Publications
Green Hydrogen Production Plants: A Techno-economic Review
Aug 2024
Publication
Green hydrogen stands as a promising clean energy carrier with potential net-zero greenhouse gas emissions. However different system-level configurations for green hydrogen production yield different levels of efficiency cost and maturity necessitating a comprehensive assessment. This review evaluates the components of hydrogen production plants from technical and economic perspectives. The study examines six renewable energy sources—solar photovoltaics solar thermal wind biomass hydro and geothermal—alongside three types of electrolyzers (alkaline proton exchange membrane and solid oxide electrolyzer cells) and five hydrogen storage methods (compressed hydrogen liquid hydrogen metal hydrides ammonia and liquid organic hydrogen carriers). A comprehensive assessment of 90 potential system configurations is conducted across five key performance indicators: the overall system cost efficiency emissions production scale and technological maturity. The most cost-effective configurations involve solar photovoltaics or wind turbines combined with alkaline electrolyzers and compressed hydrogen storage. For enhanced system efficiency geothermal sources or biomass paired with solid oxide electrolyzer cells utilizing waste heat show significant promise. The top technologically mature systems feature combinations of solar photovoltaics wind turbines geothermal or hydroelectric power with alkaline electrolyzers using compressed hydrogen or ammonia storage. The highest hydrogen production scales are observed in systems with solar PV wind or hydro power paired with alkaline or PEM electrolyzers and ammonia storage. Configurations using hydro geothermal wind or solar thermal energy sources paired with alkaline electrolyzers and compressed hydrogen or liquid organic hydrogen carriers yield the lowest life cycle GHG emissions. These insights provide valuable decision-making tools for researchers business developers and policymakers guiding the optimization of system efficiency and the reduction of system costs.
Design of a Hydrogen Refueling Station with Hydrogen Production by Electrolysis, Storage and Dispensing for a Bus Fleet in the City of Valencia
Jul 2024
Publication
Hydrogen technologies are evolving to decarbonise the transport sector. The present work focuses on the technical design of a Hydrogen Refueling Station to supply hydrogen to five buses in the city of Valencia Spain. The study deals with the technical selection of the components from production to consumption setting an efficient standardisation method. Different calculation are used to size the storage systems for 70.8 kg of hydrogen produced by the elecrolyser daily. For the high-pressure storage system massive and cascade methods are proposed being the last one more efficient (1577.53 Nm3 non usable volume compared to 9948.95 Nm3 of the massive method).
Low-Carbon Economic Scheduling of Integrated Energy System Considering Flexible Supply–Demand Response and Diversified Utilization of Hydrogen
Feb 2025
Publication
With the large-scale deployment of renewable energy the issue of wind power consumption has become increasingly prominent leading to serious wind energy abandonment. In order to promote energy sustainability this paper proposes a low-carbon economic scheduling model of an integrated energy system (IES) that combines the flexible supply–demand response with the diversified utilization of hydrogen energy. A mixedinteger linear programming model is developed and solved using the commercial solver GUROBI to obtain the scheduling scheme that minimizes total costs. First decoupling analysis is performed for combined heat and power (CHP) units and the organic Rankine cycle (ORC) is introduced to enable dynamic output adjustments. On the demand side a flexible demand response mechanism is introduced which allows various types of loads to transfer within the scheduling cycle or substitute for each other within the same period. Additionally combining the clean characteristics of hydrogen this paper introduces hydrogen-doped CHP and other utilization strategies and develops a diversified utilization structure of hydrogen. A small IES is used for case analysis to verify the effectiveness of the above strategies. The results show that the proposed strategy can entirely consume wind power reduce total cost by 21.32% and decrease carbon emissions by 44.83% thereby promoting low-carbon economic operation and sustainable energy development of the system.
A Multi-objective Planning Tool for the Optimal Supply of Green Hydrogen for an Inustrial Port Area Decarbonisation
Jul 2024
Publication
This study addresses the challenge of decarbonizing highly energy-intensive Industrial Port Areas (IPA) focusing on emissions from various sources like ship traffic warehouses buildings cargo handling equipment and hardto-abate industry typically hosted in port areas. The analysis and proposal of technological solutions and their optimal integration in the context of IPA is a topic of growing scientific interest with considerable social and economic implications. Representing the main novelties of the work this study introduces (i) the development of a novel IPA energy and green hydrogen hub located in a tropical region (Singapore); (ii) a multi-objective optimization approach to analyse synthesize and optimize the design and operation of the hydrogen and energy hub with the aim of supporting decision-making for decarbonization investments. A sensitivity analysis identifies key parameters affecting optimization results indicating that for large hydrogen demands imported ammonia economically outperforms other green hydrogen carriers. Conversely local hydrogen production via electrolysis becomes economically viable when the capital cost of alkaline electrolyser drops by at least 30 %. Carbon tax influences the choice of green hydrogen but its price variation mainly impacts system operation rather than design. Fuel cells and batteries are not considered economically feasible solutions in any scenario.
Hydrogen Energy in Electrical Power Systems: A Review and Future Outlook
Aug 2024
Publication
Hydrogen energy as a zero-carbon emission type of energy is playing a significant role in the development of future electricity power systems. Coordinated operation of hydrogen and electricity will change the direction and shape of energy utilization in the power grid. To address the evolving power system and promote sustainable hydrogen energy development this paper initially examines hydrogen preparation and storage techniques summarizes current research and development challenges and introduces several key technologies for hydrogen energy application in power systems. These include hydrogen electrification technology hydrogen-based medium- and long-term energy storage and hydrogen auxiliary services. This paper also analyzes several typical modes of hydrogen–electricity coupling. Finally the future development direction of hydrogen energy in power systems is discussed focusing on key issues such as cost storage and optimization.
Hydrogen in Natural Gas Grids: Prospects and Recommendations About Gas Flow Meters
Aug 2024
Publication
To inject green hydrogen (H2) into the existing natural gas (NG) infrastructure is one way to decarbonize the European energy system. However asset readiness is necessary to be successful. Preliminary analysis and experimental results about the compatibility of hydrogen and natural gas mixtures (H2NG) with the actual gas grids make the scientific community confident about the feasibility. Nevertheless specific technical questions need more research. A significant topic of debate is the impact of H2NG mixtures on the performance of state-ofthe-art fiscal measuring devices which are essential for accurate billing. Identifying and addressing any potential degradation in their metrological performance due to H2NG is critical for decision-making. However the literature lacks data about the gas meters’ technologies currently installed in the NG grids such as a comprehensive overview of their readiness at different concentrations while data are fragmented among different sources. This paper addresses these gaps by analyzing the main characteristics and categorizing more than 20000 gas meters installed in THOTH2 project partners’ grids and by summarizing the performance of traditional technologies with H2NG mixtures and pure H2 based on literature review operators experience and manufacturers knowledge. Based on these insights recommendations are given to stakeholders on overcoming the identified barriers to facilitate a smooth transition.
Artificial Intelligence for Hydrogen-Enabled Integrated Energy Systems: A Systematic Review
Aug 2024
Publication
Hydrogen-enabled Integrated Energy Systems (H-IES) stand out as a promising solution with the potential to replace current non-renewable energy systems. However their development faces challenges and has yet to achieve widespread adoption. These main challenges include the complexity of demand and supply balancing dynamic consumer demand and challenges in integrating and utilising hydrogen. Typical energy management strategies within the energy domain rely heavily on accurate models from domain experts or conventional approaches such as simulation and optimisation approaches which cannot be satisfied in the real-world operation of H-IES. Artificial Intelligence (AI) or Advanced Data Analytics (ADA) especially Machine Learning (ML) has the ability to overcome these challenges. ADA is extensively used across several industries however further investigation into the incorporation of ADA and hydrogen for the purpose of enabling H-IES needs to be investigated. This paper presents a systematic literature review to study the research gaps research directions and benefits of ADA as well as the role of hydrogen in H-IES.
A Comparative Techno-economic Assessment Between Solar-based Hydrogen Production by Methane Pyrolysis and Water Electrolysis Methods
Jan 2025
Publication
The transition towards clean and economically viable hydrogen production is crucial for ensuring energy sustainability and mitigating climate change. This transition can be effectively facilitated by using renewable energy sources and advanced hydrogen production methods. Methane pyrolysis and water electrolysis emerge as crucial techniques for achieving hydrogen production with minimal carbon intensity. Recognizing the unique opportunity presented by solar energy for both processes this study presents a comparative techno-economic analysis between solar-based molten salt methane pyrolysis (SMSMP) and solar-based solid oxide electrolyzer cell (SSOEC). This study offers a guideline for selecting SMSMP vs SSOEC for cities across theworld. In particular a comprehensive case study including five cities worldwide—San Antonio Edmonton Auckland Seville and Lyon—is conducted utilizing their dynamic solar data and localized prices of methane and electricity to provide a realistic comparison. The results indicate the superior economic feasibility of SMSMP across all case studies. Among different case studies San Antonio and Auckland have the lowest hydrogen costs for SMSMP (2.31 $/kgH2) and SSOEC (5.19 $/kgH2) respectively. It was also concluded that SMSMP is preferred over SSOEC in average to ideal solar conditions given its full dependency on solar thermal energy. However the SSOEC has the potential to achieve better economic feasibility by incorporating clean hydrogen tax incentives and reducing the costs associated with renewable energy infrastructure in the future.
An Assessment of Decarbonisation Pathways for Intercontinental Deep-sea Shipping Using Power-to-X Fuels
Aug 2024
Publication
Shipping corridors act as the arteries of the global economy. The maritime shipping sector is also a major source of greenhouse gas emissions accounting for 2.9% of the global total. The international nature of the shipping sector combined with issues surrounding the use of battery technology means that these emissions are considered difficult to eliminate. This work explores the transition to renewable fuels by examining the use of electrofuels (in the form of liquid hydrogen methane methanol ammonia and Fischer-Tropsch fuel) to decarbonise large container ships from a technical economic and environmental perspective. For an equivalent range to current fossil fuel vessels the cargo capacity of vessels powered by electrofuels decreases by between 3% and 16% depending on the fuel of choice due to the lower energy density compared with conventional marine fuels. If vessel operators are willing to sacrifice range cargo space can be preserved by downsizing onboard energy storage which necessitates more frequent refuelling. For a realistic green hydrogen cost of €3.5/kg (10.5 €c/kWh) in 2030 the use of electrofuels in the shipping sector results in an increase in the total cost of ownership of between 124% and 731% with liquid hydrogen in an internal combustion engine being the most expensive and methanol in an internal combustion engine resulting in the lowest cost increase. Despite this we find that the increased transportation costs of some consumer goods to be relatively small adding for example less than €3.27 to the cost of a laptop. In general fuels which do not require cryogenic storage and can be used in internal combustion engines result in the lowest cost increases. For policymakers reducing the environmental impact of the shipping sector is a key priority. The use of liquid hydrogen which results in the largest cost increase offers a 70% reduction in GHG emissions for an electricity carbon intensity of 80 gCO2e/ kWh which is the greatest reduction of all fuels assessed in this work. A minimum carbon price of €400/tCO2 is required to allow these fuels to reach parity with conventional shipping operations. To meet European Union emissions reductions targets electricity with an emissions intensity below 40 gCO2e/kWh is required which suggests that for electrofuels to be truly sustainable direct connection with a source of renewable electricity is required.
