China, People’s Republic
Optimization Operation Strategy for Comprehensive Energy System Considering Multi-Mode Hydrogen Transportation
Dec 2024
Publication
The transformation from a fossil fuel economy to a low-carbon economy has reshaped the way energy is transmitted. As most renewable energy is obtained in the form of electricity using green electricity to produce hydrogen is considered a promising energy carrier. However most studies have not considered the transportation mode of hydrogen. In order to encourage the utilization of renewable energy and hydrogen this paper proposes a comprehensive energy system optimization operation strategy considering multi-mode hydrogen transport. Firstly to address the shortcomings in the optimization operation of existing systems regarding hydrogen transport modeling is conducted for multi-mode hydrogen transportation through hydrogen tube trailers and pipelines. This model reflects the impact of multi-mode hydrogen delivery channels on hydrogen utilization which helps promote the consumption of new energy in electrolysis cells to meet application demands. Based on this the constraints of electrolyzers combined heat and power units hydrogen fuel cells and energy storage systems in integrated energy systems (IESs) are further considered. With the objective of minimizing the daily operational cost of the comprehensive energy system an optimization model for the operation considering multi-mode hydrogen transport is constructed. Lastly based on simulation examples the impact of multi-mode hydrogen transportation on the operational cost of the system is analyzed in detail. The results indicate that the proposed optimization strategy can reduce the operational cost of the comprehensive energy system. Hydrogen tube trailers and pipelines will have a significant impact on operational costs. Properly allocating the quantity of hydrogen tube trailers and pipelines is beneficial for reducing the operational costs of the system. Reasonable arrangement of hydrogen transportation channels is conducive to further promoting the green and economic operation of the system.
Pressure Dependence of CO2 Effect on Hydrogen-assisted Fatigue Crack Growth in Two Pipeline Steels
Oct 2024
Publication
This study investigated the pressure-dependent CO2 effect on the hydrogen embrittlement of X80 and GB20# pipeline steels by combining experiments and first-principles calculations. Results revealed that the CO2 effect enhanced the fatigue crack growth for GB20# steel in 10 MPa CO₂-enriched hydrogen mixtures. However the improved degree by the CO₂ effect at 10 MPa was less pronounced than at 0.4 MPa which was found for the first time. This was attributed to the decreased adsorption rate of CO₂ on iron as hydrogen pressure increased. Therefore in high-pressure CO₂-enriched hydrogen mixtures CO2 could not significantly accelerate the inherent rapid hydrogen uptake at high pressure.
Research on Energy Management of Hydrogen Fuel Cell Bus Based on Deep Reinforcement Learning Considering Velocity Control
Aug 2023
Publication
In the vehicle-to-everything scenario the fuel cell bus can accurately obtain the surrounding traffic information and quickly optimize the energy management problem while controlling its own safe and efficient driving. This paper proposes an energy management strategy (EMS) that considers speed control based on deep reinforcement learning (DRL) in complex traffic scenarios. Using SUMO simulation software (Version 1.15.0) a two-lane urban expressway is designed as a traffic scenario and a hydrogen fuel cell bus speed control and energy management system is designed through the soft actor–critic (SAC) algorithm to effectively reduce the equivalent hydrogen consumption and fuel cell output power fluctuation while ensuring the safe efficient and smooth driving of the vehicle. Compared with the SUMO–IDM car-following model the average speed of vehicles is kept the same and the average acceleration and acceleration change value decrease by 10.22% and 11.57% respectively. Compared with deep deterministic policy gradient (DDPG) the average speed is increased by 1.18% and the average acceleration and acceleration change value are decreased by 4.82% and 5.31% respectively. In terms of energy management the hydrogen consumption of SAC–OPT-based energy management strategy reaches 95.52% of that of the DP algorithm and the fluctuation range is reduced by 32.65%. Compared with SAC strategy the fluctuation amplitude is reduced by 15.29% which effectively improves the durability of fuel cells.
A Review of Hydrogen Production via Seawater Electrolysis: Current Status and Challenges
Oct 2024
Publication
Seawater electrolysis represents a promising green energy technology with significant potential for efficient energy conversion. This study provides an in-depth examination of the key scientific challenges inherent in the seawater-electrolysis process and their potential solutions. Initially it analyzes the potential issues of precipitation and aggregation at the cathode during hydrogen evolution proposing strategies such as self-cleaning cathodes and precipitate removal to ensure cathode stability in seawater electrolysis. Subsequently it addresses the corrosion challenges faced by anode catalysts in seawater introducing several anti-corrosion strategies to enhance anode stability including substrate treatments such as sulfidation phosphidation selenidation and LDH (layered double hydroxide) anion intercalation. Additionally this study explores the role of regulating the electrode surface microenvironment and forming unique coordination environments for active atoms to enhance seawater electrolysis performance. Regulating the surface microenvironment provides a novel approach to mitigating seawater corrosion. Contrary to the traditional understanding that chloride ions accelerate anode corrosion certain catalysts benefit from the unique coordination environment of chloride ions on the catalyst surface potentially enhancing oxygen evolution reaction (OER) performance. Lastly this study presents the latest advancements in the industrialization of seawater electrolysis including the in situ electrolysis of undiluted seawater and the implementation of three-chamber dual anion membranes coupled with circulating electrolyte systems. The prospects of seawater electrolysis are also explored.
Design and Performance Optimization of a Radial Turbine Using Hydrogen Combustion Products
Dec 2024
Publication
The combustion of hydrogen increases the water content of the combustion products affecting the aerodynamic performance of turbines using hydrogen as a fuel. This study aims to design a radial turbine using the differential evolution (DE) algorithm to improve its characteristics and optimize its aerodynamic performance through an orthogonal experiment and analysis of means (ANOM). The effects of varying water content in combustion products ranging from 12% to 22% on the performance of the radial turbine are also investigated. After optimization the total–static efficiency of the radial turbine increased to 89.12% which was 1.59% higher than the preliminary design. The study found that flow loss in the impeller primarily occurred at the leading edge trailing edge and the inlet of the suction surface tip and outlet. With a 10% increase in water content the enthalpy dropped Mach number increased and turbine power increased by 4.64% 1.71% and 2.41% respectively. However the total static efficiency and mass flow rate decreased by 0.71% and 2.13% respectively. These findings indicate that higher water content in hydrogen combustion products enhances the turbine’s output power while reducing the combustion products’ mass flow rate.
Greenhouse Gas Reduction Potential and Economics of Green Hydrogen via Water Electrolysis: A Systematic Review of Value-Chain-Wide Decarbonization
May 2024
Publication
Green hydrogen generated via water electrolysis has become an essential energy carrier for achieving carbon neutrality globally because of its versatility in renewable energy consumption and decarbonization applications in hard-to-abate sectors; however there is a lack of systematic analyses of its abatement potential and economics as an alternative to traditional technological decarbonization pathways. Based on bibliometric analysis and systematic evaluation methods this study characterizes and analyzes the literature on the Web of Science from 1996 to 2023 identifying research hotspots methodological models and research trends in green hydrogen for mitigating climate change across total value chain systems. Our review shows that this research theme has entered a rapid development phase since 2016 with developed countries possessing more scientific results and closer partnerships. Difficult-to-abate sectoral applications and cleaner production are the most famous value chain links and research hotspots focus on three major influencing factors: the environment; techno-economics; and energy. Green hydrogen applications which include carbon avoidance and embedding to realize carbon recycling have considerable carbon reduction potential; however uncertainty limits the influence of carbon reduction cost assessment indicators based on financial analysis methods for policy guidance. The abatement costs in the decarbonization sector vary widely across value chains electricity sources baseline scenarios technology mixes and time scenarios. This review shows that thematic research trends are focused on improving and optimizing solutions to uncertainties as well as studying multisectoral synergies and the application of abatement assessment metrics.
