Applications & Pathways
Electrocatalysts Based on Metal@carbon Core@shell Nanocomposites: An Overview
Aug 2018
Publication
Developing low-cost high-performance catalysts is of fundamental significance for electrochemical energy conversion and storage. In recent years metal@carbon core@shell nanocomposites have emerged as a unique class of functional nanomaterials that show apparent electrocatalytic activity towards a range of reactions such as hydrogen evolution reaction oxygen evolution reaction oxygen reduction reaction and CO2 reduction reaction that are important in water splitting fuel cells and metal-air batteries. The activity is primarily attributed to interfacial charge transfer from the metal core to the carbon shell that manipulate the electronic interactions between the catalyst surface and reaction intermediates and varies with the structures and morphologies of the metal core (elemental composition core size etc.) and carbon shell (doping layer thickness etc.). Further manipulation can be achieved by the incorporation of a third structural component. A perspective is also included highlighting the current gap between theoretical modeling and experimental results and technical challenges for future research.
Integrated Ni-P-S Nanosheets Array as Superior Electrocatalysts for Hydrogen Generation
Jan 2017
Publication
Searching for efficient and robust non-noble electrocatalysts for hydrogen generation is extremely desirable for future green energy systems. Here we present the synthesis of integrated Ni-P-S nanosheets array including Ni2P and NiS on nickel foam by a simple simultaneous phosphorization and sulfurization strategy. The resultant sample with optimal composition exhibits superior electrocatalytic performance for hydrogen evolution reaction (HER) in a wide pH range. In alkaline media it can generate current densities of 10 20 and 100 mA cm−2 at low overpotentials of only −101.9 −142.0 and −207.8 mV with robust durability. It still exhibits high electrocatalytic activities even in acid or neutral media. Such superior electrocatalytic performances can be mainly attributed to the synergistic enhancement of the hybrid Ni-P-S nanosheets array with integration microstructure. The kind of catalyst gives a new insight on achieving efficient and robust hydrogen generation.
Integration of Open Slag Bath Furnace with Direct Reduction Reactors for New‐Generation Steelmaking
Jan 2022
Publication
The present paper illustrates an innovative steel processing route developed by employing hydrogen direct reduced pellets and an open slag bath furnace. The paper illustrates the direct reduction reactor employing hydrogen as reductant on an industrial scale. The solution allows for the production of steel from blast furnace pellets transformed in the direct reduction reactor. The reduced pellets are then melted in open slag bath furnaces allowing carburization for further refining. The proposed solution is clean for the decarbonization of the steel industry. The kinetic chemical and thermodynamic issues are detailed with particular attention paid to the slag conditions. The proposed solution is also supported by the economic evaluation compared to traditional routes.
High CO2 Absorption Capacity of Metal-Based Ionic Liquids: A Molecular Dynamics Study
Apr 2020
Publication
The absorption of CO2 is of importance in carbon capture utilization and storage technology for greenhouse gas control. In the present work we clarified the mechanism of how metal-based ionic liquids (MBILs) Bmim[XCln]m (X is the metal atom) enhance the CO2 absorption capacity of ILs via performing molecular dynamics simulations. The sparse hydrogen bond interaction network constructed by CO2 and MBILs was identified through the radial distribution function and interaction energy of CO2-ion pairs which increase the absorption capacity of CO2 in MBILs. Then the dynamical properties including residence time and self-diffusion coefficient confirmed that MBILs could also promote the diffusion process of CO2 in ILs. That's to say the MBILs can enhance the CO2 absorption capacity and the diffusive ability simultaneously. Based on the analysis of structural energetic and dynamical properties the CO2 absorption capacity of MBILs increases in the order Cl− → [ZnCl4]2-→ [CuCl4]2-→ [CrCl4]- → [FeCl4]- revealing the fact that the short metal–Cl bond length and small anion volume could facilitate the performance of CO2 absorbing process. These findings show that the metal–Cl bond length and effective volume of the anion can be the effective factors to regulate the CO2 absorption process which can also shed light on the rational molecular design of MBILs for CO2 capture and other key chemical engineering processes such as IL-based gas sensors nano-electrical devices and so on.
