Applications & Pathways
Ammonia Production from Clean Hydrogen and the Implications for Global Natural Gas Demand
Jan 2023
Publication
Non-energy use of natural gas is gaining importance. Gas used for 183 million tons annual ammonia production represents 4% of total global gas supply. 1.5-degree pathways estimate an ammonia demand growth of 3–4-fold until 2050 as new markets in hydrogen transport shipping and power generation emerge. Ammonia production from hydrogen produced via water electrolysis with renewable power (green ammonia) and from natural gas with CO2 storage (blue ammonia) is gaining attention due to the potential role of ammonia in decarbonizing energy value chains and aiding nations in achieving their net-zero targets. This study assesses the technical and economic viability of different routes of ammonia production with an emphasis on a systems level perspective and related process integration. Additional cost reductions may be driven by optimum sizing of renewable power capacity reducing losses in the value chain technology learning and scale-up reducing risk and a lower cost of capital. Developing certification and standards will be necessary to ascertain the extent of greenhouse gas emissions throughout the supply chain as well as improving the enabling conditions including innovative finance and de-risking for facilitating international trade market creation and large-scale project development.
A Review on Industrial Perspectives and Challenges on Material, Manufacturing, Design and Development of Compressed Hydrogen Storage Tanks for the Transportation Sector
Jul 2022
Publication
Hydrogen fuel cell technology is securing a place in the future of advanced mobility and the energy revolution as engineers explore multiple paths in the quest for decarbonization. The feasibility of hydrogen-based fuel cell vehicles particularly relies on the development of safe lightweight and cost-competitive solutions for hydrogen storage. After the demonstration of hundreds of prototype vehicles today commercial hydrogen tanks are in the first stages of market introduction adopting configurations that use composite materials. However production rates remain low and costs high. This paper intends to provide an insight into the evolving scenario of solutions for hydrogen storage in the transportation sector. Current applications in different sectors of transport are covered focusing on their individual requirements. Furthermore this work addresses the efforts to produce economically attractive composite tanks discussing the challenges surrounding material choices and manufacturing practices as well as cutting-edge trends pursued by research and development teams. Key issues in the design and analysis of hydrogen tanks are also discussed. Finally testing and certification requirements are debated once they play a vital role in industry acceptance.
The Potential for Hydrogen Ironmaking in New Zealand
Oct 2022
Publication
Globally iron and steel production is responsible for approximately 6.3% of global man-made carbon dioxide emissions because coal is used as both the combustion fuel and chemical reductant. Hydrogen reduction of iron ore offers a potential alternative ‘near-zero-CO2’ route if renewable electrical power is used for both hydrogen electrolysis and reactor heating. This paper discusses key technoeconomic considerations for establishing a hydrogen direct reduced iron (H2-DRI) plant in New Zealand. The location and availability of firm renewable electricity generation is described the experimental feasibility of reducing locally-sourced titanomagnetite irons and in hydrogen is shown and a high-level process flow diagram for a counter-flow electrically heated H2-DRI process is developed. The minimum hydrogen composition of the reactor off-gas is 46% necessitating the inclusion of a hydrogen recycle loop to maximise chemical utilisation of hydrogen and minimize costs. A total electrical energy requirement of 3.24 MWh per tonne of H2-DRI is obtained for the base-case process considered here. Overall a maximum input electricity cost of no more than US$80 per MWh at the plant is required to be cost-competitive with existing carbothermic DRI processes. Production cost savings could be achieved through realistic future improvements in electrolyser efficiency (∼ US$5 per tonne of H2-DRI) and heat exchanger (∼US$3 per tonne). We conclude that commercial H2-DRI production in New Zealand is entirely feasible but will ultimately depend upon the price paid for firm electrical power at the plant.
