Publications

Importing substantial amount of green hydrogen from countries like South Africa which have abundant solar and wind potentials to replace fossil fuels has attracted interest in developed regions. This study analyses South African strategies for improving and decarbonizing the power sector while also producing hydrogen for export. These strategies include the Integrated Resource Plan the Transmission Development Plan Just Energy Transition and Hydrogen Society Roadmap for grid connected hydrogen production in 2030. Results based on an hourly resolution optimisation in Plexos indicate that annual grid-connected hydrogen production of 500 kt can lead to a 20–25% increase in the cost of electricity in scenarios with lower renewable energy penetration due to South African emission constraints by 2030. While the price of electricity is still in acceptable range and the price of hydrogen can be competitive on the international market (2–3 USD/kgH2 for production) the emission factor of this hydrogen is higher than the one of grey hydrogen ranging from 13 to 24 kgCO2/kgh2. When attempting to reach emission factors based on EU directives the three policy roadmaps become unfeasible and free capacity expansion results in significant sixteen-fold increase of wind and seven-fold increase in solar installations compared to 2023 levels by 2030 in South Africa.

The global energy sector accounts for ~75% of total greenhouse gas (GHG) emissions. Low-carbon energy carriers such as hydrogen are seen as necessary to enable an energy transition away from the current fossilderived energy paradigm. Thus the hydrogen economy concept is a key part of decarbonizing the global en ergy system. Hydrogen storage and transport are two of key elements of hydrogen economy. Hydrogen can be stored in various forms including its gaseous liquid and solid states as well as derived chemical molecules. Among these liquid hydrogen due to its high energy density ambient storage pressure high hydrogen purity (no contamination risks) and mature technology (stationary liquid hydrogen storage) is suitable for the transport of large-volumes of hydrogen over long distances and has gained increased attention in recent years. However there are critical obstacles to the development of liquid hydrogen systems namely an energy intensive liquefaction process (~13.8 kWh/kgLH2) and high hydrogen boil-off losses (liquid hydrogen evaporation during storage 1–5% per day). This review focuses on the current state of technology development related to the liquid hydrogen supply chain. Hydrogen liquefaction cryogenic storage technologies liquid hydrogen transmission methods and liquid hydrogen regasification processes are discussed in terms of current industrial applications and underlying technologies to understand the drivers and barriers for liquid hydrogen to become a commer cially viable part of the emerging global hydrogen economy. A key finding of this technical review is that liquid hydrogen can play an important role in the hydrogen economy - as long as necessary technological transport and storage innovations are achieved in parallel to technology demonstrations and market development efforts by countries committed liquid hydrogen as part of their hydrogen strategies.

Switching to renewable resources for hydrogen production is essential. Present hydrogen resources such as coal oil and natural gas are depleted and rapidly moving to a dead state and they possess a high carbon footprint. Wastewater is a promising avenue in searching for a renewable hydrogen production resource. Profuse techniques are preferred for hydrogen production. Among them electrolysis is great with wastewater against biological processes by hydrogen purity. Present obstacles behind the process are conversion efficiency intensive energy and cost. This review starts with hydrogen demand wastewater availability and their H2 potential then illustrates the three main types of electrolysis. The main section highlights renewable energy-assisted electrolysis because of its low carbon footprint and zero emission potential for various water electrolysis. High-temperature steam solid oxide electrolysis is a viable option for future scaling due to the versatile adoption of photo electric and thermal energy. A glance at some effective aspirations to large-scale H2 economics such as co-generation biomass utilization Microbial electrolysis waste to low-cost green electrode Carbon dioxide hydrogenation and minerals recovery. This study gives a broader view of facing challenges via versatile future perspectives to eliminate the obstacles above. renewable green H2 along with a low carbon footprint and cost potential to forward the large-scale wastewater electrolysis H2 production in addition to preserving the environment from wastewater and fossil fuel. Geographical and seasonal availability constraints are unavoidable; therefore energy storage and coupling of power sources is essential to attain consistent supply. The lack of regulations and policies supporting the development and adoption of these technologies did not reduce the gap between research and implementation. Life cycle assessment of this electrolysis process is rarely available so we need to focus on the natural effect of this process on the environment.