Green Energy Fuelling Stations in Road Transport: Poland in the European and Global Context
Aug 2025
Publication
The transition to green energy in the transport sector is becoming a priority in the context of global climate challenges and the European Green Deal. This paper investigates the development of alternative fuelling stations particularly electric vehicle (EV) charging infrastructure and hydrogen stations across EU countries with a focus on Poland. It combines a policy and technology overview with a quantitative scientific analysis offering a multidimensional perspective on green infrastructure deployment. A Pearson correlation analysis reveals significant links between charging station density and both GDP per capita and the share of renewable energy. The study introduces an original Infrastructure Accessibility Index (IAI) to compare infrastructure availability across EU member states and models Poland’s EV charging station demand up to 2030 under multiple growth scenarios. Furthermore the article provides a comprehensive overview of biofuels including first- second- and third-generation technologies and highlights recent advances in hydrogen and renewable electricity integration. Emphasis is placed on life cycle considerations energy source sustainability and economic implications. The findings support policy development toward zero-emission mobility and the decarbonisation of transport systems offering recommendations for infrastructure expansion and energy diversification strategies.
Performance and Emissions Characteristics of Hydrogen-diesel Heavy-duty Engines: The Influence of Engine Control Parameters
Feb 2025
Publication
The introduction of gaseous hydrogen (H2) into the intake air of a heavy-duty diesel engine results in H2-diesel dual-fuel (HDDF) combustion which offers a near-term pathway to reduce CO2 emissions in heavy-duty longhaul trucking. Since H2 introduction impacts oxygen availability combustion characteristics and emissions simultaneously it is imperative to appropriately optimize and control the input parameters including intake air pressure diesel injection timing and EGR ratio. This study investigates the impacts of these controlling parameters on the combustion characteristics limiting factors and emissions of an HDDF engine. Experimental tests were conducted on a 2.4 L single-cylinder research engine under medium load and speed conditions (1200 rpm 8 bar brake mean effective pressure) with varying H2 fractions. The results show that engine performance and combustion parameters are not solely influenced by H2 introduction. Instead the key factor is how H2 introduction affects combustion phasing and fuels equivalence ratio at various intake air pressures and diesel injection timings. The findings demonstrate that technical challenges in HDDF combustion such as combustion harshness (indicated by maximum rate of pressure rise) and unburned H2 (“H2 slip”) can be addressed through coordinated control of intake air pressure diesel injection timing and EGR ratio based on H2 energy ratio. At high H2 energy ratios adding 20% EGR effectively reduced combustion harshness by up to 40% and NOx emissions by 68% with negligible impact on brake thermal efficiency and H2 slip. At a given EGR level precise control of combustion phasing and intake pressure enabled the introduction of 40% H2 energy ratio resulting in 40% reduction in CO₂ emissions and 55% reduction in particulate matter emissions with no increase in NOx levels compared to the baseline diesel operation. These outcomes establish simultaneous adjustment of key engine control parameters as a practical strategy to maximize H2 introduction while addressing technical challenges in HDDF combustion. This ensures comparable engine performance with significantly lower CO2 emissions compared to conventional heavy-duty diesel engines.
Net-Zero Greenhouse Gas Emission Electrified Aircraft Propulsion for Large Commercial Transport
Sep 2024
Publication
Until recently electrified aircraft propulsion (EAP) technology development has been driven by the dual objectives of reducing greenhouse gas (GHG) emissions and addressing the depletion of fossil fuels. However the increasing severity of climate change posing a significant threat to all life forms has resulted in the global consensus of achieving net-zero GHG emissions by 2050. This major shift has alerted the aviation electrification industry to consider the following: What is the clear path forward for EAP technology development to support the net-zero GHG goals for large commercial transport aviation? The purpose of this paper is to answer this question. After identifying four types of GHG emissions that should be used as metrics to measure the effectiveness of each technology for GHG reduction the paper presents three significant categories of GHG reduction efforts regarding the engine evaluates the potential of EAP technologies within each category as well as combinations of technologies among the different categories using the identified metrics and thus determines the path forward to support the net-zero GHG objective. Specifically the paper underscores the need for the aviation electrification industry to adapt adjust and integrate its EAP technology development into the emerging new engine classes. These innovations and collaborations are crucial to accelerate net-zero GHG efforts effectively.
Assessing the Impacts of Net Zero Transport Scenarios in France on Biomass Resources, Hydrogen and Electricity Consumption
May 2025
Publication
The transport sector in France accounts for 30% of national emissions and will require significant decarbonization effort to achieve carbon neutrality in 2050. Various technological solutions from electric vehicles to renewable fuel such as biofuels and e-fuels as well as changes in demand are envisioned to reach this target. We build three technological foresight scenarios and two sufficiency variants mainly based on different readings of the European regulations banning the sale of internalcombustion-engine vehicles and setting Sustainable Aviation Fuel incorporation rates. The transport hydrogen and biomass sectors are modeled in system dynamics to assess the detail impacts of these scenarios on biomass resources and energy consumption. In all scenarios the total electricity demand increases drastically regardless of the technological choices made for the vehicle fleets mainly due to the production of e-fuels for aviation. None of the technological scenarios studied suggest that biomass supply is unfeasible. However in a scenario with low electrification there is a potentially increased dependence on imports for waste oils and fats and competing uses or tensions with other demand sectors may arise over some biomass for anaerobic digestion and lignocellulosic resources. To reduce these potential tensions and the demand for electricity sufficiency measures seem necessary in addition to technological advancements.
Liquid Air Energy Storage (LAES) Integrated into the Hydrogen Economy - Techno-economic Optimization of Waste Cold Recovery from Liquid Hydrogen Regasification
Jul 2025
Publication
A liquid air energy storage (LAES) system is a promising Carnot battery configuration capable of efficiently recovering waste heat and cold energy carriers. Among these liquid hydrogen (LH₂) regasification presents a significant opportunity due to its high exergy content and its regasification temperature which aligns well with the liquid air liquefaction process. While most existing studies focus on integrating LAES with liquid natural gas (LNG) regasification or improving hydrogen liquefaction via liquid air regasification this work takes a novel approach by enhancing liquid air liquefaction through the utilization of waste cold from LH₂ regasification. Additionally this study explores an economic innovation the valorization of clean dry air discharged by LAES which has not been extensively examined in prior literature. A novel LAES configuration is proposed and subjected to a techno-economic analysis comparing its performance with a stand-alone LAES system. Results show that the proposed integration increases round-trip efficiency by 15 % reduces the levelized cost of storage by 60 % and achieves a payback period of under 10 years. These findings provide valuable insights for both academia and industry advancing the development of more efficient and economically viable LAES systems.
Experimental Investigation on Knock Characteristics from Pre-Chamber Gas Engine Fueled by Hydrogen
Feb 2024
Publication
Hydrogen-fueled engines require large values of the excess air ratio in order to achieve high thermal efficiency. A low value of this coefficient promotes knocking combustion. This paper analyzes the conditions for the occurrence of knocking combustion in an engine with a turbulent jet ignition (TJI) system with a passive pre-chamber. A single-cylinder engine equipped with a TJI system was running with an air-to-fuel equivalence ratio λ in the range of 1.25–2.00 and the center of combustion (CoC) was regulated in the range of 2–14 deg aTDC (top dead center). Such process conditions made it possible to fully analyze the ascension of knock combustion until its disappearance with the increase in lambda and CoC. Measures of knock in the form of maximum amplitude pressure oscillation (MAPO) and integral modulus of pressure oscillation (IMPO) were used. The absolute values of these indices were pointed out which can provide the basis for the definition of knock combustion. Based on our own work the MAPO index > 1 bar was defined determining the occurrence of knocking (without indicating its quality). In addition taking into account MAPO it was concluded that IMPO > 0.13 bar·deg is the quantity responsible for knocking combustion.
Spatial Optimization Strategies for China's Hydrogen Infrastructure Industry Chain
Oct 2024
Publication
Promoting the development of China’s hydrogen energy industry is crucial for achieving green energy transition. However existing research lacks systematic studies on the spatial layout of the hydrogen industry chain. This study constructed a comprehensive theoretical framework encompassing hardware infrastructure software systems and soft power. Using multi-source heterogeneous data GIS analysis and NVivo text coding methods the current regional layout and challenges of China’s hydrogen infrastructure industry chain were systematically evaluated. The findings determined that economically developed eastern regions lead in infrastructure and soft power while central and western regions leverage their resource and manufacturing advantages. Major challenges include regional imbalances in hardware infrastructure uneven distribution of soft power and misalignment between software systems and actual needs. Analysis of the “14th Five-Year Plan” of various regions elucidated deep insights into the diversity of local hydrogen energy development strategies identifying five types of hydrogen cities: resource-advantaged market-oriented regionally collaborative innovation-driven and policy-supported. Accordingly strategies to enhance industry chain synergy clarify city roles and optimize regional ecosystems were proposed. It is recommended to integrate hydrogen infrastructure with urban planning and incorporate environmental impact assessments into spatial optimization decisions. This study provides a systematic analytical framework and progressive policy recommendations for the efficient and green layout of China’s hydrogen infrastructure offering important implications for the sustainable development of the hydrogen industry and other rapidly developing economies.
Hydrogen Materials and Technologies in the Aspect of Utilization in the Polish Energy Sector
Nov 2024
Publication
Currently modern hydrogen technologies due to their low or zero emissions constitute one of the key elements of energy transformation and sustainable development. The growing interest in hydrogen is driven by the European climate policy aimed at limiting the use of fossil fuels for energy purposes. Although not all opinions regarding the technical and economic potential of hydrogen energy are positive many prepared forecasts and analyses show its prospective importance in several areas of the economy. The aim of this article is to provide a comprehensive review of modern materials current hydrogen technologies and strategies and show the opportunities problems and challenges Poland faces in the context of necessary energy transformation. The work describes the latest trends in the production transportation storage and use of hydrogen. The environmental social and economic aspects of the use of green hydrogen were discussed in addition to the challenges and expectations for the future in the field of hydrogen technologies. The main goals of the development of the hydrogen economy in Poland and the directions of actions necessary to achieve them were also presented. It was found that the existence of the EU CO2 emissions allowance trading system has a significant impact on the costs of hydrogen production. Furthermore the production of green hydrogen will become economically justified as the costs of energy obtained from renewable sources decrease and the costs of electrolysers decline. However the realisation of this vision depends on the progress of scientific research and technical innovations that will reduce the costs of hydrogen production. Government support mechanisms for the development of hydrogen infrastructure and technologies will also be of key importance.