A Review of Key Components of Hydrogen Recirculation Subsystem for Fuel Cell Vehicles
Jul 2022
Publication
Hydrogen energy and fuel cell technology are critical clean energy roads to pursue carbon neutrality. The proton exchange membrane fuel cell (PEMFC) has a wide range of commercial application prospects due to its simple structure easy portability and quick start-up. However the cost and durability of the PEMFC system are the main barriers to commercial applications of fuel cell vehicles. In this paper the core hydrogen recirculation components of fuel cell vehicles including mechanical hydrogen pumps ejectors and gas–water separators are reviewed in order to understand the problems and challenges in the simulation design and application of these components. The types and working characteristics of mechanical pumps used in PEMFC systems are summarized. Furthermore corresponding design suggestions are given based on the analysis of the design challenges of the mechanical hydrogen pump. The research on structural design and optimization of ejectors for adapting wide power ranges of PEMFC systems is analyzed. The design principle and difficulty of the gas–water separator are summarized and its application in the system is discussed. In final the integration and control of hydrogen recirculation components controlled cooperatively to ensure the stable pressure and hydrogen supply of the fuel cell under dynamic loads are reviewed.
Recent Progress in Ammonia Fuel Cells and their Potential Applications
Nov 2020
Publication
Conventional technologies are largely powered by fossil fuel exploitation and have ultimately led to extensive environmental concerns. Hydrogen is an excellent carbon-free energy carrier but its storage and long-distance transportation remain big challenges. Ammonia however is a promising indirect hydrogen storage medium that has well-established storage and transportation links to make it an accessible fuel source. Moreover the notion of ‘green ammonia’ synthesised from renewable energy sources is an emerging topic that may open significant markets and provide a pathway to decarbonise a variety of applications reliant on fossil fuels. Herein a comparative study based on the chosen design working principles advantages and disadvantages of direct ammonia fuel cells is summarised. This work aims to review the most recent advances in ammonia fuel cells and demonstrates how close this technology type is to integration with future applications. At present several challenges such as material selection NOx formation CO2 tolerance limited power densities and long-term stability must still be overcome and are also addressed within the contents of this review
Optimal Scheduling of a Hydrogen-Based Energy Hub Considering a Stochastic Multi-Attribute Decision-Making Approach
Jan 2023
Publication
Nowadays the integration of multi-energy carriers is one of the most critical matters in smart energy systems with the aim of meeting sustainable energy development indicators. Hydrogen is referred to as one of the main energy carriers in the future energy industry but its integration into the energy system faces different open challenges which have not yet been comprehensively studied. In this paper a novel day-ahead scheduling is presented to reach the optimal operation of a hydrogen-based energy hub based on a stochastic multi-attribute decision-making approach. In this way the energy hub model is first developed by providing a detailed model of Power-to-Hydrogen (P2H) facilities. Then a new multi-objective problem is given by considering the prosumer’s role in the proposed energy hub model as well as the integrated demand response program (IDRP). The proposed model introduces a comprehensive approach from the analysis of the historical data to the final decision-making with the aim of minimizing the system operation cost and carbon emission. Moreover to deal with system uncertainty the scenario-based method is applied to model the renewable energy resources fluctuation. The proposed problem is defined as mixed-integer non-linear programming (MINLP) and to solve this problem a simple augmented e-constrained (SAUGMECON) method is employed. Finally the simulation of the proposed model is performed on a case study and the obtained results show the effectiveness and benefits of the proposed scheme.
Environmental and Energy Life Cycle Analyses of Passenger Vehicle Systems Using Fossil Fuel-derived Hydrogen
Sep 2021
Publication
Hydrogen energy utilization is expected due to its environmental and energy efficiencies. However many issues remain to be solved in the social implementation of hydrogen energy through water electrolysis. This analyzes and compares the energy consumption and GHG emissions of fossil fuel-derived hydrogen and gasoline energy systems over their entire life cycle. The results demonstrate that for similar vehicle weights the hydrogen energy system consumes 1.8 MJ/km less energy and emits 0.15 kg-CO 2 eq./km fewer GHG emissions than those of the gasoline energy system. Hydrogen derived from fossil fuels may contribute to future energy systems due to its stable energy supply and economic efficiency. Lowering the power source carbon content also improved the environmental and energy efficiencies of hydrogen energy derived from fossil fuels.
