity of the existing regulatory framework for certification to ensure its availability when manufacturers apply for aircraft certification. This paper presents the work conducted under the Clean Aviation CONCERTO project to advance certification readiness by comprehensively identifying gaps in the current European regulations. Generic methodologies were developed for regulatory gap and risk analyses and applied to a hydrogen turbine aircraft with non-propulsive fuel cells as the APU. The gap analysis conducted on certification specifications for large and normal-category airplanes as well as engines confirmed the overall adequacy of many existing requirements. However important gaps exist to appropriately address hydrogen hazards particularly concerning fire and explosion hydrogen storage and fuel systems crashworthiness and occupant survivability. The paper concludes by identifying critical areas for certification and highlighting the need for complementary hydrogen phenomenology data which are key to guiding future research and regulatory efforts for certification readiness maturation.
Hydrogen Storage Potential of Salado Formation in the Permian Basin of West Texas, United States
Jun 2025
Publication
Hydrogen (H2) has the potential to become a cleaner fuel alternative to increase energy mix versatility as part of a low-carbon economy. Geological H2 storage represents a key component of the emerging H2 value chain since large-scale energy generation linked to energy generation and large-scale industrial applications will require significant upscaling of geological storage. Geological H2 storage can take place in both salt domes and bedded salt formations. Bedded salt formations offer a significant advantage for H2 storage over salt domes because of their widespread availability. This research focuses on evaluating the H2 storage potential of the Salado Formation a bedded salt deposit in the Permian Basin of West Texas in the United States. Using data from 3268 well logs this study analyzes an area of 136100 km2 to identify suitable depth and net halite thickness for H2 storage in salt caverns. In addition this work applies a novel geostatistical workflow to quantify the uncertainty in the formation’s storage potential. The H2 working gas potential of the Salado Formation ranges from 0.62 to 17.53 Tsm3 (1.75–49.68 PWh of stored energy) across low-risk to high-risk scenarios with a median potential of 1.19 Tsm3 (3.37 PWh). The counties with the largest storage potential are: Lea in New Mexico and Gaines and Andrews in Texas. These three counties account for more than 75 % of the formation’s total storage potential. This is the first study to quantify uncertainty in H2 storage estimates for a bedded salt formation while providing a detailed breakdown of results by county and 1 km2 grid sections. The findings of this work offer critical insights for developing H2 infrastructure in the Permian Basin. The Permian Basin of West Texas has the potential to become an important hub for H2 production from both natural gas and/or renewable energy. Estimating H2 storage potential is an important contribution to assess the feasibility of the entire H2 value chain in Texas. An interactive map accompanies this work allowing the readers to explore the results visually.
A Review of Integrated Carbon Capture and Hydrogen Storage: AI-Driven Optimization for Efficiency and Scalability
Jun 2025
Publication
Achieving global net-zero emissions by 2050 demands integrated and scalable strategies that unite decarbonization technologies across sectors. This review provides a forwardlooking synthesis of carbon capture and storage and hydrogen systems emphasizing their integration through artificial intelligence to enhance operational efficiency reduce system costs and accelerate large-scale deployment. While CCS can mitigate up to 95% of industrial CO2 emissions and hydrogen particularly blue hydrogen offers a versatile low-carbon energy carrier their co-deployment unlocks synergies in infrastructure storage and operational management. Artificial intelligence plays a transformative role in this integration enabling predictive modeling anomaly detection and intelligent control across capture transport and storage networks. Drawing on global case studies (e.g. Petra Nova Northern Lights Fukushima FH2R and H21 North of England) and emerging policy frameworks this study identifies key benefits technical and regulatory challenges and innovation trends. A novel contribution of this review lies in its AI-focused roadmap for integrating CCS and hydrogen systems supported by a detailed analysis of implementation barriers and policy-enabling strategies. By reimagining energy systems through digital optimization and infrastructure synergy this review outlines a resilient blueprint for the transition to a sustainable low-carbon future.
Above-ground Hydrogen Storage: A State-of-the-art Review
Oct 2024
Publication
Hydrogen is increasingly recognized as a clean energy alternative offering effective storage solutions for widespread adoption. Advancements in storage electrolysis and fuel cell technologies position hydrogen as a pathway toward cleaner more efficient and resilient energy solutions across various sectors. However challenges like infrastructure development cost-effectiveness and system integration must be addressed. This review comprehensively examines above-ground hydrogen storage technologies and their applications. It highlights the importance of established hydrogen fuel cell infrastructure particularly in gaseous and LH2 systems. The review favors material-based storage for medium- and long-term needs addressing challenges like adverse thermodynamics and kinetics for metal hydrides. It explores hydrogen storage applications in mobile and stationary sectors including fuel-cell electric vehicles aviation maritime power generation systems off-grid stations power backups and combined renewable energy systems. The paper underscores hydrogen’s potential to revolutionize stationary applications and co-generation systems highlighting its significant role in future energy landscapes.
Hydrogen-based Technologies towards Energy-resilient Low-carbon Buildings: Opportunities and Challenges Review
Oct 2025
Publication
Towards low-carbon buildings with resilient energy performance renewable energy resources and flexible energy assets play key roles in managing the electrical and heat demands. Hydrogen-based systems represent a promising solution through renewable hydrogen production and long-term storage. This paper systematically reviews 35 peer-reviewed studies (1990–2024) on hydrogen integration in buildings focusing on demand-side management (DSM) optimization methods and system performance. The review covers the environmental impacts feasibility and economic viability of integrating different hydrogen systems for supplying energy. Across critical reviews case studies hydrogen supplementary systems achieved CO2 reductions between 12 % and 87 % operational cost decreases of up to 40 % and efficiency gains exceeding 80 %. Payback periods varied widely between 9 and 20 years demonstrating high investment costs. Key gaps include limited field validation economic feasibility and public acceptance of hydrogen homes. One key area for future investigation is optimizing energy flows across production storage and demand particularly in Vehicle-to-Building (V2B) applications. This review paper highlights opportunities especially the potential of hydrogen system in decarbonization of buildings by long-term energy storage barriers and policy needs for implementing hydrogen technologies in grid-connected and remote areas to enhance sustainable and resilient buildings.
