Korea, Republic of
Sector Coupling and Migration towards Carbon-Neutral Power Systems
Feb 2023
Publication
There is increasing interest in migrating to a carbon-neutral power system that relies on renewable energy due to concerns about greenhouse gas emissions energy shortages and global warming. However the increasing share of renewable energy has added volatility and uncertainty to power system operations. Introducing new devices and using flexible resources may help solve the problem but expanding the domain of the problem can be another solution. Sector coupling which integrates production consumption conversion and storage by connecting various energy domains could potentially meet the needs of each energy sector. It can also reduce the generation of surplus energy and unnecessary carbon emissions. As a result sector coupling an integrated energy system increases the acceptance of renewable energy in the traditional power system and makes it carbon neutral. However difficulties in large-scale integration low conversion efficiency and economic feasibility remain obstacles. This perspective paper discusses the background definition and components of sector coupling as well as its functions and examples in rendering power systems carbon-neutral. The current limitations and outlook of sector coupling are also examined.
An Analysis on the Compressed Hydrogen Storage System for the Fast-Filling Process of Hydrogen Gas at the Pressure of 82 MPa
May 2021
Publication
During the fast-filling of a high-pressure hydrogen tank the temperature of hydrogen would rise significantly and may lead to failure of the tank. In addition the temperature rise also reduces hydrogen density in the tank which causes mass decrement into the tank. Therefore it is of practical significance to study the temperature rise and the amount of charging of hydrogen for hydrogen safety. In this paper the change of hydrogen temperature in the tank according to the pressure rise during the process of charging the high-pressure tank in the process of a 82-MPa hydrogen filling system the final temperature the amount of filling of hydrogen gas and the change of pressure of hydrogen through the pressure reducing valve and the performance of heat exchanger for cooling high-temperature hydrogen were analyzed by theoretical and numerical methods. When high-pressure filling began in the initial vacuum state the condition was called the “First cycle”. When the high-pressure charging process began in the remaining condition the process was called the “Second cycle”. As a result of the theoretical analysis the final temperatures of hydrogen gas were calculated to be 436.09 K for the first cycle of the high-pressure tank and 403.55 for the second cycle analysis. The internal temperature of the buffer tank increased by 345.69 K and 32.54 K in the first cycle and second cycles after high-pressure filling. In addition the final masses were calculated to be 11.58 kg and 12.26 kg for the first cycle and second cycle of the high-pressure tank respectively. The works of the paper can provide suggestions for the temperature rise of 82 MPa compressed hydrogen storage system and offer necessary theory and numerical methods for guiding safe operation and construction of a hydrogen filling system.
Greenhouse Gas Emissions of Conventional and Alternative Vehicles: Predictions Based on Energy Policy Analysis in South Korea
Mar 2020
Publication
This paper compares the well-to-wheel (WTW) greenhouse gas (GHG) emissions of representative vehicle types–internal combustion engine vehicle (ICEV) hybrid electric vehicle (HEV) plug-in hybrid electric vehicle (PHEV) battery electric vehicle (BEV) and fuel cell electric vehicle (FCEV)–in the future (2030) based on a WTW analysis for the present (2017) and an analysis of various energy policies that could affect future emissions. South Korea was selected as the target region because it has detailed energy policies related to alternative vehicles. The WTW analysis for the present was performed based on three sets of subordinate analyses: (1) life cycle analyses of eight base fuels; (2) life cycle analyses of electricity and hydrogen; and (3) analyses of the fuel economies of seven vehicle types. From the WTW analysis for the present the national average WTW GHG emissions of ICEV-gasoline ICEV-diesel ICEV-liquefied petroleum gas HEV PHEV BEV and FCEV were calculated as 225 233 201 159 133 109 and 55 g-CO2-eq./km respectively. For calculating the WTW GHG emissions in the future two policies regarding electricity production and three policies regarding hydrogen production were analysed. Three cases with varying the degrees of improvements in fuel economies were considered. Six future scenarios were constructed and each scenario represented the case in which each energy policy is enacted. In the reference scenario for compact car the WTW GHG emissions of ICEVs-gasoline HEV PHEV BEV-200 mile FCEV were analysed as 161 110 97 86 and 91 g-CO2-eq./km respectively. The differences between ICEV/HEV and BEV were predicted to decrease in the future mainly due to larger improvements of ICEV/HEV in fuel economies compared to that of BEV. The future life cycle GHG emissions of electricity and hydrogen were calculated according to energy policy. Both two policies regarding power generation were confirmed to increase the benefits of utilizing BEVs but current energy policy regarding hydrogen production were confirmed to decrease the benefits of utilizing FCEVs. Based on the comprehensive results of this study a framework was proposed to evaluate the impacts of an energy policy regarding electricity and hydrogen production on the benefits of using BEVs and FCEVs compared to using HEVs and ICEVs. This framework can also be utilized in other countries when they assess and establish their energy policies.
