Applications & Pathways
Hydrogen Vehicle Adoption: Perceptions, Barriers, and Global Strategies
Oct 2025
Publication
This paper analyzes the potential of hydrogen technologies in transport placing it within the context of global environmental and energy challenges. Its primary purpose is to eval‑ uate the prospects for the implementation of these technologies at international and na‑ tional levels including Poland. This study utilizes a literature review and an analysis of the results of a highly limited exploratory pilot survey measuring public perception of hydrogen technology in transport. It is critical to note that the survey was conducted on a small non‑representative sample and exhibited a strong geographical bias primarily collecting responses from Europe (50 people) and North America (30 people). This study also details hydrogen vehicle types (FCEV HICE) and the essential infrastructure required (HRS). Despite solid technological foundations the development of hydrogen technology heavily relies on non‑technical factors such as infrastructure development support pol‑ icy and social acceptance. Globally the number of vehicles and stations is growing but remains limited with the pace of development correlating with the involvement of coun‑ tries. The pilot survey revealed a generally positive perception of the technology (mainly due to environmental benefits) but highlighted three key barriers: limited availability of refueling infrastructure—51.5% of respondents strongly agreed on this obstacle high pur‑ chase and maintenance costs and insufficient public awareness. Infrastructure subsidies and tax breaks were identified as effective incentives. Hydrogen technology offers a poten‑ tially competitive and sustainable transport solution but it demands significant systemic support intensive investment in large‑scale infrastructure expansion and comprehensive educational activities. Further governmental engagement is crucial. The severe limitations resulting from the pilot nature of the survey should be rigorously taken into account dur‑ ing interpretation.
Assessment of Regional Hydrogen Refueling Station Layout Planning and Carbon Reduction Benefits Based on Multi-Dimensional Factors of Population, Land, and Demand
Oct 2025
Publication
The urgent global transition toward low-carbon energy systems has highlighted the need for systematic planning of hydrogen refueling stations (HRS) to facilitate clean energy adoption. This study develops an integrated framework for regional HRS layout optimization and carbon emission assessment considering population distribution land area and hydrogen demand. Using Hainan Province as a case study the model estimates regional hydrogen demand determines optimal HRS deployment evaluates spatial coverage and refueling distances and quantifies potential carbon emission reductions under various renewable energy scenarios. Model validation with Haikou demonstrates its reliability and applicability at the regional scale. Results indicate pronounced spatial disparities in hydrogen demand and infrastructure requirements emphasizing that prioritizing station deployment in densely populated urban areas can enhance accessibility and maximize emission reduction. The framework offers a practical data-efficient tool for policymakers and planners to guide early-stage hydrogen infrastructure development and supports strategies for regional decarbonization and sustainable energy transitions.
Methodology for Evaluating and Comparing Different Sustainable Energy Generation and Storage Systems for Residential Buildings—Application to the Case of Spain
Nov 2025
Publication
This paper focuses on assessing different sustainable energy generation and storage systems for residential buildings in Spain identifying the best-performing system according to the end-user requirements. As outlined by the consulted literature the authors have selected two types of hybrid configurations—a Photovoltaic System with Battery Backup (PSBB) and a Photovoltaic System with Hydrogen Hybrid Storage Backup (PSHB)—and a Grid-Based System with Renewable Hydrogen Contribution (GSHC) is proposed. A Fuzzy Analytical Hierarchy Process methodology (FAHP) is employed for evaluating the hybrid power systems from a multi-criteria approach: acquisition operational and environmental. The main requirements for selecting the optimal system are organized under these criteria and evaluated using key performance indicators. This methodology allows the selection of the best option considering objective and subjective system performance indicators. Beyond establishing the ranking a sensitivity analysis was conducted to provide insights into how individual criteria influence the ranking of the hybrid power systems alternatives. The results demonstrate that the selection of hybrid power systems for a residential building is highly dependent on consumer preferences but the PSBB system scores highly in operation and acquisition criteria while the GSHC has good performance in all the criteria.
