China, People’s Republic
Sustainable Hydrogen Production from Waste Plastics via Staged Chemical Looping Gasification with Iron-based Oxygen Carrier
Aug 2025
Publication
Thermo-chemical conversion of waste plastics offers a sustainable strategy for integrated waste management and clean energy generation. To address the challenges of low gas yield and rapid catalyst deactivation due to coking in conventional gasification processes an innovative three-stage chemical looping gasification (CLG) system specifically designed for enhanced hydrogen-rich syngas production was proposed in this work. A comparative analysis between conventional gasification and the staged CLG system were firstly conducted coupled with online gas analysis for mechanistic elucidation. The influence of Fe/Al molar ratios in oxygen carriers and their cyclic stability were systematically examined through multicycle experiments. Results showed that the three-stage CLG in the presence of Fe1Al2 demonstrated exceptional performance achieving 95.23 mmol/gplastic of H2 and 129.89 mmol/gplastic of syngas respectively representing 1.32-fold enhancement over conventional method. And the increased H2/CO ratio (2.68-2.75) reflected better syngas quality via water-gas shift. Remarkably the oxygen carrier maintained nearly 100% of its initial activity after 7 redox cycles attributed to the incorporation of Al2O3 effectively mitigating sintering and phase segregation through metal-support interactions. These findings establish a three-stage CLG configuration with Fe-Al oxygen carriers as an efficient platform for efficient hydrogen production from waste plastics contributing to sustainable waste valorisation and carbon-neutral energy systems.
Coordinated Operation of Alternative Fuel Vehicle-integrated Microgrid in a Coupled Power-transportation Network: A Stackelberg-Nash Game Framework
Sep 2025
Publication
With the rapid development of alternative fuel vehicles (AFVs) and renewable energy sources the increasing coordination between electric vehicles (EVs) and hydrogen vehicles (HVs) in urban coupled powertransportation networks (CPTNs) fosters optimized energy scheduling and enhanced system performance. This study proposes a two-level Stackelberg-Nash game framework for AFV-integrated microgrids in a CPTN to enhance the economic efficiency of microgrid. This framework employs a Stackelberg game model to define the leader-follower relationship between the microgrid operator and the vehicle-to-grid (V2G) aggregator. Nash equilibrium games are established to capture competitive interactions among charging stations (CSs) and among hydrogen refueling stations (HRSs). Furthermore an optimal scheduling model is proposed to minimize microgrid operation costs considering the spatiotemporal dynamics and user preferences of EVs and HVs supported by the proposed dynamic choice model. A game-theoretic pricing and incentive mechanism promotes AFV participation in V2G services enhancing the profitability of CSs and HRSs. Afterward a momentum-enhanced Stackelberg-Nash equilibrium algorithm is developed to address the bi-level optimization problem. Finally numerical simulations validate the effectiveness of the proposed method in improving economic efficiency and reducing operation costs. The proposed approach offers an effective solution for integrating large-scale AFV fleets into sustainable urban energy and transportation systems.
Exploration of Processability Limitations of Fiber Placement and Thickness Stacking Optimization of Thermoplastic Composite Hydrogen Storage Cylinders for Hydrogen-powered Aircraft
Dec 2024
Publication
Hydrogen-powered aircraft as a cutting-edge exploration of clean-energy air transportation have more stringent requirements for lightweight hydrogen storage equipment due to the limitations of aircraft weight and volume. Composite hydrogen storage cylinders have become one of the preferred solutions for hydrogen storage systems in hydrogen-powered aircraft due to their light weight and high strength. However during the automated placement of high-stiffness thermoplastic composites (T700/PEEK) fibers can buckle or fracture in the header section. As the header radius decreases the overlap of adjacent tows increases resulting in buildup in the thickness of the polar pores which contradicts the lightweight requirements. To solve this problem this paper derives the trajectory algorithm as a manufacturing process limitation when thermoplastic fiber bundles are laid without wrinkles and the effect of different ellipsoid ratios of head profile changes on the overlap of fiber bundles is investigated. The larger the ellipsoid ratio of the prolate ellipsoid is the smaller overlap of gaps generated by neighboring fiber bundles is and the overlap at the pole holes is also smaller whereas the change of the oblate ellipsoid is not significant. The prolate ellipsoid has more application and research value than the oblate ellipsoid in terms of processability which is of great exploration significance for the design and fabrication of thermoplastic composite hydrogen storage cylinders for hydrogen-powered aircraft.
The Energy Management Strategies for Fuel Cell Electric Vehicles: An Overview and Future Directions
Sep 2025
Publication
The rapid development of fuel cell electric vehicles (FCEVs) has highlighted the critical importance of optimizing energy management strategies to improve vehicle performance energy efficiency durability and reduce hydrogen consumption and operational costs. However existing approaches often face limitations in real-time applicability adaptability to varying driving conditions and computational efficiency. This paper aims to provide a comprehensive review of the current state of FCEV energy management strategies systematically classifying methods and evaluating their technical principles advantages and practical limitations. Key techniques including optimization-based methods (dynamic programming model predictive control) and machine learning-based approaches (reinforcement learning deep neural networks) are analyzed and compared in terms of energy distribution efficiency computational demand system complexity and real-time performance. The review also addresses emerging technologies such as artificial intelligence vehicle-to-everything (V2X) communication and multi-energy collaborative control. The outcomes highlight the main bottlenecks in current strategies their engineering applicability and potential for improvement. This study provides theoretical guidance and practical reference for the design implementation and advancement of intelligent and adaptive energy management systems in FCEVs contributing to the broader goal of efficient and low-carbon vehicle operation.
The Effect of Jet-Induced Disturbances on the Flame Characteristics of Hydrogen–Air Mixtures
Oct 2025
Publication
To mitigate explosion hazards arising from hydrogen leakage and subsequent mixing with air the injection of inert gases can substantially diminish explosion risk. However prevailing research has predominantly characterized inert gas dilution effects on explosion behavior under quiescent conditions largely neglecting the turbulence-mediated explosion enhancement inherent to dynamic mixing scenarios. A comprehensive investigation was conducted on the combustion behavior of 30% 50% and 70% H2-air mixtures subjected to jet-induced (CO2 N2 He) turbulent flow incorporating quantitative characterization of both the evolving turbulent flow field and flame front dynamics. Research has demonstrated that both an increased H2 concentration and a higher jet medium molecular weight increase the turbulence intensity: the former reduces the mixture molecular weight to accelerate diffusion whereas the latter results in more pronounced disturbances from heavier molecules. In addition when CO2 serves as the jet medium a critical flame radius threshold emerges where the flame propagation velocity decreases below this threshold because CO2 dilution effects suppress combustion whereas exceeding it leads to enhanced propagation as initial disturbances become the dominant factor. Furthermore at reduced H2 concentrations (30–50%) flow disturbances induce flame front wrinkling while preserving the spherical geometry; conversely at 70% H2 substantial flame deformation occurs because of the inverse correlation between the laminar burning velocity and flame instability governing this transition. Through systematic quantitative analysis this study elucidates the evolutionary patterns of both turbulent fields and flame fronts offering groundbreaking perspectives on H2 combustion and explosion propagation in turbulent environments.
Impact of Hydrogen Release on Accidental Consequences in Deep-Sea Floating Photovoltaic Hydrogen Production Platforms
Jul 2025
Publication
Hydrogen is a potential key component of a carbon-neutral energy carrier and an input to marine industrial processes. This study examines the consequences of coupled hydrogen release and marine environmental factors during floating photovoltaic hydrogen production (FPHP) system failures. A validated three-dimensional numerical model of FPHP comprehensively characterizes hydrogen leakage dynamics under varied rupture diameters (25 50 100 mm) transient release duration dispersion patterns and wind intensity effects (0–20 m/s sea-level velocities) on hydrogen–air vapor clouds. FLACS-generated data establish the concentration–dispersion distance relationship with numerical validation confirming predictive accuracy for hydrogen storage tank failures. The results indicate that the wind velocity and rupture size significantly influence the explosion risk; 100 mm ruptures elevate the explosion risk producing vapor clouds that are 40–65% larger than 25 mm and 50 mm cases. Meanwhile increased wind velocities (>10 m/s) accelerate hydrogen dilution reducing the high-concentration cloud volume by 70–84%. Hydrogen jet orientation governs the spatial overpressure distribution in unconfined spaces leading to considerable shockwave consequence variability. Photovoltaic modules and inverters of FPHP demonstrate maximum vulnerability to overpressure effects; these key findings can be used in the design of offshore platform safety. This study reveals fundamental accident characteristics for FPHP reliability assessment and provides critical insights for safety reinforcement strategies in maritime hydrogen applications.