Decarbonisation and Hydrogen Integration of Steel Industries: Recent Development, Challenges and Technoeconomics Analysis
Feb 2023
Publication
The steel industry is one of the major sources of greenhouse gas emissions with significant energy demand. Currently 73% of the world’s steel is manufactured through the coal-coke-based blast furnace-basic oxygen furnace route (BF-BOF) emitting about two tonnes of CO2 per tonne of steel produced. This review reports the major technologies recent developments challenges and technoeconomic comparison of steelmaking technol ogies emphasising the integration of hydrogen in emerging and established ironmaking and steelmaking pro cesses. Significant trials are underway especially in Germany to replace coal injected in the tuyeres of the blast furnace with hydrogen. However it is not clear that this approach can be extended beyond 30% replacement of coke because of the associated technical challenges. Direct smelting and fluidised bed technologies can emit 20%–30% less CO2 without carbon capture and storage utilisation. The implications of hydrogen energy in these technologies as a substitute for natural gas and coal are yet to be fully explored. A hydrogen-based direct reduction of iron ore (DRI) and steel scrap melting in an electric arc furnace (EAF) appeared to be the most mature technological routes to date capable of reducing CO2 emission by 95% but rely on the availability of rich iron concentrates as feed materials. Shaft furnace technologies are the common DRI-making process with a share of over 72% of the total production. The technology has been developed with natural gas as the main fuel and reductant. However it is now being adapted to operate predominantly on hydrogen to produce a low-carbon DRI product. Plasma and electrolysis-based iron and steelmaking are some of the other potential technologies for the application of hydrogen with a CO2 reduction potential of over 95%. However these technologies are in the preliminary stage of development with a technology readiness level of below 6. There are many technological challenges for the application of hydrogen in steel manufacturing such as challenges in distributing heat due to the endothermic H2 reduction process balancing carbon content in the product steel (particularly using zerocarbon DRI) removal of gangue materials and sourcing of cost-competitive renewable hydrogen and highquality iron ore (65>Fe). As iron ore quality degrades worldwide several companies are considering melting DRI before steelmaking possibly using submerged arc technology to eliminate gangue materials. Hence sig nificant laboratory and pilot-scale demonstrations are required to test process parameters and product qualities. Our analysis anticipates that hydrogen will play an instrumental role in decarbonising steel industries by 2035.
Design Considerations and Preliminary Hydrodynamic Analysis of an Offshore Decentralised Floating Wind-hydrogen System
Sep 2024
Publication
Despite the number of works on the techno-economics of offshore green hydrogen production there is a lack of research on the design of floating platforms to concomitantly support hydrogen production facilities and wind power generation equipment. Indeed previous studies on offshore decentralised configuration for hydrogen production implicitly assume that a floating platform designed for wind power generation (FOWT) can be also suitable as a floating wind hydrogen system (FWHS). This work proposes a novel design for an offshore decentralised FWHS and analyses the effects of the integration of the hydrogen facilities on the platform’s dynamics and how this in turn affects the performances of the wind turbine and the hydrogen equipment. Our findings indicate that despite the reduction in platform’s stability the performance of the wind turbine is barely affected. Regarding the hydrogen system our results aim at contributing to further assessment and design of this equipment for offshore conditions.
Comprehensive Review of Carbon Capture and Storage Integration in Hydrogen Production: Opportunities, Challenges, and Future Perspectives
Oct 2024
Publication
The growing emphasis on renewable energy highlights hydrogen’s potential as a clean energy carrier. However traditional hydrogen production methods contribute significantly to carbon emissions. This review examines the integration of carbon capture and storage (CCS) technologies with hydrogen production processes focusing on their ability to mitigate carbon emissions. It evaluates various hydrogen production techniques including steam methane reforming electrolysis and biomass gasification and discusses how CCS can enhance environmental sustainability. Key challenges such as economic technical and regulatory obstacles are analyzed. Case studies and future trends offer insights into the feasibility of CCS–hydrogen integration providing pathways for reducing greenhouse gases and facilitating a clean energy transition.
Closed Loop Model Predictive Control of a Hybrid Battery-Hydrogen Energy Storage System using Mixed-Integer Linear Programming
Mar 2024
Publication
The derivation of an efficient operational strategy for storing intermittent renewable energies using a hybrid battery-hydrogen energy storage system is a difficult task. One approach for deriving an efficient operational strategy is using mathematical optimization in the context of model predictive control. However mathematical optimization derives an operational strategy based on a non-exact mathematical system representation for a specified prediction horizon to optimize a specified target. Thus the resulting operational strategies can vary depending on the optimization settings. This work focuses on evaluating potential improvements in the operational strategy for a hybrid batteryhydrogen energy storage system using mathematical optimization. To investigate the operation a simulation model of a hybrid energy storage system and a tailor-made mixed integer linear programming optimization model of this specific system are utilized in the context of a model predictive control framework. The resulting operational strategies for different settings of the model predictive control framework are compared to a rule-based controller to show the potential benefits of model predictive control compared to a conventional approach. Furthermore an in-depth analysis of different factors that impact the effectiveness of the model predictive controller is done. Therefore a sensitivity analysis of the effect of different electricity demands and resource sizes on the performance relative to a rule-based controller is conducted. The model predictive controller reduced the energy consumption by at least 3.9 % and up to 17.9% compared to a rule-based controller. Finally Pareto fronts for multi-objective optimizations with different prediction and control horizons are derived and compared to the results of a rule-based controller. A cost reduction of up to 47 % is achieved by a model predictive controller with a prediction horizon of 7 days and perfect foresight. Keywords: Model Predictive Control Optimization Mixed Integer Linear Programming Hybrid Battery-Hydrogen Energy Storage System
A Thermodynamically Consistent Methodology to Develop Predictive Simplified Kinetics for Detonation Simulations
Sep 2023
Publication
The number of species and elementary reactions needed for describing the oxidation of fuels increases with the size of the molecule and in turn the complexity of detailed mechanisms. Although the kinetics for conventional fuels (H2 CH4 C3H8...) are somewhat well-established chemical integration in detonation applications remains a major challenge. Significant efforts have been made to develop reduction techniques that aim to keep the predictive capabilities of detailed mechanisms intact while minimizing the number of species and reactions required. However as their starting point of development is based on homogeneous reactors or ZND profiles reduced mechanisms comprising a few species and reactions are not predictive. The methodology presented here relies on defining virtual chemical species such that the thermodynamic equilibrium of the ZND structure is properly recovered thereby circumventing the need to account for minor intermediate species. A classical asymptotic expression relating the ignition delay time with the reaction rate constant is then used to fit the Arrhenius coefficients targeting computations carried out with detailed kinetics. The methodology was extended to develop a three-step mechanism in which the Arrhenius coefficients were optimized to accurately reproduce the one-dimensional laminar ZND structure and the D−κ curves for slightly-curved quasi-steady detonation waves. Two-dimensional simulations performed with the three-step mechanism successfully reproduce the spectrum of length scales present in soot foils computed with detailed kinetics (i.e. cell regularity and size). Results attest for the robustness of the proposed methodology/approximation and its flexibility to be adapted to different configurations.
On the Green Transformation of the Iron and Steel Industry: Market and Competition Aspects of Hydrogen Biomass Options
Feb 2024
Publication
The iron and steel industry is a major emitter of carbon dioxide globally. To reduce their carbon footprint the iron and steel industry pursue different decarbonization strategies including deploying bio-based materials and energy carriers for reduction carburisation and/or energy purposes along their value-chains. In this study two potential roles for biomass were analysed: (a) substituting for fossil fuels in iron-ore pellets induration and (b) carburisation of DRI (direct reduced iron) produced via fully hydrogen-based reduction. The purpose of the study was to analyse the regional demand-driven price and allocative effects of biomass assortments under different biomass demand scenarios for the Swedish iron and steel industry. Economic modelling was used in combination with spatial biomass supply assessments to predict the changes on relevant biomass markets. The results showed that the estimated demand increases for forest biomass will have significant regional price effects. Depending on scenario the biomass demand will increase up to 25 percent causing regional prices to more than doubling. In general the magnitude of the price effects was driven by the volumes and types of biomasses needed in the different scenarios with larger price effects for harvesting residues and industrial by-products compared to those of roundwood. A small price effect of roundwood means that the incentives for forest-owners to increase their harvests and thus also the availability of harvest residues are small. Flexibility in the feedstock sourcing (both regarding quality and geographic origin) will thus be important if forest biomass is to satisfy demands in iron and steel industry.
The Impact of the Configuration of a Hydrogen Refueling Station on Risk Level
Nov 2024
Publication
The paper discusses potential hazards at hydrogen refueling stations for transportation vehicles: cars and trucks. The main hazard analyzed here is an uncontrolled gas release due to a failure in one of the structures in the station: storage tanks of different pressure levels or a dispenser. This may lead to a hydrogen cloud occurring near the source of the release or at a given distance. The range of the cloud was analyzed in connection to the amount of the released gas and the wind velocity. The results of the calculations were compared for chosen structures in the station. Then potential fires and explosions were investigated. The hazard zones were calculated with respect to heat fluxes generated in the fires and the overpressure generated in explosions. The maximum ranges of these zones vary from about 14 to 30 m and from about 9 to 14 m for a fires and an explosions of hydrogen respectively. Finally human death probabilities are presented as functions of the distance from the sources of the uncontrolled hydrogen releases. These are shown for different amounts and pressures of the released gas. In addition the risk of human death is determined along with the area where it reaches the highest value in the whole station. The risk of human death in this area is 1.63 × 10−5 [1/year]. The area is approximately 8 square meters.
Experimental Study of the Mitigation of Hydrogen-Air Explosions by Inhibiting Powder
Sep 2023
Publication
The development of hydrogen production technologies and new uses represents an opportunity to accelerate the ecological transition and create a new industrial sector. However the risks associated with the use of hydrogen must be considered. Mitigation of a hydrogen explosion in an enclosure is partly based on prevention strategies such as detection and ventilation and protection strategies such as explosion venting. Even if applications involving hydrogen probably are most interesting for vented explosions in weak structures the extreme reactivity of hydrogen-air mixtures often excludes the use of regular venting devices such as in highly constrained urban environments. Thus having alternative mitigation solutions can make the effects of the explosion acceptable by reducing the flame speed and the overpressure loading or suppressing the secondary explosion. The objective of this paper is to present experimental studies of the mitigation of hydrogen-air deflagration in a 4 m3 vented enclosure by injection of inhibiting powder (NaHCO₃). After describing the experimental set-up the main experimental results are presented for several trial configurations showing the influence of inhibiting powder in the flammable cloud on flame propagation. An interpretation of the mitigating effect of inhibiting powder on the explosion effects is proposed based on the work of Proust et al.
Explosion Free in Fire Self-venting (TPRD-less) Composite Tanks: Performance Under Fire Intervention Conditions
Sep 2023
Publication
This paper describes the performance of explosion free in fire self-venting (TPRD-less) composite tanks of Type IV in fires of realistic intensity HRR/A=1 MW/m2 in conditions of first responders’ intervention. This breakthrough safety technology does not require the use of thermally activated pressure relief devices (TPRD). It provides microleaks-no-burst (LNB) performance of high-pressure hydrogen storage tanks in a fire. Two fire intervention strategies are investigated one is the removal of a vehicle with LNB tank from the fire and another is the extinction of the fire. The removal from the fire scenario is investigated for one carbon-carbon and one carbon-basalt double-composite wall tank prototype. The fire extinction scenario is studied for four carbon-basalt prototypes. All six prototypes of 7.5 L volume and nominal working pressure of 70 MPa demonstrated safe release of hydrogen through microchannels of the composite wall after melting a liner. The technology allows fire brigades to apply standard intervention strategies and tactics at the fire scene with hydrogen vehicles if LNB tanks are used in the vehicle.
Near-term Infrastructure Rollout and Investment Strategies for Net-zero Hydrogen Supply Chains
Feb 2024
Publication
Low-carbon hydrogen plays a key role in European industrial decarbonization strategies. This work investigates the cost-optimal planning of European low-carbon hydrogen supply chains in the near term (2025–2035) comparing several hydrogen production technologies and considering multiple spatial scales. We focus on mature hydrogen production technologies: steam methane reforming of natural gas biomethane reforming biomass gasification and water electrolysis. The analysis includes carbon capture and storage for natural gas and biomass-derived hydrogen. We formulate and solve a linear optimization model that determines the costoptimal type size and location of hydrogen production and transport technologies in compliance with selected carbon emission targets including the EU fit for 55 target and an ambitious net-zero emissions target for 2035. Existing steam methane reforming capacities are considered and optimal carbon and biomass networks are designed. Findings identify biomass-based hydrogen production as the most cost-efficient hydrogen technology. Carbon capture and storage is installed to achieve net-zero carbon emissions while electrolysis remains costdisadvantageous and is deployed on a limited scale across all considered sensitivity scenarios. Our analysis highlights the importance of spatial resolution revealing that national perspectives underestimate costs by neglecting domestic transport needs and regional resource constraints emphasizing the necessity for highly decarbonized infrastructure designs aligned with renewable resource availabilities.
