Publications
Performance Analysis of Natural Gas Centrifugal Compressors Under Hydrogen-Blended Conditions
Nov 2025
Publication
The transport of natural gas blended with hydrogen is a key strategy for the low-carbon energy transition. However the influence mechanism of its thermo-physical property variations on centrifugal compressor performance remains insufficiently understood. This study systematically investigates the effects of the hydrogen blending ratio (HBR 0–30%) inlet temperature and rotational speed on key compressor parameters (pressure ratio polytropic efficiency and outlet temperature) through numerical simulations. In order to evaluate the influence of hydrogen blending on the performance and stability of centrifugal compressors a three-dimensional model of the compressor was established and the simulation conducted was verified with the experimental data. Results indicate that under constant inlet conditions both the pressure ratio and outlet temperature decrease with increasing HBR while polytropic efficiency remains relatively stable. Hydrogen blending significantly expands the surge margin shifting both surge and choke lines downward and consequently reducing the stable operating range by 27.11% when hydrogen content increases from 0% to 30%. This research provides theoretical foundations and practical guidance for optimizing hydrogen-blended natural gas centrifugal compressor design and operational control.
Green Hydrogen as a Decarbonization Pathway for Steel Industry in Pakistan
Nov 2025
Publication
The global steel industry emits 1.92 tons of CO2 per ton of output and faces urgent pressure to decarbonize. In Pakistan the sector accounts for 0.29 tons of CO2 per ton of output with limited mitigation frameworks in place. Green hydrogen (GH2)-based steelmaking offers a strategic pathway toward decarbonization. However realizing its potential depends on access to renewable energy. Despite Pakistan’s substantial technical wind potential of 340 GW grid limitations currently restrict wind power to only 4% of national electricity generation. This study explores GH2 production through sector coupling and power wheeling repurposing curtailed wind energy from Sindh to supply Karachi’s steel industry and proposing a phased roadmap for GH enabling fossil fuel substitution industrial resilience and alignment with global carbon-border regulations.
Enhancing Green Hydrogen Forecasting with a Spatio-temporal Graph Convolutional Network Optimized by the Ninja Algorithm
Nov 2025
Publication
In light of increased international efforts to combat climate change sustainable infrastructure is shifting toward green hydrogen produced through renewable-powered electrolysis. Still it is challenging to forecast the production of green hydrogen because environmental and system factors are variable both in time and space. We introduce a new system that utilizes a Spatio-Temporal Graph Convolutional Network (STGCN) and a novel algorithm the Ninja Optimization Algorithm (NiOA) to address this issue. Using the framework binary NiOA performs feature selection while continuous NiOA optimizes both the model architecture and the number of variables in the data simultaneously. It is clear from the research that forecasting results have shown significant improvement. The STGCN model achieved an R2 of 0.8769 and an MSE of 0.00375 whereas the STGCN with NiOA reached an R2 of 0.9815 and an MSE of only 7.48 × 10−8. Due to these improvements adaptive metaheuristics show even greater promise in delivering more accurate forecasting and reduced computational requirements for addressing critical environmental issues. The suggested strategy can be followed repeatedly providing a solid framework for the effective modeling of renewable energy systems and making green hydrogen projects more dependable.
An Effective Integrated Optimal Day-ahead and Real-time Power Scheduling Approach for Hydrogen-based Microgrid
Oct 2025
Publication
The increasing penetration of renewable energy sources in power systems poses significant challenges for maintaining grid reliability mainly due to the variability and uncertainty of solar and demand profiles. Microgrids equipped with diverse storage technologies have emerged as a promising solution to address these issues.This paper proposes an integrated day-ahead and real-time power scheduling approach for grid-connected microgrids equipped with both conventional and hydrogen-based ESSs. While existing strategies often address day-ahead and real-time scheduling separately or rely on a single storage technology this work introduces a unified framework that exploits the complementary characteristics of batteries and hydrogen systems. The proposed approach is based on a novel two-stage stochastic optimization model embedded within a hierarchical optimization framework to address these two intertwined problems efficiently. For the day-ahead scheduling a two-stage stochastic programming energy management model is solved to optimize the microgrid schedule based on forecasted load demand and PV production profiles. Building upon the day-ahead schedule another optimization model is solved which addresses real-time power imbalances caused by deviations in actual PV production and load demand power profiles with respect to the forecasted ones with the aim of minimizing operational disruptions. Simulation results demonstrate the validity of the proposed approach achieving both cost reductions and minimal power imbalances. By dynamically adjusting energy flows and using both conventional batteries and hydrogen systems the proposed approach ensures improved reliability reduced operational costs and enhanced integration of RES in microgrids. These findings highlight the potential of the proposed hierarchical framework to support the large-scale deployment of RES while ensuring resilient and cost-effective microgrid operations.
