Institution of Gas Engineers & Managers

As a clean and renewable energy source for sustainable development hydrogen energy has gained a lot of attention from the general public and researchers. Hydrogen production by electrolysis of water is the most important approach to producing hydrogen and it is also the main way to realize carbon neutrality. In this paper the main technologies of hydrogen production by electrolysis of water are discussed in detail; their characteristics advantages and disadvantages are analyzed; and the selection criteria and design criteria of catalysts are presented. The catalysts used in various hydrogen production technologies and their characteristics are emphatically expounded aiming at optimizing the existing catalyst system and developing new high-performance high-stability and low-cost catalysts. Finally the problems and solutions in the practical design of catalysts are discussed and explored.

Hydrogen has attracted widespread attention as a carbon-neutral energy source but developing efficient and safe hydrogen storage technologies remains a huge challenge. Recently liquid organic hydrogen carriers (LOHCs) technology has shown great potential for efficient and stable hydrogen storage and transport. This technology allows for safe and economical large-scale transoceanic transportation and long-cycle hydrogen storage. In particular traditional organic hydrogen storage liquids are derived from nonrenewable fossil fuels through costly refining procedures resulting in unavoidable environmental contamination. Biomass holds great promise for the preparation of LOHCs due to its unique carbon-balance properties and feasibility to manufacture aromatic and nitrogen-doped compounds. According to recent studies almost 100% conversion and 92% yield of benzene could be obtained through advanced biomass conversion technologies showing great potential in preparing biomass-based LOHCs. Overall the present LOHCs systems and their unique applications are introduced in this review and the technical paths are summarized. Furthermore this paper provides an outlook on the future development of LOHCs technology focusing on biomass-derived aromatic and N-doped compounds and their applications in hydrogen storage.

Modernising Australia’s old truck fleet and adopting a more stringent standard to reduce emissions and air pollutants is a primary objective for the Australian truck sector. Various strategies worldwide have been introduced to cut emissions and pollutants in the truck sector such as a low-emission strategy supported by strict diesel standards and a zero-emission strategy to shift to battery-electric or hydrogen trucks. The paper focuses on emissions and local air pollutants of trucks under various transition scenarios at both the tailpipe and the wider supply chain including domestic power generation and hydrogen production. In contrast for diesel we focus on tailpipe outputs following fuel standards in Australia given diesel is imported other than in some limited refineries. We compare and recommend actions that government and truck operators may take in the near to longer term in transitioning to cleaner energy. We tested a number of scenarios using a decision support system incorporating all the latest information on costs and emissions for all truck classes using diesel electric or hydrogen. A key finding from our scenario tests is that the current electricity mix has high carbon emissions and air pollutants due to fossil fuel-fired sources for power generation. Without improvement in using renewable energy sources in the future transitioning to electric trucks implies more carbon emissions and air pollutants in the atmosphere from power plants even though electric trucks generate zero tailpipe emissions. The main motivation for switching to zero-emission trucks is energy cost savings. We urge the government to decide on a clear roadmap for the truck sector before the sector is in a position to take action to shift to low or zero-emission trucks without totally relying on the likely reduction of emission intensity in electricity and renewable energy production.

Hydrogen storage might be key to the success of the hydrogen economy and hence the energy transition in Germany. One option for cost-effective storage of large quantities of hydrogen is the geological subsurface. However previous experience with underground hydrogen storage is restricted to salt caverns which are limited in size and space. In contrast pore storage facilities in aquifers -and/or depleted hydrocarbon reservoirs- could play a vital role in meeting base load needs due to their wide availability and large storage capacity but experiences are limited to past operations with hydrogen-bearing town gas. To overcome this barrier here we investigate hydrogen storage in porous storage systems in a two-step process: 1) First we investigate positive and cautionary indicators for safe operations of hydrogen storage in pore storage systems. 2) Second we estimate hydrogen storage capacities of pore storage systems in (current and decommissioned) underground natural gas storage systems and saline aquifers. Our systematic review highlights that optimal storage conditions in terms of energy content and hydrogen quality are found in sandstone reservoirs in absence of carbonate and iron bearing accessory minerals at a depth of approx. 1100 m and a temperature of at least 40°C. Porosity and permeability of the reservoir formation should be at least 20% and 5 × 10−13 m2 (~500 mD) respectively. In addition the pH of the brine should fall below 6 and the salinity should exceed 100 mg/L. Based on these estimates the total hydrogen storage capacity in underground natural gas storages is estimated to be up to 8 billion cubic meters or (0.72 Mt at STP) corresponding to 29 TWh of energy equivalent of hydrogen. Saline aquifers may offer additional storage capacities of 81.6–691.8 Mt of hydrogen which amounts to 3.2 to 27.3 PWh of energy equivalent of hydrogen the majority of which is located in the North German basin. Pore storage systems could therefore become a crucial element of the future German hydrogen infrastructure especially in regions with large industrial hydrogen (storage) demand and likely hydrogen imports via pipelines and ships.

Europe’s electricity transmission expansion suffers many delays despite its significance for integrating renewable electricity. A hydrogen network reusing the existing gas network could not only help to supply the demand for low-emission fuels but could also balance variations in wind and solar energies across the continent and thus avoid power grid expansion. Our investigation varies the allowed expansion of electricity and hydrogen grids in net-zero CO2 scenarios for a sector-coupled European energy system capturing transmission bottlenecks renewable supply and demand variability and pipeline retrofitting and geological storage potentials. We find that a hydrogen network connecting regions with low-cost and abundant renewable potentials to demand centers electrofuel production and cavern storage sites reduces system costs by up to 26 bnV/a (3.4%). Although expanding both networks together can achieve the largest cost reductions by 9.9% the expansion of neither is essential for a net-zero system as long as higher costs can be accepted and flexibility options allow managing transmission bottlenecks.

