Publications
2D MXene: From Synthesis to Storage - Exploring their Potential as Sparking Materials for Hydrogen Storage
Jul 2025
Publication
In the advancing landscape of sustainable energy the development of efficient and reversible hydrogen storage materials operable under ambient conditions remains a critical challenge for material scientists and the broader research community. Hydrogen owing to its exceptionally high energy density is regarded as a leading candidate for facilitating the transition from conventional fossil fuels to cleaner renewable energy systems. However alongside its production the safe and efficient storage of hydrogen presents a significant bottleneck due to its low volumetric density and associated safety concerns.<br/>Conventional storage techniques such as high-pressure compression and cryogenic liquefaction though widely used demand complex infrastructure and carry substantial safety risks. These limitations have steered growing interest toward solid-state hydrogen storage systems that rely on physisorption or chemisorption mechanisms preferably operating near ambient conditions. Consequently the pursuit of materials with favourable thermodynamics and kinetics for reversible hydrogen uptake and release has become imperative. Among the emerging candidates MXenes a class of two-dimensional (2D) materials comprising transition metal carbides nitrides or carbonitrides have garnered significant attention due to their high surface area tuneable surface chemistry and excellent conductivity.<br/>Despite the growing body of literature on hydrogen storage using MXenes a comprehensive evaluation that bridges the gap between theoretical predictions and experimental realities remains limited. This review addresses that gap by critically examining current strategies for solid-state hydrogen storage with a particular emphasis on MXene-based materials. It highlights the influence of synthesis techniques on structural properties discusses the mechanisms of hydrogen interaction with MXene surfaces and evaluates their practical implications in real-world applications. While the potential of MXenes in hydrogen storage is considerable it is not yet fully realized. This article provides an in-depth assessment of the current advancements challenges and future directions for MXene-based materials in the context of hydrogen storage offering valuable insights for both fundamental research and applied energy systems.
Numerical Simulation of the Transport and the Thermodynamic Properties of Imported Natural Gas Inected with Hydrogen in the Manifold
Nov 2023
Publication
Blending hydrogen with natural gas (NG) is an efficient method for transporting hydrogen on a large scale at a low cost. The manifold at the NG initial station is an important piece of equipment that enables the blending of hydrogen with NG. However there are differences in the components and component contents of imported NG from different countries. The components of hydrogen-blended NG can affect the safety and efficiency of transportation through pipeline systems. Therefore numerical simulations were performed to investigate the blending process and changes in the thermodynamic properties of four imported NGs and hydrogen in the manifold. The higher the heavy hydrocarbon content in the imported NG the longer the distance required for the gas to mix uniformly with hydrogen in the pipeline. Hydrogen blending reduces the temperature and density of NG. The gas composition is the main factor affecting the molar calorific value of a gas mixture and hydrogen blending reduces the molar calorific value of NG. The larger the content of high-molar calorific components in the imported NG the higher the molar calorific value of the gas after hydrogen blending. Increasing both the temperature and hydrogen mixing ratio reduces the Joule-Thomson coefficient of the hydrogen-blended NG. The results of this study provide technical references for the transport of hydrogen-blended NG.
An Estimation of Green Hydrogen Generation from Wind Energy: A Case Study from KSA
Sep 2023
Publication
Actually green hydrogen is viewed as a fundamental component in accelerating energy transition and empowering a sustainable future. The current study focuses on the estimation of green hydrogen generation by using wind energy via electrolysis in four sites located in Saudi Arabia. Results showed that the yearly amount of hydrogen that could be generated by using wind turbine ranges between 2542877 kg in Rafha and 3676925 kg in Dhahran. The hydrogen generated could be used to fuel vehicles and decrease the amount of GHG emission from vehicles in KSA. Also hydrogen may be used to store the excess of wind energy and to support the achievement of vision 2030 of the Kingdom. An economic assessment is carried out also in this paper. Results showed that the LCOH by using wind energy in KSA ranges from 2.82 $/kg to 3.81 $/kg.
