Publications
Hydrogen Storage Potential in Underground Coal Gasification Cavities: A MD Simulation of Hydrogen Adsorption and Desorption Behavior in Coal Nanopores
May 2025
Publication
Underground hydrogen storage (UHS) in geological formations presents a viable option for long-term large-scale H2 storage. A physical coal model was constructed based on experimental tests and a MD simulation was used to investigate the potential of UHS in underground coal gasification (UCG) cavities. We investigated H2 behavior under various conditions including temperatures ranging from 278.15 to 348.15 K pressures in the range of 5–20 MPa pore sizes ranging from 1 to 20 nm and varying water content. We also examined the competitive adsorption dynamics of H2 in the presence of CH4 and CO2 . The findings indicate that the optimal UHS conditions for pure H2 involve low temperatures and high pressures. We found that coal nanopores larger than 7.5 nm optimize H2 diffusion. Additionally higher water content creates barriers to hydrogen diffusion due to water molecule clusters on coal surfaces. The preferential adsorption of CO2 and CH4 over H2 reduces H2 -coal interactions. This work provides a significant understanding of the microscopic behaviors of hydrogen in coal nanopores at UCG cavity boundaries under various environmental factors. It also confirms the feasibility of underground hydrogen storage (UHS) in UCG cavities.
Effect of Hydrogen Co-Firing with Natural Gas on Thermal Efficiency and CO2 Emissions in Gas Turbine Power Plant
Mar 2025
Publication
The Indonesian government has established an energy transition policy for decarbonization including the target of utilizing hydrogen for power generation through a co-firing scheme. Several studies indicate that hydrogen co-firing in gas-fired power plants can reduce CO2 emissions while improving efficiency. This study develops a simulation model for hydrogen co-firing in an M701F gas turbine at the Cilegon power plant using Aspen HYSYS. The impact of different hydrogen volume fractions (5–30%) on thermal efficiency and CO2 emissions is analyzed under varying operational loads (100% 75% and 50%). The simulation results show an increase in thermal efficiency with each 5% increment in the hydrogen fraction averaging 0.32% at 100% load 0.34% at 75% load and 0.37% at 50% load. The hourly CO2 emission rate decreased by an average of 2.16% across all operational load variations for every 5% increase in the hydrogen fraction. Meanwhile the average reduction in CO2 emission intensity at the 100% 75% and 50% operational loads was 0.017 0.019 and 0.023 kg CO2/kWh respectively.
Exploring Natural Hydrogen Potential in Alberta's Western Canadian Sedimentary Basin
Oct 2025
Publication
Natural hydrogen or "white hydrogen" has recently garnered attention as a viable and cost-effective energy resource due to its low-carbon footprint and high energy density positioning it as a key contributor to the transition towards a sustainable low-carbon energy system. This study represents Alberta’s first systematic effort to evaluate natural hydrogen potential in the province using publicly available geological geospatial and gas composition datasets. By mapping hydrogen occurrences against key geological features in the Western Canadian Sedimentary Basin (WCSB) we identify regions with strong geological potential for natural hydrogen generation migration and accumulation while addressing data uncertainties. Within the WCSB formations like the Montney Cardium Bearpaw Manville Belly River McMurray and Lea Park are identified as zones likely for hydrogen generation by prominent mechanisms including hydrocarbon decomposition water-rock reactions with iron-rich sediments and organic pyrolysis. Formation proximity to the underlying Canadian Shield may also suggest potential for basement-derived hydrogen migration via deep-seated faults and shear zones. Salt deposits (Elk Point Group - Prairie evaporites Cold Lake and Lotsberg) and deep shales (e.g. Kaskapau Lea Park Wapiabi) provide effective cap rock potential while reservoirs like porous sandstone (e.g. Dunvegan Spirit River Cardium) and fractured carbonate (e.g. Keg River) formations offer favorable accumulation conditions. Hydrogen occurrences in relation to geological features identify Southern Eastern and West-Central plains as prominent natural Hydrogen generation and accumulation areas. Alberta’s established energy infrastructure as well as subsurface expertise positions it as a potential leader in natural hydrogen exploration. As Alberta’s first systematic investigation this study provides a preliminary assessment of natural hydrogen potential and outlines recommended next steps to guide future exploration and research. Targeted research on specific generation and accumulation mechanisms and source identification through isotopic and geochemical fingerprinting will be crucial for exploration de-risking and viability assessment in support of net-zero emission initiatives.
Enhancing Durability of Raney-Ni-based Electrodes for Hydrogen Evolution Reaction in Alkaline Water Electrolysis: Mitigating Reverse Current and H2 Bubble Effects using a NiP Protective Layer
Oct 2025
Publication
Raney Ni (R-Ni) electrodes are used as hydrogen evolution reaction catalysts in alkaline water electrolysis (AWE). However they are not durable because of reverse current-induced oxidation and catalyst damage from H2 bubbles. Reverse current triggers Ni phase changes and mechanical stress leading to catalyst delamination while bubbles block active sites increase resistance and cause structural damage. These issues have been addressed individually but not simultaneously. In this study a P-doped Ni (NiP) protective layer is electroplated on the R-Ni electrode to overcome both challenges. The NiP protective layer inhibits oxidation reducing Ni phase changes and preventing catalyst delamination. Enhanced surface wettability minimizes nucleation and facilitates faster bubble detachment reducing bubble-related damage. Electrochemical tests reveal that NiP/R-Ni exhibits a 26 mV lower overpotential than that of R-Ni at −400 mA cm−2 indicating higher catalytic activity. Accelerated degradation tests (ADTs) demonstrate the retention of the NiP/R-Ni catalyst layer with only a 25 mV increase in overpotential after ADT which is significantly less than that of R-Ni. Real-time impedance analysis reveals the presence of small rapidly detaching bubbles on NiP/R-Ni. Overall the NiP protective layer on R-Ni simultaneously mitigates both reverse current and H2 bubble-induced degradation improving catalytic activity and durability during AWE.
A Configuration and Scheduling Optimization Method for Integrated Energy Systems Considering Massive Flexible Load Resources
Mar 2025
Publication
Introduction: With the increasing demand for energy utilization efficiency and minimization of environmental carbon emissions in industrial parks optimizing the configuration and scheduling of integrated energy systems has become crucial. This study focuses on integrated energy systems with massive flexible load resources aiming to maximize energy utilization efficiency while reducing environmental impact. Methods: To model the uncertainties in wind and solar power outputs we employed three-parameter Weibull distribution models and Beta distribution models. Flexible loads were categorized into three types to match different electricity consumption patterns. Additionally an enhanced Kepler Optimization Algorithm (EKOA) was proposed incorporating chaos mapping and adaptive learning rate strategies to improve search scope convergence speed and solution efficiency. The effectiveness of the proposed optimization scheduling and configuration methods was validated through a case study of an industrial park located in a coastal area of southeastern China. Results: The results show that using three-parameter Weibull distribution models and Beta distribution models more accurately reflects the variations in actual wind speeds and solar irradiance levels achieving peak shaving and valley filling effects and enhancing renewable energy utilization. The EKOA algorithm significantly reduced curtailment rates of wind and solar power generation while achieving substantial economic benefits. Compared with other operation modes of hydrogen the daily average cost is reduced by 12.92% and external electricity purchases are reduced by an average of 20.2 MW h/day. Discussion: Although our approach shows potential in improving energy utilization efficiency and economic gains this paper only considered hydrogen energy for single-use pathways and did not account for the economic benefits from selling hydrogen in the market. Future research will further incorporate hydrogen demand response mechanisms and optimize the output of integrated energy systems from the perspective of spot markets. These findings provide valuable references for relevant engineering applications.
