Publications
Modeling Hydrogen-Assisted Combustion of Liquid Fuels in Compression-Ignition Engines Using a Double-Wiebe Function
Oct 2025
Publication
This article discusses the potential of using the double-Wiebe function to model combustion in a compression-ignition engine fueled by diesel fuel or its substitutes such as hydrotreated vegetable oil (HVO) and rapeseed methyl ester (RME) and hydrogen injected into the engine intake manifold. The hydrogen amount ranged from 0 to 35% of the total energy content of the fuels burned. It was found that co-combustion of liquid fuel with hydrogen is characterized by two distinct combustion phases: premixed and diffusion combustion. The premixed phase occurring just after ignition is characterized by a rapid combustion rate which increases with an increase in hydrogen injected. The novelty in this work is the modified formula for a double-Wiebe function and the proposed parameters of this function depending on the amount of hydrogen added for co-combustion with liquid fuel. To model this combustion process the modified double-Wiebe function was proposed which can model two phases with different combustion rates. For this purpose a normalized HRR was calculated and based on this curve coefficients for the double-Wiebe function were proposed. Satisfactory consistency with the experiment was achieved at a level determined by the coefficient of determination (R-squared) of above 0.98. It was concluded that the presented double-Wiebe function can be used to model combustion in 0-D and 1-D models for fuels: RME and HVO with hydrogen addition.
Numerical Study of Liquid Hydrogen Internal Flow in Liquid Hydrogen Storage Tank
Oct 2025
Publication
As a key zero-carbon energy carrier the accurate measurement of liquid hydrogen flow in its industrial chain is crucial. However the ultra-low temperature ultra-low density and other properties of liquid hydrogen can introduce calibration errors. To enhance the measurement accuracy and reliability of liquid hydrogen flow this study investigates the heat and mass transfer within a 1 m3 non-vented storage tank during the calibration process of a liquid hydrogen flow standard device that integrates combined dynamic and static gravimetric methods. The vertical tank configuration was selected to minimize the vapor–liquid interface area thereby suppressing boil-off gas generation and enhancing pressure stability which is critical for measurement accuracy. Building upon research on cryogenic flow standard devices as well as tank experiments and simulations this study employs computational fluid dynamics (CFD) with Fluent 2024 software to numerically simulate liquid hydrogen flow within a non-vented tank. The thermophysical properties of hydrogen crucial for the accuracy of the phase-change simulation were implemented using high-fidelity real-fluid data from the NIST Standard Reference Database as the ideal gas law is invalid under the cryogenic conditions studied. Specifically the Lee model was enhanced via User-Defined Functions (UDFs) to accurately simulate the key phasechange processes involving coupled flash evaporation and condensation during liquid hydrogen refueling. The simulation results demonstrated good agreement with NASA experimental data. This study systematically examined the effects of key parameters including inlet flow conditions and inlet liquid temperature on the flow characteristics of liquid hydrogen entering the tank and the subsequent heat and mass transfer behavior within the tank. The results indicated that an increase in mass flow rate elevates tank pressure and reduces filling time. Conversely a decrease in the inlet liquid hydrogen temperature significantly intensifies heat and mass transfer during the initial refueling stage. These findings provide important theoretical support for a deeper understanding of the complex physical mechanisms of liquid hydrogen flow calibration in non-vented tanks and for optimizing calibration accuracy.
Insights from Swirl Number and Ambient Pressure Variations with a Hydrogen/Ammonia Swirl Stabilized Diffusion Flame
Oct 2025
Publication
Contemporary research into decarbonized fuels such as H2/NH3 has highlighted complex challenges with applied combustion with marked changes in thermochemical properties leading to significant issues such as limited operational range flashback and instability particularly when attempts are made to optimize emissions production in conventional lean-premixed systems. Non-premixed configurations may address some of these issues but often lead to elevated NOx production particularly when ammonia is retained in the fuel mixture. Optimized fuel injection and blending strategies are essential to mitigate these challenges. This study investigates the application of a 75 %/25 %mol H2/NH3 blend in a swirl-stabilized combustor operated at elevated conditions of inlet temperature (500 K) and ambient pressure (0.11–0.6 MPa). A complex nonmonotonic relationship between swirl number and increasing ambient combustor pressure is demonstrated highlighting the intricate interplay between swirling flow structures and reaction kinetics which remains poorly understood. At medium swirl (SN = 0.8) an increase in pressure initially reduces NO emissions diminishing past ~0.3 MPa with an opposing trend evident for high swirl (SN = 2.0) as NO emissions fall rapidly when combustor pressure approaches 0.6 MPa. High-fidelity numerical modeling is presented to elucidate these interactions in detail. Numerical data generated using Detached Eddy Simulations (DES) were validated against experimental results to demonstrate a change in flame anchoring on the axial shear layer and marked change in recirculated flow structure successfully capturing the features of higher swirl number flows. Favorable comparisons are made with optical data and a reduction in NO emissions with increasing pressure is demonstrated to replicate changes to the swirling flame chemical kinetics. Findings provide valuable insights into the combustion behavior of hydrogen-rich ammonia flames contributing to the development of cleaner combustion technologies.
Hybrid Renewable Energy Systems for Off-Grid Electrification: A Comprehensive Review of Storage Technologies, Metaheuristic Optimization Approaches and Key Challenges
Nov 2025
Publication
Hybrid Renewable Energy Systems (HRESs) are a practical solution for providing reliable low-carbon electricity to off-grid and remote communities. This review examines the role of energy storage within HRESs by systematically comparing electrochemical mechanical thermal and hydrogen-based technologies in terms of technical performance lifecycle cost operational constraints and environmental impact. We synthesize findings from implemented off-grid projects across multiple countries to evaluate real-world performance metrics including renewable fraction expected energy not supplied (EENS) lifecycle cost and operation & maintenance burdens. Special attention is given to the emerging role of hydrogen as a long-term and cross-sector energy carrier addressing its technical regulatory and financial barriers to widespread deployment. In addition the paper reviews real-world implementations of off-grid HRES in various countries summarizing practical outcomes and lessons for system design and policy. The discussion also includes recent advances in metaheuristic optimization algorithms which have improved planning efficiency system reliability and cost-effectiveness. By combining technological operational and policy perspectives this review identifies current challenges and future directions for developing sustainable resilient and economically viable HRES that can accelerate equitable electrification in remote areas. Finally the review outlines key limitations and future directions calling for more systematic quantitative studies long-term field validation of emerging technologies and the development of intelligent Artificial Intelligence (AI)-driven energy management systems within broader socio-techno-economic frameworks. Overall this work offers concise insights to guide researchers and policymakers in advancing the practical deployment of sustainable and resilient HRES.
The Energy Transition in Colombia: Government Projections and Realistic Scenarios
Nov 2025
Publication
Energy transition is crucial for climate change mitigation and Sustainable Development Goals (SDGs) and has been a key government focus in Colombia since 2022 which must carefully consider its energy roadmap. This study evaluates three potential scenarios for achieving nearly 100% renewable energy by 2035: replacing fossil fuels with biofuels using hydrogen for transport and industrial heat and relying entirely on renewable electricity. This paper discusses these scenarios’ technical economic and social challenges including the need for substantial investments in renewable energy technologies and energy storage systems to replace fossil fuels. The discussion highlights the importance of balancing energy security environmental concerns and economic growth while addressing social priorities such as poverty eradication and access to healthcare and education. The results show that while the Colombian government’s energy transition goals are commendable a rapid energy transition requires 4 to 8 times the government’s projected 34 billion USD investment making it economically unfeasible. Notably focusing on wind photovoltaic and green hydrogen systems which need storage is too costly. Furthermore replacing fossil fuels in transport is impractical though increasing biofuel production could partially substitute fossil fuels. Less energy-intensive alternatives like trains and waterway transport should be considered to reduce energy demand and carbon footprint.
