Applications & Pathways
The Influence of Hydrogen Desorption on Micromechanical Properties and Tribological Behavior of Iron and Carbon Steels
Dec 2018
Publication
The influence of the previous electrolytic hydrogenation on the micromechanical properties and tribological behavior of the surface layers of iron and carbon steels has been studied. The concentrations of diffusion-moving and residual hydrogen in steels are determined depending on the carbon content. It is shown that the amount of sorbed hydrogen is determined by the density of dislocations and the relative volume of cementite. After desorption of diffusion-moving hydrogen the microhardness increases and materials plasticity decreases. The change of these characteristics decreases with the increase of carbon content in the steels. Internal stresses increase and redistribute under hydrogen desorption. Fragmentation of ferrite and perlite occurs as a result of electrolytic hydrogenation. Ferrite is characterized by the structure fragmentation and change of the crystallographic orientation of planes. The perlite structure shows the crushing of cementite plates and their destruction. The influence of hydrogen desorption on the microhardness of structural components of ferrite-perlite steels is shown. Large scattering of microhardness is found in perlite due to different diffusion rates of hydrogen because of the unequally oriented cementite plates. It was found that the tendency of materials to blister formation is reduced with the increase of carbon content. The influence of hydrogen on the tribological behaviour of steels under dry and boundary friction has been studied. It is shown that hydrogen desorption intensifies the materials wear. After hydrogen desorption tribological behaviour is determined by the adhesion interaction between the contacting pairs.
Initial Assessment of a Fuel Cell—Gas Turbine Hybrid Propulsion Concept
Jan 2022
Publication
A fuel cell—gas turbine hybrid propulsion concept is introduced and initially assessed. The concept uses the water mass flow produced by a hydrogen fuel cell in order to improve the efficiency and power output of the gas turbine engine through burner steam injection. Therefore the fuel cell product water is conditioned through a process of condensation pressurization and revaporization. The vaporization uses the waste heat of the gas turbine exhaust. The functional principles of the system concept are introduced and discussed and appropriate methodology for an initial concept evaluation is formulated. Essential technology fields are surveyed in brief. The impact of burner steam injection on gas turbine efficiency and sizing is parametrically modelled. Simplified parametric models of the fuel cell system and key components of the water treatment process are presented. Fuel cell stack efficiency and specific power levels are methodically derived from latest experimental studies at the laboratory scale. The overall concept is assessed for a liquid hydrogen fueled short-/medium range aircraft application. Block fuel savings of up to 7.1% are found for an optimum design case based on solid oxide fuel cell technology. The optimum design features a gas turbine water-to-air ratio of 6.1% in cruise and 62% reduced high-level NOx emissions.
An Energy Autonomous House Equipped with a Solar PV Hydrogen Conversion System
Dec 2015
Publication
The use of RES in buildings is difficult for their random nature; therefore the plants using photovoltaic solar collectors must be connected to a power supply or interconnected with Energy accumulators if the building is isolated. The conversion of electricity into hydrogen technology is best suited to solve the problem and allows you to transfer the solar energy captured from day to night from summer to winter. This paper presents the feasibility study for a house powered by PV cogeneration solar collectors that reverse the electricity on the control unit that you command by a PC to power the household using a heat pump an electrolytic cell for the production of hydrogen to accumulate; control units sorting to the utilities the electricity produced by the fuel cell. The following are presented: The Energy analysis of the building the plant design economic analysis.
Deep-Decarbonisation Pathways for UK Industry
Dec 2020
Publication
The Climate Change Committee (CCC) commissioned Element Energy to improve our evidence base on the potential of industrial deep-decarbonisation measures (fuel switching CCS/BECCS measures to reduce methane emissions) and develop pathways for their application. This report summarises the evidence and results of the work including:
- Evidence on the key constraints and costs for technology and infrastructure deployment
- The methodology and new Net Zero Industry Pathway (N-ZIP) model used to determine deep-decarbonisation pathways for UK industry (drawing on the evidence above)
- A set of pathways and wider sensitivities produced using the N-ZIP model which fed into the CCC’s Sixth Carbon Budget pathways
- Recommended actions and policy measures as informed by the study.
