Publications
Renewable Hydrogen Trade, in a Global Decarbonised Energy System
Jan 2025
Publication
Renewable hydrogen has emerged as a potentially critical energy carrier for achieving climate change mitigation goals. International trade could play a key role in meeting hydrogen demand in a globally decarbonized energy system. To better understand this role we have developed a modelling framework that incorporates hydrogen supply and demand curves and a market equilibrium model to maximize social welfare. Applying this framework we investigate two scenarios: an unrestricted trade scenario where hydrogen trade is allowed between all regions globally and a regional independence scenario where trade is restricted to be intra-regional only. Under the unrestricted trade scenario global hydrogen demand could reach 234 Mt by 2050 with 31.2% met through international trade. Key trade routes identified include North Africa to Europe the Middle East to Developing Asia and South America to Japan and South Korea. In the regional independence scenario most regions could meet their demand domestically except for Japan and South Korea due to self-insufficiency. Finally this analysis reveals that producers in North Africa and South America are likely to gain more economic value from international trade compared to other producing regions. The results offer key insights for policymakers and investors for shaping future hydrogen trade policies and investment decisions.
Digital Real-Time Simulation and Power Quality Analysis of a Hydrogen-Generating Nuclear-Renewable Integrated Energy System
Feb 2025
Publication
This paper investigates the challenges and solutions associated with integrating a hydrogen-generating nuclear-renewable integrated energy system (NR-IES) under a transactive energy framework. The proposed system directs excess nuclear power to hydrogen production during periods of low grid demand while utilizing renewables to maintain grid stability. Using digital real-time simulation (DRTS) in the Typhoon HIL 404 model the dynamic interactions between nuclear power plants electrolyzers and power grids are analyzed to mitigate issues such as harmonic distortion power quality degradation and low power factor caused by large non-linear loads. A three-phase power conversion system is modeled using the Typhoon HIL 404 model and includes a generator a variable load an electrolyzer and power filters. Active harmonic filters (AHFs) and hybrid active power filters (HAPFs) are implemented to address harmonic mitigation and reactive power compensation. The results reveal that the HAPF topology effectively balances cost efficiency and performance and significantly reduces active filter current requirements compared to AHF-only systems. During maximum electrolyzer operation at 4 MW the grid frequency dropped below 59.3 Hz without filtering; however the implementation of power filters successfully restored the frequency to 59.9 Hz demonstrating its effectiveness in maintaining grid stability. Future work will focus on integrating a deep reinforcement learning (DRL) framework with real-time simulation and optimizing real-time power dispatch thus enabling a scalable efficient NR-IES for sustainable energy markets.
The Geopolitics of Hydrogen, Volume 1: European Strategies in Global Perspective
Jan 2024
Publication
Rainer Quitzow,
Yana Zabanova,
Almudena Nunez,
Ines Bouacida,
Michał Smoleń,
Wojciech Żelisko,
John Szabo,
Ignacio Urbasos,
Gonzalo Escribano,
Andrea Prontera,
Roelof Stam,
Coby van der Linder,
Pier Stapersma,
Stefan Ćetković,
Janek Stockburger,
Jon Birger Skjærseth,
Per Ove Eikeland,
Tor Håkon Jackson Inderberg and
Mari Lie Larsen