Investments in Green Hydrogen as a Flexibility Source for the European Power System by 2050: Does it Pay Off?
Oct 2024
Publication
The European Union aims to deploy a high share of renewable energy sources in Europe’s power system by 2050. Large-scale intermittent wind and solar power production requires flexibility to ensure an adequate supply–demand balance. Green hydrogen (GH) can increase power systems’ flexibility and decrease renewable energy production’s curtailment. However investing in GH is costly and dependent on electricity prices which are important for operational costs in electrolysis. Moreover the use of GH for power system flexibility might not be economically viable if there is no hydrogen demand from the hydrogen market. If so questions would arise as to what would be the incentives to introduce GH as a source of flexibility in the power system and how would electrolyzer costs hydrogen demand and other factors affect the economic viability of GH usage for power system flexibility. The paper implements a European power system model formulated as a stochastic program to address these questions. The authors use the model to compare various instances with hydrogen in the power system to a no-hydrogen instance. The results indicate that by 2050 deployment of approximately 140 GW of GH will pay off investments and make the technology economically viable. We find that the price of hydrogen is estimated to be around €30/MWh.
Technical and Cost Analysis of Zero-emission High-speed Ferries: Retrofitting from Diesel to Green Hydrogen
Feb 2024
Publication
This paper proposes a technical and cost analysis model to assess the change in costs of a zeroemission high-speed ferry when retrofitting from diesel to green hydrogen. Both compressed gas and liquid hydrogen are examined. Different scenarios explore energy demand energy losses fuel consumption and cost-effectiveness. The methodology explores how variation in the ferry's total weight and equipment efficiency across scenarios impact results. Applied to an existing diesel high-speed ferry on one of Norway's longest routes the study under certain assumptions identifies compressed hydrogen gas as the current most economical option despite its higher energy consumption. Although the energy consumption of the compressed hydrogen ferry is slightly more than the liquid hydrogen counterpart its operating expenses are considerably lower and comparable to the existing diesel ferry on the route. However constructing large hydrogen liquefaction plants could reduce liquid hydrogen's cost and make it competitive with both diesel and compressed hydrogen gas. Moreover liquid hydrogen allows the use of a superconducting motor to enhance efficiency. Operating the ferry with liquid hydrogen and a superconducting motor besides its technical advantages offers promising economic viability in the future comparable to diesel and compressed hydrogen gas options. Reducing the ferry's speed and optimizing equipment improves fuel efficiency and economic viability. This research provides valuable insights into sustainable zero-emission high-speed ferries powered by green hydrogen.
Analysis of Operational Parameters and Emissions in a Domestic Natural Gas Heating Appliance with Hydrogen Blending
Dec 2024
Publication
The weather-dependent nature of renewable energy production has led to periodic overproduction making hydrogen production a practical solution for storing excess energy. In addition to conventional storage methods such as physical tanks or chemical bonding using the existing natural gas network as a storage medium has also proven to be effective. Households can play a role in this process as well. The purpose of these experiments is to evaluate the parameters of a household heating device currently in use but not initially designed for hydrogen operation. The appliance used in the tests has a closed combustion chamber with a natural draft induced by a density difference which is a common type. The tests were conducted at nominal load with a mix of 0–40 V/V% hydrogen and natural gas; no flashbacks or other issues occurred. As the hydrogen ratio increased from 0 to 40 V/V% the input heat decreased from 3.9 kW to 3.4 kW. The NOx concentration in the flue gas dropped from 26.2 ppm to 14.2 ppm and the CO2 content decreased from 4.5 V/V% to 3.4 V/V%. However the CO con centration slightly increased from 40.0 ppm to 44.1 ppm. Despite these changes efficiency remained stable fluctuating between 86.9% and 87.0%. The internal flame cone height was 3.27 mm when using natural gas but reduced sharply to just 0.38 mm when using 62 V/V% hydrogen. In addition to the fact that the article examines a group of devices that has been rarely investigated but is also widely distributed it also provides valuable experience for other experiments since the experiments were carried out with a higher hydrogen ratio compared to previous works.
CFD Simulations of Hydrogen Tank Fuelling: Sensitivity to Turbulence Model and Grid Resolution
Dec 2023
Publication
CFD modelling of compressed hydrogen fuelling provides information on the hydrogen and tank structure temperature dynamics required for onboard storage tank design and fuelling protocol development. This study compares five turbulence models to develop a strategy for costeffective CFD simulations of hydrogen fuelling while maintaining a simulation accuracy acceptable for engineering analysis: RANS models k-ε and RSM; hybrid models SAS and DES; and LES model. Simulations were validated against the fuelling experiment of a Type IV 29 L tank available in the literature. For RANS with wall functions and blended models with near-wall treatment the simulated average hydrogen temperatures deviated from the experiment by 1–3% with CFL ≈ 1–3 and dimensionless wall distance y + ≈ 50–500 in the tank. To provide a similar simulation accuracy the LES modelling approach with near-wall treatment requires mesh with wall distance y + ≈ 2–10 and demonstrates the best-resolved flow field with larger velocity and temperature gradients. LES simulation on this mesh however implies a ca. 60 times longer CPU time compared to the RANS modelling approach and 9 times longer compared to the hybrid models due to the time step limit enforced by the CFL ≈ 1.0 criteria. In all cases the simulated pressure histories and inlet mass flow rates have a difference within 1% while the average heat fluxes and maximum hydrogen temperature show a difference within 10%. Compared to LES the k-ε model tends to underestimate and DES tends to overestimate the temperature gradient inside the tank. The results of RSM and SAS are close to those of LES albeit of 8–9 times faster simulations.
Design of Long-Life Wireless Near-Field Hydrogen Gas Sensor
Sep 2023
Publication
A wireless near-field hydrogen gas sensor is proposed which detects the leaking hydrogen near its source to achieve fast response and high reliability. The proposed sensor can detect leaking hydrogen in 100ms with nearly no delay due to hydrogen diffusion in space. The overall response time is shortened by orders of magnitude compared to conventional sensors according to simulation results. Over 1 year of maintenance interval is empowered by wireless design based on Bluetooth low energy protocol.
Accidental Releases of Hydrogen in Maintenance Garages: Modelling and Assessment
Sep 2023
Publication
This study investigates the light gas dispersion behaviour in a maintenance garage with natural or forced ventilation. A scaled-down garage model (0.71 m high 3.07 m long and 3.36 m wide) equipped with gas and velocity sensors was used in the experiments. The enclosure had four rectangular vents at the ceiling and four at the bottom on two opposing side walls. The experiments were performed by injecting helium continuously through a 1-mm downward-facing nozzle until a steady state was reached. The sensitivity parameters included helium injection rate the elevation of the injection nozzle and forced flow speeds. Exhaust fans were placed at one or all of the top vent(s) to mimic forced ventilation. Numerical simulations conducted using GOTHIC a general-purpose thermal-hydraulic code and calculations with engineering models were compared with experimental measurements to determine the relative suitability of each approach to predict the light gas transport behaviour. The GOTHIC simulations captured the trends of the helium distribution gas movement in the enclosure and the passive vent flows reasonably well. Lowesmith’s model predictions for the helium transients in the upper uniform layer were also in good agreement with the natural venting experiments.
Techno-economic Analysis of Direct Air Carbon Capture and Hydrogen Production Integrated with a Small Modular Reactor
Dec 2023
Publication
This study aims to explore the techno-economic potential of harnessing waste heat from a Small Modular Reactor (SMR) to fuel Direct Air Carbon Capture (DACC) and High Temperature Steam Electrolysis (HTSE) technologies. The proposed system’s material flows and energy demands are modelled via the ASPEN Plus v12.1 where results are utilised to provide estimates of the Levelised Cost of DACC (LCOD) and Levelised Cost of Hydrogen (LCOH). The majority of thermal energy and electrical utilities are assumed to be supplied directly by the SMR. A sensitivity analysis is then performed to investigate the effects of core operational parameters of the system. Key results indicate levelised costs of 4.66 $/kgH2 at energy demands of 34.37 kWh/kgH2 and 0.02 kWh/kgH2 thermal for HTSE hydrogen production and 124.15 $/tCO2 at energy demands of 31.67 kWh/tCO2 and 126.33 kWh/tCO2 thermal for carbon capture; parameters with most impact on levelised costs are air intake and steam feed for LCOD and LCOH respectively. Both levelised costs i.e. LCOD and LCOH would decrease with the production scale. The study implies that an integrated system of DACC and HTSE provided the best cost-benefit results however the cost-benefit analysis is heavily subjective to geography politics and grid demand.
Performance Comparison of Hydrogen Dispersion Models in Enclosure Adapted to Forced Ventilation
Sep 2023
Publication
In confined spaces hydrogen released with low momentum tends to accumulate in a layer below the ceiling; the concentration in this layer rises and can rapidly enter the flammability range. In this context ventilation is a key safety equipment to prevent the formation of such flammable volumes. To ensure its well-sizing to each specific industrial context it is necessary to dispose of reliable engineering models. Currently the existing engineering models dealing with the buoyancy-driven H2 dispersion in a ventilated enclosure mainly focus on the natural-ventilation phenomenon. However forced ventilation is in some situations more adapted to the industrial context as the wind direction and intensity remains constant and under control. Therefore two existing wind-assisted ventilation models elaborated by Hunt and Linden [1] and Lowesmith et al. [2] were tested on forced ventilation applications. The main assumption consists in assuming a blowing ventilation system rather than a suction system as the composition and velocity of the entering air are known. The fresh air enters the down opening and airhydrogen mixture escapes through the upper one. The adapted models are then validated with experimental data releasing helium rather than hydrogen. Experiments are conducted on a 1-m3 ventilated box controlling the release and ventilation rates. The agreement between both analytical and experimental results is discussed from the different comparisons performed.
Study on Liquid Hydrogen Leakage and Diffusion Behavior in a Hydrogen Production Station
Jun 2024
Publication
Liquid hydrogen storage is an important way of hydrogen storage and transportation which greatly improves the storage and transportation efficiency due to the high energy density but at the same time brings new safety hazards. In this study the liquid hydrogen leakage in the storage area of a hydrogen production station is numerically simulated. The effects of ambient wind direction wind speed leakage mass flow rate and the mass fraction of gas phase at the leakage port on the diffusion behavior of the liquid hydrogen leakage were investigated. The results show that the ambient wind direction directly determines the direction of liquid hydrogen leakage diffusion. The wind speed significantly affects the diffusion distance. When the wind speed is 6 m/s the diffusion distance of the flammable hydrogen cloud reaches 40.08 m which is 2.63 times that under windless conditions. The liquid hydrogen leakage mass flow rate and the mass fraction of the gas phase have a greater effect on the volume of the flammable hydrogen cloud. As the leakage mass flow rate increased from 5.15 kg/s to 10 kg/s the flammable hydrogen cloud volume increased from 5734.31 m3 to 10305.5 m3 . The installation of a barrier wall in front of the leakage port can limit the horizontal diffusion of the flammable hydrogen cloud elevate the diffusion height and effectively reduce the volume of the flammable hydrogen cloud. This study can provide theoretical support for the construction and operation of hydrogen production stations.
