Netherlands
Effect of Precooled Inlet Gas Temperature and Mass flow Rate on Final State of Charge During Hydrogen Vehicle Refueling
Mar 2015
Publication
Short refuelling time and high final state of charge are among the main hydrogen car user's requirements. To meet these requirements without exceeding the tank materials safety limits hydrogen precooling is needed. Filling experiments with different inlet gas temperatures and mass flow rates have been executed using two different types of on-board tanks (type 3 and 4). State of charge has a strong dependency on the inlet gas temperature. This dependency is more visible for type 4 tanks. Lowest precooling temperature (−40 °C) is not always required in order to meet user's requirements so energy savings can be achieved if the initial conditions of the tank are correctly identified. The results of the experiments performed have been compared with the SAE J2601 look-up tables for non-communication fillings. A big safety margin has been observed in these tables. Refuelling could be performed faster and with less demanding precooling requirements if the initial conditions and the configuration of the hydrogen storage system are well known.
CFD Benchmark Based on Experiments of Helium Dispersion in a 1m3 Enclosure–intercomparisons for Plumes
Sep 2013
Publication
In the context of the French DIMITRHY project ANR-08-PANH006 experiments have been carried out to measure helium injections in a cubic 1 m3 box - GAMELAN in a reproducible and quantitative manner. For the present work we limit ourselves to the unique configuration of a closed box with a small hole at its base to prevent overpressure. This case leads to enough difficulties of modelisations to deserve our attention. The box is initially filled with air and injections of helium through a tube of diameter 20 mm is operated. The box is instrumented with catharometres to measure the helium volume concentration within an accuracy better than 0.1%. We present the CFD (Fluent and CASTEM ANSYS-CFX and ADREA-HF) calculations results obtained by 5 different teams participating to the benchmark in the following situation: the case of a plume release of helium in a closed box (4NL/min). Parts of the CFD simulations were performed in the European co-funded project HyIndoor others were performed in the French ANR-08-PANH006 DimitrHy project.
Assessment of a CFD Model for Simulations of Fast Filling of Hydrogen Tanks with Pre-cooling
Sep 2013
Publication
High gas temperatures can be reached inside a hydrogen tank during the filling process because of the large pressure increase (up to 70-80 MPa) and because of the short time (~3 minutes) of the process. High temperatures can potentially jeopardize the structural integrity of the storage system and one of the strategies to reduce the temperature increase is to pre-cool the hydrogen before injecting it into the tank. Computational Fluid Dynamics (CFD) tools have the capabilities of capturing the flow field and the temperature rise in the tank. The results of CFD simulations of fast filling with pre-cooling are shown and compared with experimental data to assess the accuracy of the CFD model
Risk Assessment of Hydrogen Explosion for Private Car with Hydrogen-driven Engine
Sep 2009
Publication
The aim of the study is to identify and quantify the additional risks related to hydrogen explosions during the operation of a hydrogen-driven car. In a first attempt the accidents or failures of a simple one-tank hydrogen storage system have been studied as a main source of risk. Three types of initiators are taken into account: crash accidents fire accidents without crash (no other cars are involved) and hydrogen leakages in normal situation with following ignition. The consequences of hydrogen ignition and/or explosion depend strongly on environmental conditions (geometry wind etc.) therefore the different configurations of operational and environmental conditions are specified.<br/>Then Event Tree/Fault Tree methods are applied for the risk assessment.<br/>The results of quantification permit to draw conclusions about the overall added risk of hydrogen technology as well as about the main contributors to the risk. Results of this work will eventually contribute to the on-going pre-normative research in the field of hydrogen safety.
Comparison of Modelling Approaches for CFD Simulations of High Pressure Hydrogen Releases
Sep 2011
Publication
Several approaches have been used in the past to model the source of a high pressure under-expanded jet such as the computationally expensive resolution of the jet shock structure and the simpler pseudo-source or notional nozzle approaches. In each approach assumptions are made introducing inaccuracies in the CFD calculations. This work assesses the effect of different source modelling approaches on the accuracy of CFD calculations by comparing simulation results to experimental data of the axial distribution of the flow velocity and H2 concentration.
