United Kingdom
Putting Bioenergy With Carbon Capture and Storage in a Spatial Context: What Should Go Where?
Mar 2022
Publication
This paper explores the implications of siting a bioenergy with carbon capture and storage (BECCS) facility to carbon emission performances for three case-study supply chains using the Carbon Navigation System (CNS) model. The three case-study supply chains are a wheat straw derived BECCS-power a municipal solid waste derived BECCS-waste-to-energy and a sawmill residue derived BECCS-hydrogen. A BECCS facility needs to be carefully sited taking into consideration its local low carbon infrastructure available biomass and geography for successful deployment and achieving a favorable net-negative carbon balance. On average across the three supply chains a 10 km shift in the siting of the BECCS facility results in an 8.6–13.1% increase in spatially explicit supply chain emissions. BECCS facilities producing low purity CO2 at high yields have lower spatial emissions when located within the industrial clusters while those producing high purity CO2 at low yields perform better outside the clusters. A map is also generated identifying which of the three modeled supply chains delivers the lowest spatially explicit supply chain emission options for any given area of the UK at a 1 MtCO2/yr capture scale.
Research Progress, Trends, and Current State of Development on PEMFC-New Insights from a Bibliometric Analysis and Characteristics of Two Decades of Research Output
Nov 2022
Publication
The consumption of hydrogen could increase by sixfold in 2050 compared to 2020 levels reaching about 530 Mt. Against this backdrop the proton exchange membrane fuel cell (PEMFC) has been a major research area in the field of energy engineering. Several reviews have been provided in the existing corpus of literature on PEMFC but questions related to their evolutionary nuances and research hotspots remain largely unanswered. To fill this gap the current review uses bibliometric analysis to analyze PEMFC articles indexed in the Scopus database that were published between 2000–2021. It has been revealed that the research field is growing at an annual average growth rate of 19.35% with publications from 2016 to 2012 alone making up 46% of the total articles available since 2000. As the two most energy-consuming economies in the world the contributions made towards the progress of PEMFC research have largely been from China and the US. From the research trend found in this investigation it is clear that the focus of the researchers in the field has largely been to improve the performance and efficiency of PEMFC and its components which is evident from dominating keywords or phrases such as ‘oxygen reduction reaction’ ‘electrocatalysis’ ‘proton exchange membrane’ ‘gas diffusion layer’ ‘water management’ ‘polybenzimidazole’ ‘durability’ and ‘bipolar plate’. We anticipate that the provision of the research themes that have emerged in the PEMFC field in the last two decades from the scientific mapping technique will guide existing and prospective researchers in the field going forward.
Sustainable Synthetic Carbon Based Fuels for Transport
Sep 2019
Publication
The report considers two types of sustainable synthetic fuels: electro fuels (efuels) and synthetic biofuels. Efuels are made by combining hydrogen (from for example the electrolysis of water) with carbon dioxide (from direct air capture or a point source). Synthetic biofuels can be made from biological material (for example waste from forestry) or from further processing biofuels (for example ethanol).<br/>Whilst synthetic fuels can be “dropped in” to existing engines they are currently more expensive than fossil fuels and in the case of efuels could be thought of as an inefficient use of renewable electricity. However where renewable electricity is cheap and plentiful the manufacture and export of bulk efuels might make economic sense.<br/>Key research challenges identified include improving the fundamental understanding of catalysis; the need to produce cheap low-carbon hydrogen at scale; and developing sources of competitively priced low carbon energy are key to the development of synthetic efuels and biofuels. The UK has the research skills and capacity to improve many of these process steps such as in catalysis and biotechnology and to provide a further area of UK leadership in low-carbon energy.
Hydrogen Champion Report: Recommendations to Government and Industry to Accelerate the Development of the UK Hydrogen Economy
Mar 2023
Publication
The UK Hydrogen Champion engaged with stakeholders across the hydrogen value chain between July and December 2022.<br/>This report summarises their findings and makes recommendations for government and industry to accelerate the growth of the hydrogen sector.
Trapping, Hysteresis and Ostwald Ripening in Hydrogen Storage: A Pore-scale Imaging Study
Jan 2024
Publication
Green hydrogen produced from surplus electricity during peak production can be injected into subsurface reservoirs and retrieved during high-demand periods. In this study X-ray tomography was employed to examine hysteresis resulting from repeated hydrogen injection and withdrawal. An unsteady state experiment was performed to evaluate the distribution of hydrogen and brine after drainage and imbibition cycles: images of the pore-space configuration of fluids were taken immediately once injection had stopped and after waiting for a period of 16 h with no flow. A Bentheimer sandstone sample with a length of 60 mm and diameter of 12.8 mm was used and hydrogen was injected at ambient temperature and a pore pressure of 1 MPa. The gas flow rate was decreased from 2 ml/min to 0.08 ml/min over three cycles of gas injection followed by water flooding while the brine injection rate was kept constant. The results showed the presence of capillary pressure hysteresis and hydrogen migration through Ostwald ripening due to the diffusion of gas dissolved in the brine. These phenomena were characterized through analysis of interfacial curvature area connectivity and pore occupancy. The hydrogen tended to reside in the larger pore spaces consistent with water-wet conditions. 16 h after flow had stopped the hydrogen aggregated into larger ganglia with a single large connected ganglion dominating the volume. Moreover the Euler characteristic decreased after 16 h indicating an improvement in connectivity. The work implies that Ostwald ripening – mass transport of dissolved gas – leads to less hysteresis and better connectivity than would be assumed ignoring this effect as done in assessments of hydrocarbon flow and trapping.
Techno-economic Viability of Islanded Green Ammonia as a Carbon-free Energy Vector and as a Substitute for Conventional Production
Jul 2020
Publication
Decarbonising ammonia production is an environmental imperative given that it independently accounts for 1.8% of global carbon dioxide emissions and supports the feeding of over 48% of the global population. The recent decline of production costs and its potential as an energy vector warrant investigation of whether green ammonia production is commercially competitive. Considering 534 locations in 70 countries and designing and operating the islanded production process to minimise the levelised cost of ammonia (LCOA) at each we show the range of achievable LCOA the cost of process flexibility the components of LCOA and therein the scope of LCOA reduction achievable at present and in 2030. These results are benchmarked against ammonia spot prices cost per GJ of refined fuels and the LCOE of alternative energy storage methods. Currently a LCOA of $473 t1 is achievable at the best locations the required process flexibility increases the achievable LCOA by 56%; the electrolyser CAPEX and operation are the most significant costs. By 2030 $310 t1 is predicted to be achievable with multiple locations below $350 t1 . At $25.4 GJ11 ) that do not have the benefit of being carbon-free.
EU Decarbonization under Geopolitical Pressure: Changing Paradigms and Implications for Energy and Climate Policy
Mar 2023
Publication
This paper aims to assess the impact of EU energy and climate policy as a response to Russia’s war in Ukraine on the EU decarbonization enterprise. It showcases how the Russian invasion was a crunch point that forced the EU to abandon its liberal market dogma and embrace in practice an open strategic autonomy approach. This led to an updated energy and climate policy with significant changes underpinning its main pillars interdependence diversification and the focus of market regulation and build-up. The reversal of enforced interdependence with Russia and the legislative barrage to support and build-up a domestic clean energy market unlocks significant emission reduction potential with measures targeting energy efficiency solar wind and hydrogen development; an urban renewable revolution and electricity and carbon market reforms standing out. Such positive decarbonization effects however are weakened by source and fuel diversification moves that extend to coal and shale gas especially when leading to an infrastructure build-up and locking-in gas use in the mid-term. Despite these caveats the analysis overall vindicates the hypothesis that geopolitics constitutes a facilitator and accelerator of EU energy transition.
