Korea, Republic of
Behavior of Barrier Wall under Hydrogen Storage Tank Explosion with Simulation and TNT Equivalent Weight Method
Mar 2023
Publication
Hydrogen gas storage place has been increasing daily because of its consumption. Hydrogen gas is a dream fuel of the future with many social economic and environmental benefits to its credit. However many hydrogen storage tanks exploded accidentally and significantly lost the economy infrastructure and living beings. In this study a protection wall under a worst-case scenario explosion of a hydrogen gas tank was analyzed with commercial software LS-DYNA. TNT equivalent method was used to calculate the weight of TNT for Hydrogen. Reinforced concrete and composite protection wall under TNT explosion was analyzed with a different distance of TNT. The initial dimension of the reinforced concrete protection wall was taken from the Korea gas safety code book (KGS FP217) and studied the various condition. H-beam was used to make the composite protection wall. Arbitrary-Lagrangian-Eulerian (ALE) simulation from LS-DYNA and ConWep pressure had a good agreement. Used of the composite structure had a minimum displacement than a normal reinforced concrete protection wall. During the worst-case scenario explosion of a hydrogen gas 300 kg storage tank the minimum distance between the hydrogen gas tank storage and protection wall should be 3.6 m.
Photocatalytic Hydrogen Evolution from Biomass Conversion
Feb 2021
Publication
Biomass has incredible potential as an alternative to fossil fuels for energy production that is sustainable for the future of humanity. Hydrogen evolution from photocatalytic biomass conversion not only produces valuable carbon-free energy in the form of molecular hydrogen but also provides an avenue of production for industrially relevant biomass products. This photocatalytic conversion can be realized with efficient sustainable reaction materials (biomass) and inexhaustible sunlight as the only energy inputs. Reported herein is a general strategy and mechanism for photocatalytic hydrogen evolution from biomass and biomass-derived substrates (including ethanol glycerol formic acid glucose and polysaccharides). Recent advancements in the synthesis and fundamental physical/mechanistic studies of novel photocatalysts for hydrogen evolution from biomass conversion are summarized. Also summarized are recent advancements in hydrogen evolution efciency regarding biomass and biomass-derived substrates. Special emphasis is given to methods that utilize unprocessed biomass as a substrate or synthetic photocatalyst material as the development of such will incur greater benefts towards a sustainable route for the evolution of hydrogen and production of chemical feedstocks.
Multi-functional Hybrid Energy System for Zero-energy Residential Buildings: Integrating Hydrogen Production and Renewable Energy Solutions
Jan 2025
Publication
The increasing global residential energy demand causes carbon emissions and ecological impacts necessitating cleaner efficient solutions. This study presents an innovative hybrid energy system integrating wind power and gas turbines for a four-story 16-unit residential building. The system generates electricity heating cooling and hydrogen using a Proton Exchange Membrane electrolyzer and a compression chiller. Integrating the electrolyzer enables hydrogen production and demonstrates hydrogen’s potential as a versatile clean energy carrier for systems contributing to advancements in hydrogen utilization. Simulations with Engineering Equation Solver software coupled with neural network-based multi-objective optimization fine-tuned parameters such as gas turbine efficiency wind turbine count and gas turbine inlet temperature to enhance exergy efficiency and reduce operational costs. The optimized system achieves an energy efficiency of 33.69% and an exergy efficiency of 36.95% and operates at $446.04 per hour demonstrating economic viability. It produces 51061 MWh annually exceeding the building’s energy demands and allowing surplus energy use elsewhere. BEopt simulations confirm the system meets residential needs by providing 2.52 GWh of electricity 3.36 GWh of heating and 5.11 GWh of cooling annually. This system also generates 10 kg of hydrogen per hour and achieves a CO₂ reduction of 10416 tons/year. The wind farm (25 turbines) provides most of the energy at 396.7 dollars per hour while the gas turbine operates at 80% efficiency. By addressing the challenges of intermittent renewable energy in residential Zero-Energy Buildings this research offers a scalable and environmentally friendly solution contributing to sustainable urban living and advancing hydrogen energy applications.