Experimental Validation of Hydrogen Fuel−Cell and Battery−Based Hybrid Drive without DC−−DC for Light Scooter under Two Typical Driving Cycles
Dec 2021
Publication
Faced with key obstacles such as the short driving range long charging time and limited volume allowance of battery−−powered electric light scooters in Asian cities the aim of this study is to present a passive fuel cell/battery hybrid system without DC−−DC to ensure a compact volume and low cost. A novel topology structure of the passive fuel cell/battery power system for the electric light scooter is proposed and the passive power system runs only on hydrogen. The power performance and efficiency of the passive power system are evaluated by a self−developed test bench before installation into the scooters. The results of this study reveal that the characteristics of stable power output quick response and the average efficiency are as high as 88% during the Shanghainese urban driving cycle and 89.5% during the Chinese standard driving cycle. The results pre‐ sent the possibility that this passive fuel cell/battery hybrid powertrain system without DC−DC is practical for commercial scooters.
Improvement of Low Temperature Activity and Stability of Ni Catalysts with Addition of Pt for Hydrogen Production Via Steam Reforming of Ethylene Glycol
Nov 2018
Publication
Hydrogen production by steam reforming of ethylene glycol (EG) at 300 °C was investigated over SiO2 and CeO2 supported Pt–Ni bimetallic catalysts prepared by incipient wetness impregnation methods. It was observed that impregnation sequence of Pt and Ni can affect the performance of catalysts apparently. Catalyst with Pt first and then Ni addition showed higher EG conversion and H2 yield owing to the Ni enrichment on the surface and the proper interaction between Pt and Ni. It was observed that although SiO2 supported catalysts exhibited better activity and H2 selectivity CeO2 supported ones had better stability. This is attributed to the less coke formation on CeO2. Increasing Pt/Ni ratio enhanced the reaction activity and Pt3–Ni7 catalysts with 3 wt% Pt and 7 wt% Ni showed the highest activity and stability. Ni surficial enrichment facilitated the C—C bond rupture and water gas shift reactions; and Pt addition inhibited methanation reaction. Electron transfer and hydrogen spillover from Pt to Ni suppressed carbon deposition. These combined effects lead to the excellent performance of Pt3–Ni7 supported catalysts.
Functional Model of Power Grid Stabilization in the Green Hydrogen Supply Chain System—Conceptual Assumptions
Dec 2022
Publication
Green hydrogen supply chain includes supply sources production and distribution of hydrogen produced from renewable energy sources (RES). It is a promising scientific and application area as it is related to the problem of instability of power grids supplied with RES. The article presents the conceptual assumptions of the research on the design of a functional multi-criteria model of the stabilization model architecture of energy distribution networks based on a hydrogen energy buffer taking into account the applicable use of hydrogen. The aim of the research was to identify the variables contributing to the stabilization of the operation of distribution networks. The method used to obtain this result was a systematic review of the literature using the technique of in-depth analysis of full-text articles and expert consultations. The concept of a functional model was described as a matrix in two dimensions in which the identified variables were embedded. The first dimension covers the phases of the supply chain: procurement and production along with storage and distribution. The second dimension divides the separate factors into technical economic and logistic. The research was conducted in the context of system optimization from the point of view of the operator of the energy distribution system. As a result of the research several benefits resulting from stabilization using a hydrogen buffer were identified. Furthermore the model may be used in designing solutions stabilizing the operation of power grids in which there are surpluses of electricity produced from RES. Due to the applied multidimensional approach the developed model is recommended for use as it enables the design of solutions in a systemic manner. Due to the growing level of energy obtained from renewable energy sources the issue of stabilizing the energy network is becoming increasingly important for energy network distributors.