Nuclear Cogeneration: Civil Nuclear Energy in a Low-carbon Future
Oct 2020
Publication
This policy briefing considers how the use of nuclear energy could be expanded to make the most of the energy produced and also to have the flexibility to complement an energy system with a growing input of intermittent renewable energy.<br/>What is nuclear cogeneration?<br/>Nuclear cogeneration is where the heat generated by a nuclear power station is used not only to generate electricity but to address some of the ‘difficult to decarbonise’ energy demands such as domestic heating and hydrogen production. It also enables a nuclear plant to be used more flexibly by switching between electricity generation and cogeneration applications.<br/>Applications for nuclear cogeneration<br/>Heat generated by civil nuclear reactors can be extracted at two different points for applications requiring either low-temperature or high-temperature heat. Each application differs in many aspects of operation and have different challenges.<br/>Low-temperature cogeneration<br/>Applications for the lower temperature ‘waste’ heat include:<br/>District heating<br/>Seawater desalination<br/>Low-temperature industrial process heating<br/>High-temperature cogeneration<br/>Higher temperature heat can be accessed earlier and used for:<br/>High-temperature industrial process heating<br/>Hydrogen production<br/>Sustainable synthetic fuel production<br/>Direct air capture<br/>Thermal energy storage<br/>Challenges of cogeneration systems<br/>Whilst some nuclear cogeneration applications have been employed in many countries the economic benefit of widescale nuclear cogeneration needs to be determined. However if the construction cost reductions for small modular reactors (SMRs) can be realised and the regulation and licencing processes streamlined then the additional revenue benefits of cogeneration could be material for SMRs and for the future of nuclear generation in the UK.<br/>Other outstanding issues include the ownership of reactors the future demand for hydrogen and other cogeneration products at a regional national and international level and the cost of carbon and dependable power.
Multi-port Coordination: Unlocking Flexibility and Hydrogen Opportunities in Green Energy Networks
Mar 2024
Publication
Seaports are responsible for consuming a large amount of energy and producing a sizeable amount of environmental emissions. However optimal coordination and cooperation present an opportunity to transform this challenge into an opportunity by enabling flexibility in their generation and load units. This paper introduces a coordination framework for exploiting flexibility across multiple ports. The proposed method fosters cooperation between ports in achieving lower environmental emissions while leveraging flexibility to increase their revenue. This platform allows ports to participate in providing flexibility for the energy grid through the introduction of a green port-to-grid concept while optimising their cooperation. Furthermore the proximity to offshore wind farms is considered an opportunity for the ports to investigate their role in harnessing green hydrogen. The proposed method explores the hydrogen storage capability of ports as an opportunity for increasing the techno-economic benefits particularly through coupling them with offshore wind farms. Compared to existing literature the proposed method enjoys a comprehensive logistics-electric model for the ports a novel coordination framework for multi-port flexibility and the potentials of hydrogen storage for the ports. These unique features position this paper a valuable reference for research and industry by demonstrating realistic cooperation among ports in the energy network. The simulation results confirm the effectiveness of the proposed port flexibility coordination from both environmental and economic perspectives.
Ammonia as a Suitable for Fuel Cells
Aug 2014
Publication
Ammonia an important basic chemical is produced at a scale of 150 million tons per year. Half of hydrogen produced in chemical industry is used for ammonia production. Ammonia containing 17.5 wt% hydrogen is an ideal carbon-free fuel for fuel cells. Compared to hydrogen ammonia has many advantages. In this mini-review the suitability of ammonia as fuel for fuel cells the development of different types of fuel cells using ammonia as the fuel and the potential applications of ammonia fuel cells are briefly reviewed.
Quantifying the Impacts of Heat Decarbonisation Pathways on the Future Electricity and Gas Demand
May 2022
Publication
The decarbonisation of heat supply will play a critical role in meeting the emissions reduction target. There is however great uncertainty associated with the achievable levels of heat decarbonisation and the optimal heat technology mix which can have serious implications for the future electricity and gas demand. This work employs an integrated gas electricity and heat supply model to quantify the impacts of heat decarbonisation pathways on the future electricity and gas demand. A case study in the Great Britain is performed considering two heat decarbonisation scenarios in 2050: one is the predominantly electrified heat supply and the other is the predominantly hydrogen-based heat supply. The electricity demand becomes more volatile in the electrified heat scenario as the peak surges to 107.3 GW compared to 51.1 GW in the 2018 reference scenario while the peak in hydrogen-based heat scenario is 78.4 GW. The peak gas demand declines from 247.6 GW for 2018 to 81.7 GW for electrified heat scenario and to 85.1 GW for hydrogen-based heat scenario confirming that the seasonality associated with heat demand is shifting away from the gas network and towards electricity network. Moreover a sensitivity analysis shows that the future electricity demand is highly sensitive to parameters such as relative heat demand coefficient of performance of air source heat pumps and share of electricity in hydrogen production. Finally the application of a load shifting strategy demonstrates that demand-side flexibility has the potential to maintain the electricity system balance and minimise the generation and network infrastructure requirements arising from heat electrification. While the case study presented in this paper is based on the Great Britain the findings regarding the future electricity and gas demand are relevant for the global energy transition.
Water Electrolysis: From Textbook Knowledge to the Latest Scientific Strategies and Industrial Developments
May 2022
Publication
Replacing fossil fuels with energy sources and carriers that are sustainable environmentally benign and affordable is amongst the most pressing challenges for future socio-economic development. To that goal hydrogen is presumed to be the most promising energy carrier. Electrocatalytic water splitting if driven by green electricity would provide hydrogen with minimal CO2 footprint. The viability of water electrolysis still hinges on the availability of durable earth-abundant electrocatalyst materials and the overall process efficiency. This review spans from the fundamentals of electrocatalytically initiated water splitting to the very latest scientific findings from university and institutional research also covering specifications and special features of the current industrial processes and those processes currently being tested in large-scale applications. Recently developed strategies are described for the optimisation and discovery of active and durable materials for electrodes that ever-increasingly harness first principles calculations and machine learning. In addition a technoeconomic analysis of water electrolysis is included that allows an assessment of the extent to which a large-scale implementation of water splitting can help to combat climate change. This review article is intended to cross-pollinate and strengthen efforts from fundamental understanding to technical implementation and to improve the ‘junctions’ between the field’s physical chemists materials scientists and engineers as well as stimulate much-needed exchange among these groups on challenges encountered in the different domains.
The Hydrogen Fuel Cell Battery: Replacing the Combustion Engine in Heavy Vehicles
Nov 2022
Publication
This opinion piece describes how the optimal integration of hydrogen-fuel-cell with battery in a heavy highly-utilised vehicle can extend vehicle range while cutting refuelling time and reducing cost compared to a pure battery electric vehicle.
OIES Podcast: Global Trade of Hydrogen: What is the Best Way to Transfer Hydrogen Over Long Distances?
Aug 2022
Publication
In this podcast David Ledesma talks with Rahmat Poudineh Senior Research Fellow and Aliaksei Patonia Research Fellow on issues and options with respect to long distance transportation of the hydrogen.
Hydrogen currently is mainly a local or regional commodity. If hydrogen is to become a truly global-traded commodity it needs to be transported over long transoceanic distances in an economical way. However unlike natural gas shipping compressed or liquefied hydrogen over long distances is very inefficient and expensive. At the same time hydrogen can be converted into multiple carriers with a higher energy density and higher transport capacity such as liquid ammonia toluene/methylcyclohexane (MCH) or methanol. These chemicals have their own advantages and drawbacks and their techno-economic characteristics in terms of boil-off gas and thermodynamic and conversion losses play a key role in the efficiency of transoceanic transportation of the hydrogen.