Gamified Learning for Sustainability: An Innovative Approach to Enhance Hydrogen Literacy and Environmental Awareness Through Simulation-Based Education
Mar 2025
Publication
The transition to sustainable energy systems presents a critical challenge for the 21st century necessitating both technological advancements and transformative educational strategies to foster awareness and knowledge. Hydrogen technologies are pivotal for decarbonization yet public understanding and acceptance remain limited. This study introduces and evaluates a novel gamified educational framework uniquely integrating simulationbased learning collaborative problem-solving and adaptive instructional scaffolding to enhance hydrogen literacy and sustainability awareness. Unlike traditional pedagogical approaches this method actively engages learners in real-world decision-making scenarios bridging the gap between theoretical knowledge and practical applications. This study involved adolescents aged 13–15 from two distinct educational and cultural contexts one in Europe and one in the Middle East. A pre–post study design assessed knowledge acquisition gamification engagement and environmental awareness shifts. Findings reveal statistically significant improvements in technical knowledge and strong positive perceptions of gamified learning as an effective sustainability education tool across both cultural groups (Europe and the Middle East). Variations in engagement across cultural contexts suggest the need for adaptive context-sensitive educational frameworks. While the findings indicate significant short-term knowledge gains this study does not assess long-term knowledge retention which remains an important area for future research. This research contributes to sustainability education by demonstrating how strategically designed gamification can foster behavioral engagement enhance environmental literacy and support the global energy transition agenda. This study offers a pioneering perspective on integrating interactive learning methodologies to cultivate sustainability competencies among younger generations.
Integrated Energy Storage and Transmission Solutions: Evaluating hydrogen, Ammonia, and Compressed Air for Offshore Wind Power Delivery
Mar 2025
Publication
This paper introduces a novel dual-purpose transmission system that integrates power transmission and energy storage using hydrogen ammonia and compressed air—an area largely unexplored in the literature. Unlike conventional cable transmission which requires separate storage infrastructure the proposed approach leverages the transmission medium itself as an energy storage solution enhancing system efficiency and reducing costs. By incorporating a defined storage allocation factor this study examines the delivery of offshore-generated power to onshore locations calculating the necessary media flow rates and evaluating the required transportation infrastructure including tunnels and pipelines. A comparative cost-effectiveness analysis is conducted to determine optimal conditions under which storage-integrated transmission outperforms conventional cable transmission. Various transmission powers storage fractions pressures and distances are analysed to assess feasibility and economic viability. The findings indicate that for a 75 % storage allocation factor compressed air can transmit up to 450 MW over 300 km more cost-effectively than cables while hydrogen enables 230 MW transmission beyond 310 km. Ammonia proves to be the most efficient facilitating the transmission of over 2000 MW across distances exceeding 140 km at a lower cost than cables all without requiring onshore storage. Moreover for a 500-km transmission line compressed air hydrogen and ammonia can store the equivalent of 62 58 and 152 h of wind farm output respectively significantly reducing the need for additional onshore storage. This study fills a critical research gap by optimizing offshore wind power delivery through an innovative cost-effective and scalable transmission and storage approach.
Synergies Between Green Hydrogen and Renewable Energy in South Africa
Aug 2025
Publication
South Africa has excellent conditions for renewable energy generation making it well placed to produce green hydrogen for both domestic use and export. In building a green hydrogen economy around export markets it will face competition from countries with equivalent or better resources and/or that are located closer to export markets (e.g. in North Africa and the Middle East) or have lower capital costs (developed markets like Australia and Canada). South Africa however has an extensive energy system with unserved electricity demand. The ability to trade electricity with the national grid (feeding into the grid during times of peak dedicated renewable energy supply and extracting from the grid during times of low dedicated renewable energy availability) could reduce the cost of producing green hydrogen by as much as 10–25 %. This paper explores the opportunity for South African green hydrogen producers presented by the electricity supply crisis that has been ongoing since 2007. It highlights the potential for a mutually reinforcing growth cycle between renewable energy and green hydrogen to be established which will contribute not only to the mitigation of greenhouse gas emissions but to the local economy and broader society.
Progress on Research and Application of Energy and Power Systems for Inland Waterway Vessels: A Case Study of the Yangtze River in China
Aug 2025
Publication
This study focuses on the power systems of inland waterway vessels in Chinese Yangtze River systematically outlining the low-carbon technology pathways for different power system types. A comparative analysis is conducted on the technical feasibility emission reduction potential and economic viability of LNG methanol ammonia pure electric and hybrid power systems revealing the bottlenecks hindering the large-scale application of each system. Key findings indicate that: (1) LNG and methanol fuels offer significant short-term emission reductions in internal combustion engine power systems yet face constraints from methane slip and insufficient green methanol production capacity respectively; (2) ammonia enables zero-carbon operations but requires breakthroughs in combustion stability and synergistic control of NOX; (3) electric vessels show high decarbonization potential but battery energy density limits their range while PEMFC lifespan constraints and SOFC thermal management deficiencies impede commercialization; (4) hybrid/range-extended power systems with superior energy efficiency and lower retrofitting costs serve as transitional solutions for existing vessels though challenged by inadequate energy management strategies and multi-equipment communication protocol interoperability. A phased transition pathway is proposed: LNG/methanol engines and hybrid systems dominate during 2025–2030; ammonia-powered systems and solid-state batteries scale during 2030–2035; post-2035 operations achieve zero-carbon shipping via green hydrogen/ammonia.
Hydrogen Mole Fraction Distributions Inferred from Inverse-LIF Measurements on High-pressure Hydrogen Injections
Oct 2025
Publication
The mixing of fuel and ambient in a compression-igniting combustion engine is a critical process affecting ignition delay burn duration and cycle efficiency. This study aims to visualize and quantify hydrogen mole fraction distributions resulting from high-pressure (10 MPa) hydrogen injections into an inert pressurized (1 MPa) nitrogen ambient at room temperature. Using inverse planar laser-induced fluorescence in which the ambient rather than the jet is seeded with a fluorescent tracer two different injectors (nozzle hole sizes of 0.55 and 0.65 mm) and two different tracers (toluene and acetone) are compared. It is concluded that a non-intensified CCD camera for fluorescence detection is superior to the use of an intensified one due to the linear behavior on contrast. The two injectors produce similar jets in terms of jet penetration and angle. Jet penetration derived from inverse-LIF measurements agree with Schlieren data on nominally the same jets but the hydrogen mole fractions are generally 2.5-5 percent lower than those obtained by planar Rayleigh scattering. Quasi-steadiness and self-similarity were found for ensemble-averaged mole fraction distributions of both injectors which aligns with theory and highlights the importance of using RANS simulations or time-averaged experiments for future comparisons.
Multi-Fuel SOFC System Modeling for Ship Propulsion: Comparative Performance Analysis and Feasibility Assessment of Ammonia, Methanol and Hydrogen as Marine Fuels
Oct 2025
Publication
To reduce fossil fuel dependency in shipping adopting alternative fuels and innovative propulsion systems is essential. Solid Oxide Fuel Cells (SOFC) powered by hydrogen carriers represent a promising solution. This study investigates a multi-fuel SOFC system for ocean-going vessels capable of operating with ammonia methanol or hydrogen thus enhancing bunkering flexibility. A thermodynamic model is developed to simulate the performance of a 3 kW small-scale system subsequently scaling up to a 10 MW configuration to meet the power demand of a container ship used as the case study. Results show that methanol is the most efficient fueling option reaching a system efficiency of 58% while ammonia and hydrogen reach slightly lower values of about 55% and 51% respectively due to higher auxiliary power consumption. To assess technical feasibility two installation scenarios are considered for accommodating multiple fuel tanks. The first scenario seeks the optimal fuel share equivalent to the diesel tank’s chemical energy (17.6 GWh) minimizing mass increase. The second scenario optimizes the fuel share within the available tank volume (1646 m3 ) again minimizing mass penalties. In both cases feasibility results have highlighted that changes are needed in terms of cargo reduction equal to 20.3% or alternatively in terms of lower autonomy with an increase in refueling stops. These issues can be mitigated by the benefits of increased bunkering flexibility
Quantifying Natural Hydrogen Generation Rates and Volumetric Potential in Onshore Serpentinization
Mar 2025
Publication
This study explores the generation of natural hydrogen through the serpentinization of onshore ultramafic rocks highlighting its potential as a clean energy resource. By investigating critical factors such as mineral composition temperature and pressure the research develops an empirical model using multiple regression analysis to predict hydrogen generation rates under varying geological conditions. A novel five-stage volumetric calculation methodology is introduced to estimate hydrogen production from ultramafic rock bodies. The application of this framework to the Giles Complex an ultramafic-mafic intrusion in Australia suggests a hydrogen generation potential of approximately 2.24 × 1013 kg of hydrogen through partial serpentinization. This estimate is based on the assumed mineral composition depth and temperature conditions within the intrusion which influence the extent of serpentinization reactions. The findings demonstrate the significant potential of ultramafic complexes for natural hydrogen production and provide a foundation for advancing natural hydrogen exploration refining predictive models and supporting sustainable energy development.