Enhancing Regional Integrated Energy Systems Through Seasonal Hydrogen Storage: Insights from a Stackelberg Game Model
Nov 2025
Publication
This study enhances regional integrated energy systems by proposing a Stackelberg planning–operation model with seasonal hydrogen storage addressing source–network separation. An equilibrium algorithm is developed that integrates a competitive search routine with mixed-integer optimization. In the price–energy game framework the hydrogen storage operator is designated as the leader while energy producers load aggregators and storage providers act as followers facilitating a distributed collaborative optimization strategy within the Stackelberg game. Using an industrial park in northern China as a case study the findings reveal that the operator’s initiative results in a revenue increase of 38.60% while producer profits rise by 6.10% and storage-provider profits surge by 108.75%. Additionally renewable accommodation reaches 93.86% reflecting an absolute improvement of 20.60 percentage points. Total net energy imbalance decreases by 55.70% and heat-loss load is reduced by 31.74%. Overall the proposed approach effectively achieves cross-seasonal energy balancing and multi-party gains providing an engineering-oriented reference for addressing energy imbalances in regional integrated energy systems.
Hydrogen Blending as a Transitional Solution for Decarbonizing the Jordanian Electricity Generation Sector
Nov 2025
Publication
While renewable energy deployment has accelerated in recent years fossil fuels continue to play a dominant role in electricity generation worldwide. This necessitates the development of transitional strategies to mitigate greenhouse gas emissions from this sector while gradually reducing reliance on fossil fuels. This study investigates the potential of blending green hydrogen with natural gas as a transitional solution to decarbonize Jordan’s electricity sector. The research presents a comprehensive techno-economic and environmental assessment evaluating the compatibility of the Arab Gas Pipeline and major power plants with hydrogen–natural gas mixtures considering blending limits energy needs environmental impacts and economic feasibility under Jordan’s 2030 energy scenario. The findings reveal that hydrogen blending between 5 and 20 percent can be technically achieved without major infrastructure modifications. The total hydrogen demand is estimated at 24.75 million kilograms per year with a reduction of 152.7 thousand tons of carbon dioxide per annum. This requires 296980 cubic meters of water per year equivalent to only 0.1 percent of the National Water Carrier’s capacity indicating a negligible impact on national water resources. Although technically and environmentally feasible the project remains economically constrained requiring a carbon price of $1835.8 per ton of carbon dioxide for economic neutrality.
Hydrothermal Treatment of Kitchen Waste as a Strategy for Dark Fermentation Biohydrogen Production
Nov 2025
Publication
This study presents an innovative approach to the production of hydrogen from liquids following hydrothermal treatment of biowaste offering a potential solution for renewable energy generation and waste management. By combining biological and hydrothermal processes the efficiency of H2 production can be significantly improved contributing to a reduced carbon footprint and lower reliance on fossil fuels. The inoculum used was fermented sludge from a wastewater treatment plant which had been thermally pretreated to enhance microbial activity towards hydrogen production. Kitchen waste consisting mainly of plant-derived materials (vegetable matter) was used as a substrate. The process was conducted in batch 1-L bioreactors. The results showed that higher pretreatment temperatures (up to 180 ◦C) increased the hydrolysis of compounds and enhanced H2 production. However temperatures above 180 ◦C resulted in the formation of toxic compounds such as catechol and hydroquinone which inhibited H2 production. The highest hydrogen production was achieved at 180 ◦C (approximately 66 mL H2/gTVSKW). The standard Gompertz model was applied to describe the process kinetics and demonstrated an excellent fit with the experimental data (R2 = 0.99) confirming the model’s suitability for optimizing H2 production. This work highlights the potential of combining hydrothermal and biological processes to contribute to the development of sustainable energy systems within the circular economy.
Green Hydrogen Market and Green Cryptocurrencies: A Dynamic Correlation Analysis
Nov 2025
Publication
The urgent need to mitigate climate change has elevated green hydrogen as a sustainable alternative to fossil fuels while green cryptocurrencies have emerged to address the environmental concerns of traditional cryptocurrency mining. This study investigates the dynamic correlation between the green hydrogen market and selected green cryptocurrencies (Cardano Stellar Hedera Algorand and Chia) from July 2021 to April 2024 utilizing the Dynamic Conditional Correlation GARCH (DCC-GARCH) model with robustness checks using EGARCH and GJR-GARCH specifications. Our findings reveal significant correlations with peaks reaching up to 50% in 2022 a period likely influenced by the Russia-Ukraine conflict. Subsequently a decline in these correlations was observed in 2023. These results underscore the interconnectedness of sustainability-driven markets suggesting potential contagion effects during periods of global instability. The high persistence of correlation shocks (α + β values approaching unity) indicates that correlation regimes tend to be long- lasting with important implications for portfolio diversification and risk management strategies. Robustness checks using EGARCH and GJR-GARCH specifications confirmed qualitatively similar patterns reinforcing the validity of our findings into the evolving landscape of green finance and energy
Application of Machine Learning and Data Augmentation Algorithms in the Discovery of Metal Hydrides for Hydrogen Storage
Nov 2025
Publication
The development of efficient and sustainable hydrogen storage materials is a key challenge for realizing hydrogen as a clean and flexible energy carrier. Among various options metal hydrides offer high volumetric storage density and operational safety yet their application is limited by thermodynamic kinetic and compositional constraints. In this work we investigate the potential of machine learning (ML) to predict key thermodynamic properties—equilibrium plateau pressure enthalpy and entropy of hydride formation—based solely on alloy composition using Magpie-generated descriptors. We significantly expand an existing experimental dataset from ~400 to 806 entries and assess the impact of dataset size and data augmentation using the PADRE algorithm on model performance. Models including Support Vector Machines and Gradient Boosted Random Forests were trained and optimized via grid search and cross-validation. Results show a marked improvement in predictive accuracy with increased dataset size while data augmentation benefits are limited to smaller datasets and do not improve accuracy in underrepresented pressure regimes. Furthermore clustering and cross-validation analyses highlight the limited generalizability of models across different material classes though high accuracy is achieved when training and testing within a single hydride family (e.g. AB2). The study demonstrates the viability and limitations of ML for accelerating hydride discovery emphasizing the importance of dataset diversity and representation for robust property prediction.
Performance Analysis of Natural Gas Centrifugal Compressors Under Hydrogen-Blended Conditions
Nov 2025
Publication
The transport of natural gas blended with hydrogen is a key strategy for the low-carbon energy transition. However the influence mechanism of its thermo-physical property variations on centrifugal compressor performance remains insufficiently understood. This study systematically investigates the effects of the hydrogen blending ratio (HBR 0–30%) inlet temperature and rotational speed on key compressor parameters (pressure ratio polytropic efficiency and outlet temperature) through numerical simulations. In order to evaluate the influence of hydrogen blending on the performance and stability of centrifugal compressors a three-dimensional model of the compressor was established and the simulation conducted was verified with the experimental data. Results indicate that under constant inlet conditions both the pressure ratio and outlet temperature decrease with increasing HBR while polytropic efficiency remains relatively stable. Hydrogen blending significantly expands the surge margin shifting both surge and choke lines downward and consequently reducing the stable operating range by 27.11% when hydrogen content increases from 0% to 30%. This research provides theoretical foundations and practical guidance for optimizing hydrogen-blended natural gas centrifugal compressor design and operational control.
Green Hydrogen as a Decarbonization Pathway for Steel Industry in Pakistan
Nov 2025
Publication
The global steel industry emits 1.92 tons of CO2 per ton of output and faces urgent pressure to decarbonize. In Pakistan the sector accounts for 0.29 tons of CO2 per ton of output with limited mitigation frameworks in place. Green hydrogen (GH2)-based steelmaking offers a strategic pathway toward decarbonization. However realizing its potential depends on access to renewable energy. Despite Pakistan’s substantial technical wind potential of 340 GW grid limitations currently restrict wind power to only 4% of national electricity generation. This study explores GH2 production through sector coupling and power wheeling repurposing curtailed wind energy from Sindh to supply Karachi’s steel industry and proposing a phased roadmap for GH enabling fossil fuel substitution industrial resilience and alignment with global carbon-border regulations.