CFD Investigation of Filling and Emptying of Hydrogen Tanks
Oct 2015
Publication
During the filling of hydrogen tanks high temperatures can be generated inside the vessel because of the gas compression while during the emptying low temperatures can be reached because of the gas expansion. The design temperature range goes from −40 °C to 85 °C. Temperatures outside that range could affect the mechanical properties of the tank materials. CFD analyses of the filling and emptying processes have been performed in the HyTransfer project. To assess the accuracy of the CFD model the simulation results have been compared with new experimental data for different filling and emptying strategies. The comparison between experiments and simulations is shown for the temperatures of the gas inside the tank for the temperatures at the interface between the liner and the composite material and for the temperatures on the external surface of the vessel.
Hydrogen Tank Filling Experiments at the JRC-IE Gastef Facility
Sep 2011
Publication
Storage of gases under pressure including hydrogen is a well-known technique. However the use in vehicles of hydrogen at pressures much higher than those applicable in natural gas cars still requires safety and performance studies with respect to the verification of the existing standards and regulations. The JRC-IE has developed a facility GasTeF for carrying out tests on full-scale high pressure vehicle’s tanks for hydrogen or natural gas. Typical tests performed in GasTeF are static permeation measurements of the storage system and hydrogen cycling in which tanks are fast filled and slowly emptied using hydrogen pressurised up to 70 MPa for at least 1000 times according to the requirements of the EU regulation on type-approval of hydrogen-powered motor vehicles. Moreover the temperature evolution of the gas inside and outside the tank is monitored using an ad-hoc designed thermocouples array system. This paper reports the first experimental results on the temperature distribution during hydrogen cycling tests.
Ia-HySafe Standard Benchmark Exercise Sbep-V21- Hydrogen Release and Accumulation within a Non-Ventilated Ambient Pressure Garage at Low Release Rates
Sep 2011
Publication
The successful Computational Fluid Dynamics (CFD) benchmarking activity originally started within the EC-funded Network of Excellence HySafe (2004-2009) continues within the research topics of the recently established “International Association of Hydrogen Safety” (IA-HySafe). The present contribution reports the results of the standard benchmark problem SBEP-V21. Focus is given to hydrogen dispersion and accumulation within a non-ventilated ambient pressure garage both during the release and post-release periods but for very low release rates as compared to earlier work (SBEP-V3). The current experiments were performed by CEA at the GARAGE facility under highly controlled conditions. Helium was vertically released from the centre of the 5.76 m (length) x 2.96 m (width) x 2.42 m (height) facility 22 cm from the floor from a 29.7 mm diameter opening at a volumetric rate of 18 L/min (0.027 g/s equivalent hydrogen release rate compared to 1 g/s for SBEP-V3) and for a period of 3740 seconds. Helium concentrations were measured with 57 catharometric sensors at various locations for a period up to 1.1 days. The simulations were performed using a variety of CFD codes and turbulence models. The paper compares the results predicted by the participating partners and attempts to identify the reasons for any observed disagreements.
Uncertainties in Explosion Risk Assessment for a Hydrogen Refuelling Station
Sep 2011
Publication
The project “Towards a Hydrogen Refuelling Infrastructure for Vehicles” (THRIVE) aimed at the determination of conditions to stimulate the building of a sustainable infrastructure for hydrogen as a car fuel in The Netherlands. Economic scenarios were constructed for the development of such an infrastructure for the next one to four decades. The eventual horizon will require the erection of a few hundred to more than a thousand hydrogen refuelling stations (HRS) in The Netherlands. The risk acceptability policy in The Netherlands implemented in the External Safety Establishments decree requires the assessment and management of safety risks imposed on the public by car fuelling stations. In the past a risk-informed policy has been developed for the large scale introduction of liquefied petroleum gas (LPG) as a car fuel and a similar policy will also be required if hydrogen is introduced in the public domain. A risk assessment methodology dedicated to cope with accident scenarios relevant for hydrogen applications is to be developed. Within the THRIVE project a demo risk assessment was conducted for the possible implementation of an HRS within an existing station for conventional fuels. The studied station is located in an urban area occupied with housing and commercial activities. The HRS is based on delivery and on-site storage of liquid hydrogen and dispensing of high pressure gaseous hydrogen into vehicles. The main challenges in the risk assessment were in the modelling of release and dispersion of liquid hydrogen. Definition of initial conditions for computational fluid dynamics (CFD) modelling to evaluate dispersion of a cold hydrogen air mixture appears rather complex and is not always fully understood. The modelling assumptions in the initial conditions determine to a large extent the likelihood and severity of potential explosion effects. The paper shows the results of the investigation and the sensitivity to the basic assumptions in the model input.
