Germany
Investigation of an Intensified Thermo-Chemical Experimental Set-Up for Hydrogen Production from Biomass: Gasification Process Integrated to a Portable Purification System—Part II
Jun 2022
Publication
Biomass gasification is a versatile thermochemical process that can be used for direct energy applications and the production of advanced liquid and gaseous energy carriers. In the present work the results are presented concerning the H2 production at a high purity grade from biomass feedstocks via steam/oxygen gasification. The data demonstrating such a process chain were collected at an innovative gasification prototype plant coupled to a portable purification system (PPS). The overall integration was designed for gas conditioning and purification to hydrogen. By using almond shells as the biomass feedstock from a product gas with an average and stable composition of 40%-v H2 21%-v CO 35%-v CO2 2.5%-v CH4 the PPS unit provided a hydrogen stream with a final concentration of 99.99%-v and a gas yield of 66.4%.
Study of Attenuation Effect of Water Droplets on Shockwaves from Hydrogen Explosion
Sep 2021
Publication
The increasing demand for renewable energy storage may position hydrogen as one of the major players in the future energy system. However to introduce such technology high level of safety must be offered. In particular for the accident scenarios with combustion or explosion of the unintendedly released hydrogen in partially or fully confined volumes such as e.g. road tunnel the effective countermeasures preventing or reducing the risk of equipment damages and person injuries should be established. A mitigation strategy could be the use of existing fire suppression system which can inject water as a spray. The shock waves resulted from hydrogen explosion could be weakened by the water droplets met on the shock path. In the presented work an attenuation effect of water droplets presence on the strength of the passing shock was studied. The analysis of the different attenuation mechanisms was performed and estimation of the effect of spray parameters such as droplet size and spray density on the shock wave was carried out. For the quantitative evaluation of the attenuation potential a numerical model for the COM3D combustion code was developed. The novel model for the droplet behavior accounting for the realistic correlations for the fluid (water) particle drag force linked with the corresponding droplet breakup model describing droplet atomization is presented. The model was validated against literature experimental data and was used for the blind simulations of the hydrogen test facility in KIT.
Carbon Footprint and Energy Transformation Analysis of Steel Produced via a Direct Reduction Plant with an Integrated Electric Melting Unit
Aug 2022
Publication
The production of fat steel products is commonly linked to highly integrated sites which include hot metal generation via the blast furnace basic oxygen furnace (BOF) continuous casting and subsequent hot-rolling. In order to reach carbon neutrality a shift away from traditional carbon-based metallurgy is required within the next decades. Direct reduction (DR) plants are capable to support this transition and allow even a stepwise reduction in CO2 emissions. Nevertheless the implementation of these DR plants into integrated metallurgical plants includes various challenges. Besides metallurgy product quality and logistics special attention is given on future energy demand. On the basis of carbon footprint methodology (ISO 14067:2019) diferent scenarios of a stepwise transition are evaluated and values of possible CO2equivalent (CO2eq) reduction are coupled with the demand of hydrogen electricity natural gas and coal. While the traditional blast furnace—BOF route delivers a surplus of electricity in the range of 0.7 MJ/kg hot-rolled coil; this surplus turns into a defcit of about 17 MJ/ kg hot-rolled coil for a hydrogen-based direct reduction with an integrated electric melting unit. On the other hand while the product carbon footprint of the blast furnace-related production route is 2.1 kg CO2eq/kg hot-rolled coil; this footprint can be reduced to 0.76 kg CO2eq/kg hot-rolled coil for the hydrogen-related route provided that the electricity input is from renewable energies. Thereby the direct impact of the processes of the integrated site can even be reduced to 0.15 kg CO2eq/ kg hot-rolled coil. Yet if the electricity input has a carbon footprint of the current German or European electricity grid mix the respective carbon footprint of hot-rolled coil even increases up to 3.0 kg CO2eq/kg hot-rolled coil. This underlines the importance of the availability of renewable energies.