Hydrogen Production from Winery Wastewater Through a Dual-Chamber Microbial Electrolysis Cell
Jun 2025
Publication
This study explores the feasibility of producing biohydrogen from winery wastewater using a dual-chamber microbial electrolysis cell (MEC). A mixed microbial consortium pre-adapted to heavy-metal environments and enriched with Geobacter sulfurreducens was anaerobically cultivated from diverse waste streams. Over 5000 h of development the MEC system was progressively adapted to winery wastewater enabling long-term electrochemical stability and high organic matter degradation. Upon winery wastewater addition (5% v/v) the system achieved a sustained hydrogen production rate of (0.7 ± 0.3) L H2 L −1 d −1 with an average current density of (60 ± 4) A m−3 and COD removal efficiency exceeding 55% highlighting the system’s resilience despite the presence of inhibitory compounds. Coulombic efficiency and cathodic hydrogen recovery reached (75 ± 4)% and (87 ± 5)% respectively. Electrochemical impedance spectroscopy provided mechanistic insight into charge transfer and biofilm development correlating resistive parameters with biological adaptation. These findings demonstrate the potential of MECs to simultaneously treat agro-industrial wastewaters and recover energy in the form of hydrogen supporting circular resource management strategies.
e-REFORMER for Sustainable Hydrogen Production: Enhancing Efficiency in the Steam Methane Reforming Process
Aug 2025
Publication
Electrifying heat supply in chemical processes offers a strategic pathway to reduce CO2 emissions associated with fossil fuel combustion. This study investigates the retrofit of an existing terrace-wall Steam Methane Reformer (SMR) in an ammonia plant by replacing fuel-fired burners with electric resistance heaters in the radiant section. The proposed e-REFORMER concept is applied to a real-world case producing hydrogen-rich syngas at 29000 Nm3 /h with simulation and energy analysis performed using Aspen HYSYS®. The results show that electric heating reduces total thermal input by 3.78 % lowers direct flue gas CO2 emissions by 91.56 % and improves furnace thermal efficiency from 85.6 % to 88.9 % (+3.3 %). The existing furnace design and convection heat recovery system are largely preserved maintaining process integration and plant operability. While the case study reflects a medium-scale plant the methodology applies to larger facilities and supports integration with decarbonised power grids and Carbon Capture Utilisation and Storage (CCUS) technologies. This work advances current literature by addressing full-system integration of electrification within hydrogen and ammonia production chains offering a viable pathway to improve energy efficiency and reduce industrial emissions.
Novel Sustainability Assessment Methodology with Alternative Use Impact Accounting: Application on Use of Hydrogen in Transportation Sector
Sep 2025
Publication
This study presents the application of a new sustainability assessment methodology. It aims to improve the information that can be obtained from a sustainability assessment including the concept of alternative usage impact. To prove the effectiveness of this methodology three different hydrogen production methodologies considering its consumption in transportation sector is the case of study. The methodologies considered are Steam Methane Reform using natural gas Proton Exchange Membrane electrolysis one using grid electricity and the other study case using central tower solar power plant electricity from the PS10 facility. While separately green hydrogen is the technology with less environmental impact when considering the full system and the impact of the green hydrogen on the rest of the resources the integration of green hydrogen technology is not the most environmentally sustainable. Similar behavior is observed in the economic and technical fields. The different accounting of combinations of technologies and the impact on the resource which is not used provides the sustainability performance of the overall system. These results show that in order to account the all impacts taking place in a energy technology integration its impact on the rest of resources and uses provide more valuable information.
Analysis of the Main Hydrogen Production Technologies
Sep 2025
Publication
Hydrogen as a clean energy source has enormous potential in addressing global climate change and energy security challenges. This paper discusses different hydrogen production methodologies (steam methane reforming and water electrolysis) focusing on the electrolysis process as the most promising method for industrial-scale hydrogen generation. The review delved into three main electrolysis methods including alkaline water electrolysis proton exchange membrane electrolysis and anion exchange membrane electrolysis cells. Also the production of hydrogen as a by-product by means of membrane cells and mercury cells. The process of reforming natural gas (mainly methane) using steam is currently the predominant technique comprising approximately 96% of the world’s hydrogen synthesis. However it is carbon intensive and therefore not sustainable over time. Water as a renewable resource carbon-free and rich in hydrogen (11.11%) offers one of the best solutions to replace hydrogen production from fossil fuels by decomposing water. This article highlights the fundamental principles of electrolysis recent membrane studies and operating parameters for hydrogen production. The study also shows the amount of pollutant emissions (g of CO2/g of H2) associated with a hydrogen color attribute. The integration of water electrolysis with renewable energy sources constitutes an efficient and sustainable strategy in the production of green hydrogen minimizing environmental impact and optimizing the use of clean energy resources.
Spatial Planning Policies for Export-oriented Green-hydrogen Projects in Chile, Namibia, and South Africa
Jun 2025
Publication
Export-oriented green-hydrogen projects (EOGH2P) are being developed in regions with optimal renewableenergy resources. Their reliance on economies of scale makes them land-intensive and object of spatial planning policies. However the impact of spatial planning on the development of EOGH2P remains underexplored. Drawing on the spatial planning and megaproject literatures the analysis of planning documents and expert interviews this paper analyzes how spatial planning influences the development of EOGH2P in Chile Namibia and South Africa. The three countries have developed different spatial planning approaches for EOGH2Ps and are analyzed by employing a comparative case-study design. Our findings reveal that Namibia pursues a restrictive approach South Africa a facilitative approach whereas Chile is shifting from a market-based to a restrictive approach. The respective approaches reflect different political priorities and stakeholder interests and imply diverse effects on the development of EOGH2Ps in terms of their number size shared infrastructure socioenvironmental impact and acceptance. This study underscores the need for well-designed spatial planning frameworks and provides insights for planners and stakeholders on their potential effects.
Determining the Hydrogen Conversion Rates of a Passive Catalytic Recombiner for Hydrogen Risk Mitigation
May 2025
Publication
Hydrogen can play a key role as short- and long-term energy storage solution in an energy grid with fluctuating renewable sources. In technologies using hydrogen there is always the risk of unintended leakages due to the low density of gaseous hydrogen. The risk becomes specifically high in confined areas where leaking hydrogen could easily mix with air and form flammable gas mixtures. In the maritime transportation large and congested geometries can be subject to accumulation of hydrogen. A mitigation measure for areas where venting is insufficient or even impossible is the installation of catalytic recombiners. The operational behavior can be described with numerical models which are required to optimize the location and to assess the efficiency of the mitigation solution. In the present study we established an experimental procedure in the REKO-4 facility a 5.5 m³ vessel to determine the recombination rate obtained from a recombiner. Based on the experimental data an engineering correlation was developed to be used for simulations in safety assessments.