The Link Between Microstructural Heterogeneity and Hydrogen Redistribution
Jul 2025
Publication
Green hydrogen is likely to play a major role in decarbonising the aviation industry. It is crucial to understand the effects of microstructure on hydrogen redistribution which may be implicated in the embrittlement of candidate fuel system metals. We have developed a multiscale finite element modelling framework that integrates micromechanical and hydrogen transport models such that the dominant microstructural effects can be efficiently accounted for at millimetre length scales. Our results show that microstructure has a significant effect on hydrogen localisation in elastically anisotropic materials which exhibit an interesting interplay between microstructure and millimetre-scale hydrogen redistribution at various loading rates. Considering 316L stainless steel and nickel a direct comparison of model predictions against experimental hydrogen embrittlement data reveals that the reported sensitivity to loading rate may be strongly linked with rate-dependent grain scale diffusion. These findings highlight the need to incorporate microstructural characteristics in hydrogen embrittlement models.
Modeling and Simulation of Coupled Biochemical and Two-phase Compositional Flow in Underground Hydrogen Storage
Aug 2025
Publication
Integrating microbial activity into underground hydrogen storage models is crucial for simulating longterm reservoir behavior. In this work we present a coupled framework that incorporates bio-geochemical reactions and compositional flow models within the Matlab Reservoir Simulation Toolbox (MRST). Microbial growth and decay are modeled using a double Monod formulation with populations influenced by hydrogen and carbon dioxide availability. First a refined Equation of State (EoS) is employed to accurately capture hydrogen dissolution thereby improving phase behavior and modeling of microbial activity. The model is then discretized using a cell-centered finite-volume method with implicit Euler time discretization. A fully coupled fully implicit strategy is considered. Our implementation builds upon MRST’s compositional module by incorporating the Søreide–Whitson EoS microbial reaction kinetics and specific effects such as bio-clogging and molecular diffusion. Through a series of 1D 2D and 3D simulations we analyze the effects of microbialinduced bio-geochemical transformations on underground hydrogen storage in porous media.These results highlight that accounting for bio-geochemical effects can substantially impact hydrogen loss purity and overall storage performance.
Comprehensive Review of Emerging Trends in Thermal Energy Storage Mechanisms, Materials and Applications
Aug 2025
Publication
Thermal energy storage (TES) technologies are emerging as key enablers of sustainable energy systems by providing flexibility and efficiency in managing thermal resources across diverse applications. This review comprehensively examines the latest advancements in TES mechanisms materials and structural designs including sensible heat latent heat and thermochemical storage systems. Recent innovations in nano-enhanced phase change materials (PCMs) hybrid TES configurations and intelligent system integration are highlighted. The role of advanced computational methods such as digital twins and AI-based optimization in enhancing TES performance is also explored. Applications in renewable energy systems industrial processes district heating networks and green hydrogen production are discussed along with associated challenges and future research directions. This review aims to synthesize current knowledge while identifying pathways for accelerating the development and practical deployment of next-generation TES technologies.
Feasibility of Using Rainwater for Hydrogen Production via Electrolysis: Experimental Evaluation and Ionic Analysis
Oct 2025
Publication
This study evaluates the feasibility of employing rainwater as an alternative feedstock for hydrogen production via electrolysis. While conventional systems typically rely on high-purity water—such as deionized or distilled variants—these can be cost-prohibitive and environmentally intensive. Rainwater being naturally available and minimally treated presents a potential sustainable alternative. In this work a series of comparative experiments was conducted using a proton exchange membrane electrolyzer system operating with both deionized water and rainwater collected from different Austrian locations. The chemical composition of rainwater samples was assessed through inductively coupled plasma ion chromatography and visual rapid tests to identify impurities and ionic profiles. The electrolyzer’s performance was evaluated under equivalent operating conditions. Results indicate that rainwater in some cases yielded comparable or marginally superior efficiency compared to deionized water attributed to its inherent ionic content. The study also examines the operational risks linked to trace contaminants and explores possible strategies for their mitigation.
Hydrogen-Based Solutions for Enhancing Frequency Stability in Renewable Energy-Integrated Power Systems
Mar 2025
Publication
With the increasing adoption of renewable energy sources such as solar and wind power it is essential to achieve carbon neutrality. However several shortcomings including their intermittence pose significant challenges to the stability of the electrical grid. This study explores hydrogen-based technologies such as fuel cells and water electrolysis systems as an effective solution to improve frequency stability and address the problems of power grid reliability. Using power system analysis programs modeling and simulations performed on IEEE-25 Bus and Jeju Island systems demonstrate the potential of these technologies to mitigate reductions reduce transmission constraints and stabilize frequencies. The results show that hydrogen-based systems are important factors enabling sustainable energy transition.
Market Readiness Analysis: Expected Uptake of Alternative Fuel Heavy-duty Vehicles until 2030 and their Corresponding Infrastructure Needs
Jun 2025
Publication
This report assesses the market readiness of zero-emission heavy-duty vehicles and the required infrastructure to meet the 45% emission reduction targets set by the revised CO2 standards by 2030. Achieving these goals requires the widespread adoption of zero-emission vehicles and a robust recharging and hydrogen refuelling infrastructure Three main aspects are investigated: the market readiness of the vehicles considering both the demand and supply side the corresponding infrastructure requirements and the barriers. Building on the inputs of the stakeholders a ‘study scenario’ is developed. This scenario shows a concrete picture of what the zero-emission heavy-duty vehicle fleet and its infrastructure requirement could look like by 2030. There are however key barriers that need to be overcome such as high total cost of ownership limited electricity grid capacity lengthy permitting processes and uncertainty in hydrogen availability and pricing. Stakeholders also emphasize the importance of policy drivers such as emissions trading systems and tolling and tax reforms to stimulate demand. In conclusion achieving the 2030 targets demands a coordinated approach involving manufacturers operators and policymakers to address infrastructure gaps market barriers and policy incentives ensuring the transition to a zero-emission HDV fleet.
A Study on Thermal Management Systems for Fuel-Cell Powered Regional Aircraft
Jun 2025
Publication
This work studies the feasibility of integrating a hydrogen-powered propulsion system in a regional aircraft at the conceptual design level. The developed system consists of fuel cells which will be studied at three technological levels and batteries also studied for four hybridization factors (X = 0 0.05 0.10 0.20). Hydrogen can absorb great thermal loads since it is stored in the tank at cryogenic temperatures and is used as fuel in the fuel cells at around 80 ◦C. Taking advantage of this characteristic two thermal management system (TMS) architectures were developed to ensure the proper functioning of the aircraft during the designated mission: A1 which includes a vapor compression system (VCS) and A2 which omits it for a simpler design. The models were developed in MATLAB® and consist of different components and technologies commonly used in such systems. The analysis reveals that A2 due to the exclusion of the VCS outperformed A1 in weight (10–23% reduction) energy consumption and drag. A1’s TMS required significantly more energy due to the VCS compressor. Hybridization with batteries increased system weight substantially (up to 37% in A2) and had a greater impact on energy consumption in A2 due to additional fan work. Hydrogen’s heat sink capacity remained underutilized and the hydrogen tank was deemed suitable for a non-integral fuselage design. A2 had the lowest emissions (10–20% lower than A1 for X = 0) but hybridization negated these benefits significantly increasing emissions in pessimistic scenarios.
