Applications & Pathways
Hydrogen Blending and the Gas Commercial Framework - Report on Conclusions of NIA study
Sep 2020
Publication
Blending hydrogen into the gas grid could be an important stepping stone during the transition to a sustainable net zero system. In particular it may: provide a significant and reliable source of demand for hydrogen producers supporting the investment case for hydrogen; provide learnings and incremental change towards what could potentially become a 100% hydrogen grid; and immediately decarbonise a portion of the gas flowing through the grid. Technical questions relating to hydrogen blending are being taken forward by the industry (e.g. through the HyDeploy project in relation to the maximum potential blend of hydrogen that can be accommodated without end user appliances needing to be altered or replaced). But if blending is to take place changes to commercial arrangements will be necessary as today these assume a relatively uniform gas quality. In particular the commercial framework will need to ensure that limits on the percentage of hydrogen that can safely be blended (currently expected to be around 20% by volume) are not exceeded. We have been commissioned by Cadent to undertake a Network Innovation Allowance (NIA) project to identify the changes required to the gas commercial framework that will enable hydrogen blending in the GB gas grid and to set out a roadmap for how these can be delivered. This report sets out our recommendations.
Conceptual Study and Development of an Autonomously Operating, Sailing Renewable Energy Conversion System
Jun 2022
Publication
With little time left for humanity to reduce climate change to a tolerable level a highly scalable and rapidly deployable solution is needed that can be implemented by any country. Offshore wind energy in international waters is an underused resource and could even be harnessed by landlocked countries. In this paper the use of sailing wind turbines operating autonomously in high seas to harvest energy is proposed. The electrical energy that is generated by the wind turbine is converted to a renewable fuel and stored onboard. Later the fuel will be transferred to shore or to other destinations of use. The presented idea is explored at the system level where the basic subsystems necessary are identified and defined such as energy conversion and storage as well as propulsion subsystems. Moreover various operating possibilities are investigated including a comparison of different sailing strategies and fuels for storage. Existing ideas are also briefly addressed and an example concept is suggested as well. In this paper the proposed sailing renewable energy conversion system is explored at a higher level of abstraction. Following up on this conceptual study more detailed investigations are necessary to determine whether the development of such a sailing renewable energy conversion system is viable from an engineering economic and environmental point of view.
Everything About Hydrogen Podcast: FCEV's "Down Under"
Dec 2020
Publication
On today's show the EAH team will be joined by Brendan Norman to talk about deployment of sustainable FCEV technologies across many different segments of the transport sector and utility vehicles. Brendan is the CEO of H2X a new vehicle manufacturing company based in Sydney with a manufacturing facility in Port Kembla will deliver its first hydrogen FCEVs to market beginning in 2022 before expanding its vehicle offerings in subsequent years. Brendan joined the EAH team via SquadCast from Kuala Lumpur to talk fuel cells with us and you don't want to miss the excellent discussion that we had on this week's episode.
The podcast can be found on their website
The podcast can be found on their website
Incentive Structures for Power-to-X and E-fuel Pathways for Transport in EU and Member States
Jun 2022
Publication
Though Power-to-X pathways primarily Power-to-Liquids attract interest as solutions for decarbonising parts of the transport sector that are not suitable for electrification the regulatory framework until recently slowed down their implementation. This paper examines the updates in the main aspects of the legal framework in the European Union from 2019 to the beginning of 2022 related to Power-to-X: support schemes specific targets and potential barriers. The results show increasing interest and market entrance of electrolysis and push from the different actors and regulatory parties to establish solutions that will enable faster upscaling. However it is visible from the National Energy and Climate Plans and hydrogen strategies that the most emphasis is still on hydrogen as an end fuel for personal vehicles or power-to-gas. On the other hand few countries have implemented legal frameworks facilitating diverse PtX pathways without focusing solely on hydrogen. Nevertheless revisions of RED II have finally set up specific targets for electrofuels and Fit for 55 has introduced new actions supporting electrofuels in aviation and marine transport.
