Publications
Experimental Study of the Mitigation of Hydrogen-Air Explosions by Aqueous Foam
Sep 2023
Publication
The development of hydrogen production technologies as well as new uses represents an opportunity both to accelerate the ecological transition and to create an industrial sector. However the risks associated with the use of hydrogen must not be overlooked. The mitigation of a hydrogen explosion in an enclosure is partly based on prevention strategies such as detection and ventilation but also on protection strategies such as explosion venting. However in several situations such as in highly constrained urban environments the discharge of the explosion through blast walls could generate significant overpressure effects outside the containment which are unacceptable. Thus having alternative mitigation solutions can make the effects of the explosion acceptable by reducing the flame speed and the overpressure loading or suppressing the secondary explosion. The objective of this paper is to present the experimental study of the mitigation of hydrogen-air deflagration in a 4 m3 vented enclosure by injection of aqueous foam. After a description of the experimental set-up the main experimental results are presented showing the influence of aqueous foam on flame propagation (Fig. 1). Different foam expansion ratios were investigated. An interpretation of the mitigating effect of foam on the explosion effects is proposed based on the work of Kichatov [5] and Zamashchikov [2].
The Technopolitics of Hydrogen: Arab Gulf States' Pursuit of Significance in a Climate-Constrained World
Nov 2024
Publication
Despite uncertainties surrounding the hydrogen economy’s emergence in terms of technological innovation production storage and transport policy and regulation economic viability and environmental impact coun tries worldwide actively pursue initiatives to engage in this critical energy transition. Politicians analysts and global experts see ‘clean’ hydrogen as the ultimate solution for addressing the climate crisis. This optimism is shared by several major oil and gas-exporting nations which are investing heavily in hydrogen infrastructure to establish themselves as future global hubs. Oman Saudi Arabia and the United Arab Emirates (UAE) are especially well-positioned benefiting from strategic advantages over other hydrogen-producing regions in the Global South. Advocates in these countries view hydrogen as a potential ‘silver bullet’ for sustaining political and economic influence in a world increasingly shaped by climate constraints. Western technology and expertise play a significant role in supporting these efforts. By using various qualitative methods this paper employs and expand the concept of technopolitics to evaluate the role of industrialized nations in endorsing the Gulf states’ authoritarian top-down techno-optimistic approach to their sustainability agenda.
How Would Structural Change in Electricity and Hydrogen End Use Impact Low-Carbon Transition of an Energy System? A Case Study of China
Feb 2024
Publication
Driven by global targets to reduce greenhouse gas emissions energy systems are expected to undergo fundamental changes. In light of carbon neutrality policies China is expected to significantly increase the proportion of hydrogen and electricity in its energy system in the future. Nevertheless the future trajectory remains shrouded in uncertainty. To explore the potential ramifications of varying growth scenarios pertaining to hydrogen and electricity on the energy landscape this study employs a meticulously designed bottom-up model. Through comprehensive scenario calculations the research aims to unravel the implications of such expansions and provide a nuanced analysis of their effects on the energy system. Results show that with an increase in electrification rates cumulative carbon dioxide emissions over a certain planning horizon could be reduced at the price of increased unit reduction costs. By increasing the share of end-use electricity and hydrogen from 71% to 80% in 2060 the unit carbon reduction cost will rise by 17%. Increasing shares of hydrogen could shorten the carbon emission peak time by approximately five years but it also brings an increase in peak shaving demand.
Synergy-based Hydrogen Pricing in Hydrogen-Integrated Electric Power System: Sensititivy Analysis
Nov 2024
Publication
Hydrogen price significantly impacts its potential as a viable alternative in the sustainable energy transition. This study introduces a synergy-based Hydrogen Pricing Mechanism (HPM) within an integrated framework. The HPM leverages synergy between a Renewable-Penetrated Electric Power System (RP-EPS) and a Hydrogen Energy System (HES). Utilizing the Alternating Direction Method of Multipliers (ADMM) it facilitates data exchange quantifying integration levels and simplifying the complexities. The study assesses the HPM’s operational sensitivity across various scenarios of hydrogen generation transportation and storage. It also evaluates the benefits of synergy-based versus stand-alone HPMs. Findings indicate that the synergy-based HPM effectively integrates infrastructure and operational improvements from both EPS and HES leading to optimized hydrogen pricing.
