Publications
Potential of Salt Caverns for Hydrogen Storage in Southern Ontario, Canada
Jul 2023
Publication
Salt caverns produced by solution mining in Southern Ontario provide ideal spaces for gas storage due to their low permeability. Underground hydrogen storage (UHS) is an important part of the future renewable energy market in Ontario in order to achieve global carbon neutrality and to fill the gap left by retiring nuclear power plants. However large-scale hydrogen storage is still restricted by limited storage space on the ground’s surface. In this study hydrogen’s physical and chemical properties are first introduced and characterized by low molecular weight high diffusivity low solubility and low density. Then the geological conditions of the underground reservoirs are analyzed especially salt caverns. Salt caverns with their inert cavity environments and stable physical properties offer the most promising options for future hydrogen storage. The scales heights and thicknesses of the roof and floor salt layers and the internal temperatures and pressures conditions of salt caverns can affect stabilities and storage capacities. Finally several potential problems that may affect the safe storage of hydrogen in salt caverns are discussed. Through the comprehensive analysis of the influencing factors of hydrogen storage in salt caverns this study puts forward the most appropriate development strategy for salt caverns which provides theoretical guidance for UHS in the future and helps to reduce the risk of large-scale storage design.
Combining Renewable Sources Towards Negative Carbon Emission Hydrogen
Apr 2023
Publication
Multi-energy systems that combine different energy sources and carriers to improve the overall technical economic and environmental performance can boost the energy transition. In this paper we posit an innovative multi-energy system for green hydrogen production that achieves negative carbon emissions by combining bio-fuel membraneintegrated steam reforming and renewable electricity electrolysis. The system produces green hydrogen and carbon dioxide both at high purity. We use thermo-chemical models to determine the system performance and optimal working parameters. Specifically we focus on its ability to achieve negative carbon emissions. The results show that in optimal operating conditions the system can capture up to 14.1 g of CO2 per MJ of stored hydrogen and achieves up to 70% storage efficiency. Therefore we prove that a multi-energy system may reach the same efficiency of an average electrolyzer while implementing carbon capture. In the same optimal operating conditions the system converts 7.8 kg of biogas in 1 kg of hydrogen using 3.2 kg of oxygen coming from the production of 6.4 kg of hydrogen through the electrolyzer. With such ratios we estimate that the conversion of all the biogas produced in Europe with our system could result in the installation of additional dedicated 800 GWp - 1280 GWp of photovoltaic power or of 266 GWp - 532 GWp of wind power without affecting the distribution grid and covering yearly the 45% of the worldwide hydrogen demand while removing from the atmosphere more than 2% of the European carbon dioxide emissions.
Everything About Hydrogen Podcast: Policy Simplicity & Certainty
Mar 2023
Publication
On this episode of Everything About Hydrogen we have Daria Nochevnik the Director of Policy and Partnerships for Hydrogen Council.
The podcast can be found on their website.
The podcast can be found on their website.
Paving the Way: Analysing Energy Transition Pathways and Green Hydrogen Exports in Developing Countries - The Case of Algeria
Apr 2024
Publication
The measures needed to limit global warming pose a particular challenge to current fossil fuel exporters who must not only decarbonise their local energy systems but also compensate for the expected decline in fossil fuel revenues. One possibility is seen in the export of green hydrogen. Using Algeria as a case study this paper analyses how different levels of ambition in hydrogen exports energy efficiency and fuel switching affect the costoptimal expansion of the power sector for a given overall emissions reduction path. Despite falling costs for photovoltaics and wind turbines the results indicate that in countries with very low natural gas prices such as Algeria a fully renewable electricity system by 2050 is unlikely without appropriate policy measures. The expansion of renewable energy should therefore start early given the high annual growth rates required which will be reinforced by additional green hydrogen exports. In parallel energy efficiency is a key factor as it directly mitigates CO2 emissions from fossil fuels and reduces domestic electricity demand which could instead be used for hydrogen production. Integrating electrolysers into the power system could potentially help to reduce specific costs through load shifting. Overall it seems advisable to analyse hydrogen exports together with local decarbonisation in order to better understand their interactions and to reduce emissions as efficiently as possible. These results and the methodology could be transferred to other countries that want to become green hydrogen exporters in the future and are therefore a useful addition for researchers and policy makers.