On the other hand apart from techno-economic features there are other factors to consider for long distance transportation of the hydrogen via its careers. Here such issues as safety public acceptance as well as legal and regulatory constraints may come into play. Another factor is the availability of the industries and infrastructures already developed around any of possible hydrogen carriers as well as their potential industrial applicability beyond hydrogen. Finally technological progress in other decarbonization applications and most importantly full commercialization of CCUS solutions is likely to dramatically change the approach towards long distance hydrogen transportation.
The podcast can be found on their website.
Hydrogen currently is mainly a local or regional commodity. If hydrogen is to become a truly global-traded commodity it needs to be transported over long transoceanic distances in an economical way. However unlike natural gas shipping compressed or liquefied hydrogen over long distances is very inefficient and expensive. At the same time hydrogen can be converted into multiple carriers with a higher energy density and higher transport capacity such as liquid ammonia toluene/methylcyclohexane (MCH) or methanol. These chemicals have their own advantages and drawbacks and their techno-economic characteristics in terms of boil-off gas and thermodynamic and conversion losses play a key role in the efficiency of transoceanic transportation of the hydrogen.
On the other hand apart from techno-economic features there are other factors to consider for long distance transportation of the hydrogen via its careers. Here such issues as safety public acceptance as well as legal and regulatory constraints may come into play. Another factor is the availability of the industries and infrastructures already developed around any of possible hydrogen carriers as well as their potential industrial applicability beyond hydrogen. Finally technological progress in other decarbonization applications and most importantly full commercialization of CCUS solutions is likely to dramatically change the approach towards long distance hydrogen transportation.
The podcast can be found on their website.
Economic Analysis of a Zero-carbon Liquefied Hydrogen Tanker Ship
Jun 2022
Publication
The green hydrogen economy is considered one of the sustainable solutions to mitigate climate change. This study provides an economic analysis of a novel liquified hydrogen (LH2) tanker fuelled by hydrogen with a total capacity of ~280000 m3 of liquified hydrogen named ‘JAMILA’. An established economic method was applied to investigate the economic feasibility of the JAMILA ship as a contribution to the future zero-emission target. The systematic economic evaluation determined the net present value of the LH2 tanker internal rate of return payback period and economic value added to support and encourage shipyards and the industrial sector in general. The results indicate that the implementation of the LH2 tanker ship can cover the capital cost of the ship within no more than 2.5 years which represents 8.3% of the assumed 30-year operational life cycle of the project in the best maritime shipping prices conditions and 6 years in the worst-case shipping marine economic conditions. Therefore the assessment of the economic results shows that the LH2 tankers may be a worthwhile contribution to the green hydrogen economy.
Techno-economic Study of a 100-MW-class Multi-energy Vehicle Charging/Refueling Station: Using 100% Renewable, Liquid Hydrogen, and Superconductor Technologies
Dec 2022
Publication
Renewable energies such as the wind energy and solar energy generate low-carbon electricity which can directly charge battery electric vehicles (BEVs). Meanwhile the surplus electricity can be used to produce the “green hydrogen” which provides zero-emission hydrogen fuels to those fuel cell electric vehicles (FCEVs). In order to charge/refuel multi-energy vehicles we propose a novel scheme of hybrid hydrogen/electricity supply using cryogenic and superconducting technologies. In this scheme the green hydrogen is further liquefied into the high-density and low-pressure liquid hydrogen (LH2) for bulk energy storage and transmission. Taking the advantage of the cryogenic environment of LH2 (20 K) it can also be used as the cryogen to cool down super conducting cables to realize the virtually zero-loss power transmission from 100 % renewable sources to vehicle charging stations. This hybrid LH2/electricity energy pipeline can realize long-distance large-capacity and high efficiency clean energy transmission to fulfil the hybrid energy supply demand for BEVs and FCEVs. For the case of a 100 MW-class hybrid hydrogen/electricity supply station the system principle and energy management strategy are analyzed through 9 different operating sub-modes. The corresponding static and dynamic economic modeling are performed and the economic feasibility of the hybrid hydrogen/electricity supply is verified using life-cycle analysis. Taking an example of wind power capacity 1898 MWh and solar power capacity 1619 MWh per day the dynamic payback period is 15.06 years the profitability index is 1.17 the internal rate of return is 7.956 % and the accumulative NPV is 187.92 M$. The system design and techno-economic analysis can potentially offer a technically/economically superior solution for future multi-energy vehicle charging/refueling systems.
Fuel Cell Development for New Energy Vehicles (NEVs) and Clean Air in China
Apr 2018
Publication
This paper reviews the background to New Energy Vehicles (NEV) policies in China and the key scientific and market challenges that need to be addressed to accelerate fuel cells (FCs) in the rapidly developing NEV market. The global significance of the Chinese market key players core FC technologies and future research priorities are discussed.
Effect of State of Charge on Type IV Hydrogen Storage Tank Rupture in a Fire
Sep 2021
Publication
The use of hydrogen storage tanks at 100% of nominal working pressure NWP is expected only after refuelling. Driving between refuellings is characterised by the state of charge SoC<100%. There is experimental evidence that Type IV tanks tested in a fire at initial pressures below one-third of its NWP depending on a fire source were leaking without rupture. This paper aims at understanding this phenomenon and the development of a predictive model. The numerical research has demonstrated that the heat transfer from fire through the composite overwrap is sufficient to melt the polymer liner. This initiates hydrogen microleaks through the composite wall before it loses the load-bearing ability when the resin degrades deep enough to cause the tank to rupture. The dependence of tank fire-resistance rating (FRR) on the SoC is presented for tanks of volume in the range 36-244 L. The tank wall thickness non-uniformity i.e. thinner composite at the dome area is identified as a serious issue for tank’s fire resistance that must be addressed by tank manufacturers and OEMs. The effect of the burst pressure ratio on FRR is investigated. It is concluded that thermal parameters of the composite wall i.e. decomposition heat and temperatures play a vital role in simulations of tank failure and thus FRR.
Jet Zero Strategy: Delivering Net Zero Aviation by 2050
Jul 2022
Publication
The Jet Zero strategy sets out how we will achieve net zero aviation by 2050.<br/>It focuses on the rapid development of technologies in a way that maintains the benefits of air travel whilst maximising the opportunities that decarbonisation can bring to the UK.<br/>The Jet Zero strategy includes a 5-year delivery plan setting out the actions that will need to be taken in the coming years to support the delivery of net zero aviation by 2050. We will be monitoring progress and reviewing and updating our strategy every 5 years.<br/>The strategy is informed by over 1500 responses to the Jet Zero consultation and the Jet Zero further technical consultation to which we have issued a summary of responses and government response.<br/>The Jet Zero investment flightpath is part of a series of roadmaps to be published over the course of 2022 for each sector of the Prime Minister’s Ten point plan for a green industrial revolution.<br/>It showcases the UK’s leading role in the development and commercialisation of new low and zero emission aviation technologies. It also highlights investment opportunities across systems efficiencies sustainable aviation fuels and zero emission aircraft.
HydroGenerally - Episode 5: Hydrogen for Glass Production
May 2022
Publication
In this fifth episode Steffan Eldred and Neelam Mughal from Innovate UK KTN discuss how the glass industry is driving new hydrogen developments and research and explore the hydrogen transition opportunities and challenges in this sector alongside their special guest Rob Ireson Innovation and Partnerships Manager at Glass Futures Ltd.