Design of Clean Steel Production with Hydrogen: Impact of Electricity System Composition
Dec 2021
Publication
In Europe electrification is considered a key option to obtain a cleaner production of steel at the same time as the electricity system production portfolio is expected to consist of an increasing share of varying renewable electricity (VRE) generation mainly in the form of solar PV and wind power. We investigate cost-efficient designs of hydrogen-based steelmaking in electricity systems dominated by VRE. We develop and apply a linear cost-minimization model with an hourly time resolution which determines cost-optimal operation and sizing of the units in hydrogen-based steelmaking including an electrolyser direct reduction shaft electric arc furnace as well as storage for hydrogen and hot-briquetted iron pellets. We show that the electricity price following steelmaking leads to savings in running costs but to increased capital cost due to investments in the overcapacity of steel production units and storage units for hydrogen and hot-briquetted iron pellets. For two VRE-dominated regions we show that the electricity price following steel production reduces the total steel production cost by 23% and 17% respectively as compared to continuous steel production at a constant level. We also show that the cost-optimal design of the steelmaking process is dependent upon the electricity system mix.
Assessment of Operational Performance for an Integrated ‘Power to Synthetic Natural Gas’ System
Dec 2021
Publication
This article presents a power to SNG (synthetic natural gas) system that converts hydrogen into SNG via a methanation process. In our analysis detailed models for all the elements of the system are built. We assume a direct connection between a wind farm and a hydrogen generator. For the purposes of our calculations we also assume that the hydrogen generator is powered by the renewable source over a nine-hour period per day (between 21:00 and 06:00) and this corresponds to the off-peak period in energy demand. In addition a hydrogen tank was introduced to maximize the operating time of the methanation reactor. The cooperation between the main components of the system were simulated using Matlab software. The primary aim of this paper is to assess the influence of various parameters on the operation of the proposed system and to optimize its yearly operation via a consideration of the most important constraints. The analyses also examine different nominal power values of renewables from 8 to 12 MW and hydrogen generators from 3 to 6 MW. Implementing the proposed configuration taking into account the direct connection of the hydrogen generator and the methanation reactor showed that it had a positive effect on the dynamics and the operating times of the individual subsystems within the tested configuration
Design and Costs Analysis of Hydrogen Refuelling Stations Based on Different Hydrogen Sources and Plant Configurations
Jan 2022
Publication
In this study the authors present a techno-economic assessment of on-site hydrogen refuelling stations (450 kg/day of H2 ) based on different hydrogen sources and production technologies. Green ammonia biogas and water have been considered as hydrogen sources while cracking autothermal reforming and electrolysis have been selected as the hydrogen production technologies. The electric energy requirements of the hydrogen refuelling stations (HRSs) are internally satisfied using the fuel cell technology as power units for ammonia and biogas-based configurations and the PV grid-connected power plant for the water-based one. The hydrogen purification where necessary is performed by means of a Palladium-based membrane unit. Finally the same hydrogen compression storage and distribution section are considered for all configurations. The sizing and the energy analysis of the proposed configurations have been carried out by simulation models adequately developed. Moreover the economic feasibility has been performed by applying the life cycle cost analysis. The ammonia-based configurations are the best solutions in terms of hydrogen production energy efficiency (>71% LHV) as well as from the economic point of view showing a levelized cost of hydrogen (LCOH) in the range of 6.28 EUR/kg to 6.89 EUR/kg a profitability index greater than 3.5 and a Discounted Pay Back Time less than five years.
Measurement Challenges for Hydrogen Vehicles
Apr 2019
Publication
Uptake of hydrogen vehicles is an ideal solution for countries that face challenging targets for carbon dioxide reduction. The advantage of hydrogen fuel cell electric vehicles is that they behave in a very similar way to petrol engines yet they do not emit any carbon containing products during operation. The hydrogen industry currently faces the dilemma that they must meet certain measurement requirements (set by European legislation) but cannot do so due to a lack of available methods and standards. This paper outlines the four biggest measurement challenges that are faced by the hydrogen industry including flow metering quality assurance quality control and sampling.
