Publications

Water management is crucial for the performance of anion exchange membrane water electrolyzers (AEM-WEs) to maintain membrane hydration and enable phase separation between hydrogen gas and liquid water. Therefore careful material selection for the anode and cathode is essential to enhance reactant/product transport and optimize water management under ‘dry cathode’ conditions. This study investigates the wetting characteristics of two commercially available porous transport layers (PTLs) used in AEM-WE: carbon paper and carbon paper with a microporous layer (MPL). Wettability was measured under static quasi-static and dynamic conditions to assess the effect of water and electrolytes (NaOH KOH K2CO3) across concentrations (up to 1 M) and operational temperatures (20 °C to 92 °C). Carbon paper exhibits mild hydrophobicity (advancing contact angles of ∼120° however with receding contact angle ∼0°) whereas carbon paper with MPL demonstrates superhydrophobicity (advancing and receding contact angles >145° and low contact angle hysteresis) maintaining a stable Cassie-Baxter wetting state. Dynamic wetting experiments confirmed the robustness of the superhydrophobicity in carbon paper with MPL facilitating phase separation between hydrogen gas and liquid water. The presence of supporting electrolytes did not significantly affect wettability and the materials retained hydrophobic properties across different temperatures. These findings highlight the importance of MPLs in optimizing water transport and gas rejection within AEM-WEs ensuring efficient and stable operation under “dry cathode” conditions. These PTLs (with and without the addition of the MPL) were integrated into AEM-WE and polarization curves were run. Preliminary data in a specific condition suggested the presence of the MPL within the PTL enhance AEM-WE performance.

Within energy system analysis there is discourse regarding the role and economic benefits of nuclear energy in terms of overall system costs. The reported findings range from considerable drawbacks to substantial benefits depending on the chosen models scenarios and underlying assumptions. This article addresses existing gaps by demonstrating how subtle variations in model assumptions significantly impact analysis outcomes. Historically uncertainties associated with nuclear energy costs have been well documented whereas renewable energy costs have steadily declined and have been relatively predictable. However as land availability increasingly constrains future renewable expansion development is shifting from onshore to offshore locations where cost uncertainties are greater and anticipated cost reductions are less reliable. This study emphasizes this fundamental shift highlighting how uncertainties in future renewable energy costs could strengthen the economic case of nuclear energy within fully integrated sector-coupled energy systems especially when the costs of all technologies and weather conditions are set in the moderate range. Focusing specifically on Denmark this article presents a thorough sensitivity analysis of renewable energy costs and weather conditions within anticipated future ranges providing a nuanced perspective on the role of nuclear energy. Ultimately the findings underscore that when examining total annual system costs the differences between scenarios with low and high nuclear energy shares are minimal and are within ±5 % for the baseline assumptions while updated adjustments reduce this variation to ±1 %.

Hydrogen production from water electrolysis can not only reduce greenhouse gas emissions but also has abundant raw materials which is one of the ideal ways to produce hydrogen from new energy. The hydrogen production power supply is the core component of the new energy electrolytic water hydrogen production device and its characteristics have a significant impact on the efficiency and purity of hydrogen production and the service life of the electrolytic cell. In essence the DC/DC converter provides the large current required for hydrogen production. For the converter its input still needs the support of a DC power supply. Given the maturity and technical characteristics of new energy power generation integrating energy storage into offshore energy systems enables stable power supply. This configuration not only mitigates energy fluctuations from renewable sources but also further reduces electrolysis costs providing a feasible pathway for large-scale commercialization of green hydrogen production. First this paper performs a simulation analysis on the wind–solar hybrid energy storage power generation system to demonstrate that the wind–solar–storage system can provide stable power support. It places particular emphasis on the significance of hydrogen production power supply design—this focus stems primarily from the fact that electrolyzers impose specific requirements on high operating current levels and low current ripple which exert a direct impact on the electrolyzer’s service life hydrogen production efficiency and operational safety. To suppress the current ripple induced by high switching frequency and high output current traditional approaches typically involve increasing the output inductor. However this method substantially increases the volume and weight of the device reduces the rate of current change and ultimately results in a degradation of the system’s dynamic response performance. To this end this paper focuses on developing a virtual impedance control technology aiming to reduce the ripple amplitude while avoiding an increase in the filter inductor. Owing to constraints in current experimental conditions this research temporarily relies on simulation data. Specifically a programmable power supply is employed to simulate the voltage output of the wind–solar–storage hybrid system thereby bringing the simulation as close as possible to the actual operating conditions of the wind–solar–storage hydrogen production system. The experimental results demonstrate that the proposed method can effectively suppress the ripple amplitude maintain high operating efficiency and ultimately meet the expected research objectives. That makes it particularly suitable as a high-quality power supply for offshore hydrogen production systems that have strict requirements on volume and weight.