Hydrogen Energy Systems for Decarbonizing Smart Cities and Industrial Applications: A Review
Oct 2025
Publication
Hydrogen is increasingly recognized as a key energy vector for achieving deep decarbonization across urban and industrial sectors. Supporting global efforts to reduce greenhouse gas (GHG) emissions and achieve the Sustainable Development Goals (SDGs) it is essential to understand the multi-sectoral role of the hydrogen value chain spanning production storage and end-use applications with particular emphasis on smart city systems and industrial processes. Green hydrogen production technologies including alkaline water electrolysis (AWE) proton exchange membrane (PEM) electrolysis anion exchange membrane (AEM) electrolysis and solid oxide electrolysis cells (SOECs) are evaluated in terms of efficiency scalability and integration potential. Storage pathways are examined across physical storage (compressed gas cryo-compressed and liquid hydrogen) material-based storage (solid-state absorption in metal hydrides and chemical carriers such as LOHCs and ammonia) and geological storage (salt caverns depleted gas reservoirs and deep saline aquifers) highlighting their suitability for urban and industrial contexts. In the smart city domain hydrogen is analyzed as an enabler of zero-emission transportation low-carbon residential and commercial heating and renewable-integrated smart grids with long-duration storage capabilities. System-level studies demonstrate that coordinated integration of these applications can deliver higher overall energy efficiency deeper reductions in life-cycle GHG emissions and improved resilience of urban energy systems compared with sector-specific approaches. Policy frameworks safety standards and digitalization strategies are reviewed to illustrate how hydrogen infrastructure can be embedded into interconnected urban energy systems. Furthermore industrial applications focus on hydrogen’s potential to decarbonize energy-intensive processes and enable sector coupling between electricity heat and manufacturing. The environmental implications of hydrogen deployment are also considered including resource efficiency life-cycle emissions and ecosystem impacts. In contrast to reviews addressing isolated aspects of hydrogen technologies this study synthesizes technological infrastructural and policy dimensions integrating insights from over 400 studies to highlight the multifaceted role of hydrogen in sustainable urban development and industrial decarbonization and the added benefits achievable through coordinated cross-sector deployment strategies.
Numerical Simulation Study of Gas Stratification in Hydrogen-Enriched Natural Gas Pipelines
Jun 2025
Publication
Hydrogen blending in natural gas pipelines facilitates renewable energy integration and cost-effective hydrogen transport. Due to hydrogen’s lower density and higher leakage potential compared to natural gas understanding hydrogen concentration distribution is critical. This study employs ANSYS Fluent 2022 R1 with a realizable k-ε model to analyze flow dynamics of hydrogen–methane mixtures in horizontal and undulating pipelines. The effects of hydrogen blending ratios pressure (3–8 MPa) and pipeline geometry were systematically investigated. Results indicate that in horizontal pipelines hydrogen concentrations stabilize near initial values across pressure variations with minimal deviation (maximum increase: 1.6%). In undulating pipelines increased span length of elevated sections reduces maximum hydrogen concentration while maintaining proximity (maximum increase: 0.65%) to initial levels under constant pressure. Monitoring points exhibit concentration fluctuations with changing pipeline parameters though no persistent stratification occurs. However increasing the undulating height elevation difference leads to an increase in the maximum hydrogen concentration at the top of the pipeline rising from 3.74% to 9.98%. The findings provide theoretical insights for safety assessments of hydrogen–natural gas co-transport and practical guidance for pipeline design optimization.
Europe's Environment 2025 - Main Report, Europe's Environment and Climate: Knowledge for Resilience, Prosperity and Sustainability
Jan 2025
Publication
Every five years as mandated in its founding regulation the European Environment Agency (EEA) publishes a state of the environment report. Europe's environment 2025 provides decision makers at European and national levels as well as the general public with a comprehensive and cross-cutting assessment on environment climate and sustainability in Europe. Europe's environment 2025 is the 7th state of the environment report published by the EEA since 1995. Europe's environment 2025 has been prepared in close collaboration with the EEA’s European Environment Information and Observation Network (Eionet). The report draws on the Eionet’s vast expertise of leading experts and scientists in the environmental field across the EEA’s 32 member countries and six cooperating countries.
Multi-time Scaling Optimization for Electric Station Considering Uncertainties of Renewable Energy and EVs
Oct 2025
Publication
The development of new energy vehicles particularly electric vehicles (EVs) and hydrogen fuel cell vehicles (HFCVs) represents a strategic initiative to address climate change and foster sustainable development. Integrating PV with hydrogen production into hybrid electricity-hydrogen energy stations enhances land and energy efficiency but introduces scheduling challenges due to uncertainties. A multi-time scale scheduling framework which includes day-ahead and intraday optimization is established using fuzzy chance-constrained programming to minimize costs while considering the uncertainties of PV generation and charging/refueling demand. Correspondingly trapezoidal membership function and triangular membership function are used for the fuzzy quantification of day-ahead and intraday predictions of photovoltaic power generation and load demands. The system achieves 29.37% lower carbon emissions and 17.73% reduced annualized costs compared to day-ahead-only scheduling. This is enabled by real-time tracking of PV/load fluctuations and optimized electrolyzer/fuel cell operations maximizing renewable energy utilization. The proposed multi-time scale framework dynamically addresses short-term fluctuations in PV generation and load demand induced by weather variability and temporal dynamics. By characterizing PV/load uncertainties through fuzzy methods it enables formulation of chance-constrained programming models for operational risk quantification. The confidence level – reflecting decision-makers’ reliability expectations – progressively increases with refined temporal resolution balancing economic efficiency and operational reliability.
Development and Validation of an All-metal Scroll Pump for PEM Fuel Cell Hydrogen Recirculation
Oct 2025
Publication
Hydrogen recirculation is essential for maintaining fuel efficiency and durability in Proton Exchange Membrane Fuel Cell (PEMFC) systems particularly in automotive range extender applications. This study presents the design simulation and experimental validation of a dry all-metal scroll pump developed for hydrogen recirculation in a 5 kW PEMFC system. The pump operates without oil or polymer seals offering long-term compatibility with dry hydrogen. Two prototypes were fabricated: SP1 incorporating PTFE-bronze tip seals and SP2 a fully metallic seal-free design. A fully deterministic one-dimensional (1D) model was developed to predict thermodynamic performance including leakage and heat transfer effects and validated against experimental results. SP1 achieved higher flow rates due to reduced axial leakage but experienced elevated friction and temperature. In contrast SP2 provided improved thermal stability and lower friction with slightly reduced flow performance. The pump demonstrated a maximum flow rate of 50 l/min and an isentropic efficiency of 82.2 % at 2.5 bara outlet pressure. Simulated performance showed strong agreement with experimental results with deviations under 5 %. The findings highlight the critical role of thermal management and manufacturing tolerances in dry scroll pump design. The seal-free liquid-cooled scroll architecture presents a promising solution for compact oil-free hydrogen recirculation in low-power fuel cell systems.