The podcast can be found on their website
The podcast can be found on their website
Assessment of Hydrogen Flame Length Full Bore Pipeline Rupture
Sep 2021
Publication
The study aims at the development of a safety engineering methodology for the assessment of flame length after full-bore rupture of hydrogen pipeline. The methodology is validated using experimental data on hydrogen jet flame from full-bore pipeline rupture by Acton et al. (2010). The experimental pressure dynamics in the hydrogen pipeline system is simulated using previously developed adiabatic and “isothermal” blowdown models. The hydrogen release area is taken as equal similar to the experiment to doubled pipeline cross-section as hydrogen was coming out from both sides of the ruptured pipe. The agreement with the experimental pressure decay in the piping system was achieved using discharge coefficient CD=0.26 and CD=0.21 for adiabatic and “isothermal” blowdown model respectively that indicates significant friction and minor pressure losses. The hydrogen flame length was calculated using the dimensionless correlation by Molkov and Saffers (2013). The correlation relies on the density of hydrogen in the choked flow at the pipe exit. The maximum experimental flame length between 92 m and 111 m was recorded at 6 s after the pipe rupture under the ground. The calculated by the dimensionless correlation flame length is 110 m and 120 m for the “isothermal” and adiabatic blowdown model respectively. This is an acceptable accuracy for such a large-scale experiment. It is concluded that the methodology can be applied as an engineering tool to assess flame length resulting from ruptured hydrogen pipelines.
Optimising Fuel Supply Chains within Planetary Boundaries: A Case Study of Hydrogen for Road Transport in the UK
Jul 2020
Publication
The world-wide sustainability implications of transport technologies remain unclear because their assessment often relies on metrics that are hard to interpret from a global perspective. To contribute to filling this gap here we apply the concept of planetary boundaries (PBs) i.e. a set of biophysical limits critical for operating the planet safely to address the optimal design of sustainable fuel supply chains (SCs) focusing on hydrogen for vehicle use. By incorporating PBs into a mixed-integer linear programming model (MILP) we identify SC configurations that satisfy a given transport demand while minimising the PBs transgression level i.e. while reducing the risk of surpassing the ecological capacity of the Earth. On applying this methodology to the UK we find that the current fossil-based sector is unsustainable as it transgresses the energy imbalance CO2 concentration and ocean acidification PBs heavily i.e. five to 55-fold depending on the downscale principle. The move to hydrogen would help to reduce current transgression levels substantially i.e. reductions of 9–86% depending on the case. However it would be insufficient to operate entirely within all the PBs concurrently. The minimum impact SCs would produce hydrogen via water electrolysis powered by wind and nuclear energy and store it in compressed form followed by distribution via rail which would require as much as 37 TWh of electricity per year. Our work unfolds new avenues for the incorporation of PBs in the assessment and optimisation of energy systems to arrive at sustainable solutions that are entirely consistent with the carrying capacity of the planet.
Multi-model Assessment of Heat Decarbonisation Options in the UK Using Electricity and Hydrogen
May 2022
Publication
Delivering low-carbon heat will require the substitution of natural gas with low-carbon alternatives such as electricity and hydrogen. The objective of this paper is to develop a method to soft-link two advanced investment-optimising energy system models RTN (Resource-Technology Network) and WeSIM (Whole-electricity System Investment Model) in order to assess cost-efficient heat decarbonisation pathways for the UK while utilising the respective strengths of the two models. The linking procedure included passing on hourly electricity prices from WeSIM as input to RTN and returning capacities and locations of hydrogen generation and shares of electricity and hydrogen in heat supply from RTN to WeSIM. The outputs demonstrate that soft-linking can improve the quality of the solution while providing useful insights into the cost-efficient pathways for zero-carbon heating. Quantitative results point to the cost-effectiveness of using a mix of electricity and hydrogen technologies for delivering zero-carbon heat also demonstrating a high level of interaction between electricity and hydrogen infrastructure in a zero-carbon system. Hydrogen from gas reforming with carbon capture and storage can play a significant role in the medium term while remaining a cost-efficient option for supplying peak heat demand in the longer term with the bulk of heat demand being supplied by electric heat pumps.
Feasibility of Hydrogen Storage in Depleted Hydrocarbon Chalk Reservoirs: Assessment of Biochemical and Chemical Effects
Jul 2022
Publication
Hydrogen storage is one of the energy storage methods that can help realization of an emission free future by saving surplus renewable energy for energy deficit periods. Utilization of depleted hydrocarbon reservoirs for large-scale hydrogen storage may be associated with the risk of chemical/biochemical reactions. In the specific case of chalk reservoirs the principal reactions are abiotic calcite dissolution acetogenesis methanogenesis and biological souring. Here we use PHREEQC to evaluate the dynamics and the extent of hydrogen loss by each of these reactions in hydrogen storage scenarios for various Danish North Sea chalk hydrocarbon reservoirs. We find that: (i) Abiotic calcite dissolution does not occur in the temperature range of 40-180◦ C. (ii) If methanogens and acetogens grow as slow as the slowest growing methanogens and acetogens reported in the literature methanogenesis and acetogenesis cannot cause a hydrogen loss more than 0.6% per year. However (iii) if they proceed as fast as the fastest growing methanogens and acetogens reported in the literature a complete loss of all injected hydrogen in less than five years is possible. (iv) Co-injection of CO2 can be employed to inhibit calcite dissolution and keep the produced methane due to methanogenesis carbon neutral. (v) Biological sulfate reduction does not cause significant hydrogen loss during 10 years but it can lead to high hydrogen sulfide concentrations (1015 ppm). Biological sulfate reduction is expected to impact hydrogen storage only in early stages if the only source of sulfur substrates are the dissolved species in the brine and not rock minerals. Considering these findings we suggest that depleted chalk reservoirs may not possess chemical/biochemical risks and be good candidates for large-scale underground hydrogen storage.
The Effect of a Nuclear Baseload in a Zero-carbon Electricity System: An Analysis for the UK
Jan 2023
Publication
This paper explores the effect of having a nuclear baseload in a 100% carbon-free electricity system The study analyses numerous 8 scenarios based on different penetrations of conventional nuclear wind and solar PV power different levels of overgeneration 9 and different combinations between medium and long duration energy stores (hydrogen and compressed air respectively) to 10 determine the configuration that achieves the lowest total cost of electricity (TCoE). 11 At their current cost new baseload nuclear power plants are too expensive. Results indicate the TCoE is minimised when demand 12 is supplied entirely by renewables with no contribution from conventional nuclear. 13 However small modular reactors may achieve costs of ~£60/MWh (1.5x current wind cost) in the future. With such costs 14 supplying ~80% of the country’s electricity demand with nuclear power could minimise the TCoE. In this scenario wind provides 15 the remaining 20% plus a small percentage of overgeneration (~2.5%). Hydrogen in underground caverns provides ~30.5 TWh (81 16 days) of long-duration energy storage while CAES systems provide 2.8 TWh (~8 days) of medium-duration storage. This 17 configuration achieves costs of ~65.8 £/MWh. Batteries (required for short duration imbalances) are not included in the figure. 18 The TCoE achieved will be higher once short duration storage is accounted for.
Agreement for the Low Carbon Hydrogen Production Business Model
Dec 2022
Publication
The Heads of Terms for the Low Carbon Hydrogen Agreement sets out the government’s proposal for the final hydrogen production business model design. It will form the basis of the Low Carbon Hydrogen Agreement the business model contract between the government appointed counterparty and a low carbon hydrogen producer.<br/>The business model will provide revenue support to hydrogen producers to overcome the operating cost gap between low carbon hydrogen and high carbon fuels. It has been designed to incentivise investment in low carbon hydrogen production and use and in doing so deliver the government’s ambition of up to 10GW of low carbon hydrogen production capacity by 2030.