Safety Issues of a Hydrogen Refueling Station and a Prediction for an Overpressure Reduction by a Barrier Using OpenFOAM Software for an SRI Explosion Test in an Open Space
Oct 2022
Publication
Safety issues arising from a hydrogen explosion accident in Korea are discussed herein. In order to increase the safety of hydrogen refueling stations (HRSs) the Korea Gas Safety Corporation (KGS) decided to install a damage-mitigation wall also referred to as a barrier around the storage tanks at the HRSs after evaluating the consequences of hypothetical hydrogen explosion accidents based on the characteristics of each HRS. To propose a new regulation related to the barrier installation at the HRSs which can ensure a proper separation distance between the HRS and its surrounding protected facilities in a complex city KGS planned to test various barrier models under hypothetical hydrogen explosion accidents to develop a standard model of the barrier. A numerical simulation to investigate the effect of the recommended barrier during hypothetical hydrogen explosion accidents in the HRS will be performed before installing the barrier at the HRSs. A computational fluid dynamic (CFD) code based on the open-source software OpenFOAM will be developed for the numerical simulation of various accident scenarios. As the first step in the development of the CFD code we conducted a hydrogen vapor cloud explosion test with a barrier in an open space which was conducted by the Stanford Research Institute (SRI) using the modified XiFoam solver in OpenFOAMv1912. A vapor cloud explosion (VCE) accident may occur due to the leakage of gaseous hydrogen or liquefied hydrogen owing to a failure of piping connected to the storage tank in an HRS. The analysis results using the modified XiFoam predicted the peak overpressure variation from the near field to the far field of the explosion site through the barrier with an error range of approximately ±30% if a proper analysis methodology including the proper mesh distribution in the grid model is chosen. In addition we applied the proposed analysis methodology using the modified XiFoam to barrier shapes that varied from that used in the test to investigate its applicability to predict peak overpressure variations with various barrier shapes. Through the application analysis we concluded that the proposed analysis methodology is sufficient for evaluating the safety effect of the barrier which will be recommended through experimental research during VCE accidents at the HRSs.
CFD Modeling on Natural and Forced Ventilation During Hydrogen Leaks in a Pressure Regulator Process of a Residential Area
Mar 2022
Publication
Hydrogen fuel cells have been installed in more than 100 facilities and numerous homes in Ulsan hydrogen town in the Republic of Korea. Despite the advantages of hydrogen accidents can still occur near residential areas. Thus appropriate risk mitigation plans should be established. In this study a computational fluid dynamics (CFD) model of natural and forced ventilation is presented as an emergency response to hydrogen leakages in pressure regulator equipment housing. The CFD model is developed and investigated using three vent configurations: UP CROSS and UP-DOWN. The simulation results indicate that the UPDOWN configuration achieves the lowest internal hydrogen concentration out of the three. In addition the relationship between the total vent size and internal hydrogen concentration is determined. A vent size of 12% of the floor area has the lowest hydrogen concentration. The use of nitrogen for forced ventilation during emergencies is proposed to ensure that the hydrogen concentration of the released gas is less than one-fourth of the lower flammability 2 / 25 limit of hydrogen. Compared to natural ventilation the time required to reach safe conditions is decreased when nitrogen forced ventilation is used.