Simulation of Hydrogen Drying via Adsorption in Offshore Hydrogen Production
Sep 2025
Publication
According to the international standard ISO 14687:2019 for hydrogen fuel quality the maximum allowable concentration of water in hydrogen for use in refueling stations and storage systems must not exceed 5 µmol/mol. Therefore an adsorption purification process following the electrolyzer is necessary. This study numerically investigates the adsorption of water and the corresponding water loading on zeolite 13X BFK based on the mass flows entering the adsorption column from three 5 MW electrolyzers coupled to a 15 MW offshore wind turbine. As the mass flow is influenced by wind speed a direct comparison between realistic wind speeds and adsorption loading is presented. The presented numerical discretization of the model also accounts for perturbations in wind speed and consequently mass flows. In addition adsorption isobars were measured for water on zeolite 13X BFK within the required pressure and temperature range. The measured data was utilized to fit parameters to the Langmuir–Freundlich isotherm.
Providing the Transport Sector in Europe with Fossil Free Energy - A Model-based Analysis under Consideration of the MENA Region
Mar 2025
Publication
For reaching the European greenhouse gas emission targets the phase-in of alternative technologies and energy carriers is crucial for all sectors. For the transport sector synthetic fuels are–next to electromobility–a promising option especially for long-distance shipping and air transport. Within this context the import of synthetic fuels from the Middle East and Northern Africa (MENA) region seems attractive due to low costs for renewable electricity in this region and low transport costs of synthetic fuels at the same time. Against this background this paper analyzes the role of the MENA region in meeting the future synthetic fuel demand in Europe using a cost-optimizing energy supply model. In this model the production storage and transport of electricity hydrogen and synthetic fuels by various technologies in both European and MENA countries in the period up to 2050 are explicitly modeled. Thereby different scenarios are analyzed to depict regional differences in investment risks: a base scenario that does not take into account regional differences in investments risks and three risk scenarios with different developments of regional investment risks. Sensitivity analyses are also carried out to derive conclusions about the robustness of results. Results show that meeting the future synthetic fuel demand in Europe to a large extent by imports from the MENA region can be an attractive option from an economic point of view. If investment risks are incorporated however lower import quotas of synthetic fuels are economically attractive for Europe: the higher generation costs are outweighed by the lower investments risks in Europe to a certain extent. Thereby investment risks outweigh other factors such as transport distance or renewable electricity generation costs in terms of exporting MENA regions and a synthetic fuel import is especially attractive from MENA countries with low investment risks. Concluding within this paper detailed export relations between MENA and EU considering investment risks were modeled for the first time. These model results should be complemented by a more in-depth analysis of the MENA countries including evaluating opportunities for local value chain development sustainability concerns (including social factors) and optimal site selection.
Hydrogen Cargo Bikes as a Data-driven Solution for Last-mile Decarbonization
Oct 2025
Publication
The growing demand for low-emission urban freight has intensified efficiency challenges in lastmile delivery especially in dense city centres. This study assesses hydrogen-powered cargo bikes as a scalable zero-emission alternative to fossil fuel vans and battery-electric cargo bikes. Using real-world logistics data from Rome we apply simulation models including Monte Carlo cost analysis Artificial Intelligence driven routing K-means station placement and fleet scaling. Results show hydrogen bikes deliver 15% more parcels daily than electric counterparts reduce refuelling detours by 31.4% and lower per-trip fuel use by 32%. They can cut up to 120 metric tons of CO2 annually per 100-bike fleet. While battery-electric cargo bikes remain optimal for short trips hydrogen bikes offer superior uptime range and rapid refuelling—ideal for highfrequency mid-distance logistics. Under supportive pricing and infrastructure hydrogen cargo bikes represent a resilient and sustainable solution for decarbonizing last-mile delivery in city areas.
Ammonia–Hydrogen Dual-Fuel Combustion: Strategies for Optimizing Performance and Reducing Emissions in Internal Combustion Engines
Jun 2025
Publication
The urgent need to mitigate climate change and reduce greenhouse gas emissions has accelerated the search for sustainable and scalable energy carriers. Among the different alternatives ammonia stands out as a promising carbon-free fuel thanks to its high energy density efficient storage and compatibility with existing infrastructure. Moreover it can be produced through sustainable green processes. However its application in internal combustion engines is limited by several challenges including low reactivity narrow flammability limits and high ignition energy. These factors can compromise combustion efficiency and contribute to increased unburned ammonia emissions. To address these limitations hydrogen has emerged as a complementary fuel in dual-fuel configurations with ammonia. Hydrogen’s high reactivity enhances flame stability ignition characteristics and combustion efficiency while reducing emissions of unburned ammonia. This review examines the current status of dual-fuel ammonia and hydrogen combustion strategies in internal combustion engines and summarizes the experimental results. It highlights the potential of dual-fuel systems to optimize engine performance and minimize emissions. It identifies key challenges knowledge gaps and future research directions to support the development and widespread adoption of ammonia–hydrogen dual-fuel technologies.
Dynamic Life cycle Assessment of Climate Change Impacts of Hydrogen Production from Energy Crops
Oct 2025
Publication
Life Cycle Assessments (LCAs) are predominantly conducted using a static approach which aggregates emissions over time without considering emissions timing. Additionally LCAs often assume biogenic carbon neutrality neglecting site-specific forest carbon fluxes and temporal trade-offs. This study applies both static and dynamic LCA and incorporates biogenic carbon to evaluate the climate change impact of hydrogen production. It focuses on gasification of eucalyptus woodchips cultivated on former marginal grasslands (BIO system) which avoids competition with land used for food production. A case study is presented in western Andalusia (Spain) with the aim to replace hydrogen produced via the conventional steam methane reforming (SMR) pathway (BAU system) at La Rabida ´ refinery. The CO2FIX model was used to simulate biogenic carbon fluxes providing insights into carbon sequestration dynamics and it was found that the inclusion of biogenic carbon flows from eucalyptus plantations dramatically reduced CO₂ equivalent emissions (176 % in the static approach and 369 % in the dynamic approach) primarily due to soil and belowground biomass carbon sequestration. The dynamic LCA showed significantly lower CO₂ emissions than the static LCA (106 % reduction) shifting emissions from − 1.79 kg CO₂/kg H₂ in the static approach to − 3.69 kg CO₂/kg H₂ in the dynamic approach. These findings highlight the need to integrate emission dynamics and biogenic carbon flows into LCA methodologies to support informed decision-making and the development of more effective environmental policies.