Wind Power to Methanol: Renewable Methanol Production Using Electricity, Electrolysis of Water and CO2 Air Capture
Feb 2020
Publication
A 100 MW stand-alone wind power to methanol process has been evaluated to determine the capital requirement and power to methanol efficiency. Power available for electrolysis determines the amount of hydrogen produced. The stoichiometric amount of CO2– required for the methanol synthesis – is produced using direct air capture. Integration of utilities for CO2 air capture hydrogen production from co-harvested water and methanol synthesis is incorporated and capital costs for all process steps are estimated. Power to methanol efficiency is determined to be around 50%. The cost of methanol is around 300€ ton−1 excluding and 800€ ton−1 including wind turbine capital cost. Excluding 300 M€ investment cost for 100 MW of wind turbines total plant capital cost is around 200 M€. About 45% of the capital cost is reserved for the electrolysers 50% for the CO2 air capture installation and 5% for the methanol synthesis system. The conceptual design and evaluation shows that renewable methanol produced from air captured CO2 water and renewable electricity is becoming a realistic option at reasonable costs of 750–800 € ton−1.
Everything About Hydrogen Podcast: Can CUTRIC Clean Canada?
Mar 2021
Publication
When the pandemic recedes lockdowns and restrictions are relaxed and eventually eliminated and millions of residents in cities across the world begin to return to their offices and workplaces public transit systems will once again be at the core of billions of commuters' daily activities. Urban transit systems are designed to move huge volumes of people through cities and communities quickly reliably and cost-efficiently (some systems accomplish these goals better than others!). The energy needed to run these networks of cars trains and buses is enormous and today most of it comes from fossil fuels. How can communities - both large and small - redesign their transit systems to eliminate operational carbon emissions in the future?
The podcast can be found on their website
The podcast can be found on their website
Integration of Hydrogen and Synthetic Natural Gas within Legacy Power Generation Facilities
Jun 2022
Publication
Whilst various new technologies for power generation are continuously being evaluated the owners of almost-new facilities such as combined-cycle gas turbine (CCGT) plants remain motivated to adapt these to new circumstances and avoid the balance-sheet financial impairments of underutilization. Not only are the owners reluctant to decommission the legacy CCGT assets but system operators value the inertia and flexibilities they contribute to a system becoming predominated with renewable generation. This analysis therefore focuses on the reinvestment cases for adapting CCGT to hydrogen (H2 ) synthetic natural gas (SNG) and/or retrofitted carbon capture and utilization systems (CCUS). Although H2 either by itself or as part of SNG has been evaluated attractively for longer-term electricity storage the business case for how it can be part of a hybrid legacy CCGT system has not been analyzed in a market context. This work compares the power to synthetic natural gas to power (PSNGP) adaptation with the simpler and less expensive power to hydrogen to power (P2HP) adaptation. Both the P2HP and PSNGP configurations are effective in terms of decarbonizations. The best results of the feasibility analysis for a UK application with low CCGT load factors (around 31%) were obtained for 100% H2 (P2HP) in the lower range of wholesale electricity prices (less than 178 GBP/MWh) but in the higher range of prices it would be preferable to use the PSNGP configuration with a low proportion of SNG (25%). If the CCGT load factor increased to 55% (the medium scenario) the breakeven profitability point between P2HP and PSNGP decreased to a market price of 145 GBP/MWh. Alternatively with the higher load factors (above 77%) satisfactory results were obtained for PSNGP using 50% SNG if with market prices above 185 GBP/MWh.
Everything About Hydrogen Podcast: Hydrogen in the E-Mobility Sector
Oct 2021
Publication
Quantron AG was created in 2019 as a high-tech spin-off of the well-known Haller GmbH & Co. KG with the vision of paving the way for e-mobility in inner-city and regional passenger and cargo transportation. Quantron AG combines innovative ability and expertise in e-vans e-trucks and e-buses with the long-standing knowledge and experience of Haller GmbH & Co. KG in the commercial vehicle sector. The company's approach to e-Mobility is defined by its commitment to leveraging the most effective zero-emission vehicle technology for the use case which means Quantron is building both hydrogen fuel cell electric vehicles (FCEVs) and battery electric vehicles (BEVs) for its clients.