A Hydrogen Vision for the UK
Apr 2023
Publication
This report shows how the infrastructure that exists today can evolve from one based on the supply of fossil fuels to one providing the backbone of a clean hydrogen system. The ambitious government hydrogen targets across the UK will only be met with clarity focus and partnership. The gas networks are ready to play their part in the UK’s energy future. They have a plan know what is needed to deliver it and are taking the necessary steps to do just that.
SSEXHY Experimental Results on Pressure Dynamics from Head-on Reflections of Hydrogen Flames
Sep 2023
Publication
In the past few years CEA has been fully involved at both experimental and modeling levels in projects related to hydrogen safety in nuclear and chemical industries and has carried out a test program using the experimental bench SSEXHY (Structure Submitted to an EXplosion of HYdrogen) in order to build a database of the deformations of simple structures following an internal hydrogen explosion. Different propagation regimes of explosions were studied varying from detonations to slow deflagrations.<br/>During the experimental campaign it was found that high-speed deflagrations corresponding to relatively poor hydrogen-air mixtures resulted in higher specimen deformation compared to those related to detonations of nearly stoichiometric mixtures. This paper explains this counter-intuitive result from qualitative and quantitative points of view. It is shown that the overpressure and impulse from head-on reflections of hydrogen flames corresponding to poor mixtures of specific concentrations could have very high values at the tube end.
Towards a Resilience Evaluation Framework for Hydrogen Supply Chains: A Systematic Literature Review and Future Research Agenda
Dec 2024
Publication
Hydrogen energy is crucial for achieving net zero targets making the resilience of hydrogen supply chains (HSCs) increasingly important. Understanding current research on HSC resilience is key to enhancing it. Few studies summarise HSC resilience evaluation methods and link them to the general supply chain resilience and complex adaptive system (CAS) evaluation approaches. This study addresses this gap by systematically reviewing the literature on HSC resilience evaluations defining HSC resilience and conducting content analysis. It proposes a conceptual framework integrating technical operational and organisational perspectives. Each perspective is further subdivided based on the course of events resulting in a system-based HSC resilience evaluation frame work with three layers of analysis. By linking HSC indicators with CAS theory and supply chain performance metrics the study offers novel insights into HSC resilience evaluations identifies research gaps provides prac tical guidance for practitioners and outlines future research directions for advancing HSC resilience understanding.
Industrial Waste Gases as a Resource for Sustainable Hydrogen Production: Resource Availability, Production Potential, Challenges, and Prospects
May 2024
Publication
Industrial sectors pivotal for the economic prosperity of nations rely heavily on affordable reliable and environmentally friendly energy sources. Industries like iron and steel oil refineries and coal-fired power plants while instrumental to national economies are also the most significant contributors to waste gases that contain substantial volumes of carbon monoxide (CO). CO can be converted to a highly efficient and carbon free fuel hydrogen (H2) through a well-known water gas shift reaction. However the untapped potential of H2 from waste industrial streams is yet to be explored. This is the first article that investigates the potential of H2 production from industrial waste gases. The available resource (i.e. CO) and its H2 production potential are estimated. The article also provides insights into the principal challenges and potential avenues for long-term adoption. The results showed that 249.14 MTPY of CO are available to produce 17.44 MTPY of H2 annually. This suggests a significant potential for H2 production from waste gases to revolutionize industrial waste management and contribute significantly towards Sustainable Development Goals 7 9 and 13ensuring access to affordable reliable sustainable and modern energy for all and taking decisive climate action respectively.
Towards a Multi-color Hydrogen Production Network? Competing Imaginaries of Development in Northern Patagonia, Argentina
Feb 2024
Publication
Green hydrogen has recently gained importance as a key element in the transition to a low-carbon energy future sparking a boom in possible production regions. This article aims at situating incipient hydrogen production in the Argentine province of Río Negro within a global production network (GPN). The early configuration of the hydrogen-GPN includes several stakeholders and is contested in many ways. To explore the possible materialization of the hydrogen economy in Argentina this article links GPN literature to the concept of sociotechnical imaginaries. In so doing this study finds three energy imaginaries linked to hydrogen development: First advocates of green hydrogen (GH2) project a sociotechnical imaginary in which GH2 is expected to promote scientific and technological progress. Second proponents of blue hydrogen point to Vaca Muerta and the role of natural gas for energy autonomy. Third opponents of the GH2 project question the underlying growth and export model emphasizing conservation and domestic energy sovereignty. The competition between different capital fractions i.e. green and fossil currently poses the risk of pro-fossil path decisions and lock-in effects. Current power constellations have led to the replacement of green with low-emission resulting in the promotion of multi-colored hydrogen. This is particularly evident in the draft for the new national hydrogen law and the actors involved in defining the national hydrogen strategy. The conceptual combination of actors and their interests their current power relations and the sociotechnical imaginaries they deploy illustrates how Argentina's energy future is already being shaped today.
