Publications

This review presents a broad exploration of the techno economic evaluation of different technologies utilized in the production of hydrogen from both renewable and non-renewable sources. These encompass methods ranging from extracting hydrogen from fossil fuels or biomass to employing microbial processes electrolysis of water and various thermochemical cycles. A rigorous techno-economic evaluation of hydrogen production technologies can provide a critical cost comparison for future resource allocation priorities and trajectory. This evaluation will have a great impact on future hydrogen production projects and the development of new approaches to reduce overall production costs and make it a cheaper fuel. Different methods of hydrogen production exhibit varying efficiencies and costs: fast pyrolysis can yield up to 45% hydrogen at a cost range of $1.25 to $2.20 per kilogram while gasification operating at temperatures exceeding 750°C faces challenges such as limited small-scale coal production and issues with tar formation in biomass. Steam methane reforming which constitutes 48% of hydrogen output experiences cost fluctuations depending on scale whereas auto-thermal reforming offers higher efficiency albeit at increased costs. Chemical looping shows promise in emissions reduction but encounters economic hurdles and sorptionenhanced reforming achieves over 90% hydrogen but requires CO2 storage. Renewable liquid reforming proves effective and economically viable. Additionally electrolysis methods like PEM aim for costs below $2.30 per kilogram while dark fermentation though cost-effective grapples with efficiency challenges. Overcoming technical economic barriers and managing electricity costs remains crucial for optimizing hydrogen production in a low-carbon future necessitating ongoing research and development efforts.

The increase in the feasibility of hydrogen-based generation makes it a promising addition to the realm of renewable energies that are being employed to address the issue of electric vehicle charging. This paper presents technical and an economical approach to evaluate a newer off-grid hybrid PV-hydrogen energy-based recharging station in the city of Jamshoro Pakistan to meet the everyday charging needs of plug-in electric vehicles. The concept is designed and simulated by employing HOMER software. Hybrid PV-hydrogen and PV-hydrogenbattery are the two different scenarios that are carried out and compared based on their both technical as well as financial standpoints. The simulation results are evident that the hybrid PV- hydrogen-battery energy system has much more financial and economic benefits as compared with the PV-hydrogen energy system. Moreover it is also seen that costs of energy from earlier from hybrid PV-hydrogen-battery is more appealing i.e. 0.358 $/kWh from 0.412 $/kWh cost of energy from hybrid PV-hydrogen. The power produced by the hybrid PV- hydrogen - battery energy for the daily load demand of 1700 kWh /day consists of two powers produced independently by the PV and fuel cells of 87.4 % and 12.6 % respectively.

Hydrogen and methane as secondary fuels in diesel engines can be promising solutions to meet energy demand. The current study investigated the effect of the specialty gases of different compositions on diesel engine performance and exhaust gases. Four gases with various compositions of exhaust gas recirculation (Carbon monoxide Carbon dioxide and Nitrogen) and fuels (Hydrogen and Methane) were used at various mass flow rates of 10 20 and 25 LPM (liter per minute) and various engine speeds of 2000 2500 3000 and 3500 rpm (revolutions per minute). The procured results revealed that adding specialty gases improved brake thermal efficiency and power. Similarly the brake-specific fuel consumption was also massively retarded compared to diesel due to the influence of the hydrogen and methane composition. However the fuel with the higher nitrogen reported less BTE (brake thermal efficiency) and comparatively higher exhaust gas temperature owing to the higher presence of nitrogen in their composition. Regarding emissions including exhaust gas recirculation dropped the formation of pollutants efficiently compared to diesel. Among various fuels Case 1 (30 % H2 5 % CH4 5 CO2 and 60 % CO) reported the lowest emission of NOx and Case 2 (25 % H2 5 % CH4 5 CO2 30 % CO and 35 % N2) of CO and CO2 emissions. Generally specialty gases with a variable composition of exhaust gas recirculation gases can be a promising sustainable replacement for existing fossil fuels.