Sustainability Assessment and Engineering of Emerging Aircraft Technologies—Challenges, Methods and Tools
Jul 2020
Publication
Driven by concerns regarding the sustainability of aviation and the continued growth of air traffic increasing interest is given to emerging aircraft technologies. Although new technologies such as battery-electric propulsion systems have the potential to minimise in-flight emissions and noise environmental burdens are possibly shifted to other stages of the aircraft’s life cycle and new socio-economic challenges may arise. Therefore a life-cycle-oriented sustainability assessment is required to identify these hotspots and problem shifts and to derive recommendations for action for aircraft development at an early stage. This paper proposes a framework for the modelling and assessment of future aircraft technologies and provides an overview of the challenges and available methods and tools in this field. A structured search and screening process is used to determine which aspects of the proposed framework are already addressed in the scientific literature and in which areas research is still needed. For this purpose a total of 66 related articles are identified and systematically analysed. Firstly an overview of statistics of papers dealing with life-cycle-oriented analysis of conventional and emerging aircraft propulsion systems is given classifying them according to the technologies considered the sustainability dimensions and indicators investigated and the assessment methods applied. Secondly a detailed analysis of the articles is conducted to derive answers to the defined research questions. It illustrates that the assessment of environmental aspects of alternative fuels is a dominating research theme while novel approaches that integrate socio-economic aspects and broaden the scope to battery-powered fuel-cell-based or hybrid-electric aircraft are emerging. It also provides insights by what extent future aviation technologies can contribute to more sustainable and energy-efficient aviation. The findings underline the need to harmonise existing methods into an integrated modelling and assessment approach that considers the specifics of upcoming technological developments in aviation.
Accumulation of Inert Impurities in a Polymer Electrolyte Fuel Cell System with Anode Recirculation and Periodic Purge: A Simple Analytical Model
Mar 2022
Publication
Anode recirculation with periodic purge is commonly used in polymer electrolyte fuel cell systems to control the accumulation of nitrogen water and other impurities that are present in the fuel or diffuse through the membrane from the cathode compartment. In this work we develop a simple generalized analytical model that simulates the time dependence of the accumulation of inert impurities in the anode compartment of such a system. It is shown that when there is transport out of the anode chamber the inert species is expected to accumulate exponentially until equilibrium is reached when the rate of inert entering the anode in the fuel supply and/or via crossover from the cathode is balanced by the rate of leakage and/or crossover to the cathode. The model is validated using recently published experimental data for the accumulation of N2 CH4 and CO2 in a recirculated system. The results show that nitrogen accumulation needs to be taken into account to properly adjust system parameters such as purge rate purge volume and recirculation rate. The use of this generalized analytical model is intended to aid the selection of these system parameters to optimize performance in the presence of inerts.
Assessment of the Economic Efficiency of the Operation of Low-Emission and Zero-Emission Vehicles in Public Transport in the Countries of the Visegrad Group
Nov 2021
Publication
Transport is one of the key sectors of the European economy. However the intensive development of transport caused negative effects in the form of an increase in the emission of harmful substances. The particularly dramatic situation took place in the V4 countries. This made it necessary to implement solutions reducing emissions in transport including passenger transport. Such activities can be implemented in the field of implementation of low-emission and zero-emission vehicles for use. That is why the European Union and the governments of the Visegrad Group countries have developed numerous recommendations communications laws and strategies that order carriers to implement low- and zero-emission mobility. Therefore transport organizers and communication operators faced the choice of the type of buses. From an economic point of view each entrepreneur is guided by the economic efficiency of the vehicles used. Hence the main aim of the article was to conduct an economic evaluation of the operational efficiency of ecological vehicles. As more than 70% of vehicles in use in the European Union are still diesel driven the economic efficiency assessment was also made for vehicles with traditional diesel drive. To conduct the research the method of calculating the total cost of ownership of vehicles in operation was used. As a result of the research it was found that electric buses are the cheapest in the entire period of use (15 years) and then those powered by CNG. On the other hand the cost of using hydrogen buses is the highest. This is due to the high purchase prices of these vehicles. However the EU as well as the governments of individual countries support enterprises and communication operators by offering them financing for investments. The impact of the forecasted fuel and energy prices and the planned inflation on operating costs was also examined. In this case the analyses showed that the forecasted changes in fuel and energy prices as well as the expected inflation will significantly affect the costs of vehicle operation and the economic efficiency of using various types of drives. These changes will have a positive impact on the implementation of zero-emission vehicles into exploitation. Based on the analyses it was found that in 2035 hydrogen buses will have the lowest operating costs.