Charting the Course: Navigating Decarbonisation Pathways in Greece, Germany, The Netherlands, and Spain’s Industrial Sectors
Jul 2024
Publication
In the quest for a sustainable future energy-intensive industries (EIIs) stand at the forefront of Europe’s decarbonisation mission. Despite their significant emissions footprint the path to comprehensive decarbonisation remains elusive at EU and national levels. This study scrutinises key sectors such as non-ferrous metals steel cement lime chemicals fertilisers ceramics and glass. It maps out their current environmental impact and potential for mitigation through innovative strategies. The analysis spans across Spain Greece Germany and the Netherlands highlighting sector-specific ecosystems and the technological breakthroughs shaping them. It addresses the urgency for the industry-wide adoption of electrification the utilisation of green hydrogen biomass bio-based or synthetic fuels and the deployment of carbon capture utilisation and storage to ensure a smooth transition. Investment decisions in EIIs will depend on predictable economic and regulatory landscapes. This analysis discusses the risks associated with continued investment in high-emission technologies which may lead to premature decommissioning and significant economic repercussions. It presents a dichotomy: invest in climate-neutral technologies now or face the closure and offshoring of operations later with consequences for employment. This open discussion concludes that while the technology for near-complete climate neutrality in EIIs exists and is rapidly advancing the higher costs compared to conventional methods pose a significant barrier. Without the ability to pass these costs to consumers the adoption of such technologies is stifled. Therefore it calls for decisive political commitment to support the industry’s transition ensuring a greener more resilient future for Europe’s industrial backbone.
Towards the Design of a Hydrogen-powered Ferry for Cleaner Passenger Transport
Aug 2024
Publication
The maritime transportation sector is a large and growing contributor of greenhouse gas and other emissions. Therefore stringent measures have been taken by the International Maritime Organization to mitigate the environmental impact of the international shipping. These lead to the adoption of new technical solutions involving clean fuels such as hydrogen and high efficiency propulsion technologies that is fuel cells. In this framework this paper proposes a methodological approach aimed at supporting the retrofit design process of a car-passenger ferry operating in the Greece’s western maritime zone whose conventional powertrain is replaced with a fuel cell hybrid system. To this aim first the energy/power requirements and the expected hydrogen consumption of the vessel are determined basing on a typical operational profile retrieved from data provided by the shipping company. Three hybrid powertrain configurations are then proposed where fuel cell and batteries are balanced out according to different design criteria. Hence a new vessel layout is defined for each of the considered options by taking into account on-board weight and space constraints to allocate the components of the new hydrogen-based propulsion systems. Finally the developed vessel configurations are simulated in a virtual towing tank environment in order to assess their hydrodynamic response and compare them with the original one thus providing crucial insights for the design process of new hydrogen-fueled vessel solutions. Findings from this study reveal that the hydrogen-based configurations of the vessel are all characterized by a slight reduction of the payload mainly due to the space required to allocate the hydrogen storage system; instead the hydrodynamic behavior of the H2 powered vessels is found to be similar to the one of the original Diesel configuration; also from a hydrodynamic point of view the results show that mid load operating conditions get relevance for the design process of the hybrid vessels.
The Role of Hydrogen in the Energy Mix: A Scenario Analysis for Turkey Using OSeMOSYS
Dec 2024
Publication
The urgent need to tackle climate change drives the research on new technologies to help the transition of energy systems. Hydrogen is under significant consideration by many countries as a means to reach zero-carbon goals. Turkey has also started to develop hydrogen projects. In this study the role of hydrogen in Turkey’s energy system is assessed through energy modeling using the cost optimization analytical tool Open Source Energy Modelling System (OSeMOSYS). The potential effects of hydrogen blending into the natural gas network in the Turkish energy system have been displayed by scenario development. The hydrogen is produced via electrolysis using renewable electricity. As a result by using hydrogen a significant reduction in carbon dioxide emissions was observed; however the accumulated capital investment value increased. Furthermore it was shown that hydrogen has the potential to reduce Turkey’s energy import dependency by decreasing natural gas demand.