The podcast can be found on the website
The podcast can be found on the website
Optimized Configuration of Diesel Engine-Fuel Cell-Battery Hybrid Power Systems in a Platform Supply Vessel to Reduce CO2 Emissions
Mar 2022
Publication
The main objective of this paper is to select the optimal configuration of a ship’s power system considering the use of fuel cells and batteries that would achieve the lowest CO2 emissions also taking into consideration the number of battery cycles. The ship analyzed in this work is a Platform Supply Vessel (PSV) used to support oil and gas offshore platforms transporting goods equipment and personnel. The proposed scheme considers the ship’s retrofitting. The ship’s original main generators are maintained and the fuel cell and batteries are installed as complementary sources. Moreover a sensitivity analysis is pursued on the ship’s demand curve. The simulations used to calculate the CO2 emissions for each of the new hybrid configurations were developed using HOMER software. The proposed solutions are auxiliary generators three types of batteries and a protonexchange membrane fuel cell (PEMFC) with different sizes of hydrogen tanks. The PEMFC and batteries were sized as containerized solutions and the sizing of the auxiliary engines was based on previous works. Each configuration consists of a combination of these solutions. The selection of the best configuration is one contribution of this paper. The new configurations are classified according to the reduction of CO2 emitted in comparison to the original system. For different demand levels the results indicate that the configuration classification may vary. Another valuable contribution of this work is the sizing of the battery and hydrogen storage systems. They were installed in 20 ft containers since the installation of batteries fuel cells and hydrogen tanks in containers is widely used for ship retrofit. As a result the most significant reduction of CO2 emissions is 10.69%. This is achieved when the configuration includes main generators auxiliary generators a 3119 kW lithium nickel manganese cobalt (LNMC) battery a 250 kW PEMFC and 581 kg of stored hydrogen.
Porosity and Thickness Effect of Pd–Cu–Si Metallic Glasses on Electrocatalytic Hydrogen Production and Storage
Aug 2021
Publication
This contribution places emphasis on tuning pore architecture and film thickness of mesoporous Pd–Cu–Si thin films sputtered on Si/SiO2 substrates for enhanced electrocatalytic and hydrogen sorption/desorption activity and their comparison with the state-of-the-art thin film electrocatalysts. Small Tafel slope of 43 mV dec–1 for 1250 nm thick coatings with 2 µm diameter pores with 4.2 µm interspacing (H2) electrocatalyst with comparable hydrogen overpotentials to the literature suggests its use for standard fuel cells. The largest hydrogen sorption has been attained for the 250 nm thick electrocatalyst on 5 µm pore diameter and 12 µm interspacing (2189 µC cm–2 per CV cycle) making it possible for rapid storage systems. Moreover the charge transfer resistance described by an equivalent circuit model has an excellent correlation with Tafel slopes. Along with its very low Tafel slope of 42 mV dec–1 10 nm thick H2 pore design electrocatalyst has the highest capacitive response of ∼0.001 S sn cm–2 and is promising to be used as a nano-charger and hydrogen sensor.
The Role of Research and Innovation in Europe for the Decarbonisation of Waterborne Transport
Sep 2021
Publication
Waterborne transport contributes to around 14% of the overall greenhouse gas emissions of transport in the European Union and it is among the most efficient modes of transport. Nonetheless considering the aim of making the European Union carbon-neutral by 2050 and the fundamental role of waterborne transport within the European economy effort is needed to reduce its environmental impact. This paper provides an assessment of research and innovation measures aiming at decreasing waterborne transport’s CO2 emissions by assessing European projects based on the European Commission’s Transport Research and Innovation Monitoring and Information System (TRIMIS). Additionally it provides an outlook of the evolution of scientific publications and intellectual property activity in the area. The review of project findings suggests that there is no single measure which can be considered as a problem solver in the area of the reduction of waterborne CO2 emissions and only the combination of different innovations should enable reaching this goal. The highlighted potential innovations include further development of lightweight composite materials innovative hull repair methods wind assisted propulsion engine efficiency waste heat electrification hydrogen and alternative fuels. The assessment shows prevalence of funding allocated to technological measures; however non-technological ones like improved vessel navigation and allocation systems also show a great potential for the reduction of CO2 emissions and reduction of negative environmental impacts of waterborne transport.