Examining the Nature of Two-dimensional Transverse Waves in Marginal Hydrogen Detonations using Boundary Layer Loss Modeling with Detailed Chemistry
Sep 2023
Publication
Historically it has been a challenge to simulate the experimentally observed cellular structures and marginal behavior of multidimensional hydrogen-oxygen detonations in the presence of losses even with detailed chemistry models. Very recently a quasi-two-dimensional inviscid approach was pursued where losses due to viscous boundary layers were modeled by the inclusion of an equivalent mass divergence in the lateral direction using Fay’s source term formulation with Mirels’ compressible boundary layer solutions. The same approach was used for this study along with the inclusion of thermally perfect detailed chemistry in order to capture the correct ignition sensitivity of the gas to dynamic changes in the thermodynamic state behind the detonation front. In addition the strength of transverse waves and their impact on the detonation front was investigated. Here the detailed San Diego mechanism was applied and it has been found that the detonation cell sizes can be accurately predicted without the need to prescribe specific parameters for the combustion model. For marginal cases where the detonation waves approach their failure limit quasi-stable mode behavior was observed where the number of transverse waves monotonically decreased to a single strong wave over a long enough distance. The strong transverse waves were also found to be slightly weaker than the detonation front indicating that they are not overdriven in agreement with recent studies.
Considering Carbon–Hydrogen Coupled Integrated Energy Systems: A Pathway to Sustainable Energy Transition in China Under Uncertainty
Oct 2024
Publication
The low-carbon construction of integrated energy systems is a crucial path to achieving dual carbon goals with the power-generation side having the greatest potential for emissions reduction and the most direct means of reduction which is a current research focus. However existing studies lack the precise modeling of carbon capture devices and the cascaded utilization of hydrogen energy. Therefore this paper establishes a carbon capture power plant model based on a comprehensive flexible operational mode and a coupled model of a two-stage P2G (Power-to-Gas) device exploring the “energy time-shift” characteristics of the coupled system. IGDT (Information Gap Decision Theory) is used to discuss the impact of uncertainties on the power generation side system. The results show that by promoting the consumption of clean energy and utilizing the high energy efficiency of hydrogen while reducing reliance on fossil fuels the proposed system not only meets current energy demands but also achieves a more efficient emission reduction laying a solid foundation for a sustainable future. By considering the impact of uncertainties the system ensures resilience and adaptability under fluctuating renewable energy supply conditions making a significant contribution to the field of sustainable energy transition.
Recent Advances in Combustion Science Related to Hydrogen Safety
Dec 2024
Publication
Hydrogen is a key pillar in the global Net Zero strategy. Rapid scaling up of hydrogen production transport distribution and utilization is expected. This entails that hydrogen which is traditionally an industrial gas will come into proximity of populated urban areas and in some situations handled by the untrained public. To realize all their benefits hydrogen and its technologies must be safely developed and deployed. The specific properties of hydrogen involving wide flammability range low ignition energy and fast flame speed implies that any accidental release of hydrogen can be easily ignited. Comparing with conventional fuels combustion systems fueled by hydrogen are also more prone to flame instability and abnormal combustion. This paper aims to provide a comprehensive review about combustion research related to hydrogen safety. It starts with a brief introduction which includes some overview about risk analysis codes and standards. The core content covers ignition fire explosions and deflagration to detonation transition (DDT). Considering that DDT leads to detonation and that detonation may also be induced directly under special circumstances the subject of detonation is also included for completeness. The review covers laboratory medium and large-scale experiments as well as theoretical analysis and numerical simulation results. While highlights are provided at the end of each section the paper closes with some concluding remarks highlighting the achievements and key knowledge gaps.
Performance Assessment and Optimization of the Ultra-High Speed Air Compressor in Hydrogen Fuel Cell Vehicles
Feb 2024
Publication
Air compressors in hydrogen fuel cell vehicles play a crucial role in ensuring the stability of the cathode air system. However they currently face challenges related to low efficiency and poor stability. To address these issues the experimental setup for the pneumatic performance of air compressors is established. The effects of operational parameters on energy consumption efficiency and mass flow rate of the air compressor are revealed based on a Morris global sensitivity analysis. Considering a higher flow rate larger efficiency and lower energy consumption simultaneously the optimal operating combination of the air compressor is determined based on grey relational multi-objective optimization. The optimal combination of operational parameters consisted of a speed of 80000 rpm a pressure ratio of 1.8 and an inlet temperature of 18.3 °C. Compared to the average values the isentropic efficiency achieved a 48.23% increase and the mass flow rate rose by 78.88% under the optimal operational combination. These findings hold significant value in guiding the efficient and stable operation of air compressors. The comprehensive methodology employed in this study is applicable further to investigate air compressors for hydrogen fuel cell vehicles.
The Necessity and Feasibility of Hydrogen Storage for Large-Scale, Long-Term Energy Storage in the New Power System in China
Jun 2023
Publication
In the process of building a new power system with new energy sources as the mainstay wind power and photovoltaic energy enter the multiplication stage with randomness and uncertainty and the foundation and support role of large-scale long-time energy storage is highlighted. Considering the advantages of hydrogen energy storage in large-scale cross-seasonal and cross-regional aspects the necessity feasibility and economy of hydrogen energy participation in long-time energy storage under the new power system are discussed. Firstly power supply and demand production simulations were carried out based on the characteristics of new energy generation in China. When the penetration of new energy sources in the new power system reaches 45% long-term energy storage becomes an essential regulation tool. Secondly by comparing the storage duration storage scale and application scenarios of various energy storage technologies it was determined that hydrogen storage is the most preferable choice to participate in large-scale and long-term energy storage. Three long-time hydrogen storage methods are screened out from numerous hydrogen storage technologies including salt-cavern hydrogen storage natural gas blending and solid-state hydrogen storage. Finally by analyzing the development status and economy of the above three types of hydrogen storage technologies and based on the geographical characteristics and resource endowment of China it is pointed out that China will form a hydrogen storage system of “solid state hydrogen storage above ground and salt cavern storage underground” in the future.
Advantages and Technological Progress of Hydrogen Fuel Cell Vehicles
Jun 2023
Publication
The automotive industry is undergoing a profound transformation driven by the need for sustainable and environmentally friendly transportation solutions [1]. In this context fuel cell technology has emerged as a promising alternative offering clean efficient and high-performance power sources for vehicles [2]. Fuel cell vehicles are electric vehicles that use fuel cell systems as a single power source or as a hybrid power source in combination with rechargeable energy storage systems. A typical fuel cell system for electric vehicle is exhibited in Figure 1 which provides a comprehensive demonstration of this kind of complex system. Hydrogen energy is a crucial field in the new energy revolution and will become a key pillar in building a green efficient and secure new energy system. As a critical field for hydrogen utilization fuel cell vehicles will play an important role in the transformation and development of the automotive industry. The development of fuel cell vehicles offers numerous advantages such as strong power outputs safety reliability and economic energy savings [3]. However improvements must urgently be made in existing technologies such as fuel cell stacks (including proton exchange membranes catalysts gas diffusion layers and bipolar plates) compressors and onboard hydrogen storage systems [4]. The advantages and current technological status are analyzed here.