Achieving net-zero emissions requires major changes across a nation’s economy energy and land systems particularly due to sectors where emissions are difficult to eliminate. Here we adapt two global scenarios from the International Energy Agency—the net-zero emissions by 2050 and the Stated Policies Scenario—using an integrated numerical economic-energy model tailored to Australia. We explore how emissions may evolve by sector and identify key technologies for decarbonisation. Our results show that a rapid shift to near-zero emissions electricity is central to reducing costs and enabling wider emissions reductions. From 2030 onwards carbon removal through land management and engineered solutions such as direct air capture and bioenergy with carbon capture and storage becomes critical. Australia is also well-positioned to become a global supplier of clean energy such as hydrogen made using renewable electricity helping reduce emissions beyond its borders.

Hydrogen (H2) has the potential to become a cleaner fuel alternative to increase energy mix versatility as part of a low-carbon economy. Geological H2 storage represents a key component of the emerging H2 value chain since large-scale energy generation linked to energy generation and large-scale industrial applications will require significant upscaling of geological storage. Geological H2 storage can take place in both salt domes and bedded salt formations. Bedded salt formations offer a significant advantage for H2 storage over salt domes because of their widespread availability. This research focuses on evaluating the H2 storage potential of the Salado Formation a bedded salt deposit in the Permian Basin of West Texas in the United States. Using data from 3268 well logs this study analyzes an area of 136100 km2 to identify suitable depth and net halite thickness for H2 storage in salt caverns. In addition this work applies a novel geostatistical workflow to quantify the uncertainty in the formation’s storage potential. The H2 working gas potential of the Salado Formation ranges from 0.62 to 17.53 Tsm3 (1.75–49.68 PWh of stored energy) across low-risk to high-risk scenarios with a median potential of 1.19 Tsm3 (3.37 PWh). The counties with the largest storage potential are: Lea in New Mexico and Gaines and Andrews in Texas. These three counties account for more than 75 % of the formation’s total storage potential. This is the first study to quantify uncertainty in H2 storage estimates for a bedded salt formation while providing a detailed breakdown of results by county and 1 km2 grid sections. The findings of this work offer critical insights for developing H2 infrastructure in the Permian Basin. The Permian Basin of West Texas has the potential to become an important hub for H2 production from both natural gas and/or renewable energy. Estimating H2 storage potential is an important contribution to assess the feasibility of the entire H2 value chain in Texas. An interactive map accompanies this work allowing the readers to explore the results visually.

Hydrogen is increasingly recognized as a clean energy alternative offering effective storage solutions for widespread adoption. Advancements in storage electrolysis and fuel cell technologies position hydrogen as a pathway toward cleaner more efficient and resilient energy solutions across various sectors. However challenges like infrastructure development cost-effectiveness and system integration must be addressed. This review comprehensively examines above-ground hydrogen storage technologies and their applications. It highlights the importance of established hydrogen fuel cell infrastructure particularly in gaseous and LH2 systems. The review favors material-based storage for medium- and long-term needs addressing challenges like adverse thermodynamics and kinetics for metal hydrides. It explores hydrogen storage applications in mobile and stationary sectors including fuel-cell electric vehicles aviation maritime power generation systems off-grid stations power backups and combined renewable energy systems. The paper underscores hydrogen’s potential to revolutionize stationary applications and co-generation systems highlighting its significant role in future energy landscapes.

This study explores the feasibility of producing biohydrogen from winery wastewater using a dual-chamber microbial electrolysis cell (MEC). A mixed microbial consortium pre-adapted to heavy-metal environments and enriched with Geobacter sulfurreducens was anaerobically cultivated from diverse waste streams. Over 5000 h of development the MEC system was progressively adapted to winery wastewater enabling long-term electrochemical stability and high organic matter degradation. Upon winery wastewater addition (5% v/v) the system achieved a sustained hydrogen production rate of (0.7 ± 0.3) L H2 L −1 d −1 with an average current density of (60 ± 4) A m−3 and COD removal efficiency exceeding 55% highlighting the system’s resilience despite the presence of inhibitory compounds. Coulombic efficiency and cathodic hydrogen recovery reached (75 ± 4)% and (87 ± 5)% respectively. Electrochemical impedance spectroscopy provided mechanistic insight into charge transfer and biofilm development correlating resistive parameters with biological adaptation. These findings demonstrate the potential of MECs to simultaneously treat agro-industrial wastewaters and recover energy in the form of hydrogen supporting circular resource management strategies.