Deployment of Modular Renewable Energy Sources and Energy Storage Schemes in a Renewable Energy Valley
Nov 2025
Publication
While community energy initiatives and pilot projects have demonstrated technical feasibility and economic benefits their site-specific nature limits transferability to systematic scalable investment models. This study addresses this gap by proposing a modular framework for Renewable Energy Valleys (REVs) developed from real-world Community Energy Lab (CEL) demonstrations in Crete Greece which is an island with pronounced seasonal demand fluctuation strong renewable potential and ongoing hydrogen valley initiatives. Four modular business schemes are defined each representing different sectoral contexts by combining a baseline of 50 residential units with one representative large consumer (hotel rural households with thermal loads municipal swimming pool or hydrogen bus). For each scheme a mixed-integer linear programming model is applied to optimally size and operate integrated solar PV wind battery (BAT) energy storage and hydrogen systems across three renewable energy penetration (REP) targets: 90% 95% and 99.9%. The framework incorporates stochastic demand modeling sector coupling and hierarchical dispatch schemes. Results highlight optimal technology configurations that minimize dependency on external sources and curtailment while enhancing reliability and sustainability under Mediterranean conditions. Results demonstrate significant variation in optimal configurations across sectors and targets with PV capacity ranging from 217 kW to 2840 kW battery storage from 624 kWh to 2822 kWh and hydrogen systems scaling from 65.2 kg to 192 kg storage capacity. The modular design of the framework enables replication beyond the specific context of Crete supporting the scalable development of Renewable Energy Valleys that can adapt to diverse sectoral mixes and regional conditions.
Feasibility and Sensitivity Analysis of an Off-Grid PV/Wind Hybrid Energy System Integrated with Green Hydrogen Production: A Case Study of Algeria
Nov 2025
Publication
Algeria’s transition toward sustainable energy requires the exploitation of its abundant solar and wind resources for green hydrogen production. This study assesses the technoeconomic feasibility of an off-grid PV/wind hybrid system integrated with a hydrogen subsystem (electrolyzer fuel cell and hydrogen storage) to supply both electricity and hydrogen to decentralized sites in Algeria. Using HOMER Pro five representative Algerian regions were analyzed accounting for variations in solar irradiation wind speed and groundwater availability. A deferrable water-extraction and treatment load was incorporated to model the water requirements of the electrolyzer. In addition a comprehensive sensitivity analysis was conducted on solar irradiation wind speed and the capital costs of PV panels and wind turbines to capture the effects of renewable resource and investment cost fluctuations. The results indicate significant regional variation with the levelized cost of energy (LCOE) ranging from 0.514 to 0.868 $/kWh the levelized cost of hydrogen (LCOH) between 8.31 and 12.4 $/kg and the net present cost (NPC) between 10.28 M$ and 17.7 M$ demonstrating that all cost metrics are highly sensitive to these variations.
Benefit Allocation Strategies for Electric–Hydrogen Coupled Virtual Power Plants with Risk–Reward Tradeoffs
Nov 2025
Publication
Driven by carbon neutrality goals electric–hydrogen coupled virtual power plants (EHCVPPs) integrate renewable hydrogen production with power system flexibility resources emerging as a critical technology for large-scale renewable integration. As distributed energy resources (DERs) within EHCVPPs diversify heterogeneous resources generate diversified market values. However inadequate benefit allocation mechanisms risk reducing participation incentives destabilizing cooperation and impairing operational efficiency. To address this benefit allocation must balance fairness and efficiency by incorporating DERs’ regulatory capabilities risk tolerance and revenue contributions. This study proposes a multi-stage benefit allocation framework incorporating risk–reward tradeoffs and an enhanced optimization model to ensure sustainable EHCVPP operations and scalability. The framework elucidates bidirectional risk–reward relationships between DERs and EHCVPPs. An individualized risk-adjusted allocation method and correction mechanism are introduced to address economic-centric inequities while a hierarchical scheme reduces computational complexity from diverse DERs. The results demonstrate that the optimized scheme moderately reduces high-risk participants’ shares increasing operator revenue by 0.69% demand-side gains by 3.56% and reducing generation-side losses by 1.32%. Environmental factors show measurable yet statistically insignificant impacts. The framework meets stakeholders’ satisfaction and minimizes deviation from reference allocations.