Techno-Economic Analysis of Onsite Sustainable Hydrogen Production via Ammonia Decomposition with Heat Recovery System
Jun 2025
Publication
Hydrogen offers a promising solution to reduce emissions in the energy sector with the growing need for decarbonisation. Despite its environmental benefits the use of hydrogen presents significant challenges in storage and transport. Many studies have focused on the different types of hydrogen production and analysed the pros and cons of each technique for different applications. This study focuses on techno-economic analysis of onsite hydrogen production through ammonia decomposition by utilising the heat from exhaust gas generated by hydrogen-fuelled gas turbines. Aspen Plus simulation software and its economic evaluation system are used. The Siemens Energy SGT-400 gas turbine’s parameters are used as the baseline for the hydrogen gas turbine in this study together with the economic parameters of the capital expenditure (CAPEX) and operating expenditure (OPEX) are considered. The levelised cost of hydrogen (LCOH) is found to be 5.64 USD/kg of hydrogen which is 10.6% lower than that of the conventional method where a furnace is used to increase the temperature of ammonia. A major contribution of the LCOH comes from the ammonia feed cost up to 99%. The price of ammonia is found to be the most sensitive parameter of the contribution to LCOH. The findings of this study show that the use of ammonia decomposition via heat recovery for onsite hydrogen production with ammonic recycling is economically viable and highlight the critical need to further reduce the prices of green ammonia and blue ammonia in the future.
Techno-Economic Evaluation of a Floating Photovoltaic-Powered Green Hydrogen for FCEV for Different Köppen Climates
Sep 2025
Publication
The escalating global demand for electricity coupled with environmental concerns and economic considerations has driven the exploration of alternative energy sources creating competition for land with other sectors. A comprehensive analysis of a 10 MW floating photovoltaic (FPV) system deployed across different Köppen climate zones along with techno-economic analysis involves evaluating technical efficiency and economic viability. Technical parameters are assessed using PVsyst simulation and HOMER Pro. While economic analysis considers return on investment net present value internal rate of return and payback period. Results indicate that temperate and dry zones exhibit significant electricity generation potential from an FPV. The study outlines the payback period with the lowest being 5.7 years emphasizing the system’s environmental benefits by reducing water loss in the form of evaporation. The system is further integrated with hydrogen generation while estimating the number of cars that can be refueled at each location with the highest amount of hydrogen production being 292817 kg/year refueling more than 100 cars per day. This leads to an LCOH of GBP 2.84/kg for 20 years. Additionally the comparison across different Koppen climate zones suggests that even with the high soiling losses dry climate has substantial potential; producing up to 18829587 kWh/year of electricity and 292817 kg/year of hydrogen. However factors such as high inflation can reduce the return on investment to as low as 13.8%. The integration of FPV with hydropower plants is suggested for enhanced power generation reaffirming its potential to contribute to a sustainable energy future while addressing the UN’s SDG7 SDG9 SDG13 and SDG15.
Optimizing Storage Parameters for Underground Hydrogen Storage in Aquifers: Cushion Gas Selection, Well Pattern Design, and Purity Control
Oct 2025
Publication
Underground hydrogen storage in aquifers is a promising solution to address the imbalance between energy supply and demand yet its practical implementation requires optimized strategies to ensure high efficiency and economic viability. To improve the storage and production efficiency of hydrogen it is essential to select the appropriate cushion gas and to study the influence of reservoir and process parameters. Based on the conceptual model of aquifer with single-well injection and production three potential cushion gas (carbon dioxide nitrogen and methane) were studied and the changes in hydrogen recovery for each cushion gas were compared. The effects of temperature initial pressure porosity horizontal permeability vertical to horizontal permeability ratio permeability gradient hydrogen injection rate and hydrogen production rate on the purity of recovered hydrogen were investigated. Additionally the impact of different well pattern on the purity of recovered hydrogen was studied. The results indicate that methane is the most effective cushion gas for improving hydrogen recovery in UHS. Different well patterns have significant impacts on the purity of recovered hydrogen. The mole fractions of methane in the produced gas for the single-well line-drive pattern and five-spot pattern were 16.8% 5% and 3.05% respectively. Considering the economic constraints the five-spot well pattern is most suitable for hydrogen storage in aquifers. Reverse rhythm reservoirs with smaller permeability differences should be chosen to achieve relatively high hydrogen recovery and purity of recovered hydrogen. An increase in hydrogen production rate leads to a significant decrease in the purity of the recovered hydrogen. In contrast hydrogen injection rate has only a minor effect. These findings provide actionable guidance for the selection of cushion gas site selection and operational design of aquifer-based hydrogen storage systems contributing to the large-scale seasonal storage of hydrogen and the balance of energy supply and demand.
Environmental and Economic Assessment of Large-scale Hydrogen Supply Chains across Europe: LOHC vs Other Hydrogen Technologies
Oct 2025
Publication
I. Rey,
V.L. Barrio and
I. Agirre
The transition to decarbonized energy systems positions hydrogen as a critical vector for achieving climate neutrality yet its large-scale transportation and storage remain key challenges. This study presents a comprehensive life cycle assessment (LCA) and economic analysis of large-scale H2 supply chains evaluating the liquid organic hydrogen carrier (LOHC) system based on benzyltoluene/perhydro-benzyltoluene (H0-BT/H12-BT) against conventional technologies: compressed gaseous hydrogen (CGH2) liquid hydrogen (LH2) and liquid ammonia (LNH3). The analysis includes multiple H2 transportation scenarios across Europe considering the steps: conditioning sea transportation post-processing and land distribution by truck or pipeline. Environmentally LOHC currently faces higher environmental impacts than CGH2 driven by energy-intensive dehydrogenation process. Truck-based distribution further amplifies impacts particularly over long distances while pipeline-based distribution significantly reduces the environmental burdens where infrastructure exists. Sensitivity analysis reveals that using H2 for dehydrogenation heat lowers process-level impacts but increases overall supply chain impacts questioning its net environmental benefit. Economically LOHC remains competitive despite high dehydrogenation costs benefiting from low sea transportation expenses compatibility with existing fossil fuel infrastructure and potential for future CAPEX and OPEX improvements. While CGH2 outperforms LH2 and LNH3 avoiding energy-intensive liquefaction and cracking its storage requirements add considerable costs. For land distribution LOHC trucks are optimal at lower capacities whereas repurposed natural gas pipelines favour CGH2 at higher scale reducing costs by up to 84 %. Despite current trade-offs the scalability flexibility and synergies with existing infrastructure position LOHC as a promising solution for long-distance H2 transport contingent on technological maturation to mitigate dehydrogenation impacts.