Sector Coupling Potential of Wind-based Hydrogen Production and Fuel Cell Train Operation in Regional Rail Transport in Berlin and Brandenburg
Jan 2021
Publication
As the transport sector is ought to be decarbonized fuel-cell-powered trains are a viable zero-tailpipe technology alternative to the widely employed diesel multiple units in regional railway service on non-electrified tracks. Carbon-free hydrogen can be provided by water-electrolysis from renewable energies. In this study we introduce an approach to assess the potential of wind-based hydrogen for use in adjacent regional rail transport by applying a GIS approach in conjunction with a site-level cost model. In Brandenburg about 10.1 million train-km annually could be switched to fuel cell electric train operation. This relates to a diesel consumption of appr. 9.5 million liters today. If fuel cell trains would be employed that translated to 2198 annual tons hydrogen annually. At favorable sites hydrogen costs of approx. 6.40 €/kg - including costs of hydrogen refueling stations - could be achieved. Making excess hydrogen available for other consumers would further decrease hydrogen production costs.
Hydrogen Refueling Station Networks for Heavy-duty Vehicles in Future Power Systems
May 2020
Publication
A potential solution to reduce greenhouse gas (GHG) emissions in the transport sector is to use alternatively fuelled vehicles (AFV). Heavy-duty vehicles (HDV) emit a large share of GHG emissions in the transport sector and are therefore the subject of growing attention from global regulators. Fuel cell and green hydrogen technologies are a promising option to decarbonize HDVs as their fast refuelling and long vehicle ranges are consistent with current logistic operational requirements. Moreover the application of green hydrogen in transport could enable more effective integration of renewable energies (RE) across different energy sectors. This paper explores the interplay between HDV Hydrogen Refuelling Stations (HRS) that produce hydrogen locally and the power system by combining an infrastructure location planning model and an electricity system optimization model that takes grid expansion options into account. Two scenarios – one sizing refuelling stations to support the power system and one sizing them independently of it – are assessed regarding their impacts on the total annual electricity system costs regional RE integration and the levelized cost of hydrogen (LCOH). The impacts are calculated based on locational marginal pricing for 2050. Depending on the integration scenario we find average LCOH of between 4.83 euro/kg and 5.36 euro/kg for which nodal electricity prices are the main determining factor as well as a strong difference in LCOH between north and south Germany. Adding HDV-HRS incurs power transmission expansion as well as higher power supply costs as the total power demand increases. From a system perspective investing in HDV-HRS in symbiosis with the power system rather than independently promises cost savings of around seven billion euros per annum. We therefore conclude that the co-optimization of multiple energy sectors is important for investment planning and has the potential to exploit synergies.
Electric and Hydrogen Rail: Potential Contribution to Net Zero in the UK
Sep 2020
Publication
Electric trains (ET) and hydrogen trains (HT) are considered zero emission at the point of use. True emissions are dependent upon non-tailpipe sources primarily in energy production. We present UK carbon dioxide (CO2) operating emission model outputs for conventionally fuelled trains (CFT) ETs and HTs between 2017 and 2050 under four National Grid electricity generation scenarios.
Comparing four service categories (urban regional intercity and high speed) to private conventionally fuelled vehicles (CFV) and electric vehicles considering average distance travelled per trip under different passenger capacity levels (125% 100% 75% 50% and 25%).
Results indicate by 2050 at 100% capacity CFTs produce a fifth of the emissions of CFVs per kilometre per person. Under two degree generation scenario by 2050 ETs produced 14 times and HTs produced five times less emissions than CFTs. Policymakers should encourage shifts away from private vehicles to public transport powered by low carbon electricity.
Comparing four service categories (urban regional intercity and high speed) to private conventionally fuelled vehicles (CFV) and electric vehicles considering average distance travelled per trip under different passenger capacity levels (125% 100% 75% 50% and 25%).