Enhancing Green Hydrogen Forecasting with a Spatio-temporal Graph Convolutional Network Optimized by the Ninja Algorithm
Nov 2025
Publication
In light of increased international efforts to combat climate change sustainable infrastructure is shifting toward green hydrogen produced through renewable-powered electrolysis. Still it is challenging to forecast the production of green hydrogen because environmental and system factors are variable both in time and space. We introduce a new system that utilizes a Spatio-Temporal Graph Convolutional Network (STGCN) and a novel algorithm the Ninja Optimization Algorithm (NiOA) to address this issue. Using the framework binary NiOA performs feature selection while continuous NiOA optimizes both the model architecture and the number of variables in the data simultaneously. It is clear from the research that forecasting results have shown significant improvement. The STGCN model achieved an R2 of 0.8769 and an MSE of 0.00375 whereas the STGCN with NiOA reached an R2 of 0.9815 and an MSE of only 7.48 × 10−8. Due to these improvements adaptive metaheuristics show even greater promise in delivering more accurate forecasting and reduced computational requirements for addressing critical environmental issues. The suggested strategy can be followed repeatedly providing a solid framework for the effective modeling of renewable energy systems and making green hydrogen projects more dependable.
An Effective Integrated Optimal Day-ahead and Real-time Power Scheduling Approach for Hydrogen-based Microgrid
Oct 2025
Publication
The increasing penetration of renewable energy sources in power systems poses significant challenges for maintaining grid reliability mainly due to the variability and uncertainty of solar and demand profiles. Microgrids equipped with diverse storage technologies have emerged as a promising solution to address these issues.This paper proposes an integrated day-ahead and real-time power scheduling approach for grid-connected microgrids equipped with both conventional and hydrogen-based ESSs. While existing strategies often address day-ahead and real-time scheduling separately or rely on a single storage technology this work introduces a unified framework that exploits the complementary characteristics of batteries and hydrogen systems. The proposed approach is based on a novel two-stage stochastic optimization model embedded within a hierarchical optimization framework to address these two intertwined problems efficiently. For the day-ahead scheduling a two-stage stochastic programming energy management model is solved to optimize the microgrid schedule based on forecasted load demand and PV production profiles. Building upon the day-ahead schedule another optimization model is solved which addresses real-time power imbalances caused by deviations in actual PV production and load demand power profiles with respect to the forecasted ones with the aim of minimizing operational disruptions. Simulation results demonstrate the validity of the proposed approach achieving both cost reductions and minimal power imbalances. By dynamically adjusting energy flows and using both conventional batteries and hydrogen systems the proposed approach ensures improved reliability reduced operational costs and enhanced integration of RES in microgrids. These findings highlight the potential of the proposed hierarchical framework to support the large-scale deployment of RES while ensuring resilient and cost-effective microgrid operations.
Blockchain-based Traceability and Certifications of Hydrogen Refueling Station Components
Oct 2025
Publication
As hydrogen gains prominence in energy systems its adoption as an energy source for fuel cell electric vehicles (FCEVs) necessitates the establishment of hydrogen refueling stations (HRS). These stations contain critical compo-nents including nozzles storage tanks heat exchangers and compressors which must be certified by regulatory agen-cies to ensure safety and public trust. Current certification processes are fragmented and manually intensive creating inefficiencies and limiting transparency across the infrastructure lifecycle. In this paper we propose a blockchain-based solution that creates a secure and auditable network for certifying key HRS components. The system integrates an EVM-compatible blockchain decentralized storage and a modular suite of smart contracts (SCs) that formalize registration bidding accreditation certification and governance. Each contract encodes a distinct actor-driven work-flow enabling traceable and role-specific operations. A Decentralized Application (DApp) interface supports real-time and role-based interaction across the ecosystem. We present and evaluate the SCs and their underlying algorithms us-ing gas usage analysis load testing and security auditing. Load testing across the certification lifecycle shows stable transaction throughput and predictable cost profiles under increasing actor activity. A static security analysis con-firms resilience against common vulnerabilities. Our cost analysis indicates that while the framework is technically deployable on public blockchains the execution costs of certain functions make it more cost-effective for private blockchains or Layer 2 networks. We also compare our framework with existing systems to highlight its novelty and technical advantages. Our SCs DApp interface and load testing scripts are publicly available on GitHub.
Modelling a Small-scale Hydrogen Valley: Optimisation Under Techno-economic and Environmental Perspectives
Oct 2025
Publication
Renewable hydrogen is a promising pathway to decarbonise hard-to-electrify sectors though its widespread deployment remains hindered by economic challenges. Hydrogen valleys integrated regional systems have emerged as a strategic solution to scale up hydrogen infrastructure and demand. This study assesses the technoeconomic feasibility of a hydrogen valley in southeastern Crete based on the CRAVE-H2 project using a MixedInteger Linear Programming (MILP) optimisation model. The system serves multiple end-uses: touristic fuel cell buses and a vessel as well as cold ironing for ships at berth. In addition to renewable generators electricity can be supplied via a hybrid storage system or purchased from the grid with dispatch optimised according to hourly market prices. A customised modelling framework is developed within PyPSA using the Linopy extension enabling the inclusion of piecewise affine approximations of non-linear performance curves for electrolysers and fuel cells alongside operating range constraints. Hydrogen leakage is also explicitly modelled to assess its environmental and economic implications. The model delivers optimal component sizing energy dispatch strategies and key performance metrics including Levelised Cost Of Hydrogen (LCOH) aggregated Levelised Cost Of Energy (LCOE) and carbon intensity. Most scenarios yield competitive LCOH values between 5.36 and 8.21 €/kgH2 increasing to 15 €/kgH2 under full decarbonisation due to extensive storage investments. Hydrogen emissions that may exceed 10 % of total production in worst-case scenarios become more pronounced in fully decarbonised scenarios. These findings underline the importance of emissions tracking and provide practical insights to inform the design of cost-effective low-emission hydrogen valleys.
Pathways to Green Hydrogen Production as a Sustainable Energy Solution in Kenya by 2040
Nov 2025
Publication
Given the Kenyan challenges in energy availability accessibility and affordability exploring green hydrogen as a sustainable energy solution is supreme. This study aimed to assess the potential of green hydrogen production a transformative clean energy technology and its implications for Kenya's future energy. The specific objectives were to identify the drivers of change that could accelerate green hydrogen adoption and policy recommendations. The study employed a scenario planning approach focusing on four key steps: defining the scenario and time horizon identifying drivers of change and developing and applying scenarios. The diffusion of innovation theory guided the study. Twelve key critical drivers of change were identified with societal and industry acceptance of green hydrogen and compatibility with existing energy infrastructure being the strongest drivers of change from cross-impact analysis results. The study outlined four plausible future scenarios for adoption: Successful Production (best scenario) Low Production Chaotic Transition and Rejection of Green Hydrogen Production (worst scenario). Major opportunities include advancements in hydrogen production export potential and job creation. Cost competitiveness analysis is essential comparing Kenya's hydrogen with traditional fuels and African peers. Economic models suggest that Kenya's renewable energy can lower costs enhancing its position in clean energy innovation. However critical challenges involve regulatory uncertainty ethical concerns public misconceptions about green hydrogen safety and financial barriers due to high initial investment costs. The study recommended that the Kenyan government invest in renewable energy infrastructure formulate a comprehensive national hydrogen policy and establish an enabling environment to attract private investment. In conclusion green hydrogen production stands as a strategic pillar for Kenya’s sustainable energy transition and further research should focus on strengthening regulatory frameworks and enhancing public engagement to unlock its full potential.
Uncertainty Ahead: Should Stand-alone Energy Systems Bet on Hydrogen Backup?
Oct 2025
Publication
Achieving net zero by 2050 will require decarbonising stand-alone energy applications. Hydrogen is increasingly viewed as a promising energy carrier but its economic viability remains uncertain due to the lack of consensus on future demand and limited deployment of key components such as fuel cells in stationary stand-alone applications. This study investigates whether hybridising batteries with hydrogen can deliver meaningful cost benefits under future cost trajectories. Using a Monte Carlo framework we simulate 8000 scenarios across constant and seasonal load profiles varying the capital costs of batteries fuel cells electrolysers and hydrogen tanks based on 2025 estimates and 2050 projections. Our results show that hydrogen integration only becomes economically attractive when multiple component costs decline simultaneously. The fuel cell-to-battery power capital cost ratio emerges as the dominant driver of levelised cost of energy (LCOE) improvements. For constant loads median LCOE savings remain below 12 % with more than 5 % savings only achieved when the fuel cell cost is less than 7 times that of the battery. Seasonal nighttime loads offer a wider theoretical LCOE savings range (0–156 %) but substantial gains occur only under unrealistic cost mixes where battery costs remain high and fuel cell costs fall sharply. These findings highlight the sensitivity of hydrogen viability to load profile characteristics and cost interdependencies. They underscore the need for targeted cost reduction strategies particularly for fuel cells to justify added system complexity. These findings are important considerations for future investment and policy decisions.