Innovative Aircraft Heat Exchanger Integration for Hydrogen-electric Propulsion
Sep 2025
Publication
Propulsion systems in aircraft using reciprocating engines often face the challenge of managing thermal loads effectively. This problem is similar to the utilisation of polymer electrolyte membrane fuel cell systems which despite their high efficiency emit a high proportion of heat when converting chemical energy into electrical energy. Transfer of the rejected heat to the air is efficiently performed by heat exchangers. Since convective heat transfer is physically linked to fluid friction at the heat exchanger walls a pressure loss occurs. In a high-speed flow regime of the aircraft during cruise the integration of heat exchangers combined with a fan stage inside a nacelle (thus forming an impeller configuration) represents a promising approach for the dual benefit of dissipating excess heat and harnessing it for additional thrust generation through the ram jet effect. Striving for enhanced thrust performance of hydrogen electric commercial aircraft this paper presents the results of a parameter study based on a 1D-modelling approach. The focus is placed on the influence of design and operating parameters (ambient conditions fan pressure ratio diffusion ratio airside temperature difference) on performance and sizing of the proposed propulsion system. It is shown that the proposed system performs best at an altitude of 11 km and with increasing freestream Mach number. Furthermore the main challenges related to the combination of a thrust generation system with a heat exchanger in terms of sizing in particularly the required heat exchanger dimensions under different operating conditions are discussed.
Development of the Hydrogen Market and Local Green Hydrogen Offtake in Africa
Jun 2025
Publication
Creating a hydrogen market in Africa is a great opportunity to assist in the promotion of sustainable energy solutions and economic growth. This article addresses the legislation and regulations that need to be developed to facilitate growth in the hydrogen market and allow local green hydrogen offtake across the continent. By reviewing current policy and strategy within particular African countries and best practices globally from key hydrogen economies the review establishes compelling issues challenges and opportunities unique to Africa. The study identifies the immense potential in Africa for renewable energy and in particular for solar and wind as the foundation for the production of green hydrogen. It examines how effective policy frameworks can establish a vibrant hydrogen economy by bridging infrastructural gaps cost hurdles and regulatory barriers. The paper also addresses how local offtake contracts for green hydrogen can be used to stimulate economic diversification energy security and sustainable development. Policy advice is provided to assist African authorities and stakeholders in the deployment of enabling regulatory frameworks and the mobilization of funds. The paper contributes to global hydrogen energy discussions by introducing Africa as an eligible stakeholder in the emerging hydrogen economy and outlining prospects for its inclusion into regional and global energy supply chains.
Opportunities and Challenges of Latent Thermal Energy Usage in the Hydrogen Economy
Aug 2025
Publication
Hydrogen plays a key role in decarbonising hard-to-abate sectors like aviation steel and shipping. However producing pure hydrogen requires significant energy to break chemical bonds from its sources such as gas and water. Ideally the energy used for this process should match the energy output from hydrogen but in reality energy losses occur at various stages of the hydrogen economy—production packaging delivery and use. This results in needing more energy to operate the hydrogen economy than it can ultimately provide. To address this passive power sources like latent thermal energy storage systems can help reduce costs and improve efficiency. These systems can enable passive cooling or electricity generation from waste heat cutting down on the extra energy needed for compression liquefaction and distribution. This study explores integrating latent thermal energy storage into all stages of the hydrogen economy offering a cost and sizing approach for such systems. The integration could reduce costs close the waste-heat recycling loop and support green hydrogen production for achieving NetZero by 2050.
Numerical Simulation Study on Hydrogen Leakage and Explosion of Hydrogen Fuel Cell Buses
Aug 2025
Publication
This study explores the safety problems of hydrogen leakage and explosion in hydrogen fuel cell buses through Computational Fluid Dynamics simulations. The research investigates the diffusion behavior of hydrogen in the passenger cabin depending on the leakage position and flow rates identifying a stratified constant-concentration layer formed at the top of the cabin. Leakage near the rear wall of the vehicle provided the highest hydrogen concentration while at higher flow rates the diffusive process accelerated the spreading of flammable hydrogen concentrations. Hydrogen ignition simulations showed a fast internal pressure increase and secondary explosions outside the vehicle. Thermal hazards in the cases were higher than overpressure. The research’s additional analysis of ignition timing and source location shows that overpressure peaked initially with delayed ignition but declined afterward while rear-ignited flames exhibited the farthest high-temperature hazard range at 10.88 m. These findings are fundamental for giving insight into hydrogen behavior in confined spaces and thus guiding risk assessment and emergency response planning for the development of safety protocols in hydrogen fuel cell buses contributing to the safer implementation of hydrogen energy in public transportation.
Fractal Fuzzy‑Based Multi‑criteria Assessment of Sustainability in Rare Earth Use for Hydrogen Storage
Aug 2025
Publication
The use of rare earth elements in hydrogen storage processes offers significant advantages in terms of increasing technological efficiency and ensuring system security. However this process also creates some serious problems in terms of environmental and economic sustainability. It is necessary to determine the most critical indicators affecting the sustainable use of these elements. Studies on this subject in the literature are quite limited and this may lead to wrong investment decisions. The main purpose of this study is to determine the most important indicators to increase the sustainable use of rare earth elements in hydrogen storage processes. An original decision-making model in which Siamese network logarithmic percentage-change driven objective weighting (LOPCOW) fractal fuzzy numbers and weighted influence super matrix with precedence (WISP) approaches are integrated in the study. This study provides an original contribution to the literature by identifying the most critical indicators affecting the sustainable use of rare earths in hydrogen storage processes by presenting an innovative model. Fractal structures such as Koch Snowflake Cantor Dust and Sierpinski Triangle can model complex uncertainties more successfully. Fractal structures are particularly effective in modeling linguistic fuzziness because their recursive nature closely mirrors the layered and imprecise way humans often express subjective judgments. Unlike linear fuzzy sets fractals can capture the patterns of ambiguity found in expert evaluations. Hydrogen storage capacity and government supports are determined as the most vital criteria affecting sustainability in rare earth use.
Interactions Between Gas Hydrate and Hydrogen in Nature: Laboratory Evidence of Hydrogen Incorporation
Oct 2025
Publication
Natural hydrogen is generated via serpentinization radiolysis and organic metagenesis in geological settings. After expulsion from the source and along its upward migration path the free gas may encounter hydratebearing sediments. To simulate this natural scenario CH4 hydrate and CH4 + C3H8 hydrate were synthesized at 5.0 MPa and exposed to a hydrogen-containing gas mixture. In-situ Raman spectroscopic measurements demonstrated the incorporation of H2 molecules into the hydrate phase even at a partial pressure of 0.5 MPa. Exsitu Raman spectroscopic characterization of hydrates formed from a CH4 + H2 gas mixture at 5.0 MPa confirmed the H2 inclusion within the large cavities of structure I. The results show that the interactions between H2 and the natural gas hydrate phase range from the incorporation of H2 molecules into the hydrate phase to the rapid dissociation of the gas hydrate depending on thermodynamic conditions and H2 concentration in the coexisting gas phase.