Profitability Model of Green Hydrogen Production on an Existing Wind Power Plant Location
Feb 2024
Publication
This paper presents a new economic profitability model for a power-to-gas plant producing green hydrogen at the site of an existing wind power plant injected into the gas grid. The model is based on a 42 MW wind power plant for which an optimal electrolyzer of 10 MW was calculated based on the 2500 equivalent full load hours per year and the projection of electricity prices. The model is calculated on an hourly level for all variables of the 25 years of the model. With the calculated breakeven electricity price of 74.23 EUR/MWh and the price of green hydrogen production of 99.44 EUR/MWh in 2045 the wind power plant would produce 22410 MWh of green hydrogen from 31% of its total electricity production. Green hydrogen injected into the gas system would reduce the level of CO2 emissions by 4482 tons. However with the projected prices of natural gas and electricity the wind power plant would cover only 20% of the income generated by the electricity delivered to the grid by producing green hydrogen. By calculating different scenarios in the model the authors concluded that the introduction of a premium subsidy model is necessary to accelerate deployment of electrolyzers at the site of an existing wind power plant in order to increase the wind farm profitability.
Hydrogen Production from Municipal Waste and Low Grade Lignite Blend
Nov 2024
Publication
The updraft rotating bed gasifier (URBG) offers a sustainable solution for waste-to-energy conversion utilizing low-grade lignite and municipal solid waste (MSW) from metropolitan dumping sites. This study investigates the co-gasification of lignite with various MSW components demonstrating a significant enhancement in gasification efficiency due to the synergistic effects arising from their higher hydrogen-to-carbon (H/C) ratios. We find feedstock blending is key to maximizing gasification efficiency from 11% to 52% while reducing SO emissions from 739 mg/kg to 155 mg/kg. Increasing the combustion zone temperature to 1100 K resulted in a peak hydrogen yield which was 19% higher than at 800 K. However steam management is complicated as increasing it improves hydrogen fraction in produced gas but gasification efficiency is compromised. These findingsshowcase the URBG’s potential to address both energy production and waste management challenges guiding fossil-reliant regions toward a more sustainable energy future.
Numerical Simulation of Transition to Detonation in a Hydrogen-air Mixture Due to Shock Wave Focusing on a 90-Deg Wedge
Sep 2023
Publication
The interaction of a shock wave with a specific angle or concave wall due to its reflection and focusing is a way to onset the detonation provided sufficiently strong shock wave. In this work we present numerical simulation results of the detonation initiation due to the shock reflection and focusing in a 90-degree wedge for mixtures of H2 and air. The code used was ddtFoam [1–3] that is a component of the larger OpenFOAM open-source CFD package of density-based code for solving the unsteady compressible Navier-Stokes equations. The numerical model represents the 2-D geometry of the experiments performed by Rudy [4]. The numerical results revealed three potential scenarios in the corner after reflection: shock wave reflection without ignition deflagrative ignition with intermediate transient regimes with a delayed transition to detonation in lagging combustion zone at around 1.8 mm from the apex of the wedge and ignition with an instantaneous transition to detonation with the formation of the detonation wave in the corner tip. In the experimental investigation the transition velocity for the stoichiometric mixture was approximately 715 m/s while in the numerical simulation the transition velocity for the stoichiometric mixture was 675.65 m/s 5.5% decrease in velocity.
Study on the Application of a Multi-Energy Complementary Distributed Energy System Integrating Waste Heat and Surplus Electricity for Hydrogen Production
Feb 2024
Publication
To improve the recovery of waste heat and avoid the problem of abandoning wind and solar energy a multi-energy complementary distributed energy system (MECDES) is proposed integrating waste heat and surplus electricity for hydrogen storage. The system comprises a combined cooling heating and power (CCHP) system with a gas engine (GE) solar and wind power generation and miniaturized natural gas hydrogen production equipment (MNGHPE). In this novel system the GE’s waste heat is recycled as water vapor for hydrogen production in the waste heat boiler while surplus electricity from renewable sources powers the MNGHPE. A mathematical model was developed to simulate hydrogen production in three building types: offices hotels and hospitals. Simulation results demonstrate the system’s ability to store waste heat and surplus electricity as hydrogen thereby providing economic benefit energy savings and carbon reduction. Compared with traditional energy supply methods the integrated system achieves maximum energy savings and carbon emission reduction in office buildings with an annual primary energy reduction rate of 49.42–85.10% and an annual carbon emission reduction rate of 34.88–47.00%. The hydrogen production’s profit rate is approximately 70%. If the produced hydrogen is supplied to building through a hydrogen fuel cell the primary energy reduction rate is further decreased by 2.86–3.04% and the carbon emission reduction rate is further decreased by 12.67–14.26%. This research solves the problem of waste heat and surplus energy in MECDESs by the method of hydrogen storage and system integration. The economic benefits energy savings and carbon reduction effects of different building types and different energy allocation scenarios were compared as well as the profitability of hydrogen production and the factors affecting it. This has a positive technical guidance role for the practical application of MECDESs.