The Hydrogen Dilemma: An Industrial Site-specific Case Study on the Transformation Pathway Toward Renewable Hydrogen
Jul 2025
Publication
Future renewable energy systems are expected to heavily rely on low-emission hydrogen not least as a crucial feedstock for industry. Although there are numerous pan-European system studies exploring a cost-efficient hydrogen ramp-up a number of issues are driving companies to develop site-specific transformation strategies that are not always in line with the results of these large-scale studies. Addressing this gap this study contributes a detailed analysis of a real-world chemical site in Southern Germany that depends on hydrogen as a feedstock. In doing so insights in industry transformation options and its implications at site level are provided. Applying a cost-optimizing energy system model several corporate strategies and extensive sensitivity analyses for the transition to renewable hydrogen are evaluated for the period 2025 to 2045. This involves considering onsite interdependencies between the production and use of hydrogen as a feedstock and the site’s electricity and heat sector. The results show that under a purely rational strategy and current expectations the transformation to renewable hydrogen will not become competitive before 2045 while neither expensive emission allowances nor low-priced hydrogen supply on their own will result in a substantially accelerated transformation. This highlights the need for additional policy measures. Furthermore it is demonstrated that under almost any realistic condition within the following 20 years using hydrogen for heat generation below 200 ◦C is unlikely. Therefore prioritizing the electrification of process heat supply while waiting for hydrogen imports would be a logical approach for reducing greenhouse gas emissions.
Can Africa Serve Europe with Hydrogen Energy from Its Renewables?—Assessing the Economics of Shipping Hydrogen and Hydrogen Carriers to Europe from Different Parts of the Continent
Apr 2023
Publication
There exists no single optimal way for transporting hydrogen and other hydrogen carriers from one port to the other globally. Its delivery depends on several factors such as the quantity distance economics and the availability of the required infrastructure for its transportation. Europe has a strategy to invest in the production of green hydrogen in Africa to meet its needs. This study assessed the economic viability of shipping liquefied hydrogen (LH2 ) and hydrogen carriers to Germany from six African countries that have been identified as countries with great potential in the production of hydrogen. The results obtained suggest that the shipping of LH2 to Europe (Germany) will cost between 0.47 and 1.55 USD/kg H2 depending on the distance of travel for the ship. Similarly the transportation of hydrogen carriers could range from 0.19 to 0.55 USD/kg H2 for ammonia 0.25 to 0.77 USD/kg H2 for LNG 0.24 to 0.73 USD/kg H2 for methanol and 0.43 to 1.28 USD/kg H2 for liquid organic hydrogen carriers (LOHCs). Ammonia was found to be the ideal hydrogen carrier since it recorded the least transportation cost. A sensitivity analysis conducted indicates that an increase in the economic life by 5 years could averagely decrease the cost of LNG by some 13.9% NH3 by 13.2% methanol by 7.9% LOHC by 8.03% and LH2 by 12.41% under a constant distance of 6470 nautical miles. The study concludes with a suggestion that if both foreign and local participation in the development of the hydrogen market is increased in Africa the continent could supply LH2 and other hydrogen carriers to Europe at a cheaper price using clean fuel.