The iron and steel industry (ISI) plays a significant role in carbon emissions contributing approximately 15% of the nation’s total emissions in China. Transitioning to low-carbon practices is crucial for achieving the country’s carbon neutrality goals. This paper reviews the current state of China’s ISI and assesses the feasibility of various decarbonization technologies including hydrogen utilization biomass substitution zero-carbon electricity Carbon Capture Utilization and Storage (CCUS) as well as their combinations. The blast furnace–basic oxygen furnace (BF-BOF) process currently dominates the industry with an overwhelming share of around 90% presenting significant challenges for decarbonization. In contrast the Direct Reduced Iron–Electric Arc Furnace (DRI-EAF) process is still at the demonstration project stage but it is rapidly growing and shows great potential for achieving net-zero emissions. Electric arc furnaces (EAFs) that use scrap steel account for about 9% of production and have the lowest energy consumption. However their production capacity is limited by the availability of scrap steel. Among numerous options blue hydrogen carbon-neutral biomass and CCUS technologies have relatively low costs and high technological maturity. Nevertheless no single technology can currently achieve deep decarbonization while significantly reducing costs. The nation needs to select the most suitable decarbonization strategies based on geographical location infrastructure and economic conditions. The government should enact corresponding policies provide economic incentives and ensure mitigation of the environmental and social impacts during the decarbonization transition.

Many developing countries seek to participate in the emerging global green hydrogen industry not only as exporters of green hydrogen and its derivatives to Europe and the Far East but also to use it for their own energy security and green transition. They hope that new development paths will lead to late-comer industrialisation. This article assesses corresponding prospects in Chile and Namibia two countries that pursue particularly ambitious plans on green hydrogen. To better understand the chances for path creation ex ante the authors draft an innovative framework that refers to context factors – that is structure – and three types of transformative agency. Against the backdrop of information from secondary sources and a series of expert interviews they uncover sound institutional reforms and initiatives of place-based leadership to promote the green hydrogen industry. However Chile and Namibia lack Schumpeterian entrepreneurship. It therefore remains to be seen whether new development paths will be inclusive contributing to in-country development. Typical downsides of extractive industries in resource peripheries might occur.

The hydrogen internal combustion engine (H2-ICE) is proposed as a robust and viable solution to decarbonise the heavy-duty on- and off-road as well as the light-duty automotive sectors of the transportation markets and is therefore the subject of rapidly growing research interest. With the potential for engine performance improvement by controlling the internal mixture formation and avoiding combustion anomalies hydrogen direct injection (H2DI) is a promising combustion mode. Furthermore the H2-ICE poses an attractive proposition for original equipment manufacturers (OEMs) and their suppliers since the fundamental base engine design components and manufacturing processes are largely unchanged. Nevertheless to deliver the highest thermal efficiency and zero-harm levels of tailpipe emissions moderate adaptations are needed to the engine control air path fuel injection and ignition systems. Therefore in this article critical design features fuel-air mixing combustion regimes and exhaust after-treatment systems (EATS) for H2DI engines are carefully assessed.