Hydrogen Risk Assessment Studies: A Review Toward Environmental Sustainability
Jan 2025
Publication
The transition to hydrogen as a clean energy source is critical for addressing climate change and supporting environmental sustainability. This review provides an accessible summary of general research trends in hydrogen risk assessment methodologies enabling diverse stakeholders including researchers policymakers and industry professionals to gain insights into this field. By examining representative studies across theoretical experimental and simulation-based approaches the review highlights prominent trends and applications within academia and industry. The key focus is on evaluating risks in stationary and transportation applications paying particular attention to hydrogen storage systems transportation infrastructures and energy systems. By offering a concise yet informative summary of hydrogen risk assessment trends this paper aims to serve as a foundational resource for fostering safer and more sustainable hydrogen systems.
Diffusible Hydrogen Behavior and Delayed Fracture of Cold Rolled Martensitic Steel in Consideration of Automotive Manufacturing Process and Vehicle Service Environment
Oct 2020
Publication
This study aims to elucidate the behavior of diffusible hydrogen and delayed fracture in martensitic steel with 1500 MPa strength during automotive painting process and under vehicle service conditions. A sequential process of automotive pretreatment line and vehicle service environment is simulated to evaluate the hydrogen pick up in each process. In case of the automotive painting line the absorption of hydrogen is within the common range in the process of phosphating treatment and electrodeposition. The baking process plays an effective role for desorbing the diffusible hydrogen absorbed during the automotive pre-treatment such as zinc-phosphating and electrodeposition process. In case of the corrosion environment under the automotive driving conditions hydrogen induced delayed fracture is accelerated as the exposure time increases. Further it is clarified that severe plastic deformation are the significant factors for hydrogen induced delayed fracture under with low pH value and present of chloride ion in a chemical solution parameter. In summary hydrogen is transported constantly during electrodeposition sequential line process of automobile manufacturing below the hydrogen content of 0.5 ppm which is not critical value for leading to hydrogen delayed fracture based on results of slow strain rate tensile tests. However exposure to extreme conditions under service environment of vehicle such as acidic solution and chloride chemistry solution that result in high level of hydrogen absorption severe plastic deformation in the sheared edge and constantly applied internal or external stresses can cause the hydrogen induced delayed fracture in the fully martensitic steels.
Strategic Public Relations Policy for Accelerating Hydrogen Acceptance: Insights from an Expert Survey in South Korea
Aug 2024
Publication
Hydrogen has great growth potential due to its green carbon-neutral nature but public acceptance is low due to negative perceptions of the dangers associated with hydrogen energy. Safety concerns particularly related to its flammability and explosiveness are an obstacle to hydrogen energy policy. In South Korea recent hydrogen-related explosions have exacerbated these concerns undermining public confidence. This study developed public relations (PR) strategies to manage risk perception and promote hydrogen energy acceptance by analyzing the opinions of government officials and experts using SWOT factors the TOWS matrix and the analytic hierarchy process. The findings highlight the importance of addressing weaknesses and threats in PR efforts. Key weaknesses include Korea’s technological lag and the low localization of core hydrogen technologies both of which hinder competitiveness and negatively impact public perception of hydrogen energy. Notable threats include deteriorating energy dependency and expanding global carbon regulations. This information can be used to influence attitudes and foster public acceptance of hydrogen energy policies. Emphasizing weaknesses and threats may result in more effective PR strategies even if they do not directly address the primary concerns of scientific experts. The persuasive insights identified in this study can support future policy communication and PR strategies.