Numerical Investigation of Transmission and Sealing Characteristics of Salt Rock, Limestone, and Sandstone for Hydrogen Underground Energy Storage in Ontario, Canada
Feb 2025
Publication
With the accelerating global transition to clean energy underground hydrogen storage (UHS) has gained significant attention as a flexible and renewable energy storage technology. Ontario Canada as a pioneer in energy transition offers substantial underground storage potential with its geological conditions of salt limestone and sandstone providing diverse options for hydrogen storage. However the hydrogen transport characteristics of different rock media significantly affect the feasibility and safety of energy storage projects warranting in-depth research. This study simulates the hydrogen flow and transport characteristics in typical energy storage digital rock core models (salt rock limestone and sandstone) from Ontario using the improved quartet structure generation set (I-QSGS) and the lattice Boltzmann method (LBM). The study systematically investigates the distribution of flow velocity fields directional characteristics and permeability differences covering the impact of hydraulic changes on storage capacity and the mesoscopic flow behavior of hydrogen in porous media. The results show that salt rock due to its dense structure has the lowest permeability and airtightness with extremely low hydrogen transport velocity that is minimally affected by pressure differences. The microfracture structure of limestone provides uneven transport pathways exhibiting moderate permeability and fracture-dominated transport characteristics. Sandstone with its higher porosity and good connectivity has a significantly higher transport rate compared to the other two media showing local high-velocity preferential flow paths. Directional analysis reveals that salt rock and sandstone exhibit significant anisotropy while limestone’s transport characteristics are more uniform. Based on these findings salt rock with its superior sealing ability demonstrates the best hydrogen storage performance while limestone and sandstone also exhibit potential for storage under specific conditions though further optimization and validation are required. This study provides a theoretical basis for site selection and operational parameter optimization for underground hydrogen storage in Ontario and offers valuable insights for energy storage projects in similar geological settings globally.
Enhancing Hydrogen Production from Chlorella sp. Biomass by Pre-Hydrolysis with Simultaneous Saccharification and Fermentation (PSSF)
Mar 2019
Publication
Simultaneous saccharification and fermentation (SSF) and pre-hydrolysis with SSF (PSSF) were used to produce hydrogen from the biomass of Chlorella sp. SSF was conducted using an enzyme mixture consisting of 80 filter paper unit (FPU) g-biomass−1 of cellulase 92 U g-biomass−1 of amylase and 120 U g-biomass−1 of glucoamylase at 35 ◦C for 108 h. This yielded 170 mL-H2 g-volatile-solids−1 (VS) with a productivity of 1.6 mL-H2 g-VS−1 h −1 . Pre-hydrolyzing the biomass at 50 ◦C for 12 h resulted in the production of 1.8 g/L of reducing sugars leading to a hydrogen yield (HY) of 172 mL-H2 g-VS−1 . Using PSSF the fermentation time was shortened by 36 h in which a productivity of 2.4 mL-H2 g-VS−1 h −1 was attained. To the best of our knowledge the present study is the first report on the use of SSF and PSSF for hydrogen production from microalgal biomass and the HY obtained in the study is by far the highest yield reported. Our results indicate that PSSF is a promising process for hydrogen production from microalgal biomass.
Realizing the Role of Hydrogen Energy in Ports: Evidence from Ningbo Zhoushan Port
Jul 2025
Publication
The maritime sector’s transition to sustainable energy is critical for achieving global carbon neutrality with container terminals representing a key focus due to their high energy consumption and emissions. This study explores the potential of hydrogen energy as a decarbonization solution for port operations using the Chuanshan Port Area of Ningbo Zhoushan Port (CPANZP) as a case study. Through a comprehensive analysis of hydrogen production storage refueling and consumption technologies we demonstrate the feasibility and benefits of integrating hydrogen systems into port infrastructure. Our findings highlight the successful deployment of a hybrid “wind-solar-hydrogen-storage” energy system at CPANZP which achieves 49.67% renewable energy contribution and an annual reduction of 22000 tons in carbon emissions. Key advancements include alkaline water electrolysis with 64.48% efficiency multi-tier hydrogen storage systems and fuel cell applications for vehicles and power generation. Despite these achievements challenges such as high production costs infrastructure scalability and data integration gaps persist. The study underscores the importance of policy support technological innovation and international collaboration to overcome these barriers and accelerate the adoption of hydrogen energy in ports worldwide. This research provides actionable insights for port operators and policymakers aiming to balance operational efficiency with sustainability goals.
Risk Analysis of Hydrogen Leakage at Hydrogen Producing and Refuelling Integrated Station
Feb 2025
Publication
Hydrogen energy is considered the most promising clean energy in the 21st century so hydrogen refuelling stations (HRSs) are crucial facilities for storage and supply. HRSs might experience hydrogen leakage (HL) incidents during their operation. Hydrogen-producing and refuelling integrated stations (HPRISs) could make thermal risks even more prominent than those of HRSs. Considering HL as the target in the HPRIS through the method of fault tree analysis (FTA) and analytic hierarchy process (AHP) the importance degree and probability importance were appraised to obtain indicators for the weight of accident level. In addition the influence of HL from storage tanks under ambient wind conditions was analysed using the specific model. Based upon risk analysis of FTA AHP and ALOHA preventive measures were obtained. Through an evaluation of importance degree and probability importance it was concluded that misoperation material ageing inadequate maintenance and improper design were four dominant factors contributing to accidents. Furthermore four crucial factors contributing to accidents were identified by the analysis of the weight of the HL event with AHP: heat misoperation inadequate maintenance and valve failure. Combining the causal analysis of FTA with the expert weights from AHP enables the identification of additional crucial factors in risk. The extent of the hazard increased with wind speed and yet wind direction did not distinctly affect the extent of the risk. However this did affect the direction in which the risk spreads. It is extremely vital to rationally plan upwind and downwind buildings or structures equipment and facilities. The available findings of the research could provide theoretical guidance for the applications and promotion of hydrogen energy in China as well as for the proactive safety and feasible emergency management of HPRISs.
After-Treatment Technologies for Emissions of Low-Carbon Fuel Internal Combustion Engines: Current Status and Prospects
Jul 2025
Publication
In response to increasingly stringent emission regulations low-carbon fuels have received significant attention as sustainable energy sources for internal combustion engines. This study investigates four representative low-carbon fuels methane methanol hydrogen and ammonia by systematically summarizing their combustion characteristics and emission profiles along with a review of existing after-treatment technologies tailored to each fuel type. For methane engines unburned hydrocarbon (UHC) produced during lowtemperature combustion exhibits poor oxidation reactivity necessitating integration of oxidation strategies such as diesel oxidation catalyst (DOC) particulate oxidation catalyst (POC) ozone-assisted oxidation and zoned catalyst coatings to improve purification efficiency. Methanol combustion under low-temperature conditions tends to produce formaldehyde and other UHCs. Due to the lack of dedicated after-treatment systems pollutant control currently relies on general-purpose catalysts such as three-way catalyst (TWC) DOC and POC. Although hydrogen combustion is carbon-free its high combustion temperature often leads to elevated nitrogen oxide (NOx) emissions requiring a combination of optimized hydrogen supply strategies and selective catalytic reduction (SCR)-based denitrification systems. Similarly while ammonia offers carbon-free combustion and benefits from easier storage and transportation its practical application is hindered by several challenges including low ignitability high toxicity and notable NOx emissions compared to conventional fuels. Current exhaust treatment for ammonia-fueled engines primarily depends on SCR selective catalytic reduction-coated diesel particulate filter (SDPF). Emerging NOx purification technologies such as integrated NOx reduction via hydrogen or ammonia fuel utilization still face challenges of stability and narrow effective temperatures.