Global Greenhouse Gas Emissions Mitigation Potential of Existing and Planned Hydrogen Projects
Nov 2025
Publication
Hydrogen will play a critical role in decarbonizing diverse economic sectors. However given limited sustainable resources and the energy-intensive nature of its production prioritizing its applications will be essential. Here we analyse approximately 2000 (low-carbon) hydrogen projects worldwide encompassing operational and planned initiatives until 2043 quantifying their greenhouse gas (GHG) emissions and mitigation potential from a life cycle perspective. Our results demonstrate the variability in GHG emissions of hydrogen applications depending on the geographical location and hydrogen source used. The most climate-effective hydrogen applications include steel-making biofuels and ammonia while hydrogen use for road transport power generation and domestic heating should be discouraged as more favourable alternatives exist. Planned low-carbon hydrogen projects could generate 110 MtH2 yr−1 emit approximately 0.4 GtCO2e yr−1 and potentially reduce net life cycle GHG emissions by 0.2–1.1 GtCO2e yr−1 by 2043 depending on the substituted product or service. Addressing the current hydrogen implementation gap and prioritizing climate-effective applications are crucial for meeting decarbonization goals.
Assessing the Impact of Integration of Hydrogen Blending from Municipal Solid Waste and Biomass with Gas Turbine on Performance of Traditional Coal Power Plants
Oct 2025
Publication
Producing hydrogen from municipal solid waste (MSW) presents a transformative and sustainable solution for waste management. This paper presents a system that integrates MSW gasification with a traditional coal power plant (TCPP) along with biomass gasification and a gas turbine. It also incorporates a water recovery Rankine cycle (RC) that utilizes flue gas for electricity generation making it a key strategy for cleaner energy and effective waste disposal. The study examines three scenarios: MSWHIRBGT1 MSWHIRBG and MSWHIRBGT2. In the MSWHIRBGT2 electricity generation reaches 877 MW. This achievement results from the injection of hydrogen from MSW gasification into the TCPP boiler combined with advanced biomass technologies and flue gas recovery from TCPP. MSWHIRBGT2 achieves energy and exergy efficiencies of 46.9 % and 43.05 % making it the optimal choice for enhancing power generation in future energy solutions. All scenarios resulted in reduced CO2 emissions compared to a conventional coal-fired power plant of the same capacity highlighting the proposed system’s contribution to a cleaner environment. Furthermore the impact of different percentages of injected hydrogen on the concentrations of CO CO2 H2 H2S SO3 and SO2 in the flue gas is analyzed. Results show that higher hydrogen injection reduces CO by 81 % and H2 by 94 % while increasing SO3 and CO2 levels by 96 % and 39 % respectively. This demonstrates the environmental benefits of the technologies being implemented.
Life Cycle Assessment of Hydrogen-based Fuels Use in Internal Combustion Engines of Container Ships until 2050
Oct 2025
Publication
Hydrogen-based fuels are potential candidates to help international shipping achieve net-zero greenhouse gas (GHG) emissions by around 2050. This paper quantifies the environmental impacts of liquid hydrogen liquid ammonia and methanol used in a Post-Panamax container ship from 2020 to 2050. It considers cargo capacity changes electricity decarbonization and hydrogen production transitions under two International Energy Agency scenarios: the Stated Policies Scenario (STEPS) and the Net Zero Emissions by 2050 Scenario (NZE). Results show that compared to the existing HFO ship hydrogen-based propulsion systems can decrease cargo weight capacity by 0.3 % to 25 %. In the NZE scenario hydrogen-based fuels can reduce GHG emissions per tonne-nautical mile by 48 %–65 % compared to heavy fuel oil by 2050. Even with fully renewable hydrogenbased fuels 18 %–31 % of GHG emissions would still remain. Using hydrogen-based fuels in internal combustion engines requires attention to minimize environmental trade-offs.
Sustainability-aligned Pathways for Energy Transition: A Review of Low-carbon Energy Network Solutions
Nov 2025
Publication
Transformation of the energy sector is necessary to meet climate targets and ensure universal access to reliable and affordable energy. Despite progress more than 675 million people still lack electricity and 770 million face an unreliable power supply. Renewable energy now provides nearly 30 % of global electricity generation and represents approximately 17.9 % of total final energy consumption. This amount is insufficient for the 1.5 ◦C pathway and requires a tripling of renewable capacity by 2030. Energy efficiency also lags with average annual gains of 1.6 % compared with the 4 % required for climate-aligned energy scenarios. Therefore this paper reviews pathways toward decentralized low-carbon solutions that can accelerate global energy transformation. The review paper examines how technologies such as microgrids virtual power plants energy storage systems and vehicleto-grid (V2G) solutions are reshaping modern energy systems. It highlights that digitalization smart grids and sector integration are key to building flexible and consumer-focused networks. However achieving sustainable energy access requires more than new technologies. Strong governance fair financing and social inclusion are equally important to ensure a just and balanced energy transition. Case studies from Asia Africa and Latin America show how policy innovative financing and regional cooperation can drive progress despite challenges such as underinvestment fossil fuel dependency and energy poverty. The review demonstrates that an integrated approach combining technological innovation financial mechanisms and inclusive policies can collectively build low-carbon resilient and equitable energy systems.
Competition and Equilibrium in Future Global Renewable Hydrogen Trade: A Game-theoretic Analysis
Nov 2025
Publication
Global renewable hydrogen trade is expected to play a key role in decarbonizing future energy systems. Yet hydrogen exporters may deviate from perfectly competitive behaviour to influence prices similarly to the existing fossil fuel market with important implications for consumer welfare and the pace of the energy transition. This study develops a global renewable hydrogen trade model that captures potential strategic interactions among exporters using a Stackelberg game-theoretic framework. The model is formulated as an Equilibrium Problem with Equilibrium Constraints (EPEC) and solved under three alternative equilibria: a profitmaximizing Nash equilibrium a cost-minimizing Nash equilibrium and a welfare-maximizing benchmark representing perfect competition. Results indicate that producers may strategically reduce their export quantities by up to 40 % relative to perfect competition to maximize profits. Such behaviour raises prices to a minimum of 4.5 USD/kg in 2050 across major import markets thereby significantly eroding consumer surplus. Strategic behaviour of dominant exporters also shifts trade flows reshaping the global allocation of hydrogen supply. Sensitivity analysis further reveals that financing costs play a key role in shaping strategic producers’ behaviour with lower financing costs helping to reduce prices and stimulate demand. These findings highlight the implications of imperfect competition in global hydrogen trade and suggest that policy measures may be needed to mitigate potential negative consequences.
Modeling Electrochemical Impedance Spectroscopy of Hydrogen Complexes During Hydrogen Evolution on Single-stom Electrocatalysts
Nov 2025
Publication
Single Atom Catalysts (SACs) are an emerging frontier in heterogeneous electrocatalysis. They are made of metal atoms atomically dispersed on a matrix. A lot of attention has been dedicated to the study of Hydrogen Evolution Reaction (HER) mechanism due to its relevance in energy conversion technologies both with computational and experimental methods. The classical HER mechanism can be described by a Volmer–Heyrovsky–Tafel mechanism where the two desorption steps are competitive. The Volmer-Heyrovsky mechanism is conventionally proposed for single-atom catalysts. It has been computationally demonstrated that hydrogen complexes can form on SACs due to their analogy with homogeneous catalysts. Unfortunately it is hard to “visualize” these species experimentally. Electrochemical Impedance Spectroscopy (EIS) could be the most promising approach to study electrocatalytic mechanisms. In this work we present microkinetic and Electrochemical Impedance Spectroscopy models for HER on SACs describing Volmer-Heyrovsky and a mechanism mediated by the formation of hydrogen complexes. Our simulated data applied to a case study based on Pd@TiN show that Tafel plots will not suffice in the visualization of hydrogen complexes formation and will need the support of electrochemical impedance spectra in order to clarify the correct mechanism.