Exploring Decentralized Ammonia Synthesis for Hydrogen Storage and Transport: A Comprehensive CFD Investigation with Experimental Validation and Parametric Study
Sep 2023
Publication
Hydrogen energy plays a vital role in the transition towards a carbon-neutral society but faces challenges in storage and transport as well as in production due to fluctuations in renewable electricity generation. Ammonia (NH3 ) as a carbon-neutral hydrogen carrier offers a promising solution to the energy storage and transport problem. To realize its potential and support the development of a hydrogen economy exploring NH3 synthesis in a decentralized form that integrates with distributed hydrogen production systems is highly needed. In this study a computational fluid dynamics (CFD) model for the Ruthenium (Ru) catalysts-based Haber– Bosch reactor is developed. First a state-of-the-art kinetic model comprehensively describing the complex catalytic reaction is assessed for its sensitivity and applicability to temperature pressure and conversion. Then the kinetic model is integrated into the CFD model and its accuracy is verified through comparison with experimental data obtained from different Ru-based catalysts and operation conditions. Detailed CFD results for a given case are presented offering a visual understanding of thermal gradients and species distributions inside the reactor. Finally a CFD-based parametric study is performed to reveal the impacts of key operation parameters and optimize the NH3 synthesis reactor. The results show that the NH3 production rate is predominantly influenced by temperature with a two-fold difference observed for every 30 ◦C variation while pressure primarily affects the equilibrium. Additionally the affecting mechanism of space velocity is thoroughly discussed and the best value for efficient NH3 synthesis is found to be 180000 h−1. In conclusion the CFD model and simulation results provide valuable insights for the design and control of decentralized NH3 synthesis reactor and operation contributing to the advancement of sustainable energy technologies.
Real-Time Energy Management Strategy of Hydrogen Fuel Cell Hybrid Electric Vehicles Based on Power Following Strategy–Fuzzy Logic Control Strategy Hybrid Control
Nov 2023
Publication
Fuel cell hybrid electric vehicles have the advantages of zero emission high efficiency and fast refuelling etc. and are one of the key directions for vehicle development. The energy management problem of fuel cell hybrid electric vehicles is the key technology for power distribution. The traditional power following strategy has the advantage of a real-time operation but the power correction is usually based only on the state of charge of a lithium battery which causes the operating point of the fuel cell to be in the region of a low efficiency. To solve this problem this paper proposes a hybrid power-following-fuzzy control strategy where a fuzzy logic control strategy is used to optimise the correction module based on the power following strategy which regulates the state of charge while correcting the output power of the fuel cell towards the efficient operating point. The results of the joint simulation with Matlab + Advisor under the Globally Harmonised Light Vehicle Test Cycle Conditions show that the proposed strategy still ensures the advantages of real-time energy management and for the hydrogen fuel cell the hydrogen consumption is reduced by 13.5% and 4.1% compared with the power following strategy and the fuzzy logic control strategy and the average output power variability is reduced by 14.6% and 5.1% respectively which is important for improving the economy of the whole vehicle and prolonging the lifetime of fuel cell.
Feasibility Study on the Provision of Electricity and Hydrogen for Domestic Purposes in the South of Iran using Grid-connected Renewable Energy Plants
Dec 2018
Publication
This work presents a feasibility study on the provision of electricity and hydrogen with renewable grid connected and off-the-grid systems for Bandar Abbas City in the south of Iran. The software HOMER Pro® has been used to perform the analysis. A techno-enviro-economic study comparing a hybrid system consisting of the grid/wind turbine and solar cell is done. The wind turbine is analyzed using four types of commercially available vertical axis wind turbines (VAWTs). According to the literature review no similar study has been performed so far on the feasibility of using VAWTs and also no work exists on the use of a hybrid system in the studied area. The results indicated that the lowest price of providing the required hydrogen was $0.496 which was achieved using the main grid. Also the lowest price of the electricity generated was $1.55 which was obtained through using EOLO VAWT in the main grid/wind turbine/solar cell scenario. Also the results suggested that the highest rate of preventing CO2 emission which was also the lowest rate of using the national grid with 3484 kg/year was associated with EOLO wind turbines where only 4% of the required electricity was generated by the national grid.