Blockchain-based Traceability and Certifications of Hydrogen Refueling Station Components
Oct 2025
Publication
As hydrogen gains prominence in energy systems its adoption as an energy source for fuel cell electric vehicles (FCEVs) necessitates the establishment of hydrogen refueling stations (HRS). These stations contain critical compo-nents including nozzles storage tanks heat exchangers and compressors which must be certified by regulatory agen-cies to ensure safety and public trust. Current certification processes are fragmented and manually intensive creating inefficiencies and limiting transparency across the infrastructure lifecycle. In this paper we propose a blockchain-based solution that creates a secure and auditable network for certifying key HRS components. The system integrates an EVM-compatible blockchain decentralized storage and a modular suite of smart contracts (SCs) that formalize registration bidding accreditation certification and governance. Each contract encodes a distinct actor-driven work-flow enabling traceable and role-specific operations. A Decentralized Application (DApp) interface supports real-time and role-based interaction across the ecosystem. We present and evaluate the SCs and their underlying algorithms us-ing gas usage analysis load testing and security auditing. Load testing across the certification lifecycle shows stable transaction throughput and predictable cost profiles under increasing actor activity. A static security analysis con-firms resilience against common vulnerabilities. Our cost analysis indicates that while the framework is technically deployable on public blockchains the execution costs of certain functions make it more cost-effective for private blockchains or Layer 2 networks. We also compare our framework with existing systems to highlight its novelty and technical advantages. Our SCs DApp interface and load testing scripts are publicly available on GitHub.
Modelling a Small-scale Hydrogen Valley: Optimisation Under Techno-economic and Environmental Perspectives
Oct 2025
Publication
Renewable hydrogen is a promising pathway to decarbonise hard-to-electrify sectors though its widespread deployment remains hindered by economic challenges. Hydrogen valleys integrated regional systems have emerged as a strategic solution to scale up hydrogen infrastructure and demand. This study assesses the technoeconomic feasibility of a hydrogen valley in southeastern Crete based on the CRAVE-H2 project using a MixedInteger Linear Programming (MILP) optimisation model. The system serves multiple end-uses: touristic fuel cell buses and a vessel as well as cold ironing for ships at berth. In addition to renewable generators electricity can be supplied via a hybrid storage system or purchased from the grid with dispatch optimised according to hourly market prices. A customised modelling framework is developed within PyPSA using the Linopy extension enabling the inclusion of piecewise affine approximations of non-linear performance curves for electrolysers and fuel cells alongside operating range constraints. Hydrogen leakage is also explicitly modelled to assess its environmental and economic implications. The model delivers optimal component sizing energy dispatch strategies and key performance metrics including Levelised Cost Of Hydrogen (LCOH) aggregated Levelised Cost Of Energy (LCOE) and carbon intensity. Most scenarios yield competitive LCOH values between 5.36 and 8.21 €/kgH2 increasing to 15 €/kgH2 under full decarbonisation due to extensive storage investments. Hydrogen emissions that may exceed 10 % of total production in worst-case scenarios become more pronounced in fully decarbonised scenarios. These findings underline the importance of emissions tracking and provide practical insights to inform the design of cost-effective low-emission hydrogen valleys.
Pathways to Green Hydrogen Production as a Sustainable Energy Solution in Kenya by 2040
Nov 2025
Publication
Given the Kenyan challenges in energy availability accessibility and affordability exploring green hydrogen as a sustainable energy solution is supreme. This study aimed to assess the potential of green hydrogen production a transformative clean energy technology and its implications for Kenya's future energy. The specific objectives were to identify the drivers of change that could accelerate green hydrogen adoption and policy recommendations. The study employed a scenario planning approach focusing on four key steps: defining the scenario and time horizon identifying drivers of change and developing and applying scenarios. The diffusion of innovation theory guided the study. Twelve key critical drivers of change were identified with societal and industry acceptance of green hydrogen and compatibility with existing energy infrastructure being the strongest drivers of change from cross-impact analysis results. The study outlined four plausible future scenarios for adoption: Successful Production (best scenario) Low Production Chaotic Transition and Rejection of Green Hydrogen Production (worst scenario). Major opportunities include advancements in hydrogen production export potential and job creation. Cost competitiveness analysis is essential comparing Kenya's hydrogen with traditional fuels and African peers. Economic models suggest that Kenya's renewable energy can lower costs enhancing its position in clean energy innovation. However critical challenges involve regulatory uncertainty ethical concerns public misconceptions about green hydrogen safety and financial barriers due to high initial investment costs. The study recommended that the Kenyan government invest in renewable energy infrastructure formulate a comprehensive national hydrogen policy and establish an enabling environment to attract private investment. In conclusion green hydrogen production stands as a strategic pillar for Kenya’s sustainable energy transition and further research should focus on strengthening regulatory frameworks and enhancing public engagement to unlock its full potential.