Photocatalytic Hydrogen Evolution from Biomass Conversion
Feb 2021
Publication
Biomass has incredible potential as an alternative to fossil fuels for energy production that is sustainable for the future of humanity. Hydrogen evolution from photocatalytic biomass conversion not only produces valuable carbon-free energy in the form of molecular hydrogen but also provides an avenue of production for industrially relevant biomass products. This photocatalytic conversion can be realized with efficient sustainable reaction materials (biomass) and inexhaustible sunlight as the only energy inputs. Reported herein is a general strategy and mechanism for photocatalytic hydrogen evolution from biomass and biomass-derived substrates (including ethanol glycerol formic acid glucose and polysaccharides). Recent advancements in the synthesis and fundamental physical/mechanistic studies of novel photocatalysts for hydrogen evolution from biomass conversion are summarized. Also summarized are recent advancements in hydrogen evolution efciency regarding biomass and biomass-derived substrates. Special emphasis is given to methods that utilize unprocessed biomass as a substrate or synthetic photocatalyst material as the development of such will incur greater benefts towards a sustainable route for the evolution of hydrogen and production of chemical feedstocks.
Modelling and Simulation of a Hydrogen-Based Hybrid Energy Storage System with a Switching Algorithm
Oct 2022
Publication
Currently transitioning from fossil fuels to renewable sources of energy is needed considering the impact of climate change on the globe. From this point of view there is a need for development in several stages such as storage transmission and conversion of power. In this paper we demonstrate a simulation of a hybrid energy storage system consisting of a battery and fuel cell in parallel operation. The novelty in the proposed system is the inclusion of an electrolyser along with a switching algorithm. The electrolyser consumes electricity to intrinsically produce hydrogen and store it in a tank. This implies that the system consumes electricity as input energy as opposed to hydrogen being the input fuel. The hydrogen produced by the electrolyser and stored in the tank is later utilised by the fuel cell to produce electricity to power the load when needed. Energy is therefore stored in the form of hydrogen. A battery of lower capacity is coupled with the fuel cell to handle transient loads. A parallel control algorithm is developed to switch on/off the charging and discharging cycle of the fuel cell and battery depending upon the connected load. Electrically equivalent circuits of a polymer electrolyte membrane electrolyser polymer electrolyte membrane fuel cell necessary hydrogen oxygen water tanks and switching controller for the parallel operation were modelled with their respective mathematical equations in MATLAB® Simulink®. In this paper we mainly focus on the modelling and simulation of the proposed system. The results showcase the simulated system’s mentioned advantages and compare its ability to handle loads to a battery-only system.
Dynamic Mechanical Fatigue Behavior of Polymer Electrolyte Membranes for Fuel Cell Electric Vehicles Using a Gas Pressure-Loaded Blister
Nov 2021
Publication
This study reports on an innovative press-loaded blister hybrid system equipped with gas-chromatography (PBS-GC) that is designed to evaluate the mechanical fatigue of two representative types of commercial Nafion membranes under relevant PEMFC operating conditions (e.g. simultaneously controlling temperature and humidity). The influences of various applied pressures (50 kPa 100 kPa etc.) and blistering gas types (hydrogen oxygen etc.) on the mechanical resistance loss are systematically investigated. The results evidently indicate that hydrogen gas is a more effective blistering gas for inducing dynamic mechanical losses of PEM. The changes in proton conductivity are also measured before and after hydrogen gas pressure-loaded blistering. After performing the mechanical aging test a decrease in proton conductivity was confirmed which was also interpreted using small angle X-ray scattering (SAXS) analysis. Finally an accelerated dynamic mechanical aging test is performed using the homemade PBS-GC system where the hydrogen permeability rate increases significantly when the membrane is pressure-loaded blistering for 10 min suggesting notable mechanical fatigue of the PEM. In summary this PBS-GC system developed in-house clearly demonstrates its capability of screening and characterizing various membrane candidates in a relatively short period of time (<1.5 h at 50 kPa versus 200 h).