Willingness of Chinese Households to Pay Extra for Hydrogen-fuelled Buses: A Survey Based on Willingness to Pay
Mar 2023
Publication
Hydrogen-fuelled buses play an important role in the construction of low-carbon cities as a means of green travel. Beijing as a pilot city of hydrogen-fuelled buses in China is very important in the promotion of hydrogen-fuelled buses in China. Unfortunately the public acceptance of hydrogen-fuelledfuelled buses and their environmental positive externality value have not been studied. In this paper we investigated the willingness of Beijing households to pay for the promotion of hydrogen-fuelled buses and its influencing factors by means of a web-based questionnaire. The spike model was also used to estimate the willingness to pay (WTP) for hydrogen buses. The results show that the WTP of Beijing households is CNY 3.19 per trip. The value of a positive environmental externality is approximately CNY 29.15 million per trip. Household income level environmental knowledge individual environmental ethics and perceived behavioural control are the main influencing factors of WTP. Therefore policymakers should strengthen publicity efforts to increase individuals’ environmental awareness and environmental ethics and optimize the layout of hydrogen-fuelled bus schedules and riding experiences to improve individuals’ perceptual and behaviour control. Finally the positive environmental externality value of hydrogen buses should be valued which will help increase investor interest.
Deep Decarbonisation Pathways of the Energy System in Times of Unprecedented Uncertainty in the Energy Sector
May 2023
Publication
Unprecedented investments in clean energy technology are required for a net-zero carbon energy system before temperatures breach the Paris Agreement goals. By performing a Monte-Carlo Analysis with the detailed ETSAPTIAM Integrated Assessment Model and by generating 4000 scenarios of the world’s energy system climate and economy we find that the uncertainty surrounding technology costs resource potentials climate sensitivity and the level of decoupling between energy demands and economic growth influence the efficiency of climate policies and accentuate investment risks in clean energy technologies. Contrary to other studies relying on exploring the uncertainty space via model intercomparison we find that the CO2 emissions and CO2 prices vary convexly and nonlinearly with the discount rate and climate sensitivity over time. Accounting for this uncertainty is important for designing climate policies and carbon prices to accelerate the transition. In 70% of the scenarios a 1.5 ◦C temperature overshoot was within this decade calling for immediate policy action. Delaying this action by ten years may result in 2 ◦C mitigation costs being similar to those required to reach the 1.5 ◦C target if started today with an immediate peak in emissions a larger uncertainty in the medium-term horizon and a higher effort for net-zero emissions.
THyGA - Roadmap H2NG for Europe
May 2023
Publication
This report aims at summarizing the different stakeholders’ opinions on H2NG blends and cross them with the THyGA results to recommend some necessary actions to prepare the field for operational large-scale blending (liability delayed ignition adjustment…).
Exploring Key Operational Factors for Improving Hydrogen Production in a Pilot-scale Microbial Electrolysis Cell Treating Urban Wastewater
Jun 2023
Publication
Bioelectrochemical systems (BES) are becoming popular technologies with a plethora of applications in the environmental field. However research on the scale-up of these systems is scarce. To understand the limiting factors of hydrogen production in microbial electrolysis cell (MEC) at pilot scale a 135 L MEC was operated for six months under a wide range of operational conditions: applied potential [0.8-1.1 V] hydraulic residence time [1.1-3.9 d] and temperature [18-30 ºC] using three types of wastewater; synthetic (900 mg CODs L-1) raw urban wastewater (200 mg CODs L-1) and urban wastewater amended with acetate (1000 mg CODs L-1). The synthetic wastewater yielded the maximum current density (1.23 A m-2) and hydrogen production (0.1 m3 m-3 d-1) ever reported in a pilot scale MEC with a cathodic recovery of 70% and a coulombic efficiency of 27%. In contrast the use of low COD urban wastewater limited the plant performance. Interestingly it was possible to improve hydrogen production by reducing the hydraulic residence time finding the optimal applied potential or increasing the temperature. Further the pilot plant demonstrated a robust capacity to remove the organic matter present in the wastewater under different conditions with removal efficiencies above 70%. This study shows improved results compared to similar MEC pilot plants treating domestic wastewater in terms of hydrogen production and treatment efficiency and also compares its performance against conventional activated sludge processes.