Uncertainty Ahead: Should Stand-alone Energy Systems Bet on Hydrogen Backup?
Oct 2025
Publication
Achieving net zero by 2050 will require decarbonising stand-alone energy applications. Hydrogen is increasingly viewed as a promising energy carrier but its economic viability remains uncertain due to the lack of consensus on future demand and limited deployment of key components such as fuel cells in stationary stand-alone applications. This study investigates whether hybridising batteries with hydrogen can deliver meaningful cost benefits under future cost trajectories. Using a Monte Carlo framework we simulate 8000 scenarios across constant and seasonal load profiles varying the capital costs of batteries fuel cells electrolysers and hydrogen tanks based on 2025 estimates and 2050 projections. Our results show that hydrogen integration only becomes economically attractive when multiple component costs decline simultaneously. The fuel cell-to-battery power capital cost ratio emerges as the dominant driver of levelised cost of energy (LCOE) improvements. For constant loads median LCOE savings remain below 12 % with more than 5 % savings only achieved when the fuel cell cost is less than 7 times that of the battery. Seasonal nighttime loads offer a wider theoretical LCOE savings range (0–156 %) but substantial gains occur only under unrealistic cost mixes where battery costs remain high and fuel cell costs fall sharply. These findings highlight the sensitivity of hydrogen viability to load profile characteristics and cost interdependencies. They underscore the need for targeted cost reduction strategies particularly for fuel cells to justify added system complexity. These findings are important considerations for future investment and policy decisions.
Global Greenhouse Gas Emissions Mitigation Potential of Existing and Planned Hydrogen Projects
Nov 2025
Publication
Hydrogen will play a critical role in decarbonizing diverse economic sectors. However given limited sustainable resources and the energy-intensive nature of its production prioritizing its applications will be essential. Here we analyse approximately 2000 (low-carbon) hydrogen projects worldwide encompassing operational and planned initiatives until 2043 quantifying their greenhouse gas (GHG) emissions and mitigation potential from a life cycle perspective. Our results demonstrate the variability in GHG emissions of hydrogen applications depending on the geographical location and hydrogen source used. The most climate-effective hydrogen applications include steel-making biofuels and ammonia while hydrogen use for road transport power generation and domestic heating should be discouraged as more favourable alternatives exist. Planned low-carbon hydrogen projects could generate 110 MtH2 yr−1 emit approximately 0.4 GtCO2e yr−1 and potentially reduce net life cycle GHG emissions by 0.2–1.1 GtCO2e yr−1 by 2043 depending on the substituted product or service. Addressing the current hydrogen implementation gap and prioritizing climate-effective applications are crucial for meeting decarbonization goals.
Assessing the Impact of Integration of Hydrogen Blending from Municipal Solid Waste and Biomass with Gas Turbine on Performance of Traditional Coal Power Plants
Oct 2025
Publication
Producing hydrogen from municipal solid waste (MSW) presents a transformative and sustainable solution for waste management. This paper presents a system that integrates MSW gasification with a traditional coal power plant (TCPP) along with biomass gasification and a gas turbine. It also incorporates a water recovery Rankine cycle (RC) that utilizes flue gas for electricity generation making it a key strategy for cleaner energy and effective waste disposal. The study examines three scenarios: MSWHIRBGT1 MSWHIRBG and MSWHIRBGT2. In the MSWHIRBGT2 electricity generation reaches 877 MW. This achievement results from the injection of hydrogen from MSW gasification into the TCPP boiler combined with advanced biomass technologies and flue gas recovery from TCPP. MSWHIRBGT2 achieves energy and exergy efficiencies of 46.9 % and 43.05 % making it the optimal choice for enhancing power generation in future energy solutions. All scenarios resulted in reduced CO2 emissions compared to a conventional coal-fired power plant of the same capacity highlighting the proposed system’s contribution to a cleaner environment. Furthermore the impact of different percentages of injected hydrogen on the concentrations of CO CO2 H2 H2S SO3 and SO2 in the flue gas is analyzed. Results show that higher hydrogen injection reduces CO by 81 % and H2 by 94 % while increasing SO3 and CO2 levels by 96 % and 39 % respectively. This demonstrates the environmental benefits of the technologies being implemented.