Chapters:<br/>♦ Introduction by Rainer Quitzow and Yana Zabanova<br/>♦ The EU in the Global Hydrogen Race: Bringing Together Climate Action Energy Security and Industrial Policy by Yana Zabanova<br/>♦ Germany’s Hydrogen Strategy: Securing Industrial Leadership in a Carbon–Neutral Economy by Almudena Nunez and Rainer Quitzow<br/>♦ France’s Hydrogen Strategy: Focusing on Domestic Hydrogen Production to Decarbonise Industry and Mobility by Ines Bouacida<br/>♦ International Dimension of the Polish Hydrogen Strategy. Conditions and Potential for Future Development by Michał Smoleń and Wojciech Żelisko<br/>♦ Hydrogen Affairs in Hungary’s Politically Confined Ambition byJohn Szabo<br/>♦ Spain’s Hydrogen Ambition: Between Reindustrialisation and Export-Led Energy Integration with the EU by Ignacio Urbasos and Gonzalo Escribano<br/>♦ Italian Hydrogen Policy: Drivers Constraints and Recent Developments by Andrea Prontera<br/>♦ Hydrogen Policy in the Netherlands: Laying the Foundations for a Scalable Hydrogen Value Chain by Roelof Stam Coby van der Linde and Pier Stapersma<br/>♦ Hydrogen Strategy of Sweden: Unpacking the Multiple Drivers and Potential Barriers to Hydrogen Development by Stefan Ćetković and Janek Stockburger<br/>♦ Norway’s Hydrogen Strategy: Unveiling Green Opportunities and Blue Export Ambitions by Jon Birger Skjærseth Per Ove Eikeland Tor Håkon Jackson Inderberg and Mari Lie Larsen<br/>♦ The Geopolitics of Hydrogen in Europe: The Interplay between EU and Member State Policies by Rainer Quitzow and Yana Zabanova
Comparative Study and Optimization of Energy Management Strategies for Hydrogen Fuel Cell Vehicles
Sep 2024
Publication
Fuel cell hybrid systems due to their combination of the high energy density of fuel cells and the rapid response capability of power batteries have become an important category of new energy vehicles. This paper discusses energy management strategies in hydrogen fuel cell vehicles. Firstly a detailed comparative analysis of existing PID control strategies and Adaptive Equivalent Consumption Minimization Strategies (A-ECMSs) is conducted. It was found that although A-ECMS can balance the energy utilization of the fuel cell and power battery well the power fluctuations of the fuel cell are significant leading to increased hydrogen consumption. Therefore this paper proposes an improved Adaptive Low-Pass Filter Equivalent Consumption Minimization Strategy (A-LPF-ECMS). By introducing low-pass filtering technology transient changes in fuel cell power are smoothed effectively reducing fuel consumption. Simulation results show that under the 6*FTP75 cycle the energy loss of A-LPF-ECMS is reduced by 10.89% (compared to the PID strategy) and the equivalent hydrogen consumption is reduced by 7.1%; under the 5*WLTC cycle energy loss is reduced by 5.58% and equivalent hydrogen consumption is reduced by 3.18%. The research results indicate that A-LPF-ECMS performs excellently in suppressing fuel cell power fluctuations under idling conditions significantly enhancing the operational efficiency of the fuel cell and showing high application value.
Voltage Losses in Zero-gap Alkaline Water Electrolysis
Apr 2021
Publication
Reducing the gap between the electrodes and diaphragm to zero is an often adopted strategy to reduce the ohmic drop in alkaline water electrolyzers for hydrogen production. We provide a thorough account of the current–voltage relationship in such a zero-gap configuration over a wide range of electrolyte concentrations and current densities. Included are voltage components that are not often experimentally quantified like those due to bubbles hydroxide depletion and dissolved hydrogen and oxygen. As is commonly found for zero-gap configurations the ohmic resistance was substantially larger than that of the separator. We find that this is because the relatively flat electrode area facing the diaphragm was not active likely due to separator pore blockage by gas the electrode itself and or solid deposits. Over an e-folding time-scale of ten seconds an additional ohmic drop was found to arise likely due to gas bubbles in the electrode holes. For electrolyte concentrations below 0.5 M an overpotential was observed associated with local depletion of hydroxide at the anode. Finally a high supersaturation of hydrogen and oxygen was found to significantly increase the equilibrium potential at elevated current densities. Most of these voltage losses are shown to be easily avoidable by introducing a small 0.2 mm gap greatly improving the performance compared to zero-gap.