Blue Hydrogen Production from Natural Gas Reservoirs: A Review of Application and Feasibility
Feb 2023
Publication
Recently interest in developing H2 strategies with carbon capture and storage (CCS) technologies has surged. Considering that this paper reviews recent literature on blue H2 a potential low-carbon short-term solution during the H2 transition period. Three key aspects were the focus of this paper. First it presents the processes used for blue H2 production. Second it presents a detailed comparison between blue H2 and natural gas as fuels and energy carriers. The third aspect focuses on CO2 sequestration in depleted natural gas reservoirs an essential step for implementing blue H2. Globally ~ 75% of H2 is produced using steam methane reforming which requires CCS to obtain blue H2. Currently blue H2 needs to compete with other advancing technologies such as green H2 solar power battery storage etc. Compared to natural gas and liquefied natural gas blue H2 gas results in lower CO2 emissions since CCS is applied. However transporting liquefied and compressed blue H2 entails higher energy economic and environmental costs. CCS must be appropriately implemented to produce blue H2 successfully. Due to their established capacity to trap hydrocarbons over geologic time scales depleted natural gas reservoirs are regarded as a viable option for CCS. Such a conclusion is supported by several simulation studies and field projects in many countries. Additionally there is much field experience and knowledge on the injection and production performance of natural gas reservoirs. Therefore using the existing site infrastructure converting these formations into storage reservoirs is undemanding.
Does Time Matter? A Multi-level Assessment of Delayed Energy Transitions and Hydrogen Pathways in Norway
Mar 2023
Publication
The Russian invasion of Ukraine has undeniably disrupted the EU's energy system and created a window of opportunity for an acceleration of the low-carbon energy transition in Europe. As the trading bloc's biggest gas supplier Norway faces the imminent threat of fast-depleting gas reserves and declining value for its exports. Norway is trying to beat the clock by aggressively exploring more petroleum therefore delaying its energy transition. In anticipation of the future drop in gas prices Norway is counting on blue hydrogen to valorise its gas resources before gradually shifting to green hydrogen export. Against this background this article seeks to understand how changes in the EU's energy landscape have affected the energy export sector and low-carbon hydrogen export developments in Norway from a multi-level perspective. Using the exploratory scenario approach the article assesses the implications of the different petroleum exploration outcomes on the development of the low-carbon hydrogen export market in Norway. The findings show that despite gas discoveries there is an urgent need for a phase-out plan for the Norwegian petroleum sector. For low-carbon hydrogen to play an important role in Norway's energy transition time is of the essence and action needs to be taken during this window of opportunity. An industrial sector and its value chain could take 25 years to transform which means that actions and policies for a full transformation pathway need to take place in Norway by 2025 to be ready for a climate-neutral Europe in 2050.
Green Hydrogen in Developing Countries
Aug 2020
Publication
In the future green hydrogen—hydrogen produced with renewable energy resources—could provide developing countries with a zero-carbon energy carrier to support national sustainable energy objectives and it needs further consideration by policy makers and investors. Developing countries with good renewable energy resources could produce green hydrogen locally generating economic opportunities and increasing energy security by reducing exposure to oil price volatility and supply disruptions. Support from development finance institutions and concessional funds could play an important role in deploying first-of-a-kind green hydrogen projects accelerating the uptake of green hydrogen in developing countries and increasing capacity and creating the necessary policy and regulatory enabling environment.
An Improved Passive Scalar Model for Hazardous H2-Air Ignition Prediction
Sep 2023
Publication
As hydrogen becomes an increasingly popular alternative fuel for transportation the need for tools to predict ignition events has grown. Recently a cost-effective passive scalar formulation has been developed to address this need [1]. This approach employs a self-reacting scalar to model the hydrogenair chain-branched explosion (due to reactions of the type Reactant + Radical → Radical + Radical). The scalar branching rate is derived analytically from the kinetic Jacobian matrix [2]. The method accurately reproduces ignition delays obtained by detailed chemistry for temperatures above crossover where branching is the dominant process. However for temperatures below the crossover temperature where other phenomena like thermal runaway are more significant the scalar approach fails to predict ignition events correctly. Therefore modifications to the scalar framework have been made to extend its validity across the entire temperature range. Additionally a simple technique for approximating the molecular diffusion of the scalar has been developed using the eigenvector of the Jacobian which accounts for differences in the radical pool’s composition and non-unity Lewis number effects. The complete modified framework is presented and its capability is evaluated in canonical scenarios and a more challenging double mixing layer.