Hydrogen Storage Potential of Unlined Granite Rock Caverns: Experimental and Numerical Investigations on Geochemical Interactions
Jun 2025
Publication
Underground Hydrogen Storage (UHS) offers a promising solution for large-scale energy storage yet suitable geological formations are often scarce. Unlined rock caverns (URCs) constructed in crystalline rocks like granite present a novel alternative particularly in regions where salt caverns or porous media are unsuitable. Despite their potential URCs remain largely unexplored for hydrogen storage. This study addresses this gap by providing one of the first comprehensive investigations into the geochemical interactions between hydrogen and granite host rock using a combined experimental and numerical approach. Granite powder samples were exposed to hydrogen and inert gas (N₂) in brine at room temperature and 5 MPa pressure for 14 weeks. Results showed minimal reactivity of silicate minerals with hydrogen indicated by negligible differences in elemental concentrations between H₂ and N₂ atmospheres. A validated geochemical model demonstrated that existing thermodynamic databases can accurately predict silicate‑hydrogen interactions. Additionally a kinetic batch model was developed to simulate long-term hydrogen storage under commercial URC conditions at Haje. The model predicts a modest 0.65 % increase in mineral volume over 100 years due to mineral precipitation which decreases net porosity and potentially enhances hydrogen containment by limiting leakage pathways. These findings support the feasibility of granite URCs for UHS providing a stable long-term storage option in regions lacking traditional geological formations. By filling a critical knowledge gap this study advances scalable hydrogen storage solutions contributing to the development of resilient renewable energy infrastructure.
Modeling Homogeneous, Stratified, and Diffusion Combustion in Hydrogen SI Engines Using the Wiebe Approach
Jun 2025
Publication
The use of hydrogen as a fuel for piston engines enables environmentally friendly and efficient operation. However several challenges arise in the combustion process limiting the development of hydrogen engines. These challenges include abnormal combustion the high burning velocity of hydrogen-enriched mixtures increased nitrogen oxide emissions and others. A rational organization of hydrogen combustion can partially or fully mitigate these issues through the use of advanced methods such as late direct injection charge stratification dual injection jet-guided operation and others. However mathematical models describing hydrogen combustion for these methods are still under development complicating the optimization and refinement of hydrogen engines. Previously we proposed a mathematical model based on Wiebe functions to describe premixed and diffusion combustion as well as relatively slow combustion in lean-mixture zones behind the flame front and near-wall regions. This study further develops the model by accounting for the combined influence of the mixture composition and engine speed mixture stratification and the effects of injection and ignition parameters on premixed and diffusion combustion. Special attention is given to combustion modeling in an engine with single injection and jet-guided operation.
Experimental Study on the Effects of Injection Pressure and Injection Timing on Combustion and Emissions in a Direct-injection Hydrogen Engine
Oct 2025
Publication
Hydrogen internal combustion engines are pivotal components of the power industry for achieving zero-carbon emissions. However the development of hydrogen engines is still in its infancy and experimental research on their injection strategies lacks systematization. In this study the individual impacts of hydrogen injection pressure (within low-pressure ranges) and injection timing as well as their coupling effects on combustion characteristics engine efficiency and exhaust emissions were experimentally investigated. Results show that under fixed timing an injection pressure of 25–27.5 bar yields the highest and earliest peak in-cylinder pressures whereas at 15 bar the ignition delay increases to 14.7°CA the flame development duration extends to 8.57°CA and the late combustion duration shortens to 41.37°CA; the exhaust gas temperature peaks at 628 K at 20 bar and NOX peaks at 537 ppm at 25 bar. BTE (brake thermal efficiency) exhibits a U-shaped relationship with pressure with the minimum efficiency occurring near 25 bar when timing is held constant; advancing start of injection from 130° BTDC to 170° BTDC reduces both NOX and exhaust gas temperature with the optimal fuel economy at 140° BTDC and a peak in-cylinder pressure that is approximately 7 % higher and occurs 2–3°CA earlier at 130–140° BTDC. In the pressure–timing maps IMEP (indicated mean effective pressure) is maximized at 30 bar and 90° BTDC; BTE reaches 33.5 % at 25 bar and 100° BTDC; NOX attains a minimum at 25 bar and 110° BTDC while the exhaust gas temperature is lowest at 25 bar and 120° BTDC. Injection pressure is the primary lever for regulating fuel economy and emissions while injection timing mainly adjusts combustion phasing and IMEP. The results provide clear guidance for calibrating low-pressure hydrogen injection systems supply benchmark data for model validation and support the development of practical control strategies for hydrogen engines.
Potential Vulnerability of US Green Hydrogen in a World of Interdependent Networks
Jul 2025
Publication
Green hydrogen is viewed as a promising pathway to future decarbonized energy systems. However hydrogen production depends on a few critical minerals particularly platinum and iridium. Here we examine how the supply of these minerals is subject to vulnerabilities hidden in interdependent global networks of trade and investment. We develop an index to quantify these vulnerabilities for a combination of a target country an investing country an intermediary country and a commodity. Focusing on the US as the target country for the import of platinum and iridium we show how vulnerability-inducing investing countries changed between 2010 and 2019. We find that the UK is consistently among investing countries that can potentially induce US vulnerabilities via intermediary exporters of platinum and iridium with South Africa being the primary intermediary country. Future research includes incorporating geopolitical factors and technological innovations to move the index closer from potential to real-world vulnerabilities.
Equipment Sizing and Operation Strategy of Photovoltaic-Powered Hydrogen Refueling Station Based on AE-PEM Coupled Hydrogen Production
Mar 2025
Publication
With the global commercialization of hydrogen fuel cell vehicles the number of hydrogen refueling stations is steadily increasing. On-site hydrogen production stations are expected to play a key role in future power systems by absorbing renewable energy and supplying electricity during peak grid loads aiding in peak shaving and load leveling. However renewable energy sources like photovoltaic (PV) systems have highly fluctuating power generation curves making it difficult to provide stable energy for hydrogen production. Traditional stations mainly use alkaline electrolyzers (AE) which are sensitive to power fluctuations leading to operational instability. To address this this paper proposes using capacitors and energy storage batteries to mitigate PV fluctuations and introduces a combined AE and Proton Exchange Membrane (PEM) electrolyzer hydrogen production method. Study cases demonstrate that capacitors and energy storage batteries reduce the variance of PV power output by approximately 0.02. Building on this the hybrid approach leverages the low cost of AE and the rapid response of PEM electrolyzers to better adapt to PV fluctuations and maximize PV absorption. The model is mathematically formulated and the station’s equipment planning and operational strategy are optimized using CPLEX. The results show that compared to pure AE and PEM hydrogen production the combined AE and PEM hydrogen production method reduces the total annual cost of the hydrogen refueling station by 4.3% and 5.9% respectively.
Machine Learning for the Optimization and Performance Prediction of Solid Oxide Electrolysis Cells: A Review
Mar 2025
Publication
Solid oxide electrolysis cells (SOECs) represent a promising technology because they have the potential to achieve greater efficiency than existing electrolysis methods making them a strong candidate for sustainable hydrogen production. SOECs utilize a solid oxide electrolyte which facilitates the migration of oxygen ions while maintaining gas impermeability at temperatures between 600 ◦C and 900 ◦C. This review provides an overview of the recent advancements in research and development at the intersection of machine learning and SOECs technology. It emphasizes how data-driven methods can improve performance prediction facilitate material discovery and enhance operational efficiency with a particular focus on materials for cathode-supported cells. This paper also addresses the challenges associated with implementing machine learning for SOECs such as data scarcity and the need for robust validation techniques. This paper aims to address challenges related to material degradation and the intricate electrochemical behaviors observed in SOECs. It provides a description of the reactions that may be involved in the degradation mechanisms taking into account thermodynamic and kinetic factors. This information is utilized to construct a fault tree which helps categorize various faults and enhances understanding of the relationship between their causes and symptoms.