Environmental Assessment of Hydrogen Utilization in Various Applications and Alternative Renewable Sources for Hydrogen Production: A Review
May 2023
Publication
Rapid industrialization is consuming too much energy and non-renewable energy resources are currently supplying the world’s majority of energy requirements. As a result the global energy mix is being pushed towards renewable and sustainable energy sources by the world’s future energy plan and climate change. Thus hydrogen has been suggested as a potential energy source for sustainable development. Currently the production of hydrogen from fossil fuels is dominant in the world and its utilization is increasing daily. As discussed in the paper a large amount of hydrogen is used in rocket engines oil refining ammonia production and many other processes. This paper also analyzes the environmental impacts of hydrogen utilization in various applications such as iron and steel production rocket engines ammonia production and hydrogenation. It is predicted that all of our fossil fuels will run out soon if we continue to consume them at our current pace of consumption. Hydrogen is only ecologically friendly when it is produced from renewable energy. Therefore a transition towards hydrogen production from renewable energy resources such as solar geothermal and wind is necessary. However many things need to be achieved before we can transition from a fossil-fuel-driven economy to one based on renewable energy
Risk Assessment of Explosion Accidents in Hydrogen Fuel-Cell Rooms Using Experimental Investigations and Computational Fluid Dynamics Simulations
Oct 2023
Publication
For the safe utilization and management of hydrogen energy within a fuel-cell room in a hydrogen-fueled house an explosion test was conducted to evaluate the potential hazards associated with hydrogen accident scenarios. The overpressure and heat radiation were measured for an explosion accident at distances of 1 2 3 5 and 10 m for hydrogen–air mixing ratios of 10% 25% 40% and 60%. When the hydrogen–air mixture ratio was 40% the greatest overpressure was 24.35 kPa at a distance of 1 m from the fuel-cell room. Additionally the thermal radiation was more than 1.5 kW/m2 which could cause burns at a distance of 5 m from the hydrogen fuel-cell room. Moreover a thermal radiation in excess of 1.5 kW/m2 was computed at a distance of 3 m from the hydrogen fuel-cell room when the hydrogen–air mixing ratio was 25% and 60%. Consequently an explosion in the hydrogen fuel-cell room did not considerably affect fatality levels but could affect the injury levels and temporary threshold shifts. Furthermore the degree of physical damage did not reach major structural damage levels causing only minor structural damage.
Recent Developments in Materials for Physical Hydrogen Storage: A Review
Jan 2024
Publication
The depletion of reliable energy sources and the environmental and climatic repercussions of polluting energy sources have become global challenges. Hence many countries have adopted various renewable energy sources including hydrogen. Hydrogen is a future energy carrier in the global energy system and has the potential to produce zero carbon emissions. For the non-fossil energy sources hydrogen and electricity are considered the dominant energy carriers for providing end-user services because they can satisfy most of the consumer requirements. Hence the development of both hydrogen production and storage is necessary to meet the standards of a “hydrogen economy”. The physical and chemical absorption of hydrogen in solid storage materials is a promising hydrogen storage method because of the high storage and transportation performance. In this paper physical hydrogen storage materials such as hollow spheres carbon-based materials zeolites and metal– organic frameworks are reviewed. We summarize and discuss the properties hydrogen storage densities at different temperatures and pressures and the fabrication and modification methods of these materials. The challenges associated with these physical hydrogen storage materials are also discussed.
Risk Assessment of a Hydrogen Refueling Station in an Urban Area
May 2023
Publication
After the Paris Agreement was signed in 2015 many countries worldwide focused on the hydrogen economy aiming for eco-friendly and renewable energy by moving away from the existing carbon economy which has been the primary source of global warming. Hydrogen is the most common element on Earth. As a light substance hydrogen can diffuse quickly; however it also has a small risk of explosion. Representative explosion accidents have included the Muskingum River Power Plant Vapor Cloud Explosion accident in 2007 and the Silver Eagle Refinery Vapor Cloud Explosion accident in 2009. In addition there was an explosion in a hydrogen tank in Gangneung Korea in May 2019 and a hydrogen refueling station (HRS) in Norway exploded in 2018. Despite this risk Korea is promoting the establishment of HRSs in major urban centers including downtown areas and public buildings by using the Regulatory Sandbox to install HRSs. This paper employed the Hydrogen Risk Assessment Model (HyRAM) of Sandia National Laboratories (SNL) a quantitative risk assessment (QRA) program specialized in hydrogen energy for HRSs installed in major urban hubs. A feasibility evaluation of the site conditions of an HRS was conducted using the French land use planning method based on the results obtained through evaluation using the HyRAM and the overpressure results of PHAST 8.0. After a risk assessment we confirmed that an HRS would be considered safe even if it was installed in the city center within a radius of influence of jet fires and overpressure.
Prediction of Freezing Time During Hydrogen Fueling Using Machine Learning
Nov 2024
Publication
This study presents a method for predicting nozzle surface temperature and the timing of frost formation during hydrogen refueling using machine learning. A continuous refueling system was implemented based on a simulation model that was developed and validated in previous research. Data were collected under various boundary conditions and eight regression models were trained and evaluated for their predictive performance. Hyperparameter optimization was performed using random search to enhance model performance. The final models were validated by applying boundary conditions not used during model development and comparing the predicted values with simulation results. The comparison revealed that the maximum error rate occurred after the second refueling with a value of approximately 4.79%. Currently nitrogen and heating air are used for defrosting and frost reduction which can be costly. The developed machine learning models are expected to enable prediction of both frost formation and defrosting timings potentially allowing for more cost-effective management of defrosting and frost reduction strategies.