A Model for Cost- and Greenhouse Gas Optimal Material and Energy Allocation of Biomass and Hydrogen
Nov 2022
Publication
BENOPT an optimal material and energy allocation model is presented which is used to assess cost-optimal and/or greenhouse gas abatement optimal allocation of renewable energy carriers across power heat and transport sectors. A high level of detail on the processes from source to end service enables detailed life-cycle greenhouse gas and cost assessments. Pareto analyses can be performed as well as thorough sensitivity analyses. The model is designed to analyse optimal biomass and hydrogen usage as a complement to integrated assessment and power system models
Fuel Cell Electrical Vehicles as Mobile Coupled Heat and Power Backup-Plant in Neighbourhoods
Apr 2022
Publication
Fuel cell electric vehicles (FCEVs) can be used during idle times to convert hydrogen into electricity in a decentralised manner thus ensuring a completely renewable energy supply. In addition to the electric power waste heat is generated in the fuel cell stack that can also be used. This paper investigates how the energy demand of a compiled German neighbourhood can be met by FCEVs and identifies potential technical problems. For this purpose energy scenarios are modelled in the Open Energy System Modelling Framework (oemof). An optimisation simulation finds the most energetically favourable solution for the 10-day period under consideration. Up to 49% of the heat demand for heating and hot water can be covered directly by the waste heat of the FCEVs. As the number of battery electric vehicles (BEVs) to be charged increases so does this share. 5 of the 252 residents must permanently provide an FCEV to supply the neighbourhood. The amount of hydrogen required was identified as a problem. If the vehicles cannot be supplied with hydrogen in a stationary way 15 times more vehicles are needed than required in terms of performance due to the energy demand.
Iron as Recyclable Energy Carrier: Feasibility Study and Kinetic Analysis of Iron Oxide Reduction
Oct 2022
Publication
Carbon-free and sustainable energy storage solutions are required to mitigate climate change. One possible solution especially for stationary applications could be the storage of energy in metal fuels. Energy can be stored through reduction of the oxide with green hydrogen and be released by combustion. In this work a feasibility study for iron as possible metal fuel considering the complete energy cycle is conducted. Based on equilibrium calculations it could be shown that the power-to-power efficiency of the iron/iron oxide cycle is 27 %. As technology development requires a more detailed description of both the reduction and the oxidation a first outlook is given on the kinetic analysis of the reduction of iron oxides with hydrogen. Based on thermogravimetric experiments using Fe2O3 Fe3O4 and FeO it could be shown that the reduction is a three-step process. The maximum reduction rate can be achieved with a hydrogen content of 25 %. Based on the experimental results a reaction mechanism and accompanied kinetic data were developed for description of Fe2O3 reduction with H2 under varying experimental conditions.
Favorable Start-Up Behavior of Polymer Electrolyte Membrane Water Electrolyzers
Nov 2022
Publication
Dynamically-operated water electrolyzers enable the production of green hydrogen for cross-sector applications while simultaneously stabilizing power grids. In this study the start-up phase of polymer electrolyte membrane (PEM) water electrolyzers is investigated in the context of intermittent renewable energy sources. During the start-up of the electrolysis system the temperature increases which directly influences hydrogen production efficiency. Experiments on a 100 kWel electrolyzer combined with simulations of electrolyzers with up to 1 MWel were used to analyze the start-up phase and assess its implications for operators and system designers. It is shown that part-load start-up at intermediate cell voltages of 1.80 V yields the highest efficiencies of 74.0 %LHV compared to heat-up using resistive electrical heating elements which reaches maximum efficiencies of 60.9 %LHV. The results further indicate that large-scale electrolyzers with electrical heaters may serve as flexible sinks in electrical grids for durations of up to 15 min.
Storage Batteries in Photovoltaic-electrochemical Device for Solar Hydrogen Production
Aug 2021
Publication
Hydrogen produced by water electrolysis and electrochemical batteries are widely considered as primary routes for the long- and short-term storage of photovoltaic (PV) energy. At the same time fast power ramps and idle periods in PV power generation may cause degradation of water splitting electrochemical (EC) cells. Implementation of batteries in PV-EC systems is a viable option for smoothening out intermittence of PV power. Notably the spreading of PV energy over the diurnal cycle reduces power of the EC cell and thus its overpotential loss. We study these potential advantages theoretically and experimentally for a simple parallel connected combination of PV EC and battery cells (PV-EC-B) operated without power management electronics. We show feasibility of the unaided operation of PV-EC-B device in a relevant duty cycle and explore how PV-EC-B system can operate at higher solar-to-hydrogen efficiency than the equivalent reference PV-EC system despite the losses caused by the battery.