Roadmap to Hydrogen in the NTS - National Grid Gas Transmission
Jan 2020
Publication
DNV GL believes that the National Transmission System (NTS) will be central to the future of decarbonised energy in the UK. The future NTS could transmit natural gas hydrogen blends of the two and carbon dioxide. New pipelines will be built however a large cost-saving is available if the existing NTS assets can also be re-purposed. To move towards this future National Grid Gas Transmission wants to develop a project to trial injection hydrogen into the NTS. This is an opportunity to show that National Grid is part of the solution to achieving Net Zero. The trial will demonstrate to the Government and public that re-purposing the NTS is cost-effective safe and involves minimal disruption.
This report sets out a roadmap of projects to provide the knowledge needed for the trial. The roadmap was developed by assessing the knowledge required and how much of it already existed. The knowledge already available is summarised in this report with references to where further details can be found. Gaps in the knowledge are then described. The roadmap consists of projects to conduct work to close the knowledge gaps. The results are summarised in the figures below and in the box to the right.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
This report sets out a roadmap of projects to provide the knowledge needed for the trial. The roadmap was developed by assessing the knowledge required and how much of it already existed. The knowledge already available is summarised in this report with references to where further details can be found. Gaps in the knowledge are then described. The roadmap consists of projects to conduct work to close the knowledge gaps. The results are summarised in the figures below and in the box to the right.
This report and any attachment is freely available on the ENA Smarter Networks Portal here. IGEM Members can download the report and any attachment directly by clicking on the pdf icon above.
Developing a Hydrogen Fuel Cell Vehicle (HFCV) Energy Consumption Model for Transportation Applications
Jan 2022
Publication
This paper presents a simple hydrogen fuel cell vehicle (HFCV) energy consumption model. Simple fuel/energy consumption models have been developed and employed to estimate the energy and environmental impacts of various transportation projects for internal combustion engine vehicles (ICEVs) battery electric vehicles (BEVs) and hybrid electric vehicles (HEVs). However there are few published results on HFCV energy models that can be simply implemented in transportation applications. The proposed HFCV energy model computes instantaneous energy consumption utilizing instantaneous vehicle speed acceleration and roadway grade as input variables. The mode accurately estimates energy consumption generating errors of 0.86% and 2.17% relative to laboratory data for the fuel cell estimation and the total energy estimation respectively. Furthermore this work validated the proposed model against independent data and found that the new model accurately estimated the energy consumption producing an error of 1.9% and 1.0% relative to empirical data for the fuel cell and the total energy estimation respectively. The results demonstrate that transportation engineers policy makers automakers and environmental engineers can use the proposed model to evaluate the energy consumption effects of transportation projects and connected and automated vehicle (CAV) transportation applications within microscopic traffic simulation models.
Green Hydrogen Value Chain in the Sustainability for Port Operations: Case Study in the Region of Valparaiso, Chile
Dec 2021
Publication
The paper presents a complete value chain for the use of green hydrogen in a port facility. The main objective was to propose the sizing of the main components that make up green hydrogen to ensure the supply of 1 MWe in replacing the diesel generator. The energy demand required for the port was determined by establishing the leading small and large-scale conventional energyconsuming equipment. Hence 60 kgH2 was required to ensure the power supply. The total electrical energy to produce all the hydrogen was generated from photovoltaic solar energy considering threegeneration scenarios (minimum maximum and the annual average). In all cases the energy supply in the electrolyzer was 3.08 MWe. In addition the effect of generating in the port facility using a diesel generator and a fuel cell was compared. The cost of 1 kgH2 could be 4.09 times higher than the cost of 1 L of diesel meaning that the output kWh of each system is economically similar. In addition the value of electrical energy through a Power Purchase Agreement (PPA) was a maximum of 79.79 times the value of a liter of diesel. Finally the Levelized Cost of Energy (LCOE) was calculated for two conditions in which the MWe was obtained from the fuel cell without and with the photovoltaic solar plant.