CO2 Emissions Reduction through Increasing H2 Participation in Gaseous Combustible—Condensing Boilers Functional Response
Apr 2022
Publication
Considering the imperative reduction in CO2 emissions both from household heating and hot water producing facilities one of the mainstream directions is to reduce hydrocarbons in combustibles by replacing them with hydrogen. The authors analyze condensing boilers operating when hydrogen is mixed with standard gaseous fuel (CH4 ). The hydrogen (H2 ) volumetric participation in the mixture is considered to vary in the range of 0 to 20%. The operation of the condensing boilers will be numerically modeled by computational programs and prior validated by experimental studies concluded in a European Certified Laboratory. The study concluded that an increase in the combustible flow with 16% will compensate the maximum H2 concentration situation with no other implications on the boiler’s thermal efficiency together with a decrease in CO2 emissions by approximately 7%. By assuming 0.9 (to/year/boiler) the value of CO2 emissions reduction for the condensing boiler determined in the paper and extrapolating it for the estimated number of boilers to be sold for the period 2019–2024 a 254700-ton CO2/year reduction resulted.
Everything About Hydrogen Podcast: Masters of Scale: Mobilizing the Mobility Sector (Around Hydrogen Fuel Cells)
Nov 2020
Publication
We talk a lot on the EAH podcast series about where hydrogen fuel cell electric vehicles (FCEVs) fit into the overall zero emission vehicle (ZEV) ecosystem. From personal passenger vehicles and the family car to commercial trucking and public transportation fleets and everything in between. Different vehicles and different use cases call for different capabilities and that is what makes the future of decarbonized transportation co interesting.
The podcast can be found on their website
The podcast can be found on their website
Potentials of Hydrogen Technologies for Sustainable Factory Systems
Mar 2021
Publication
The industrial sector is the world’s second largest emitter of greenhouse gases hence a methodology for decarbonizing factory systems is crucial for achieving global climate goals. Hydrogen is an important medium for the transition towards carbon neutral factories due to its broad applicability within the factory including its use in electricity and heat generation and as a process gas or fuel. One of the main challenges is the identification of economically and environmentally suitable design scenarios such as for the entire value chain for hydrogen generation and application. For example the infrastructure for renewable electricity hydrogen generation hydrogen conversion (e.g. into synthetic fuels) storage and transport systems as well as application in the factory. Due to the high volatility of energy generation and the related dynamic interdependencies within a factory system a valid technical economic and environmental evaluation of benefits induced by hydrogen technologies can only be achieved using digital factory models. In this paper we present a framework to integrate hydrogen technologies into factory systems. This enables decision makers to identify promising measures according to their expected impact and collect data for appropriate factory modelling. Furthermore a concept for factory modelling and simulation is presented and demonstrated in a case study from the electronics industry assessing the use of hydrogen for decentralized power and heat generation.
Prospects of Fuel Cell Combined Heat and Power Systems
Aug 2020
Publication
Combined heat and power (CHP) in a single and integrated device is concurrent or synchronized production of many sources of usable power typically electric as well as thermal. Integrating combined heat and power systems in today’s energy market will address energy scarcity global warming as well as energy-saving problems. This review highlights the system design for fuel cell CHP technologies. Key among the components discussed was the type of fuel cell stack capable of generating the maximum performance of the entire system. The type of fuel processor used was also noted to influence the systemic performance coupled with its longevity. Other components equally discussed was the power electronics. The thermal and water management was also noted to have an effect on the overall efficiency of the system. Carbon dioxide emission reduction reduction of electricity cost and grid independence were some notable advantages associated with fueling cell combined heat and power systems. Despite these merits the high initial capital cost is a key factor impeding its commercialization. It is therefore imperative that future research activities are geared towards the development of novel and cheap materials for the development of the fuel cell which will transcend into a total reduction of the entire system. Similarly robust systemic designs should equally be an active research direction. Other types of fuel aside hydrogen should equally be explored. Proper risk assessment strategies and documentation will similarly expand and accelerate the commercialization of this novel technology. Finally public sensitization of the technology will also make its acceptance and possible competition with existing forms of energy generation feasible. The work in summary showed that proton exchange membrane fuel cell (PEM fuel cell) operated at a lower temperature-oriented cogeneration has good efficiency and is very reliable. The critical issue pertaining to these systems has to do with the complication associated with water treatment. This implies that the balance of the plant would be significantly affected; likewise the purity of the gas is crucial in the performance of the system. An alternative to these systems is the PEM fuel cell systems operated at higher temperatures.