Hydrogen Production from Pyrolysis of Biomass Components
Sep 2025
Publication
Hydrogen energy is key for the global green energy transition and biomass thermochemical has become an important option for green hydrogen production due to its carbon neutrality advantage. Pyrolysis is the initial step of thermochemical technologies. A systematic analysis of the mechanism of H2 production from biomass pyrolysis is significant for the subsequent optimal design of efficient biomass thermochemical H2 production technologies. Biomass is mainly composed of cellulose hemicellulose and lignin and differences in their physicochemical properties and structures directly affect the pyrolysis hydrogen production process. In this study thermogravimetry-mass spectrometry-Fourier transform infrared spectroscopy (TG-MS-FTIR) was employed and fixed-bed pyrolysis experiments were conducted to systematically investigate the pyrolysis of biomass component with focusing on hydrogen production. According to the results of TG-MS-FTIR experiments hemicellulose produced hydrogen through the breaking of C-H bonds in short chains and acetyl groups as well as secondary cracking of volatiles and condensation of aromatic rings at high temperatures. Cellulose produced hydrogen through the breaking of C-H bonds in volatiles generated from sugar ring cleavage along with char gasification and condensation of aromatic rings at high temperatures. Lignin produced hydrogen through ether bond cleavage breaking of methoxy groups as well as cleavage of phenylpropane side chains and condensation of aromatic rings at high temperatures. Results from fixed-bed pyrolysis experiments further showed that hemicellulose exhibited the strongest hydrogen production capacity with the maximum H2 production efficiency of 6.09 mmol/g the maximum H2 selectivity of 17.79% and the maximum H2 effectiveness of 59% at 800°C.
Narratives and Counter-narratives in Sustainability Transitions: A Study on the Port of Rotterdam from a Multi-level Perspectives
Sep 2025
Publication
Infrastructure projects can act as niches for innovation development contribute to strategic goals of network owners and drive broader systemic transitions. However limited research has examined how sustainability transitions are shaped through narratives and counternarratives around infrastructure projects. Using a case study of the port of Rotterdam we analyze how three embedded projects - Maasvlakte 2 RDM Campus and the Hydrogen Pipeline - reflected and shaped evolving narratives and counter-narratives over a 20-year sustainability transition. Grounded in the Multi-Level Perspective (MLP) the study demonstrates how an infrastructure owner like the Port of Rotterdam Authority (PoRA) strategically mobilized narrative framing to reshape existing regimes over time. The study contributes to the debate on project management and transition studies by highlighting how infrastructure project owners respond to transition-related tensions by shaping defending and adapting project narratives over time thereby influencing sustainability trajectories.
Comparative Review of Natural Gas Vehicles During the Energy Transition
Jul 2025
Publication
The global climate crisis necessitates the urgent implementation of sustainable practices and carbon emission reduction strategies across all sectors. Transport as a major contributor to greenhouse gas emissions requires transitional technologies to bridge the gap between fossil fuel dependency and renewable energy systems. Natural gas recognised as the cleanest fossil-derived fuel with approximately half the CO2 emissions of coal and 75% of oil presents a potential transitional solution through Natural Gas Vehicles (NGVs). This manuscript presents several distinctive contributions that advance the understanding of Natural Gas Vehicles within the contemporary energy transition landscape while synthesising updated emission performance data. Specifically the feasibility and sustainability of NGVs are investigated within the energy transition framework by systematically incorporating recent technological developments and environmental economic and infrastructure considerations in comparison to conventional vehicles (diesel and petrol) and unconventional alternatives (electric and hydrogen-fuelled). The analysis reveals that NGVs can reduce CO2 emissions by approximately 25% compared to petrol vehicles on a well-to-wheel basis with significant reductions in NOx and particulate matter. However these environmental benefits depend heavily on the source and type of natural gas used (CNG or LNG) while economic viability hinges largely on governmental policies and infrastructure development. The findings suggest that NGVs can serve as an effective transitional technology in the transport sector’s sustainability pathway particularly in regions with established natural gas infrastructure but require supportive policy frameworks to overcome implementation barriers.
Analysis of Specific Failure Conditions in Electrified Propulsion Systems using Cryogenic Hydrogen as a Primary Energy Carrier
Aug 2025
Publication
In order to minimize emissions of the aerospace sector and thus its impact on the climate several novel concepts of propulsion systems for aircraft are being developed. Many of these concepts do not use an energy source based on the combustion of hydrocarbons but other means of energy generation and storage like hydrogen fuel cells and corresponding hydrogen storage systems. The use of hydrogen as a primary energy carrier in aircraft poses novel and different hazards when compared to conventional propulsion and fuel storage systems. The study described in the present paper identifies analyzes and evaluates failure conditions and corresponding hazards that are associated with the electrified propulsion systems. Mitigation strategies to prevent failures to occur or decrease their severity are recommended. The effects of the assessed failures on aircraft crew and occupants are classified as catastrophic hazardous or major as defined in the according Certification Specifications. Failure Conditions occurring at the aircraft system and subsystem levels are considered and their effect on the aircraft and propulsion system is assessed. The hazards identified mostly emerge due to the properties of the gaseous or liquid hydrogen. They include the flammability of gaseous hydrogen and the very low temperatures of cryogenic liquid hydrogen as well as the installation of high voltage power infrastructure and high capacity heat exchangers.
Machine Learning Models for the Prediction of Hydrogen Solubility in Aqueous Systems
Aug 2025
Publication
Hydrogen storage is integral to reducing CO2 emissions particularly in the oil and gas industry. However a primary challenge involves the solubility of hydrogen in subsurface environments particularly saline aquifers. The dissolution of hydrogen in saline water can impact the efficiency and stability of storage reservoirs necessitating detailed studies of fluid dynamics in such settings. Beyond its role as a clean energy carrier and precursor for synthetic fuels and chemicals understanding hydrogen’s solubility in subsurface conditions can significantly enhance storage technologies. When hydrogen solubility is high it can reduce reservoir pressure and alter the chemical composition of the storage medium undermining process efficiency. Machine learning techniques have gained prominence in predicting physical and chemical properties across various systems. One of the most complex challenges in hydrogen storage is predicting its solubility in saline water influenced by factors such as pressure temperature and salinity. Machine learning models offer substantial promise in improving hydrogen storage by identifying intricate nonlinear relationships among these parameters. This study uses machine learning algorithms to predict hydrogen solubility in saline aquifers employing techniques such as Bayesian inference linear regression random forest artificial neural networks (ANN) support vector machines (SVM) and least squares boosting (LSBoost). Trained on experimental data and numerical simulations these models provide precise predictions of hydrogen solubility which is strongly influenced by pressure temperature and salinity under a wide range of thermodynamic conditions. Among these methods RF outperformed the others achieving an R2 of 0.9810 for test data and 0.9915 for training data with RMSE values of 0.048 and 0.032 respectively. These findings emphasize the potential of machine learning to significantly optimize hydrogen storage and reservoir management in saline aquifers.