Hydrogen Strategy Update to the Market: July 2022
Jul 2022
Publication
Low carbon hydrogen is our new home-grown super-fuel which will be vital for our energy security and to meet our legally binding commitment to achieve net zero by 2050. The UK Hydrogen Strategy published in August 2021 outlined a comprehensive roadmap for the development of a thriving UK hydrogen economy over the coming decade. In the British Energy Security Strategy published in April this year the government doubled the UK’s hydrogen production ambition to up to 10GW by 2030. This increased ambition cements our place firmly at the forefront of the global race to develop hydrogen as a secure low carbon replacement for fossil fuels in the transition to greater energy security and net zero. Since the publication of the UK Hydrogen Strategy we have continued to deliver on our commitments setting out new policy and funding for hydrogen across the value chain and bringing together the international community around shared hydrogen objectives to rapidly develop a global hydrogen economy. Hydrogen was a key component of the Net Zero Strategy COP26 and the British Energy Security Strategy. The Hydrogen Investment Package and opening of the £240 million Net Zero Hydrogen Fund in April marked a major step forward in delivering government support to drive further private investment into hydrogen production in the UK. To keep industry informed on the government’s ongoing work to develop the hydrogen economy we committed in the UK Hydrogen Strategy to producing regular updates to the market as our policy develops. In addition to offering an accessible ‘one stop shop’ of government policy development and support schemes these updates will provide industry and investors with further clarity on the direction of travel of hydrogen policy across the value chain so that government and industry can work together most effectively and with the necessary pace to build a world-leading low carbon hydrogen sector in the UK.
Prospects of Fuel Cell Combined Heat and Power Systems
Aug 2020
Publication
Combined heat and power (CHP) in a single and integrated device is concurrent or synchronized production of many sources of usable power typically electric as well as thermal. Integrating combined heat and power systems in today’s energy market will address energy scarcity global warming as well as energy-saving problems. This review highlights the system design for fuel cell CHP technologies. Key among the components discussed was the type of fuel cell stack capable of generating the maximum performance of the entire system. The type of fuel processor used was also noted to influence the systemic performance coupled with its longevity. Other components equally discussed was the power electronics. The thermal and water management was also noted to have an effect on the overall efficiency of the system. Carbon dioxide emission reduction reduction of electricity cost and grid independence were some notable advantages associated with fueling cell combined heat and power systems. Despite these merits the high initial capital cost is a key factor impeding its commercialization. It is therefore imperative that future research activities are geared towards the development of novel and cheap materials for the development of the fuel cell which will transcend into a total reduction of the entire system. Similarly robust systemic designs should equally be an active research direction. Other types of fuel aside hydrogen should equally be explored. Proper risk assessment strategies and documentation will similarly expand and accelerate the commercialization of this novel technology. Finally public sensitization of the technology will also make its acceptance and possible competition with existing forms of energy generation feasible. The work in summary showed that proton exchange membrane fuel cell (PEM fuel cell) operated at a lower temperature-oriented cogeneration has good efficiency and is very reliable. The critical issue pertaining to these systems has to do with the complication associated with water treatment. This implies that the balance of the plant would be significantly affected; likewise the purity of the gas is crucial in the performance of the system. An alternative to these systems is the PEM fuel cell systems operated at higher temperatures.
Fuel Cell Products for Sustainable Transportation and Stationary Power Generation: Review on Market Perspective
Mar 2023
Publication
The present day energy supply scenario is unsustainable and the transition towards a more environmentally friendly energy supply system of the future is inevitable. Hydrogen is a potential fuel that is capable of assisting with this transition. Certain technological advancements and design challenges associated with hydrogen generation and fuel cell technologies are discussed in this review. The commercialization of hydrogen-based technologies is closely associated with the development of the fuel cell industry. The evolution of fuel cell electric vehicles and fuel cell-based stationary power generation products in the market are discussed. Furthermore the opportunities and threats associated with the market diffusion of these products certain policy implications and roadmaps of major economies associated with this hydrogen transition are discussed in this review.
Industrial Boilers: Study to Develop Cost and Stock Assumptions for Options to Enable or Require Hydrogen-ready Industrial Boilers
Dec 2022
Publication
This study aims to help the Department for Business Energy and Industrial Strategy (BEIS) determine whether the government should intervene to enable or require hydrogen-ready industrial boiler equipment. It will do this based on information from existing literature along with qualitative and quantitative information from stakeholder engagement. The study draws on evidence gathered through BEIS’ Call for Evidence (CfE) on hydrogen-ready industrial boilers. The assessment will advance the overall understanding of hydrogen-ready industrial boilers based on four outputs: definitions of hydrogen-readiness comparisons of the cost and resource requirement to install and convert hydrogen-ready industrial boiler equipment supply chain capacity for conversion to hydrogen and estimates of the UK industrial boiler population.
Hydrogen Embrittlement Characteristics in Cold-drawn High-strength Stainless Steel Wires
Mar 2023
Publication
Hydrogen uptake and embrittlement characteristics of a cold-drawn austenitic stainless steel wire were investigated. Slow strain rate testing and fracture surface analysis were applied to determine the hydrogen embrittlement resistance providing an apparent decrease in resistance to hydrogen embrittlement for a 50% degree of cold deformation. The hydrogen content was assessed by thermal desorption and laser-induced breakdown spectroscopy establishing a correlation between the total absorbed hydrogen and the intensity of near-surface hydrogen. The sub-surface hydrogen content of the hot-rolled specimen was determined to be 791 wt.ppm.
Towards Net-zero Compatible Hydrogen from Steam Reformation - Techno-economic Analysis of Process Design Options
Dec 2022
Publication
Increased consumption of low-carbon hydrogen is prominent in the decarbonisation strategies of many jurisdictions. Yet prior studies assessing the current most prevalent production method steam reformation of natural gas (SRNG) have not sufficiently evaluated how process design decisions affect life cycle greenhouse gas (GHG) emissions. This techno-economic case study assesses cradle-to-gate emissions of hydrogen produced from SRNG with CO2 capture and storage (CCS) in British Columbia Canada. Four process configurations with amine-based CCS using existing technology and novel process designs are evaluated. We find that cradle-to-gate GHG emission intensity ranges from 0.7 to 2.7 kgCO2e/kgH2 – significantly lower than previous studies of SRNG with CCS and similar to the range of published estimates for hydrogen produced from renewable-powered electrolysis. The levelized cost of hydrogen (LCOH) in this study (US$1.1–1.3/kgH2) is significantly lower than published estimates for renewable-powered electrolysis.
Extended Design Philosophy of Hydrogen Transport Pipelines
Oct 2024
Publication
This paper examines some specific design issues associated with hydrogen transportation via pipelines based on recent field development study of high-throughput hydrogen pipelines. A mechanical design review is undertaken and the current design practices and challenge are examined first. An array of key parameters considered to have significant bearing on the hydrogen pipeline general mechanical design are considered and assessed including OOR imperfections combined stress and design factors thermal gradients joint mismatch and fabrication fatigue assessment installation specifications and material consideration. Some of these are typically ignored for the conventional pipeline design but open to rationalization for hydrogen charged pipeline systems subject to material embrittlement risk arising from hydrogen absorption. Complementary to the current design standards and as a spur to discussion on the hydrogen pipeline design analysis special considerations and recommendations are proposed on materials specification additional design criteria and construction assessments and their rationale to mitigate material embrittlement with a view to improving hydrogen pipeline design reliability and integrity management potentially leading to some tangible cost saving.
A Critical Analysis of Morocco’s Green Hydrogen Roadmap: A Modelling Approach to Assess Country Readiness from the Energy Trilemma Perspective
Apr 2024
Publication
Morocco despite its heavy reliance on imported fossil fuels which made up 68% of electricity generation in 2020 has recognised its significant renewable energy potential. The Nationally Determined Contribution (NDC) commitment is to reduce emissions by 45.5% from baseline levels with international assistance and abstain from constructing new coal plants. Moreover the Green Hydrogen Roadmap aims to export 10 TWh of green hydrogen by 2030 as well as use it for local electricity storage. This paper critically analyses this Roadmap and Morocco’s readiness to reach its ambitious targets focusing specifically on an energy trilemma perspective and using OSeMOSYS (Open-Source energy Modelling System) for energy modelling. The results reveal that the NDC scenario is only marginally more expensive than the least-cost scenario at around 1.3% (approximately USD 375 million) and facilitates a 23.32% emission reduction by 2050. An important note is the continued reliance on existing coal power plants across all scenarios which challenges both energy security and emissions. The assessment of the Green Hydrogen Scenarios highlights that it could be too costly for the Moroccan government to fund the Green Hydrogen Roadmap at this scale which leads to increased imports of polluting fossil fuels for cost reduction. In fact the emission levels are 39% higher in the green hydrogen exports scenario than in the least-cost scenario. Given these findings it is recommended that the Green Hydrogen Roadmap be re-evaluated with a suggestion for a postponement and reduction in scope.