Progress in Power-to-Gas Energy Systems
Dec 2022
Publication
Hydrogen is expected to become a key component in the decarbonized energy systems of the future. Its unique chemical characteristics make hydrogen a carbon-free fuel that is suitable to be used as broadly as fossil fuels are used today. Since hydrogen can be produced by splitting water molecules using electricity as the only energy input needed hydrogen offers the opportunity to produce a fully renewable fuel if the electricity input also only stems from renewable sources. Once renewable electricity is converted into hydrogen it can be stored over long periods of time and transported over long even intercontinental distances. Underground hydrogen storage pipelines compressors liquefaction-units and transportation ships are infrastructures and suitable technologies to establish a global hydrogen energy system. Several chemical synthesis routes exist to produce more complex products from green hydrogen to fulfil the demands of various end-users and industries. One exemplary power-to-gas product is methane which can be used as a natural gas substitute. Furthermore ammonia alcohols kerosene and all other important products from hydrocarbon chemistry can be synthesized using green hydrogen.
Digital Navigation of Energy–structure–function Maps for Hydrogen-bonded Porous Molecular Crystals
Feb 2021
Publication
Energy–structure–function (ESF) maps can aid the targeted discovery of porous molecular crystals by predicting the stable crystalline arrangements along with their functions of interest. Here we compute ESF maps for a series of rigid molecules that comprise either a triptycene or a spiro-biphenyl core functionalized with six different hydrogen-bonding moieties. We show that the positioning of the hydrogen-bonding sites as well as their number has a profound influence on the shape of the resulting ESF maps revealing promising structure–function spaces for future experiments. We also demonstrate a simple and general approach to representing and inspecting the high-dimensional data of an ESF map enabling an efficient navigation of the ESF data to identify ‘landmark’ structures that are energetically favourable or functionally interesting. This is a step toward the automated analysis of ESF maps an important goal for closed-loop autonomous searches for molecular crystals with useful functions.
Electric and Hydrogen Buses: Shifting from Conventionally Fuelled Cars in the UK
May 2020
Publication
For the UK to meet their national target of net zero emissions as part of the central Paris Agreement target further emphasis needs to be placed on decarbonizing public transport and moving away from personal transport (conventionally fuelled vehicles (CFVs) and electric vehicles (EVs)). Electric buses (EBs) and hydrogen buses (HBs) have the potential to fulfil requirements if powered from low carbon renewable energy sources.
A comparison of carbon dioxide (CO2) emissions produced from conventionally fuelled buses (CFB) EBs and HBs between 2017 and 2050 under four National Grid electricity scenarios was conducted. In addition emissions per person at different vehicle capacity levels (100% 75% 50% and 25%) were projected for CFBs HBs EBs and personal transport assuming a maximum of 80 passengers per bus and four per personal vehicle.
Results indicated that CFVs produced 30 g CO2km−1 per person compared to 16.3 g CO2 km−1 per person by CFBs by 2050. At 100% capacity under the two-degree scenario CFB emissions were 36 times higher than EBs 9 times higher than HBs and 12 times higher than EVs in 2050. Cumulative emissions under all electricity scenarios remained lower for EBs and HBs.
Policy makers need to focus on encouraging a modal shift from personal transport towards sustainable public transport primarily EBs as the lowest level emitting vehicle type. Simple electrification of personal vehicles will not meet the required targets. Simultaneously CFBs need to be replaced with EBs and HBs if the UK is going to meet emission targets.
A comparison of carbon dioxide (CO2) emissions produced from conventionally fuelled buses (CFB) EBs and HBs between 2017 and 2050 under four National Grid electricity scenarios was conducted. In addition emissions per person at different vehicle capacity levels (100% 75% 50% and 25%) were projected for CFBs HBs EBs and personal transport assuming a maximum of 80 passengers per bus and four per personal vehicle.
Results indicated that CFVs produced 30 g CO2km−1 per person compared to 16.3 g CO2 km−1 per person by CFBs by 2050. At 100% capacity under the two-degree scenario CFB emissions were 36 times higher than EBs 9 times higher than HBs and 12 times higher than EVs in 2050. Cumulative emissions under all electricity scenarios remained lower for EBs and HBs.
Policy makers need to focus on encouraging a modal shift from personal transport towards sustainable public transport primarily EBs as the lowest level emitting vehicle type. Simple electrification of personal vehicles will not meet the required targets. Simultaneously CFBs need to be replaced with EBs and HBs if the UK is going to meet emission targets.