An Overview of Hydrogen Valleys: Current Status, Challenges and their Role in Increased Renewable Energy Penetration
Sep 2024
Publication
Renewable hydrogen is a flexible and versatile energy vector that can facilitate the decarbonization of several sectors and simultaneously ease the stress on the electricity grids that are currently being saturated with intermittent renewable power. But hydrogen technologies are currently facing limitations related to existing infrastructure limitations available markets as well as production storage and distribution costs. These challenges will be gradually addressed through the establishment operation and scaling-up of hydrogen valleys. Hydrogen valleys are an important stepping stone towards the full-scale implementation of the hydrogen economy with the target to foster sustainability lower carbon emissions and derisk the associated hydrogen technologies. These hydrogen ecosystems integrate renewable energy sources efficient hydrogen production storage transportation technologies as well as diverse end-users within a defined geographical region. This study offers an overview of the hydrogen valleys concept analyzing the critical aspects of their design and the key segments that constitute the framework of a hydrogen valley. А holistic overview of the key characteristics of a hydrogen valley is provided whereas an overview of key on-going hydrogen valley projects is presented. This work underscores the importance of addressing challenges related to the integration of renewable energy sources into electricity grids as well as scale-up challenges associated with economic and market conditions society awareness and political decision-making.
Risky Business? Evaluating Hydrogen Partnerships Established by Germany, The Netherlands, and Belgium
Dec 2023
Publication
Following the introduction of the EU’s Hydrogen Strategy in 2020 as part of the European Green Deal some EU member states have deployed a very active hydrogen diplomacy. Germany The Netherlands and Belgium have been the most active ones establishing no less than 40 bilateral hydrogen trade partnerships with 30 potential export countries in the last three years. However concerns have been voiced about whether such hydrogen trade relationships can be economically feasible geopolitically wise environmentally sustainable and socially just. This article therefore evaluates these partnerships considering three risk dimensions: economic political and sustainability (covering both environmental and justice) risks. The analysis reveals that the selection of partner countries entails significant trade-offs. Four groups of partner countries can be identified based on their respective risk profile: “Last Resorts” “Volatile Ventures” “Strategic Gambits” and “Trusted Friends”. Strikingly less than one-third of the agreements are concluded with countries that fall within the “Trusted Friends” category which have the lowest overall risk profile. These findings show the need for policy makers to think much more strategically about which partnerships to pursue and to confront tough choices about which risks and trade-offs they are willing to accept.
A Review on the Research Progress and Application of Compressed Hydrogen in the Marine Hydrogen Fuel Cell Power System
Jan 2024
Publication
The urgency to mitigate greenhouse gas emissions from maritime vessels has intensified due to the increasingly stringent directives set forth by the International Maritime Organization (IMO). These directives specifically address energy efficiency enhancements and emissions reduction within the shipping industry. In this context hydrogen is the much sought after fuel for all the global economies and its applications for transportation and propulsion in particular is crucial for cutting down carbon emissions. Nevertheless the realization of hydrogen-powered vessels is confronted by substantial technical hurdles that necessitate thorough examination. This study undertakes a comprehensive analysis encompassing diverse facets including distinct variations of hydrogen fuel cells hydrogen internal combustion engines safety protocols associated with energy storage as well as the array of policies and commercialization endeavors undertaken globally for the advancement of hydrogen-propelled ships. By amalgamating insights from these multifaceted dimensions this paper adeptly encapsulates the myriad challenges intrinsic to the evolution of hydrogen-fueled maritime vessels while concurrently casting a forward-looking gaze on their prospective trajectory.
The Potential of Polymers and Glass to Enhance Hydrogen Storage Capicity: A Mathematical Approach
Dec 2024
Publication
This manuscript contributes to understanding the role of hydrogen in different materials emphasizing polymers and composite materials to increase hydrogen storage capacity in those materials. Hydrogen storage is critical in advancing and optimizing sustainable energy solutions that are essential for improving their performance. Capillary arrays which offer increased surface area and optimized storage geometries present a promising avenue for enhancing hydrogen uptake. This work evaluates various polymers and glass for their mechanical properties and strength with 700 bar inner pressure loads within capillary tubes. A theoretical mathematical approach was employed to quantify the impact of material properties on storage capacity. Our results demonstrate that certain polymers (e.g. Zylon AS Dyneema SK99) and glass types (S-2 Glass) exhibit superior hydrogen storage potential due to their enhanced strength and low density. These findings suggest that integrating the proposed materials into capillary array systems can significantly improve hydrogen storage efficiency (15–37 wt.% and 37–40 g/L) making them viable candidates for next-generation energy storage systems. This study provides valuable insights into material selection and structural design strategies for high-capacity hydrogen storage technologies.
Review on Techno-economics of Hydrogen Production Using Current and Emerging Processes: Status and Perspectives
Feb 2024
Publication
This review presents a broad exploration of the techno economic evaluation of different technologies utilized in the production of hydrogen from both renewable and non-renewable sources. These encompass methods ranging from extracting hydrogen from fossil fuels or biomass to employing microbial processes electrolysis of water and various thermochemical cycles. A rigorous techno-economic evaluation of hydrogen production technologies can provide a critical cost comparison for future resource allocation priorities and trajectory. This evaluation will have a great impact on future hydrogen production projects and the development of new approaches to reduce overall production costs and make it a cheaper fuel. Different methods of hydrogen production exhibit varying efficiencies and costs: fast pyrolysis can yield up to 45% hydrogen at a cost range of $1.25 to $2.20 per kilogram while gasification operating at temperatures exceeding 750°C faces challenges such as limited small-scale coal production and issues with tar formation in biomass. Steam methane reforming which constitutes 48% of hydrogen output experiences cost fluctuations depending on scale whereas auto-thermal reforming offers higher efficiency albeit at increased costs. Chemical looping shows promise in emissions reduction but encounters economic hurdles and sorptionenhanced reforming achieves over 90% hydrogen but requires CO2 storage. Renewable liquid reforming proves effective and economically viable. Additionally electrolysis methods like PEM aim for costs below $2.30 per kilogram while dark fermentation though cost-effective grapples with efficiency challenges. Overcoming technical economic barriers and managing electricity costs remains crucial for optimizing hydrogen production in a low-carbon future necessitating ongoing research and development efforts.
The Latest Voyage of Discovery - Quantifying the Consequences of LH2 Releases for the Marine Industry
Sep 2023
Publication
Following a desktop study undertaken in 2021 to identify hazard scenarios associated with the use of liquid and compressed hydrogen on commercial shipping Shell has started a programme of large-scale experiments on the consequences of a release of liquid hydrogen. This work will compliment on-going research Shell has sponsored within several joint industry projects but will also address immediate concerns that the maritime industry has for the transportation of liquid hydrogen (LH2). This paper will describe the first phase of experiments involving the release of LH2 onto various substrates as well as dispersion across an instrumented test pad. These results will be used to address the following uncertainties in risk assessments within the hydrogen economy such as (1) Quantify the impact of low wind speed and high humidity on the buoyancy of both a passive and momentum jet dispersion cloud (2) Gather additional data on liquid hydrogen jet fires (3) Understand the likelihood for the formation of a sustained pool of hydrogen (4) Characterise materials especially passive fire protective coatings that are exposed to LH2. Not only will these experiments generate validation data to provide confidence in the Shell consequence tool FRED but they will also be used by Shell to support updates and new regulations developed by the International Maritime Organisation as it seeks to reduce CO2 intensity in the maritime industry.
Techno-economic Analysis of Stand-alone Hybrid PV-Hydrogen-Based Plug-in Electric Vehicle Charging Station
Sep 2024
Publication
The increase in the feasibility of hydrogen-based generation makes it a promising addition to the realm of renewable energies that are being employed to address the issue of electric vehicle charging. This paper presents technical and an economical approach to evaluate a newer off-grid hybrid PV-hydrogen energy-based recharging station in the city of Jamshoro Pakistan to meet the everyday charging needs of plug-in electric vehicles. The concept is designed and simulated by employing HOMER software. Hybrid PV-hydrogen and PV-hydrogenbattery are the two different scenarios that are carried out and compared based on their both technical as well as financial standpoints. The simulation results are evident that the hybrid PV- hydrogen-battery energy system has much more financial and economic benefits as compared with the PV-hydrogen energy system. Moreover it is also seen that costs of energy from earlier from hybrid PV-hydrogen-battery is more appealing i.e. 0.358 $/kWh from 0.412 $/kWh cost of energy from hybrid PV-hydrogen. The power produced by the hybrid PV- hydrogen - battery energy for the daily load demand of 1700 kWh /day consists of two powers produced independently by the PV and fuel cells of 87.4 % and 12.6 % respectively.
Elevating Sustainability with a Multi-Renewable Hydrogen Generation System Empowered by Machine Learning and Multi-objective Optimisation
Apr 2024
Publication
The global energy landscape is rapidly shifting toward cleaner lower-carbon electricity generation necessitating a transition to alternate energy sources. Hydrogen particularly green hydrogen looks to be a significant solution for facilitating this transformation as it is produced by water electrolysis with renewable energy sources such as solar irradiations wind speed and biomass residuals. Traditional energy systems are costly and produce energy slowly due to unpredictability in resource supply. To address this challenge this work provides a novel technique that integrates a multi-renewable energy system using multi objective optimization algorithm to meets the machine learning-based forecasted load model. Several forecasting models including Autoregressive Integrated Moving Average(ARIMA) Random Forest and Long Short-Term Memory Recurrent Neural Network (LSTMRNN) are assessed for develop the statistical metrics values such as RMSE MAE and MAPE. The selected Non-Sorting Moth Flame Optimization (NSMFO) algorithm demonstrates technological prowess in efficiently achieving global optimization particularly when handling multiple objective functions. This integrated method shows enormous promise in technological economic and environmental terms emphasizing its ability to promote energy sustainability targets.
Utilization of Hydrogen and Methane as Energy Carriers with Exhaust Gas Recirculation for Sustainable Diesel Engines
May 2024
Publication
Hydrogen and methane as secondary fuels in diesel engines can be promising solutions to meet energy demand. The current study investigated the effect of the specialty gases of different compositions on diesel engine performance and exhaust gases. Four gases with various compositions of exhaust gas recirculation (Carbon monoxide Carbon dioxide and Nitrogen) and fuels (Hydrogen and Methane) were used at various mass flow rates of 10 20 and 25 LPM (liter per minute) and various engine speeds of 2000 2500 3000 and 3500 rpm (revolutions per minute). The procured results revealed that adding specialty gases improved brake thermal efficiency and power. Similarly the brake-specific fuel consumption was also massively retarded compared to diesel due to the influence of the hydrogen and methane composition. However the fuel with the higher nitrogen reported less BTE (brake thermal efficiency) and comparatively higher exhaust gas temperature owing to the higher presence of nitrogen in their composition. Regarding emissions including exhaust gas recirculation dropped the formation of pollutants efficiently compared to diesel. Among various fuels Case 1 (30 % H2 5 % CH4 5 CO2 and 60 % CO) reported the lowest emission of NOx and Case 2 (25 % H2 5 % CH4 5 CO2 30 % CO and 35 % N2) of CO and CO2 emissions. Generally specialty gases with a variable composition of exhaust gas recirculation gases can be a promising sustainable replacement for existing fossil fuels.