Modelling Studies of the Hazards Posed by Liquid Hydrogen Use in Civil Aviation
Sep 2021
Publication
As part of the ENABLEH2 project modelling studies have been carried out to examine liquid hydrogen release and dispersion behaviour for different LH2 aircraft and airport infrastructure leak/spill accident scenarios. The FLACS CFD model has been used to simulate the potential hazard effects following an accidental LH2 leak including the extent of the flammable LH2 clouds formed magnitude of explosion overpressures and pool fire radiation hazards. A comparison has also been made between the relative hazard consequences of using LH2 with conventional Jet A/A-1 fuel. The results indicate that in the event of accidental fuel leak/spill LH2 has some safety advantages over Jet A/A-1 but will also introduce additional hazards not found with Jet A/A-1 that will need to be carefully managed and mitigated against.
Progress and Prospects of Reversible Solid Oxide Fuel Cell Materials
Dec 2021
Publication
Reversible solid oxide fuel cell (RSOFC) is an energy device that flexibly interchanges between electrical and chemical energy according to people’s life and production needs. The development of cell materials affects the stability and cost of the cell but also restricts its market-oriented development. After decades of research by scientists a lot of achievements and progress have been made on RSOFC materials. According to the composition and requirements of each component of RSOFC this article summarizes the research progress based on materials and discusses the merits and demerits of current cell materials in electrochemical performance. According to the efficiency of different materials in solid oxide fuel cell (SOFC mode) and solid oxide electrolyzer (SOEC mode) the challenges encountered by RSOFC in the operation are evaluated and the future development of RSOFC materials is boldly prospected.
Advancing Hydrogen: A Closer Look at Implementation Factors, Current Status and Future Potential
Dec 2023
Publication
This review article provides a comprehensive analysis of the hydrogen landscape outlining the imperative for enhanced hydrogen production implementation and utilisation. It places the question of how to accelerate hydrogen adoption within the broader context of sustainable energy transitions and international commitments to reduce carbon emissions. It discusses influencing factors and policies for best practices in hydrogen energy application. Through an in-depth exploration of key factors affecting hydrogen implementation this study provides insights into the complex interplay of both technical and logistical factors. It also discusses the challenges of planning constructing infrastructure and overcoming geographical constraints in the transition to hydrogen-based energy systems. The drive to achieve net-zero carbon emissions is contingent on accelerating clean hydrogen development with blue and green hydrogen poised to complement traditional fuels. Public–private partnerships are emerging as catalysts for the commercialisation of hydrogen and fuel-cell technologies fostering hydrogen demonstration projects worldwide. The anticipated integration of clean hydrogen into various sectors in the coming years signifies its importance as a complementary energy source although specific applications across industries remain undefined. The paper provides a good reference on the gradual integration of hydrogen into the energy landscape marking a significant step forward toward a cleaner greener future.
Understanding Costs in Hydrogen Infrastructure Networks: A Multi-stage Approach for Spatially-aware Pipeline Design
Jan 2025
Publication
The emergence and design of hydrogen transport infrastructures are crucial steps towards the development of a hydrogen economy. However pipeline routing remains underdeveloped in hydrogen infrastructure design models despite its significant impact on the resultant cost and network configuration. Many previous studies assume uniform cost surfaces on which pipelines are designed. Studies that consider a variable cost surface focus on designing candidate networks rather than bespoke routes for a given infrastructure. This study proposes a novel multi-stage approach based on a graph-based Steiner tree with Obstacles Genetic Algorithm (StObGA) to route pipelines on a complex cost surface for multi-source multi-sink hydrogen networks. The application of StObGA results in cost savings of 20–40% compared to alternative graph-based methods that assume uniform cost surfaces. Furthermore this publication presents an in-depth methodological comparative analysis of different pipeline routing and sizing methods used in the literature and discusses their impact. Finally we demonstrate how this model can generate design variations and provide practical insights to inform industry and policymakers.
Review of Next Generation Hydrogen Production from Offshore Wind Using Water Electrolysis
Dec 2023
Publication
Hydrogen produced using renewable energy from offshore wind provides a versatile method of energy storage and power-to-gas concepts. However few dedicated floating offshore electrolyser facilities currently exist and therefore conditions of the offshore environment on hydrogen production cost and efficiency remain uncertain. Therefore this review focuses on the conversion of electrical energy to hydrogen using water electrolysis located in offshore areas. The challenges associated with the remote locations fluctuating power and harsh conditions are highlighted and recommendations for future electrolysis system designs are suggested. The latest research in polymer electrolyte membrane alkaline and membraneless electrolysis are evaluated in order to understand their capital costs efficiency and current research status for achieving scaled manufacturing to the GW scale required in the next three decades. Operating fundamentals that govern the performance of each device are investigated and future recommendations of research specifically for the integration of water electrolysers with offshore wind turbines is presented.
Hydrogen UK Supply Chain Strategic Assessment
Sep 2024
Publication
Hydrogen offers the UK a unique opportunity to deliver on our Net Zero ambitions enabling deep decarbonisation of the parts of the energy system that are challenging to electrify balancing the energy system by providing large scale long duration energy storage and reducing pressure on electricity infrastructure. The UK Government in recognition of the centrality of hydrogen to the future energy system has set a 10GW hydrogen production ambition to be achieved by 2030. This ambition and its supporting policies such as the Hydrogen Business Model the Low Carbon Hydrogen Standard and the Hydrogen Transport and Storage Business Models will unlock private sector investment and kick-start the UK’s hydrogen activity. Encouragingly the UK has a positive track record of deploying low carbon technologies. The combination of the UK’s world leading policies and incentive schemes alongside a vibrant Research Development and Innovation (RD&I) and engineering environment has enabled rapid deployment of technologies such as offshore wind and electric vehicles. Yet despite being world leaders in deployment early opportunities for regional supply chain growth and job creation were not fully realised and taken advantage of from inception. The hydrogen sector is therefore at a tipping point. To capitalise on the economic opportunity hydrogen offers the UK must learn from prior technology deployments and build a strong domestic hydrogen supply chain in parallel to championing deployment.
Hydrogen is unique amongst low carbon technologies. It represents a significant economic opportunity with future hydrogen markets estimated by the Hydrogen Innovation Initiative to be worth $8tn and hydrogen technology markets estimated to reach $1tn by 20501 but crucially it is also still a nascent market. Unlike many other low carbon technologies where supply chains are already well established hydrogen supply chains are embryonic meaning that the UK has an opportunity to anchor these supply chains here and establish itself as a global leader.
The UK is well placed to capitalise on this opportunity with favourable geography and geology that enables us to produce and store hydrogen cost effectively coupled with a strong pipeline of hydrogen projects a stable policy environment that is attractive to investors and a wealth of transferable skills and expertise from the oil and gas industry.
We must ensure that alongside our focus on deployment we are also investing in technology and supply chains. Not only will this deliver exponential economic benefits from the projects supported by Government but it will also enable us to tackle increasing global supply chain constraints. Hydrogen UK estimated in its Economic Impact Assessment that hydrogen could deliver 30000 jobs annually and £7bn of GVA by 2030
It is important to be targeted and strategic in our investment and activities and recognise that hydrogen represents a wide range of technologies and the UK should not expect to lead in every area. Hydrogen UK with the support of the Hydrogen Delivery Council has undertaken analysis of the hydrogen value chain building on UK strengths and identifying the high value items that can deliver significant impact and benefit to the UK. We have also conducted widespread engagement with project developers to identify the barriers to utilising UK technology in projects and with technology developers to identify the challenges and barriers to investing and siting development and manufacturing in the UK.