Optimizing Sustainable Energy Systems: A Comparative Study of Geothermal-powered Desalination for Green Hydrogen Production
Oct 2024
Publication
The synergy between hydrogen and water is crucial in moving towards a sustainable energy future. This study explores the integration of geothermal energy with desalination and hydrogen production systems to address water and clean energy demands. Two configurations one using multi-effect distillation (MED) and the other reverse osmosis (RO) were designed and compared. Both configurations utilized geothermal energy with MED directly using geothermal heat and RO converting geothermal energy into electricity to power desalination. The systems are evaluated based on various performance indicators including net power output desalinated water production hydrogen production exergy efficiency and levelized costs. Multi-objective optimization using an artificial neural network (ANN) and genetic algorithm (GA) was conducted to identify optimal operational conditions. Results highlighted that the RO-based system demonstrated higher water production efficiency achieving a broader range of optimal solutions and lower levelized costs of water (LCOW) and hydrogen production while the MED-based system offered economic advantages under specific conditions. A case study focused on Canada illustrated the potential benefits of these systems in supporting hydrogen-powered vehicles and residential water needs emphasizing the significant impact of using high-quality desalinated water to enhance the longevity and efficiency of proton exchange membrane electrolyzers (PEME). This research provides valuable insights into the optimal use of geothermal energy for sustainable water and hydrogen production.
Hydrogen Engine Conversion Aspects
Oct 2024
Publication
The transition from traditional petrol-based combustion engines to hydrogen-powered systems represents a promising advancement in sustainable and clean energy solutions. This review paper explores the intricacies of converting a conventional internal combustion engine to operate on hydrogen gas. Key topics include the performance limitations of hydrogen engines the role of water injection in combustion modulation and the investigation of direct injection and port injection systems. This review also examines challenges associated with lean and rich mixtures risks of backfire and pre-ignition and the conversion’s overall impact on engine performance and longevity. Additionally this paper discusses hydrogen lubrication to prevent mechanical wear and addresses emission-related considerations.
The Integration of Thermal Energy Storage Within Metal Hydride Systems: A Comprehensive Review
Dec 2024
Publication
Hydrogen storage technologies are key enablers for the development of low-emission sustainable energy supply chains primarily due to the versatility of hydrogen as a clean energy carrier. Hydrogen can be utilized in both stationary and mobile power applications and as a lowenvironmental-impact energy source for various industrial sectors provided it is produced from renewable resources. However efficient hydrogen storage remains a significant technical challenge. Conventional storage methods such as compressed and liquefied hydrogen suffer from energy losses and limited gravimetric and volumetric energy densities highlighting the need for innovative storage solutions. One promising approach is hydrogen storage in metal hydrides which offers advantages such as high storage capacities and flexibility in the temperature and pressure conditions required for hydrogen uptake and release depending on the chosen material. However these systems necessitate the careful management of the heat generated and absorbed during hydrogen absorption and desorption processes. Thermal energy storage (TES) systems provide a means to enhance the energy efficiency and cost-effectiveness of metal hydride-based storage by effectively coupling thermal management with hydrogen storage processes. This review introduces metal hydride materials for hydrogen storage focusing on their thermophysical thermodynamic and kinetic properties. Additionally it explores TES materials including sensible latent and thermochemical energy storage options with emphasis on those that operate at temperatures compatible with widely studied hydride systems. A detailed analysis of notable metal hydride–TES coupled systems from the literature is provided. Finally the review assesses potential future developments in the field offering guidance for researchers and engineers in advancing innovative and efficient hydrogen energy systems.