Impact of Polymers on Magnesium-Based Hydrogen Storage Systems
Jun 2022
Publication
In the present scenario much importance has been provided to hydrogen energy systems (HES) in the energy sector because of their clean and green behavior during utilization. The developments of novel techniques and materials have focused on overcoming the practical difficulties in the HES (production storage and utilization). Comparatively considerable attention needs to be provided in the hydrogen storage systems (HSS) because of physical-based storage (compressed gas cold/cryo compressed and liquid) issues such as low gravimetric/volumetric density storage conditions/parameters and safety. In material-based HSS a high amount of hydrogen can be effectively stored in materials via physical or chemical bonds. In different hydride materials Mg-based hydrides (Mg–H) showed considerable benefits such as low density hydrogen uptake and reversibility. However the inferior sorption kinetics and severe oxidation/contamination at exposure to air limit its benefits. There are numerous kinds of efforts like the inclusion of catalysts that have been made for Mg–H to alter the thermodynamic-related issues. Still those efforts do not overcome the oxidation/contamination-related issues. The developments of Mg–H encapsulated by gas-selective polymers can effectively and positively influence hydrogen sorption kinetics and prevent the Mg–H from contaminating (air and moisture). In this review the impact of different polymers (carboxymethyl cellulose polystyrene polyimide polypyrrole polyvinylpyrrolidone polyvinylidene fluoride polymethylpentene and poly(methyl methacrylate)) with Mg–H systems has been systematically reviewed. In polymer-encapsulated Mg–H the polymers act as a barrier for the reaction between Mg–H and O2/H2O selectively allowing the H2 gas and preventing the aggregation of hydride nanoparticles. Thus the H2 uptake amount and sorption kinetics improved considerably in Mg–H.
Comparative Risk Assessment of a Hydrogen Refueling Station Using Gaseous Hydrogen and Formic Acid as the Hydrogen Carrier
Mar 2023
Publication
To realize a hydrogen economy many studies are being conducted regarding the development and analysis of hydrogen carriers. Recently formic acid has been receiving attention as a potential hydrogen carrier due to its high volumetric energy density and relatively safe characteristics. However hydrogen refueling systems using formic acid are very different from conventional hydrogen refueling stations and quantitative risks assessments need to be conducted to verify their safe usage. In this study a comparative safety analysis of a formic acid hydrogen refueling station (FAHRS) and a gaseous hydrogen refueling station (GHRS) was conducted. Since there is no FAHRS under operation a process simulation model was developed and integrated with quantitative risk assessment techniques to perform safety analysis. Results of the analysis show that the FAHRS poses less risk than the GHRS where the vapor cloud explosion occurring in the buffer tank is of greatest consequence. A GHRS poses a greater risk than an FAHRS due to the high pressure required to store hydrogen in the tube trailer. The mild operating conditions required for storage and dehydrogenation of formic acid contribute to the low risk values of an FAHRS. For risk scenarios exceeding the risk limit risk mitigation measures were applied to design a safe process for GHRS. The results show that the installation of active safety systems for the GHRS allow the system to operate within acceptable safety regions.
Techno-Economic Analysis of Hydrogen–Natural Gas Blended Fuels for 400 MW Combined Cycle Power Plants (CCPPs)
Sep 2023
Publication
Various research and development activities are being conducted to use hydrogen an environmentally friendly fuel to achieve carbon neutrality. Using natural gas–hydrogen blends has advantages such as the usage of traditional combined cycle power plant (CCPP) technology and existing natural gas piping infrastructure. Therefore we conducted CCPP process modeling and economic analysis based on natural gas–hydrogen blends. For process analysis we developed a process model for a 400 MW natural gas CCPP using ASPEN HYSYS and confirmed an error within the 1% range through operation data validation. For economic analysis we comparatively reviewed the levelized cost of electricity (LCOE) of CCPPs using hydrogen blended up to 0.5 mole fraction. For LCOE sensitivity analysis we used fuel cost capital expenditures capacity factor and power generation as variables. LCOE is 109.15 KRW/kWh when the hydrogen fuel price is 2000 KRW/kg and the hydrogen mole fraction is increased to 0.5 a 5% increase from the 103.9 KRW/kWh of CCPPs that use only natural gas. Economic feasibility at the level of 100% natural gas CCPPs is possible by reducing capital expenditures (CAPEX) by at least 20% but net output should be increased by at least 5% (20.47 MW) when considering only performance improvement.