The report can be found on Hydrogen UK's website.
Hydrogen is unique amongst low carbon technologies. It represents a significant economic opportunity with future hydrogen markets estimated by the Hydrogen Innovation Initiative to be worth $8tn and hydrogen technology markets estimated to reach $1tn by 20501 but crucially it is also still a nascent market. Unlike many other low carbon technologies where supply chains are already well established hydrogen supply chains are embryonic meaning that the UK has an opportunity to anchor these supply chains here and establish itself as a global leader.
The UK is well placed to capitalise on this opportunity with favourable geography and geology that enables us to produce and store hydrogen cost effectively coupled with a strong pipeline of hydrogen projects a stable policy environment that is attractive to investors and a wealth of transferable skills and expertise from the oil and gas industry.
We must ensure that alongside our focus on deployment we are also investing in technology and supply chains. Not only will this deliver exponential economic benefits from the projects supported by Government but it will also enable us to tackle increasing global supply chain constraints. Hydrogen UK estimated in its Economic Impact Assessment that hydrogen could deliver 30000 jobs annually and £7bn of GVA by 2030
It is important to be targeted and strategic in our investment and activities and recognise that hydrogen represents a wide range of technologies and the UK should not expect to lead in every area. Hydrogen UK with the support of the Hydrogen Delivery Council has undertaken analysis of the hydrogen value chain building on UK strengths and identifying the high value items that can deliver significant impact and benefit to the UK. We have also conducted widespread engagement with project developers to identify the barriers to utilising UK technology in projects and with technology developers to identify the challenges and barriers to investing and siting development and manufacturing in the UK.
The report can be found on Hydrogen UK's website.
Technoeconomic, Environmental and Multi-criteria Decision Making Investigations for Optimisation of Off-grid Hybrid Renewable Energy System with Green Hydrogen Production
Jan 2024
Publication
The current study presents a comprehensive investigation of different energy system configurations for a remote village community in India with entirely renewable electricity. Excess electricity generated by the systems has been stored using two types of energy storage options: lithium-ion batteries and green hydrogen production through the electrolysers. The hybrid renewable energy system (HRES) configurations have been sized by minimising the levelised cost of energy (LCOE). In order to identify the best-performing HRES configuration economic and environmental performance indicators has been analysed using the multi-criteria decision-making method (MCDM) TOPSIS. Among the evaluated system configurations system-1 with a photovoltaic panel (PV) size of 310.24 kW a wind turbine (WT) size of 690 kW a biogas generator (BG) size of 100 kW a battery (BAT) size of 174 kWh an electrolyser (ELEC) size of 150 kW a hydrogen tank (HT) size of 120 kg and a converter (CONV) size of 106.24 kW has been found to be the best-performing system since it provides the highest relative closeness (RC) value (∼0.817) and also has the lowest fuel consumption rate of 2.31 kg/kWh. However system-6 shows the highest amount of CO2 (143.97 kg/year) among all the studied system configurations. Furthermore a detailed technical economic and environmental analysis has been conducted on the optimal HRES configuration. The minimum net present cost (NPC) LCOE and cost of hydrogen (COH) for system 1 has been estimated to be $1960584 $0.44/kWh and $22.3/kg respectively.
The Cost of Clean Hydrogen from Offshore Wind and Electrolysis
Feb 2024
Publication
The decarbonization of industry heating and transportation is a major challenge for many countries’ energy transition. Hydrogen is a direct low-carbon fuel alternative to natural gas offering a higher flexibility in the range of possible applications yet currently most hydrogen is produced using carbonintensive steam methane reforming due to cost considerations. Therefore this study explores the economics of a prominent low-carbon method of hydrogen production comparing the cost of hydrogen generation from offshore wind farms with and without grid electricity imports to conventional hydrogen production methods. A novel techno-economic model for offshore electrolysis production costs is presented which makes hydrogen production fully dispatchable leveraging geological salt-cavern storage. This model determines the lifetime costs aportioned across the system components as well as the Levelized Cost of Hydrogen (LCOH). Using the United Kingdom as a case study LCOH from offshore wind power is calculated to be €8.68 /kgH2 using alkaline electrolysis (AEL) €10.49 /kgH2 using proton exchange membrane electrolysis (PEMEL) and €10.88 /kgH2 with grid electricity to backup the offshore wind power. A stochastic Monte-Carlo model is used to asses the uncertainty on costs and identify the cost of capital electrolyser and wind farm capital costs and cost of electricity as the most important drivers of LCOH across the different scenarios. Reducing the capital cost to comparative levels observed on today’s wind farms alone could see AEL LCOH fall to €5.32 /kgH2 near competitive with conventional generation methods.
Net Zero Fuel (Mixed Hydrogen and Biofuels) Cement Clinker: Characterisation, Microstructure, and Performance
Oct 2024
Publication
Over 35% of the CO2 associated with cement production comes from operational energy. The cement industry needs alternative fuels to meet its net zero emissions target. This study investigated the influence of hydrogen mixed with biofuels herein designated net zero fuel as an alternative to coal on the clinker quality and performance of cement produced in an industrial cement plant. Scanning electron microscopy X-ray diffraction and nuclear magnetic resonance were coupled to study the clinker mineralogy and polymorphs. Hydration and microstructure development in plain and slag blended cements based on the clinker were compared to commercial cement equivalent. The results revealed a lower alite/belite ratio but a significant proportion of the belite was of the α’H-C2S polymorph. These reacted faster and compensated for the alite/belite ratio. Gel and micro-capillary pores were densified which reduced total porosity and attained comparable strength to the reference plain and blended cement. This study demonstrates that the investigated net zero fuel-produced clinker meets compositional and strength requirements for plain and blended cement providing a feasible pathway for the cement industry to lower its operational carbon significantly.
Towards Sustainable Mobility: A Systematic Review of Hydrogen Refueling Station Security Assessment and Risk Prevention
Jan 2025
Publication
The signing of the Paris Agreement in 2016 established the goals of countries around the world for the transition from traditional fossil energy to sustainable energy in the 21st century. Reduce carbon emissions using new sustainable energy sources while safeguarding the energy needs of social development. The advantages of hydrogen fuel cell vehicles such as no carbon emissions long battery life and short hydrogenation time make them the development direction of new energy vehicles in many countries. Many countries such as the United Kingdom China and Japan have formulated hydrogen energy development plans. As the hub and supply station of the hydrogen energy transportation network the hydrogen refueling station is crucial to the development of the hydrogen economy. This paper summarizes the current main hydrogen storage methods and the existing risks analyzes the main security threats of hydrogen refueling stations and discusses the security system to prevent hydrogen embrittlement and hydrogen explosion. Finally the hydrogen refueling station is compared with the petrol station and the future security development and management pattern of the hydrogen refueling station is summarized. The security assessment of the hydrogen refueling station is carried out in this paper which provides theoretical support for the development of hydrogen refueling stations from the perspective of security.