Results indicate by 2050 at 100% capacity CFTs produce a fifth of the emissions of CFVs per kilometre per person. Under two degree generation scenario by 2050 ETs produced 14 times and HTs produced five times less emissions than CFTs. Policymakers should encourage shifts away from private vehicles to public transport powered by low carbon electricity.
Hydrogen Powered Aviation: A Fact-based Study of Hydrogen Technology, Economics, and Climate Impact by 2050
Jul 2020
Publication
This report assesses the potential of hydrogen (H2) propulsion to reduce aviation’s climate impact. To reduce climate impact the industry will have to introduce further levers such as radically new technology significantly scale sustainable aviation fuels (SAF) such as synthetic fuel (synfuel) temporarily rely on offsets in large quantities or rely on a combination thereof. H2 propulsion is one such technology and this report assesses its potential in aviation. Developed with input from leading companies and research institutes it projects the technological development of H2 combustion and fuel cell-powered propulsion evaluates their technical and economic feasibility compares them to synfuel and considers implications on aircraft design airport infrastructure and fuel supply chains.
Expected Impacts on Greenhouse Gas and Air Pollutant Emissions Due to a Possible Transition Towards a Hydrogen Economy in German Road Transport
Nov 2020
Publication
Transitioning German road transport partially to hydrogen energy is among the possibilities being discussed to help meet national climate targets. This study investigates impacts of a hypothetical complete transition from conventionally-fuelled to hydrogen-powered German transport through representative scenarios. Our results show that German emissions change between −179 and +95 MtCO2eq annually depending on the scenario with renewable-powered electrolysis leading to the greatest emissions reduction while electrolysis using the fossil-intense current electricity mix leads to the greatest increase. German energy emissions of regulated pollutants decrease significantly indicating the potential for simultaneous air quality improvements. Vehicular hydrogen demand is 1000 PJ annually requiring 446–525 TWh for electrolysis hydrogen transport and storage which could be supplied by future German renewable generation supporting the potential for CO2-free hydrogen traffic and increased energy security. Thus hydrogen-powered transport could contribute significantly to climate and air quality goals warranting further research and political discussion about this possibility.
South Korea’s Big Move to Hydrogen Society
Nov 2020
Publication
Extensive energy consumption has become a major concern due to increase of greenhouse gas emissions and global warming. Hence hydrogen has attracted attention as a green fuel with zero carbon emission for green transportation through production of electric vehicles with hydrogen fuel cells. South Korea has launched a hydrogen society policy with the objective of expanding production of hydrogen from renewable energy sources. The hydrogen economy will play a critical role in reducing atmospheric pollution and global arming. However new development of infrastructure for hydrogen refuelling and increasing awareness of the hydrogen economy is required together with reduced prices of hydrogen-driven vehicles that are promising options for a sustainable green hydrogen economy.
CFD Simulations of Filling and Emptying of Hydrogen Tanks
Jun 2016
Publication
During the filling of hydrogen tanks high temperatures can be generated inside the vessel because of the gas compression while during the emptying low temperatures can be reached because of the gas expansion. The design temperature range goes from −40 °C to 85 °C. Temperatures outside that range could affect the mechanical properties of the tank materials. CFD analyses of the filling and emptying processes have been performed in the HyTransfer project. To assess the accuracy of the CFD model the simulation results have been compared with new experimental data for different filling and emptying strategies. The comparison between experiments and simulations is shown for the temperatures of the gas inside the tank for the temperatures at the interface between the liner and the composite material and for the temperatures on the external surface of the vessel.