A Review on Electric Vehicle Charging Station Planning: Infrastructure Placement, Sizing, Upgrades, and Uncertainties
Nov 2025
Publication
Electric Vehicles (EVs) are rapidly expanding resulting in increased demand on power systems and transportation networks. This study reviews recent advancements in planning EV Charging Stations (EVCSs) focusing on siting sizing grid upgrades and managing uncertainty. Analysis suggests that while many studies optimize either the location or the size of these stations few consider their combined effects resulting in missed opportunities for synergy. A lack of attention to cross-sector integration with hydrogen inadequate treatment of grid reinforcement and fragmented approaches to modeling uncertainties such as EV behavior renewable energy variability and market dynamics is also observed. To address these gaps a synthesis of the interdependencies between siting and sizing is provided along with a review of multi-energy integration opportunities an evaluation of Vehicle-to-Grid technology and smart charging including technical benefits and challenges strategies that link the deployment of EVCS to grid upgrades and a taxonomy of uncertainty sources along with advanced stochastic and data-driven solutions. This review emphasizes the importance of integrated data-informed planning in the development of EV charging infrastructure.
Coordinated Operation Mechanism of Electric-hydrogen-traffic Coupling System that Considers Carbon Emissions and Uncertainties
Nov 2025
Publication
During the critical period of energy transition the collaborative optimization of the electricity-hydrogentransportation coupling system is of vital importance for achieving efficient energy utilization and sustainable development.This paper proposes a collaborative operation mechanism of Distributed Robust Optimization (DRO) considering carbon emissions. Firstly a Stackelberg game dynamic pricing strategy is constructed for the integrated energy station (IES) and the electricity-hydrogen hybrid charging station (HRS) where the upper-level IES optimizes the electricity price setting strategy and the lower-level HRS dynamically adjusts the electricity purchase-hydrogen production plan. Secondly the Wasserstein distance is used to describe the uncertainties of hydrogen vehicle loads and wind-solar power generation and a bisection algorithm-column constraint generation (BA-C&CG) hybrid algorithm is designed to solve the model. Finally the numerical example verification shows that the daily operation cost of HRS under the proposed mechanism is as low as 1108.53 EUR which is 10.58 % and 7.38 % lower than that of the commonly used stochastic optimization (SO) and robust optimization (RO) respectively. The variance analysis (F = 536.05P < 0.001) confirms that the cost advantage is statistically significant. In terms of carbon emission reduction effect the DRO-Stackelberg game model has the lowest daily carbon cost (6.98EUR). This mechanism effectively balances the economic and robustness of the system and the single dispatch calculation time is only 112.09 s meeting the real-time operation requirements of engineering. It provides technical support for the low-carbon collaborative operation of the electricity-hydrogen-transportation coupling system.
Inverse Design and Porous Metal Printing of GDL-integrated Flow Field Plates for High-temperature Hydrogen Fuel Cells
Nov 2025
Publication
High-temperature (HT) proton exchange membrane (PEM) fuel cells (FC) offer key advantages for sustainable transportation especially in heavy-duty applications due to their improved thermal efficiency and water management. This study introduces an inverse design framework to develop flow field plates integrated with a gas diffusion layer (GDL) enabling scalable electrochemical performance from the unit cell to the plate level. A reduced-order homogenization-based multiphysics model is developed to evaluate designs with approximately 1000× faster computation. Flow channel orientation is optimized using a tensor field method and dehomogenized into manufacturable geometries. Optimized designs validated through high-fidelity 3D simulations show up to 12% higher average current density and 88% lower pressure drop compared to conventional parallel and mesh configurations. To address fabrication challenges solid-to-porous metal additive manufacturing is employed producing monolithic structures that integrate flow channels with a porous metal GDL. Both numerical and physical tests confirm high permeability and improved power output compared to carbon-based GDLs. These findings highlight the effectiveness of combining advanced computational modeling with metal 3D printing to enhance the performance and manufacturability of high-temperature PEMFC supporting their broader adoption in sustainable energy applications.