In-house Green Hydrogen Production for Steelmaking Decarbonisation using Steel Slag as Thermal Energy Storage Material: A Life Cycle Assessment
Nov 2024
Publication
Steel production is a highly energy-intensive industry responsible for significant greenhouse gas emissions. Electrification of this sector is challenging making green hydrogen technology a promising alternative. This research performs a thermodynamic analysis of green hydrogen production for steel manufacturing using the direct reduction method. Four solid oxide electrolyzer (SOE) modules replace the traditional reformer to produce 2.88 kg/s of hydrogen gas serving as a reducing agent for iron pellets to yield 30 kg/s of molten steel. These modules are powered by 37801 photovoltaic units. Additionally a thermal storage system utilizing 1342 tons of steel slag stores waste heat from Electric Arc Furnace (EAF) exhaust gases. This stored energy preheats iron scraps charged into the EAF reducing energy consumption by 5%. A life cycle assessment conducted using open LCA software reveals that the global warming potential (GWP) for the entire process with a capacity of 30 kg/s equates to 93 kg of CO2. The study also assesses other environmental impacts such as acidification potential ozone formation fine particle formation and human toxicity. Results indicate that the EAF significantly contributes to global warming and fine particle formation while the direct reduction process notably impacts ozone formation and acidification potential.
Insights into Site Evaluation for Underground Hydrogen Storage (UHS) on Gas Mixing-the Effects of Meter-Scale Heterogeniety and Associated Reservoir Characterization Parameters
Feb 2025
Publication
Underground Hydrogen Storage (UHS) as an emerging large-scale energy storage technology has shown great promise to ensure energy security with minimized carbon emission. A set of comprehensive UHS site evaluation criteria based on important factors that affect UHS performances is needed for its potential commercialization. This study focuses on the UHS site evaluation of gas mixing. The economic implications of gas mixing between injected hydrogen gas and the residual or cushion gas in a porous storage reservoir is an emerging problem for Underground Hydrogen Storage (UHS). It is already clear that reservoir scale heterogeneity such as formation structure (e.g. formation dip angle) and facies heterogeneity of the sedimentary rock may considerably affect the reservoir-scale mechanical dispersion-induced gas mixing during UHS in high permeability braided-fluvial systems (a common depleted reservoir type for UHS). Following this finding the current study uses the processmimicking modeling software to build synthetic meandering-fluvial reservoir models. Channel dimensions and the presence of abandoned channel facies are set as testing parameters resulting in 4 simulation cases with 200 realizations. Numerical flow simulations are performed on these models to investigate and compare the effects of reservoir and metre-scale heterogeneity on UHS gas mixing. Through simulation channel dimensions (reservoir-scale heterogeneity) are found to affect the uncertainty of produced gas composition due to mixing (represented by the P10-P90 difference of hydrogen fraction in a produced stream) by up to 42%. The presence of abandoned channel facies (metre-scale heterogeneity) depending on their architectural relationship with meander belts could also influence the gas mixing process to a comparable extent (up to 40%). Moreover we show that there is no clear statistical correlation between gas mixing and typical reservoir characterization parameters such as original gas in place (OGIP) average reservoir permeability and the Dykstra-Parsons coefficient. Instead the average time of travel of all reservoir cells calculated from flow diagnostics shows a negative correlation with the level of gas mixing. These results reveal the importance of 3D reservoir architecture analysis (integration of multiple levels of heterogeneity) to UHS site evaluation on gas mixing in depleted gas reservoirs. This study herein provides valuable insights into UHS site evaluation regarding gas mixing.
Modeling and Optimization of Renewable Hydrogen Systems: A Systematic Methodological Review and Machine Learning Integration
Nov 2024
Publication
The renewable hydrogen economy is recognized as an integral solution for decarbonizing energy sectors. However high costs have hindered widespread deployment. One promising way of reducing the costs is optimization. Optimization generally involves finding the configuration of the renewable generation and hydrogen system components that maximizes return on investment. Previous studies have included many aspects into their optimisations including technical parameters and different costs/socio-economic objective functions however there is no clear best-practice framework for model development. To address these gaps this critical review examines the latest development in renewable hydrogen microgrid models and summarises the best modeling practice. The findings show that advances in machine learning integration are improving solar electricity generation forecasting hydrogen system simulations and load profile development particularly in data-scarce regions. Additionally it is important to account for electrolyzer and fuel cell dynamics rather than utilizing fixed performance values. This review also demonstrates that typical meteorological year datasets are better for modeling solar irradiation than first-principle calculations. The practicability of socio-economic objective functions is also assessed proposing that the more comprehensive Levelized Value Addition (LVA) is best suited for inclusion into models. Best practices for creating load profiles in regions like the Global South are discussed along with an evaluation of AI-based and traditional optimization methods and software tools. Finally a new evidence-based multi-criteria decision-making framework integrated with machine learning insights is proposed to guide decision-makers in selecting optimal solutions based on multiple attributes offering a more comprehensive and adaptive approach to renewable hydrogen system optimization.
Methanol Fuel Production, Utilization, and Techno-economy: A Review
Aug 2025
Publication
Climate change and the unsustainability of fossil fuels are calling for cleaner energies such as methanol as a fuel. Methanol is one of the simplest molecules for energy storage and is utilized to generate a wide range of products. Since methanol can be produced from biomass numerous countries could produce and utilize biomethanol. Here we review methanol production processes techno-economy and environmental viability. Lignocellulosic biomass with a high cellulose and hemicellulose content is highly suitable for gasifcation-based biomethanol production. Compared to fossil fuels the combustion of biomethanol reduces nitrogen oxide emissions by up to 80% carbon dioxide emissions by up to 95% and eliminates sulphur oxide emission. The cost and yield of biomethanol largely depend on feedstock characteristics initial investment and plant location. The use of biomethanol as complementary fuel with diesel natural gas and dimethyl ether is benefcial in terms of fuel economy thermal efciency and reduction in greenhouse gas emissions.
Assessment of Hydrogen Storage and Pipelines for Hydrogen Farm
Feb 2025
Publication
This paper presents a thorough initial evaluation of hydrogen gaseous storage and pipeline infrastructure emphasizing health and safety protocols as well as capacity considerations pertinent to industrial applications. As hydrogen increasingly establishes itself as a vital energy vector within the transition towards low-carbon energy systems the formulation of effective storage and transportation solutions becomes imperative. The investigation delves into the applications and technologies associated with hydrogen storage specifically concentrating on compressed hydrogen gas storage elucidating the principles underlying hydrogen compression and the diverse categories of hydrogen storage tanks including pressure vessels specifically designed for gaseous hydrogen containment. Critical factors concerning hydrogen gas pipelines are scrutinized accompanied by a review of appropriate compression apparatus types of compressors and particular pipeline specifications necessary for the transport of both hydrogen and oxygen generated by electrolysers. The significance of health and safety in hydrogen systems is underscored due to the flammable nature and high diffusivity of hydrogen. This paper defines the recommended health and safety protocols for hydrogen storage and pipeline operations alongside exemplary practices for the effective implementation of these protocols across various storage and pipeline configurations. Moreover it investigates the function of oxygen transport pipelines and the applications of oxygen produced from electrolysers considering the interconnected safety standards governing hydrogen and oxygen infrastructure. The conclusions drawn from this study facilitate the advancement of secure and efficient hydrogen storage and pipeline systems thereby furthering the overarching aim of scalable hydrogen energy deployment within both energy and industrial sectors.
OIES Podcast - Key Energy Themes for 2024
Jan 2024
Publication
In this latest OIES podcast James Henderson talks to Bill Farren-Price the new Head of the Gas Programme about some of Key Themes identified by OIES research fellows for 2024. After a review of the outcomes from 2023 we look at the oil and gas markets and discuss a common theme around the contrast between the fundamental tightness in both markets compared with the relative softness of prices. We then move onto a number of energy transition issues starting with some of the key actions from COP28 that need to be implemented in 2024 and following with a review of the outlook for carbon markets hydrogen developments and offshore wind. We also consider the impact of emerging competition between regions over green industrial policy. Finally we consider some of the key geopolitical drivers for 2024 with the influence of China being the most critical. However in an election year for so many countries it will be critical to follow the key policy announcements of the main candidates and of most critically the outcome of the US election in November.
The podcast can be found on their website
The podcast can be found on their website
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