Today the hydrogen is considered an essential element in speeding up the energy transition and generate important environmental benefits. Not all hydrogen is the same though. The “green hydrogen” which is produced using renewable energy and electrolysis to split water is really and completely sustainable for stationary and mobile applications. This paper is focused on the techno-economic analysis of an on-site hydrogen refueling station (HRS) in which the green hydrogen production is assured by a PV plant that supplies electricity to an alkaline electrolyzer. The hydrogen is stored in low pressure tanks (200 bar) and then is compressed at 900 bar for refueling FCHVs by using the innovative technology of the ionic compressor. From technical point of view the components of the HRS have been sized for assuring a maximum capacity of 450 kg/day. In particular the PV plant (installed in the south of Italy) has a size of 8MWp and supplies an alkaline electrolyzer of 2.1 MW. A Li-ion battery system (size 3.5 MWh) is used to store the electricity surplus and the grid-connection of the PV plant allows to export the electricity excess that cannot be stored in the battery system. The economic analysis has been performed by estimating the levelized cost of hydrogen (LCOH) that is an important economic indicator based on the evaluation of investment operational & maintenance and replacement costs. Results highlighted that the proposed on-site configuration in which the green hydrogen production is assured is characterized by a LCOH of 10.71 €/kg.

This paper presents a comprehensive safety assessment of hydrogen production using Alkaline Water Electrolysis (AWE). The study utilizes various risk assessment methodologies including Hazard Identification (HAZID) What-If analysis Fault Tree Analysis (FTA) Event Tree Analysis (ETA) and Bow Tie analysis to systematically identify and evaluate potential hazards associated with the AWE process. Key findings include the identification of critical hazards such as hydrogen leaks oxygen-related risks and maintenance challenges. The assessment emphasizes the importance of robust safety measures including preventive and mitigative strategies to manage these risks effectively. Consequence modeling highlights significant threat zones for thermal radiation and explosion risks underscoring the need for comprehensive safety protocols and emergency response plans. This work contributes valuable insights into hydrogen safety providing a framework for risk assessment and mitigation in hydrogen production facilities crucial for the safe and sustainable development of hydrogen infrastructure in the global energy transition.

Innovative approaches on clean alternative energy sources are important for future decarbonization. Electrification and hydrogen energy are crucial pathways for decarbonization in both transportation and buildings. However life-cycle stage-wise carbon intensity is still unclear for both hydrogen- and electricity-driven energy. Furthermore systematic evaluation on low-carbon transition pathways is insufficient specifically within the Internet of Energy that interfaces hydrogen and electricity. Here a generic approach is proposed for quantifying life-cycle stage-wise carbon intensity of both hydrogen- and electricity-driven energy internets. Life-cycle decarbonization effects on vehicle pathways are compared with traditional vehicles with internal-combustion engines. Techno-economic and environmental feasibility of the future advanced hydrogen-driven Internet of Energy is analyzed based on net present value. The region-wise carbon-intensity map and associated decarbonization strategies will help researchers and policymakers in promoting sustainable development with the hydrogen economy.

This study introduces a novel hybrid solar–biomass cogeneration power plant that efficiently produces heat electricity carbon dioxide and hydrogen using concentrated solar power and syngas from cotton stalk biomass. Detailed exergy-based thermodynamic economic and environmental analyses demonstrate that the optimized system achieves an exergy efficiency of 48.67% and an exergoeconomic factor of 80.65% and produces 51.5 MW of electricity 23.3 MW of heat and 8334.4 kg/h of hydrogen from 87156.4 kg/h of biomass. The study explores four scenarios for green hydrogen production pathways including chemical looping reforming and supercritical water gasification highlighting significant improvements in levelized costs and the environmental impact compared with other solar-based hybrid systems. Systems 2 and 3 exhibit superior performance with levelized costs of electricity (LCOE) of 49.2 USD/MWh and 55.4 USD/MWh and levelized costs of hydrogen (LCOH) of between 10.7 and 19.5 USD/MWh. The exergoenvironmental impact factor ranges from 66.2% to 73.9% with an environmental impact rate of 5.4–7.1 Pts/MWh. Despite high irreversibility challenges the integration of solar energy significantly enhances the system’s exergoeconomic and exergoenvironmental performance making it a promising alternative as fossil fuel reserves decline. To improve competitiveness addressing process efficiency and cost reduction in solar concentrators and receivers is crucial.