Effect on Diesel Engine Performance Parameters Using Hydrogen and Oxygen Produced on Demand
Oct 2022
Publication
Hydrogen is seen as a future energy carrier since its chemical compounds make up a large part of the Earth’s surface. This study sought to analyze the impact related to the inclusion of hydrogen and oxygen gases produced on demand by an alkaline electrolyzer to the engine added directly through the fuel intake line. For this purpose performance parameters were monitored such as liquid fuel consumption and greenhouse gas emissions and correlated to any effect observed on the engine’s power output and combustion behavior. A 58 kVA nominal power motor-generator was used coupled with a resistive load bank (20 kW) where two fuel configurations were tested (diesel injection only and a mixture of diesel hydrogen and oxygen) and compared. A total of 42 tests were performed considering both the admission gases into the fuel intake line and also diesel supply only for baseline. A substantial decrease in fuel consumption was observed (7.59%) when the blend configuration was used despite a decrease in the engine’s work (1.07%). It was also possible to see a common pattern between NO and NO2 emissions for both fuel configurations while the behavior of the CO2 and CO emissions indicated a higher complete diesel burning fraction when using the gases on demand. Therefore we can verify that the use of hydrogen and oxygen gases produced on demand in the fuel intake line is a promising alternative to provide a decrease in liquid fuel consumption and an overall improvement in engine combustion.
Numerical Modeling for Rapid Charging of Hydrogen Gas Vessel in Fuel Cell Vehicle
Feb 2023
Publication
As a fuel for power generation high-pressure hydrogen gas is widely used for transportation and its efficient storage promotes the development of fuel cell vehicles (FCVs). However as the filling process takes such a short time the maximum temperature in the storage tank usually undergoes a rapid increase which has become a thorny problem and poses great technical challenges to the steady operation of hydrogen FCVs. For security reasons SAE J2601/ISO 15869 regulates a maximum temperature limit of 85 ◦C in the specifications for refillable hydrogen tanks. In this paper a two-dimensional axisymmetric and a three-dimensional numerical model for fast charging of Type III 35 MPa and 70 MPa hydrogen vehicle cylinders are proposed in order to effectively evaluate the temperature rise within vehicle tanks. A modified standard k-ε turbulence model is utilized to simulate hydrogen gas charging. The equation of state for hydrogen gas is adopted with the thermodynamic properties taken from the National Institute of Standards and Technology (NIST) database taking into account the impact of hydrogen gas’ compressibility. To validate the numerical model three groups of hydrogen rapid refueling experimental data are chosen. After a detailed comparison it is found that the simulated results calculated by the developed numerical model are in good agreement with the experimental results with average temperature differences at the end time of 2.56 K 4.08 K and 4.3 K. The present study provides a foundation for in-depth investigations on the structural mechanics analysis of hydrogen gas vessels during fast refueling and may supply some technical guidance on the design of charging experiments.
Everything About Hydrogen Podcast: Decarbonizing Steel and Industrial Manufacturing
May 2022
Publication
H2 Green Steel was founded in 2020 with the aim to build a large-scale green steel production in northern Sweden. H2 Green Steel is on a mission to undertake the global steel industry’s greatest ever technological shift. By 2024 H2 Green Steel will be in production at their Boden site and by 2030 will produce five million tonnes of green steel annually. Vargas co-founder and a major shareholder in Northvolt is also H2 Green Steel’s founder and largest shareholder. The EAH team speaks with Kajsa Ryttberg-Wallgren head of the Hydrogen Business Unit at H2 Green Steel.