Economic Analysis of a Photovoltaic Hydrogen Refueling Station Based on Hydrogen Load
Sep 2023
Publication
With the goal of achieving “carbon peak in 2030 and carbon neutrality in 2060” as clearly proposed by China the transportation sector will face long–term pressure on carbon emissions and the application of hydrogen fuel cell vehicles will usher in a rapid growth period. However true “zero carbon” emissions cannot be separated from “green hydrogen”. Therefore it is of practical significance to explore the feasibility of renewable energy hydrogen production in the context of hydrogen refueling stations especially photovoltaic hydrogen production which is applied to hydrogen refueling stations (hereinafter referred to “photovoltaic hydrogen refueling stations”). This paper takes a hydrogen refueling station in Shanghai with a supply capacity of 500 kg/day as the research object. Based on a characteristic analysis of the hydrogen demand of the hydrogen refueling station throughout the day this paper studies and analyzes the system configuration operation strategy environmental effects and economics of the photovoltaic hydrogen refueling station. It is estimated that when the hydrogen price is no less than 6.23 USD the photovoltaic hydrogen refueling station has good economic benefits. Additionally compared with the conventional hydrogen refueling station it can reduce carbon emissions by approximately 1237.28 tons per year with good environmental benefits.
Off-grid Wind/Hydrogen Systems with Multi-electrolyzers: Optimized Operational Strategies
Sep 2023
Publication
Optimized operation of wind/hydrogen systems can increase the system efficiency and further reduce the hydrogen production cost. In this regard extensive research has been done but there is a lack of detailed electrolyzer models and effective management of multiple electrolyzers considering their physical restrictions. This work proposes electrolyzer models that integrate the efficiency variation caused by load level change start–stop cycle (including hot and cold start) thermal management and degradation caused by frequent starts. Based on the proposed models three operational strategies are considered in this paper: two traditionally utilized methods simple start–stop and cycle rotation strategies and a newly proposed rolling optimizationbased strategy. The results from daily operation show that the new strategy results in a more balanced load level among the electrolyzers and a more stable temperature. Besides from a yearly operation perspective it is found that the proposed rolling optimization method results in more hydrogen production higher system efficiency and lower LCOH. The new method leads to hydrogen production of 311297 kg compared to 289278 kg and 303758 kg for simple start–stop and cycle rotation methods. Correspondingly the system efficiencies for the new simple start–stop and cycle rotation methods are 0.613 0.572 and 0.587. The resulting LCOH from the new method is 3.89 e/kg decreasing by 0.35 e/kg and 0.21 e/kg compared to the simple start–stop and cycle rotation methods. Finally the proposed model is compared with two conventional models to show its effectiveness in revealing more operational details and reliable results.
Study on the Inherent Safety of On-board Methanol Reforming Hydrogen Production Fuel Cell System
Sep 2023
Publication
Methanol as a liquid phase hydrogen storage carrier has broad prospects. Although the on-board methanol reforming hydrogen fuel cell system (MRFC) has long been proposed to replace the traditional hydrogen fuel cell vehicle the inherent safety of the system itself has rarely been studied. This paper adopted the improved method of Inherently Safer Process Piping (ISPP) to evaluate the pipeline inherent safety of MRFC. The process data such as temperature pressure viscosity and density were obtained by simulating the MRFC in ASPEN HYSYS. The Process Stream Characteristic Index (PSCI) and risk assessment of jet fire and vapor cloud explosion was carried out for the key streams with those simulated data. The results showed the risk ranks of different pipelines in the MRFC and the countermeasures were given according to different risk ranks. Through the in-depth study of the evaluation results this paper demonstrates the risk degree of the system in more detail and reduces the fuzziness of risk rating. By applying ISPP to the small integrated system of MRFC this paper realizes the leap of inherent safety assessment method in the object and provides a reference for the inherent safety assessment of relevant objects in the future.
Flexibility Value of Multimodal Hydrogen Energy Utilization in Electric–Hydrogen–Thermal Systems
Jun 2024
Publication
Hydrogen energy is now a crucial technological option for decarbonizing energy systems. Comprehensive utilization is a typical mode of hydrogen energy deployment leveraging its excellent conversion capabilities. Hydrogen is often used in combination with electrical and thermal energy. However current hydrogen utilization modes are relatively singular resulting in low energy utilization efficiency and high wind curtailment rates. To improve energy utilization efficiency and promote the development of hydrogen energy we discuss three utilization modes of hydrogen energy including hydrogen storage integration into a fuel cell and gas turbine hybrid power generation system and hydrogen methanation. We propose a hydrogen energy system with multimodal utilization and integrate it into an electrolytic hydrogen–thermal integrated energy system (EHTIES). A mixed-integer linear programming (MILP) optimization scheduling model for the EHT-IES is developed and solved using the Cplex solver to improve the operational feasibility of the EHTIES focusing on minimizing economic costs and reducing wind curtailment rates. Case studies in northwest China verify the effectiveness of the proposed model. By comparing various utilization modes energy storage methods and scenarios this study demonstrated that integrating a hydrogen energy system with multimodal utilization into the EHT-IES offers significant technical benefits. It enhances energy utilization efficiency and promotes the absorption of wind energy thereby increasing the flexibility of the EHT-IES.
Analysis of China’s Low-Carbon Power Transition Path Considering Low-Carbon Energy Technology Innovation
Jan 2025
Publication
Innovation in key low-carbon technologies plays a supporting role in achieving a high-quality low-carbon transition in the power sector. This paper aims to integrate research on the power transition pathway under the “dual carbon” goals with key technological innovation layouts. First it deeply analyzes the development trends of three key low-carbon technologies in the power sector—new energy storage CCUS and hydrogen energy—and establishes a quantitative model for their technological support in the low-carbon transition of the power sector. On this basis the objective function and constraints of traditional power planning models are improved to create an integrated optimization model for the power transition pathway and key low-carbon technologies. Finally a simulation analysis is conducted using China’s power industry “dual carbon” pathway as a case study. The optimization results include the power generation capacity structure power generation mix carbon reduction pathway and key low-carbon technology development path for China from 2020 to 2060. Additionally the impact of uncertainties in breakthroughs in new energy storage CCUS and hydrogen technologies on the power “dual carbon” pathway is analyzed providing technological and decision-making support for the low-carbon transition of the power sector.
Integration of Underground Green Hydrogen Storage in Hybrid Energy Generation
May 2024
Publication
One of the major challenges in harnessing energy from renewable sources like wind and solar is their intermittent nature. Energy production from these sources can vary based on weather conditions and time of day making it essential to store surplus energy for later use when there is a shortfall. Energy storage systems play a crucial role in addressing this intermittency issue and ensuring a stable and reliable energy supply. Green hydrogen sourced from renewables emerges as a promising solution to meet the rising demand for sustainable energy addressing the depletion of fossil fuels and environmental crises. In the present study underground hydrogen storage in various geological formations (aquifers depleted hydrocarbon reservoirs salt caverns) is examined emphasizing the need for a detailed geological analysis and addressing potential hazards. The paper discusses challenges associated with underground hydrogen storage including the requirement for extensive studies to understand hydrogen interactions with microorganisms. It underscores the importance of the issue with a focus on reviewing the the various past and present hydrogen storage projects and sites as well as reviewing the modeling studies in this field. The paper also emphasizes the importance of incorporating hybrid energy systems into hydrogen storage to overcome limitations associated with standalone hydrogen storage systems. It further explores the past and future integrations of underground storage of green hydrogen within this dynamic energy landscape.