Power-to-gas and the Consequences: Impact of Higher Hydrogen Concentrations in Natural Gas on Industrial Combustion Processes
Sep 2017
Publication
Operators of public electricity grids today are faced with the challenge of integrating increasing numbers of renewable and decentralized energy sources such as wind turbines and photovoltaic power plants into their grids. These sources produce electricity in a very inconstant manner due to the volatility of wind and solar power which further complicates power grid control and management. One key component that is required for modern energy infrastructures is the capacity to store large amounts of energy in an economically feasible way.<br/>One solution that is being discussed in this context is “power-to-gas” i.e. the use of surplus electricity to produce hydrogen (or even methane with an additional methanation process) which is then injected into the public natural gas grid. The huge storage capacity of the gas grid would serve as a buffer offering benefits with regards to sustainability and climate protection while also being cost-effective since the required infrastructure is already in place.<br/>One consequence would be however that the distributed natural gas could contain larger and fluctuating amounts of hydrogen. There is some uncertainty how different gas-fired applications and processes react to these changes. While there have already been several investigations for domestic appliances (generally finding that moderate amounts of H2 do not pose any safety risks which is the primary focus of domestic gas utilization) there are still open questions concerning large-scale industrial gas utilization. Here in addition to operational safety factors like efficiency pollutant emissions (NOX) process stability and of course product quality have to be taken into account.<br/>In a German research project Gas- und Wärme-Institut Essen e. V. (GWI) investigated the impact of higher and fluctuating hydrogen contents (up to 50 vol.-% much higher than what is currently envisioned) on a variety of industrial combustion systems using both numerical and experimental methods. The effects on operational aspects such as combustion behavior flame monitoring and pollutant emissions were analyzed.<br/>Some results of these investigations will be presented in this contribution.
Hydrogen Research: Technology First, Society Second?
Jul 2021
Publication
Hydrogen futures are in the making right in front of our eyes and will determine socio-ecological path dependencies for decades to come. However expertise on the societal effects of the hydrogen transition is in its infancy. Future energy research needs to include the social sciences humanities and interdisciplinary studies: energy cultures have to be examined as well as power relations and anticipation processes since the need for (green) hydrogen is likely to require a massive expansion of renewable energy plants.
Simulation of a Hydrogen-Air Diffusion Flame under Consideration of Component-Specific Diffusivities
Mar 2022
Publication
This work deals with the numerical investigation of a three-dimensional laminar hydrogenair diffusion flame in which a cylindrical fuel jet is surrounded by in-flowing air. To calculate the distribution of gas molecules the model solves the species conservation equation for N-1 components using infinity fast chemistry and irreversible chemical reaction. The consideration of the component-specific diffusion has a strong influence on the position of the high-temperature zone as well as on the concentration distribution of the individual gas molecules. The calculations of the developed model predict the radial and axial species and temperature distribution in the combustion chamber comparable to those from previous publications. Deviations due to a changed burner geometry and air supply narrow the flame structure by up to 50% and the high-temperature zones merge toward the central axis. Due to the reduced inflow velocity of the hydrogen the high-temperature zones develop closer to the nozzle inlet of the combustion chamber. As the power increases the length of the cold hydrogen jet increases. Furthermore the results show that the axial profiles of temperature and mass fractions scale quantitatively with the power input by the fuel.