Cryogenic Hydrogen Jet and Flame for Clean Energy Applications: Progress and Challenges
May 2023
Publication
Industries across the world are making the transition to net-zero carbon emissions as government policies and strategies are proposed to mitigate the impact of climate change on the planet. As a result the use of hydrogen as an energy source is becoming an increasingly popular field of research particularly in the aviation sector where an alternative green renewable fuel to the traditional hydrocarbon fuels such as kerosene is essential. Hydrogen can be stored in multiple ways including compressed gaseous hydrogen cryo-compressed hydrogen and cryogenic liquid hydrogen. The infrastructure and storage of hydrogen will play a pivotal role in the realisation of large-scale conversion from traditional fuels with safety being a key consideration. This paper provides a review on previous work undertaken to study the characterisation of both unignited and ignited hydrogen jets which are fundamental phenomena for the utilisation of hydrogen. This includes work that focuses on the near-field flow structure dispersion in the far-field ignition and flame characteristics with multi-physics. The safety considerations are also included. The theoretical models and computational fluid dynamics (CFD) multiphase and reactive flow approaches are discussed. Then an overview of previous experimental work is provided before focusing the review on the existing computational results with comparison to experiments. Upon completion of this review it is highlighted that the complex near-field physics and flow phenomena are areas lacking in research. The near-field flow properties and characteristics are of significant importance with respect to the ignition and combustion of hydrogen.
Knowledge and Technology Transfer via Publications, Patents, Standards: Exploring the Hydrogen Technological Innovation System
Nov 2022
Publication
Clean technologies play a crucial role in reducing greenhouse gas emissions and protecting the climate. Hydrogen is a promising energy carrier and fuel that can be used in many applications. We explore the global hydrogen technological innovation system (TIS) by analyzing the three knowledge and technology transfer channels of publications patents and standards. Since the adoption of hydrogen technologies requires trust in their safety this study specifically also focuses on hydrogen safety. Our results show that general and hydrogen safety research has increased significantly while patenting experienced stagnation. An analysis of the non-patent literature in safety patents shows little recognition of scientific publications. Similarly publications are under-represented in the analyzed 75 international hydrogen and fuel cell standards. This limited transfer of knowledge from published research to standards points to the necessity for greater involvement of researchers in standardization. We further derive implications for the hydrogen TIS and recommendations for a better and more impactful alignment of the three transfer channels.
Optimal Scheduling of Integrated Energy System Considering Hydrogen Blending Gas and Demand Response
Apr 2024
Publication
In the context of carbon neutrality and carbon peaking in order to achieve low carbon emissions and promote the efficient utilization of wind energy hydrogen energy as an important energy carrier is proposed to mix hydrogen and natural gas to form hydrogen-enriched compressed natural gas (HCNG). It is also injected into the natural gas pipeline network to achieve the transmission and utilization of hydrogen energy. At the same time the participation of demand response is considered the load’s peak and trough periods are adjusted and the large-scale consumption of renewable energy and the reduction in carbon emissions are achieved. First of all a fine model of hydrogen production and hydrogen use equipment is established to analyze the impact of adding hydrogen mixing on the economy and the low-carbon property of the system. With green certificates and demand response the utilization rate of hydrogen energy is improved to further explore the energy utilization rate and emission reduction capacity of the system. Secondly on the basis of modeling the optimal scheduling strategy is proposed with the sum of energy purchase cost equipment operation cost carbon emission cost wind curtailment cost and green certificate income as the lowest objective function. Considering the constraints such as hydrogen blending ratio and flexible load ratio of the pipeline network a low-carbon economic scheduling model of hydrogen mixed natural gas was established. The model was linearized and solved by using MATLAB 2021a and CPLEX solver. By comparing different scenarios the superiority of the model and the effectiveness of the strategy are verified.