Reliability and Risk Assessment of Hydrogen-Powered Marine Propulsion Systems Based on the Integrated FAHP-FMECA Framework
Nov 2025
Publication
With the IMO’s 2050 decarbonization target hydrogen is a key zero-carbon fuel for shipping but the lack of systematic risk assessment methods for hydrogen-powered marine propulsion systems (under harsh marine conditions) hinders its large-scale application. To address this gap this study proposes an integrated risk evaluation framework by fusing Failure Mode Effects and Criticality Analysis (FMECA) with the Fuzzy Analytic Hierarchy Process (FAHP)—resolving the limitation of traditional single evaluation tools and adapting to the dynamic complexity of marine environments. Scientific findings from this framework confirm that hydrogen leakage high-pressure storage tank valve leakage and inverter overload are the three most critical failure modes with hydrogen leakage being the primary risk source due to its high severity and detection difficulty. Further hazard matrix analysis reveals two key risk mechanisms: one type of failure (e.g. insufficient hydrogen concentration) features “high severity but low detectability” requiring real-time monitoring; the other (e.g. distribution board tripping) shows “high frequency but controllable impact” calling for optimized operations. This classification provides a theoretical basis for precise risk prevention. Targeted improvement measures (e.g. dual-sealed valves redundant cooling circuits AI-based regulation) are proposed and quantitatively validated reducing the system’s overall risk value from 4.8 (moderate risk) to 1.8 (low risk). This study’s core contribution lies in developing a universally applicable scientific framework for marine hydrogen propulsion system risk assessment. It not only fills the methodological gap in traditional evaluations but also provides a theoretical basis for the safe promotion of hydrogen shipping supporting the scientific realization of the IMO’s decarbonization goal.
Techno-economic Feasibility of Centralized and Decentralized Ammonia Production in the United States
Nov 2025
Publication
Ammonia is a cornerstone of modern agriculture supplying the nitrogen essential for crops that nourish nearly half the global population. Yet its production is responsible for ~2 % of global greenhouse gas emissions. To meet climate and food security goals sustainable low-carbon and resilient ammonia production systems are needed. Here we develop a spatially explicit techno-economic model to compare centralized and decentralized ammonia production pathways across the U.S. a major global ammonia producer and consumer spanning the full supply chain from hydrogen production to fertilizer delivery. We integrate high-resolution supply and demand data and apply linear optimization to estimate delivered ammonia costs accounting for geographic mismatches and transportation. Our results show that decentralized ammonia production whether powered by grid electricity or solar energy is substantially more expensive than centralized production from natural gas or coal. Centralized natural gas-based ammonia has a median production cost of 326 USD/tonne NH3 compared to 499 USD/tonne for coal. Decentralized grid-powered systems range from 659 to 1634 USD/tonne and solar-powered systems from 1077 to 2266 USD/tonne. Transportation costs for centralized production range from 7 to 85 USD/tonne with a median of 40 USD/tonne resulting in a delivered cost of 343 USD/tonne. Median delivered costs for decentralized grid- and solar-powered systems are 1069 and 1494 USD/tonne respectively. Decentralized systems require electricity prices below 19 USD/MWh (grid) and 17 USD/MWh (solar) to achieve cost parity well below 2024 U S. averages of 117 USD/MWh. These results highlight the economic challenges facing decentralized ammonia production and the importance of electricity cost reductions tax credits carbon pricing or further technological breakthroughs for broader viability.
Simulation of the Refuelling Process for an LH2-powered Commercial Aircraft Part 1 - Modelling and Validation
Nov 2025
Publication
Liquid hydrogen (LH2) is a promising candidate for zero emission aviation but its cryogenic properties make the refuelling process fundamentally different from that of conventional jet fuels. Although previous studies have addressed LH2 storage and system integration detailed modelling of the refuelling process remains limited. This paper presents the first part of a two-part study focused on simulation of the refuelling process for an LH2-powered commercial aircraft. An existing tank model is substantially modified to more accurately capture relevant physical phenomena including heat transfer and droplet dynamics during top-fill spray injection. Newly available experimental data on LH2 no-vent filling enables direct validation of the model under conditions that match the experimental setup. A sensitivity analysis identifies the most influential parameters that affect model precision including loss coefficient droplet diameter radiative heat ingress and vent-closing pressure. The validated model forms the basis for Part 2 of this study in which it is applied to a representative LH2-powered commercial aircraft to simulate refuelling times quantify venting losses and assess the impact of key operational settings. These results support the design of efficient LH2 refuelling systems for future aircraft and airport infrastructure.