A Control Strategy Study of a Renewable CCHP Energy System Integrated Hydrogen Production Unit - A Case Study of an Industrial Park in Jiangsu Province
Aug 2023
Publication
This paper describes a renewable energy system incorporating a hydrogen production unit to address the imbalance between energy supply and demand. The system utilizes renewable energy and hydrogen production energy to release energy to fill the power gap during peak demand power supply for demand peaking and valley filling. The system is optimized by analyzing marine predator behavioral logic and optimizing the system for maximum operational efficiency and best economic value. The results of the study show that after the optimized scheduling of the hydrogen production coupled renewable energy integrated energy system using the improved marine predator optimization algorithm the energy distribution of the whole energy system is good with the primary energy saving rate maintained at 24.75% the CO2 emission reduction rate maintained at 42.32% and the cost saving rate maintained at 0.78%. In addition this paper uses the Adaboost-BP prediction model to predictively analyze the system. The results show that as the price of natural gas increases the advantages of the combined hydrogen production renewable integrated energy system proposed in this paper become more obvious and the cumulative cost over three years is better than other related systems. These research results provide an important reference for the application and development of the system.
Towards a Future Hydrogen Supply Chain: A Review of Technologies and Challenges
Feb 2024
Publication
The overuse of fossil fuels has caused a serious energy crisis and environmental pollution. Due to these challenges the search for alternative energy sources that can replace fossil fuels is necessary. Hydrogen is a widely acknowledged future energy carrier because of its nonpolluting properties and high energy density. To realize a hydrogen economy in the future it is essential to construct a comprehensive hydrogen supply chain that can make hydrogen a key energy carrier. This paper reviews the various technologies involved in the hydrogen supply chain encompassing hydrogen production storage transportation and utilization technologies. Then the challenges of constructing a hydrogen supply chain are discussed from techno-economic social and policy perspectives and prospects for the future development of a hydrogen supply chain are presented in light of these challenges.
A Perspective on Broad Deployment of Hydrogen-fueled Vehicles for Ground Freight Transportation with a Comparison to Electric Vehicles
Oct 2024
Publication
The pressing global challenge of climate change necessitates a concerted effort to limit greenhouse gas emissions particularly carbon dioxide. A critical pathway is to replace fossil fuel sources by electrification including transportation. While electrification of light-duty vehicles is rapidly expanding the heavy-duty vehicle sector is subject to challenges notably the logistical drawbacks of the size and weight of high-capacity batteries required for range as well as the time for battery charging. This Perspective highlights the potential of hydrogen fuel-cell vehicles as a viable alternative for heavy-duty road transportation. We evaluate the implications of hydrogen integration into the freight economy energy dynamics and CO2 mitigation and envision a roadmap for a holistic energy transition. Our critical opinion presented in this Perspective is that federal incentives to produce hydrogen could foster growth in the nascent hydrogen economy. The pathway that we propose is that initial focus on operators of large fleets that could control their own fueling infrastructure. This opinion was formed from private discussions with numerous stakeholders during the formation of one of the awarded hydrogen hubs if they focus on early adopters that could leverage the hydrogen supply chain.
Effect of Wall Friction on Shock-flame Interactions in a Hydrogen-air Mixture
Sep 2023
Publication
Shock-flame interactions (SFI) occur in a variety of combustion scenarios of scientific and engineering interest which can distort the flame extend the flame surface area and subsequently enhance heat release. This process is dominated by Richtmyer-Meshkov instability (RMI) that features the perturbation growth of a density-difference interface (flame) after the shock passage. The main mechanism of RMI is the vorticity deposition results from a misalignment between pressure and density gradients. This paper focuses on the multi-dimensional interactions between shock wave and flame in a hydrogen-air mixture. The simulations of this work were conducted by solving three-dimensional fully-compressible reactive Navier-Stokes equations using a high-order numerical method on a dynamically adapting mesh. The effect of wall friction on the SFI was examined by varying wall boundary condition (free-slip/no-slip) on sidewall. The results show that the global flame perturbation grows faster with the effect of wall friction in the no-slip case than that in the free-slip case in the process of SFI. Two effects of wall friction on SFI were found: (1) flame stretching close to the no-slip wall and (2) damping of local flame perturbation at the no-slip wall. The flame stretch effect leads to a significantly higher growth rate in the global flame perturbation. By contrast the damping effect locally moderates the flame perturbation induced by RMI in close proximity to the no-slip wall because less vorticity is deposited on this part of flame during SFI.
Deep Low-Carbon Economic Optimization Using CCUS and Two-Stage P2G with Multiple Hydrogen Utilizations for an Integrated Energy System with a High Penetration Level of Renewables
Jul 2024
Publication
Integrating carbon capture and storage (CCS) technology into an integrated energy system (IES) can reduce its carbon emissions and enhance its low-carbon performance. However the full CCS of flue gas displays a strong coupling between lean and rich liquor as carbon dioxide liquid absorbents. Its integration into IESs with a high penetration level of renewables results in insufficient flexibility and renewable curtailment. In addition integrating split-flow CCS of flue gas facilitates a short capture time giving priority to renewable energy. To address these limitations this paper develops a carbon capture utilization and storage (CCUS) method into which storage tanks for lean and rich liquor and a two-stage power-to-gas (P2G) system with multiple utilizations of hydrogen including a fuel cell and a hydrogen-blended CHP unit are introduced. The CCUS is integrated into an IES to build an electricity–heat–hydrogen–gas IES. Accordingly a deep low-carbon economic optimization strategy for this IES which considers stepwise carbon trading coal consumption renewable curtailment penalties and gas purchasing costs is proposed. The effects of CCUS the twostage P2G system and stepwise carbon trading on the performance of this IES are analyzed through a case-comparative analysis. The results show that the proposed method allows for a significant reduction in both carbon emissions and total operational costs. It outperforms the IES without CCUS with an 8.8% cost reduction and a 70.11% reduction in carbon emissions. Compared to the IES integrating full CCS the proposed method yields reductions of 6.5% in costs and 24.7% in emissions. Furthermore the addition of a two-stage P2G system with multiple utilizations of hydrogen further amplifies these benefits cutting costs by 13.97% and emissions by 12.32%. In addition integrating CCUS into IESs enables the full consumption of renewables and expands hydrogen utilization and the renewable consumption proportion in IESs can reach 69.23%.
Storage Integrity During Underground Hydrogen Storage in Depleted Gas Reservoirs
Nov 2023
Publication
The transition from fossil fuels to renewable energy sources particularly hydrogen has emerged as a central strategy for decarbonization and the pursuit of net-zero carbon emissions. Meeting the demand for large-scale hydrogen storage a crucial component of the hydrogen supply chain has led to the exploration of underground hydrogen storage as an economically viable solution to global energy needs. In contrast to other subsurface storage options such as salt caverns and aquifers which are geographically limited depleted gas reservoirs have garnered increasing attention due to their broader distribution and higher storage capacity. However the safe storage and cycling of hydrogen in depleted gas reservoirs require the preservation of high stability and integrity in the caprock reservoir and wellbore. Nevertheless there exists a significant gap in the current research concerning storage integrity in underground hydrogen storage within depleted gas reservoirs and a systematic approach is lacking. This paper aims to address this gap by reviewing the primary challenges associated with storage integrity including geochemical reactions microbial activities faults and fractures and perspectives on hydrogen cycling. The study comprehensively reviews the processes and impacts such as abiotic and biotic mineral dissolution/precipitation reactivation and propagation of faults and fractures in caprock and host-rock wellbore instability due to cement degradation and casing corrosion and stress changes during hydrogen cycling. To provide a practical solution a technical screening tool has been developed considering controlling variables risks and consequences affecting storage integrity. Finally this paper highlights knowledge gaps and suggests feasible methods and pathways to mitigate these risks facilitating the development of large-scale underground hydrogen storage in depleted gas reservoirs.