Re-enacting the Hydrogen Tank Explosion of a Fuel-cell Electric Vehicle: An Experimental Study
May 2023
Publication
With the world-wide decision to reduce carbon emissions through the Paris Agreement (2015) the demand for hydrogen-fuelled vehicles has been increasing. Although hydrogen is not a toxic gas it has a wide flammable range (4e75%) and can explode due to static electricity. Therefore studies on hydrogen safety are urgently required. In this study an explosion was induced by applying fire to the lower part of a fuel cell electric vehicle (FCEV). Out of three compressed hydrogen storage tanks installed in the vehicle two did not have hydrogen fuel and one was filled with compressed gaseous hydrogen of 700 bar and forcedly deactivated its temperature-activated pressure relief device. The side-on overpressure transducers were installed by distance in main directions to measure the side-on overpressure generated by the vehicle explosion. A 10 m-long protective barrier was installed on which reflected overpressure displacement and acceleration were measured to examine the effect of attenuation of explosion damage in the event of an accident. The vehicle exploded approximately 11 min after ignition generating a blast wave fireballs and fragments. The results of the experiment showed that the protective barrier could almost completely block explosive pressure smoke and scattering generated during an explosion. Through Probit function analysis the probabilities of an accident occurring were derived based on peak overpressure peak impulse and scattering. The results of this study can be used to develop standard operating procedures (SOPs) for firefighters as the base data for setting the initial operation location and deriving the safe separation distance.
Proactive Emergency Response Strategies for First Responders to Hydrogen Gas Leakages in Vehicles
Feb 2024
Publication
The widespread use of fossil fuels in automobiles has become a concern particularly in light of recent frequent natural disasters prompting a shift towards eco-friendly vehicles to mitigate greenhouse gas emissions. This shift is evident in the rapidly increasing registration rates of hydrogen vehicles. However with the growing presence of hydrogen vehicles on roads a corresponding rise in related accidents is anticipated posing new challenges for first responders. In this study computational fluid dynamics analysis was performed to develop effective response strategies for first responders dealing with high-pressure hydrogen gas leaks in vehicle accidents. The analysis revealed that in the absence of blower intervention a vapor cloud explosion from leaked hydrogen gas could generate overpressure exceeding 13.8 kPa potentially causing direct harm to first responders. In the event of a hydrogen vehicle accident requiring urgent rescue activities the appropriate response strategy must be selected. The use of blowers can aid in developing a variety of strategies by reducing the risk of a vapor cloud explosion. Consequently this study offers a tailored response strategy for first responders in hydrogen vehicle leak scenarios emphasizing the importance of situational assessment at the incident site.
Impacts of Green Energy Expansion and Gas Import Reduction on South Korea’s Economic Growth: A System Dynamics Approach
Jun 2023
Publication
South Korea ranking ninth among the largest energy consumers and seventh in carbon dioxide emissions from 2016 to 2021 faces challenges in energy security and climate change mitigation. The primary challenge lies in transitioning from fossil fuel dependency to a more sustainable and diversified energy portfolio while meeting the growing energy demand for continued economic growth. This necessitates fostering innovation and investment in the green energy sector. This study examines the potential impact of green energy expansion (through integrating renewable energy and hydrogen production) and gas import reduction on South Korea’s economic growth using a system dynamics approach. The findings indicate that increasing investment in green energy can result in significant growth rates ranging from 7% to 35% between 2025 and 2040. Under the expansion renewable energy scenario (A) suggests steady but sustainable economic growth in the long term while the gas import reduction scenario (B) displays a potential for rapid economic growth in the short term with possible instability in the long term. The total production in Scenario B is USD 2.7 trillion in 2025 and will increase to USD 4.8 trillion by 2040. Scenario C which combines the effects of both Scenarios A and B results in consistently high economic growth rates over time and a substantial increase in total production by 2035–2040 from 20% to 46%. These findings are critical for policymakers in South Korea as they strive for sustainable economic growth and transition to renewable energy.