Offshore Renewable Hydrogen Potential in Australia: A Techno-economic and Legal Review
Jun 2025
Publication
Hydrogen is increasingly recognised as a potential critical energy carrier in decarbonising global energy systems. Australia is positioning itself as a potential leader in offshore renewable hydrogen production by leveraging existing liquified natural gas export infrastructure activating its abundant renewable energy resources and harnessing its extensive offshore marine acreage. Despite this there is limited research on the techno-economic and regulatory pathways for offshore hydrogen development in Australia as an enabler of its net zero manufacturing and export ambitions. This study offers a multidisciplinary assessment and review of Australia’s offshore renewable hydrogen potential. It aims to examine the technical legal and economic challenges and opportunities to enable and adapt the existing Australian offshore electricity regulatory regime and enable policy to facilitate future renewable offshore hydrogen licensing and production. Overall the findings provide practical insights for advancing Australia’s offshore hydrogen transition including technical innovations needed to scale offshore wind development. The study demonstrates how a specific offshore hydrogen licensing framework could reduce legal uncertainties to create economies of scale and reduce hydrogen investment risk to unlock the full potential of developing offshore renewable hydrogen projects.
A real Assessment in the Design of a Try-Out Grid-Tied Solar PV-Green Hydrogen-Battery Storage Microgrid System for Industrial Application in South Africa
Sep 2025
Publication
The carbon emission reduction mission requires a multifaceted approach in which green hydrogen is expected to play a key role. The accelerated adoption of green hydrogen technologies is vital to this journey towards carbon neutrality by 2050. However the energy transition involving green hydrogen requires a data-driven approach to ensure that the benefits are realised. The introduction of testing sites for green hydrogen technologies will be crucial in enabling the performance testing of various components within the green hydrogen value chain. This study involves an areal assessment of a selected test site for the installation of a grid-tied solar PV-green hydrogen-battery storage microgrid system at a factory facility in South Africa. The evaluation includes a site energy audit to determine the consumption profile and an analysis of the location’s weather pattern to assess its impact on the envisaged microgrid. Lastly a design of the microgrid is conceptualised. A 39 kW photovoltaic system powers the microgrid which comprises a 22 kWh battery storage system 10 kW of electrolyser capacity an 8 kW fuel cell and an 800 L hydrogen storage capacity between 30 and 40 bars.
Polymers and Composites for Hydrogen Economy: A Perspective
Oct 2025
Publication
This paper provides authors’ perspective on the current advances and challenges in utilising polymers and composites in hydrogen economy. It has originated from ‘Polymers and Composites for Hydrogen Economy’ symposium organised in March 2025 at the University of Warwick. This paper presents views from the event and thus provides a perspective from academia and industry on the ongoing advances and challenges for those materials in hydrogen applications.
Green Hydrogen Production Study in Existing Oil Refinery with Evaluating Technical, Economic, and Environmental Outcomes
Oct 2025
Publication
Green hydrogen offers a sustainable alternative source of fossil fuels to compensate for the increasing energy demand. This study addresses the increasing energy demand and the need for sustainable alternatives to fossil fuels by examining the production of green hydrogen in an existing Egyptian oil refinery. The primary objective is to evaluate the technical economic and environmental outcomes of integrating green hydrogen to increase the refinery’s hydro processing capacity. The methodology involves the use of water electrolysis powered exclusively by renewable electricity from a 60 MW solar installation with a panel surface area of 660000 m². A simulation model of alkaline electrolyzer skids was developed to assess the production of an additional 1260 kg/h of hydrogen representing a 15% increase over the existing Steam Methane Reforming (SMR) capacity. The environmental impact was quantified by calculating the reduction in CO₂ and equivalent emissions while an economic forecasting analysis was conducted to project the production costs of green versus grey hydrogen. The main results indicate that the integration is technically feasible and environmentally beneficial with a significant reduction in the refinery’s carbon footprint. Economically the study projects that by 2028 the production cost of green hydrogen will fall to 1.56 USD/kg H₂ becoming more cost-effective than grey hydrogen at 1.65 USD/kg H₂ largely due to the influence of carbon taxes and credits. This study underscores the transformative potential of green hydrogen in decarbonizing industrial processes offering a viable pathway for refineries to contribute to global climate change mitigation efforts.
Solar Enabled Pathway to Large-scale Green Hydrogen Production and Storage: A Framework for Oman's Advancing Renewable Energy Goals
Aug 2025
Publication
The utilisation of renewable energy sources for hydrogen production is increasingly vital for ensuring the long-term sustainability of global energy systems. Currently the Sultanate of Oman is actively integrating renewable energy particularly through the deployment of solar photovoltaic (PV) systems as part of its ambitious targets for the forthcoming decades. Also Oman has target to achieve 1 million tonnes of green-H2 production annually. Leveraging Oman's abundant solar resources to produce green hydrogen and promote the clean transportation industry could significantly boost the country's sustainable energy sector. This paper outlines a standalone bifacial solar-powered system designed for large-scale green hydrogen (H2) production and storage to operate both a hydrogen refuelling station and an electric vehicle charging station in Sohar Oman. Using HOMER software three scenarios: PV/Hydrogen/Battery PV/Hydrogen PV/Battery systems were compared from a techno-economic perspective. Also the night-time operation (Battery/Hydrogen) was investigated. Varying cost of electricity were obtained depending on the system from $3.91/kWh to $0.0000565kWh while the bifacial PV/Hydrogen/Battery system emerged as the most efficient option boasting a unit cost of electricity (COE) of $3.91/kWh and a levelized cost of hydrogen (LCOH) value of $6.63/kg with net present cost 199M. This system aligns well with Oman's 2030 objectives with the capacity to generate 1 million tonnes of green-H2 annually. Additionally the findings show that the surplus electricity from the system could potentially cover over 30% of Oman's total energy consumption with zero harmful emissions. The implementation of this system promises to enhance Oman's economic and transportation industries by promoting the adoption of electric and fuel cell vehicles while reducing reliance on traditional energy sources.
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