Organic Oxidation-assisted Hydrogen Production: Glycerol Electroreforming to Formate on Nickel Diselenide Nanoparticles
Jul 2025
Publication
The energy efficiency of water electrolysis is limited by the sluggish kinetics of the anodic oxygen evolution reaction (OER) which simultaneously produces a low-value product oxygen. A promising strategy to address this challenge is to replace OER with a more favorable oxidation reaction that yields a valuable co-product. In this study we investigate the electrochemical reforming of glycerol in alkaline media to simultaneously produce hydrogen at a Pt cathode and formate at a NiSe₂ anode. The NiSe₂ electrode achieves a glycerol oxidation reaction (GOR) current density of up to 100 mA cm−2 in a 1 M KOH solution containing 1 M glycerol significantly outperforming a reference elemental Ni electrode. Both electrodes exhibit high Faradaic efficiencies (FE) achieving around 93 % for formate production at an applied potential of 1.6 V vs. RHE. To rationalize this exceptional performance density functional theory (DFT) calculations were conducted revealing that the incorporation of Se into NiSe₂ enhances the glycerol adsorption and modulates the electron density thereby lowering the energy barrier for the initial dehydrogenation step in the formate formation pathway. These findings provide valuable insights for the design of cost-effective high-performance electrocatalysts for organic oxidation-assisted hydrogen production advancing a more sustainable and economically attractive route for hydrogen generation and chemical valorization.
Research of the Impact of Hydrogen Metallurgy Technology on the Reduction of the Chinese Steel Industry’s Carbon Dioxide Emissions
Feb 2024
Publication
The steel industry which relies heavily on primary energy is one of the industries with the highest CO2 emissions in China. It is urgent for the industry to identify ways to embark on the path to “green steel”. Hydrogen metallurgy technology uses hydrogen as a reducing agent and its use is an important way to reduce CO2 emissions from long-term steelmaking and ensure the green and sustainable development of the steel industry. Previous research has demonstrated the feasibility and emission reduction effects of hydrogen metallurgy technology; however further research is needed to dynamically analyze the overall impact of the large-scale development of hydrogen metallurgy technology on future CO2 emissions from the steel industry. This article selects the integrated MARKAL-EFOM system (TIMES) model as its analysis model constructs a China steel industry hydrogen metallurgy model (TIMES-CSHM) and analyzes the resulting impact of hydrogen metallurgy technology on CO2 emissions. The results indicate that in the business-as-usual scenario (BAU scenario) applying hydrogen metallurgy technology in the period from 2020 to 2050 is expected to reduce emissions by 203 million tons and make an average 39.85% contribution to reducing the steel industry’s CO2 emissions. In the carbon emission reduction scenario applying hydrogen metallurgy technology in the period from 2020 to 2050 is expected to reduce emissions by 353 million tons contributing an average of 41.32% to steel industry CO2 reduction. This study provides an assessment of how hydrogen metallurgy can reduce CO2 emissions in the steel industry and also provides a reference for the development of hydrogen metallurgy technology.
An Overview of Application-orientated Multifunctional Large-scale Stationary Battery and Hydrogen Hybrid Energy Storage System
Dec 2023
Publication
The imperative to address traditional energy crises and environmental concerns has accelerated the need for energy structure transformation. However the variable nature of renewable energy poses challenges in meeting complex practical energy requirements. To address this issue the construction of a multifunctional large-scale stationary energy storage system is considered an effective solution. This paper critically examines the battery and hydrogen hybrid energy storage systems. Both technologies face limitations hindering them from fully meeting future energy storage needs such as large storage capacity in limited space frequent storage with rapid response and continuous storage without loss. Batteries with their rapid response (90%) excel in frequent short-duration energy storage. However limitations such as a selfdischarge rate (>1%) and capacity loss (~20%) restrict their use for long-duration energy storage. Hydrogen as a potential energy carrier is suitable for large-scale long-duration energy storage due to its high energy density steady state and low loss. Nevertheless it is less efficient for frequent energy storage due to its low storage efficiency (~50%). Ongoing research suggests that a battery and hydrogen hybrid energy storage system could combine the strengths of both technologies to meet the growing demand for large-scale long-duration energy storage. To assess their applied potentials this paper provides a detailed analysis of the research status of both energy storage technologies using proposed key performance indices. Additionally application-oriented future directions and challenges of the battery and hydrogen hybrid energy storage system are outlined from multiple perspectives offering guidance for the development of advanced energy storage systems.
Economic and Resilient Operation of Hydrogen-based Microgrids: An Improved MPC-based Optimal Scheduling Scheme Considering Security Constraints of Hydrogen Facilities
Feb 2023
Publication
Optimally scheduling alkaline electrolyzers (AELs) in a hydrogen-based microgrid (HBM) can greatly unleash the operational flexibility of the HBM. However existing scheduling strategies of AELs mostly utilize a simplified AEL model which ignores the nonlinear coupling of electric-hydrogen-thermal sectors violating the AEL’s security constraints thereby making the scheduling scheme infeasible. This paper proposes an improved model predictive control (MPC) based optimal scheduling framework which incorporates a scheduling correction algorithm into the basic MPC structure. This framework is utilized for implementing economic and resilient scheduling of an HBM under normal and emergency conditions respectively. With the scheduling correction algorithm this framework can be formulated into a computationally efficient mixedinteger linear programming meanwhile guaranteeing the solutions strictly satisfy the security constraints of hydrogen facilities (i.e. AEL and hydrogen tank). Case studies are conducted based on real operating data of a Danish energy island Bornholm. The results demonstrate that the proposed scheduling scheme under normal conditions can contribute to significant comprehensive benefits from the daily operation cost saving of 68% computational time saving of 98% and satisfying the security constraints of hydrogen facilities compared to previous scheduling strategies. Besides it sharply reduces load shedding under emergency conditions by proactively allocating distributed energy sources in the HBM.
Storage and Transportation Technology Solutions Selection for Large-scale Hydrogen Energy Utilization Scenarios under the Trend of Carbon Neutralization
Apr 2021
Publication
This paper mainly introduces the main pain point of China's civil hydrogen energy supply chain - the problem of storage and transportation and analyzes the safety economy and scale effect and other issues of the existing hydrogen energy storage and transportation compares with other storage and transportation technology solutions and comprehensively screens out the storage and transportation technology solution mainly based on liquid hydrogen technology. The liquid hydrogen technology solution has significant advantages over the existing compressed hydrogen system in terms of safety economy and scale effect especially for future large-scale hydrogen energy application scenarios. In addition the future hydrogen energy storage and transportation system based on liquid hydrogen technology can help improve the overall utilization efficiency of country’s renewable energy promote the country's energy transition promote the electrification of the country's transportation sector and help achieve China's carbon emission reduction 2030/2060 target.
Optimal Scheduling of Electricity and Hydrogen Integrated Energy System Considering Multiple Uncertainties
Apr 2024
Publication
The spread of renewable energy (RE) generation not only promotes economy and the environmental protection but also brings uncertainty to power system. As the integration of hydrogen and electricity can effectively mitigate the fluctuation of RE generation an electricity-hydrogen integrated energy system is constructed. Then this paper studies the source-load uncertainties and corresponding correlation as well as the electricity-hydrogen price uncertainties and corresponding correlation. Finally an optimal scheduling model considering economy environmental protection and demand response (DR) is proposed. The simulation results indicate that the introduction of the DR strategy and the correlation of electricity-hydrogen price can effectively improve the economy of the system. After introducing the DR the operating cost of the system is reduced by 5.59% 10.5% 21.06% in each season respectively. When considering the correlation of EP and HP the operating cost of the system is reduced by 4.71% 6.47% 1.4% in each season respectively.