HIAD – Hydrogen Incident and Accident Database
Sep 2011
Publication
The Hydrogen Incident and Accident Database (HIAD) is being developed as a repository of systematic data describing in detail hydrogen-related undesired events (incidents or accidents). It is an open web-based information system serving various purposes such as a data source for lessons learnt risk communication and partly risk assessment. The paper describes the features of the three HIAD modules – the Data Entry Module (DEM) the Data Retrieval Module (DRM) and the Data Analysis Module (DAM) – and the potential impact the database may have on hydrogen safety. The importance of data quality assurance process is also addressed.
Reversible Ammonia-based and Liquid Organic Hydrogen Carriers for High-density Hydrogen Storage: Recent Progress
Feb 2019
Publication
Liquid hydrogen carriers are considered to be attractive hydrogen storage options because of their ease of integration into existing chemical transportation infrastructures when compared with liquid or compressed hydrogen. The development of such carriers forms part of the work of the International Energy Agency Task 32: Hydrogen-Based Energy Storage. Here we report the state-of-the-art for ammonia-based and liquid organic hydrogen carriers with a particular focus on the challenge of ensuring easily regenerable high-density hydrogen storage.
On the Use of Hydrogen in Confined Spaces: Results from the Internal Project InsHyde
Sep 2009
Publication
Alexandros G. Venetsanos,
Paul Adams,
Inaki Azkarate,
A. Bengaouer,
Marco Carcassi,
Angunn Engebø,
E. Gallego,
Olav Roald Hansen,
Stuart J. Hawksworth,
Thomas Jordan,
Armin Keßler,
Sanjay Kumar,
Vladimir V. Molkov,
Sandra Nilsen,
Ernst Arndt Reinecke,
M. Stöcklin,
Ulrich Schmidtchen,
Andrzej Teodorczyk,
D. Tigreat,
N. H. A. Versloot and
L. Boon-Brett
The paper presents an overview of the main achievements of the internal project InsHyde of the HySafe NoE. The scope of InsHyde was to investigate realistic small-medium indoor hydrogen leaks and provide recommendations for the safe use/storage of indoor hydrogen systems. Additionally InsHyde served to integrate proposals from HySafe work packages and existing external research projects towards a common effort. Following a state of the art review InsHyde activities expanded into experimental and simulation work. Dispersion experiments were performed using hydrogen and helium at the INERIS gallery facility to evaluate short and long term dispersion patterns in garage like settings. A new facility (GARAGE) was built at CEA and dispersion experiments were performed there using helium to evaluate hydrogen dispersion under highly controlled conditions. In parallel combustion experiments were performed by FZK to evaluate the maximum amount of hydrogen that could be safely ignited indoors. The combustion experiments were extended later on by KI at their test site by considering the ignition of larger amounts of hydrogen in obstructed environments outdoors. An evaluation of the performance of commercial hydrogen detectors as well as inter-lab calibration work was jointly performed by JRC INERIS and BAM. Simulation work was as intensive as the experimental work with participation from most of the partners. It included pre-test simulations validation of the available CFD codes against previously performed experiments with significant CFD code inter-comparisons as well as CFD application to investigate specific realistic scenarios. Additionally an evaluation of permeation issues was performed by VOLVO CEA NCSRD and UU by combining theoretical computational and experimental approaches with the results being presented to key automotive regulations and standards groups. Finally the InsHyde project concluded with a public document providing initial guidance on the use of hydrogen in confined spaces.
Workshop Report: Summary & Outcomes, Putting Science into Standards Power-to-Hydrogen and HCNG
Oct 2014
Publication
The Joint Research Centre (JRC) of the European Commission together with the European Association of Research and Technology Organisations (EARTO) the European Standards Organisations (ESO) CEN and CENELEC and the European Commission Directorate-General Enterprise and Industry (ENTR) have launched an initiative within the context of the European Forum on Science and Industry to bring the scientific and standardization communities closer together. The second and very successful workshop in a series entitled “Putting Science into Standards" was held in at the Institute for Energy and Transport of the JRC in Petten on 21-22 October 2014.<br/>The workshop focused on Power to Hydrogen (P2H) and Hydrogen Compressed Natural Gas (HCNG) which represent a promising and major contribution to the challenging management of increased integration of renewable energy sources in the overall energy system. The workshop offered a platform to exchange ideas on technologies policy and standardization issues. The participation of major stakeholders from both industry and research to this event proved fruitful in moving towards consensus on the relevant technical issues involved and at identifying a common way forward to increase the maturity and market visibility of P2H components and systems. Other outcomes include a clarification of expectations of industry of where and how policy and standardization can contribute to a competitive development of P2H and related issues. The workshop results will be used to devise a roadmap on "Opportunities for Power to Hydrogen and HCNG" by CEN/CENELEC outlining the next steps of standardization activities.