Assessing the Cost-effective Deployment and Operation of Water Electrolyzers in Global Net-zero CO2 Energy Systems
Nov 2025
Publication
This study investigates the cost-optimal capacity and operation of water electrolyzers in global net-zero CO2 energy systems. The production costs of hydrogen are largely determined by the electrolyzer capacity factor (i.e. full-load hours); therefore a global energy system model with an hourly temporal resolution was employed to consider the intermittency of variable renewable energy (VRE) and the dynamics of power system operations. Proton exchange membrane electrolysis is assumed in this study. The optimization results suggest three main findings. First water electrolysis is estimated to be a cost-effective option for achieving net-zero CO2 emissions. Under default technology assumptions the global installed capacity is projected to reach 2719 GW by 2050 with the majority of hydrogen consumed in the industry sector. Scaling up the supply chain is essential to realize this pathway. Second hydrogen and hydrogen-based fuels are economically competitive with negative emission technologies (NETs). A modest deployment of CO2 storage and NETs provides favorable conditions for water electrolysis deployment—and vice versa. Third flexible operation is critical to the widespread deployment of water electrolysis. In the default case the global weighted average capacity factor of electrolyzers is estimated at 37 % in 2050 to follow VRE output fluctuations. The results also indicate that limited operational flexibility may significantly hinder the cost-competitiveness of electrolyzer deployment.
A CFD Comparison of Interfacial Phase Change Models for Boil-off, Self-pressurisation and Thermal Stratification in Liquid Hydrogen Storage Tanks
Nov 2025
Publication
Liquid hydrogen (LH2 ) is a promising energy carrier for future clean fuel technologies. However its cryogenic storage and handling pose significant challenges particularly due to self-pressurisation and boil-off from ambient heat ingress. Accurate modelling of these phenomena is essential for the safe and efficient design of LH2 storage systems. A key aspect of such modelling is the selection and implementation of an appropriate interfacial phase change model. This study presents a comparative assessment of three widely used phase change models; the Schrage model the Modified Energy Jump (MeJ) model and the Lee model. A parametric study was conducted across three coefficients for each model with validation performed against five experimental benchmark cases from NASA’s K-Site and MHTB cryogenic tanks focusing on planar interface problems with thermally induced phase change under normal gravity. A CFD approach using STAR-CCM+ was employed to evaluate each model’s ability to predict tank pressure temperature and boil-off behaviour. The Schrage model demonstrated the most robust and accurate results exhibiting minimal sensitivity to coefficient variation and offering both numerical stability and physical fidelity. It demonstrated a maximum mean absolute percentage error (MAPE) of just 3.0% in its pressurisation predictions. The MeJ model showed comparable accuracy when its heat transfer coefficient was appropriately selected highlighting its reliance on an empirically derived coefficient. In contrast the Lee model performed the poorest exhibiting numerical divergence at high coefficient values and substantial deviation in its prediction of self-pressurisation with errors of up to 11% MAPE. These findings provide practical guidance for the selection and implementation of phase change models in CFD simulations and highlight key considerations for modelling LH2 storage tanks in industrial applications.
The Development of an Analysis Framework for the Integration of Low-carbon Hydrogen into Multi-regional Natural Gas Energy Systems
Nov 2025
Publication
In 2023 global carbon dioxide emissions reached 40 billion tonnes 60 % more than in 1990 intensifying climate concerns. This study explores hydrogen-natural gas blending as a transitional strategy for decarbonization across several regions and energy sectors – residential commercial industrial and agricultural. A multi-regional analysis framework evaluates integration of 20 % by volume low-carbon hydrogen blending into natural gas systems by identifying hydrogen producers importers and exporters based on production and import costs. Applied to Canada 528 scenarios (2026–2050) assess inter-regional hydrogen trade within Canadian provinces. The lowest-cost scenario involves Alberta exporting hydrogen produced through autothermal reforming with 91 % carbon capture and storage and British Columbia producing its own. The grid electrolysis scenario achieves the highest GHG reductions with a 4.5 % GHG mitigation in Canada with full energy system representation. These findings provide insights for policymakers and stakeholders in advancing hydrogen infrastructure and decarbonization strategies.
Techno-economic Analysis of Technologies for Decarbonizing Low- and Medium-Temperature Industrial Heat
Dec 2025
Publication
Decarbonizing industrial heat is critical for achieving climate targets. This study evaluates the economic viability of technologies for decarbonizing industrial heat in Europe through a techno-economic analysis. High-temperature heat pumps (HTHPs) and electric hydrogen and biomass boilers are compared in terms of levelized cost of heat (LCOH) under various scenarios including the impact of thermal storage leveraging dynamic electricity prices. In scenarios for the year 2030 we show that HTHPs leveraging free excess heat achieve LCOH values at least 30% to 60% lower than hydrogen boilers and up to 37% lower than biomass boilers. Integrating daily thermal storage reduces LCOH by up to 15% for heat pumps and 27% for electric boilers. By 2050 anticipated cost and efficiency improvements further enhance the competitiveness of heat pumps. These results highlight the economic advantage of HTHPs particularly when integrating excess heat and thermal storage.
Hydrogen Reduction of Combusted Iron Powder: Role of the Fluidization Regime on the Conversion
Nov 2025
Publication
Fluidized bed systems play a crucial role in industrial processes such as combustion and gasification. In the Iron Power Cycle fluidized bed systems are essential for enabling the reduction of combusted iron back to iron making them a critical component in the regeneration step of the cycle. This study investigates the impact of operating gas velocity on conversion by performing reduction experiments at three distinct fluidization numbers (us/umf): 16 (bubbling regime) 55 (transition region) and 100 (fully turbulent regime). Experiments were conducted to determine the appropriate velocities for each regime ensuring optimal fluidization conditions across reduction temperatures ranging from 500 to 700 ⚬C. The results reveal that conversion rates increase significantly with gas velocities. At 500 ⚬C operating at approximately six times higher velocity leads to a sixfold improvement in conversion when using iron-oxide particles with a Sauter mean diameter of 61 µm. However while enhanced velocities improve reaction efficiency challenges remain at elevated temperatures (T ≥ 500 ⚬C) where iron undergoes defluidization when exposed to hydrogen. Once defluidization occurs refluidization proves impossible with either hydrogen or nitrogen raising concerns about process stability. These insights highlight the potential for optimizing fluidized bed reduction through velocity control while also underscoring the need for additional measures to mitigate unstable fluidization during high-temperature iron oxide reduction.
Thermal and Heat Transfer Dynamics in High Pressure, High Aspect Ratio Hydrogen Tank Filling Processes
Nov 2025
Publication
A thermodynamic modeling framework is introduced to describe hydrogen refueling station configurations and capture detailed thermal dynamics in vehicle tanks with large aspect ratios. With an aspect ratio larger than three axial discretization of temperature allows to recover accurate temperature profiles and show that the gas and liner temperature are always highest towards the rear of the tanks. The framework is validated against experimental data and used to investigate the internal heat transfer dynamics. As aspect ratio grows larger the amount of cooling received by the rear region decreases as the incoming turbulent jet does not reach the latter. The current thermal management strategy of pre-cooling is therefore limited showing marginal improvements even with a cooling temperature of -50 ◦C. Potential solutions are to increase the filling duration time or to carefully design the tank with higher thermal diffusivity and adequate external means of cooling.
Dual S-Scheme Heterojunction Nanocomposite-chrge Transport for Photocatalytic Green Energy Production and Environmental Implementations - Where to Go?
Sep 2025
Publication
Dating back to more than one century ago the photocatalysis process has demonstrated great promise in addressing environmental problems and the energy crisis. Nevertheless some single or binary composite materials cannot meet the requirements of large-scale implementations owing to their limited photocatalytic efficiencies. Since 2021 dual S-scheme heterojunctionbased nanocomposites have been undertaken as highly efficient photoactive materials for green energy production and environmental applications in order to overcome limitations faced in traditional photocatalysts. Herein state-of-the-art protocols designed for the synthesis of dual S-scheme heterojunctions are described. How the combined three semiconductors in dual S-scheme heterojunctions can benefit from one another to achieve high energy production and efficient oxidative removal of various pollutants is deeply explained. Photocatalytic reaction mechanisms by paying special attention to the creation of Fermi levels (Ef ) and charge carriers transfer between the three semiconductors in dual S-scheme heterojunctions are discussed. An entire section has been dedicated to some examples of preparation and applications of double S-scheme heterojunction-based nanocomposites for several photocatalytic applications such as soluble pollutants photodegradation bacteria disinfection artificial photosynthesis H2 generation H2O2 production CO2 reduction and ammonia synthesis. Lastly the current challenges of dual S-scheme heterojunctions are presented and future research directions are presented. To sum up dual S-scheme heterojunction nanocomposites are promising photocatalytic materials in the pursuit of sustainable energy production and environmental remediation. In the future dual S-scheme heterojunctions are highly recommended for photoreactors engineering instead of single or binary photocatalysts to drive forward photocatalysis processes for practical green energy production and environmental protection.