A Simulation Study on Evaluating the Influence of Impurities on Hydrogen Production in Geological Carbon Dioxide Storage
Sep 2023
Publication
In this study we examined the effect of CO2 injection into deep saline aquifers considering impurities present in blue hydrogen production. A fluid model was designed for reservoir conditions with impurity concentrations of 3.5 and 20%. The results showed that methane caused density decreases of 95.16 and 76.16% at 3.5 and 20% respectively whereas H2S caused decreases of 99.56 and 98.77% respectively. Viscosity decreased from 0.045 to 0.037 cp with increasing methane content up to 20%; however H2S did not affect the viscosity. Notably CO2 with H2S impacted these properties less than methane. Our simulation model was based on the Gorae-V properties and simulated injections for 10 years followed by 100 years of monitoring. Compared with the pure CO2 injection methane reached its maximum pressure after eight years and eleven months at 3.5% and eight years at 20% whereas H2S reached maximum pressure after nine years and two months and nine years and six months respectively. These timings affected the amount of CO2 injected. With methane as an impurity injection efficiency decreased up to 73.16% whereas with H2S it decreased up to 81.99% with increasing impurity concentration. The efficiency of CO2 storage in the dissolution and residual traps was analyzed to examine the impact of impurities. The residual trap efficiency consistently decreased with methane but increased with H2S. At 20% concentration the methane trap exhibited higher efficiency at the end of injection; however H2S had a higher efficiency at the monitoring endpoint. In carbon capture and storage projects methane impurities require removal whereas H2S may not necessitate desulfurization due to its minimal impact on CO2 storage efficiency. Thus the application of carbon capture and storage (CCS) to CO2 emissions containing H2S as an impurity may enable economically viable operations by reducing additional costs.
Predictive Maintenance and Reinspection Strategies for Hydrogen Refueling Station Pressure Vessels: A Case Study in South Korea
Jul 2024
Publication
Hydrogen refueling stations rely on pressure vessels capable of withstanding pressures up to 90 MPa while mitigating concerns related to hydrogen embrittlement. However a gap exists in understanding the long-term fatigue behavior of these vessels under real operational conditions. This study focuses on evaluating the safety of SA372 pressure vessels using operational data from a hydrogen refueling station in Pyeongtaek South Korea. A predictive reinspection methodology is proposed based on this evaluation. Parameters including hydrogen-induced stress intensity factor (KIH) initial crack size (a0 c0) and pressure vessel specifications are considered to assess critical crack depth (ac) critical usage cycles (Nc) and allowable usage cycles (Nallowed). Leveraging operational data collected between August and November 2023 fatigue analysis and Rainflow counting inform reinspection schedules. Results indicate a need for mid-bank vessel reinspection within the second year high-bank vessel reinspection every 20 years and low-bank vessel reinspection every 143 years in accordance with safety regulations. Additionally a revised refueling logic is proposed to optimize vehicle charging methods and pressure ranges enhancing operational safety. This study serves as a preliminary investigation highlighting the need for broader data collection and analysis to generalize findings across multiple stations.
The Effect of Ventilation on the Hazards of Hydrogen Release in Enclosed Areas of Hydrogen-fueled Ship
Aug 2023
Publication
This paper presents a systematic investigation that encompasses the safety assessment of a fuel preparation room (FPR) intended for a hydrogen-fueled ship. The primary objective is to determine the appropriate ventilation strategy to mitigate the risks associated with potential hydrogen leakage. The study focuses on a case involving an FPR measuring 10.2 m × 5.3 m × 2.65 m which is part of a 750 DWT hydrogen-powered fishing vessel. To identify the potential events leading to hydrogen dispersion an event tree analysis is conducted. Additionally existing regulations and guidelines related to the safety assessments of hydrogen leakage in enclosed areas are summarized and analyzed. Computational fluid dynamics FLACS-CFD are utilized for the consequence analysis in order to evaluate the impact of ventilation on hydrogen dispersion and concentration within the FPR. The research findings indicate significant effects of ventilation on the hazards and safety assessments of FPRs and high-pressure fuel gas supply systems. The study highlights that hydrogen vapor tends to accumulate at the ceiling and in the corners and spaces created by the equipment. The position and size of ventilation openings greatly influence the dispersion of hydrogen leakage. Proper ventilation design including top inlet ventilation and outlet ventilation on the opposite side helps to maintain a safe FPR by facilitating the efficient dispersion of hydrogen vapor. Moreover locating inlet ventilation on the same side as the outlet ventilation is found to hinder dispersion while the cross-ventilation achieved by placing inlets and outlets on opposite sides enhances airflow and dispersion. Consequently it is recommended to prioritize the structural design of FPRs and implement enhanced safety measures. Additionally updating the relevant regulations to address these concerns is strongly advised.