Optimization Operation Method for Hydrogen-compressed Natural Gas-Integrated Energy Systems Considering Hydrogen-Thermal Multi-Energy Inertia
Dec 2024
Publication
Hydrogen-enriched compressed natural gas (HCNG) holds significant promise for renewable energy absorption and hydrogen utilization while also increasing the complexity of Integrated Energy System (IES) structures which presents challenges for optimal HCNG-IES operation. Energy inertia provides IES with potential operational flexibility. However existing HCNG-IES optimization technologies inadequately account for hydrogen and thermal inertia leaving significant opportunities to enhance system performance. In this study we begin with a comprehensive analysis and modeling of the hydrogen-thermal multi-energy inertia (HTMEI) processes which encompass the hydrogen inertia of HCNG loads and hydrogen storage tanks as well as the thermal inertia of thermal storage tanks and buildings. Following this we develop an optimization model for the operation of HCNG-IES that incorporates HTMEI to optimize the system's overall performance in terms of economic environmental and energy efficiency criteria. The resulting optimal scheduling scheme integrates the outputs of energy devices and multi-energy inertia processes. Case studies validate the efficacy of the proposed operational optimization method. The results indicate that in comparison with an operational optimization method that does not consider energy inertia the proposed approach reduces operational costs by 34.79% carbon emissions by 32.93% electricity purchased from the grid by 95.37% and natural gas consumption by 11.8%. Furthermore the analysis has verified the mutual enhancement between hydrogen inertia and thermal inertia along with their positive individual impacts on operational performance of the HCNGIES.
Minimum Hydrogen Consumption Energy Management for Hybrid Fuel Cell Ships Using Improved Weighted Antlion Optimization
Oct 2025
Publication
Energy management in hybrid fuel cell ship systems faces the dual challenges of optimizing hydrogen consumption and ensuring power quality. This study proposes an Improved Weighted Antlion Optimization (IW-ALO) algorithm for multi-objective problems. The method incorporates a dynamic weight adjustment mechanism and an elite-guided strategy which significantly enhance global search capability and convergence performance. By integrating IW-ALO with the Equivalent Consumption Minimization Strategy (ECMS) an improved weighted ECMS (IW-ECMS) is developed enabling real-time optimization of the equivalence factor and ensuring efficient energy sharing between the fuel cell and the lithium-ion battery. To validate the proposed strategy a system simulation model is established in Matlab/Simulink 2017b. Compared with the rule-based state machine control and optimization-based ECMS methods over a representative 300 s ferry operating cycle the IW-ECMS achieves a hydrogen consumption reduction of 43.4% and 42.6% respectively corresponding to a minimum total usage of 166.6 g under the specified load profile while maintaining real-time system responsiveness. These reductions reflect the scenario tested characterized by frequent load variations. Nonetheless the results highlight the potential of IW-ECMS to enhance the economic performance of ship power systems and offer a novel approach for multi-objective cooperative optimization in complex energy systems.
Production of Hydrogen-Rich Syngas via Biomass-Methane Co-Pyrolysis: Thermodynamic Analysis
Oct 2025
Publication
This study presents a thermodynamic equilibrium analysis of hydrogen-rich syngas production via biomass–methane co-pyrolysis employing the Gibbs free energy minimization method. A critical temperature threshold at 700 ◦C is identified below which methanation and carbon deposition are thermodynamically favored and above which cracking and reforming reactions dominate enabling high-purity syngas generation. Methane addition shifts the reaction pathway towards increased reduction significantly enhancing carbon and H2 yields while limiting CO and CO2 emissions. At 1200 ◦C and a 1:1 methane-tobiomass ratio cellulose produces 50.84 mol C/kg 119.69 mol H2/kg and 30.65 mol CO/kg; lignin yields 78.16 mol C/kg 117.69 mol H2/kg and 19.14 mol CO/kg. The H2/CO ratio rises to 3.90 for cellulose and 6.15 for lignin with energy contents reaching 43.16 MJ/kg and 52.91 MJ/kg respectively. Notably biomass enhances methane conversion from 25% to over 53% while sustaining a 67% H2 selectivity. These findings demonstrate that syngas composition and energy content can be precisely controlled via methane co-feeding ratio and temperature offering a promising approach for sustainable tunable syngas production.
Adaptive Hydrogen Fuel Cell Vehicle Scheduling Strategy Based on Traffic State Assessment in Power-Transportation Coupled Networks
Aug 2025
Publication
As the global demand for energy increases and the transition to renewable and clean sources accelerates microgrid (MG) has emerged as a promising solution. Hydrogen fuel cell vehicles (HFCVs) offer significant advantages over gasoline vehicles in terms of reducing carbon dioxide emissions. However the development of HFCVs is hindered by the substantial up-front costs of hydrogen refueling stations (HRSs) coupled with the high cost of hydrogen transportation and the limitations of the hydrogen supply chain. This research proposes a multimicrogrid (MMG) system that integrates hydrogen energy and utilizes it as the HRS for fuel vehicle refueling. An adaptive hydrogen energy management method is employed for fuel cell vehicles to optimize the coupling between the transportation network and the power system. An integrated transportation state assessment model is developed and a smart MMG system is deployed to receive information from the transportation network. Building on this foundation an adaptive hydrogen scheduling model is developed. HFCVs are influenced by the hydrogen price adjustments leading them to travel to different MGs for refueling which in turn regulates the unit output of the MMG system. The MMG system is then integrated with the IEEE 33 bus distribution system to analyze the daily load balance. This integrated approach results in reduced traffic congestion lower MG costs and optimized power distribution network load balance.
Techno-economic Evaluation of Retrofitting Power-to-methanol: Grid-connected Energy Arbitrage vs Standalone Renewable Energy
Aug 2025
Publication
The power-to-methanol (PtMeOH) will play a crucial role as a form of renewable chemical energy storage. In this paper PtMeOH techno-economics are assessed using the promising configuration from the previous work (Mbatha et al. [1]). This study evaluated the effect of parameters such as the CO2 emission tax electricity price and CAPEX reduction on the product methanol economic parity with respect to a reference case. Superior to previous economic studies a scenario where an existing methanol synthesis infrastructure is 100 % retrofitted with the promising electrolyser is assessed in terms of its economics and the associated economic parity. The volatile South African electricity market is considered as a case study. The sensitivity of the PtMeOH and green H2 profitability are checked. Grid-connected and standalone renewable energy PtMeOH scenarios are assessed. Foremost generalisable effect trends of these parameters on the net present value (NPV) and the levelized cost of methanol(LCOMeOH) and H2 (LCOH2) are discussed. The results show that economic parity of H2 (LCOH2 = current selling price = 4.06 €/kg) can be reached with an electricity price of 30 €/MWh and 70 % of the CAPEX. While the LCOMeOH will still be above 2 €/kg at 80 % of the CAPEX and electricity price of 20 €/MWh. This indicates that even if the CAPEX reduces to 20 % of its original in this study and the electricity price reduces to about 20 €/MWh the LCOMEOH will still not reach economic parity (LCOMeOH > current selling price = 0.44 €/kg). The results show that to make the retrofitted plant with a minimum of 20 years of life span profitable a feasible reduction in the electricity price to below 10 €/MWh along with favourable incentives such as CO2 credit and reduction in CAPEX particularly that of the electrolyser and treatment of the PtMeOH as a multiproduct plant will be required.
A Numerial Study on Hydrogen Blending in Natural Gas Pipeline by a T-pipe
Mar 2024
Publication
In order to study the flow blending and transporting process of hydrogen that injects into the natural gas pipelines a three-dimensional T-pipe blending model is established and the flow characteristics are investigated systematically by the large eddy simulation (LES). Firstly the mathematical formulation of hydrogen-methane blending process is provided and the LES method is introduced and validated by a benchmark gas blending model having experimental data. Subsequently the T-pipe blending model is presented and the effects of key parameters such as the velocity of main pipe hydrogen blending ratio diameter of hydrogen injection pipeline diameter of main pipe and operating pressure on the hydrogen-methane blending process are studied systematically. The results show that under certain conditions the gas mixture will be stratified downstream of the blending point with hydrogen at the top of the pipeline and methane at the bottom of the pipeline. For the no-stratified scenarios the distance required for uniformly mixing downstream the injection point increases when the hydrogen mixing ratio decreases the diameter of the hydrogen injection pipe and the main pipe increase. Finally based on the numerical results the underlying physics of the stratification phenomenon during the blending process are explored and an indicator for stratification is proposed using the ratio between the Reynolds numbers of the natural gas and hydrogen.