Application of Levelized and Environmental Cost Accounting Techniques to Demonstrate the Feasibility of Green Hydrogen-Powered Buses in Brazil
Feb 2025
Publication
Background: This study applied levelized cost of hydrogen (LCOH) and environmental cost accounting techniques to evaluate the feasibility of producing green hydrogen (GH2) via alkaline electrolysis for use in a bus fleet in Fortaleza Brazil. Methods: A GH2 plant with a 3 MW wind tower was considered in this financial project. A sensitivity analysis was conducted to assess the economic viability of the project considering the influence of production volume the number of electrolysis kits financing time and other kay economic indices. Revenue was derived from the sale of by-products including green hospital oxygen (GHO2) and excess wind energy. A life cycle assessment (LCA) was performed to quantify material and emission flows throughout the H2 production chain. A zero-net hydrogen price scenario was tested to evaluate the feasibility of its use in urban transportation. Results: The production of GH2 in Brazil using alkaline electrolysis powered by wind energy proved to be economically viable for fueling a hydrogen-powered bus fleet. For production volumes ranging from 8.89 to 88.9 kg H2/h the sensitivity analysis revealed high economic performance achieving a net present value (NPV) between USD 19.4 million and USD 21.8 million a payback period of 1–4 years an internal rate of return (IRR) of 24–90% and a return on investment (ROI) of 300–1400%. The LCOH decreased with increased production ranging from 56 to 25 USD/MWh. Over the project timeline GH2 production and use in the bus fleet reduced CO2 emissions by 53000–287000 t CO2 eq. The fuel cell bus fleet project demonstrated viability through fuel cost savings and revenue from carbon credit sales highlighting the economic social and environmental sustainability of GH2 use in urban transportation in Brazil.
Energy Hub Model for the Massive Adoption of Hydrogen in Power Systems
Sep 2024
Publication
A promising energy carrier and storage solution for integrating renewable energies into the power grid currently being investigated is hydrogen produced via electrolysis. It already serves various purposes but it might also enable the development of hydrogen-based electricity storage systems made up of electrolyzers hydrogen storage systems and generators (fuel cells or engines). The adoption of hydrogen-based technologies is strictly linked to the electrification of end uses and to multicarrier energy grids. This study introduces a generic method to integrate and optimize the sizing and operation phases of hydrogen-based power systems using an energy hub optimization model which can manage and coordinate multiple energy carriers and equipment. Furthermore the uncertainty related to renewables and final demands was carefully assessed. A case study on an urban microgrid with high hydrogen demand for mobility demonstrates the method’s applicability showing how the multi-objective optimization of hydrogen-based power systems can reduce total costs primary energy demand and carbon equivalent emissions for both power grids and mobility down to −145%. Furthermore the adoption of the uncertainty assessment can give additional benefits allowing a downsizing of the equipment.
Impact of Hydrogen Direct Injection on Engine Combustion and Emissions in a GDI Engine
Sep 2023
Publication
The combustion and emission characteristics of a hydrogen engine were investigated through experimental analysis using a GDI engine. To enable hydrogen in-cylinder direct injection a specialized hydrogen gas injector was employed. A comparative analysis of the combustion performance between gasoline and hydrogen fuels in a spark-ignited engine was conducted. Additionally the study experimentally explored the thermal efficiency and emission reduction potential of hydrogen engines in lean combustion modes. The results indicated a significant improvement in the combustion rate when hydrogen fuel was utilized in the spark-ignited engine. However the effective thermal efficiency was found to be lower than that of gasoline fuel due to the delayed MBF50 under stoichiometric conditions. Furthermore when compared to gasoline fuel the reduction of CO and THC emissions was accompanied by an increase in NOx emissions. Nevertheless optimizing the air dilution ratio in hydrogen engines led to an improvement in the effective thermal efficiency. Specifically under medium load conditions a Lambda value of 2.7 resulted in an effective thermal efficiency of 43.5%. Additionally under ultra-lean conditions (Lambda > 2.3) NOx emissions could be reduced to below 50 ppm reaching as low as 44 ppm. This study highlights the potential of improving combustion efficiency and reducing emissions by utilizing hydrogen fuel particularly in lean combustion modes. It contributes to the continuous development of hydrogen engine technology and promotes the implementation of cleaner and more efficient energy solutions.