Preliminary Assessment of a Hydrogen Farm Including Health and Safety and Capacity Needs
Dec 2024
Publication
The safety engineering design of hydrogen systems and infrastructure worker education and training regulatory compliance and engagement with other stakeholders are significant to the viability and public acceptance of hydrogen farms. The only way to ensure these are accomplished is for the field of hydrogen safety engineering (HSE) to grow and mature. HSE is described as the application of engineering and scientific principles to protect the environment property and human life from the harmful effects of hydrogen-related mishaps and accidents. This paper describes a whole hydrogen farm that produces hydrogen from seawater by alkaline and proton exchange membrane electrolysers then details how the hydrogen gas will be used: some will be stored for use in a combined-cycle gas turbine some will be transferred to a liquefaction plant and the rest will be exported. Moreover this paper describes the design framework and overview for ensuring hydrogen safety through these processes (production transport storage and utilisation) which include legal requirements for hydrogen safety safety management systems and equipment for hydrogen safety. Hydrogen farms are large-scale facilities used to create store and distribute hydrogen which is usually produced by electrolysis using renewable energy sources like wind or solar power. Since hydrogen is a vital energy carrier for industries transportation and power generation these farms are crucial in assisting the global shift to clean energy. A versatile fuel with zero emissions at the point of use hydrogen is essential for reaching climate objectives and decarbonising industries that are difficult to electrify. Safety is essential in hydrogen farms because hydrogen is extremely flammable odourless invisible and also has a small molecular size meaning it is prone to leaks which if not handled appropriately might cause fires or explosions. To ensure the safe and dependable functioning of hydrogen production and storage systems stringent safety procedures are required to safeguard employees infrastructure and the surrounding environment from any mishaps.
An Overview of Hydrogen’s Application for Energy Purposes in Lithuania
Nov 2023
Publication
Hydrogen has emerged as a promising climate-neutral energy carrier able to facilitate the processes of the European Union (EU) energy transition. Green hydrogen production through the electrolysis process has gained increasing interest recently for application in various sectors of the economy. As a result of the increasing renewable energy developments in the EU hydrogen is seen as one of the most promising solutions for energy storage challenges; therefore the leading countries in the energy sector are heavily investing in research of the technical obstacles for hydrogen applications and assessment of the current hydrogen market which in turn leads to the acceleration of the upscaling of hydrogen production. The main objective of this article was to provide a comprehensive overview of various green hydrogen production transportation and industrial application technologies and challenges in Europe with a separate analysis of the situation in Lithuania. Various water electrolysis technologies and their production costs are investigated along with recent developments in storage and transportation solutions. In addition the performances and limitations of electrochemical processes are presented and analysed research trends in the field are discussed and possible solutions for performance and cost improvements are overviewed. This paper proposes a discussion of perspectives in terms of future applications and research directions.
The Impact of Methane Leakage on the Role of Natural Gas in the European Energy Transition
Sep 2023
Publication
Decarbonising energy systems is a prevalent topic in the current literature on climate change mitigation but the additional climate burden caused by methane emissions along the natural gas value chain is rarely discussed at the system level. Considering a two-basket greenhouse gas neutrality objective (both CO2 and methane) we model cost-optimal European energy transition pathways towards 2050. Our analysis shows that adoption of best available methane abatement technologies can entail an 80% reduction in methane leakage limiting the additional environmental burden to 8% of direct CO2 emissions (vs. 35% today). We show that while renewable energy sources are key drivers of climate neutrality the role of natural gas strongly depends on actions to abate both associated CO2 and methane emissions. Moreover clean hydrogen (produced mainly from renewables) can replace natural gas in a substantial proportion of its end-uses satisfying nearly a quarter of final energy demand in a climate-neutral Europe.
Hazard Footprint of Alternative Fuel Storage Concepts for Hydrogen-powered Urban Buses
Nov 2023
Publication
Hydrogen mobility is a powerful strategy to fight climate change promoting the decarbonization of the transportation sector. However the higher flammability of hydrogen in comparison with traditional fuels raises issues concerning the safety of hydrogen-powered vehicles in particular when urban mobility in crowded areas is concerned. In the present study a comparative analysis of alternative hydrogen storage concepts for buses is carried out. A specific inherent safety assessment methodology providing a hazard footprint of alternative hydrogen storage technologies was developed. The approach provides a set of ex-ante safety performance indicators and integrates a sensitivity analysis performed by a Monte Carlo method. Integral models for consequence analysis and a set of baseline frequencies are used to provide a preliminary identification of the worstcase credible fire and explosion scenarios and to rank the inherent safety of alternative concepts. Cryocompressed storage in the supercritical phase resulted as the more hazardous storage concept while cryogenic storage in the liquid phase at ambient pressure scored the highest safety performance. The results obtained support risk-informed decision-making in the shift towards the promotion of sustainable mobility in urban areas.