Status and Perspectives of Key Materials for PEM Electrolyzer
Sep 2024
Publication
Proton exchange membrane water electrolyzer (PEMWE) represents a promising technology for the sustainable production of hydrogen which is capable of efficiently coupling to intermittent electricity from renewable energy sources (e.g. solar and wind). The technology with compact stack structure has many notable advantages including large current density high hydrogen purity and great conversion efficiency. However the use of expensive electrocatalysts and construction materials leads to high hydrogen production costs and limited application. In this review recent advances made in key materials of PEMWE are summarized. First we present a brief overview about the basic principles thermodynamics and reaction kinetics of PEMWE. We then describe the cell components of PEMWE and their respective functions as well as discuss the research status of key materials such as membrane electrocatalysts membrane electrode assemblies gas diffusion layer and bipolar plate. We also attempt to clarify the degradation mechanisms of PEMWE under a real operating environment including catalyst degradation membrane degradation bipolar plate degradation and gas diffusion layer degradation. We finally propose several future directions for developing PEMWE through devoting more efforts to the key materials.
Optimization of Hydrogen Production System Performance Using Photovoltaic/Thermal-Coupled PEM
Oct 2024
Publication
A proton exchange membrane electrolyzer can effectively utilize the electricity generated by intermittent solar power. Different methods of generating electricity may have different efficiencies and hydrogen production rates. Two coupled systems namely PV/T- and CPV/T-coupling PEMEC respectively are presented and compared in this study. A maximum power point tracking algorithm for the photovoltaic system is employed and simulations are conducted based on the solar irradiation intensity and ambient temperature of a specific location on a particular day. The simulation results indicate that the hydrogen production is relatively high between 11:00 and 16:00 with a peak between 12:00 and 13:00. The maximum hydrogen production rate is 99.11 g/s and 29.02 g/s for the CPV/T-PEM and PV/T-PEM systems. The maximum energy efficiency of hydrogen production in CPV/T-PEM and PV/T-PEM systems is 66.7% and 70.6%. Under conditions of high solar irradiation intensity and ambient temperature the system demonstrates higher total efficiency and greater hydrogen production. The CPV/T-PEM system achieves a maximum hydrogen production rate of 2240.41 kg/d with a standard coal saving rate of 15.5 tons/day and a CO2 reduction rate of 38.0 tons/day. Compared to the PV/T-PEM system the CPV/T-PEM system exhibits a higher hydrogen production rate. These findings provide valuable insights into the engineering application of photovoltaic/thermal-coupled hydrogen production technology and contribute to the advancement of this field.
How Would Structural Change in Electricity and Hydrogen End Use Impact Low-Carbon Transition of an Energy System? A Case Study of China
Feb 2024
Publication
Driven by global targets to reduce greenhouse gas emissions energy systems are expected to undergo fundamental changes. In light of carbon neutrality policies China is expected to significantly increase the proportion of hydrogen and electricity in its energy system in the future. Nevertheless the future trajectory remains shrouded in uncertainty. To explore the potential ramifications of varying growth scenarios pertaining to hydrogen and electricity on the energy landscape this study employs a meticulously designed bottom-up model. Through comprehensive scenario calculations the research aims to unravel the implications of such expansions and provide a nuanced analysis of their effects on the energy system. Results show that with an increase in electrification rates cumulative carbon dioxide emissions over a certain planning horizon could be reduced at the price of increased unit reduction costs. By increasing the share of end-use electricity and hydrogen from 71% to 80% in 2060 the unit carbon reduction cost will rise by 17%. Increasing shares of hydrogen could shorten the carbon emission peak time by approximately five years but it also brings an increase in peak shaving demand.
Study on the Application of a Multi-Energy Complementary Distributed Energy System Integrating Waste Heat and Surplus Electricity for Hydrogen Production
Feb 2024
Publication
To improve the recovery of waste heat and avoid the problem of abandoning wind and solar energy a multi-energy complementary distributed energy system (MECDES) is proposed integrating waste heat and surplus electricity for hydrogen storage. The system comprises a combined cooling heating and power (CCHP) system with a gas engine (GE) solar and wind power generation and miniaturized natural gas hydrogen production equipment (MNGHPE). In this novel system the GE’s waste heat is recycled as water vapor for hydrogen production in the waste heat boiler while surplus electricity from renewable sources powers the MNGHPE. A mathematical model was developed to simulate hydrogen production in three building types: offices hotels and hospitals. Simulation results demonstrate the system’s ability to store waste heat and surplus electricity as hydrogen thereby providing economic benefit energy savings and carbon reduction. Compared with traditional energy supply methods the integrated system achieves maximum energy savings and carbon emission reduction in office buildings with an annual primary energy reduction rate of 49.42–85.10% and an annual carbon emission reduction rate of 34.88–47.00%. The hydrogen production’s profit rate is approximately 70%. If the produced hydrogen is supplied to building through a hydrogen fuel cell the primary energy reduction rate is further decreased by 2.86–3.04% and the carbon emission reduction rate is further decreased by 12.67–14.26%. This research solves the problem of waste heat and surplus energy in MECDESs by the method of hydrogen storage and system integration. The economic benefits energy savings and carbon reduction effects of different building types and different energy allocation scenarios were compared as well as the profitability of hydrogen production and the factors affecting it. This has a positive technical guidance role for the practical application of MECDESs.
Economic Analysis of Hydrogen Energy Systems: A Global Perspective
Aug 2024
Publication
In the realm of renewable energy the integration of wind power and hydrogen energy systems represents a promising avenue towards environmental sustainability. However the development of cost-effective hydrogen energy storage solutions is crucial to fully realize the potential of hydrogen as a renewable energy source. By combining wind power generation with hydrogen storage a comprehensive hydrogen energy system can be established. This study aims to devise a physiologically inspired optimization approach for designing a standalone wind power producer that incorporates a hydrogen energy system on a global scale. The optimization process considers both total cost and capacity loss to determine the optimal configuration for the system. The optimal setup for an off-grid solution involves the utilization of eight distinct types of compact horizontal-axis wind turbines. Additionally a sensitivity analysis is conducted by varying component capital costs to assess their impact on overall cost and load loss. Simulation results indicate that at a 15% loss the cost of energy (COE) is $1.3772 while at 0% loss it stands at $1.6908. Capital expenses associated with wind turbines and hydrogen storage systems significantly contribute to the overall cost. Consequently the wind turbine-hydrogen storage system emerges as the most cost-effective and reliable option due to its low cost of energy.
CFD Analysis of Hydrogen Leakage from a Small Hole in a Sloping Roof Hydrogen Refueling Station
Sep 2023
Publication
As a key link in the application of hydrogen energy hydrogen refueling stations are significant for their safe operation. This paper established a three-dimensional 1:1 model for a seaport hydrogen refueling station in Ningbo City. In this work the CFD software FLUENT was used to study the influence of leakage angles on the leakage of high-pressure hydrogen through a small hole. Considering the calculation accuracy and efficiency this paper adopted the pseudo-diameter model. When the obstacle was far from the leakage hole it had almost no obstructive effect on the jet's main body. Still it affected the hydrogen whose momentum in the outer layer of the jet has been significantly decayed. In this condition there would be more hydrogen in stagnation. Thus the volume of the flammable hydrogen cloud was hardly affected while there was a significant increase in the volume of the hazardous hydrogen cloud. When the obstacle was close to the leakage hole it directly affected the jet's main body. Therefore the volume of the flammable hydrogen cloud increased. However the air impeded the hydrogen jet relatively less because the hydrogen jet contacted the obstacle more quickly. The hydrogen jet blocked by the obstacle still has some momentum. Therefore there was no more hydrogen in stagnation and no significant increase in the volume of the hazardous hydrogen cloud.