Very Low-cost Wireless Hydrogen Leak Detection for Hydrogen Infrastructure
Sep 2023
Publication
A unique hydrogen leak detection strategy is the use of powerless indicator wraps for fittings and other pneumatic elements within a hydrogen facility. One transduction mechanism of such indicators is a color change that is induced by a reaction between a pigment and released hydrogen. This is an effective way to detect hydrogen leaks and to identify their source before they become a safety event however this technology requires visual (manual) inspection to identify a color change or leak. One improvement in this strategy would be to improve the communication of the visual response to an end-user. Element One (E1) has previously developed and introduced DetecTape® a self-fusing silicone non-reversible hydrogen leak detecting tape for application to potential leak sites in hydrogen piping valves and fittings and it has been successfully commercialized with excellent feedback. Element One’s sensors can be fabricated using either pigments or thin films which both change color and conductivity. Neither change requires an external power source. The conductivity change may be communicated as a wireless transmission such as passive radio frequency identification devices (RFID) to an appropriate receiving system where it may be remotely monitored to achieve higher levels of safety and reliability at low cost. Element One will report on its recent progress in the commercial development of remotely monitored hydrogen leak detection using several wireless protocols including passive RFID.
Model for Hydrogen Production Scheduling Optimisation
Feb 2024
Publication
This scientific article presents a developed model for optimising the scheduling of hydrogen production processes addressing the growing demand for efficient and sustainable energy sources. The study focuses on the integration of advanced scheduling techniques to improve the overall performance of the hydrogen electrolyser. The proposed model leverages constraint programming and satisfiability (CP-SAT) techniques to systematically analyse complex production schedules considering factors such as production unit capacities resource availability and energy costs. By incorporating real-world constraints such as fluctuating energy prices and the availability of renewable energy the optimisation model aims to improve overall operational efficiency and reduce production costs. The CP-SAT was applied to achieve more efficient control of the electrolysis process. The optimisation of the scheduling task was set for a 24 h time period with time resolutions of 1 h and 15 min. The performance of the proposed CP-SAT model in this study was then compared with the Monte Carlo Tree Search (MCTS)-based model (developed in our previous work). The CP-SAT was proven to perform better but has several limitations. The model response to the input parameter change has been analysed.
An Improved MPC-based Energy Management Strategy for Hydrogen Fuel Cell Evs Featuring Dual-motor Coupling Powertrain
Mar 2025
Publication
Hydrogen fuel cell electric vehicles (HFCEVs) provide significant environmental benefits. Integrating dual-motor coupling powertrains (DMCPs) further enhances efficiency and dynamic performance. This article proposes an energy management strategy (EMS) for the hydrogen fuel cell/battery/super-capacitor system in an HFCEV with DMCP. Model predictive control (MPC) is adopted as the framework to optimize economic performance defined in this study as the hydrogen consumption cost and fuel cell degradation cost. To improve the prediction horizon and accuracy the torque split ratio for two varying permanent magnet synchronous motors (PMSMs) and the corresponding mode switching rules of the vehicle are initially established. Subsequently a combination of Dynamic Programming (DP) and MPC is selected as the framework utilizing a Dung Beetle Optimizer (DBO)-optimized Bidirectional Long Short-Term Memory (BiLSTM) network to refine the predictive model. Finally comparisons with other predictive models and commonly used control strategies demonstrate that the proposed EMS notably improves economic performance.
Review of the Hydrogen Supply Chain and Use in Africa
Oct 2024
Publication
The high potential in renewable energy sources (RES) and the availability of strategic minerals for green hydrogen technologies place Africa in a promising position for the development of a climate-compatible economy leveraging on hydrogen. This study reviews the potential hydrogen value chain in Africa considering production and final uses while addressing perspectives on policies possible infrastructures and facilities for hydrogen logistics. Through scientific studies research and searching in relevant repositories this review features the collection analysis of technical data and georeferenced information about key aspects of the hydrogen value chain. Detailed maps and technical data for gas transport infrastructure and liquefaction terminals in the continent are reported to inform and elaborate findings about readiness for hydrogen trading and domestic use in Africa. Specific maps and technical data have been also collected for the identification of potential hydrogen offtakers focusing on individual industrial installations to produce iron and steel chemicals and oil refineries. Finally georeferenced data are presented for main road and railway corridors as well as for most important African ports as further end-use and logistic platforms. Beyond technical information this study collects and discusses more recent perspectives about policies and implementation initiatives specifically addressing hydrogen production logistics and final use also introducing potential criticalities associated with environmental and social impacts.
HyDeploy2 - Gas Network Innovation Competition: Cadent 5th Project Progress Report
Jan 2024
Publication
The HyDeploy2 project seeks to address a key issue for UK energy customers: how to reduce the carbon they emit in heating their homes. The UK has a world class gas grid delivering heat conveniently and safely to more than 83% of homes. Emissions can be reduced by lowering the carbon content of gas through blending with hydrogen. This delivers carbon savings without customers requiring disruptive and expensive changes in their homes. It also provides the platform for deeper carbon savings by enabling wider adoption of hydrogen across the energy system.
Comparison Between Hydrogen and Syngas Fuels in an Integrated Micro Gas Turbine/Solar Field with Storage
Sep 2020
Publication
In recent years the use of alternative fuels in thermal engine power plants has gained more and more attention becoming of paramount importance to overcome the use of fuels from fossil sources and to reduce polluting emissions. The present work deals with the analysis of the response to two different gas fuels—i.e. hydrogen and a syngas from agriculture product—of a 30 kW micro gas turbine integrated with a solar field. The solar field included a thermal storage system to partially cover loading requests during night hours reducing fuel demand. Additionally a Heat Recovery Unit was included in the plant considered and the whole plant was simulated by Thermoflex® code. Thermodynamics analysis was performed on hour-to-hour basis for a given day as well as for 12 months; subsequently an evaluation of cogeneration efficiency as well as energy saving was made. The results are compared against plant performance achieved with conventional natural gas fueling. After analyzing the performance of the plant through a thermodynamic analysis the study was complemented with CFD simulations of the combustor to evaluate the combustion development and pollutant emissions formation particularly of NOx with the two fuels considered using Ansys-Fluent code and a comparison was made.
Power and Green Hydrogen Trade Potential between North African and European Countries: Conditions, Challenges, and Sustainability Prospects
Dec 2024
Publication
This study investigates the implications of hydrogen demand and trade between Europe and North Africa emphasizing how renewable energy system (RES) capacity limitations impact both regions. Growing hydrogen demand for decarbonization has fueled interest in North Africa’s potential to export green hydrogen to Europe. Using the eTIMES-EUNA model this study examines how demand trade and RES development challenges shape the energy landscapes of both regions. The findings indicate that hydrogen demand amplifies renewable electricity requirements in both regions with Europe particularly benefiting from importing hydrogen to alleviate additional RES capacity installation. Hydrogen trade reduces overall costs by 1 % yet it shifts a considerable financial burden onto North Africa demanding a rapid RES capacity expansion at a rate significantly higher than the current pace. Slower RES development in North Africa could hinder the region’s ability to meet both domestic and export targets thereby complicating Europe’s hydrogen sourcing strategies which are also challenged by social acceptance issues that limit RES deployment. These constraints in Europe necessitate adjustments to the technological mix and place additional pressure on North Africa to increase production. Furthermore the varying implications and stakes at the national level highlight the need for further analysis as individual countries may prioritize their own interests potentially leading to conflicts with neighboring nations under different development schemes. Consequently the results underscore the importance of coordinated financial and policy support to ensure equitable trade that aligns with both regions’ sustainability goals.
Environmental and Climate Impacts of a Large-scale Deployment of Green Hydrogen in Europe
Apr 2024
Publication
Green hydrogen is expected to play a vital role in decarbonizing the energy system in Europe. However large-scale deployment of green hydrogen has associated potential trade-offs in terms of climate and other environmental impacts. This study aims to shed light on a comprehensive sustainability assessment of this large-scale green hydrogen deployment based on the EMPIRE energy system modeling compared with other decarbonization paths. Process-based Life Cycle Assessment (LCA) is applied and connected with the output of the energy system model revealing 45% extra climate impact caused by the dedicated 50% extra renewable infrastructure to deliver green hydrogen for the demand in the sectors of industry and transport in Europe towards 2050. Whereas the analysis shows that green hydrogen eventually wins on the climate impact within four designed scenarios (with green hydrogen with blue hydrogen without green hydrogen and baseline) mainly compensated by its clean usage and renewable electricity supply. On the other hand green hydrogen has a lower performance in other environmental impacts including human toxicity ecotoxicity mineral use land use and water depletion. Furthermore a monetary valuation of Life Cycle Impact (LCI) is estimated to aggregate 13 categories of environmental impacts between different technologies. Results indicate that the total monetized LCI cost of green hydrogen production is relatively lower than that of blue hydrogen. In overview a large-scale green hydrogen deployment potentially shifts the environmental pressure from climate and fossil resource use to human health mineral resource use and ecosystem damage due to its higher material consumption of the infrastructure.
A New Integrated System for Carbon Capture and Clean Hydrogen Production for Sustainable Societal Utilization
Oct 2024
Publication
Hydrogen production and carbon dioxide removal are considered two of the critical pieces to achieve ultimate sustainability target. This study proposes and investigates a new variation of potassium hydroxide thermochemical cycle in order to combine hydrogen production and carbon dioxide removal synergistically. An alkali metal redox thermochemical cycle developed where the potassium hydroxide is considered by using a nonequilibrium reaction. Also the multigeneration options are explored by using two stage steam Rankine cycle multi-effect distillation desalination Li-Br absorption chiller which are integrated with potassium hydroxide thermochemical cycle for hydrogen production carbon capture power generation water desalination and cooling purposes. A comparative assessment under different scenarios is carried out. The energy and exergy efficiencies of the hydrogen production thermochemical cycle are 44.2% and 67.66% when the hydrogen generation reaction is carried out at 180°C and the separation reactor temperature set at 400°C. Among the multigeneration scenarios a trigeneration option of hydrogen power and water indicates the highest energy efficiency as 66.02%.
Optimal Expansion of a Multi-domain Virtual Power Plant for Green Hydrogen Production to Decarbonise Seaborne Passenger Transportation
Nov 2023
Publication
Many industrialised nations recently concentrated their focus on hydrogen as a viable option for the decarbonisation of fossil-intensive sectors including maritime transportation. A sustainable alternative to the conventional production of hydrogen based on fossil hydrocarbons is water electrolysis powered by renewable energy sources. This paper presents a detailed techno-economic optimisation model for sizing an electrolyser and a hydrogen storage embedded in a multi-domain virtual power plant to produce green hydrogen for seaborne passenger transportation. We base our numerical analysis on three years of historical data from a renewable-dominated 60/10 kV substation on the Danish island of Bornholm and on data for ferries to the mainland of Sweden. Our analysis shows that an electrolyser system serves as a valuable flexibility asset on the electrical demand side while supporting the thermal management of the district heating system and contributing to meeting the ferries hydrogen demand. With a sized electrolyser of 9.63 MW and a hydrogen storage of 1.45 t the hydrogen assets are able to take up a large share of the local excess electricity generation. The waste heat of the electrolyser delivers a significant share of 21.4% of the annual district heating demand. Moreover the substation can supply 26% of the hydrogen demand of the ferries from local resources. We further examine the sensitivity of the asset sizing towards investment costs electrolyser efficiency and hydrogen market prices.