Techno-economic Assessment of Hythane-fueled Industrial SOFC Systems
Nov 2025
Publication
Solid oxide fuel cell (SOFC) systems offer high-efficiency conversion of the chemical energy of fuel gases into electrical energy. To meet market and policy targets such systems must be able of operating on an industrial scale and be compatible with environmentally friendly fuels. This study models the scale-up of a 750 W naturalgas-fueled SOFC to a 240 kW system with various gas-path configurations evaluating the impact of blending up to 30 vol% of hydrogen (H2) into the methane feed. Aspen Plus simulations coupled with pressure-loss and carbon-deposition models were used to optimize recirculation ratio and reactant utilization for maximum efficiency. The parallel configuration achieved the highest electrical efficiency of 64.0 % while series-connected and intermediate systems suffered from increased pressure losses. H2 admixture simulations confirm that operation is feasible without loss of efficiency in the small- and large-scale systems due to reduced carbondeposition potential. A techno-economic analysis indicates a 91.7 % cost reduction through scale-up and a 1.6 % cost increase for adjusting the system to H2 admixtures. The economic viability of the large-scale system was evaluated for all tested fuel compositions (0.201–0.204 €/kWh) with payback times under 20 years at market-relevant electricity prices. These results demonstrate the technical and economic feasibility of large-scale H2-adapted SOFC systems for industrial decarbonization.
Direct Injection Hydrogen Combustion under Leaner Conditions in an Optical Engine using Optical/Laser Diagnostics
Nov 2025
Publication
Hydrogen’s increasing potential as an alternative fuel for heavy-duty transport has led to the conversion of conventional diesel compression-ignition engines to spark-ignition hydrogen operation. Hydrogen’s broad flammability range enables leaner operation achieving both higher engine efficiency and near-zero emissions. In particular direct injection hydrogen combustion improves volumetric efficiency and reduces problems including pre-ignition and knock related to hydrogen port-fuel injection. In the present work we performed an optical investigation of direct injection (DI) hydrogen combustion under leaner mixture conditions. The study was conducted using a heavy-duty optical diesel engine modified for spark-ignition operation. Bottom-view natural flame luminosity and OH-PLIF imaging were conducted along with in-cylinder pressure measurements. Experiments were conducted at three air-excess ratios (3 3.4 and 3.8) with spark timings (ST) varied from − 15 ◦CA aTDC to − 30 ◦CA aTDC. Hydrogen injection ended at − 30 ◦CA aTDC with the start of injection adjusted accordingly to achieve the desired lambda conditions. The maximum IMEPg corresponded to the lowest COV of the IMEPg indicating optimal spark timing for lean DI hydrogen combustion. The optimized spark timing for λ = 3 λ = 3.4 and λ = 3.8 were occurred at − 25 ◦CA aTDC − 25 ◦CA aTDC and − 30 ◦CA aTDC respectively. The corresponding COV of IMEPg values were below 5 % indicating stable combustion. The flame kernel first initiates at the spark plug and then propagates toward the piston’s outer boundary however the flame propagation does not remain as a continuous front unlike port-fuel injected hydrogen combustion. The effect of fuel stratification is evident in combustion luminosity and OH-PLIF images showing pockets of varying intensity within the combustion chamber. Natural flame luminosity images reveal incomplete flame coverage and asymmetric combustion emphasizing the need for metal engine experiments to further quantify the unburned hydrogen and associated combustion losses.