Safe Operation of Natural Gas Appliances Fuelled with Hydrogen & Natural Gas Mixtures (Progress Obtained in the Naturalhy-Project)
Sep 2007
Publication
Considering the transition towards the hydrogen economy dependent on hydrogen penetration scenario the cost of a new hydrogen pipeline infrastructure in Europe may amount to several thousands of billions of EURO’s. Therefore the examination of the potential contribution of the existing natural gas assets is a practical and logical first step. As the physical and chemical properties of hydrogen differ significantly from those of natural gas it is not at all possible to simply exchange natural gas by hydrogen in the existing infrastructure. In this paper first a brief overview will be given of the NATURALHY-project. Further the focus will be on the impact of added hydrogen on the performance of existing natural gas domestic end user appliances which is related to the operation of the natural gas grid connecting the different types of appliance. The application of the fundamental insights and carefully designed experiments comparing the behaviour of gases using justified reference conditions have been shown to offer essential progress. The Wobbe index limits of the natural gas distributed pose a first limiting factor upon the maximum allowable hydrogen concentration. Constant-Wobbe index and decreasing-Wobbe index options of H2 admixture have been studied. Considering the appliance light back H2 limiting factor for domestic appliances fuel-rich appliances are the critical ones. Also taking into account stationary gas engines gas turbines industrial applications and natural gas grid management it is not yet justified to present statements on what level of hydrogen concentration could be safely allowed in which specific natural gas distribution region. But more clarity has been obtained on combustion safety aspects of existing domestic appliances on the connection with Wobbe distribution conditions and on the bottlenecks still to be handled.
Assessing the Durability and Integrity of Natural Gas Infrastructures for Transporting and Distributing Mixtures of Hydrogen and Natural Gas
Sep 2005
Publication
Extensive infrastructure exists for the transport of natural gas and it is an obvious step to assess its use for the movement of hydrogen. The Naturalhy project’s objective is to prepare the European natural gas industry for the introduction of hydrogen by assessing the capability of the natural gas infrastructure to accept mixtures of hydrogen and natural gas. This paper presents the ongoing work within both Durability and Integrity Work Packages of the Naturalhy project. This work covers a gap in knowledge on risk assessment required for delivering H2+natural gas blends by means of the existing natural gas grids in safe operation.<br/>Experiments involving several parts of the existing infrastructure will be described that are being carried out to re-examine the major risks previously studied for natural gas including: effect of H2 on failure behaviour and corrosion of transmission pipes and their burst resistance (link to the Work Package Safety) on permeability and ageing of distribution pipes on reliability and ageing of domestic gas meters tightness to H2 of domestic appliances and their connexions. The information will be integrated into existing Durability assessment methodologies originally developed for natural gas.<br/>An Integrity Management Tool will be developed taking account of the effect of hydrogen on the materials properties. The tool should enable a cost effective selection of appropriate measures to control the structural integrity and maintaining equipment. The main measures considered are monitoring non destructive examination (pigging and non pigging) and repair strategies. The tool will cover a number of parameters e.g.: percentage of hydrogen in the gas mixture material of construction operating conditions and condition of cathodic protection. Thus the Integrity Management Tool will yield an inspection and maintenance plan based on the specific circumstances.
Safety of Laboratories for New Hydrogen Techniques
Sep 2007
Publication
In this paper a case of hydrogen release in a typical research laboratory for the characterisation of hydrogen solid-state storage materials has been considered. The laboratory is equipped with various testing equipments for the assessment of hydrogen capacity in materials typically in the 1 to 200 bar pressure range and temperatures up to 500°C. Hydrogen is delivered at 200 bar by a 50 l gas bottle and a compressor located outside the laboratory. The safety measures directly related to hydrogen hazard consist in a distributed ventilation of the laboratory and air extraction fume hoods located on top of each instrument. Goal of this work is the modelling of hydrogen accidental release in a real laboratory case in order to provide a more fundamental basis for the laboratory safety design and assist the decision on the number and position of the safety sensors. The computational fluid dynamics code (CFD) ANSYS-CFX has been selected in order to perform the numerical investigations. Two basic accidental release scenarios have been assumed both at 200 bar: a major leak corresponding to a guillotine breaking of the hydrogen distribution line and a smaller leak typical for a not properly tight junction.