Hydrogen or Electric Drive—Inconvenient (Omitted) Aspects
May 2023
Publication
Currently hydrogen and electric drives used in various means of transport is a leading topic in many respects. This article discusses the most important aspects of the operation of vehicles with electric drives (passenger cars) and hydrogen drives. In both cases the official reason for using both drives is the possibility of independence from fossil fuel supplies especially oil. The desire for independence is mainly dictated by political considerations. This article discusses the acquisition of basic raw materials for the construction of lithium-ion batteries in electric cars as well as methods for obtaining hydrogen as a fuel. The widespread use of electric passenger cars requires the construction of a network of charging stations. This article shows that taking into account the entire production process of electric cars including lithium-ion batteries the argument that they are ecological cannot be used. Additionally it was indicated that there is no concept for the use of used accumulator batteries. If hydrogen drives are used in trains there is no need to build the traction network infrastructure and then continuously monitor its technical condition and perform the necessary repairs. Of course the necessary hydrogen tanks must be built but there must be similar tanks to store oil for diesel locomotives. This paper also deals with other possibilities of hydrogen application for transformational usage e.g. the use of combustion engines driven with liquid hydrogen. Unfortunately an optimistic approach to this issue does not allow for a critical view of the whole matter. In public discussion there is no room for scientific arguments and emotions to dominate.
Green Hydrogen Supply Chain Risk Analysis: A European Hard-to-abate Sectors Perspective
May 2023
Publication
Green hydrogen is a tentative solution for the decarbonisation of hard-to-abate sectors such as steel chemical cement and refinery industries. Green hydrogen is a form of hydrogen gas that is produced using renewable energy sources such as wind or solar power through a process called electrolysis. The green hydrogen supply chain includes several interconnected entities such as renewable energy providers electrolysers distribution facilities and consumers. Although there have been many studies about green hydrogen little attention has been devoted to green hydrogen supply chain risk identification and analysis especially for hard-to-abate sectors in Europe. This research contributes to existing knowledge by identifying and analysing the European region’s green hydrogen supply chain risk factors. Using a Delphi method 7 categories and 43 risk factors are identified based on the green hydrogen supply chain experts’ opinions. The best-worst method is utilised to determine the importance weights of the risk categories and risk factors. High investment of capital for hydrogen production and delivery technology was the highest-ranked risk factor followed by the lack of enough capacity for electrolyser and policy & regulation development. Several mitigation strategies and policy recommendations are proposed for high-importance risk factors. This study provides novelty in the form of an integrated approach resulting in a scientific ranking of the risk factors for the green hydrogen supply chain. The results of this study provide empirical evidence which corroborates with previous studies that European countries should endeavour to create comprehensive and supportive standards and regulations for green hydrogen supply chain implementation.
CFD Modelling of Startup Fuelling Phase Accounting for All Hydrogen Refuelling Station Components
Sep 2023
Publication
Further development of hydrogen-fuelled transport and associated infrastructure requires fundamentally based validated and publicly accepted models for fuelling protocol development particularly for heavy-duty transport applications where protocols are not available yet. This study aims to use computational fluid dynamics (CFD) for modelling the entire hydrogen refuelling station (HRS) including all its components starting from high-pressure (HP) tanks a mass flow meter pressure control valve (PCV) a heat exchanger (HE) nozzle hose breakaway and up to 3 separate onboard tanks. The paper focuses on the initial phase of the refuelling procedure in which the main purpose is to check for leaks in the fuelling line and determine if it is safe to start fuelling. The simulation results are validated against the only publicly available data on hydrogen fuelling by Kuroki and co-authors (2021) from the NREL hydrogen fuelling station experiment. The simulation results – mass flow rate dynamics as well as pressure and temperature at different station locations - show good agreement with the measured experimental data. The development of such models is crucial for the further advancement of hydrogen-fuelled transport and infrastructure and this study presents a step towards this goal.
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