Improvement of Temperature and Humidity Control of Proton Exchange Membrane Fuel Cells
Sep 2021
Publication
Temperature and humidity are two important interconnected factors in the performance of PEMFCs (Proton Exchange Membrane Fuel Cells). The fuel and oxidant humidity and stack temperature in a fuel cell were analyzed in this study. There are many factors that affect the temperature and humidity of the stack. We adopt the fuzzy control method of multi-input and multi-output to control the temperature and humidity of the stack. A model including a driver vehicle transmission motor air feeding electrical network stack hydrogen supply and cooling system was established to study the fuel cell performance. A fuzzy controller is proven to be better in improving the output power of fuel cells. The three control objectives are the fan speed control for regulating temperature the solenoid valve on/off control of the bubble humidifier for humidity variation and the speed of the pump for regulating temperature difference. In addition the results from the PID controller stack model and the fuzzy controller stack model are compared in this research. The fuel cell bench test has been built to validate the effectiveness of the proposed fuzzy control. The maximum temperature of the stack can be reduced by 5 ◦C with the fuzzy control in this paper so the fuel cell output voltage (power) increases by an average of approximately 5.8%.
Application of Hydrogen and Hydrogen-containing Gases in Internal Combustion Engines
Nov 2019
Publication
The results of studies of the influence of hydrogen and hydrogen-containing gas additives on the parameters of various types of internal combustion engines are analyzed and summarized. It made possible to identify the features of the effect on the combustion of fuel during internal combustion engine operation at partial loads. The dependences of reducing the toxicity and fuel consumption of internal combustion engine on the amount of addition of hydrogen and a hydrogen-containing gas to the air-fuel mixture were obtained. It allowed to establish quantitative effects of free hydrogen in particular to quantify the region of small hydrogen additives and the conditions under which hydrogen exhibits the qualities of a chemically active component of the mixture.
A Numerical Investigation on De-NOx Technology and Abnormal Combustion Control for a Hydrogen Engine with EGR System
Sep 2020
Publication
The combustion emissions of the hydrogen-fueled engines are very clean but the problems of abnormal combustion and high NOx emissions limit their applications. Nowadays hydrogen engines use exhaust gas recirculation (EGR) technology to control the intensity of premixed combustion and reduce the NOx emissions. This study aims at improving the abnormal combustion and decreasing the NOx emissions of the hydrogen engine by applying a three-dimensional (3D) computational fluid dynamics (CFD) model of a single-cylinder hydrogen-fueled engine equipped with an EGR system. The results indicated that peak in-cylinder pressure continuously increased with the increase of the ignition advance angle and was closer to the top dead center (TDC). In addition the mixture was burned violently near the theoretical air–fuel ratio and the combustion duration was shortened. Moreover the NOx emissions the average pressure and the in-cylinder temperature decreased as the EGR ratio increased. Furthermore increasing the EGR ratio led to an increase in the combustion duration and a decrease in the peak heat release rate. EGR system could delay the spontaneous combustion reaction of the end-gas and reduce the probability of knocking. The pressure rise rate was controlled and the in-cylinder hot spots were reduced by the EGR system which could suppress the occurrence of the pre-ignition in the hydrogen engine.
Techno-economic Analysis of High-Pressure Metal Hydride Compression Systems
Jun 2018
Publication
Traditional high-pressure mechanical compressors account for over half of the car station’s cost have insufficient reliability and are not feasible for a large-scale fuel cell market. An alternative technology employing a two-stage hybrid system based on electrochemical and metal hydride compression technologies represents an excellent alternative to conventional compressors. The high-pressure stage operating at 100–875 bar is based on a metal hydride thermal system. A techno-economic analysis of the metal hydride system is presented and discussed. A model of the metal hydride system was developed integrating a lumped parameter mass and energy balance model with an economic model. A novel metal hydride heat exchanger configuration is also presented based on minichannel heat transfer systems allowing for effective high-pressure compression. Several metal hydrides were analyzed and screened demonstrating that one selected material namely (Ti0.97Zr0.03)1.1Cr1.6Mn0.4 is likely the best candidate material to be employed for high-pressure compressors under the specific conditions. System efficiency and costs were assessed based on the properties of currently available materials at industrial levels. Results show that the system can reach pressures on the order of 875 bar with thermal power provided at approximately 150 ◦C. The system cost is comparable with the current mechanical compressors and can be reduced in several ways as discussed in the paper.