Modeling Critical Enablers of Hydrogen Supply Chains for Decarbonization: Insights from Emerging Economies
Mar 2025
Publication
The current global energy environment is experiencing a substantial shift towards minimizing carbon emissions and enhancing sustainability due to persistent problems. Demand for sustainable end-to-end energy solutions has boosted green hydrogen as the solution to decarbonize the world. The current study has identified and evaluated 7 main criteria of 27 sub-criteria for enabling the hydrogen supply Chains for decarbonization using the Fuzzy DEMATEL technique. The results show that the most prominent enablers criteria under causal factors are: cluster-based approach for developing a green hub Cost and investment decisions Hydrogen trade policy and regulatory actions and Technology. The effect group factors include: Assessment of ecological concerns- Ecology effect Availability of Energy sources and Awareness and public outreach. This study offers insights to understand the dynamics of the hydrogen supply chains and its way ahead towards decarbonization and transition towards a low-carbon economy. This research helps various academic and industrial stakeholders to give pace to green hydrogen uptake as a vital decarbonization tool and act as a base for strategic and collaborative decisions for a resilient and responsible energy landscape.
Low-Carbon Economic Scheduling of Hydrogen-Integrated Energy Systems with Enhanced Bilateral Supply–Demand Response Considering Vehicle to Grid Under Power-to-Gas–Carbon Capture System Coupling
Feb 2025
Publication
Hydrogen-Integrated energy systems (HIESs) are pivotal in driving the transition to a low-carbon energy structure in China. This paper proposes a low-carbon economic scheduling strategy to improve the operational efficiency and reduce the carbon emissions of HIESs. The approach begins with the implementation of a stepwise carbon trading framework to limit the carbon output of the system. This is followed by the development of a joint operational model that combines hydrogen energy use and carbon capture. To improve the energy supply flexibility of HIESs modifications to the conventional combined heat and power (CHP) unit are made by incorporating a waste heat boiler and an organic Rankine cycle. This results in a flexible CHP response model capable of adjusting both electricity and heat outputs. Furthermore a comprehensive demand response model is designed to optimize the flexible capacities of electric and thermal loads thereby enhancing demand-side responsiveness. The integration of electric vehicles (EVs) into the system is analyzed with respect to their energy consumption patterns and dispatch capabilities which improves their potential for flexible scheduling and enables an optimized synergy between the demand-side flexibility and system operations. Finally a low-carbon economic scheduling model for the HIES is developed with the objective of minimizing system costs. The results show that the proposed scheduling method effectively enhances the economy low-carbon performance and flexibility of HIES operation while promoting clean energy consumption deep decarbonization of the system and the synergistic complementarity of flexible supply–demand resources. In the broader context of expanding clean energy and growing EV adoption this study demonstrates the potential of energy-saving emissionreduction systems and vehicle-to-grid (V2G) strategies to contribute to the sustainable and green development of the energy sector.
Shifting to Low-carbon Hydrogen Production Supports Job Creation but Does Not Gurantee a Just Transition
Nov 2024
Publication
Transitioning from carbon-intensive steam methane reforming to low-carbon hydrogen production is essential for decarbonizing the European industrial sector. However the employment impact of such a transition remains unclear. Here we estimate the effects using a transition pathways optimization model and industrial survey data. The results show that an electrolysis-based hydrogen sector transition would create 40000 jobs in the hydrogen sector by 2050. However these jobs are not equally distributed with Western Europe hosting the largest share (40%) and 20% of current hydrogen-producing regions experiencing net job decreases. Even after accounting for renewable energy jobs created by electrolysis-driven electricity demand growth the 2050 low-carbon hydrogen workforce would provide only 10% of the jobs currently offered by European fossil fuel production. Numerous uncertainties and regional development inequities suggest the need for sector-diversified workforce transition plans and training programs to foster skills suited to multiple low-carbon opportunities.