Lower-Carbon Hydrogen Production from Wastewater: A Comprehensive Review
Oct 2024
Publication
Hydrogen has the capability of being a potential energy carrier and providing a long-term solution for sustainable lower-carbon and ecologically benign fuel supply. Because lower-carbon hydrogen is widely used in chemical synthesis it is regarded as a fuel with no emissions for transportation. This review paper offers a novel technique for producing hydrogen using wastewater in a sustainable manner. The many techniques for producing hydrogen with reduced carbon emissions from wastewater are recognized and examined in detail taking into account the available prospects significant obstacles and potential future paths. A comparison of the assessment showed that water electrolysis and dark fermentation technologies are the most effective methods for hydrogen generation from wastewater with microbial electrolysis and photofermentation. Thus the incorporation of systems that are simultaneously producing lower-carbon hydrogen and meant for wastewater treatment is important for the minimization of emissions from greenhouse gases and recovering the energy utilized in the treatment of wastewater.
Simple Energy Model for Hydrogen Fuel Cell Vehicles: Model Development and Testing
Dec 2024
Publication
Hydrogen fuel cell vehicles (HFCVs) are a promising technology for reducing vehicle emissions and improving energy efficiency. Due to the ongoing evolution of this technology there is limited comprehensive research and documentation regarding the energy modeling of HFCVs. To address this gap the paper develops a simple HFCV energy consumption model using new fuel cell efficiency estimation methods. Our HFCV energy model leverages real-time vehicle speed acceleration and roadway grade data to determine instantaneous power exertion for the computation of hydrogen fuel consumption battery energy usage and overall energy consumption. The results suggest that the model’s forecasts align well with real-world data demonstrating average error rates of 0.0% and −0.1% for fuel cell energy and total energy consumption across all four cycles. However it is observed that the error rate for the UDDS drive cycle can be as high as 13.1%. Moreover the study confirms the reliability of the proposed model through validation with independent data. The findings indicate that the model precisely predicts energy consumption with an error rate of 6.7% for fuel cell estimation and 0.2% for total energy estimation compared to empirical data. Furthermore the model is compared to FASTSim which was developed by the National Renewable Energy Laboratory (NREL) and the difference between the two models is found to be around 2.5%. Additionally instantaneous battery state of charge (SOC) predictions from the model closely match observed instantaneous SOC measurements highlighting the model’s effectiveness in estimating real-time changes in the battery SOC. The study investigates the energy impact of various intersection controls to assess the applicability of the proposed energy model. The proposed HFCV energy model offers a practical versatile alternative leveraging simplicity without compromising accuracy. Its simplified structure reduces computational requirements making it ideal for real-time applications smartphone apps in-vehicle systems and transportation simulation tools while maintaining accuracy and addressing limitations of more complex models.
Energy Storage Strategy - Narrative
Feb 2023
Publication
This narrative document sets out the main rationale for hydrogen storage development at scale in the UK: - To meet net zero the UK will need considerable energy storage - Hydrogen storage will be a major and essential part of this - Physical hydrogen storage is needed in the UK - Only geological hydrogen storage can deliver at the scale needed within the timescales for net zero - Geological hydrogen storage should be supported through a viable business model now to ensure it comes online in the 2030s.
Reversible Solid Oxide Cell Coupled to an Offshore Wind Turbine as a Poly-generation Energy System for Auxiliary Backup Generaiton and Hydrogen Production
Nov 2022
Publication
The coupling of a reversible Solid Oxide Cell (rSOC) with an offshore wind turbine is investigated to evaluate the mutual benefits in terms of local energy management. This integrated system has been simulated with a dynamic model under a control algorithm which manages the rSOC operation in relation to the wind resource implementing a local hydrogen storage with a double function: (i) assure power supply to the wind turbine auxiliary systems during power shortages (ii) valorize the heat produced to cover the desalinization system needs. With an export-based strategy which maximize the rSOC capacity factor up to 15 tons of hydrogen could be produced for other purposes. The results show the compatibility between the auxiliary systems supply of a 2.3 MW wind turbine and a 120/21 kWe rSOC system which can cover the auxiliaries demand during wind shortages or maintenance. The total volume required by such a system occupy less than the 2% if compared with the turbine tower volume. Additionally thermal availability exceeds the desalination needs representing a promising solution for small-scale onsite desalination in offshore environments.