The podcast can be found on their website
The podcast can be found on their website
Optimal Scheduling of Multi-energy Type Virtual Energy Storage System in Reconfigurable Distribution Networks for Congestion Management
Jan 2023
Publication
The virtual energy storage system (VESS) is one of the emerging novel concepts among current energy storage systems (ESSs) due to the high effectiveness and reliability. In fact VESS could store surplus energy and inject the energy during the shortages at high power with larger capacities compared to the conventional ESSs in smart grids. This study investigates the optimal operation of a multi-carrier VESS including batteries thermal energy storage (TES) systems power to hydrogen (P2H) and hydrogen to power (H2P) technologies in hydrogen storage systems (HSS) and electric vehicles (EVs) in dynamic ESS. Further demand response program (DRP) for electrical and thermal loads has been considered as a tool of VESS due to the similar behavior of physical ESS. In the market three participants have considered such as electrical thermal and hydrogen markets. In addition the price uncertainties were calculated by means of scenarios as in stochastic programming while the optimization process and the operational constraints were considered to calculate the operational costs in different ESSs. However congestion in the power systems is often occurred due to the extreme load increments. Hence this study proposes a bi-level formulation system where independent system operators (ISO) manage the congestion in the upper level while VESS operators deal with the financial goals in the lower level. Moreover four case studies have considered to observe the effectiveness of each storage system and the simulation was modeled in the IEEE 33-bus system with CPLEX in GAMS.
On the Possibility to Simulate the Operation of a SI Engine using Alternative Gaseous Fuels
Nov 2019
Publication
A thermodynamic combustion model developed in AVL BOOST software was used in order to evaluate the pollutant emissions performance and efficiency parameters of a spark ignition engine Renault K7M-710 fueled with compressed natural gas hydrogen and blends of compressed natural gas and hydrogen (hythane). Multiple research studies have concluded that for the near future hythane could be the most promising alternative fuel because it has the advantages of both its components. In our previous work the model was validated for the performance and efficiency parameters by comparison of simulation results with experimental data acquired when the engine was fueled with gasoline. In this work the model was improved and can predict the values of pollutant emissions when the engine is running with the studied alternative fuels. As the percentage of hydrogen in hythane is increased the power of the engine rises the brake specific fuel consumption carbon dioxide carbon monoxide and total unburned hydrocarbon emissions decrease while nitrogen oxides increase. The values of peak fire pressure maximum pressure derivative and peak fire temperature in cycle are higher leading to an increased probability of knock occurrence. To avoid this phenomenon an optimum correlation between the natural gas-hydrogen blend the air-fuel ratio the spark advance and the engine operating condition needs to be found.
A Multi-objective Optimization Approach in Defining the Decarbonization Strategy of a Refinery
Mar 2022
Publication
Nowadays nearly one quarter of global carbon dioxide emissions are attributable to energy use in industry making this an important target for emission reductions. The scope of this study is hence that to define a cost-optimized decarbonization strategy for an energy and carbon intensive industry using an Italian refinery as a case study. The methodology involves the coupling of EnergyPLAN with a Multi-Objective Evolutionary Algorithm (MOEA) considering the minimization of annual cost and CO2 emissions as two potentially conflicting objectives and the energy technologies’ capacities as decision variables. For the target year 2025 EnergyPLAN+MOEA has allowed to model a range of 0-100 % decarbonization solutions characterized by optimal penetration mix of 22 technologies in the electrical thermal hydrogen feedstock and transport demand. A set of nine scenarios with different land use availabilities and implementable technologies each consisting of 100 optimal systems out of 10000 simulated ones has been evaluated. The results show on the one hand the possibility of achieving medium-high decarbonization solutions at costs close to current ones on the other how the decarbonization pathways strongly depend on the available land for solar thermal photovoltaic and wind as well as the presence of a biomass supply chain in the region.
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