Optimal Operation Strategy for Wind–Photovoltaic Power-Based Hydrogen Production Systems Considering Electrolyzer Start-Up Characteristics
Aug 2024
Publication
Combining electrolytic hydrogen production with wind–photovoltaic power can effectively smooth the fluctuation of power and enhance the schedulable wind–photovoltaic power which provides an effective solution to solve the problem of wind–photovoltaic power accommodation. In this paper the optimization operation strategy is studied for the wind–photovoltaic power-based hydrogen production system. Firstly to make up for the deficiency of the existing research on the multi-state and nonlinear characteristics of electrolyzers the three-state and power-current nonlinear characteristics of the electrolyzer cell are modeled. The model reflects the difference between the cold and hot starting time of the electrolyzer and the linear decoupling model is easy to apply in the optimization model. On this basis considering the operation constraints of the electrolyzer hydrogen storage tank battery and other equipment the optimization operation model of the wind–photovoltaic power-based hydrogen production system is developed based on the typical scenario approach. It also considers the cold and hot starting time of the electrolyzer with the daily operation cost as the goal. The results show that the operational benefits of the system can be improved through the proposed strategy. The hydrogen storage tank capacity will have an impact on the operation income of the wind–solar hydrogen coupling system and the daily operation income will increase by 0.32% for every 10% (300 kg) increase in the hydrogen storage tank capacity.
A Comprehensive Review on the Hydrogen–Natural Gas–Diesel Tri-Fuel Engine Exhaust Emissions
Aug 2024
Publication
Natural gas (NG) is favored for transportation due to its availability and lower CO2 emissions than fossil fuels despite drawbacks like poor lean combustion ability and slow burning. According to a few recent studies using hydrogen (H2 ) alongside NG and diesel in Tri-fuel mode addresses these drawbacks while enhancing efficiency and reducing emissions making it a promising option for diesel engines. Due to the importance and novelty of this the continuation of ongoing research and insufficient literature studies on HNG–diesel engine emissions that are considered helpful to researchers this research has been conducted. This review summarizes the recent research on the HNG–diesel Tri-fuel engines utilizing hydrogen-enriched natural gas (HNG). The research methodology involved summarizing the effect of engine design operating conditions fuel mixing ratios and supplying techniques on the CO CO2 NOx and HC emissions separately. Previous studies show that using natural gas with diesel increases CO and HC emissions while decreasing NOx and CO2 compared to pure diesel. However using hydrogen with diesel reduces CO CO2 and HC emissions but increases NOx. On the other hand HNG–diesel fuel mode effectively mitigates the disadvantages of using these fuels separately resulting in decreased emissions of CO CO2 HC and NOx. The inclusion of hydrogen improves combustion efficiency reduces ignition delay and enhances heat release and in-cylinder pressure. Additionally operational parameters such as engine power speed load air–fuel ratio compression ratio and injection parameters directly affect emissions in HNG–diesel Tri-fuel engines. Overall the Tri-fuel approach offers promising emissions benefits compared to using natural gas or hydrogen separately as dual-fuels.
Advances in Whole-cell Photobiological Hydrogen Production
Jan 2021
Publication
Solar energy is the largest energy source on Earth. In contrast to the limited andgreenhouse gases-emitting fossil fuels solar energy is inexhaustible carbonneutral and nonpolluting. The conversion of this most abundant but highlydiffused source into hydrogen is increasingly attractive. In nature photosyntheticmicroorganisms exploit solar energy to produce hydrogen via photosynthesiswhich is also known as photobiological hydrogen production. More recentlyvarious types of artificial materials have been developed to hybrid microorgan-isms for converting solar energy into hydrogen namely semiartificial photo-synthesis hydrogen production. Herein the strategies for converting solar energyinto hydrogen with whole-cell biocatalyst are summarized and their potentials forfuture social sustainable development are discussed.