A Cost-Optimizing Analysis of Energy Storage Technologies and Transmission Lines for Decarbonizing the UK Power System by 2035
Mar 2025
Publication
The UK net zero strategy aims to fully decarbonize the power system by 2035 anticipating a 40–60% increase in demand due to the growing electrification of the transport and heating sectors over the next thirteen years. This paper provides a detailed technical and economic analysis of the role of energy storage technologies and transmission lines in balancing the power system amidst large shares of intermittent renewable energy generation. The analysis is conducted using the cost-optimizing energy system modelling framework REMix developed by the German Aerospace Center (DLR). The obtained results of multiple optimization scenarios indicate that achieving the lowest system cost with a 73% share of electricity generated by renewable energy sources is feasible only if planning rules in England and Wales are flexible enough to allow the construction of 53 GW of onshore wind capacity. This flexibility would enable the UK to become a net electricity exporter assuming an electricity trading market with neighbouring countries. Depending on the scenario 2.4–11.8 TWh of energy storage supplies an average of 11% of the electricity feed-in with underground hydrogen storage representing more than 80% of that total capacity. In terms of storage converter capacity the optimal mix ranges from 32 to 34 GW of lithium-ion batteries 13 to 22 GW of adiabatic compressed air energy storage 4 to 24 GW of underground hydrogen storage and 6 GW of pumped hydro. Decarbonizing the UK power system by 2035 is estimated to cost $37–56 billion USD with energy storage accounting for 38% of the total system cost. Transmission lines supply 10–17% of the total electricity feed-in demonstrating that when coupled with energy storage it is possible to reduce the installed capacity of conventional power plants by increasing the utilization of remote renewable generation assets and avoiding curtailment during peak generation times.
The Hydrogen Challenge: Addressing Storage, Safety, and Environmental Concerns in the Hydrogen Economy
Aug 2025
Publication
As part of global decarbonization efforts hydrogen has emerged as a key energy carrier that can achieve deep emission reductions in various sectors. This review critically assesses the role of hydrogen in the low-carbon energy transition and highlights the interlinked challenges within the Techno-Enviro-Socio-Political (TESP) framework. It examines key aspects of deployment including production storage safety environmental impacts and socio-political factors to present an integrated view of the opportunities and barriers to large-scale adoption. Despite growing global interest over 90 % of the current global hydrogen production originated from fossilbased processes resulting in around 920 Mt of CO2 emissions two-thirds of which were attributable to fossil fuels. The Life Cycle Assessment (LCA) shows that coal-based electrolysis resulted in the highest GHG emission (144 - 1033 g CO2-eq/MJ) and an energy consumption (1.55–10.33 MJ/MJ H2). Without a switch to low-carbon electricity electrolysis cannot deliver significant climate benefits. Conversely methanol steam reforming based on renewable feedstock offered the lowest GHG intensity (23.17 g CO2-eq/MJ) and energy demand (0.23 MJ/ MJ) while biogas reforming proved to be a practical short-term option with moderate emissions (51.5 g CO2-eq/ MJ) and favourable energy figures. Catalytic ammonia cracking which is suitable for long-distance transport represents a compromise between low energy consumption (2.93 MJ/MJ) and high water intensity (8.34 L/km). The thermophysical properties of hydrogen including its low molecular weight high diffusivity and easy flammability lead to significant safety risks during storage and distribution which are exacerbated by its sensitivity to ignition and jet pulse effects. The findings show that a viable hydrogen economy requires integrated strategies that combine decarbonised production scalable storage harmonised safety protocols and cross-sector stakeholder engagement for better public acceptance. This review sets out a multi-dimensional approach to guide technological innovation policy adaptation and infrastructure readiness to support a scalable and environmentally sustainable hydrogen economy.
Understanding the Framing of Hydrogen Technology: A Cross-national Content Analysis of Newspaper Coverage in Germany, Saudi Arabia, UAE, and Egypt
Jul 2025
Publication
Introduction: The implementation of national hydrogen strategies targeting zero-emission goals has sparked public discussions regarding energy and environmental communication. However gaining societal acceptance for hydrogen technology poses a significant challenge in numerous countries. Hence this research investigates the framing of hydrogen technology through a comparative analysis of opinion-leading newspapers in Germany Saudi Arabia the United Arab Emirates and Egypt. Methods: Utilizing a quantitative framing analysis based on Entman’s framing approach this research systematically identifies media frames and comprehend their development through specific frame characteristics. A factor analysis identified six distinct frames: Hydrogen as a Sustainable Energy Solution Benefits of Economic and Political Collaboration Technological and Scientific Challenges Governance Issues and Energy Security Industrial and Climate Solutions and Economic Risk. Results: The findings reveal that newspapers frames vary significantly due to contextual factors such as national hydrogen strategies media systems political ideologies article types and focusing events. Specifically German newspapers display diverse and balanced framing in line with its pluralistic media environment and national emphasis on green hydrogen and energy security while newspapers from MENA countries primarily highlight economic and geopolitical benefits aligned with their national strategies and state-controlled media environments. Additionally the political orientation of newspapers affects the diversity of frames particularly in Germany. Moreover non-opinion articles in Germany exhibit greater framing diversity compared to opinion pieces while in the MENA region the framing remains uniform regardless of article type due to centralized media governance. A notable shift in media framing in Germany was found after a significant geopolitical event which changed the frame from climate mitigation to energy security. Discussion: This study underscores the necessity for theoretical and methodological thoroughness in identifying frames as well as the considerable impact of contextual factors on the media representation of emerging sustainable technologies.
A Review on Green Hydrogen Production by Aqueous Phase Reforming of Lignocellulose and Derivatives
Mar 2025
Publication
With the intensification of the global energy crisis hydrogen has attracted significant attention as a high-energy-density and zero-emission clean energy source. Traditional hydrogen production methods are dependent on fossil fuels and simultaneously contribute to environmental pollution. The aqueous phase reforming (APR) of renewable biomass and its derivatives has emerged as a research hotspot in recent years due to its ability to produce green hydrogen in an environmentally friendly manner. This review provides an overview of the advancements in APR of lignocellulosic biomass as a sustainable and environmentally friendly method for hydrogen production. It focuses on the reaction pathways of various biomass feedstocks (such as glucose cellulose and lignin) as well as the types and performance of catalysts used in the APR process. Finally the current challenges and future prospects in this field are briefly discussed.
Simulation of a Hybrid Plant with ICE/HT-PEMFC and On-Site Hydrogen Production from Methane Steam Reforming
Oct 2025
Publication
Hydrogen-based technologies prominently fuel cells are emerging as strategic solutions for decarbonization. They offer an efficient and clean alternative to fossil fuels for electricity generation making a tangible contribution to the European Green Deal climate objectives. The primary issue is the production and transportation of hydrogen. An on-site hydrogen production system that includes CO2 capture could be a viable solution. The proposed power system integrates an internal combustion engine (ICE) with a steam methane reformer (SMR) equipped with a CO2 capture and energy storage system to produce “blue hydrogen”. The hydrogen fuels a high-temperature polymer electrolyte membrane (HTPEM) fuel cell. A battery pack incorporated into the system manages rapid fluctuations in electrical load ensuring stability and continuity of supply and enabling the fuel cell to operate at a fixed point under nominal conditions. This hybrid system utilizes natural gas as its primary source reducing climate-altering emissions and representing an efficient and sustainable solution. The simulation was conducted in two distinct environments: Thermoflex code for the integration of the engine reformer and CO2 capture system; and Matlab/Simulink for fuel cell and battery pack sizing and dynamic system behavior analysis in response to user-demanded load variations with particular attention to energy flow management within the simulated electrical grid. The main results show an overall efficiency of the power system of 39.9% with a 33.5% reduction in CO2 emissions compared to traditional systems based solely on internal combustion engines.
Which Offers Greater Techno-Economic Potential: Oil or Hydrogen Production from Light Oil Reservoirs?