Material Compatibility in Hydrogen Infrastructure: Challenges, Advances, and Future Prospects
Oct 2025
Publication
The adoption of hydrogen as a clean energy carrier depends heavily on the development of materials capable of enduring the extreme conditions associated with its production storage and transportation. This review critically evaluates the performance of metals polymers and composites in hydrogen-rich environments focusing on degradation mechanisms such as hydrogen embrittlement rapid gas decompression and long-term fatigue. Metals like carbon steels and high-strength alloys can experience a 30–50 % loss in tensile strength due to hydrogen exposure while polymers suffer from permeability increases and sealing degradation. Composite materials though strong and lightweight may lose up to 15 % of their mechanical properties over time in hydrogen environments. The review highlights current mitigation strategies including hydrogen-resistant alloys polymer blends protective coatings composite liners and emerging technologies like predictive modeling and AI-based material design. With hydrogen production expected to reach 500 GW globally by 2030 improving material compatibility and developing international standards are essential for scaling hydrogen infrastructure safely and cost-effectively. This work presents an integrated analysis of material degradation mechanisms highlights key challenges across metals polymers and composites in hydrogen environments and explores recent innovations and future strategies to enhance durability and performance in hydrogen infrastructure.
A European Review of the Potential Role of Industrial Clusters in the Energy System When Leveraging Energy Synergies
Nov 2025
Publication
Concerns about the competitiveness of European industry led to the publication of the Draghi report. One of his recommendations is to install regional green industrial clusters around energy-intensive companies. The report identifies three benefit categories each corresponding to typical industrial symbiosis cases: improved investment cases by shared local low-carbon energy generation improved investment cases by shared infrastructure and improved energy flows for increased resource efficiency. Industrial clusters hold untapped potential to advance the energy transition and climate neutrality. However it is still unknown how and if this potential will ever be reached nor how scalable and replicable the benefits will be. This review paper aims to take a first step in exploring the potential role of industrial clusters in the energy system by exposing the research state of the art in academic literature. A literature review is performed in line with the three benefit categories according to Draghi to understand the enablers and barriers of potential synergies and their impact on the energy system. Afterwards the scalability is assessed by positioning the European industrial clusters in the larger renewable energy landscape. To illustrate the global interest a brief reflection is made on references to industrial clusters in the policy of non-European regions. The work concludes with interesting leads for future research to further advance knowledge on the importance of industrial clusters in the energy system and to stimulate the implementation of energy synergies.
Sustainable Power System Transition Pathways: Regional Decarbonisation and Resource Conservation Aided by Small Modular Reactors
Oct 2025
Publication
Clean energy technologies offer promising pathways for low-carbon transitions yet their feasibility remains uncertain particularly in rapidly developing regions. This study develops a Factorial Multi-Stochastic Optimization-driven Equilibrium (FMOE) model to assess the economic and environmental impacts of clean power deployment. Using Small Modular Reactors (SMRs) in Guangdong China as a case study the model reveals that SMRs can reduce system costs and alleviate GDP losses supporting provincial-level Nationally Determined Contributions (NDCs). If offshore wind capital costs fall to 40 % of SMRs’ SMR deployment may no longer be necessary after 2030. Otherwise SMRs could supply 22 % of capacity by 2040. The FMOE model provides a robust adaptable framework for evaluating emerging technologies under uncertainty and supports sustainable power planning across diverse regional contexts. This study offers valuable insights into the resource and economic implications of clean energy strategies contributing to global carbon neutrality and efficient energy system design.
Techno-economic Assessment of Retrofitted Combined-cycles for Power-to-hydrogen-to-power Systems in European Electricity Markets
Oct 2025
Publication
This paper investigates the performance and economic viability of Combined Cycle Gas Turbines (CCGT) operating on natural gas (NG) and hydrogen within the context of evolving electricity markets. The study is structured into several sections beginning with a benchmark analysis to establish baseline performance metrics including break-even prices and price margins for CCGTs running on NG. The research then explores various base cases and sensitivity analyses focusing on different CCGT capacity factors and the uncertainties surrounding key parameters. The study also compares the performance of CCGTs across different European countries highlighting the impact of increased price fluctuations in forecasted electricity markets. Additionally the paper examines Power-to-X-to-Power (P2X2P) configurations assessing the economic feasibility of hydrogen production and its integration into CCGT operations. The analysis considers scenarios where hydrogen is sourced externally or produced on-site using renewable energy or grid electricity during off-peak hours. The results provide insights into the competitiveness and adaptability of CCGTs in a transitioning energy landscape emphasizing the potential role of hydrogen as a flexible and sustainable energy carrier.
Public Readiness for Hydrogen Infrastructure in Community Settings: Comparative Evidence on Attitudinal Dynamics
Oct 2025
Publication
This study presents a cross-national investigation into the drivers and psychological mechanisms shaping public perceptions and acceptance of hydrogen refuelling infrastructure located in residential proximity. Parallel survey data from Japan Spain and Norway were analysed using a multigroup comparative framework. Measurement invariance was established across the three datasets subject to minor modifications within the constructs of trust in hydrogen innovation safe housing concern and perceived usefulness. The conceptual models yielded generalisable findings across countries: negative emotions exerted a stronger influence on individuals' risk perceptions than positive emotions whereas perceived usefulness had a greater impact on acceptance than perceived risk. Safe housing and environmental concerns exhibited moderating effects that amplified the influence of affective responses towards hydrogen refuelling facilities with varying magnitudes across datasets. Furthermore the incorporation of Hofstede's cultural dimensions provided insights into cross-country differences revealing that individualism uncertainty avoidance and long-term orientation explain the psychological pathways through which affective states are translated into subjective evaluations of hydrogen facilities ultimately shaping community acceptance.
High-resolution AI-based Forecasting and Techno-economic Assessment of Green Hydrogen Production from a Hybrid PV/Wind System at the Regional Scale
Oct 2025
Publication
This study presents a comprehensive framework that integrates high-resolution energy forecasting and technoeconomic modeling to assess green hydrogen production potential in Flanders Belgium. Using 15-min interval data from the Elia Group four deep learning models (LSTM BiLSTM GRU and CNN-LSTM) were developed to forecast regional photovoltaic (PV) and onshore wind energy generation. These forecasts informed the estimation of hydrogen yields and the evaluation of the levelized cost of hydrogen (LCOH) under different configurations. Results show that wind-powered hydrogen production achieves the lowest LCOH (6.63 €/kg) due to higher annual operating hours. Among electrolysis technologies alkaline electrolysis (AEL) offers the lowest cost while proton exchange membrane (PEMEL) provides greater flexibility for intermittent power sources. The hybrid PVwind system demonstrated seasonal complementarity increasing annual hydrogen yield and improving production stability. The proposed framework supports regional planning and highlights strategic investment opportunities for cost-effective green hydrogen deployment.
Machine Learning-aided Multi-objective Optimisation of Tesla Valve-based Membraneless Electrolyzer Efficiency
Oct 2025
Publication
Hydrogen (H2) is an attractive fuel due to its high specific energy and zero direct carbon emissions. Membraneless electrolyzers (MEs) offer a lower-cost route to hydrogen production but their operation is complex and current efficiencies are modest. Although multi-objective optimization is widely used its heavy compute demands and weak integration with modern learning methods limit scalability and adaptability. We introduce a practical ML-guided way to design Tesla-valve (TV) membraneless electrolyzers by building diodicity (Di) directly into the geometry search. Using multilayer-perceptron surrogates trained on 150 high-fidelity simulations (R2 > 0.95) we link four design knobs (We Wc Wd Di) to pressure drop (Δp) and ohmic loss. A Genetic Algorithm (GA)-based multi-objective search over realistic ranges delivers 60 Pareto-optimal designs that make the Δp–ohmic trade-off explicit; TOPSIS then selects a balanced geometry (We = 1.708 mm Wc = 0.200 mm Wd = 1.012 mm Di = 1.618) with ohmic loss 4.069 V and Δp 6.169 Pa. The approach delivers faster lower-cost design maps and is supported by experimental checks pointing to an actionable route for scalable interpretable optimization of sustainable hydrogen production.