Comparative TCO Analysis of Battery Electric and Hydrogen Fuel Cell Buses for Public Transport System in Small to Midsize Cities
Jul 2021
Publication
This paper shows the results of an in-depth techno-economic analysis of the public transport sector in a small to midsize city and its surrounding area. Public battery-electric and hydrogen fuel cell buses are comparatively evaluated by means of a total cost of ownership (TCO) model building on historical data and a projection of market prices. Additionally a structural analysis of the public transport system of a specific city is performed assessing best fitting bus lines for the use of electric or hydrogen busses which is supported by a brief acceptance evaluation of the local citizens. The TCO results for electric buses show a strong cost decrease until the year 2030 reaching 23.5% lower TCOs compared to the conventional diesel bus. The optimal electric bus charging system will be the opportunity (pantograph) charging infrastructure. However the opportunity charging method is applicable under the assumption that several buses share the same station and there is a “hotspot” where as many as possible bus lines converge. In the case of electric buses for the year 2020 the parameter which influenced the most on the TCO was the battery cost opposite to the year 2030 in where the bus body cost and fuel cost parameters are the ones that dominate the TCO due to the learning rate of the batteries. For H2 buses finding a hotspot is not crucial because they have a similar range to the diesel ones as well as a similar refueling time. H2 buses until 2030 still have 15.4% higher TCO than the diesel bus system. Considering the benefits of a hypothetical scaling-up effect of hydrogen infrastructures in the region the hydrogen cost could drop to 5 €/kg. In this case the overall TCO of the hydrogen solution would drop to a slightly lower TCO than the diesel solution in 2030. Therefore hydrogen buses can be competitive in small to midsize cities even with limited routes. For hydrogen buses the bus body and fuel cost make up a large part of the TCO. Reducing the fuel cost will be an important aspect to reduce the total TCO of the hydrogen bus.
The Evolution and Structure of Ignited High-pressure Cryogenic Hydrogen Jets
Jun 2022
Publication
The anticipated upscaling of hydrogen energy applications will involve the storage and transport of hydrogen at cryogenic conditions. Understanding the potential hazard arising from leaks in high-pressure cryogenic storage is needed to improve hydrogen safety. The manuscript reports a series of numerical simulations with detailed chemistry for the transient evolution of ignited high-pressure cryogenic hydrogen jets. The study aims to gain insight of the ignition processes flame structures and dynamics associated with the transient flame evolution. Numerical simulations were firstly conducted for an unignited jet released under the same cryogenic temperature of 80 K and pressure of 200 bar as the considered ignited jets. The predicted hydrogen concentrations were found to be in good agreement with the experimental measurements. The results informed the subsequent simulations of the ignited jets involving four different ignition locations. The predicted time series snapshots of temperature hydrogen mass fraction and the flame index are analyzed to study the transient evolution and structure of the flame. The results show that a diffusion combustion layer is developed along the outer boundary of the jet and a side diffusion flame is formed for the near-field ignition. For the far-field ignition an envelope flame is observed. The flame structure contains a diffusion flame on the outer edge and a premixed flame inside the jet. Due to the complex interactions between turbulence fuel-air mixing at cryogenic temperature and chemical reactions localized spontaneous ignition and transient flame extinguishment are observed. The predictions also captured the experimentally observed deflagration waves in the far-field ignited jets.
Decarbonizing China’s Energy System – Modeling the Transformation of the Electricity, Transportation, Heat, and Industrial Sectors
Nov 2019
Publication
Growing prosperity among its population and an inherent increasing demand for energy complicate China’s target of combating climate change while maintaining its economic growth. This paper therefore describes three potential decarbonization pathways to analyze different effects for the electricity transport heating and industrial sectors until 2050. Using an enhanced version of the multi-sectoral open-source Global Energy System Model enables us to assess the impact of different CO2 budgets on the upcoming energy system transformation. A detailed provincial resolution allows for the implementation of regional characteristics and disparities within China. Conclusively we complement the model-based analysis with a quantitative assessment of current barriers for the needed transformation. Results indicate that overall energy system CO2 emissions and in particular coal usage have to be reduced drastically to meet (inter-) national climate targets. Specifically coal consumption has to decrease by around 60% in 2050 compared to 2015. The current Nationally Determined Contributions proposed by the Chinese government of peaking emissions in 2030 are therefore not sufficient to comply with a global CO2 budget in line with the Paris Agreement. Renewable energies in particular photovoltaics and onshore wind profit from decreasing costs and can provide a more sustainable and cheaper energy source. Furthermore increased stakeholder interactions and incentives are needed to mitigate the resistance of local actors against a low-carbon transformation.