Simulation of the Fast Filling of Hydrogen Tanks
Sep 2009
Publication
High pressure storage of hydrogen in tanks is a promising option to provide the necessary fuel for transportation purposes. The fill process of a high-pressure tank should be reasonably short but must be designed to avoid too high temperatures in the tank. The shorter the fill should be the higher the maximum temperature in the tank climbs. For safety reasons an upper temperature limit is included in the requirements for refillable hydrogen tanks (ISO 15869) which sets the limit for any fill optimization. It is crucial to understand the phenomena during a tank fill to stay within the safety margins.<br/>The paper describes the fast filling process of hydrogen tanks by simulations based on the Computational Fluid Dynamics (CFD) code CFX. The major result of the simulations is the local temperature distribution in the tank depending on the materials of liner and outer thermal insulation. Different material combinations (type III and IV) are investigated.<br/>Some measurements from literature are available and are used to validate the approach followed in CFX to simulate the fast filling of tanks. Validation has to be continued in future to further improve the predictability of the calculations for arbitrary geometries and material combinations.
Measurement Challenges for Hydrogen Vehicles
Apr 2019
Publication
Uptake of hydrogen vehicles is an ideal solution for countries that face challenging targets for carbon dioxide reduction. The advantage of hydrogen fuel cell electric vehicles is that they behave in a very similar way to petrol engines yet they do not emit any carbon containing products during operation. The hydrogen industry currently faces the dilemma that they must meet certain measurement requirements (set by European legislation) but cannot do so due to a lack of available methods and standards. This paper outlines the four biggest measurement challenges that are faced by the hydrogen industry including flow metering quality assurance quality control and sampling.
Government Strategy on Hydrogen - The Netherlands
Apr 2020
Publication
Low-carbon gases are indispensable to any energy system that is reliable clean affordable safe and is suited to spatial integration and zero-carbon hydrogen is a crucial link in that chain1. The most common element in the universe seems to have a highly bonding effect in the Netherlands – particularly as a result of the unique starting position of our country. This is made clear in the agreements of the National Climate Agreement which includes an ambitious target for hydrogen supported by a large and broad group of stakeholders. Industrial clusters and ports regard hydrogen as an indispensable part of their future and sustainability strategy. For the transport sector hydrogen (in combination with fuel cells) is crucial to achieving zero emissions transport. The agricultural sector has identified opportunities for the production of hydrogen and for its use. Cities regions and provinces are keen to get started on implementing hydrogen.<br/>The government embraces these targets and recognises the power of the framework for action demonstrated by so many parties. The focus on clean hydrogen in the Netherlands will lead to the creation of new jobs improvements to air quality and moreover is crucial to the energy transition.
Hysafe SBEP-V20: Numerical Predictions of Release Experiments Inside a Residential Garage With Passive Ventilation
Sep 2009
Publication
This work presents the results of the Standard Benchmark Exercise Problem (SBEP) V20 of Work Package 6 (WP6) of HySafe Network of Excellence (NoE) co-funded by the European Commission in the frame of evaluating the quality and suitability of codes models and user practices by comparative assessments of code results. The benchmark problem SBEP-V20 covers release scenarios that were experimentally investigated in the past using helium as a substitute to hydrogen. The aim of the experimental investigations was to determine the ventilation requirements for parking hydrogen fuelled vehicles in residential garages. Helium was released under the vehicle for 2 h with 7.200 l/h flow rate. The leak rate corresponded to a 20% drop of the peak power of a 50 kW fuel cell vehicle. Three double vent garage door geometries are considered in this numerical investigation. In each case the vents are located at the top and bottom of the garage door. The vents vary only in height. In the first case the height of the vents is 0.063 m in the second 0.241 m and in the third 0.495 m. Four HySafe partners participated in this benchmark. The following CFD packages with the respective models were applied to simulate the experiments: ADREA-HF using k–ɛ model by partner NCSRD FLACS using k–ɛ model by partner DNV FLUENT using k–ɛ model by partner UPM and CFX using laminar and the low-Re number SST model by partner JRC. This study compares the results predicted by the partners to the experimental measurements at four sensor locations inside the garage with an attempt to assess and validate the performance of the different numerical approaches.
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