Development of a High-performance Electrolyzer for Efficient Hydrogen Production via Electrode Modification with a Commercial Catalyst
Oct 2025
Publication
A potential strategy to promote the use of clean energy is the development of catalyst-coated cathodic electrodes that are economical effective and sustainable to enhance the generation of hydrogen (H2) through the electrolysis process. This study investigates the unique design and use of stainless steel (SS) coated with a CuNiZnFeOx catalyst as both anode and cathode electrodes in the alkaline electrolysis process. The electrode exhibits an improved electrochemical behavior achieving a current density of 92 mA/cm2 at an applied voltage of 2.5 V with a surface area of 36 cm2 in 1 M KOH electrolyte at 25 ◦C. Furthermore the H2 production is systematically investigated by varying electrolyte concentration applied voltage and temperature. The results demonstrate that H2 production increases significantly with enhanced electrolyte concentration (3102 mL at 2 M KOH) applied voltage (3468 mL at 3.0 V) and temperature (3202 mL at 60 ◦C) over a 300 min electrolysis time. However optimal operating conditions are determined to be 1 M KOH 2.5 V and 25 ◦C balancing performance and energy efficiency. The improved performance is primarily attributed to enhanced ionic conductivity reduced internal resistance and the synergistic catalytic activity of the Cu-integrated NiZnFeOx coating.
Applied Simulation Study of a Metal Hydride Refrigeration System for Fuel Cell Trucks
Oct 2025
Publication
Refrigeration units in semi-trucks or rigged-body trucks have an energy demand of 8.2–12.4 MWh/y and emit 524.26 kt CO2e/y in Germany. Electrification with fuel cell systems reduces the CO2 emission but an increase of efficiency is necessary because of rapidly increasing hydrogen costs. A metal hydride refrigeration system can increase the efficiency. Even though it was already demonstrated in lab scale with 900 W this power is not sufficient to support a truck refrigeration system and the power output of the lab system was not controllable. Here we show the design and validation of a MATLAB© Simulink model of this metal hydride refrigeration system and its suitability for high power applications with a scaled-up reactor. It was scaled up to rated power of 5 kW and efficiency improvements with an advanced valve switching as well as a controlled cooling pump were implemented. Two application-relevant use cases with hydrogen mass flows from hydrogen fuel cell truck systems were analyzed. The simulation results of these use cases provide an average cooling power of 4.2 and 6.1 kW. Additionally the control of the coolant mass flow at different temperature levels a controlled hydrogen mass flow with a bypass system and an advanced valve switching mechanism increased the system efficiency of the total refrigeration system by 30 % overall.
A Systematic Analysis of Life Cycle Assessments in Hydrogen Energy Systems
Nov 2025
Publication
Hydrogen plays a central role in ensuring the fulfillment of the climate and energy goals established in the Paris Agreement. To implement sustainable and resilient hydrogen economies it is essential to analyze the entire hydrogen value chain following a Life Cycle Assessment (LCA) methodology. To determine the current methodologies approaches and research tendencies adopted when performing LCA of hydrogen energy systems a systematic literature analysis is carried out in the present study. The choices regarding the “goal and scope definition” “life cycle inventory analysis” and “life cycle impact assessment” in 70 scientific papers were assessed. Based on the collected information it was concluded that there are no similar LCA studies since specificities introduced in the system boundaries functional unit production storage transportation end-use technologies geographical specifications and LCA methodological approaches among others introduce differences among studies. This lack of harmonization triggers the need to define harmonization protocols that allow for a fair comparison between studies; otherwise the decision-making process in the hydrogen energy sector may be influenced by methodological choices. Although initial efforts have been made their adoption remains limited and greater promotion is needed to encourage wider implementation.
Energy Management of Hybrid Energy System Considering a Demand-Side Management Strategy and Hydrogen Storage System
Oct 2025
Publication
Nadia Gouda and
Hamed Aly
A hybrid energy system (HES) integrates various energy resources to attain synchronized energy output. However HES faces significant challenges due to rising energy consumption the expenses of using multiple sources increased emissions due to non-renewable energy resources etc. This study aims to develop an energy management strategy for distribution grids (DGs) by incorporating a hydrogen storage system (HSS) and demand-side management strategy (DSM) through the design of a multi-objective optimization technique. The primary focus is on optimizing operational costs and reducing pollution. These are approached as minimization problems while also addressing the challenge of achieving a high penetration of renewable energy resources framed as a maximization problem. The third objective function is introduced through the implementation of the demand-side management strategy aiming to minimize the energy gap between initial demand and consumption. This DSM strategy is designed around consumers with three types of loads: sheddable loads non-sheddable loads and shiftable loads. To establish a bidirectional communication link between the grid and consumers by utilizing a distribution grid operator (DGO). Additionally the uncertain behavior of wind solar and demand is modeled using probability distribution functions: Weibull for wind PDF beta for solar and Gaussian PDF for demand. To tackle this tri-objective optimization problem this work proposes a hybrid approach that combines well-known techniques namely the non-dominated sorting genetic algorithm II and multi-objective particle swarm optimization (Hybrid-NSGA-II-MOPSO). Simulation results demonstrate the effectiveness of the proposed model in optimizing the tri-objective problem while considering various constraints.
Decarbonising Sustainable Aviation Fuel (SAF) Pathways: Emerging Perspectives on Hydrogen Integration
Oct 2025
Publication
The growing demand for air connectivity coupled with the forecasted increase in passengers by 2040 implies an exigency in the aviation sector to adopt sustainable approaches for net zero emission by 2050. Sustainable Aviation Fuel (SAF) is currently the most promising short-term solution; however ensuring its overall sustainability depends on reducing the life cycle carbon footprints. A key challenge prevails in hydrogen usage as a reactant for the approved ASTM routes of SAF. The processing conversion and refinement of feed entailing hydrodeoxygenation (HDO) decarboxylation hydrogenation isomerisation and hydrocracking requires substantial hydrogen input. This hydrogen is sourced either in situ or ex situ with the supply chain encompassing renewables or non-renewables origins. Addressing this hydrogen usage and recognising the emission implications thereof has therefore become a novel research priority. Aside from the preferred adoption of renewable water electrolysis to generate hydrogen other promising pathways encompass hydrothermal gasification biomass gasification (with or without carbon capture) and biomethane with steam methane reforming (with or without carbon capture) owing to the lower greenhouse emissions the convincing status of the technology readiness level and the lower acidification potential. Equally imperative are measures for reducing hydrogen demand in SAF pathways. Strategies involve identifying the appropriate catalyst (monometallic and bimetallic sulphide catalyst) increasing the catalyst life in the deoxygenation process deploying low-cost iso-propanol (hydrogen donor) developing the aerobic fermentation of sugar to 14 dimethyl cyclooctane with the intermediate formation of isoprene and advancing aqueous phase reforming or single-stage hydro processing. Other supportive alternatives include implementing the catalytic and co-pyrolysis of waste oil with solid feedstocks and selecting highly saturated feedstock. Thus future progress demands coordinated innovation and research endeavours to bolster the seamless integration of the cutting-edge hydrogen production processes with the SAF infrastructure. Rigorous technoeconomic and life cycle assessments alongside technological breakthroughs and biomass characterisation are indispensable for ensuring scalability and sustainability
Coordinated Control Strategy for Island Power Generation System with Photovoltaic, Hydrogen-Fueled Gas Turbine and Hybrid Energy Storage
Oct 2025
Publication
Marine and island power systems usually incorporate various forms of energy supply which poses challenges to the coordinated control of the system under diverse irregular and complex load operation modes. To improve the stability and self-sufficiency of island-isolated microgrids with high penetration of renewable energy this study proposes a coordinated control strategy for an island microgrid with PV HGT and HESS combining primary power allocation via low-pass filtering with a fuzzy logic-based secondary correction. The fuzzy controller dynamically adjusts power distribution based on the states of charge of the battery and supercapacitor following a set of predefined rules. A comprehensive system model is developed in Matlab R2023b integrating PV generation an electrolyzer HGT and a battery–supercapacitor HESS. Simulation results across four operational cases demonstrate that the proposed strategy reduces DC bus voltage fluctuations to a maximum of 4.71% (compared to 5.63% without correction) with stability improvements between 0.96% and 1.55%. The HESS avoids overcharging and over-discharging by initiating priority charging at low SOC levels thereby extending service life. This work provides a scalable control framework for enhancing the resilience of marine and island microgrids with high renewable energy penetration.