Everything About Hydrogen Podcast: State of the Union with the Everything About Hydrogen Team
Dec 2024
Publication
Back by popular demand Christopher Jackson Alicia Eastman and Patrick Molloy speak about the industry highlights and lowlights expectations for 2025 and what we can do to improve outcomes across the board. Equal parts sweepingly generalist and mind numbing minutiae create the perfect pundit cocktail. Wallow in the bad news and celebrate the bright sides together.
The podcast can be found on their website.
The podcast can be found on their website.
Exploratory Numerical Study of Liquid Hydrogen Hazards
Sep 2023
Publication
Hydrogen is one of a handful of new low carbon solutions that will be critical for the transition to net zero. The upscaling of production and applications entails that hydrogen is likely to be stored in liquid phase (LH2) at cryogenic conditions to increase its energy density. Widespread LH2 use as an alternative fuel will require significant infrastructure upgrades to accommodate increased bulk transport storage and delivery. However current LH2 bulk storage separation distances are based on subjective expert recommendations rather than experimental observations or physical models. Experimental studies of large-scale LH2 release are challenging and costly. The existing large-scale tests are scarce and numerical studies are a viable option to investigate the existing knowledge gaps. Controlled or accidental releases of LH2 for hydrogen refueling infrastructure would result in high momentum two-phase jets or formation of liquid pools depending on release conditions. Both release scenarios lead to a flammable/explosive cloud posing a safety issue to the public.<br/>The manuscript reports exploratory study to numerically determine the safety zone resulting from cryogenic hydrogen releases related to LH2 storage and refueling using the in-house HyFOAM solver further modified for gaseous hydrogen releases at cryogenic conditions and the subsequent atmospheric dispersion and ignition within the platform of OpenFOAM V8.0. The current version of the solver neglects the flashing process by assuming that the temperature of the stored LH2 is equal to the boiling point at the atmospheric condition. Numerical simulations of dispersion and subsequent ignition of LH2 release scenarios with respect to different release orientations release rates release temperatures and weather conditions were performed. Both hydrogen concentration and temperature fields were predicted and the boundary of zones within the flammability limit was also defined. The study also considered the sensitivities of the consequences to the release orientation wind speed ambient temperature and release content etc. The effect of different barrier walls on the deflagration were also evaluated by changing the height and location.
Techno‐Economic Analysis of Hydrogen as a Storage Solution in an Integrated Energy System for an Industrial Area in China
Jun 2024
Publication
This study proposes four kinds of hybrid source–grid–storage systems consisting of pho‐ tovoltaic and wind energy and a power grid including different batteries and hydrogen storage systems for Sanjiao town. HOMER‐PRO was applied for the optimal design and techno‐economic analysis of each case aiming to explore reproducible energy supply solutions for China’s industrial clusters. The results show that the proposed system is a fully feasible and reliable solution for in‐ dustry‐based towns like Sanjiao in their pursuit of carbon neutrality. In addition the source‐side price sensitivity analysis found that the hydrogen storage solution was cost‐competitive only when the capital costs on the storage and source sides were reduced by about 70%. However the hydro‐ gen storage system had the lowest carbon emissions about 14% lower than the battery ones. It was also found that power generation cost reduction had a more prominent effect on the whole system’s NPC and LCOE reduction. This suggests that policy support needs to continue to push for genera‐ tion‐side innovation and scaling up while research on different energy storage types should be en‐ couraged to serve the needs of different source–grid–load–storage systems.
Model Predictive Control-Based Optimized Operation of a Hybrid Charging Station for Electric Vehicles
Aug 2021
Publication
This paper presents an energy management system (EMS) based on a novel approach using model predictive control (MPC) for the optimized operation of power sources in a hybrid charging station for electric vehicles (EVs). The hybrid charging station is composed of a photovoltaic (PV) system a battery a complete hydrogen system based on a fuel cell (FC) electrolyzer (EZ) and tank as an energy storage system (ESS) grid connection and six fast charging units all of which are connected to a common MVDC bus through Z-source converters (ZSC). The MPC-based EMS is designed to control the power flow among the energy sources of the hybrid charging station and reduce the utilization costs of the ESS and the dependency on the grid. The viability of the EMS was proved under a long-term simulation of 25 years in Simulink using real data for the sun irradiance and a European load profile for EVs. Furthermore this EMS is compared with a simpler alternative that is used as a benchmark which pursues the same objectives although using a states-based strategy. The results prove the suitability of the EMS achieving a lower utilization cost (-25.3%) a notable reduction in grid use (-60% approximately) and an improvement in efficiency.
Carbon Dioxide Emission in Hydrogen Production Technology from Coke Oven Gas with Life Cycle Approach
Oct 2016
Publication
The analysis of Carbon Footprint (CF) for technology of hydrogen production from cleaned coke oven gas was performed. On the basis of real data and simulation calculations of the production process of hydrogen from coke gas emission indicators of carbon dioxide (CF) were calculated. These indicators are associated with net production of electricity and thermal energy and direct emission of carbon dioxide throughout a whole product life cycle. Product life cycle includes: coal extraction and its transportation to a coking plant the process of coking coal purification and reforming of coke oven gas carbon capture and storage. The values were related to 1 Mg of coking blend and to 1 Mg of the hydrogen produced. The calculation is based on the configuration of hydrogen production from coke oven gas for coking technology available on a commercial scale that uses a technology of coke dry quenching (CDQ). The calculations were made using ChemCAD v.6.0.2 simulator for a steady state of technological process. The analysis of carbon footprint was conducted in accordance with the Life Cycle Assessment (LCA).
Regional Capabilities and Hydrogen Adoption Barriers
Dec 2023
Publication
Hydrogen is gaining importance to decarbonize the energy system and tackle the climate crisis. This exploratory study analyzes three focus groups with representatives from relevant organizations in a Northern German region that has unique beneficial characteristics for the transition to a hydrogen economy. Based upon this data (1) a category system of innovation adoption barriers for hydrogen technologies is developed (2) decision levels associated with the barriers are identified (3) detailed insights on how decision levels contribute to the adoption barriers are provided and (4) the barriers are evaluated in terms of their importance. Our analysis adds to existing literature by focusing on short-term barriers and exploring relevant decision levels and their associated adoption barriers. Our main results comprise the following: flaws in the funding system complex approval procedures lack of networks and high costs contribute to hydrogen adoption barriers. The (Sub-)State level is relevant for the uptake of the hydrogen economy. Regional entities have leeway to foster the hydrogen transition especially with respect to the distribution infrastructure. Funding policy technological suitability investment and operating costs and the availability of distribution infrastructure and technical components are highly important adoption barriers that alone can impede the transition to a hydrogen economy.
Environmental and Material Criticality Assessment of Hydrogen Production via Anion Exchange Membrane Electrolysis
Oct 2023
Publication
The need to drastically reduce greenhouse gas emissions is driving the development of existing and new technologies to produce and use hydrogen. Anion exchange membrane electrolysis is one of these rapidly developing technologies and presents promising characteristics for efficient hydrogen production. However the environmental performance and the material criticality of anion exchange membrane electrolysis must be assessed. In this work prospective life cycle assessment and criticality assessment are applied first to identify environmental and material criticality hotspots within the production of anion exchange membrane electrolysis units and second to benchmark hydrogen production against proton exchange membrane electrolysis. From an environmental point of view the catalyst spraying process heavily dominates the ozone depletion impact category while the production of the membrane represents a hotspot in terms of the photochemical ozone formation potential. For the other categories the environmental impacts are distributed across different components. The comparison of hydrogen production via anion exchange membrane electrolysis and proton exchange membrane electrolysis shows that both technologies involve a similar life-cycle environmental profile due to similar efficiencies and the leading role of electricity generation for the operation of electrolysis. Despite the fact that for proton exchange membrane electrolysis much less material is required due to a higher lifetime anion exchange membrane electrolysis shows significantly lower raw material criticality since it does not rely on platinum-group metals. Overall a promising environmental and material criticality performance of anion exchange membrane electrolysis for hydrogen production is concluded subject to the expected technical progress for this technology.
Effect of Gas Composition and Initial Turbulence on the Propagation Dynamics of Premixed Flames of Hydrogen-blended Natural Gas Fuel
Jul 2024
Publication
In order to reduce carbon emissions the effects of gas composition and initial turbulence on the premixed flame dynamics of hydrogen-blended natural gas were investigated. The results show that an increase in hydrogen content leads to earlier formation of flame wrinkles. When the equivalence ratio is 1 and hydrogen blending ratio is below 20% Tulip flames appear approximately 2.25 m away from the ignition point. When hydrogen blending ratio exceeds 20% Tulip flames appear approximately 1.3 m away from the ignition point and twisted Tulip flames appear approximately 2.5 m away from the ignition position. During the 0.05 m process of flame propagation downstream from ignition point flame propagation velocity increases by about 2 m/s for every 10% increase in hydrogen content. The increase in hydrogen content has the most significant impact on the flame propagation velocity during the ignition stage. The average flame propagation velocity increases with the increase of hydrogen blending ratio. The greater the initial turbulence the more obvious the stretching deformation of flame front structure. With the increase of wind speed the flame propagation velocity first increases and then decreases. At a wind speed of 3 m/s the flame propagation velocity reaches its maximum value.
An Analytical Model for the Electrolyser Performance Derived from Materials Parameters
Oct 2017
Publication
Hydrogen is seen as a key element for the transition from a fossil fuel based economy to a renewable sustainable economy. Hydrogen can be used either directly as an energy carrier or as a feedstock for the reduction of CO2 to synthetic hydrocarbons. Hydrogen can be produced by electrolysis decomposing water in oxygen and hydrogen. This paper presents an overview of the three major electrolysis technologies: acidic (PEM) alkaline (AEL) and solid oxide electrolysis (SOEC). An updated list of existing electrolysers and commercial providers is provided. Most interestingly the specific prices of commercial devices are also given when available. Despite tremendous development of the PEM technology in the past decades the largest and most efficient electrolysers are still alkaline. Thus this technology is expected to play a key role in the transition to the hydrogen society. A detailed description of the components in an alkaline electrolyser and an analytical model of the process are provided. The analytical model allows investigating the influence of the different operating parameters on the efficiency. Specifically the effect of temperature on the electrolyte conductivity—and thus on the efficiency—is analyzed. It is found that in the typical range of operating temperatures for alkaline electrolysers of 65˚C - 220˚C the efficiency varies by up to 3.5 percentage points increasing from 80% to 83.5% at 65˚C and 220˚C respectively.
Current Standards and Configurations for the Permitting and Operation of Hydrogen Refueling Stations
Mar 2023
Publication
The literature lacks a systematic analysis of HRS equipment and operating standards. Researchers policymakers and HRS operators could find this information relevant for planning the network's future expansion. This study is intended to address this information need by providing a comprehensive strategic overview of the regulations currently in place for the construction and maintenance of hydrogen fueling stations. A quick introduction to fundamental hydrogen precautions and hydrogen design is offered. The paper therefore provides a quick overview of hydrogen's safety to emphasize HRS standards rules and regulations. Both gaseous and liquid safety issues are detailed including possible threats and installation and operating expertise. After the safety evaluation layouts equipment and operating strategies for HRSs are presented followed by a review of in-force regulations: internationally by presenting ISO IEC and SAE standards and Europeanly by reviewing the CEN/CENELEC standards. A brief and concise analysis of Italy's HRS regulations is conducted with the goal of identifying potential insights for strategic development and more convenient technology deployment.