Optimization of Injection Molding Process Parameters for the Lining of IV Hydrogen Storage Cylinder
Jan 2023
Publication
The hydrogen storage cylinder lining was taken as the research object. The injection model of the cylinder liner was developed employing 3D software a two-cavity injection molding system was built and Moldfow was utilized for analysis to determine the best combination of injection molding process parameters. The efects of injection process parameters (melt temperature mold temperature holding pressure holding time and cooling time) on the evaluation index were analyzed by orthogonal experiment L16(45 ). The prediction data of IV hydrogen storage cylinder lining under diferent parameters were obtained by the range analysis method. The multi-objective optimization problem of injection molding process was transformed into a single-objective optimization problem by using the grey correlation analysis method. The optimal parameters such as melt temperature 270 °C mold temperature 80 °C packing pressure 55 MPa packing time 20 s and cooling time 13 s were obtained. Taguchi method was adopted to obtain SNR (signal-to-noise ratio) while range and variance methods were used for analysis. The results showed that warpage was 0.4892 mm the volume shrinkage was 12.31% the residual stress in the frst direction was 98.13 MPa and the residual stress in the second direction was 108.1 MPa. The comprehensive index was simultaneously most impacted by the melt temperature.
Mathematical Optimization Modeling for Scenario Analysis of Integrated Steelworks Transitioning Towards Hydrogen-based Reduction
Jul 2024
Publication
To reduce carbon dioxide emissions from the steel industry efforts are made to introduce a steelmaking route based on hydrogen reduction of iron ore instead of the commonly used cokebased reduction in a blast furnace. Changing fundamental pieces of steelworks affects the functions of most every system unit involved and thus warrants the question of how such a transition could optimally take place over time and no rigorous attempts have until now been made to tackle this problem mathematically. This article presents a steel plant optimization model written as a mixed-integer non-linear programming problem where aging blast furnaces and basic oxygen furnaces could potentially be replaced with shaft furnaces and electric arc furnaces minimizing costs or emissions over a long-term time horizon to identify possible transition pathways. Example cases show how various parameters affect optimal investment pathways stressing the necessity of appropriate planning tools for analyzing diverse cases.
Key Components and Design Strategy for a Proton Exchange Membrane Water Electrolyzer
Oct 2022
Publication
As the most attractive energy carrier hydrogen production through electro-chemical water splitting (EWS) is promising for resolving the serious environ-mental problems derived from the rapid consumption of fossil fuels globally. Theproton exchange membrane water electrolyzer (PEMWE) is one of the mostpromising EWS technologies and has achieved great advancements. To offer atimely reference for the progress of the PEMWE system the latest advancementsand developments of PEMWE technology are systematically reviewed. The keycomponents including the electrocatalysts PEM and porous transport layer(PTL) as well as bipolar plate (BPP) are first introduced and discussed followedby the membrane electrode assembly and cell design. The highlights are put onthe design of the electrocatalyst and the relationship of each component on theperformance of the PEMWE. Moreover the current challenges and future per-spectives for the development of PEMWE are also discussed. There is a hope thatthis review can provide a timely reference for future directions in PEMWEchallenges and perspectives.
Advancing "Carbon Peak" and "Carbon Neutrality" in China: A Comprehensive Review of Current Global Research on Carbon Capture, Utilization, and Storage Technology and its Implications
Nov 2023
Publication
Carbon capture utilization and storage (CCUS) technology plays a pivotal role in China’s “Carbon Peak” and “Carbon Neutrality” goals. This approach offers low-carbon zero-carbon and even negative-carbon solutions. This paper employs bibliometric analysis using the Web of Science to comprehensively review global CCUS progress and discuss future development prospects in China. The findings underscore it as a prominent research focus attracting scholars from both domestic and international arenas. China notably leads the global landscape in terms of research paper output with the Chinese Academy of Sciences holding a prominent position in total published papers. The research predominantly centers on refining geological storage techniques and optimizing oil and gas recovery rates. Among the CCUS pathways enhanced oil recovery technology stands out due to its relative maturity and commercial applicability particularly within the conventional oil and gas reservoirs. The application potential of enhanced gas recovery technology especially in the Sichuan and Ordos Basins in China necessitates robust research and demonstration efforts. Within China’s current energy landscape “Blue Hydrogen” emerges as the primary solution for hydrogen production in conjunction with CCUS technology. The underground coal gasification approach holds significant promise as a hydrogen production avenue albeit with inherent ecological and environmental challenges tied to geological storage that require meticulous consideration. The establishment of effective risk identification and evaluation methodologies for geological storage is imperative. The trajectory ahead involves a strategic convergence of policy technology and market dynamics to enhance China’s CCUS policy framework legislative framework standardization initiatives and pioneering technological advancements. These collective efforts converge to outline an exclusive development pathway in China. This study assumes a pivotal role in accelerating CCUS technology research and deployment enhancing oil and gas recovery efficiency and ultimately realizing the overarching goals of a “Dual Carbon” future.
Numerical Investigation of Hydrogen Production via Methane Steam Reforming in Tubular Packed Bed Reactors Integrated with Annular Metal Foam Gas Channels
Sep 2025
Publication
Methane steam reforming is the most widely adopted hydrogen production technology. To address the challenges associated with the large radial thermal resistance and low mass transfer rates inherent in the tubular packed bed reactors during the MSR process this study proposes a structural design optimization that integrates annular metal foam gas channels along the inner wall of the reforming tubes. Utilizing multi-physics simulation methods and taking the conventional tubular reactor as a baseline a comparative analysis was performed on physical parameters that characterize flow behavior heat transfer and reaction in the reforming process. The integration of the annular channels induces a radially non-uniform distribution of flow resistance in the tubes. Since the metal foam exhibits lower resistance the fluid preferentially flows through the annular channels leading to a diversion effect that enhances both convective heat transfer and mass transfer. The diversion effect redirects the central flow toward the near-wall region where the higher reactant concentration promotes the reaction. Additionally the higher thermal conductivity of the metal foam strengthens radial heat transfer further accelerating the reaction. The effects of operating parameters on performance were also investigated. While a higher inlet velocity tends to hinder the reaction in tubes integrated with annular channels it enhances the diversion effect and convective heat transfer. This offsets the adverse impact maintaining high methane conversion with lower pressure drop and thermal resistance than the conventional tubular reactor does.
Techno-Economic Assessment of Biogas-to-Methanol Processes Coupled with Low-Carbon H2 Production Technologies
Jan 2025
Publication
In order to realize carbon mitigation and the efficient utilization of waste biogas the biogas-to-methanol process is an important method. The syngas produced by the conventional biogas reforming technology is rich in CO2 and CO whereas it is poor in hydrogen. Therefore additional H2 is introduced into the system to adjusted the syngas ratio promoting the efficient conversion of the biogas. However the use of traditional H2 production technologies generally results in considerable carbon emissions. Given these points low-carbon H2 production technologies namely methane pyrolysis technology and chemical looping reforming technology are integrated with the biogas-to-methanol process to enhance carbon conversion carbon reduction and cost-saving potentials. Comprehensive technical and economic comparisons of the integrated processes are conducted. The process coupled with chemical looping reforming technology has a higher carbon conversion efficiency (73.52%) and energy efficiency (70.41%) and lower unit carbon emissions (0.73 t CO2/t methanol). Additionally the process coupled with methane pyrolysis technology has higher product revenue whereas that including chemical looping reforming technology has a lower net production cost (571.33 USD/t methanol). In summary the novel chemical looping reforming technology provides a cleaner and more sustainable pathway with which to promote the efficient conversion of biogas into methanol.
A Review of LCA Studies on Marine Alternative Fuels: Fuels, Methodology, Case Studies, and Recommendations
Jan 2025
Publication
Life Cycle Assessment (LCA) methodology can be used to quantitatively assess the greenhouse gas emissions of low- or zero-carbon marine alternative fuels throughout their life cycle (from well to wake) and is an important basis for ensuring a green energy transition in the shipping industry. This paper first clarifies the trends and requirements of low-carbon development in shipping and introduces the major ship emission reduction technologies and evaluation methods. Next the characteristics of various alternative marine fuels (i.e. LNG hydrogen methanol ammonia and biofuels) are comprehensively discussed and analyzed in terms of production storage transportation and ship applications. In addition this work provides a comprehensive overview of LCA methodology including its relevant standards and assessment tools and establishes a framework for LCA of marine alternative fuels. On this basis a literature review of the current research on LCA of marine alternative fuels from the perspectives of carbon emissions pollution emissions and economics is presented. The case review covers 64 alternative-fueled ships and 12 groups of fleets operating in different countries and waters. Finally this paper discusses the main shortcomings that exist in the current research and provides an outlook on the future development of LCA research of marine alternative fuels.