Jun 2025
Publication
The global emphasis on clean energy has increased interest in producing hydrogen from petroleum reservoirs through in situ combustion-based processes. While field practices have demonstrated the feasibility of co-producing hydrogen and oil the question of which offers greater economic potential oil or hydrogen remains central to ongoing discussions especially as researchers explore ways to produce hydrogen exclusively from petroleum reservoirs. This study presents the first integrated techno-economic model comparing oil and hydrogen production under varying injection strategies using CMG STARS for reservoir simulations and GoldSim for economic modeling. Key technical factors including injection compositions well configurations reservoir heterogeneity and formation damage (issues not addressed in previous studies) were analyzed for their impact on hydrogen yield and profitability. The results indicate that CO2-enriched injection strategies enhance hydrogen production but are economically constrained by the high costs of CO2 procurement and recycling. In contrast air injection although less efficient in hydrogen yield provides a more cost-effective alternative. Despite the technological promise of hydrogen oil revenue remains the dominant economic driver with hydrogen co-production facing significant economic challenges unless supported by policy incentives or advancements in gas lifting separation and storage technologies. This study highlights the economic trade-offs and strategic considerations crucial for integrating hydrogen production into conventional petroleum extraction offering valuable insights for optimizing hydrogen co-production in the context of a sustainable energy transition. Additionally while the present work focuses on oil reservoirs future research should extend the approach to natural gas and gas condensate reservoirs which may offer more favorable conditions for hydrogen generation.
Hydrogen Gas Blending in Gasoline GDI Engines: Combustion Analysis and Emission Control
Jun 2025
Publication
This study investigates the effects of varying hydrogen percentages in fuel blends on combustion dynamics engine performance and emissions. Experimental data and analytical equations were used to evaluate combustion parameters such as equivalent lambda in-cylinder pressure heat release rate and ignition timing. The findings demonstrate that hydrogen blending enhances combustion stability shortens ignition delay and shifts peak heat release to be closer to the top dead center (TDC). These changes improve thermal efficiency and reduce cycle-to-cycle variation. Hydrogen blending also significantly lowers carbon dioxide (CO2) and hydrocarbon (HC) emissions particularly at higher blend levels (H0–H5) while lower blends increase nitrogen oxides (NOx) emissions and risk pre-ignition due to advanced start of combustion (SOC). Engine performance improved with an average hydrogen energy contribution of 12% under a constant load. However the optimal hydrogen blending range is crucial to balancing efficiency gains and emission reductions. These results underline the potential of hydrogen as a cleaner additive fuel and the importance of optimizing blend ratios to harness its benefits effectively.
An Expert Opinion-based Perspective on Emerging Policy and Economic Research Priorities for Advancing the Low-carbon Hydrogen Sector
Jun 2025
Publication
This perspective sheds light on emerging research priorities crucial for advancing the low-carbon hydrogen sector considered critical for achieving net zero greenhouse gas emissions targets especially for hard-to-abate sectors. Our analysis follows a five-step process including drawing from news media academic discourse and expert consultations. We identify twenty-one major research challenges. Among the top priorities highlighted by experts are: (i) Evaluating the trade-offs of hydrogen-fueled power generation compared to hydrocarbon fuels and renewables with alternative storage solutions and the feasibility of co-firing hydrogen and ammonia with hydrocarbon fuels for backup or independent power generation; (ii) Exploring how global hydrogen trade could be shaped by market forces such as price volatility geopolitical dynamics and international collaborations; (iii) Examining the financial considerations for investors from developed nations pursuing hydrogen projects in resource-rich developing countries balancing costs investment risks and expected returns. We find statistically significant differences in opinions on hydrogen/ammonia co-firing for power generation between experts from China and those from the U.S. and Germany.
Macroeconomic and Environmental Impacts of Two Decarbonization Options for the Dutch Steel Industry: Green Relocation Versus Green Hydrogen Imports
Jun 2025
Publication
Decarbonizing the steel industry will require a shift towards renewable energy. However costs and emissions associated with the long-distance transport of renewable energy carriers may incentivize the relocation of steel production closer to renewable energy sources. This “green relocation” would affect regional economic structures and global trade patterns. Nevertheless the macroeconomic and environmental impacts of alternative industry location options remain underexplored. This study compares the impacts on value-added prices and emissions under two options for decarbonizing the Dutch steel industry: importing green hydrogen from Brazil to produce green steel in the Netherlands versus relocating production to Brazil and transporting green steel to the Netherlands. Impacts are analyzed by combining a price and a quantity model within an environmentally extended multiregional input-output (EE-MRIO) framework. Results suggest that the relocation option brings the greatest synergies between climate and economic goals at the global level as it leads to lower production costs smaller price effects and greater emissions reductions. However relocation also results in stronger distributive impacts across global regions. Higher carbon prices would be insufficient to counteract relocation incentives. This calls for policymakers in industrialized countries to systematically consider the possibility of green relocation when designing decarbonization and industrial competitiveness strategies.
Sustainable Hydrogen Production from Nuclear Energy
Aug 2025
Publication
The rapid increase in global warming requires that sustainable energy choices aimed at achieving net-zero greenhouse gas emissions be implemented as soon as possible. This objective emerging from the European Green Deal and the UN Climate Action could be achieved by using clean and efficient energy sources such as hydrogen produced from nuclear power. “Renewable” hydrogen plays a fundamental role in decarbonizing both the energy-intensive industrial and transport sectors while addressing the global increase in energy consumption. In recent years several strategies for hydrogen production have been proposed; however nuclear energy seems to be the most promising for applications that could go beyond the sole production of electricity. In particular nuclear advanced reactors that operate at very high temperatures (VHTR) and are characterized by coolant outlet temperatures ranging between 550 and 1000 ◦C seem the most suitable for this purpose. This paper describes the potential use of nuclear energy in coordinated and coupled configurations to support clean hydrogen production. Operating conditions energy requirements and thermodynamic performance are described. Moreover gaps that require additional technology and regulatory developments are outlined. The intermediate heat exchanger which is the key component for the integration of nuclear hybrid energy systems was studied by varying the thermal power to determine physical parameters needed for the feasibility study. The latter consisting of the comparative cost evaluation of some nuclear hydrogen production methods was carried out using the HEEP code developed by the IAEA. Preliminary results are presented and discussed.
Feasibility Assessment and Response Surface Optimisation of a Fuel Cell-integrated Sustainable Wind Farm in Italy
Sep 2025
Publication
This study explores the design and feasibility of a novel fuel cell-powered wind farm for residential electricity hydrogen/oxygen production and cooling/heating via a compression chiller. Wind turbine energy powers Proton Exchange Membrane (PEM) electrolyzers and a compression chiller unit. The proposed system was modeled using EES thermodynamic software and its economic viability was assessed. A case study across seven Italian regions with varying wind potentials evaluated the system’s feasibility in diverse weather conditions. Multi-objective optimization using Response Surface Methodology (RSM) determined the number of wind turbines as optimum number of electrolyzers & fuel cell units. Optimization results indicated that 37 wind turbines 1 fuel cell unit and 2 electrolyzer units yielded an exergy efficiency of 27.98 % and a cost rate of 619.9 $/h. TOPSIS analysis suggested 32 wind turbines 2 electrolyzers and 2 reverse osmosis units as an alternative configuration. Further twelve different scenarios were examined to enhance the distribution of wind farmgenerated electricity among the grid electrolyzers and reverse osmosis systems. revealing that directing 25 % to reverse osmosis 20 % to electrolyzers and 55 % to grid sales was optimal. Performance analysis across seven Italian cities (Turin Bologna Florence Palermo Genoa Milan and Rome) identified Genoa Palermo and Bologna as the most suitable locations due to favorable wind conditions. Implementing the system in Genoa the optimal site could produce 28435 MWh of electricity annually prevent 5801 tons of CO2 emissions (equivalent to 139218 $). Moreover selling this clean electricity to the grid could meet the annual clean electricity needs of approximately 5770 people in Italy
Cooperative Control of Hydrogen-energy Storage Microgrid System Based on Disturbance-rejection Model Predictive Control
Mar 2025
Publication
Model predictive control (MPC) requires high accuracy of the model. However the actual power system has complex dynamic characteristics. There must be unmodeled dynamics in the system modeling process which makes it difficult for MPC to perform the function of optimal control. ESO has the ability to observe and suppress errors combining the both can solve this problem. Thus this paper proposes a coordinated control strategy of hydrogen-energy storage system based on disturbance-rejection model predictive controller. Firstly this paper constructs the state-space model of the system and improves MPC. By connecting ESO and MPC in series this paper designs a matched disturbance-rejection model predictive controller and analyzes the robustness of the research system. Finally this paper verifies the effectiveness and feasibility of the disturbance-rejection model predictive controller under various working conditions. Compared with the method using only MPC the dynamic response time of the system frequency regulation under the proposed strategy in this paper is increased by about 29.9 % and the frequency drop rate is slowed down by 13.5 %. In addition under the AGC command and continuous load disturbance working conditions the maximum frequency deviation of the system under the proposed strategy is reduced by about 54.01 % and 48.96 %. The results clearly show that the proposed strategy in this paper significantly improves the dynamic response ability of the system and reduces the frequency fluctuation of the system after disturbance.