Solar Hydrogen Production and Storage in Solid Form: Prospects for Materials and Methods
Sep 2024
Publication
Climatic changes are reaching alarming levels globally seriously impacting the environment. To address this environmental crisis and achieve carbon neutrality transitioning to hydrogen energy is crucial. Hydrogen is a clean energy source that produces no carbon emissions making it essential in the technological era for meeting energy needs while reducing environmental pollution. Abundant in nature as water and hydrocarbons hydrogen must be converted into a usable form for practical applications. Various techniques are employed to generate hydrogen from water with solar hydrogen production—using solar light to split water—standing out as a cost-effective and environmentally friendly approach. However the widespread adoption of hydrogen energy is challenged by transportation and storage issues as it requires compressed and liquefied gas storage tanks. Solid hydrogen storage offers a promising solution providing an effective and low-cost method for storing and releasing hydrogen. Solar hydrogen generation by water splitting is more efficient than other methods as it uses self-generated power. Similarly solid storage of hydrogen is also attractive in many ways including efficiency and cost-effectiveness. This can be achieved through chemical adsorption in materials such as hydrides and other forms. These methods seem to be costly initially but once the materials and methods are established they will become more attractive considering rising fuel prices depletion of fossil fuel resources and advancements in science and technology. Solid oxide fuel cells (SOFCs) are highly efficient for converting hydrogen into electrical energy producing clean electricity with no emissions. If proper materials and methods are established for solar hydrogen generation and solid hydrogen storage under ambient conditions solar light used for hydrogen generation and utilization via solid oxide fuel cells (SOFCs) will be an efficient safe and cost-effective technique. With the ongoing development in materials for solar hydrogen generation and solid storage techniques this method is expected to soon become more feasible and cost-effective. This review comprehensively consolidates research on solar hydrogen generation and solid hydrogen storage focusing on global standards such as 6.5 wt% gravimetric capacity at temperatures between −40 and 60 ◦C. It summarizes various materials used for efficient hydrogen generation through water splitting and solid storage and discusses current challenges in hydrogen generation and storage. This includes material selection and the structural and chemical modifications needed for optimal performance and potential applications.
Green Hydrogen and its Unspoken Challenges for Energy Justice
Oct 2024
Publication
Green hydrogen is often promoted as a key facilitator for the clean energy transition but its implementation raises concerns around energy justice. This paper examines the socio-political and techno-economic challenges that green hydrogen projects may pose to the three tenets of energy justice: distributive procedural and recognition justice. From a socio-political perspective the risk of neocolonial resource extraction uneven distribution of benefits exclusion of local communities from decision-making and disregard for indigenous rights and cultures threaten all three justice tenets. Techno-economic factors such as water scarcity land disputes and resource-related conflicts in potential production hotspots further jeopardise distributive and recognition justice. The analysis framed by an adapted PEST model reveals that while green hydrogen holds promise for sustainable development its implementation must proactively address these justice challenges. Failure to do so could perpetuate injustices exploitation and marginalisation of vulnerable communities undermining the sustainability goals it aims to achieve. The paper highlights the need for inclusive and equitable approaches that respect local sovereignty integrate diverse stakeholders and ensure fair access and benefit-sharing. Only by centring justice considerations can the transition to green hydrogen catalyse positive social change and realise its full potential as a driver of sustainable energy systems.
Hydrogen Equipment Enclosure Risk Reduction through Earlier Detection of Component Failures
Sep 2023
Publication
Hydrogen component reliability and the hazard associated with failure rates is a critical area of research for the successful implementation and growth of hydrogen technology across the globe. The research team has partnered to quantify system risk reduction through earlier detection of hydrogen component failures. A model of hydrogen dispersion in a hydrogen equipment enclosure has been developed utilizing experimentally quantified hydrogen component leak rates as inputs. This model provides insight into the impact of hydrogen safety sensors and ventilation on the flammable mass within a hydrogen equipment enclosure. This model also demonstrates the change in safety sensor response time due to detector placement under various leak scenarios. The team looks to improve overall hydrogen system safety through an improved understanding of hydrogen component reliability and risk mitigation methods. This collaboration fits under the work program of IEA Hydrogen Task 43 Subtask E Hydrogen System Safety.
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