Life Cycle Assessment of Waste-to-hydrogen Systems for Fuel Cell Electric Buses in Glasgow, Scotland
Jun 2022
Publication
Waste-to-hydrogen (WtH) technologies are proposed as a dual-purpose method for simultaneous non-fossil-fuel based hydrogen production and sustainable waste management. This work applied the life cycle assessment approach to evaluate the carbon saving potential of two main WtH technologies (gasification and fermentation) in comparison to the conventional hydrogen production method of steam methane reforming (SMR) powering fuel cell electric buses in Glasgow. It was shown that WtH technologies could reduce CO2-eq emissions per kg H2 by 50–69% as compared to SMR. Gasification treating municipal solid waste and waste wood had global warming potentials of 4.99 and 4.11 kg CO2-eq/kg H2 respectively which were lower than dark fermentation treating wet waste at 6.6 kg CO2-eq/kg H2 and combined dark and photo fermentation at 6.4 kg CO2-eq/kg H2. The distance emissions of WtH-based fuel cell electric bus scenarios were 0.33–0.44 kg CO2-eq/km as compared to 0.89 kg CO2-eq/km for the SMR-based scenario.
Everything About Hydrogen Podcast: Digging into the Mining Industry
Jan 2021
Publication
On this episode of Everything About Hydrogen Jan Klawitter Head of International Policy for Anglo American speaks with Andrew Chris and Patrick about Anglo American's strategy for decarbonizing its mining operations and how they plan to use hydrogen and fuel cell technologies as a key part of their approach.
The podcast can be found on their website
The podcast can be found on their website
Repurposing Fischer-Tropsch and Natural Gas as Bridging Technologies for the Energy Revolution
Jun 2022
Publication
Immediate and widespread changes in energy generation and use are critical to safeguard our future on this planet. However while the necessity of renewable electricity generation is clear the aviation transport and mobility chemical and material sectors are challenging to fully electrify. The age-old Fischer-Tropsch process and natural gas industry could be the bridging solution needed to accelerate the energy revolution in these sectors – temporarily powering obsolete vehicles acting as renewable energy’s battery supporting expansion of hydrogen fuel cell technologies and the agricultural and waste sectors as they struggle to keep up with a full switch to biofuels. Natural gas can be converted into hydrogen synthetic natural gas or heat during periods of low electricity demand and converted back to electricity again when needed. Moving methane through existing networks and converting it to hydrogen on-site at tanking stations also overcomes hydrogen distribution storage problems and infrastructure deficiencies. Useful co-products include carbon nanotubes a valuable engineering material that offset emissions in the carbon nanotube and black industries. Finally excess carbon can be converted back into syngas if desired. This flexibility and the compatibility of natural gas with both existing and future technologies provides a unique opportunity to rapidly decarbonise sectors struggling with complex requirements.
Effect of Carbon Monoxide on Polymer Electrolyte Fuel Cell Performance with a Hydrogen Circulation System
Feb 2022
Publication
The effect of carbon monoxide (CO) on the performance of polymer electrolyte fuel cells (PEFCs) with either a hydrogen circulation system or a hydrogen one-way pass system is investigated and compared. The voltage drop induced by adding 0.2 ppm of CO to the PEFC with the hydrogen circulation system was less than one-tenth of that observed in the PEFC with the hydrogen one-way pass system at 1000 mA cm–2 and a cell temperature of 60 °C. Gas analysis results showed that CO concentration in the hydrogen circulation system was lower than the initially supplied CO concentration. In the hydrogen circulation system permeated oxygen from the cathode should enhance CO oxidation. This should lead to decrease the CO concentration and mitigate the voltage drop in the hydrogen circulation system.
Everything About Hydrogen Podcast: High-temperature Fuel Cells at High Altitudes
Jun 2021
Publication
HyPoint led by its CEO and co-founder Alex Ivanenko is at the cutting edge of the industry's efforts to find zero-emissions aircraft propulsion systems that do not sacrifice speed and power in the name of sustainability. HyPoint is a leading producer of high-temperature PEM fuel cells for aviation applications including for logistic drones air taxis electric vertical takeoff and landing vehicles (eVTOLs) and fixed-wing airplanes. On this episode of the EAH podcast the team speaks with Alex about the incredible pace of development and rapid innovation that he and his colleagues are driving in the hydrogen aviation space and how his company is leading the way in a highly complex and competitive race to decarbonize modern air travel.
The podcast can be found on their website
The podcast can be found on their website
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