The hydrogen supply system is one of the important components of a hydrogen fuel cell engine and its performance has an important impact on the economy and power of the engine system. In this paper a hydrogen supply system based on cyclic mode is designed for a hydrogen fuel cell stack with a full load power of 150 kW and the corresponding hydrogen fuel cell engine simulation model is built and validated. The control strategy of the fuel cell hydrogen supply system is developed and its effect is verified through bench tests. The results show that the developed control strategy can keep the volume fraction of nitrogen below 6% the hydrogen excess ratio does not exceed 1.5 under medium and high operating conditions the anode pressure is relatively stable and the stack can operate efficiently and reliably.

Offshore wind power stands out as a promising renewable energy source offering substantial potential for achieving low carbon emissions and enhancing energy security. Despite its potential the expansion of offshore wind power faces considerable constraints in offshore power transmission. Hydrogen production derived from offshore wind power emerges as an efficient solution to overcome these limitations and effectively transport energy. This study systematically devises diverse hydrogen energy supply chains tailored to the demands of the transportation and chemical industries meticulously assessing the levelized cost of hydrogen (LCOH). Our findings reveal that the most cost-efficient means of transporting hydrogen to the mainland is through pipelines particularly when the baseline distance is 50 km and the baseline electricity price is 0.05 USD/kWh. Notably delivering hydrogen directly to the port via pipelines for chemical industries proves considerably more economical than distributing it to hydrogen refueling stations with a minimal cost of 3.6 USD/kg. Additionally we assessed the levelized cost of hydrogen (LCOH) for supply chains that transmit electricity to ports via submarine cables before hydrogen production and subsequent distribution to chemical plants. In comparison to offshore hydrogen production routes these routes exhibit higher costs and reduced competitiveness. Finally a sensitivity analysis was undertaken to scrutinize the impact of delivery distance and electricity prices on LCOH. The outcomes underscore the acute sensitivity of LCOH to power prices highlighting the potential for substantial reductions in hydrogen prices through concerted efforts to lower electricity costs.

Proton-exchange membrane fuel cells (PEMFCs) are low-temperature fuel cells that have excellent starting performance due to their low operating temperature can respond quickly to frequent load fluctuations and can be manufactured in small packages. Unlike existing studies that mainly used hydrogen as fuel for PEMFCs in this study methane is used as fuel for PEMFCs to investigate its performance and economy. Methane is a major component of natural gas which is more economically competitive than hydrogen. In this study methane gas is reformed by the steam reforming method and is applied to the following five gas post-treatment systems: (a) Case 1—water– gas shift only (WGS) (b) Case 2—partial oxidation reforming only (PROX) (c) Case 3—methanation only (d) Case 4—WGS + methanation (e) Case 5—WGS + PROX. In the evaluation the carbon monoxide concentration in the gas did not exceed 10 ppm and the methane component which has a very large greenhouse effect was not regenerated in the post-treated exhaust gas. As a result Case 5 (WGS and PROX) is the only case that satisfied both criteria. Therefore we propose Case 5 as an optimized post-treatment system for methane reforming gas in ship PEMFCs.

China aims to peak CO2 emissions before 2030 and to achieve carbon neutrality before 2060; hence industrial sectors in China are keen to figure out appropriate pathways to support the national target of carbon neutrality. The objective of this study is to explore near-zero emission pathways for the steel industry of China through a detailed technology assessment. The innovative technology development has been simulated using the AIM-China/steel model developed by including material-based technologies and optimal cost analysis. Six scenarios have been given in terms of different levels of production output emission reduction and carbon tax. Near-zero emission and carbon tax scenarios have shown that China’s steel industry can achieve near-zero emission using electric furnaces and hydrogen-based direct reduction iron technologies with policy support. Based on these technologies minimised production costs have been calculated revealing that the steel produced by these technologies is cost-effective. Moreover the feedstock cost can play a key role in these technology portfolios especially the cost of scrap iron ore and hydrogen. In addition the feedstock supply can have strong regional effects and can subsequently impact the allocation of steelmaking in the future. Therefore China can achieve near-zero emissions in the steel industry and electric furnace and hydrogen-based direct reduction iron technologies are crucial to achieving them.

Hydrogen gas can provide baseload energy as society decarbonizes through the energy transition. Underground Hydrogen Storage (UHS) will be secure convenient and scalable to accommodate excess hydrogen production or compensate temporary shortfalls in energy supply. Hydrogen is a gas under all viable subsurface conditions so is invasive mobile and low-density. Methane and CO2 are also stored underground but storage parameters differ for each affecting the balance of geological storage risks. UHS in Australia is most likely to utilise conventional sedimentary reservoir rocks bound by conventional trapping closures. Hydrogen energy density will affect the competitiveness of UHS against purpose-built surface storage or solution-mined salt cavities. This study presents an overview of key considerations when screening for UHS opportunities and evaluates them for five Australian sedimentary basins. A threshold storage depth mapped across them reveals that the most prospective UHS basins will have to function as integrated energy fluid resource systems.