Assessing the Viability of Renewable Hydrogen, Ammonia, and Methanol in Decarbonizing Heavy-duty Trucks
Jan 2025
Publication
Decarbonizing heavy-duty trucks (HDTs) is both challenging and crucial for achieving carbon neutrality in the transport sector. Renewable hydrogen (H2) methanol (MeOH) and ammonia (NH3) offer potential solutions yet their economic viability and emission benefits remain largely unexplored. This study presents for the first time a comprehensive techno-economic analysis of using these three renewable fuels to decarbonize HDTs through detailed fuel and vehicle modeling. Six pathways are compared: hydrogen fuel cell electric trucks (FCET-H2) internal combustion engine trucks using MeOH (ICET-MeOH) and NH3 (ICET-NH3) as well as three indirect pathways that utilize these fuels for power generation to charge battery electric trucks (BETs). A novel “target powertrain cost” metric is introduced to assess the economic viability of FCET-H2 ICET-NH3 and ICET-MeOH relative to BETs. The results reveal that while BET pathways demonstrate higher well-to-wheel efficiencies significant opportunities exist for ICET-MeOH and ICET-NH3 in medium- and long-haul applications. Further more FCET-H2 achieves the lowest life cycle carbon emissions while ICET-MeOH and ICET-NH3 become more cost-effective as electricity costs decline. This study offers valuable insights and benchmarks for powertrain developers and policymakers addressing a critical gap in the comparative analysis of these three fuels for decarbonizing HDTs.
Optimizing Alkaline Water Electrolysis: A Dual-Model Approach for Enhanced Hydrogen Production Efficiency
Nov 2024
Publication
This study develops a semi-empirical model of an alkaline water electrolyzer (AWE) based on thermodynamic and electrochemical principles to investigate cell voltage behavior during electrolysis. By importing polarization curve test data under specific operational conditions eight undefined parameters are precisely fitted demonstrating the model’s high accuracy in describing the voltage characteristics of alkaline electrolyzers. Additionally an AWE system model is introduced to examine the influence of various operational parameters on system efficiency. This innovative approach not only provides detailed insights into the operational dynamics of AWE systems but also offers a valuable tool for optimizing performance and enhancing efficiency advancing the understanding and optimization of AWE technologies.
Assessment of Wettability and Rock-fluid Interfacial Tension of Caprock: Implications for Hydrogen and Carbon Dioxide Geo-storage
Mar 2022
Publication
Underground hydrogen (H2) storage (UHS) and carbon dioxide (CO2) geo-storage (CGS) are prominent methods of meeting global energy needs and enabling a low-carbon global economy. The pore-scale distribution reservoir-scale storage capacity and containment security of H2 and CO2 are significantly influenced by interfacial properties including the equilibrium contact angle (θE) and solid-liquid and solid-gas interfacial tensions (γSL and γSG). However due to the technical constraints of experimentally determining these parameters they are often calculated based on advancing and receding contact angle values. There is a scarcity of θE γSL and γSG data particularly related to the hydrogen structural sealing potential of caprock which is unavailable in the literature. Young's equation and Neumann's equation of state were combined in this study to theoretically compute these three parameters (θE γSL and γSG) at reservoir conditions for the H2 and CO2 geo-storage potential. Pure mica organic-aged mica and alumina nano-aged mica substrates were investigated to explore the conditions for rock wetting phenomena and the sealing potential of caprock. The results reveal that θE increases while γSG decreases with increasing pressure organic acid concentration and alkyl chain length. However γSG decreases with increasing temperatures for H2 gas and vice versa for CO2. In addition θE and γSL decrease whereas γSG increases with increasing alumina nanofluid concentration from 0.05 to 0.25 wt%. Conversely θE and γSL increase whereas γSG decreases with increasing alumina nanofluid concentration from 0.25 to 0.75 wt%. The hydrogen wettability of mica (a proxy of caprock) was generally less than the CO2 wettability of mica at similar physio-thermal conditions. The interfacial data reported in this study are crucial for predicting caprock wettability alterations and the resulting structural sealing capacity for UHS and CGS.
Exploring Decarbonization Priorities for Sustainable Shipping: A Natural Language Processing-based Experiment
Oct 2024
Publication
The shipping industry is currently the sixth largest contributor to global emissions responsible for one billion tons of greenhouse gas emissions. Urgent action is needed to achieve carbon neutrality in the shipping industry for sustainability. In this paper we use natural language processing techniques to analyze policies announcements and position papers from national and international organizations related to the decarbonization of shipping. In particular we perform the analysis using a novel matrix-based corpus and a fine-tuned machine learning model BERTopic. Our research suggests that the top four priorities for decarbonizing shipping are preventing emissions from methane leaks promoting non-carbon-based hydrogen implementing reusable modular containers to reduce packaging waste in container shipping and protecting Arctic biodiversity while promoting the Arctic shipping route to reduce costs. Our study highlights the validity of NLP techniques in quantitatively extracting critical information related to the decarbonization of the shipping industry.
An Ageing Test Standards Analysis on Thermoplastic Liners of Type IV Composite Hydrogen Storage Tanks
Mar 2023
Publication
The liner of a carbon fiber fully reinforced composite tank with thermoplastic liner (type IV) works in a hydrogen environment with varying temperature and pressure profiles. The ageing performance of the thermoplastic liner may affect hydrogen permeability and the consequent storage capacity degrade the mechanical properties and even increase the leakage risks of type IV tanks. In this paper both testing procedures and evaluation parameters of an ageing test in a hydrogen environment required in several standards are compared and analyzed. Hydrogen static exposure in a high-temperature condition with a constant temperature and pressure is suggested to be a reasonable way to accelerate the ageing reaction of thermoplastic materials. A total of 192 h is considered a superior ageing test duration to balance the test economy and safety. The ageing test temperature in the high-temperature condition is suggested as no lower than 85 ◦C while the upper limit of test pressure is suggested to be 1.25 NWP. In addition the hydrogen permeation coefficient and mechanical properties are recognized as important parameters in ageing performance evaluation. Considering the actual service conditions the influence of temperature/pressure cycling depressurization rate and humidity on the ageing performance of thermoplastics in hydrogen are advised to be investigated experimentally.
Operation Optimization of Wind/Battery Storage/Alkaline Electrolyzer System Considering Dynamic Hydrogen Production Efficiency
Aug 2023
Publication
Hydrogen energy is regarded as a key path to combat climate change and promote sustainable economic and social development. The fluctuation of renewable energy leads to frequent start/stop cycles in hydrogen electrolysis equipment. However electrochemical energy storage with its fast response characteristics helps regulate the power of hydrogen electrolysis enabling smooth operation. In this study a multi-objective constrained operation optimization model for a wind/battery storage/alkaline electrolyzer system is constructed. Both profit maximization and power abandonment rate minimization are considered. In addition some constraints such as minimum start/stop times upper and lower power limits and input fluctuation limits are also taken into account. Then the non-dominated sorting genetic algorithm II (NSGA-II) algorithm and the entropy method are used to optimize the operation strategy of the hybrid energy system by considering dynamic hydrogen production efficiency and through optimization to obtain the best hydrogen production power of the system under the two objectives. The change in dynamic hydrogen production efficiency is mainly related to the change in electrolyzer power and the system can be better adjusted according to the actual supply of renewable energy to avoid the waste of renewable energy. Our results show that the distribution of Pareto solutions is uniform which indicates the suitability of the NSGA-II algorithm. In addition the optimal solution indicates that the battery storage and alkaline electrolyzer can complement each other in operation and achieve the absorption of wind power. The dynamic hydrogen production efficiency can make the electrolyzer operate more efficiently which paves the way for system optimization. A sensitivity analysis reveals that the profit is sensitive to the price of hydrogen energy.