OH* Chemiluminescence in Non-premixed Industrial Natural Gas/hydrogen Flames under Air-fuel and Oxy-fuel Conditions: Kinetic Modeling and Experimental Validation
Oct 2025
Publication
The application of OH* chemiluminescence diagnostics is becoming increasingly prevalent in the combustion characterization of hydrogen. As the current literature is lacking a systematic study of OH* chemiluminescence in non-premixed turbulent natural gas (NG) and hydrogen (H2 ) flames the present work was designed to address this research gap. Therefore extensive experiments were performed on a semi-industrial burner operating at 50–100 kW in NG/H2–Air/O2 combustion modes which were complemented by comprehensive numerical simulations including 1D laminar counterflow diffusion flamelet calculations and full 3D CFD simulations of the semi-industrial furnace setup. In this way an OH* chemistry model is presented that accurately predicts the global reaction zone characteristics and their difference between CH4 and H2 in air-fired and oxygen-fired flames. The comprehensive numerical approach in conjunction with the subsequent study of different operating conditions yielded novel insights into both combustion modeling and the underlying thermochemical phenomena providing an essential contribution to the transition of the thermal energy sector towards hydrogen as an alternative carbon-free fuel.
Towards the Decarbonization of the Maritime Industry: Design of a Novel Methodology for the Sustainable Strategy Assessment
Oct 2025
Publication
The growing concern about the increase in European Union (EU)’s total CO2 emissions due to maritime activities and the ambitious goal of net zero emissions they are asked to fulfil by 2050 are leading the way to the adoption of new sustainable strategies. In this article a novel methodology for the classification of the sustainable actions is proposed. Moreover new indicators have been designed to compare the level of sustainable development of each port. Among them a new coefficient for the assessment of the Ports’ Potential Sustainability (PPS) have been designed. Main results showed that 56% of the actions were in the improvement and environmentally sustainable group while 19% were shift-economic actions related to the installation of technologies. As a matter of the fact all European ports under analysis have adopted cold ironing system which can reduce up to 4% of the global shipping emissions. Similarly 50% of them have already integrated renewables energies and prioritize equipment electrification in their processes. Finally the most relevant projects to optimize the energy consumption of daily operations and the main challenges that still need to be addressed have been analyzed showing the current trends maritime sector is undertaking to advance towards the sustainable development.
Life Cycle and Economic Viability Assessment of Clean Hydrogen as a Fuel in Corn Drying
Oct 2025
Publication
This study presents a comparative life cycle and economic assessment of using clean hydrogen as a sustainable alternative to natural gas and propane for corn grain drying. The study compares the environmental performance limited to GWP100 and cost-effectiveness of hydrogen from various renewable sources (hydro wind solar) and plasma pyrolysis of natural gas against conventional fossil fuels under two delivery scenarios: pipeline and trucking. A life cycle assessment is conducted using Open LCA to quantify the carbon intensity of each fuel from cradle to combustion at multiple energy requirements based on four burner efficiencies across each scenario. In parallel economic analysis is conducted by calculating the fuel cost required per ton of dried corn grains at each efficiency across both scenarios. The results indicate that green hydrogen consistently outperforms current fuels in terms of emissions but it is generally more expensive at lower burner efficiencies and in trucking scenarios. However the cost competitiveness of green hydrogen improves significantly at higher efficiency and with pipeline infrastructure development it can become more economical when compared to propane. Hydrogen produced via plasma pyrolysis offers high environmental and economic costs due to its electricity and natural gas requirements. Sensitivity analysis further explores the impact of a 50% reduction in hydrogen production and transportation costs revealing that hydrogen could become a viable option for grain drying in both pipeline and trucking scenarios. This study highlights the long-term potential of hydrogen in reducing carbon emissions and offers insights into the economic feasibility of hydrogen adoption in agricultural drying processes. The findings suggest that strategic investments in hydrogen infrastructure could significantly enhance the sustainability of agricultural practices paving the way for a greener future in food production.