This study presents the application of a new sustainability assessment methodology. It aims to improve the information that can be obtained from a sustainability assessment including the concept of alternative usage impact. To prove the effectiveness of this methodology three different hydrogen production methodologies considering its consumption in transportation sector is the case of study. The methodologies considered are Steam Methane Reform using natural gas Proton Exchange Membrane electrolysis one using grid electricity and the other study case using central tower solar power plant electricity from the PS10 facility. While separately green hydrogen is the technology with less environmental impact when considering the full system and the impact of the green hydrogen on the rest of the resources the integration of green hydrogen technology is not the most environmentally sustainable. Similar behavior is observed in the economic and technical fields. The different accounting of combinations of technologies and the impact on the resource which is not used provides the sustainability performance of the overall system. These results show that in order to account the all impacts taking place in a energy technology integration its impact on the rest of resources and uses provide more valuable information.

Export-oriented green-hydrogen projects (EOGH2P) are being developed in regions with optimal renewableenergy resources. Their reliance on economies of scale makes them land-intensive and object of spatial planning policies. However the impact of spatial planning on the development of EOGH2P remains underexplored. Drawing on the spatial planning and megaproject literatures the analysis of planning documents and expert interviews this paper analyzes how spatial planning influences the development of EOGH2P in Chile Namibia and South Africa. The three countries have developed different spatial planning approaches for EOGH2Ps and are analyzed by employing a comparative case-study design. Our findings reveal that Namibia pursues a restrictive approach South Africa a facilitative approach whereas Chile is shifting from a market-based to a restrictive approach. The respective approaches reflect different political priorities and stakeholder interests and imply diverse effects on the development of EOGH2Ps in terms of their number size shared infrastructure socioenvironmental impact and acceptance. This study underscores the need for well-designed spatial planning frameworks and provides insights for planners and stakeholders on their potential effects.

Hydrogen is increasingly recognized as a key energy vector for achieving deep decarbonization across urban and industrial sectors. Supporting global efforts to reduce greenhouse gas (GHG) emissions and achieve the Sustainable Development Goals (SDGs) it is essential to understand the multi-sectoral role of the hydrogen value chain spanning production storage and end-use applications with particular emphasis on smart city systems and industrial processes. Green hydrogen production technologies including alkaline water electrolysis (AWE) proton exchange membrane (PEM) electrolysis anion exchange membrane (AEM) electrolysis and solid oxide electrolysis cells (SOECs) are evaluated in terms of efficiency scalability and integration potential. Storage pathways are examined across physical storage (compressed gas cryo-compressed and liquid hydrogen) material-based storage (solid-state absorption in metal hydrides and chemical carriers such as LOHCs and ammonia) and geological storage (salt caverns depleted gas reservoirs and deep saline aquifers) highlighting their suitability for urban and industrial contexts. In the smart city domain hydrogen is analyzed as an enabler of zero-emission transportation low-carbon residential and commercial heating and renewable-integrated smart grids with long-duration storage capabilities. System-level studies demonstrate that coordinated integration of these applications can deliver higher overall energy efficiency deeper reductions in life-cycle GHG emissions and improved resilience of urban energy systems compared with sector-specific approaches. Policy frameworks safety standards and digitalization strategies are reviewed to illustrate how hydrogen infrastructure can be embedded into interconnected urban energy systems. Furthermore industrial applications focus on hydrogen’s potential to decarbonize energy-intensive processes and enable sector coupling between electricity heat and manufacturing. The environmental implications of hydrogen deployment are also considered including resource efficiency life-cycle emissions and ecosystem impacts. In contrast to reviews addressing isolated aspects of hydrogen technologies this study synthesizes technological infrastructural and policy dimensions integrating insights from over 400 studies to highlight the multifaceted role of hydrogen in sustainable urban development and industrial decarbonization and the added benefits achievable through coordinated cross-sector deployment strategies.