This scientific article presents a developed model for optimising the scheduling of hydrogen production processes addressing the growing demand for efficient and sustainable energy sources. The study focuses on the integration of advanced scheduling techniques to improve the overall performance of the hydrogen electrolyser. The proposed model leverages constraint programming and satisfiability (CP-SAT) techniques to systematically analyse complex production schedules considering factors such as production unit capacities resource availability and energy costs. By incorporating real-world constraints such as fluctuating energy prices and the availability of renewable energy the optimisation model aims to improve overall operational efficiency and reduce production costs. The CP-SAT was applied to achieve more efficient control of the electrolysis process. The optimisation of the scheduling task was set for a 24 h time period with time resolutions of 1 h and 15 min. The performance of the proposed CP-SAT model in this study was then compared with the Monte Carlo Tree Search (MCTS)-based model (developed in our previous work). The CP-SAT was proven to perform better but has several limitations. The model response to the input parameter change has been analysed.

The high potential in renewable energy sources (RES) and the availability of strategic minerals for green hydrogen technologies place Africa in a promising position for the development of a climate-compatible economy leveraging on hydrogen. This study reviews the potential hydrogen value chain in Africa considering production and final uses while addressing perspectives on policies possible infrastructures and facilities for hydrogen logistics. Through scientific studies research and searching in relevant repositories this review features the collection analysis of technical data and georeferenced information about key aspects of the hydrogen value chain. Detailed maps and technical data for gas transport infrastructure and liquefaction terminals in the continent are reported to inform and elaborate findings about readiness for hydrogen trading and domestic use in Africa. Specific maps and technical data have been also collected for the identification of potential hydrogen offtakers focusing on individual industrial installations to produce iron and steel chemicals and oil refineries. Finally georeferenced data are presented for main road and railway corridors as well as for most important African ports as further end-use and logistic platforms. Beyond technical information this study collects and discusses more recent perspectives about policies and implementation initiatives specifically addressing hydrogen production logistics and final use also introducing potential criticalities associated with environmental and social impacts.

In recent years the use of alternative fuels in thermal engine power plants has gained more and more attention becoming of paramount importance to overcome the use of fuels from fossil sources and to reduce polluting emissions. The present work deals with the analysis of the response to two different gas fuels—i.e. hydrogen and a syngas from agriculture product—of a 30 kW micro gas turbine integrated with a solar field. The solar field included a thermal storage system to partially cover loading requests during night hours reducing fuel demand. Additionally a Heat Recovery Unit was included in the plant considered and the whole plant was simulated by Thermoflex® code. Thermodynamics analysis was performed on hour-to-hour basis for a given day as well as for 12 months; subsequently an evaluation of cogeneration efficiency as well as energy saving was made. The results are compared against plant performance achieved with conventional natural gas fueling. After analyzing the performance of the plant through a thermodynamic analysis the study was complemented with CFD simulations of the combustor to evaluate the combustion development and pollutant emissions formation particularly of NOx with the two fuels considered using Ansys-Fluent code and a comparison was made.

Green hydrogen is expected to play a vital role in decarbonizing the energy system in Europe. However large-scale deployment of green hydrogen has associated potential trade-offs in terms of climate and other environmental impacts. This study aims to shed light on a comprehensive sustainability assessment of this large-scale green hydrogen deployment based on the EMPIRE energy system modeling compared with other decarbonization paths. Process-based Life Cycle Assessment (LCA) is applied and connected with the output of the energy system model revealing 45% extra climate impact caused by the dedicated 50% extra renewable infrastructure to deliver green hydrogen for the demand in the sectors of industry and transport in Europe towards 2050. Whereas the analysis shows that green hydrogen eventually wins on the climate impact within four designed scenarios (with green hydrogen with blue hydrogen without green hydrogen and baseline) mainly compensated by its clean usage and renewable electricity supply. On the other hand green hydrogen has a lower performance in other environmental impacts including human toxicity ecotoxicity mineral use land use and water depletion. Furthermore a monetary valuation of Life Cycle Impact (LCI) is estimated to aggregate 13 categories of environmental impacts between different technologies. Results indicate that the total monetized LCI cost of green hydrogen production is relatively lower than that of blue hydrogen. In overview a large-scale green hydrogen deployment potentially shifts the environmental pressure from climate and fossil resource use to human health mineral resource use and ecosystem damage due to its higher material consumption of the infrastructure.