Impact of Plastic Composition on the Performance of the Integrated Process of Pyrolysis and Oxidative Steam Reforming for Hydrogen Production
Aug 2025
Publication
The pyrolysis and oxidative steam reforming (P-OSR) of different types of plastics (HDPE PP PET and PS) has been carried out in a two reactor system provided with a conical spouted bed reactor (CSBR) and a fluidized bed reactor (FBR). The effect plastic composition has on the oxidative steam reforming step has been analyzed using two space time values (3.1 gcatalyst min gplastic − 1 and 12.5 gcatalyst min gplastic − 1 ) at a reforming temperature of 700 ◦C S/P ratio of 3 and ER of 0.2 (optimum conditions for autothermal reforming). The different composition of the plastics leads to differences in the yields and compositions of pyrolysis products and consequently in the performance of the oxidative steam reforming step. High conversions (> 97 %) have been achieved by using a space time of 12.5 gcat min gplastic − 1 with H2 production increasing as follows: PET ≪ PS < HDPE ≤ PP. A maximum H2 production of 25.5 wt% has been obtained by using PP which is lower than that obtained in the process of pyrolysis and in line conventional steam reforming (P-SR) of the same feedstock (34.8 wt%). The lowest H2 production (10.5 wt%) has been achieved when PET was used due to the high oxygen content of this plastic. The results obtained in this study prove that P-OSR performs very well with different feedstock thereby confirming the versatility and efficiency of this process to produce a hydrogen-rich gas.
The Financial Results of Energy Sector Companies in Europe and Their Involvement in Hydrogen Production
Jun 2025
Publication
In response to growing environmental concerns hydrogen production has emerged as a critical element in the transition to a sustainable global economy. We evaluate the impact of hydrogen production on both the financial performance and market value of energy sector companies using balanced panel data from 288 European-listed firms over the period of 2018 to 2022. The findings reveal a paradox. While hydrogen production imposes significant financial constraints it is positively recognized by market participants. Despite short-term financial challenges companies engaged in hydrogen production experience higher market value as investors view these activities as a long-term growth opportunity aligned with global sustainability goals. We contribute to the literature by offering empirical evidence on the financial outcomes and market valuation of hydrogen engagement distinguishing between production and storage activities and further categorizing production into green blue and gray hydrogen. By examining these nuances we highlight the complex relationship between financial market results. While hydrogen production may negatively impact short-term financial performance its potential for long-term value creation driven by decarbonization efforts and sustainability targets makes it attractive to investors. Ultimately this study provides valuable insights into how hydrogen engagement shapes corporate strategies within the evolving European energy landscape.
A Multi-objective Decision-making Framework for Renewable Energy Transportation
Aug 2025
Publication
The mismatch in renewable energy generation potential levelized cost and demand across different geographies highlight the potential of a future global green energy economy through the trade of green fuels. This potential and need call for modeling frameworks to make informed decisions on energy investments operations and regulations. In this work we present a multi-objective optimization framework for modeling and optimizing energy transmission strategies considering different generation locations transportation modes and often conflicting objectives of cost environmental impact and transportation risk. An illustrative case study on supplying renewable energy to Germany demonstrates the utility of the framework across diverse options and trade-offs. Sensitivity analysis reveals that the optimal energy carrier and transmission strategy depend on distance demand and existing infrastructure that can be re-purposed. The framework is adaptable across geographies and scales to offer actionable insights to guide investment operational and regulatory decisions in renewable energy and hydrogen supply chains.
Towards Decarbonizing Gas: A Generic Optimal Gas Flow Model with Linepack Constraints for Assessing the Feasibility of Hydrogen Blending in Existing Gas Networks
Aug 2025
Publication
Hydrogen blending into natural gas networks is a promising pathway to decarbonize the gas sector but requires bespoke fluid-dynamic models to accurately capture the properties of hydrogen and assess its feasibility. This paper introduces a generalizable optimal transient gas flow model for transporting homogeneous natural gashydrogen mixtures in large-scale networks. Designed for preliminary planning the model assesses whether a network can operate under a given hydrogen blending ratio without violating existing constraints such as pressure limits pipeline and compressor capacity. A distinguishing feature of the model is a multi-day linepack management strategy that engenders realistic linepack profiles by precluding mathematically feasible but operationally unrealistic solutions thereby accurately reflecting the flexibility of the gas system. The model is demonstrated on Western Australia’s 7560 km transmission network using real system topology and demand data from several representative days in 2022. Findings reveal that the system can accommodate up to 20 % mol hydrogen potentially decarbonizing 7.80 % of gas demand.
MOF-Derived Electrocatalysts for High-Efficiency Hydrogen Production via Water Electrolysis
Jun 2025
Publication
Water electrolysis for hydrogen production has garnered significant attention in the context of increasing global energy demands and the “dual-carbon” strategy. However practical implementation is hindered by challenges such as high overpotentials high catalysts costs and insufficient catalytic activity. In this study three mono and bimetallic metal−organic framework (MOFs)-derived electrocatalysts Fe-MOFs Fe/Co-MOFs and Fe/Mn-MOFs were synthesized via a one-step hydrothermal method using nitroterephthalic acid (NO2-BDC) as the ligand and NN-dimethylacetamide (DMA) as the solvent. Electrochemical tests demonstrated that the Fe/Mn-MOFs catalyst exhibited superior performance achieving an overpotential of 232.8 mV and a Tafel slope of 59.6 mV·dec−1 alongside the largest electrochemical active surface area (ECSA). In contrast Fe/Co-MOFs displayed moderate catalytic activity while Fe-MOFs exhibited the lowest efficiency. Stability tests revealed that Fe/Mn-MOFs retained 92.3% of its initial current density after 50 h of continuous operation highlighting its excellent durability for the oxygen evolution reaction (OER). These findings emphasize the enhanced catalytic performance of bimetallic MOFs compared to monometallic counterparts and provide valuable insights for the development of high-efficiency MOF-based electrocatalysts for sustainable hydrogen production.
Design and Optimization of a Solar Parabolic Dish for Steam Generation in a Blue Hydrogen Production Plant
Oct 2025
Publication
The integration of renewable energy into industrial processes is crucial for reducing the carbon footprint of conventional hydrogen production. This work presents detailed design optical–thermal simulation and performance analysis of a solar parabolic dish (SPD) system for supplying high-temperature steam to a Steam Methane Reforming (SMR) plant. A 5 m diameter dish with a focal length of 3 m was designed and optimized using COMSOL Multiphysics (version 6.2) and MATLAB (version R2023a). Optical ray tracing confirmed a geometric concentration ratio of 896× effectively focusing solar irradiation onto a helical cavity receiver. Thermal–fluid simulations demonstrated the system’s capability to superheat steam to 551 ◦C at a mass flow rate of 0.0051 kg/s effectively meeting the stringent thermal requirements for SMR. The optimized SPD system with a 5 m dish diameter and 3 m focal length was designed to supply 10% of the total process heat (≈180 GJ/day). This contribution reduces natural gas consumption and leads to annual fuel savings of approximately 141000 SAR (Saudi Riyal) along with a substantial reduction in CO2 emissions. These quantitative results confirm the SPD as both a technically reliable and economically attractive solution for sustainable blue hydrogen production.