Economic Prospects of Taxis Powered by Hydrogen Fuel Cells in Palestine
Feb 2024
Publication
Recently major problems related to fuel consumption and greenhouse gas (GHG) emissions have arisen in the transportation sector. Therefore developing transportation modes powered by alternative fuels has become one of the main targets for car manufacturers and governments around the world. This study aimed to investigate the economic prospects of using hydrogen fuel cell technology in taxi fleets in Westbank. For this purpose a model that could predict the number of taxis was developed and the expected economic implications of using hydrogen fuel cell technology in taxi fleets were determined based on the expected future fuel consumption and future fuel cost. After analysis of the results it was concluded that a slight annual increase in the number of taxis in Palestine is expected in the future due to the government restrictions on issuing new taxi permits in order to get this sector organized. Furthermore using hydrogen fuel cells in taxi fleets is expected to become more and more feasible over time due to the expected future increase in oil price and the expected significant reduction in hydrogen cost as a result of the new technologies that are expected to be used in the production and handling of hydrogen.
Which Is Preferred between Electric or Hydrogen Cars for Carbon Neutrality in the Commercial Vehicle Transportation Sector of South Korea? Implications from a Public Opinion Survey
Feb 2024
Publication
South Korea has drawn up plans to reduce greenhouse gases by 29.7 million tons by supplying 4.5 million electric and hydrogen cars by 2030 to implement the “2050 carbon neutrality” goal. This article gathers data on public preferences for electric cars (ECs) over hydrogen cars (HCs) in the commercial vehicle transportation sector through a survey of 1000 people. Moreover the strength of the preference was evaluated on a five-point scale. Of all respondents 60.0 percent preferred ECs and 21.0 percent HCs the former being 2.86 times greater than the latter. On the other hand the strength of the preference for HCs was 1.42 times greater than that for ECs. Factors influencing the preference for ECs over HCs were also explored through adopting the ordered probit model which is useful in examining ordinal preference rather than cardinal preference. The analyzed factors which are related to respondents’ characteristics experiences and perceptions can be usefully employed for developing strategies of promoting carbon neutrality in the commercial vehicle transportation sector and preparing policies to improve public acceptance thereof.
Implementation of Formic Acid as a Liquid Organic Hydrogen Carrier (LOHC): Techno-Economic Analysis and Life Cycle Assessment of Formic Acid Produced via CO2 Utilization
Sep 2022
Publication
To meet the global climate goals agreed upon regarding the Paris Agreement governments and institutions around the world are investigating various technologies to reduce carbon emissions and achieve a net-negative energy system. To this end integrated solutions that incorporate carbon utilization processes as well as promote the transition of the fossil fuel-based energy system to carbon-free systems such as the hydrogen economy are required. One of the possible pathways is to utilize CO2 as the base chemical for producing a liquid organic hydrogen carrier (LOHC) using CO2 as a mediating chemical for delivering H2 to the site of usage since gaseous and liquid H2 retain transportation and storage problems. Formic acid is a probable candidate considering its high volumetric H2 capacity and low toxicity. While previous studies have shown that formic acid is less competitive as an LOHC candidate compared to other chemicals such as methanol or toluene the results were based on out-of-date process schemes. Recently advances have been made in the formic acid production and dehydrogenation processes and an analysis regarding the recent process configurations could deem formic acid as a feasible option for LOHC. In this study the potential for using formic acid as an LOHC is evaluated with respect to the state-of-the-art formic acid production schemes including the use of heterogeneous catalysts during thermocatalytic and electrochemical formic acid production from CO2 . Assuming a hydrogen distribution system using formic acid as the LOHC each of the production transportation dehydrogenation and CO2 recycle sections are separately modeled and evaluated by means of techno-economic analysis (TEA) and life cycle assessment (LCA). Realistic scenarios for hydrogen distribution are established considering the different transportation and CO2 recovery options; then the separate scenarios are compared to the results of a liquefied hydrogen distribution scenario. TEA results showed that while the LOHC system incorporating the thermocatalytic CO2 hydrogenation to formic acid is more expensive than liquefied H2 distribution the electrochemical CO2 reduction to formic acid system reduces the H2 distribution cost by 12%. Breakdown of the cost compositions revealed that reduction of steam usage for thermocatalytic processes in the future can make the LOHC system based on thermocatalytic CO2 hydrogenation to formic acid to be competitive with liquefied H2 distribution if the production cost could be reduced by 23% and 32% according to the dehydrogenation mode selected. Using formic acid as a LOHC was shown to be less competitive compared to liquefied H2 delivery in terms of LCA but producing formic acid via electrochemical CO2 reduction was shown to retain the lowest global warming potential among the considered options.