Numerical Investigation and Simulation of Hydrogen Blending into Natural Gas Combustion
Aug 2024
Publication
This study reviews existing simulation models and describes a selected model for analysing combustion dynamics in hydrogen and natural gas mixtures specifically within non-ferrous melting furnaces. The primary objectives are to compare the combustion characteristics of these two energy carriers and assess the impact of hydrogen integration on furnace operation and efficiency. Using computational fluid dynamics (CFD) simulations incorporating actual furnace geometries and a detailed combustion and NOx emission prediction model this research aims to accurately quantify the effects of hydrogen blending. Experimental tests on furnaces using only natural gas confirmed the validity of these simulations. By providing precise predictions for temperature distribution and NOx emissions this approach reduces the need for extensive laboratory testing facilitates broader exploration of design modifications accelerates the design process and ultimately lowers product development costs.
The Current Status of Hydrogen Energy: An Overview
Sep 2023
Publication
Hydrogen is the most environmentally friendly and cleanest fuel that has the potential to supply most of the world's energy in the future replacing the present fossil fuel-based energy infrastructure. Hydrogen is expected to solve the problem of energy shortages in the near future especially in complex geographical areas (hills arid plateaus etc.) and harsh climates (desert ice etc.). Thus in this report we present a current status of achievable hydrogen fuel based on various scopes including production methods storage and transportation techniques the global market and the future outlook. Its objectives include analyzing the effectiveness of various hydrogen generation processes and their effects on the economy society and environment. These techniques are contrasted in terms of their effects on the environment manufacturing costs energy use and energy efficiency. In addition hydrogen energy market trends over the next decade are also discussed. According to numerous encouraging recent advancements in the field this review offers an overview of hydrogen as the ideal renewable energy for the future society its production methods the most recent storage technologies and transportation strategies which suggest a potential breakthrough towards a hydrogen economy. All these changes show that this is really a profound revolution in the development process of human society and has been assessed as having the same significance as the previous industrial revolution.
Research on the Dynamic Energy Conversion and Transmission Model of Renewable Energy DC Off-grid Hydrogen System
Sep 2024
Publication
The dynamic response characteristics between the multiple energy flows of electricity-hydrogen-heat in the renewable energy DC off-grid hydrogen production system are highly coupled and nonlinear which leads to the complexity of its energy conversion and transmission law. This study proposes a model to describe the dynamic nonlinear energy conversion and transmission laws specific to such systems. The model develops a nonlinear admittance framework and a conversion characteristic matrix for multi-heterogeneous energy flow subsystems based on the operational characteristics of each subsystem within the DC off-grid hydrogen production system. Building upon this foundation an energy hub model for the hydrogen production system is established yielding the electrical thermal and hydrogen energy outputs along with their respective conversion efficiencies for each subsystem. By discretizing time the energy flow at each time node within the hydrogen production system is computed revealing the system’s dynamic energy transfer patterns. Experiments were conducted using measured wind speed and irradiance data from a specific location in eastern China. Results from selected typical days were analyzed and discussed revealing that subsystem characteristics exhibit nonlinear variation patterns. This highlights the limitations of traditional models in accurately capturing these dynamics. Finally a simulation platform incorporating practical control methods was constructed to validate the model’s accuracy. Validation results demonstrate that the model possesses high accuracy providing a solid theoretical foundation for further in-depth analysis of DC off-grid hydrogen production systems.