Strategies for Joint Procurement of Fuel Cell Buses: A Study for the Fuel Cells and Hydrogen Joint Undertaking
Jun 2018
Publication
The Fuel Cells and Hydrogen Joint Undertaking (FCH JU) has supported a range of initiatives in recent years designed to develop hydrogen fuel cell buses to a point where they can fulfil their promise as a mainstream zero emission vehicle for public transport.<br/>Within this study 90 different European cities and regions have been supported in understanding the business case of fuel cell bus deployment and across these locations. The study analyses the funding and financing for fuel cell bus deployment to make them become a mainstream zero emission choice for public transport providers in cities and regions across Europe. It also outlines possible solutions for further deployment of FC buses beyond the subsidised phase.<br/>In the light of the experience of the joint tender process in the UK and in Germany the study highlights best practices for ordering fuel cell buses. Other innovative instruments explored in other countries for the orders of large quantities of fuel cells buses are presented: Special Purpose Vehicles and centralised purchase office. Finally the study deeply analyses the funding and financing for fuel cell bus deployment to make them become a mainstream zero emission choice for public transport providers in cities and regions across Europe.
Well-to-wheel Greenhouse Gas Emissions of Heavy-duty Transports: Influence of Electricity Carbon Intensity
Feb 2021
Publication
There are several alternatives for how to phase out diesel in heavy-duty transports thereby reducing the sector’s climate change impact. This paper assesses the well-to-wheel (WTW) greenhouse gas (GHG) emissions of energy carriers for heavy-duty vehicles analyzing the effect of the carbon intensity of the electricity used in production. The results show that energy carriers with high electricity dependence are not necessarily better than diesel from a WTW perspective. In particular fuels produced through electrolysis are not well suited in carbon-intense electricity systems. Conversely waste-based biofuels have low GHG emissions regardless of the electricity system. Battery-electric buses show a large reduction of GHG emissions compared to diesel buses and many other alternatives while battery-electric trucks have higher GHG emissions than diesel in carbon intense electricity systems. Thus electrifying transports or switching to renewable fuels will not suffice if the electricity system is not made renewable first.
A Roadmap for Financing Hydrogen Refueling Networks – Creating Prerequisites for H2-based Mobility
Sep 2014
Publication
Fuel cell electric vehicles (FCEVs) are zero tailpipe emission vehicles. Their large-scale deployment is expected to play a major role in the de-carbonization of transportation in the European Union (EU) and is therefore an important policy element at EU and Member State level.<br/>For FCEVs to be introduced to the market a network of hydrogen refuelling stations (HRS) first has to exist. From a technological point of view FCEVs are ready for serial production already: Hyundaiand Toyota plan to introduce FCEVs into key markets from 2015 and Daimler Ford and Nissan plan to launch mass-market FCEVs in 2017.<br/>At the moment raising funds for building the hydrogen refuelling infrastructure appears to be challenging.<br/>This study explores options for financing the HRS rollout which facilitate the involvement of private lenders and investors. It presents a number of different financing options involving public-sector bank loans funding from private-sector strategic equity investors commercial bank loans private equity and funding from infrastructure investors. The options outline the various requirements forn accessing these sources of funding with regard to project structure incentives and risk mitigation. The financing options were developed on the basis of discussions with stakeholders in the HRS rollout from industry and with financiers.<br/>This study was prepared by Roland Berger in close contact with European Investment banks and a series of private banks.<br/>This study explores in details the business cases for HRS in Germany and UK. The conclusion can be easily extrapolate to other countries.
Fuel Cell Electric Buses: Potential for Sustainable Public Transport in Europe
Oct 2015
Publication
This report provides an outlook for jointly achieving a commercialisation pathway.<br/>Building on the findings of the 2012 FCH JU technology study on alternative powertrains for urban buses this report provides an assessment of the commercialisation pathway from an operational perspective. It reflects the actual situation in which operators deploy large scale demonstration projects in the next years from a rather conservative angle and argues why it makes sense to deploy FC buses now. The insights are based on first-hand data and assessments of the coalition members from the hydrogen and fuel cell industry as well as local governments and public transport operators in Europe.
FCH JU – Key to Sustainable Energy and Transport
Jan 2019
Publication
This brochure offers an overview of the main applications of fuel cell and hydrogen technologies and how they work and provides insights into our programme and our accomplishments.