Many industrialised nations recently concentrated their focus on hydrogen as a viable option for the decarbonisation of fossil-intensive sectors including maritime transportation. A sustainable alternative to the conventional production of hydrogen based on fossil hydrocarbons is water electrolysis powered by renewable energy sources. This paper presents a detailed techno-economic optimisation model for sizing an electrolyser and a hydrogen storage embedded in a multi-domain virtual power plant to produce green hydrogen for seaborne passenger transportation. We base our numerical analysis on three years of historical data from a renewable-dominated 60/10 kV substation on the Danish island of Bornholm and on data for ferries to the mainland of Sweden. Our analysis shows that an electrolyser system serves as a valuable flexibility asset on the electrical demand side while supporting the thermal management of the district heating system and contributing to meeting the ferries hydrogen demand. With a sized electrolyser of 9.63 MW and a hydrogen storage of 1.45 t the hydrogen assets are able to take up a large share of the local excess electricity generation. The waste heat of the electrolyser delivers a significant share of 21.4% of the annual district heating demand. Moreover the substation can supply 26% of the hydrogen demand of the ferries from local resources. We further examine the sensitivity of the asset sizing towards investment costs electrolyser efficiency and hydrogen market prices.

Hydrogen is one of a handful of new low carbon solutions that will be critical for the transition to net zero. The upscaling of production and applications entails that hydrogen is likely to be stored in liquid phase (LH2) at cryogenic conditions to increase its energy density. Widespread LH2 use as an alternative fuel will require significant infrastructure upgrades to accommodate increased bulk transport storage and delivery. However current LH2 bulk storage separation distances are based on subjective expert recommendations rather than experimental observations or physical models. Experimental studies of large-scale LH2 release are challenging and costly. The existing large-scale tests are scarce and numerical studies are a viable option to investigate the existing knowledge gaps. Controlled or accidental releases of LH2 for hydrogen refueling infrastructure would result in high momentum two-phase jets or formation of liquid pools depending on release conditions. Both release scenarios lead to a flammable/explosive cloud posing a safety issue to the public.<br/>The manuscript reports exploratory study to numerically determine the safety zone resulting from cryogenic hydrogen releases related to LH2 storage and refueling using the in-house HyFOAM solver further modified for gaseous hydrogen releases at cryogenic conditions and the subsequent atmospheric dispersion and ignition within the platform of OpenFOAM V8.0. The current version of the solver neglects the flashing process by assuming that the temperature of the stored LH2 is equal to the boiling point at the atmospheric condition. Numerical simulations of dispersion and subsequent ignition of LH2 release scenarios with respect to different release orientations release rates release temperatures and weather conditions were performed. Both hydrogen concentration and temperature fields were predicted and the boundary of zones within the flammability limit was also defined. The study also considered the sensitivities of the consequences to the release orientation wind speed ambient temperature and release content etc. The effect of different barrier walls on the deflagration were also evaluated by changing the height and location.

This paper presents an energy management system (EMS) based on a novel approach using model predictive control (MPC) for the optimized operation of power sources in a hybrid charging station for electric vehicles (EVs). The hybrid charging station is composed of a photovoltaic (PV) system a battery a complete hydrogen system based on a fuel cell (FC) electrolyzer (EZ) and tank as an energy storage system (ESS) grid connection and six fast charging units all of which are connected to a common MVDC bus through Z-source converters (ZSC). The MPC-based EMS is designed to control the power flow among the energy sources of the hybrid charging station and reduce the utilization costs of the ESS and the dependency on the grid. The viability of the EMS was proved under a long-term simulation of 25 years in Simulink using real data for the sun irradiance and a European load profile for EVs. Furthermore this EMS is compared with a simpler alternative that is used as a benchmark which pursues the same objectives although using a states-based strategy. The results prove the suitability of the EMS achieving a lower utilization cost (-25.3%) a notable reduction in grid use (-60% approximately) and an improvement in efficiency.