Fuel Flexibility of Solid Oxide Fuel Cells
Aug 2021
Publication
One of the major advantages of SOFCs is their high fuel flexibility. Next to natural gas and hydrogen which are today’s most common fuels for SOFC-systems and cell-/stack-testing respectively various other fuels are applicable as well. In the literature a number of promising results show that available fuels as propane butane ammonia gasoline diesel etc. can be applied. Here the performance of an anode supported cell operated in specialized single cell test benches with different gaseous and liquid fuels and reformates thereof is presented. Fuels as ammonia dissolved urea (AddBlueTM) methane/steam and ethanol/water mixtures can directly be fed to the cell whereas propane and diesel require external reforming. It is shown that in case of a stable fuel supply the cell performance with such fuels is similar to that of appropriate mixtures of H2 N2 CO CO2 and steam if the impact of endothermic reforming or decomposition reactions is considered. Even though a stable fuel cell operation with such fuels is possible in a single cell test bench it should be pointed out that an appropriate fuel processing will be mandatory on the system level.
Review and Comparison of Worldwide Hydrogen Activities in the Rail Sector with Special Focus on On-board Storage and Refueling Technologies
Aug 2022
Publication
"This paper investigates hydrogen storage and refueling technologies that were used in rail vehicles over the past 20 years as well as planned activities as part of demonstration projects or feasibility studies. Presented are details of the currently available technology and its vehicle integration market availability as well as standardization and research and development activities. A total of 80 international studies corporate announcements as well as vehicle and refueling demonstration projects were evaluated with regard to storage and refueling technology pressure level hydrogen amount and installation concepts inside rolling stock. Furthermore current hydrogen storage systems of worldwide manufacturers were analyzed in terms of technical data.<br/>We found that large fleets of hydrogen-fueled passenger railcars are currently being commissioned or are about to enter service along with many more vehicles on order worldwide. 35 MPa compressed gaseous storage system technology currently dominates in implementation projects. In terms of hydrogen storage requirements for railcars sufficient energy content and range are not a major barrier at present (assuming enough installation space is available). For this reason also hydrogen refueling stations required for 35 MPa vehicle operation are currently being set up worldwide.<br/>A wide variety of hydrogen demonstration and retrofit projects are currently underway for freight locomotive applications around the world in addition to completed and ongoing feasibility studies. Up to now no prevailing hydrogen storage technology emerged especially because line-haul locomotives are required to carry significantly more energy than passenger trains. The 35 MPa compressed storage systems commonly used in passenger trains offer too little energy density for mainline locomotive operation - alternative storage technologies are not yet established. Energy tender solutions could be an option to increase hydrogen storage capacity here."
Political Economy of Green Hydrogen Rollout: A Global Perspective
Dec 2021
Publication
The present paper dwells on the role of green hydrogen in the transition towards climateneutral economies and reviews the central challenges for its emancipation as an economically viable source of energy. The study shows that countries with a substantial share of renewables in the energy mix advanced natural gas pipeline infrastructure and an advanced level of technological and economic development have a comparative advantage for the wider utilization of hydrogen in their national energy systems. The central conclusion this review paper is that a green hydrogen rollout in the developed and oil-exporting developing and emerging countries is not a risk for the rest of the world in terms of the increasing technological disparities and conservation of underdevelopment and concomitant socio-economic problems of the Global South. The targets anchored in Paris Agreement but even more in the EU Green Deal and the European Hydrogen Strategy will necessitate a substantial rollout of RESs in developing countries and especially in the countries of the African Union because of the prioritization of the African continent within the energy cooperation frameworks of the EU Green Deal and the EU Hydrogen Strategy. Hence the green hydrogen rollout will bridge the energy transition between Europe and Africa on the one hand and climate and development targets on the other.
Setting Thresholds to Define Indifferences and Preferences in PROMETHEE for Life Cycle Sustainability Assessment of European Hydrogen Production
Jun 2021
Publication
The Life Cycle Sustainability Assessment (LCSA) is a proven method for sustainability assessment. However the interpretation phase of an LCSA is challenging because many different single results are obtained. Additionally performing a Multi-Criteria Decision Analysis (MCDA) is one way—not only for LCSA—to gain clarity about how to interpret the results. One common form of MCDAs are outranking methods. For these type of methods it becomes of utmost importance to clarify when results become preferable. Thus thresholds are commonly used to prevent decisions based on results that are actually indifferent between the analyzed options. In this paper a new approach is presented to identify and quantify such thresholds for Preference Ranking Organization METHod for Enrichment Evaluation (PROMETHEE) based on uncertainty of Life Cycle Impact Assessment (LCIA) methods. Common thresholds and this new approach are discussed using a case study on finding a preferred location for sustainable industrial hydrogen production comparing three locations in European countries. The single LCSA results indicated different preferences for the environmental economic and social assessment. The application of PROMETHEE helped to find a clear solution. The comparison of the newly-specified thresholds based on LCIA uncertainty with default thresholds provided important insights of how to interpret the LCSA results regarding industrial hydrogen production.