Machine Learning Prediction of Photovoltaic Hydrogen Production Capacity Using Long Short-Term Memory Model
Jan 2025
Publication
The yield of photovoltaic hydrogen production systems is influenced by a number of factors including weather conditions the cleanliness of photovoltaic modules and operational efficiency. Temporal variations in weather conditions have been shown to significantly impact the output of photovoltaic systems thereby influencing hydrogen production. To address the inaccuracies in hydrogen production capacity predictions due to weather-related temporal variations in different regions this study develops a method for predicting photovoltaic hydrogen production capacity using the long short-term memory (LSTM) neural network model. The proposed method integrates meteorological parameters including temperature wind speed precipitation and humidity into a neural network model to estimate the daily solar radiation intensity. This approach is then integrated with a photovoltaic hydrogen production prediction model to estimate the region’s hydrogen production capacity. To validate the accuracy and feasibility of this method meteorological data from Lanzhou China from 2013 to 2022 were used to train the model and test its performance. The results show that the predicted hydrogen production agrees well with the actual values with a low mean absolute percentage error (MAPE) and a high coefficient of determination (R2 ). The predicted hydrogen production in winter has a MAPE of 0.55% and an R2 of 0.985 while the predicted hydrogen production in summer has a slightly higher MAPE of 0.61% and a lower R2 of 0.968 due to higher irradiance levels and weather fluctuations. The present model captures long-term dependencies in the time series data significantly improving prediction accuracy compared to conventional methods. This approach offers a cost-effective and practical solution for predicting photovoltaic hydrogen production demonstrating significant potential for the optimization of the operation of photovoltaic hydrogen production systems in diverse environments.
Multi-Seasonal Risk Assessment of Hydrogen Leakage, Diffusion, and Explosion in Hydrogen Refueling Station
Aug 2025
Publication
To reveal the influence mechanisms of seasonal climatic factors (wind speed wind direction temperature) and leakage direction on hydrogen dispersion and explosion behavior from single-source leaks at typical risk locations (hydrogen storage tanks compressors dispensers) in hydrogen refueling stations (HRSs) this work established a full-scale 1:1 three-dimensional numerical model using the FLACS v22.2 software based on the actual layout of an HRS in Xichang Sichuan Province. Through systematic simulations of 72 leakage scenarios (3 equipment types × 4 seasons × 6 leakage directions) the coupled effects of climatic conditions equipment layout and leakage direction on hydrogen dispersion patterns and explosion risks were quantitatively analyzed. The key findings indicate the following: (1) Downward leaks (−Z direction) from storage tanks tend to form large-area ground-hugging hydrogen clouds representing the highest explosion risk (overpressure peak: 0.25 barg; flame temperature: >2500 K). Leakage from compressors (±X/−Z directions) readily affects adjacent equipment. Dispenser leaks pose relatively lower risks but specific directions (−Y direction) coupled with wind fields may drive significant hydrogen dispersion toward station buildings. (2) Southeast/south winds during spring/summer promote outward migration of hydrogen clouds reducing overall station risk but causing localized accumulation near storage tanks. Conversely north/northwest winds in autumn/winter intensify hydrogen concentrations in compressor and station building areas. (3) An empirical formula integrating climatic parameters leakage conditions and spatial coordinates was proposed to predict hydrogen concentration (error < 20%). This model provides theoretical and data support for optimizing sensor placement dynamically adjusting ventilation strategies and enhancing safety design in HRSs.
Electric-thermal Collaborative System and Control for Hydrogen-fuel Cell Passenger Trains in the UK's Winter
Feb 2025
Publication
This paper presents a quantitative study on electric-thermal collaborative system for hydrogen-powered train reutilising the waste heat from fuel cell system for Heating Ventilation and Air Conditioning (HVAC). Firstly a hybrid train simulator is developed to simulate the train’s motion state. Heat generation from fuel cell is estimated using a fuel cell model while a detailed thermodynamic model for railway passenger coach is established to predict the heat demand. Furthermore an electric-thermal collaborative energy management strategy (ETCEMS) is proposed for the system to comprehensively optimise the on-train power distribution considering traction and auxiliary power. Finally comparative analysis is performed among the train with electric heater (EH) heat pump (HP) and heat pump-heat reuse (HP-HR). The results demonstrate that over a round trip the proposed HP-HR with ETC-EMS recovers over 22.88% residual heat and saves 16.17% of hydrogen consumption. For the daily operation it reduces hydrogen and energy consumption by 12.06% and 12.82 % respectively. The findings indicate that collaborative optimisation brings significant improvements on the global energy utilisation. The proposed design with ETC-EMS is potential to further enhance the economic viability of hydrail and contributes to the rail decarbonisation.
Optimizing Hydrogen Production for Sustainable Fuel Cell Electric Vehicles: Grid Impacts in the WECC Region
Jan 2025
Publication
The fuel cell electric vehicle (FCEV) is a promising transportation technology for resolving the air pollution and climate change issues in the United States. However a large-scale penetration of FCEVs would require a sustained supply of hydrogen which does not exist now. Water electrolysis can produce hydrogen reliably and sustainably if the electricity grid is clean but the impacts of FCEVs on the electricity grid are unknown. In this paper we develop a comprehensive framework to model FCEV-driving and -refueling behaviors the water electrolysis process and electricity grid operation. We chose the Western Electricity Coordinating Council (WECC) region for this case study. We modeled the existing WECC electricity grids and accounted for the additional electricity loads from FCEVs using a Production Cost Model (PCM). Additionally the hydrogen need for five million FCEVs leads to a 3% increase in electricity load for WECC. Our results show that an inflexible hydrogen-producing process leads to a 1.55% increase to the average cost of electricity while a flexible scenario leads to only a 0.9% increase. On the other hand oversized electrolyzers could take advantage of cheaper electricity generation opportunities thus lowering total system costs.
Ammonia Marine Engine Design for Enhanced Efficiency and Reduced Greenhouse Gas Emissions
Mar 2024
Publication
Pilot-diesel-ignition ammonia combustion engines have attracted widespread attentions from the maritime sector but there are still bottleneck problems such as high unburned NH3 and N2O emissions as well as low thermal efficiency that need to be solved before further applications. In this study a concept termed as in-cylinder reforming gas recirculation is initiated to simultaneously improve the thermal efficiency and reduce the unburned NH3 NOx N2O and greenhouse gas emissions of pilot-diesel-ignition ammonia combustion engine. For this concept one cylinder of the multi-cylinder engine operates rich of stoichiometric and the excess ammonia in the cylinder is partially decomposed into hydrogen then the exhaust of this dedicated reforming cylinder is recirculated into the other cylinders and therefore the advantages of hydrogen-enriched combustion and exhaust gas recirculation can be combined. The results show that at 3% diesel energetic ratio and 1000 rpm the engine can increase the indicated thermal efficiency by 15.8% and reduce the unburned NH3 by 89.3% N2O by 91.2% compared to the base/traditional ammonia engine without the proposed method. At the same time it is able to reduce carbon footprint by 97.0% and greenhouse gases by 94.0% compared to the traditional pure diesel mode.
Experimental and Numerical Research on Temperature Evolution during the Fast-Filling Process of a Type III Hydrogen Tank
May 2022
Publication
The temperature rises hydrogen tanks during the fast-filling process could threaten the safety of the hydrogen fuel cell vehicle. In this paper a 2D axisymmetric model of a type III hydrogen for the bus was built to investigate the temperature evolution during the fast-filling process. A test rig was carried out to validate the numerical model with air. It was found significant temperature rise occurred during the filling process despite the temperature of the filling air being cooled down due to the throttling effect. After verification the 2D model of the hydrogen tank was employed to study the temperature distribution and evolution of hydrogen during the fast-filling process. Thermal stratification was observed along the axial direction of the tank. Then the effects of filling parameters were examined and a formula was fitted to predict the final temperature based on the simulated results. At last an effort was paid on trying the improve the temperature distribution by increasing the injector length of the hydrogen tank. The results showed the maximal temperature and mass averaged temperature decreased by 2 K and 3.4 K with the length of the injector increased from 50 mm to 250 mm.