Life Cycle Assessment of Hydrogen-based Fuels Use in Internal Combustion Engines of Container Ships until 2050
Oct 2025
Publication
Hydrogen-based fuels are potential candidates to help international shipping achieve net-zero greenhouse gas (GHG) emissions by around 2050. This paper quantifies the environmental impacts of liquid hydrogen liquid ammonia and methanol used in a Post-Panamax container ship from 2020 to 2050. It considers cargo capacity changes electricity decarbonization and hydrogen production transitions under two International Energy Agency scenarios: the Stated Policies Scenario (STEPS) and the Net Zero Emissions by 2050 Scenario (NZE). Results show that compared to the existing HFO ship hydrogen-based propulsion systems can decrease cargo weight capacity by 0.3 % to 25 %. In the NZE scenario hydrogen-based fuels can reduce GHG emissions per tonne-nautical mile by 48 %–65 % compared to heavy fuel oil by 2050. Even with fully renewable hydrogenbased fuels 18 %–31 % of GHG emissions would still remain. Using hydrogen-based fuels in internal combustion engines requires attention to minimize environmental trade-offs.
Sustainability-aligned Pathways for Energy Transition: A Review of Low-carbon Energy Network Solutions
Nov 2025
Publication
Transformation of the energy sector is necessary to meet climate targets and ensure universal access to reliable and affordable energy. Despite progress more than 675 million people still lack electricity and 770 million face an unreliable power supply. Renewable energy now provides nearly 30 % of global electricity generation and represents approximately 17.9 % of total final energy consumption. This amount is insufficient for the 1.5 ◦C pathway and requires a tripling of renewable capacity by 2030. Energy efficiency also lags with average annual gains of 1.6 % compared with the 4 % required for climate-aligned energy scenarios. Therefore this paper reviews pathways toward decentralized low-carbon solutions that can accelerate global energy transformation. The review paper examines how technologies such as microgrids virtual power plants energy storage systems and vehicleto-grid (V2G) solutions are reshaping modern energy systems. It highlights that digitalization smart grids and sector integration are key to building flexible and consumer-focused networks. However achieving sustainable energy access requires more than new technologies. Strong governance fair financing and social inclusion are equally important to ensure a just and balanced energy transition. Case studies from Asia Africa and Latin America show how policy innovative financing and regional cooperation can drive progress despite challenges such as underinvestment fossil fuel dependency and energy poverty. The review demonstrates that an integrated approach combining technological innovation financial mechanisms and inclusive policies can collectively build low-carbon resilient and equitable energy systems.
Competition and Equilibrium in Future Global Renewable Hydrogen Trade: A Game-theoretic Analysis
Nov 2025
Publication
Global renewable hydrogen trade is expected to play a key role in decarbonizing future energy systems. Yet hydrogen exporters may deviate from perfectly competitive behaviour to influence prices similarly to the existing fossil fuel market with important implications for consumer welfare and the pace of the energy transition. This study develops a global renewable hydrogen trade model that captures potential strategic interactions among exporters using a Stackelberg game-theoretic framework. The model is formulated as an Equilibrium Problem with Equilibrium Constraints (EPEC) and solved under three alternative equilibria: a profitmaximizing Nash equilibrium a cost-minimizing Nash equilibrium and a welfare-maximizing benchmark representing perfect competition. Results indicate that producers may strategically reduce their export quantities by up to 40 % relative to perfect competition to maximize profits. Such behaviour raises prices to a minimum of 4.5 USD/kg in 2050 across major import markets thereby significantly eroding consumer surplus. Strategic behaviour of dominant exporters also shifts trade flows reshaping the global allocation of hydrogen supply. Sensitivity analysis further reveals that financing costs play a key role in shaping strategic producers’ behaviour with lower financing costs helping to reduce prices and stimulate demand. These findings highlight the implications of imperfect competition in global hydrogen trade and suggest that policy measures may be needed to mitigate potential negative consequences.