Potential of Power-to-Methane in the EU Energy Transition to a Low Carbon System Using Cost Optimization
Oct 2018
Publication
Power-to-Methane (PtM) can provide flexibility to the electricity grid while aiding decarbonization of other sectors. This study focuses specifically on the methanation component of PtM in 2050. Scenarios with 80–95% CO2 reduction by 2050 (vs. 1990) are analyzed and barriers and drivers for methanation are identified. PtM arises for scenarios with 95% CO2 reduction no CO2 underground storage and low CAPEX (75 €/kW only for methanation). Capacity deployed across EU is 40 GW (8% of gas demand) for these conditions which increases to 122 GW when liquefied methane gas (LMG) is used for marine transport. The simultaneous occurrence of all positive drivers for PtM which include limited biomass potential low Power-to-Liquid performance use of PtM waste heat among others can increase this capacity to 546 GW (75% of gas demand). Gas demand is reduced to between 3.8 and 14 EJ (compared to ∼20 EJ for 2015) with lower values corresponding to scenarios that are more restricted. Annual costs for PtM are between 2.5 and 10 bln€/year with EU28’s GDP being 15.3 trillion €/year (2017). Results indicate that direct subsidy of the technology is more effective and specific than taxing the fossil alternative (natural gas) if the objective is to promote the technology. Studies with higher spatial resolution should be done to identify specific local conditions that could make PtM more attractive compared to an EU scale.
Materials for Hydrogen-based Energy Storage - Past, Recent Progress and Future Outlook
Dec 2019
Publication
Michael Hirscher,
Volodymyr A. Yartys,
Marcello Baricco,
José Bellosta von Colbe,
Didier Blanchard,
Robert C. Bowman Jr.,
Darren P. Broom,
Craig Buckley,
Fei Chang,
Ping Chen,
Young Whan Cho,
Jean-Claude Crivello,
Fermin Cuevas,
William I. F. David,
Petra E. de Jongh,
Roman V. Denys,
Martin Dornheim,
Michael Felderhoff,
Yaroslav Filinchuk,
George E. Froudakis,
David M. Grant,
Evan MacA. Gray,
Bjørn Christian Hauback,
Teng He,
Terry D. Humphries,
Torben R. Jensen,
Sangryun Kim,
Yoshitsugu Kojima,
Michel Latroche,
Hai-wen Li,
Mykhaylo V. Lototskyy,
Joshua W. Makepeace,
Kasper T. Møller,
Lubna Naheed,
Peter Ngene,
Dag Noreus,
Magnus Moe Nygård,
Shin-ichi Orimo,
Mark Paskevicius,
Luca Pasquini,
Dorthe B. Ravnsbæk,
M. Veronica Sofianos,
Terrence J. Udovic,
Tejs Vegge,
Gavin Walker,
Colin Webb,
Claudia Weidenthaler and
Claudia Zlotea
Globally the accelerating use of renewable energy sources enabled by increased efficiencies and reduced costs and driven by the need to mitigate the effects of climate change has significantly increased research in the areas of renewable energy production storage distribution and end-use. Central to this discussion is the use of hydrogen as a clean efficient energy vector for energy storage. This review by experts of Task 32 “Hydrogen-based Energy Storage” of the International Energy Agency Hydrogen TCP reports on the development over the last 6 years of hydrogen storage materials methods and techniques including electrochemical and thermal storage systems. An overview is given on the background to the various methods the current state of development and the future prospects. The following areas are covered; porous materials liquid hydrogen carriers complex hydrides intermetallic hydrides electro-chemical storage of energy thermal energy storage hydrogen energy systems and an outlook is presented for future prospects and research on hydrogen-based energy storage
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