Analysis of Corporate Acceptance of Hydrogen Energy Technology Based on the Extended Technology Acceptance Model
Feb 2025
Publication
Hydrogen holds an important strategic position in the energy systems of many countries. Many studies have analyzed the acceptance of hydrogen energy technology from the public’s perspective but few have examined it from the corporate perspective. This paper establishes a technology acceptance model and employs structural equation modeling to investigate the factors affecting the acceptance of hydrogen energy technology within enterprises. After conducting questionnaire surveys among employees of energy enterprises electric power companies and new energy vehicle manufacturers the results indicate that while most of the interviewed enterprises have positive attitudes towards hydrogen technology their willingness to develop hydrogen business does not appear to be correspondingly positive. In addition government trust perceived benefit and social influence positively impact corporate acceptability indirectly whereas perceived risk exhibits a negative indirect effect on corporate acceptance. Finally this paper discusses the results of the above studies and makes corresponding policy recommendations.
Numerical Study of the Filling Process of a Liquid Hydrogen Storage Tank under Different Sloshing Conditions
Aug 2020
Publication
Cryogenic vessels are widely used in many areas such as liquefied natural gas (LNG) aerospace and medical fields. A suitable filling method is one of the prerequisites for the effective use of cryogenic containers. In this study the filling process for the sloshing condition of a liquid hydrogen storage tank is numerically simulated and analyzed by coupling the sloshing model and the phase-change model. The effects of different sloshing conditions during the filling process are investigated by changing the amplitude and frequency of the sloshing. Within the scope of this study there is a critical value for the effect of sloshing conditions on the pressure curve during the filling process. The critical value corresponds to a frequency f equal to 3 Hz and an amplitude A equal to 0.03 m. According to the simulation results when the sloshing exceeds the critical value the internal pressure curve of the storage tank increases significantly. Under microgravity conditions within the scope of this study the pressure curve changes less than the normal gravity even if the amplitude and frequency increase. The sloshing makes it easier for the liquid to spread along the wall during the filling process. This also further weakens the temperature stratification in the storage tank.
Modeling of Hydrogen Dispersion, Jet Fires and Explosions Caused by Hydrogen Pipeline Leakage
Dec 2023
Publication
Accidental hydrogen releases from pipelines pose significant risks particularly with the expanding deployment of hydrogen infrastructure. Despite this there has been a lack of thorough investigation into hydrogen leakage from pipelines especially under complex real-world conditions. This study addresses this gap by modeling hydrogen gas dispersion jet fires and explosions based on practical scenarios. Various factors influencing accident consequences such as leak hole size wind speed wind direction and trench presence were systematically examined. The findings reveal that both hydrogen dispersion distance and jet flame thermal radiation distance increase with leak hole size and wind speed. Specifically the longest dispersion and radiation distances occur when the wind direction aligns with the trench which is 110 m where the hydrogen concentration is 4% and 76 m where the radiation is 15.8 kW/m2 in the case of a 325 mm leak hole and wind under 10 m/s. Meanwhile pipelines lacking trenching exhibit the shortest distances 0.17 m and 0.98 m at a hydrogen concentration of 4% and 15.8 kW/m2 radiation with a leak hole size of 3.25 mm and no wind. Moreover under relatively higher wind speeds hydrogen concentration stratification occurs. Notably the low congestion surrounding the pipeline results in an explosion overpressure too low to cause damage; namely the highest overpressure is 8 kPa but this lasts less than 0.2 s. This comprehensive numerical study of hydrogen pipeline leakage offers valuable quantitative insights serving as a vital reference for facility siting and design considerations to eliminate the risk of fire incidents.
Green Hydrogen Credit Subsidized Renewable Energy-hydrogen Business Models for Achieving the Carbon Netural Future
Feb 2024
Publication
The global resurgence of hydrogen as a clean energy source particularly green hydrogen derived from renewable energy is pivotal for achieving a carbon-neutral future. However scalability poses a significant challenge. This research proposes innovative business models leveraging the low-emission property of green hydrogen to reduce its financial costs thereby fostering its widespread adoption. Key components of the business workflow are elaborated mathematical formulations of market parameters are derived and case studies are presented to demonstrate the feasibility and efficiency of these models. Results demonstrate that the substantial costs associated with the current hydrogen industry can be effectively subsidized via the implementation of proposed business models. When the carbon emission price falls within the range of approximately 86–105 USD/ton free access to hydrogen becomes a viable option for end-users. This highlights the significance and promising potential of the proposed business models within the green hydrogen credit framework.
Two-stage Optimization of Hydrogen and Storage Coordination for a Multi-region Flexible Intermodal Multi-energy Port System
Jan 2024
Publication
To address the issue of imbalanced electricity and hydrogen supply and demand in the flexible multi-energy port area system a multi-regional operational optimization and energy storage capacity allocation strategy considering the working status of flexible multi-status switches is proposed. Firstly based on the characteristics of the port area system models for system operating costs generation equipment energy storage devices flexible multi-status switches and others are established. Secondly the system is subjected to a first-stage optimization where different regions are optimized individually. The working periods of flexible multi-status switches are determined based on the results of this first-stage optimization targeting the minimization of the overall daily operating costs while ensuring 100% integration of renewable energy in periods with electricity supply-demand imbalances. Subsequently additional constraints are imposed based on the results of the first-stage optimization to optimize the entire system obtaining power allocation during system operation as well as power and capacity requirements for energy storage devices and flexible multi-status switches. Finally the proposed approach is validated through simulation examples demonstrating its advantages in terms of economic efficiency reduced power and capacity requirements for energy storage devices and carbon reduction.
Capacity Configuration Optimization for Green Hydrogen Generation by Solar-wind Hybrid Power Based on Comprehensive Performance Criteria
Aug 2023
Publication
Green hydrogen generation driven by solar-wind hybrid power is a key strategy for obtaining the low-carbon energy while by considering the fluctuation natures of solar-wind energy resource the system capacity configuration of power generation hydrogen production and essential storage devices need to be comprehensively optimized. In this work a solar-wind hybrid green hydrogen production system is developed by combining the hydrogen storage equipment with the power grid the coordinated operation strategy of solar-wind hybrid hydrogen production is proposed furthermore the NSGA-III algorithm is used to optimize the system capacity configuration with the comprehensive performance criteria of economy environment and energy efficiency. Through the implemented case study with the hydrogen production capacity of 20000 tons/year the abandoned energy power rate will be reduced to 3.32% with the electrolytic cell average load factor of 64.77% and the system achieves the remarkable carbon emission reduction. In addition with the advantage of connect to the power grid the generated surplus solar/wind power can be readily transmitted with addition income when the sale price of produced hydrogen is suggested to 27.80 CNY/kgH2 the internal rate of return of the system reaches to 8% which present the reasonable economic potential. The research provides technical and methodological suggestions and guidance for the development of solar-wind hybrid hydrogen production schemes with favorable comprehensive performance.
Key Technologies of Pure Hydrogen and Hydrogen-mixed Natural Gas Pipeline Transportation
May 2023
Publication
Thanks to the advantages of cleanliness high efficiency extensive sources and renewable energy hydrogen energy has gradually become the focus of energy development in the world’s major economies. At present the natural gas transportation pipeline network is relatively complete while hydrogen transportation technology faces many challenges such as the lack of technical specifications high safety risks and high investment costs which are the key factors that hinder the development of hydrogen pipeline transportation. This paper provides a comprehensive overview and summary of the current status and development prospects of pure hydrogen and hydrogen-mixed natural gas pipeline transportation. Analysts believe that basic studies and case studies for hydrogen infrastructure transformation and system optimization have received extensive attention and related technical studies are mainly focused on pipeline transportation processes pipe evaluation and safe operation guarantees. There are still technical challenges in hydrogen-mixed natural gas pipelines in terms of the doping ratio and hydrogen separation and purification. To promote the industrial application of hydrogen energy it is necessary to develop more efficient low-cost and low-energy-consumption hydrogen storage materials.