Review of Energy Portfolio Optimization in Energy Markets Considering Flexibility of Power-to-X
Mar 2023
Publication
Power-to-X is one of the most attention-grabbing topics in the energy sector. Researchers are exploring the potential of harnessing power from renewable technologies and converting it into fuels used in various industries and the transportation sector. With the current market and research emphasis on Power-to-X and the accompanying substantial investments a review of Power-to-X is becoming essential. Optimization will be a crucial aspect of managing an energy portfolio that includes Power-to-X and electrolysis systems as the electrolyzer can participate in multiple markets. Based on the current literature and published reviews none of them adequately showcase the state-of-the-art optimization algorithms for energy portfolios focusing on Power-to-X. Therefore this paper provides an in-depth review of the optimization algorithms applied to energy portfolios with a specific emphasis on Power-to-X aiming to uncover the current state-of-the-art in the field.
Comparative Life Cycle Assessment of Battery and Fuel Cell Electric Cars, Trucks, and Buses
Mar 2024
Publication
Addressing the pressing challenge of global warming reducing greenhouse gas emissions in the transportation sector is a critical imperative. Battery and fuel cell electric vehicles have emerged as promising solutions for curbing emissions in this sector. In this study we conducted a comprehensive life cycle assessment (LCA) for typical passenger vehicles heavy-duty trucks and city buses using either proton-exchange membrane fuel cells or Li-ion batteries with different cell chemistries. To ensure accuracy we supplemented existing studies with data from the literature particularly for the recycling phase as database limitations were encountered. Our results highlight that fuel cell and battery systems exhibit large emissions in the production phase. Recycling can significantly offset some of these emissions but a comparison of the technologies examined revealed considerable differences. Overall battery electric vehicles consistently outperform fuel cell electric vehicles regarding absolute greenhouse gas emissions. Hence we recommend prioritizing battery electric over fuel cell vehicles. However deploying fuel cell electric vehicles could become attractive in a hydrogen economy scenario where other factors e. g. the conversion and storage of surplus renewable electricity via electrolysis become important.
Permeation Tests in Type-approval Regulations for Hydrogen Fuelled Vehicles: Analysis and Testing Experiences at the JRC-GASTEF Facility
Jan 2023
Publication
This article presents an analysis of the permeation tests established in the current regulations for the type-approval of on board tanks in hydrogen vehicles. The analysis is done from the point of view of a test maker regarding the preparation for the execution of a permeation test. The article contains a description of the required instrumentation and set-up to carry out a permeation test according to the applicable standards and regulations. Tank conditions at the beginning of the test configuration of permeation chamber duration of the test or permeation rate to be reported are aspects that are not well-defined in regulations. In this paper we examine the challenges when carrying out a permeation test and propose possible solutions to overcome them with the intention of supporting test makers and helping the development of permeation test guidelines.
Life-cycle Assessment of Hydrogen Utilization in Power Generation: A Systematic Review of Technological and Methodological Choices
Jul 2022
Publication
Interest in reducing the greenhouse gas emissions from conventional power generation has increased the focus on the potential use of hydrogen to produce electricity. Numerous life-cycle assessment (LCA) studies of hydrogen-based power generation have been published. This study reviews the technological and methodological choices made in hydrogen-based power generation LCAs. A systematic review was chosen as the research method to achieve a comprehensive and minimally biased overview of hydrogen-based power generation LCAs. Relevant articles published between 2004 and 2021 were identified by searching the Scopus and Web of Science databases. Electrolysis from renewable energy resources was the most widely considered type of hydrogen production in the LCAs analyzed. Fuel cell technology was the most common conversion equipment used in hydrogen-based electricity LCAs. A significant number of scenarios examine the use of hydrogen for energy storage and co-generation purposes. Based on qualitative analysis the methodological choices of LCAs vary between studies in terms of the functional units allocations system boundaries and life-cycle impact assessment methods chosen. These discrepancies were likely to influence the value of the environmental impact results. The findings of the reviewed LCAs could provide an environmental profile of hydrogen-based electricity systems identify hotspots drive future research define performance goals and establish a baseline for their large-scale deployment.
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