The Hydrogen Economy can Reduce Costs of Climate Change Mitigation by up to 22%
May 2024
Publication
In response to the urgent need to mitigate climate change via net-zero targets many nations are renewing their interest in clean hydrogen as a net-zero energy carrier. Although clean hydrogen can be directly used in various sectors for deep decarbonization the relatively low energy density and high production costs have raised doubts as to whether clean hydrogen development is worthwhile. Here we improve on the GCAM model by including a more comprehensive and detailed representation of clean hydrogen production distribution and demand in all sectors of the global economy and simulate 25 scenarios to explore the costeffectiveness of integrating clean hydrogen into the global energy system. We show that due to costly technical obstacles clean hydrogen can only provide 3%–9% of the 2050 global final energy use. Nevertheless clean hydrogen deployment can reduce overall energy decarbonization costs by 15%–22% mainly via powering ‘‘hard-to-electrify’’ sectors that would otherwise face high decarbonization expenditures. Our work provides practical references for cost-effective clean hydrogen planning.
Premier, Progress and Prospects in Renewable Hydrogen Generation: A Review
May 2023
Publication
Renewable hydrogen production has an opportunity to reduce carbon emissions in the transportation and industrial sectors. This method generates hydrogen utilizing renewable energy sources such as the sun wind and hydropower lowering the number of greenhouse gases released into the environment. In recent years considerable progress has been made in the production of sustainable hydrogen particularly in the disciplines of electrolysis biomass gasification and photoelectrochemical water splitting. This review article figures out the capacity efficiency and cost-effectiveness of hydrogen production from renewable sources effectively comparing the conventionally used technologies with the latest techniques which are getting better day by day with the implementation of the technological advancements. Governments investors and industry players are increasingly interested in manufacturing renewable hydrogen and the global need for clean energy is expanding. It is projected that facilities for manufacturing renewable hydrogen as well as infrastructure to support this development would expand hastening the transition to an environment-friendly and low-carbon economy
Systems-Based Safety Analysis for Hydrogen-Driven Autonomous Ships
Jun 2024
Publication
In the maritime domain hydrogen fuel cell propulsion and autonomous vessels are two important issues that are yet to be implemented together because of a few challenges. It is obvious that there are several individual safety studies on Maritime Autonomous Surface Ships and hydrogen storage as well as fuel cells based on various risk assessment tools but the combined safety studies that include hydrogen fuel cells on autonomous vessels with recent risk analysis methods are extremely limited. This research chooses the “System-Theoretic Process Analysis” (STPA) method which is a recent method for potential risk identification and mitigation. Both hydrogen and autonomous vessels are analyzed and assessed together with the STPA method. Results are not speculative but rather flexible compared to conventional systems. The study finds a total of 44 unsafe control actions (UCAs) evolved from human and central control unit controllers through STPA. Further the loss scenarios (LS) are identified that lead to those UCAs so that loss scenarios can be assessed and UCAs can be mitigated for safe operation. The objective of this study is to ensure adequate safety for hydrogen fuel cell propulsion on autonomous vessels.
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