Modeling Electrochemical Impedance Spectroscopy of Hydrogen Complexes During Hydrogen Evolution on Single-stom Electrocatalysts
Nov 2025
Publication
Single Atom Catalysts (SACs) are an emerging frontier in heterogeneous electrocatalysis. They are made of metal atoms atomically dispersed on a matrix. A lot of attention has been dedicated to the study of Hydrogen Evolution Reaction (HER) mechanism due to its relevance in energy conversion technologies both with computational and experimental methods. The classical HER mechanism can be described by a Volmer–Heyrovsky–Tafel mechanism where the two desorption steps are competitive. The Volmer-Heyrovsky mechanism is conventionally proposed for single-atom catalysts. It has been computationally demonstrated that hydrogen complexes can form on SACs due to their analogy with homogeneous catalysts. Unfortunately it is hard to “visualize” these species experimentally. Electrochemical Impedance Spectroscopy (EIS) could be the most promising approach to study electrocatalytic mechanisms. In this work we present microkinetic and Electrochemical Impedance Spectroscopy models for HER on SACs describing Volmer-Heyrovsky and a mechanism mediated by the formation of hydrogen complexes. Our simulated data applied to a case study based on Pd@TiN show that Tafel plots will not suffice in the visualization of hydrogen complexes formation and will need the support of electrochemical impedance spectra in order to clarify the correct mechanism.
Assessing the Cost-effective Deployment and Operation of Water Electrolyzers in Global Net-zero CO2 Energy Systems
Nov 2025
Publication
This study investigates the cost-optimal capacity and operation of water electrolyzers in global net-zero CO2 energy systems. The production costs of hydrogen are largely determined by the electrolyzer capacity factor (i.e. full-load hours); therefore a global energy system model with an hourly temporal resolution was employed to consider the intermittency of variable renewable energy (VRE) and the dynamics of power system operations. Proton exchange membrane electrolysis is assumed in this study. The optimization results suggest three main findings. First water electrolysis is estimated to be a cost-effective option for achieving net-zero CO2 emissions. Under default technology assumptions the global installed capacity is projected to reach 2719 GW by 2050 with the majority of hydrogen consumed in the industry sector. Scaling up the supply chain is essential to realize this pathway. Second hydrogen and hydrogen-based fuels are economically competitive with negative emission technologies (NETs). A modest deployment of CO2 storage and NETs provides favorable conditions for water electrolysis deployment—and vice versa. Third flexible operation is critical to the widespread deployment of water electrolysis. In the default case the global weighted average capacity factor of electrolyzers is estimated at 37 % in 2050 to follow VRE output fluctuations. The results also indicate that limited operational flexibility may significantly hinder the cost-competitiveness of electrolyzer deployment.
A CFD Comparison of Interfacial Phase Change Models for Boil-off, Self-pressurisation and Thermal Stratification in Liquid Hydrogen Storage Tanks
Nov 2025
Publication
Liquid hydrogen (LH2 ) is a promising energy carrier for future clean fuel technologies. However its cryogenic storage and handling pose significant challenges particularly due to self-pressurisation and boil-off from ambient heat ingress. Accurate modelling of these phenomena is essential for the safe and efficient design of LH2 storage systems. A key aspect of such modelling is the selection and implementation of an appropriate interfacial phase change model. This study presents a comparative assessment of three widely used phase change models; the Schrage model the Modified Energy Jump (MeJ) model and the Lee model. A parametric study was conducted across three coefficients for each model with validation performed against five experimental benchmark cases from NASA’s K-Site and MHTB cryogenic tanks focusing on planar interface problems with thermally induced phase change under normal gravity. A CFD approach using STAR-CCM+ was employed to evaluate each model’s ability to predict tank pressure temperature and boil-off behaviour. The Schrage model demonstrated the most robust and accurate results exhibiting minimal sensitivity to coefficient variation and offering both numerical stability and physical fidelity. It demonstrated a maximum mean absolute percentage error (MAPE) of just 3.0% in its pressurisation predictions. The MeJ model showed comparable accuracy when its heat transfer coefficient was appropriately selected highlighting its reliance on an empirically derived coefficient. In contrast the Lee model performed the poorest exhibiting numerical divergence at high coefficient values and substantial deviation in its prediction of self-pressurisation with errors of up to 11% MAPE. These findings provide practical guidance for the selection and implementation of phase change models in CFD simulations and highlight key considerations for modelling LH2 storage tanks in industrial applications.