Magnesium-Based Hydrogen Storage Alloys: Advances, Strategies, and Future Outlook for Clean Energy Applications
May 2024
Publication
Magnesium-based hydrogen storage alloys have attracted significant attention as promising materials for solid-state hydrogen storage due to their high hydrogen storage capacity abundant reserves low cost and reversibility. However the widespread application of these alloys is hindered by several challenges including slow hydrogen absorption/desorption kinetics high thermodynamic stability of magnesium hydride and limited cycle life. This comprehensive review provides an in-depth overview of the recent advances in magnesium-based hydrogen storage alloys covering their fundamental properties synthesis methods modification strategies hydrogen storage performance and potential applications. The review discusses the thermodynamic and kinetic properties of magnesium-based alloys as well as the effects of alloying nanostructuring and surface modification on their hydrogen storage performance. The hydrogen absorption/desorption properties of different magnesium-based alloy systems are compared and the influence of various modification strategies on these properties is examined. The review also explores the potential applications of magnesium-based hydrogen storage alloys including mobile and stationary hydrogen storage rechargeable batteries and thermal energy storage. Finally the current challenges and future research directions in this field are discussed highlighting the need for fundamental understanding of hydrogen storage mechanisms development of novel alloy compositions optimization of modification strategies integration of magnesium-based alloys into hydrogen storage systems and collaboration between academia and industry.
Numerical Study on a Diesel/Dissociated Methanol Gas Compression Ignition Engine with Exhaust Gas Recirculation
Aug 2023
Publication
Bo Li,
Yihua Chen,
Fei Zhong and
Xu Hao
Hydrogen is the most promising alternative fuel in the field of engines. Exhaust heat assisted methanol dissociation is an attractive approach for generating hydrogen. In this work simulations are conducted on a compression ignition engine fueled with different proportions of diesel-dissociated methanol gas (DMG) blends at intermediate engine speed full load and 0% EGR ratio. The results reveal that the indicated thermal efficiency and indicated mean effective pressure are greatly enhanced combustion efficiency is increased and regular emissions of CO HC and soot are reduced while NOx emissions are reduced with increased DMG substitution. In addition a simulation is conducted at an intermediate engine speed full load 15% DMG substitution ratio and varying EGR ratios of 0–20%. The results indicate that the dual-fuel engine outperforms the original engine with respect to power fuel economy and regular emissions once an optimal EGR rate is adopted.
Review of the Status and Prospects of Fiber Optic Hydrogen Sensing Technology
Aug 2023
Publication
With the unprecedented development of green and renewable energy sources the proportion of clean hydrogen (H2 ) applications grows rapidly. Since H2 has physicochemical properties of being highly permeable and combustible high-performance H2 sensors to detect and monitor hydrogen concentration are essential. This review discusses a variety of fiber-optic-based H2 sensor technologies since the year 1984 including: interferometer technology fiber grating technology surface plasma resonance (SPR) technology micro lens technology evanescent field technology integrated optical waveguide technology direct transmission/reflection detection technology etc. These technologies have been evolving from simply pursuing high sensitivity and low detection limits (LDL) to focusing on multiple performance parameters to match various application demands such as: high temperature resistance fast response speed fast recovery speed large concentration range low cross sensitivity excellent long-term stability etc. On the basis of palladium (Pd)-sensitive material alloy metals catalysts or nanoparticles are proposed to improve the performance of fiberoptic-based H2 sensors including gold (Au) silver (Ag) platinum (Pt) zinc oxide (ZnO) titanium oxide (TiO2 ) tungsten oxide (WO3 ) Mg70Ti30 polydimethylsiloxane (PDMS) graphene oxide (GO) etc. Various microstructure processes of the side and end of optical fiber H2 sensors are also discussed in this review.
CFD Simulation and ANN Prediction of Hydrogen Leakage and Diffusion Behavior in a Hydrogen Refuelling Station
Sep 2023
Publication
Hydrogen refuelling stations are an important part of the infrastructure for promoting the hydrogen economy. Since hydrogen is a flammable and explosive gas hydrogen released from high-pressure hydrogen storage equipment in hydrogen refuelling stations will likely cause combustion or explosion accidents. Studying high-pressure hydrogen leakage in hydrogen refuelling stations is a prerequisite for promoting hydrogen fuel cell vehicles and hydrogen refuelling stations. In this work an actual-size hydrogen refuelling station model was established on the ANSYS FLUENT software platform. The computational fluid dynamics (CFD) models for hydrogen leakage simulation were validated by comparing the simulation results with experimental data in the literature. The effects of ambient wind speed wind direction leakage rate and leakage direction on the diffusion behaviors of the released hydrogen were investigated. The spreading distances of the flammable hydrogen cloud were predicted using an artificial neural network for horizontal leakage. The results show that the leak direction strongly affected the flammable cloud flow. The ambient wind speed has complicated effects on spreading the flammable cloud. The wind makes the flammable cloud move in certain directions and the higher wind speed accelerates the diffusion of the flammable gas in the air. The results of the study can be used as a reference for the study of high-pressure hydrogen leakage in hydrogen refuelling stations.
Equivalent Minimum Hydrogen Consumption of Fuzzy Control-Based Fuel Cells: Exploration of Energy Management Strategies for Ships
Feb 2024
Publication
Aiming to solve the problems of insufficient dynamic responses the large loss of energy storage life of a single power cell and the large fluctuation in DC (direct current) bus voltage in fuel cell vessels this study takes a certain type of fuel cell ferry as the research object and proposes an improved equivalent minimum hydrogen consumption energy management strategy based on fuzzy logic control. First a hybrid power system including a fuel cell a lithium–iron–phosphate battery and a supercapacitor is proposed with the simulation of the power system of the modified mother ship. Second a power system simulation model and a double-closed-loop PI (proportion integration) control model are established in MATLAB/Simulink to design the equivalent hydrogen consumption model and fuzzy logic control strategy. The simulation results show that under the premise of meeting the load requirements the control strategy designed in this paper improves the Li-ion battery’s power the Li-ion battery’s SOC (state of charge) the bus voltage stability and the equivalent hydrogen consumption significantly compared with those before optimization which improves the stability and economy of the power system and has certain practical engineering value.
Progress and Prospect of the Novel Integrated SOFC-ICE Hybrid Power System: System Design, Mass and Heat Integration, System Optimization and Techno-economic Analysis
Jan 2023
Publication
This paper presents a review of system design and analysis control strategy optimization and heat and mass integration of integrated solid oxide fuel cell (SOFC) and reciprocating internal combustion engine (ICE) system. Facing the future power-fuel-power path both SOFC and ICE can adapt to a variety of fuels which is one evidence that ICE is amenable to integration with SOFC while SOFC is more efficient cleaner and quieter than ICE. Different system topologies are classified whose dynamic performances are also analyzed. In addition the heat and mass integration of system is discussed. Moreover the combustion modes of ICE which can be applied to steady combustion high efficiency and low emissions are analyzed and compared. Meanwhile the potential and methods of system waste heat recovery are discussed. The exergy analysis energy density and techno-economy are discussed. Finally the results are discussed in the last section with the final conclusion that SOFC-ICE systems are very suitable for long-distance transportation such as maritime and aviation which can also solve problems of the carbon and pollutant emissions with the background of engine cannot be replaced in maritime while the system can adapt a variety of alternative fuels.