A Simulation Study on Evaluating the Influence of Impurities on Hydrogen Production in Geological Carbon Dioxide Storage
Sep 2023
Publication
In this study we examined the effect of CO2 injection into deep saline aquifers considering impurities present in blue hydrogen production. A fluid model was designed for reservoir conditions with impurity concentrations of 3.5 and 20%. The results showed that methane caused density decreases of 95.16 and 76.16% at 3.5 and 20% respectively whereas H2S caused decreases of 99.56 and 98.77% respectively. Viscosity decreased from 0.045 to 0.037 cp with increasing methane content up to 20%; however H2S did not affect the viscosity. Notably CO2 with H2S impacted these properties less than methane. Our simulation model was based on the Gorae-V properties and simulated injections for 10 years followed by 100 years of monitoring. Compared with the pure CO2 injection methane reached its maximum pressure after eight years and eleven months at 3.5% and eight years at 20% whereas H2S reached maximum pressure after nine years and two months and nine years and six months respectively. These timings affected the amount of CO2 injected. With methane as an impurity injection efficiency decreased up to 73.16% whereas with H2S it decreased up to 81.99% with increasing impurity concentration. The efficiency of CO2 storage in the dissolution and residual traps was analyzed to examine the impact of impurities. The residual trap efficiency consistently decreased with methane but increased with H2S. At 20% concentration the methane trap exhibited higher efficiency at the end of injection; however H2S had a higher efficiency at the monitoring endpoint. In carbon capture and storage projects methane impurities require removal whereas H2S may not necessitate desulfurization due to its minimal impact on CO2 storage efficiency. Thus the application of carbon capture and storage (CCS) to CO2 emissions containing H2S as an impurity may enable economically viable operations by reducing additional costs.
Recent Progress in Conducting Polymers for Hydrogen Storage and Fuel Cell Applications
Oct 2020
Publication
Hydrogen is a clean fuel and an abundant renewable energy resource. In recent years huge scientific attention has been invested to invent suitable materials for its safe storage. Conducting polymers has been extensively investigated as a potential hydrogen storage and fuel cell membrane due to the low cost ease of synthesis and processability to achieve the desired morphological and microstructural architecture ease of doping and composite formation chemical stability and functional properties. The review presents the recent progress in the direction of material selection modification to achieve appropriate morphology and adsorbent properties chemical and thermal stabilities. Polyaniline is the most explored material for hydrogen storage. Polypyrrole and polythiophene has also been explored to some extent. Activated carbons derived from conducting polymers have shown the highest specific surface area and significant storage. This review also covers recent advances in the field of proton conducting solid polymer electrolyte membranes in fuel cells application. This review focuses on the basic structure synthesis and working mechanisms of the polymer materials and critically discusses their relative merits.
CFD Thermo‑Hydraulic Evaluation of a Liquid Hydrogen Storage Tank with Different Insulation Thickness in a Small‑Scale Hydrogen Liquefier
Aug 2023
Publication
Accurate evaluation of thermo‑fluid dynamic characteristics in tanks is critically important for designing liquid hydrogen tanks for small‑scale hydrogen liquefiers to minimize heat leakage into the liquid and ullage. Due to the high costs most future liquid hydrogen storage tank designs will have to rely on predictive computational models for minimizing pressurization and heat leakage. Therefore in this study to improve the storage efficiency of a small‑scale hydrogen liquefier a three‑ dimensional CFD model that can predict the boil‑off rate and the thermo‑fluid characteristics due to heat penetration has been developed. The prediction performance and accuracy of the CFD model was validated based on comparisons between its results and previous experimental data and a good agreement was obtained. To evaluate the insulation performance of polyurethane foam with three different insulation thicknesses the pressure changes and thermo‑fluid characteristics in a partially liquid hydrogen tank subject to fixed ambient temperature and wind velocity were investigated nu‑ merically. It was confirmed that the numerical simulation results well describe not only the temporal variations in the thermal gradient due to coupling between the buoyance and convection but also the buoyancy‑driven turbulent flow characteristics inside liquid hydrogen storage tanks with differ‑ ent insulation thicknesses. In the future the numerical model developed in this study will be used for optimizing the insulation systems of storage tanks for small‑scale hydrogen liquefiers which is a cost‑effective and highly efficient approach.