The Development of an Analysis Framework for the Integration of Low-carbon Hydrogen into Multi-regional Natural Gas Energy Systems
Nov 2025
Publication
In 2023 global carbon dioxide emissions reached 40 billion tonnes 60 % more than in 1990 intensifying climate concerns. This study explores hydrogen-natural gas blending as a transitional strategy for decarbonization across several regions and energy sectors – residential commercial industrial and agricultural. A multi-regional analysis framework evaluates integration of 20 % by volume low-carbon hydrogen blending into natural gas systems by identifying hydrogen producers importers and exporters based on production and import costs. Applied to Canada 528 scenarios (2026–2050) assess inter-regional hydrogen trade within Canadian provinces. The lowest-cost scenario involves Alberta exporting hydrogen produced through autothermal reforming with 91 % carbon capture and storage and British Columbia producing its own. The grid electrolysis scenario achieves the highest GHG reductions with a 4.5 % GHG mitigation in Canada with full energy system representation. These findings provide insights for policymakers and stakeholders in advancing hydrogen infrastructure and decarbonization strategies.
Techno-economic Analysis of Technologies for Decarbonizing Low- and Medium-Temperature Industrial Heat
Dec 2025
Publication
Decarbonizing industrial heat is critical for achieving climate targets. This study evaluates the economic viability of technologies for decarbonizing industrial heat in Europe through a techno-economic analysis. High-temperature heat pumps (HTHPs) and electric hydrogen and biomass boilers are compared in terms of levelized cost of heat (LCOH) under various scenarios including the impact of thermal storage leveraging dynamic electricity prices. In scenarios for the year 2030 we show that HTHPs leveraging free excess heat achieve LCOH values at least 30% to 60% lower than hydrogen boilers and up to 37% lower than biomass boilers. Integrating daily thermal storage reduces LCOH by up to 15% for heat pumps and 27% for electric boilers. By 2050 anticipated cost and efficiency improvements further enhance the competitiveness of heat pumps. These results highlight the economic advantage of HTHPs particularly when integrating excess heat and thermal storage.
Hydrogen Reduction of Combusted Iron Powder: Role of the Fluidization Regime on the Conversion
Nov 2025
Publication
Fluidized bed systems play a crucial role in industrial processes such as combustion and gasification. In the Iron Power Cycle fluidized bed systems are essential for enabling the reduction of combusted iron back to iron making them a critical component in the regeneration step of the cycle. This study investigates the impact of operating gas velocity on conversion by performing reduction experiments at three distinct fluidization numbers (us/umf): 16 (bubbling regime) 55 (transition region) and 100 (fully turbulent regime). Experiments were conducted to determine the appropriate velocities for each regime ensuring optimal fluidization conditions across reduction temperatures ranging from 500 to 700 ⚬C. The results reveal that conversion rates increase significantly with gas velocities. At 500 ⚬C operating at approximately six times higher velocity leads to a sixfold improvement in conversion when using iron-oxide particles with a Sauter mean diameter of 61 µm. However while enhanced velocities improve reaction efficiency challenges remain at elevated temperatures (T ≥ 500 ⚬C) where iron undergoes defluidization when exposed to hydrogen. Once defluidization occurs refluidization proves impossible with either hydrogen or nitrogen raising concerns about process stability. These insights highlight the potential for optimizing fluidized bed reduction through velocity control while also underscoring the need for additional measures to mitigate unstable fluidization during high-temperature iron oxide reduction.
Thermal and Heat Transfer Dynamics in High Pressure, High Aspect Ratio Hydrogen Tank Filling Processes
Nov 2025
Publication
A thermodynamic modeling framework is introduced to describe hydrogen refueling station configurations and capture detailed thermal dynamics in vehicle tanks with large aspect ratios. With an aspect ratio larger than three axial discretization of temperature allows to recover accurate temperature profiles and show that the gas and liner temperature are always highest towards the rear of the tanks. The framework is validated against experimental data and used to investigate the internal heat transfer dynamics. As aspect ratio grows larger the amount of cooling received by the rear region decreases as the incoming turbulent jet does not reach the latter. The current thermal management strategy of pre-cooling is therefore limited showing marginal improvements even with a cooling temperature of -50 ◦C. Potential solutions are to increase the filling duration time or to carefully design the tank with higher thermal diffusivity and adequate external means of cooling.
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