Real-Time Energy Management of a Microgrid Using MPC-DDQN-Controlled V2H and H2V Operations with Renewable Energy Integration
Aug 2025
Publication
This paper presents the design and implementation of an Intelligent Home Energy Management System in a smart home. The system is based on an economically decentralized hybrid concept that includes photovoltaic technology a proton exchange membrane fuel cell and a hydrogen refueling station which together provide a reliable secure and clean power supply for smart homes. The proposed design enables power transfer between Vehicle-to-Home (V2H) and Home-to-Vehicle (H2V) systems allowing electric vehicles to function as mobile energy storage devices at the grid level facilitating a more adaptable and autonomous network. Our approach employs Double Deep Q-networks for adaptive control and forecasting. A Multi-Agent System coordinates actions between home appliances energy storage systems electric vehicles and hydrogen power devices to ensure effective and cost-saving energy distribution for users of the smart grid. The design validation is carried out through MATLAB/Simulink-based simulations using meteorological data from Tunis. Ultimately the V2H/H2V system enhances the utilization reliability and cost-effectiveness of residential energy systems compared with other management systems and conventional networks.
Optimal Control of an Over-actuated Spark-Ignited Hydrogen Engine
Jun 2025
Publication
The spark-ignited (SI) hydrogen combustion engine has the potential to noticeably reduce greenhouse gas emissions from passenger cars. To prevent nitrogen oxide emissions and to increase fuel efficiency and power output complex air paths and operating strategies are utilized. This makes the engine control problem more complex challenging the conventional engine calibration process. This work combines and extends the state-of-the-art in real-time combustion engine modeling and optimal control presenting a novel control concept for the efficient operation of a hydrogen combustion engine. The extensive experimental validation with a 1.5 l three-cylinder hydrogen SI engine and a dynamically operated engine test bench with emission and in-cylinder pressure measurements provides a comprehensible comparison to conventional engine control. The results demonstrate that the proposed optimal control decreased the load tracking errors by a factor of up to 2.8 and increased the engine efficiency during lean operation by up to 10 percent while decreasing the calibration effort compared to conventional engine control.
Towards Net-Zero: Comparative Analysis of Hydrogen Infrastructure Development in USA, Canada, Singapore, and Sri Lanka
Sep 2025
Publication
This paper compares national hydrogen (H2) infrastructure plans in Canada the United States (the USA) Singapore and Sri Lanka four countries with varying geographic and economic outlooks but shared targets for reaching net-zero emissions by 2050. It examines how each country approaches hydrogen production pipeline infrastructure policy incentives and international collaboration. Canada focuses on large-scale hydrogen production utilizing natural resources and retrofitted natural gas pipelines supplemented by carbon capture technology. The USA promotes regional hydrogen hubs with federal investment and intersectoral collaboration. Singapore suggests an innovation-based import-dominant strategy featuring hydrogen-compatible infrastructure in a land-constrained region. Sri Lanka maintains an import-facilitated pilot-scale model facilitated by donor funding and foreign collaboration. This study identifies common challenges such as hydrogen embrittlement leakages and infrastructure scalability as well as fundamental differences based on local conditions. Based on these findings strategic frameworks are proposed including scalability adaptability partnership policy architecture digitalization and equity. The findings highlight the importance of localized hydrogen solutions supported by strong international cooperation and international partnerships.
Dissociative Adsorption of Hydrogen in Hydrogen-Blended Natural Gas Pipelines: A First Principles and Thermodynamic Analysis
Jun 2025
Publication
This study employs first principles calculations and thermodynamic analyses to investigate the dissociative adsorption of hydrogen on the Fe(110) surface. The results show that the adsorption energies of hydrogen at different sites on the iron surface are −1.98 eV (top site) −2.63 eV (bridge site) and −2.98 eV (hollow site) with the hollow site being the most stable adsorption position. Thermodynamic analysis further reveals that under operational conditions of 25 ◦C and 12 MPa the Gibbs free energy change (∆G) for hydrogen dissociation is −1.53 eV indicating that the process is spontaneous under pipeline conditions. Moreover as temperature and pressure increase the spontaneity of the adsorption process improves thus enhancing hydrogen transport efficiency in pipelines. These findings provide a theoretical basis for optimizing hydrogen transport technology in natural gas pipelines and offer scientific support for mitigating hydrogen embrittlement improving pipeline material performance and developing future hydrogen transportation strategies and safety measures.
Design and Analysis of Small‑Scale Hydrogen Valleys Success Factors: A Stratified Network‑Based Hybrid Fuzzy Approach
Sep 2025
Publication
Hydrogen energy one of the renewable energy sources plays a crucial role in combating climate change since its usage aims to reduce carbon emissions and enhance energy security. As the global energy trend moves toward cleaner alternatives countries start to adapt their energy strategies. In this transition hydrogen is one of the energy sources with the potential to increase long-term energy security. Developing countries face challenges such as high energy import dependency rising industrial demand and the need for infrastructure modernization making hydrogen valleys one of the viable solutions since they integrate hydrogen production storage distribution and utilization at one facility. However establishing small-scale hydrogen valleys requires a comprehensive decision-making strategy consisting of technical financial environmental social and political factors while addressing uncertainties in the system. To systematically manage the process this study proposes a Z-numberbased fuzzy cognitive mapping approach which models the interdependencies among success factors supported by Z-number Decision-Making Trial and Evaluation Laboratory for structured prioritization with a multi-expert perspective. The results indicate that Financial Factors emerged as the most critical category with Government Incentives Infrastructure Investment Cost and Land Acquisition Cost ranking as the top three sub-success factors. Availability of Skilled Workforce and Regional Energy Supply followed in importance which demonstrates the importance of social and technical dimensions in the hydrogen valley development. These findings demonstrate the critical role of policy support infrastructure readiness and workforce availability in the design process. Sensitivity analyses are also conducted to present robustness of the given decisions for the analysis of the results. Based on the results and analyses possible implications based on the policy and practical dimensions are also discussed. By integrating fuzzy logic and Z-numbers the study aims to minimize loss of information enhances the analytical background for decision-making and provides a strategic roadmap for hydrogen valley development.
A Fuzzy Multi-Criteria Framework for Sustainability Assessment of Wind–Hydrogen Energy Projects: Method and Case Application
Oct 2025
Publication
This study develops a comprehensive framework for assessing the sustainability performance of wind power systems integrated with hydrogen storage (WPCHS). Unlike previous works that mainly emphasized economic or environmental indicators our approach incorporates a balanced set of economic environmental and social criteria supported by expert evaluation. To address the uncertainty in human judgment we introduce an interval-valued fuzzy TOPSIS model that provides a more realistic representation of expert assessments. A case study in Manjil Iran demonstrates the application of the model highlighting that project A4 outperforms other alternatives. The findings show that both economic factors (e.g. levelized cost of energy) and social aspects (e.g. poverty alleviation) strongly influence project rankings. Compared with earlier studies in Europe and the Middle East this work contributes by extending the evaluation scope beyond financial and environmental metrics to include social sustainability thereby enhancing decision-making relevance for policymakers and investors.
Capacity Configuration and Benefit Assessment of Deep-Sea Wind–Hydrogen System Considering Dynamic Hydrogen Price
Sep 2025
Publication
Against the backdrop of the global transition towards clean energy deep-sea wind-power hydrogen production integrates offshore wind with green hydrogen technology. Addressing the technical coupling complexity and the impact of uncertain hydrogen prices this paper develops a capacity optimization model. The model incorporates floating wind turbine output the technical distinctions between alkaline (ALK) electrolyzers and proton exchange membrane (PEM) electrolyzers and the synergy with energy storage. Under three hydrogen price scenarios the results demonstrate that as the price increases from 26 CNY/kg to 30 CNY/kg the optimal ALK capacity decreases from 2.92 MW to 0.29 MW while the PEM capacity increases from 3.51 MW to 5.51 MW. Correspondingly the system’s Net Present Value (NPV) exhibits an upward trend. To address the limitations of traditional methods in handling multi-dimensional benefit correlations and information ambiguity a comprehensive benefit evaluation framework encompassing economic technical environmental and social synergies was constructed. Sensitivity analysis indicates that the comprehensive benefit level falls within a relatively high-efficiency interval. The numerical characteristics an entropy value of 3.29 and a hyper-entropy of 0.85 demonstrate compact result distribution and robust stability validating the applicability and stability of the proposed offshore wind–hydrogen benefit assessment model.
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