Total Cost of Ownership Analysis for Hydrogen and Battery Powertrains: A Comparative Study in Finnish Heavy-duty Transport
Sep 2024
Publication
The road transport sector is one of the major contributors to greenhouse gas emissions as it still largely relies on traditional powertrain solutions. While some progress has been made in the passenger car sector with the diffusion of battery electric vehicles heavy-duty transport remains predominantly dependent on diesel internal combustion engines. This research aims to evaluate and compare three potential solutions for the decarbonisation of heavy-duty freight transport from an economic perspective: Battery Electric Trucks (BETs) Fuel Cell Electric Trucks (FCETs) and Hydrogen-fuelled Internal Combustion Engine Trucks (H2ICETs). The study focuses on the Finnish market and road network where affordable and low-carbon electricity creates an ideal environment for the development of alternative powertrain vehicles. The analysis employs the Total Cost of Ownership (TCO) method which allows for a comprehensive assessment of all cost components associated with the vehicles throughout their entire lifecycle encompassing both initial expenses and operational costs. Among the several factors affecting the results the impact of the three powertrain technologies on the admissible payloads has been taken into account. The study specifically focuses on the costs directly incurred by the truck owner. Additionally to evaluate the cost effectiveness of the proposed powertrain technologies under different scenarios a sensitivity analysis on electricity and hydrogen prices is conducted. The outcomes of this study reveal that no single powertrain solution emerges as universally optimal as the most cost-effective choice depends strongly on the truck type and its use (i.e. daily mileage). For relatively small trucks (18 t) covering short driving distances (approximately 100 to 200 km/day) BETs prove to be the best solution due to their higher efficiency and lower vehicle costs compared to FCETs. Conversely for larger trucks (42 and 76 t) engaged in longer hauls (>300 km/day) H2ICETs exhibit larger cost benefits due to their lower vehicle costs among the three options under investigation. Finally for small trucks (18 t) travelling long distances (200 km/day or more) FCETs represent a competitive choice due to their high efficiency and costeffective energy storage system. Considering future advancements in FCETs and BETs in terms of improved performance and reduced investment cost the fuel cell-based solution is expected to emerge as the best option across various combinations of truck sizes and daily mileages.
An Overview of the Photocatalytic Water Splitting over Suspended Particles
Jan 2021
Publication
The conversion of solar to chemical energy is one of the central processes considered in the emerging renewable energy economy. Hydrogen production from water splitting over particulate semiconductor catalysts has often been proposed as a simple and a cost-effective method for largescale production. In this review we summarize the basic concepts of the overall water splitting (in the absence of sacrificial agents) using particulate photocatalysts with a focus on their synthetic methods and the role of the so-called “co-catalysts”. Then a focus is then given on improving light absorption in which the Z-scheme concept and the overall system efficiency are discussed. A section on reactor design and cost of the overall technology is given where the possibility of the different technologies to be deployed at a commercial scale and the considerable challenges ahead are discussed. To date the highest reported efficiency of any of these systems is at least one order of magnitude lower than that deserving consideration for practical applications.
In-situ Direct Seawater Electrolysis Using Floating Platform in Ocean with Uncontrollable Wave Motion
Jun 2024
Publication
Direct hydrogen production from inexhaustible seawater using abundant offshore wind power offers a promising pathway for achieving a sustainable energy industry and fuel economy. Various direct seawater electrolysis methods have been demonstrated to be effective at the laboratory scale. However larger-scale in situ demonstrations that are completely free of corrosion and side reactions in fluctuating oceans are lacking. Here fluctuating conditions of the ocean were considered for the first time and seawater electrolysis in wave motion environment was achieved. We present the successful scaling of a floating seawater electrolysis system that employed wind power in Xinghua Bay and the integration of a 1.2 Nm3 h−1 -scale pilot system. Stable electrolysis operation was achieved for over 240 h with an electrolytic energy consumption of 5 kWh Nm−3 H2 and a high purity (>99.9%) of hydrogen under fluctuating ocean conditions (0~0.9 m wave height 0~15 m s−1 wind speed) which is comparable to that during onshore water electrolysis. The concentration of impurity ions in the electrolyte was low and stable over a long period of time under complex and changing scenarios. We identified the technological challenges and performances of the key system components and examined the future outlook for this emerging technology.
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