Optimizing Green Hydrogen Cost with PV Energy and Storage
Oct 2025
Publication
This work develops a replicable method for designing the optimal renewable hydrogen production facility applicable to any site and based on technical parameters and actual equipment costs. The solution is based on the integration of photovoltaic (PV) energy with lithium-ion battery storage systems which maximizes electrolyzer operating hours and significantly reduces the Levelized Cost of Hydrogen (LCOH). This study shows that increasing the inclination of the photovoltaic modules reduces the need for storage optimizing operation and extending the electrolyzer’s annual operating hours. In the Seville case study with current costs and efficiencies a minimum LCOH of €4.43/kg was achieved a value well below market benchmarks opening the door to a potentially competitive industrial business. The analysis confirms that electrolyzer efficiency—particularly specific power consumption—is the most important factor in reducing costs while technological progress in photovoltaics storage and equipment promises further reductions in the coming years. Overall the proposed methodology offers a practical and scalable tool to accelerate the economic viability of green hydrogen in a variety of contexts.
Mapping Green Hydrogen Research in North Africa: A Bibliometric Approach for Strategic Foresight
Oct 2025
Publication
This bibliometric analysis aims to map the evolution disciplinary structure and collaboration dynamics of green hydrogen (GH) research in North Africa from 2019 to 2025. Drawing on a corpus of ~39000 global publications indexed in Scopus and analysed through SciVal we isolate and examine the contributions of Egypt Morocco Algeria Tunisia and Libya. Egypt leads the region with 842 publications and a field-weighted citation impact of 2.42 followed by Morocco (232 Pubs. FWCI 2.30) and Algeria (184 Pubs. FWCI 1.65). Notably Tunisia exhibits the highest growth factor (41 times since 2019) while Libya remains marginal with only 18 publications in the GH field. The region is well represented in Energy and Environmental fields but is underrepresented in trendy areas such as Materials and Chemical Engineering highlighting critical gaps in consistency sophistication and technical infrastructure. While international collaboration exceeds 69% for most countries it rarely translates into a high impact compared to the global average. Conversely the limited industrial collaboration shows the highest citation impact (e.g. Tunisia: 68 citations/publications). A thematic analysis reveals shared strengths in electrolytic hydrogen production and renewable energy integration with Egypt showing diversification into microalgae and nanocomposites and Morocco excelling in techno-economic assessments and ammonia-based systems. By revealing patterns in research quality collaboration and thematic positioning this study offers evidence-based insights to inform national science strategies enhance regional cooperation and position North Africa more strategically in the emerging global green hydrogen economy.
Integrated Modeling of Steam Methane Reforming and Carbon Capture for Blue Hydrogen Production
Nov 2025
Publication
The increasing global demand for clean energy highlights hydrogen as a strategic energy carrier due to its high energy density and carbon-free utilization. Currently steam methane reforming (SMR) is the most widely applied method for hydrogen production; however its high CO2 emissions undermine the environmental benefits of hydrogen. Blue hydrogen production integrates carbon capture and storage (CCS) technologies to overcome this drawback in the SMR process significantly reducing greenhouse gas emissions. This study integrated a MATLAB-R2025b-based plug flow reactor (PFR) model for SMR kinetics with an Aspen HYSYS-based CCS system. The effects of reformer temperature (600–1000 ◦C) and steam-to-carbon (S/C) ratio (1–5) on hydrogen yield and CO2 emission intensity were investigated. Results show that hydrogen production increases with temperature reaching maximum conversion at 850–1000 ◦C while the optimum performance is achieved at S/C ratios of 2.5–3.0 balancing high hydrogen yield and minimized methane slip. Conventional SMR generates 9–12 kgCO2/kgH2 emissions whereas SMR + CCS reduces this to 2–3 kgCO2/kgH2 achieving more than 75% reduction. The findings demonstrate that SMR + CCS integration effectively mitigates emissions and provides a sustainable bridging technology for blue hydrogen production supporting the transition toward lowcarbon energy systems.
Computational Fluid Dynamic Modeling and Parametric Optimization of Hydrogen Adsorption in Stationary Hydrogen Tanks
Nov 2025
Publication
A. Ousegui and
B. Marcos
This study investigates hydrogen storage enhancement through adsorption in porous materials by coupling the Dubinin–Astakhov (D-A) adsorption model with H2 conservation equations (mass momentum and energy). The resulting system of partial differential equations (PDEs) was solved numerically using the finite element method (FEM). Experimental work using activated carbon as an adsorbent was carried out to validate the model. The comparison showed good agreement in terms of temperature distribution average pressure of the system and the amount of adsorbed hydrogen (H2). Further simulations with different adsorbents indicated that compact metal–organic framework 5 (MOF-5) is the most effective material in terms of H2 adsorption. Additionally the pair (273 K 800 s) remains the optimal combination of injection temperature and time. The findings underscore the prospective advantages of optimized MOF-5-based systems for enhanced hydrogen storage. These systems offer increased capacity and safety compared to traditional adsorbents. Subsequent research should investigate multi-objective optimization of material properties and system geometry along with evaluating dynamic cycling performance in practical operating conditions. Additionally experimental validation on MOF-5-based storage prototypes would further reinforce the model’s predictive capabilities for industrial applications.
Analysis of Fuel Cell Electric Vehicle Performance Under Standard Electric Vehicle Driving Protocol
Nov 2025
Publication
The paper studies and analyzes electric vehicle engines powered by hydrogen under the WLTP standard driving protocol. The driving range extension is estimated using a specific protocol developed for FCEV compared with the standard value for battery electric vehicles. The driving range is extended by 10 km averaging over the four protocols with a maximum of 11.6 km for the FTP-75 and a minimum of 7.7 km for the WLTP. This driving range extension represents a 1.8% driving range improvement on average. Applying the FCEV current weight the driving range is extended to 18.9 km and 20.4 km on average when using power source energy capacity standards for BEVs and FCEVs.
Advancing Sustainable Energy Transitions: Insights on Finance, Policy, Infrastructure, and Demand-side Integration
Nov 2025
Publication
Achieving the 1.5 ◦C global temperature target and reaching net-zero emissions by 2050 require a fundamental transformation of energy systems driven by the rapid deployment of renewable energy technologies and underpinned by systemic policy financial and infrastructural reform. The manuscript adopts a literature-driven approach synthesizing findings from existing scholarly sources that shape the transition to sustainable energy systems. It begins by outlining global progress toward climate targets emphasizing the critical role of renewable energy in decarbonizing electricity industry and transport sectors. The manuscript explores recent technological advancements and trends in solar wind hydrogen and emerging clean technologies highlighting their impact on global energy supply chains and production models. Particular attention is given to the complexities of integrating renewable energy into existing infrastructure including grid modernization digitaliation and storage technologies. On the demand side the article examines changing consumption patterns electrification and the role of distributed generation in shaping future energy landscapes. Investment and finance emerge as central challenges with the paper analyzing the disparities in capital costs between developed and developing economies and the need for innovative green finance instruments to de-risk investment. The manuscript further identifies structural barriers including policy uncertainty supply chain constraints and permitting delays as key impediments to progress. Nonetheless the article outlines significant opportunities for scaling up renewable deployment through international cooperation targeted subsidies and public-private partnerships. The manuscript concludes by emphasizing the necessity of coherent and enforceable policy frameworks to align national commitments with global climate goals. It calls for an integrated multi-stakeholder approach to ensure that finance infrastructure demand and governance evolve in tandem thereby enabling a just inclusive and resilient global energy transition.
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