Hydrogen Strategies Under Uncertainty: Risk-Averse Choices for Green Hydrogen Pathways
Oct 2025
Publication
The last decade has been characterized by a growing environmental awareness and the rise of climate change concerns. Continuous advancement of renewable energy technologies in this context has taken a central stage on the global agenda leading to a diverse array of innovations ranging from cutting-edge green energy production technologies to advanced energy storage solutions. In this evolving context ensuring the sustainability of energy systems—through the reduction of carbon emissions enhancement of energy resilience and responsible resource integration—has become a primary objective of modern energy planning. The integration of hydrogen technologies for power-to-gas (P2G) and power-topower (P2P) and energy storage systems is one of the areas where the most remarkable progress is being made. However real case implementations are lagging behind expectations due to large-scale investments needed which under high energy price uncertainty act as a barrier to widespread adoption. This study proposes a risk-averse approach for sizing an Integrated Hybrid Energy System considering the uncertainty of electricity and gas prices. The problem is formulated as a mixed-integer program and tested on a real-world case study. The analysis sheds light on the value of synergies and innovative solutions that hold the promise of a cleaner more sustainable future for generations to come.
Modeling Hydrogen-Assisted Combustion of Liquid Fuels in Compression-Ignition Engines Using a Double-Wiebe Function
Oct 2025
Publication
This article discusses the potential of using the double-Wiebe function to model combustion in a compression-ignition engine fueled by diesel fuel or its substitutes such as hydrotreated vegetable oil (HVO) and rapeseed methyl ester (RME) and hydrogen injected into the engine intake manifold. The hydrogen amount ranged from 0 to 35% of the total energy content of the fuels burned. It was found that co-combustion of liquid fuel with hydrogen is characterized by two distinct combustion phases: premixed and diffusion combustion. The premixed phase occurring just after ignition is characterized by a rapid combustion rate which increases with an increase in hydrogen injected. The novelty in this work is the modified formula for a double-Wiebe function and the proposed parameters of this function depending on the amount of hydrogen added for co-combustion with liquid fuel. To model this combustion process the modified double-Wiebe function was proposed which can model two phases with different combustion rates. For this purpose a normalized HRR was calculated and based on this curve coefficients for the double-Wiebe function were proposed. Satisfactory consistency with the experiment was achieved at a level determined by the coefficient of determination (R-squared) of above 0.98. It was concluded that the presented double-Wiebe function can be used to model combustion in 0-D and 1-D models for fuels: RME and HVO with hydrogen addition.
Insights from Swirl Number and Ambient Pressure Variations with a Hydrogen/Ammonia Swirl Stabilized Diffusion Flame
Oct 2025
Publication
Contemporary research into decarbonized fuels such as H2/NH3 has highlighted complex challenges with applied combustion with marked changes in thermochemical properties leading to significant issues such as limited operational range flashback and instability particularly when attempts are made to optimize emissions production in conventional lean-premixed systems. Non-premixed configurations may address some of these issues but often lead to elevated NOx production particularly when ammonia is retained in the fuel mixture. Optimized fuel injection and blending strategies are essential to mitigate these challenges. This study investigates the application of a 75 %/25 %mol H2/NH3 blend in a swirl-stabilized combustor operated at elevated conditions of inlet temperature (500 K) and ambient pressure (0.11–0.6 MPa). A complex nonmonotonic relationship between swirl number and increasing ambient combustor pressure is demonstrated highlighting the intricate interplay between swirling flow structures and reaction kinetics which remains poorly understood. At medium swirl (SN = 0.8) an increase in pressure initially reduces NO emissions diminishing past ~0.3 MPa with an opposing trend evident for high swirl (SN = 2.0) as NO emissions fall rapidly when combustor pressure approaches 0.6 MPa. High-fidelity numerical modeling is presented to elucidate these interactions in detail. Numerical data generated using Detached Eddy Simulations (DES) were validated against experimental results to demonstrate a change in flame anchoring on the axial shear layer and marked change in recirculated flow structure successfully capturing the features of higher swirl number flows. Favorable comparisons are made with optical data and a reduction in NO emissions with increasing pressure is demonstrated to replicate changes to the swirling flame chemical kinetics. Findings provide valuable insights into the combustion behavior of hydrogen-rich ammonia flames contributing to the development of cleaner combustion technologies.
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