Multi-Physics Digital Model of an Aluminum 2219 Liquid Hydrogen Aircraft Tank
Feb 2024
Publication
Future liquid hydrogen-powered aircraft requires the design and optimization of a large number of systems and subsystems with cryogenic tanks being one of the largest and most critical. Considering previous space applications these tanks are usually stiffened by internal members such as stringers frames and stiffeners resulting in a complex geometry that leads to an eventual reduction in weight. Cryogenic tanks experience a variety of mechanical and thermal loading conditions and are usually constructed out of several different materials. The complexity of the geometry and the loads highlights the necessity for a computational tool in order to conduct analysis. In this direction the present work describes the development of a multi-physics finite element digital simulation conducting heat transfer and structural analysis in a fully parametric manner in order to be able to support the investigation of different design concepts materials geometries etc. The capabilities of the developed model are demonstrated by the design process of an independent-type aluminum 2219 cryogenic tank for commuter aircraft applications. The designed tank indicates a potential maximum take-off weight reduction of about 8% for the commuter category and demonstrates that aluminum alloys are serious candidate materials for future aircraft.
Hydrogen Storage Performance During Underground Hydrogen Storage in Depleted Gas Reservoirs: A Review
Mar 2024
Publication
Hydrogen has emerged as a promising alternative to meet the growing demand for sustainable and renewable energy sources. Underground hydrogen storage (UHS) in depleted gas reservoirs holds significant potential for large-scale energy storage and the seamless integration of intermittent renewable energy sources due to its capacity to address challenges associated with the intermittent nature of renewable energy sources ensuring a steady and reliable energy supply. Leveraging the existing infrastructure and well-characterized geological formations depleted gas reservoirs offer an attractive option for large-scale hydrogen storage implementation. However significant knowledge gaps regarding storage performance hinder the commercialization of UHS operation. Hydrogen deliverability hydrogen trapping and the equation of state are key areas with limited understanding. This literature review critically analyzes and synthesizes existing research on hydrogen storage performance during underground storage in depleted gas reservoirs; it then provides a high-level risk assessment and an overview of the techno-economics of UHS. The significance of this review lies in its consolidation of current knowledge highlighting unresolved issues and proposing areas for future research. Addressing these gaps will advance hydrogen-based energy systems and support the transition to a sustainable energy landscape. Facilitating efficient and safe deployment of UHS in depleted gas reservoirs will assist in unlocking hydrogen’s full potential as a clean and renewable energy carrier. In addition this review aids policymakers and the scientific community in making informed decisions regarding hydrogen storage technologies.
A Comprehensive Overview of Technologies Applied in Hydrogen Valleys
Dec 2024
Publication
Hydrogen valleys are encompassed within a defined geographical region with various technologies across the entire hydrogen value chain. The scope of this study is to analyze and assess the different hydrogen technologies for their application within the hydrogen valley context. Emphasizing on the coupling of renewable energy sources with electrolyzers to produce green hydrogen this study is focused on the most prominent electrolysis technologies including alkaline proton exchange membrane and solid oxide electrolysis. Moreover challenges related to hydrogen storage are explored alongside discussions on physical and chemical storage methods such as gaseous or liquid storage methanol ammonia and liquid organic hydrogen carriers. This article also addresses the distribution of hydrogen within valley operations especially regarding the current status on pipeline and truck transportation methods. Furthermore the diverse applications of hydrogen in the mobility industrial and energy sectors are presented showcasing its potential to integrate renewable energy into hard-to-abate sectors.
Economic Analysis of Hydrogen Energy Systems: A Global Perspective
Aug 2024
Publication
In the realm of renewable energy the integration of wind power and hydrogen energy systems represents a promising avenue towards environmental sustainability. However the development of cost-effective hydrogen energy storage solutions is crucial to fully realize the potential of hydrogen as a renewable energy source. By combining wind power generation with hydrogen storage a comprehensive hydrogen energy system can be established. This study aims to devise a physiologically inspired optimization approach for designing a standalone wind power producer that incorporates a hydrogen energy system on a global scale. The optimization process considers both total cost and capacity loss to determine the optimal configuration for the system. The optimal setup for an off-grid solution involves the utilization of eight distinct types of compact horizontal-axis wind turbines. Additionally a sensitivity analysis is conducted by varying component capital costs to assess their impact on overall cost and load loss. Simulation results indicate that at a 15% loss the cost of energy (COE) is $1.3772 while at 0% loss it stands at $1.6908. Capital expenses associated with wind turbines and hydrogen storage systems significantly contribute to the overall cost. Consequently the wind turbine-hydrogen storage system emerges as the most cost-effective and reliable option due to its low cost of energy.
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