Options for Methane Fuel Processing in PEMFC System with Potential Maritime Applications
Nov 2022
Publication
Proton-exchange membrane fuel cells (PEMFCs) are low-temperature fuel cells that have excellent starting performance due to their low operating temperature can respond quickly to frequent load fluctuations and can be manufactured in small packages. Unlike existing studies that mainly used hydrogen as fuel for PEMFCs in this study methane is used as fuel for PEMFCs to investigate its performance and economy. Methane is a major component of natural gas which is more economically competitive than hydrogen. In this study methane gas is reformed by the steam reforming method and is applied to the following five gas post-treatment systems: (a) Case 1—water– gas shift only (WGS) (b) Case 2—partial oxidation reforming only (PROX) (c) Case 3—methanation only (d) Case 4—WGS + methanation (e) Case 5—WGS + PROX. In the evaluation the carbon monoxide concentration in the gas did not exceed 10 ppm and the methane component which has a very large greenhouse effect was not regenerated in the post-treated exhaust gas. As a result Case 5 (WGS and PROX) is the only case that satisfied both criteria. Therefore we propose Case 5 as an optimized post-treatment system for methane reforming gas in ship PEMFCs.
Thermal Design of a Biohydrogen Production System Driven by Integrated Gasification Combined Cycle Waste Heat Using Dynamic Simulation
Apr 2022
Publication
Utilizing biological processes for hydrogen production via gasification is a promising alternative method to coal gasification. The present study proposes a dynamic simulation model that uses a one-dimensional heat-transfer analysis method to simulate a biohydrogen production system. The proposed model is based on an existing experimental design setup. It is used to simulate a biohydrogen production system driven by the waste heat from an integrated gasification combined cycle (IGCC) power plant equipped with carbon capture and storage technologies. The data from the simulated results are compared with the experimental measurement data to validate the developed model’s reliability. The results show good agreement between the experimental data and the developed model. The relative root-mean-square error for the heat storage feed-mixing and bioreactor tanks is 1.26% 3.59% and 1.78% respectively. After the developed model’s reliability is confirmed it is used to simulate and optimize the biohydrogen production system inside the IGCC power plant. The bioreactor tank’s time constant can be improved when reducing the operating volume of the feed-mixing tank by the scale factors of 0.75 and 0.50 leading to a 15.76% and 31.54% faster time constant respectively when compared with the existing design.
Premier, Progress and Prospects in Renewable Hydrogen Generation: A Review
May 2023
Publication
Renewable hydrogen production has an opportunity to reduce carbon emissions in the transportation and industrial sectors. This method generates hydrogen utilizing renewable energy sources such as the sun wind and hydropower lowering the number of greenhouse gases released into the environment. In recent years considerable progress has been made in the production of sustainable hydrogen particularly in the disciplines of electrolysis biomass gasification and photoelectrochemical water splitting. This review article figures out the capacity efficiency and cost-effectiveness of hydrogen production from renewable sources effectively comparing the conventionally used technologies with the latest techniques which are getting better day by day with the implementation of the technological advancements. Governments investors and industry players are increasingly interested in manufacturing renewable hydrogen and the global need for clean energy is expanding. It is projected that facilities for manufacturing renewable hydrogen as well as infrastructure to support this development would expand hastening the transition to an environment-friendly and low-carbon economy
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