A Comparative Study on Energy Efficiency of the Maritime Supply Chains for Liquefied Hydrogen, Ammonia, Methanol and Natural Gas
Jun 2023
Publication
To cope with climate change emerging fuels- hydrogen ammonia and methanol- have been proposed as promising energy carriers that will replace part of the liquefied natural gas (LNG) in future maritime scenarios. Energy efficiency is an important indicator for evaluating the system but the maritime supply system for emerging fuels has yet to be revealed. In this study the energy efficiency of the maritime supply chain of hydrogen ammonia methanol and natural gas is investigated considering processes including production storage loading transport and unloading. A sensitivity analysis of parameters such as ambient temperature storage time pipeline length and sailing time is also carried out. The results show that hydrogen (2.366%) has the highest daily boil-off gas (BOG) rate and wastes more energy than LNG (0.413%) with ammonia and methanol both being lower than LNG. The recycling of BOG is of great importance to the hydrogen supply chain. When produced from renewable energy sources methanol (98.02%) is the most energy efficient followed by ammonia with hydrogen being the least (89.10%). This assessment shows from an energy efficiency perspective that ammonia and methanol have the potential to replace LNG as the energy carrier of the future and that hydrogen requires efficient BOG handling systems to increase competitiveness. This study provides some inspirations for the design of global maritime supply systems for emerging fuels.
China and Italy’s Energy Development Trajectories: Current Landscapes and Future Cooperation Potential
Feb 2024
Publication
In order to achieve the ambitious goal of “carbon neutrality” countries around the world are striving to develop clean energy. Against this background this paper takes China and Italy as representatives of developing and developed countries to summarize the energy structure composition and development overview of the two countries. The paper analyzes the serious challenges facing the future energy development of both countries and investigates the possibilities of energy cooperation between the two countries taking into account their respective advantages in energy development. By comparing the policies issued by the two governments to encourage clean energy development this paper analyzes the severe challenges faced by the two countries’ energy development in the future and combines their respective energy development advantages to look forward to the possibility of energy cooperation between the two countries in the future. This lays the foundation for China and Italy to build an “Energy Road” after the “Silk Road”.
Feasibility of Scaling Up the Cost-Competitive and Clean Electrolytic Hydrogen Supply in China
May 2024
Publication
Scaling up clean hydrogen supply in the near future is critical to achieving China’s hydrogen development target. This study established an electrolytic hydrogen development mechanism considering the generation mix and operation optimization of power systems with access to hydrogen. Based on the incremental cost principle we quantified the provincial and national clean hydrogen production cost performance levels in 2030. The results indicated that this mechanism could effectively reduce the production cost of clean hydrogen in most provinces with a national average value of less than 2 USD·kg−1 at the 40-megaton hydrogen supply scale. Provincial cooperation via power transmission lines could further reduce the production cost to 1.72 USD·kg−1. However performance is affected by the potential distribution of hydrogen demand. From the supply side competitiveness of the mechanism is limited to clean hydrogen production while from the demand side it could help electrolytic hydrogen fulfil a more significant role. This study could provide a solution for the ambitious development of renewables and the hydrogen economy in China.
Cost Trajectory of Hydrogen Fuel Cell Technology in China
Apr 2025
Publication
Reducing the cost of hydrogen fuel cell technology is crucial in propelling the hydrogen economy and achieving decarbonized energy systems. This study identifies the hydrogen fuel cell cost trajectory through a multi-stage learning curve model highlighting technology learning mechanisms across different stages. Findings show that innovation and production contribute to cost reduction and the learning by researching holds a more significant role presently while the learning by doing takes precedence in the long term achieving a 14% learning rate. The cost predictions imply that the system cost of hydrogen fuel cell is expected to fall below 1000 yuan/kW after 2031. Moreover the scenario analyses highlight the conducive role of various hydrogen production technologies and the evolution of cost influencing factors on cost reduction. Our research provides critical insights into the evolving dynamics of technological learning and cost trajectory in the hydrogen fuel cell industry with significant implications for policy-making.
Numerical Simulation of Hydrogen–Coal Blending Combustion in a 660 MW Tangential Boiler
Feb 2024
Publication
With the adjustment of energy structure the utilization of hydrogen energy has been widely attended. China’s carbon neutrality targets make it urgent to change traditional coal-fired power generation. The paper investigates the combustion of pulverized coal blended with hydrogen to reduce carbon emissions. In terms of calorific value the pulverized coal combustion with hydrogen at 1% 5% and 10% blending ratios is investigated. The results show that there is a significant reduction in CO2 concentration after hydrogen blending. The CO2 concentration (mole fraction) decreased from 15.6% to 13.6% for the 10% hydrogen blending condition compared to the non-hydrogen blending condition. The rapid combustion of hydrogen produces large amounts of heat in a short period which helps the ignition of pulverized coal. However as the proportion of hydrogen blending increases the production of large amounts of H2O gives an overall lower temperature. On the other hand the temperature distribution is more uniform. The concentrations of O2 and CO in the upper part of the furnace increased. The current air distribution pattern cannot satisfy the adequate combustion of the fuel after hydrogen blending.
Design of Long-Life Wireless Near-Field Hydrogen Gas Sensor
Feb 2024
Publication
A compact wireless near-field hydrogen gas sensor is proposed which detects leaking hydrogen near its source to achieve fast responses and high reliability. A semiconductor-type sensing element is implemented in the sensor which can provide a significant response in 100 ms when stimulated by pure hydrogen. The overall response time is shortened by orders of magnitude compared to conventional sensors according to simulation results which will be within 200 ms compared with over 25 s for spatial concentration sensors under the worst conditions. Over 1 year maintenance intervals are enabled by wireless design based on the Bluetooth low energy protocol. The average energy consumption during a single alarm process is 153 µJ/s. The whole sensor is integrated on a 20 × 26 mm circuit board for compact use.
Analysis of Hydrogen Embrittlement on Aluminum Alloys for Vehicle-Mounted Hydrogen Storage Tanks: A Review
Aug 2021
Publication
High-pressure hydrogen tanks which are composed of an aluminum alloy liner and a carbon fiber wound layer are currently the most popular means to store hydrogen on vehicles. Nevertheless the aluminum alloy is easily affected by high-pressure hydrogen which leads to the appearance of hydrogen embrittlement (HE). Serious HE of hydrogen tank represents a huge dangers to the safety of vehicles and passengers. It is critical and timely to outline the mainstream approach and point out potential avenues for further investigation of HE. An analysis including the mechanism (including hydrogen-enhanced local plasticity model hydrogen-enhanced decohesion mechanism and hydrogen pressure theory) the detection (including slow strain rate test linearly increasing stress test and so on) and methods for the prevention of HE on aluminum alloys of hydrogen vehicles (such as coating) are systematically presented in this work. Moreover the entire experimental detection procedures for HE are expounded. Ultimately the prevention measures are discussed in detail. It is believed that further prevention measures will rely on the integration of multiple prevention methods. Successfully solving this problem is of great significance to reduce the risk of failure of hydrogen storage tanks and improve the reliability of aluminum alloys for engineering applications in various industries including automotive and aerospace.
The Role of Hydrogen in the Energy Transition of the Oil and Gas Industry
May 2024
Publication
Hydrogen primarily produced from steam methane reforming plays a crucial role in oil refining and provides a solution for the oil and gas industry's long-term energy transition by reducing CO2 emissions. This paper examines hydrogen’s role in this transition. Firstly experiences from oil and gas exploration including in-situ gasification can be leveraged for hydrogen production from subsurface natural hydrogen reservoirs. The produced hydrogen can serve as fuel for generating steam and heat for thermal oil recovery. Secondly hydrogen can be blended into gas for pipeline transportation and used as an alternative fuel for oil and gas hauling trucks. Additionally hydrogen can be stored underground in depleted gas fields. Lastly oilfield water can be utilized for hydrogen production using geothermal energy from subsurface oil and gas fields. Scaling up hydrogen production faces challenges such as shared use of oil and gas infrastructures increased carbon tax for promoting blue hydrogen and the introduction of financial incentives for hydrogen production and consumption hydrogen leakage prevention and detection.
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