A Modelling Study for the Integration of a PEMFC Micro-CHP in Domestic Building Services Design
May 2018
Publication
Fuel cell based micro-combined heat and power (CHP) units used for domestic applications can provide significant cost and environmental benefits for end users and contribute to the UK’s 2050 emissions target by reducing primary energy consumption in dwellings. Lately there has been increased interest in the development of systematic methods for the design of such systems and their smoother integration with domestic building services. Several models in the literature whether they use a simulation or an optimisation approach ignore the dwelling side of the system and optimise the efficiency or delivered power of the unit. However the design of the building services is linked to the choice of heating plant and its characteristics. Adding the dwelling’s energy demand and temperature constraints in a model can produce more general results that can optimise the whole system not only the micro-CHP unit. The fuel cell has various heat streams that can be harvested to satisfy heat demand in a dwelling and the design can vary depending on the proportion of heat needed from each heat stream to serve the energy demand. A mixed integer non-linear programming model (MINLP) that can handle multiple heat sources and demands is presented in this paper. The methodology utilises a process systems engineering approach. The model can provide a design that integrates the temperature and water flow constraints of a dwelling’s heating system with the heat streams within the fuel cell processes while optimising total CO2 emissions. The model is demonstrated through different case studies that attempt to capture the variability of the housing stock. The predicted CO2 emissions reduction compared to a conventionally designed building vary from 27% to 30% and the optimum capacity of the fuel cell ranges between 1.9 kW and 3.6 kW. This research represents a significant step towards an integrated fuel cell micro-CHP and dwelling design.
Operation Analysis of Selected Domestic Appliances Supplied with Mixture of Nitrogen-Rich Natural Gas with Hydrogen
Dec 2021
Publication
This is article presents the results of the testing of the addition of a hydrogen-to-nitrogen-rich natural gas of the Lw group and its influence on the operation of selected gas-fired domestic appliances. The tests were performed on appliances used for the preparation of meals and hot water production for hygienic and heating purposes. The characteristics of the tested gas appliances are also presented. The burners and their controllers with which the tested appliances were equipped were adapted for the combustion of Lw natural gas. The tested appliances reflected the most popular designs for domestic gas appliances in their group used both in Poland and in other European countries. The tested appliances were supplied with nitrogen-rich natural gas of the Lw group and a mixture of this gas with hydrogen at 13.2% content. The article presents the approximate percentage compositions of the gases used during the tests and their energy parameters. The research was focused on checking the following operating parameters and the safety of the tested appliances: the rated heat input thermal efficiency combustion quality ignition flame stability and transfer. The article contains an analysis of the test results referring in detail to the issue of decreasing the heat input of the appliances by lowering the energy parameters of the nitrogen-rich natural gas of the Lw group mixture with a hydrogen addition and how it influenced the thermal efficiency achieved by the appliances. The conclusions contain an explanation regarding among other things how the design of an appliance influences the thermal efficiency achieved by it in relation to the heat input decrease. In the conclusions on the basis of the research results answers have been provided to the following questions: (1) Whether the hydrogen addition to the nitrogen-rich natural gas of the Lw group will influence the safe and proper operation of domestic gas appliances; (2) What hydrogen percentage can be added to the nitrogen-rich natural gas of the Lw group in order for the appliances adapted for combusting it to operate safely and effectively without the need for modifying them?
Living Carbon Free – Exploring What a Net-zero Target Means for Households
Jun 2019
Publication
The Energy Systems Catapult (ESC) explored the role of households in a net-zero emissions society to accompany the CCC’s Net Zero report looking at opportunities and challenges for households to reduce emissions from today’s levels and to support the stretch from an 80% emissions reduction to a net-zero greenhouse gas target. As well as describing a net-zero emissions world for households of different types the ESC looked at average household emissions under different decarbonisation scenarios and the options households can take to contribute to the decarbonisation effort.
This supported the Net Zero Technical report.
This supported the Net Zero Technical report.
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