Comprehensive Review of Development and Applications of Hydrogen Energy Technologies in China for Carbon Neutrality: Technology Advances and Challenges
Jul 2024
Publication
Concerning the transition from a carbon-based energy economy to a renewable energy economy hydrogen is considered an essential energy carrier for efficient and broad energy systems in China in the near future. China aims to gradually replace fossil fuel-based power generation with renewable energy technologies to achieve carbon neutrality by 2060. This ambitious undertaking will involve building an industrial production chain spanning the production storage transportation and utilisation of hydrogen energy by 2030 (when China’s carbon peak will be reached). This review analyses the current status of technological R&D in China’s hydrogen energy industry. Based on published data in the open literature we compared the costs and carbon emissions for grey blue and green hydrogen production. The primary challenges concerning hydrogen transportation and storage are highlighted in this study. Given that primary carbon emissions in China are a result of power generation using fossil fuels we provide an overview of the advances in hydrogen-to-power industry technology R&D including hydrogen-related power generation technology hydrogen fuel cells hydrogen internal combustion engines hydrogen gas turbines and catalytic hydrogen combustion using liquid hydrogen carriers (e.g. ammonia methanol and ethanol).
An Assessment Methodology for International Hydrogen Competitiveness: Seven Case Studies Compared
Jun 2024
Publication
Currently the global energy structure is undergoing a transition from fossil fuels to renewable energy sources with the hydrogen economy playing a pivotal role. Hydrogen is not only an important energy carrier needed to achieve the global goal of energy conservation and emission reduction it represents a key object of the future international energy trade. As hydrogen trade expands nations are increasingly allocating resources to enhance the international competitiveness of their respective hydrogen industries. This paper introduces an index that can be used to evaluate international hydrogen competitiveness and elucidate the most competitive countries in the hydrogen trade. To calculate the competitiveness scores of seven major prospective hydrogen market participants we employed the entropy weight method. This method considers five essential factors: potential resources economic and financial base infrastructure government support and institutional environment and technological feasibility. The results indicate that the USA and Australia exhibit the highest composite indices. These findings can serve as a guide for countries in formulating suitable policies and strategies to bolster the development and international competitiveness of their respective hydrogen industries.
Path Analysis of Using Hydrogen Energy to Reduce Greenhouse Gas Emissions in Global Aviation
Jul 2024
Publication
The rapid growth of global aviation emissions has significantly impacted the environment leading to an urgent need to use carbon reduction methods. This paper analyzes global aviation’s carbon dioxide (CO2) N2O and CH4 emission changes under different hydrogen energy application paths. The global warming potential over a 100-year period (GWP100) method is used to convert the emissions of N2O and CH4 into CO2-equivalent. Here we report the results: if the global aviation industry begins using hydrogen turbine engines by 2040 it could reduce cumulative CO2-equivalent emissions by 2.217E+10 tons by 2080 which is 2.12% higher than starting hydrogen fuel cell engines in 2045. However adopting hydrogen fuel cell engines 10 years earlier shows greater reduction capabilities than hydrogen turbine engines achieving an accumulated reduction of 3.006E+10 tons of CO2-equivalent emissions. Therefore the timing of adoption notably affects hydrogen fuel cell engines more than hydrogen turbine engines. Delaying adoption makes hydrogen fuel cell engines’ performance lag hydrogen turbine engines.
A Review of Control Strategies for Proton Exchange Membrane (PEM) Fuel Cells and Water Electrolysers: From Automation to Autonomy
Jul 2024
Publication
Proton exchange membrane (PEM) based electrochemical systems have the capability to operate in fuel cell (PEMFC) and water electrolyser (PEMWE) modes enabling efficient hydrogen energy utilisation and green hydrogen production. In addition to the essential cell stacks the system of PEMFC or PEMWE consists of four sub-systems for managing gas supply power thermal and water respectively. Due to the system’s complexity even a small fluctuation in a certain sub-system can result in an unexpected response leading to a reduced performance and stability. To improve the system’s robustness and responsiveness considerable efforts have been dedicated to developing advanced control strategies. This paper comprehensively reviews various control strategies proposed in literature revealing that traditional control methods are widely employed in PEMFC and PEMWE due to their simplicity yet they suffer from limitations in accuracy. Conversely advanced control methods offer high accuracy but are hindered by poor dynamic performance. This paper highlights the recent advancements in control strategies incorporating machine learning algorithms. Additionally the paper provides a perspective on the future development of control strategies suggesting that hybrid control methods should be used for future research to leverage the strength of both sides. Notably it emphasises the role of artificial intelligence (AI) in advancing control strategies demonstrating its significant potential in facilitating the transition from automation to autonomy.
Flame Acceleration, Detonation Limit and Heat Loss for Hydrogen-Oxygen Mixture at Cryogenic Temperature of 77 K
Sep 2023
Publication
Experiments are performed in hydrogen-oxygen mixtures at the cryogenic temperature of 77 K with the equivalence ratio of 1.5 and 2.0. The optical fibers pressure sensors and the smoked foils are used to record the flame velocity overpressure evolution curve and detonation cells respectively. The 1st and 2nd shock waves are captured and they finally merge to form a stronger precursor shock wave prior to the onset of detonation. The cryogenic temperature will cause the larger expansion ratio which results in the occurrence of strong flame acceleration. The stuttering mode the galloping mode and the deflagration mode are observed when the initial pressure decreases from 0.50 atm to 0.20 atm with the equivalence ratio of 1.5 and the detonation limit is within 0.25-0.30 atm. The heat loss effect on the detonation limit is analysed. In addition the regularity of detonation cell is investigated and the larger post-shock specific heat ratio !"" and the lower normalized activation energy # at lower initial pressure will cause the more regular detonation cell. Also the detonation cell width is predicted by a model of = ($) ⋅ Δ# and the prediction results are mainly consistent with the experimental results.
Optimal Multi-layer Economical Schedule for Coordinated Multiple Mode Operation of Wind-solar Microgrids with Hybrid Energy Storage Systems
Nov 2023
Publication
The aim of this paper is the design and implementation of an advanced model predictive control (MPC) strategy for the management of a wind–solar microgrid (MG) both in the islanded and grid-connected modes. The MG includes energy storage systems (ESSs) and interacts with external hydrogen and electricity consumers as an extra feature. The system participates in two different electricity markets i.e. the daily and real-time markets characterized by different time-scales. Thus a high-layer control (HLC) and a low-layer control (LLC) are developed for the daily market and the real-time market respectively. The sporadic characteristics of renewable energy sources and the variations in load demand are also briefly discussed by proposing a controller based on the stochastic MPC approach. Numerical simulations with real wind and solar generation profiles and spot prices show that the proposed controller optimally manages the ESSs even when there is a deviation between the predicted scenario determined at the HLC and the real-time one managed by the LLC. Finally the strategy is tested on a lab-scale MG set up at Khalifa University Abu Dhabi UAE.
Microwave-enhanced Hydrogen Production: A Review
Apr 2023
Publication
Currently the massive use of fossil fuels which still serve as the dominant global energy has led to the release of large amounts of greenhouse gases. Providing abundant clean and safe renewable energy is one of the major technical challenges for humankind. Nowadays hydrogen-based energy is widely considered a potentially ideal energy carrier that could provide clean energy in the fields of transportation heat and power generation and energy storage systems almost without any impact on the environment after consumption. However a smooth energy transition from fossil-fuel-based energy to hydrogen-based energy must overcome a number of key challenges that require scientific technological and economic support. To accelerate the hydrogen energy transition advanced efficient and cost-effective methods for producing hydrogen from hydrogen-rich materials need to be developed. Therefore in this study a new alternative method based on the use of microwave (MW) heating technology in enhanced hydrogen production pathways from plastic biomass low-carbon alcohols and methane pathways compared with conventional heating methods is discussed. Furthermore the mechanisms of MW heating MW-assisted catalysis and MW plasma are also discussed. MW-assisted technology usually has the advantages of low energy consumption easy operation and good safety practices which make it a promising solution to supporting the future hydrogen society
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