Fuel Cell Systems for Long-endurance Autonomous Underwater Vehicles - Challenges and Benefits
Jun 2019
Publication
Autonomous underwater vehicles (AUVs) are programmable robotic vehicles that can drift drive or glide through the ocean without real-time control by human operators. AUVs that also can follow a planned trajectory with a chosen depth profile are used for geophysical surveys subsea pipeline inspection marine archaeology and more. Most AUVs are followed by a mother ship that adds significantly to the cost of an AUV mission. One pathway to reduce this need is to develop long-endurance AUVs by improving navigation autonomy and energy storage. Long-endurance AUVs can open up for more challenging mission types than what is possible today. Fuel cell systems are a key technology for increasing the endurance of AUVs beyond the capability of batteries. However several challenges exist for underwater operation of fuel cell systems. These are related to storage or generation of hydrogen and oxygen buoyancy and trim and the demanding environment of the ambient seawater. Protecting the fuel cell inside a sealed container brings along more challenges related to condensation cooling and accumulation of inert gases or reactants. This paper elaborates on these technical challenges and describes the solutions that the Norwegian Defence Research Establishment (FFI) has chosen in its development of a fuel cell system for long-endurance AUVs. The reported solutions enabled a 24 h demonstration of FFI's fuel cell system under water. The remaining work towards a prototype sea trial is outlined.
Cleaner Energy Solutions using Wind Energy and Hydrogen Production in Agriculture
Feb 2025
Publication
This study evaluates the integration of wind energy into greenhouse agriculture in the Safi region a major agricultural area in Morocco. As part of cleaner energy systems five wind turbines were analyzed to determine their performance. After performing a statistical analysis using the Weibull distribution with two parameters the results showed that the VESTAS V82- 0.9/1.65MW – 70m turbine was the most efficient. It achieved a capacity factor of 41.72% an annual energy production of 3 326.17 MWh and the ability to supply electricity to 6 960 m² of agricultural greenhouses. Environmental benefits include a significant reduction in carbon dioxide emissions. Economically the results vary with a payback period of less than 5 years for the VESTAS turbine but a longer period of 10.49 years for the Norwin – 30m turbine. To address fluctuations in wind energy caused by daily wind speed variations this innovative study explores combining wind power with hydrogen production. The results indicate that the Safi region has the potential to produce between 25 188.76 kg and 44 875.25 kg of hydrogen annually depending on the turbine used. Additionally this approach could reduce annual CO2 emissions by up to 2 606 609 kg. These findings highlight a promising innovation in cleaner energy systems to enhance agricultural sustainability through renewable energy solutions.
Hydrogen Demand Estimation for Sustainable Transport: A Comprehensive Review
Aug 2025
Publication
Hydrogen demand estimation for various transport modes supports policy and decision-making for the transition towards a sustainable low-carbon future transport system. It is one of the major factors that determine infrastructure construction production and distribution cost optimisation. Researchers have developed various methods for modelling hydrogen demand and its geographical distribution each based on different sets of predictor variables. This paper systematically reviews these methods and examines the key variables used in hydrogen demand estimation including the number of vehicles travel distance penetration rate and fuel economy. It emphasises the role of spatial analysis in uncovering the geographical distribution of hydrogen demand providing insights for strategic infrastructure planning. Furthermore the discussion underscores the significance of minimising uncertainty by incorporating multiple scenarios into the model thereby accommodating the dynamic nature of hydrogen adoption in transport. The necessity for multi-temporal estimation which accounts for the changing nature of hydrogen demand over time is also highlighted. In addition this paper advocates for a holistic approach to hydrogen demand estimation integrating spatiotemporal analysis. Future research could enhance the reliability of hydrogen demand models by addressing uncertainty through advanced modelling techniques to improve accuracy and spatial-temporal resolution.
Adaptive Sliding Mode Control of an Interleaved Buck Converter–Proton Exchange Membrane Electrolyzer for a Green Hydrogen Production System
Mar 2025
Publication
This paper presents an advanced Adaptive Sliding Mode Control (ASMC) strategy specifically developed for a hydrogen production system based on a Proton Exchange Membrane electrolyzer (PEM electrolyzer). This work utilized a static model of the PEM electrolyzer characterized by its V-I electrical characteristic which was approximated by a linear equation. The ASMC was designed to estimate the coefficients of this equation which are essential for designing an efficient controller. The primary objective of the proposed control strategy is to ensure the overall stability of the integrated system comprising both an interleaved buck converter (IBC) and PEM electrolyzer. The control framework aims to maintain the electrolyzer voltage at its reference value despite the unknown coefficients while ensuring equal current distribution among the three parallel legs of the IBC. The effectiveness of the proposed approach was demonstrated through numerical simulations in MATLAB-SIMULINK and was validated by the experimental results. The results showed that the proposed ASMC achieved a voltage tracking error of less than 2% and a current distribution imbalance of only 1.5%. Furthermore the controller exhibited strong robustness to parameter variations effectively handling fluctuations in the electrolyzer’s ohmic resistance (Rohm) (from ±28.75% to ±40.35%) and in the reversible voltage (Erev) (from ±28.67% to ±40.19%) highlighting its precision and reliability in real-world applications.
Optimal Configuration of Hydrogen- and Battery-based Electric Bus Transit Systems
Feb 2025
Publication
Electric bus transit is crucial in reducing greenhouse gas (GHG) emissions decreasing fossil fuel reliance and combating climate change. However the transition to electric-powered buses demands a comprehensive plan for optimal resource allocation technology choice infrastructure deployment and component sizing. This study develops system configuration optimization models for battery electric buses (BEBs) and hydrogen fuel cell buses (HFCBs) minimizing all related costs (i.e. capital and operational costs). These models optimize component sizing of the charging/refueling stations fleet configuration and energy/fuel management system in three operational schemes: BEBs opportunity charging BEBs overnight charging and electrolysis-powered HFCBs overnight refueling. The results indicate that the BEB opportunity system is the most economically viable choice. Meanwhile HFCB requires a higher cost (134.5%) and produces more emissions (215.7%) than the BEB overnight charging system. A sensitivity analysis indicates that a significant reduction in the HFCB unit and electricity costs is required to compete economically with BEB systems.
The Transition to an Eco-Friendly City as a First Step Toward Climate Neutrality with Green Hydrogen
Mar 2025
Publication
A city of the future will need to be eco-friendly while meeting general social and economic requirements. Hydrogen-based technologies provide solutions for initially limiting CO2 emissions with prospects indicating complete decarbonization in the future. Cities will need to adopt and integrate these technologies to avoid a gap between the development of hydrogen production and its urban application. Achievable results are analyzed by injecting hydrogen into the urban methane gas network initially in small proportions but gradually increasing over time. This paper also presents a numerical application pertaining to the city of Bucharest Romania—a metropolis with a population of 2.1 million inhabitants. Although the use of fuel cells is less advantageous for urban transport compared to electric battery-based solutions the heat generated by hydrogen-based technologies such as fuel cells can be efficiently utilized for residential heating. However storage solutions are required for residential consumption separate from that of urban transport along with advancements in electric transport using existing batteries which necessitate a detailed economic assessment. For electricity generation including cogeneration gas turbines have proven to be the most suitable solution. Based on the analyzed data the paper synthesizes the opportunities offered by hydrogen-based technologies for a city of the future.
Hydrogen for a Sustainable Europe
Nov 2024
Publication
This brochure provides a detailed overview of the EU’s funding mechanisms and an inspiring look at real projects managed by CINEA. These examples illustrate how diverse stakeholders from industry leaders to research institutions are translating hydrogen ambitions into impactful on-the-ground solutions that address both technological and societal needs.
Optimum Geological Storage Depths for Structural H2 Geo-storage
Sep 2021
Publication
H2 geo-storage has been suggested as a key technology with which large quantities of H2 can be stored and withdrawn again rapidly. One option which is currently explored is H2 storage in sedimentary geologic for mations which are geographically widespread and potentially provide large storage space. The mechanism which keeps the buoyant H2 in the subsurface is structural trapping where a caprock prevents the H2 from rising by capillary forces. It is therefore important to assess how much H2 can be stored via structural trapping under given geo-thermal conditions. This structural trapping capacity is thus assessed here and it is demonstrated that an optimum storage depth for H2 exists at a depth of 1100 m at which a maximum amount of H2 can be stored. This work therefore aids in the industrial-scale implementation of a hydrogen economy.
Designing Effective Hydrogen Markets: Policy Recommendations from Electricity and Gas Market Reform
Aug 2025
Publication
For low-carbon hydrogen to become a viable decarbonization solution the creation of a robust and effective market is essential. This paper examines the applicability of market reforms from the renewable energy natural gas and liquefied natural gas (LNG) sectors with a focus on pricing mechanisms business models and infrastructure access to facilitate hydrogen market development. Applying the Structure-Conduct-PerformanceRegulation (SCP-R) framework and informed by stakeholder insights we identify critical enablers for advancing the hydrogen market formation. Our analysis highlights the importance of innovative pricing strategies and regulatory measures incentivizing investment and managing risks. Establishing a market reference price for low-carbon hydrogen — akin to benchmarks in the natural gas and LNG sectors—is critical for ensuring transparency predictability and regional adaptability in trade. Additionally customized business models are also needed to mitigate volume risks for producers. Government interventions such as offtake agreements and the development of hydrogen hubs are indispensable for fostering competition and driving decarbonization.
European Maritime Transport Environmental Report 2025
Jan 2025
Publication
This second edition of the European Maritime Transport Environmental Report (EMTER 2025) examines the progress made towards achieving Europe′s decarbonisation targets and environmental goals for the maritime sector while indicating the most important trends key challenges and opportunities. The objective was to update the indicators developed for the first report analyse new datasets and fill existing gaps to provide a data and knowledge-based assessment of the maritime transport sector′s transition to sustainability.
Distributed Robust Optimal Control Strategy for Integrated Energy Systems based on Energy Trading
Sep 2025
Publication
Under the background of energy interconnection and low-carbon electricity integrated energy systems (IES) play an important role in energy conservation and emission reduction. To further promote the low-carbon transition of energy this paper proposes a distributed robust optimal control strategy for IESs based on energy trading. Firstly an IES model that includes an electric hydrogen module and gas hydrogen doping combined heat and power is established and ladder-type carbon trading is introduced to reduce carbon emissions. Secondly for the energy trading issues between photovoltaic (PV) prosumers and IES a bi-level model is constructed using Stackelberg game method where the IES acts as the leader and the PV prosumers as the followers. Noteworthy a distributed robust optimization method is used to address the uncertainty of renewable energy and load. Additionally the Nash bargaining method ensures an equitable balance of benefits among the various IESs and encourages them to participate in market transactions. On this basis an intermediary transaction mode is proposed to address cheating behaviors in trading. Finally the simulation results demonstrate that the proposed strategy not only effectively promotes cooperative operation among multiple IESs but also significantly reduces the system’s operating costs and carbon emissions.
Distribution of Relaxation Times Analysis of High-temperature PEM Fuel Cell Impedance Spectra
Feb 2017
Publication
In this study Distribution of Relaxation Times (DRT) was successfully demonstrated in the analysis of the impedance spectra of High-Temperature Polymer Electrolyte Membrane Fuel Cells (HT-PEMFC) doped with phosphoric acid. Electrochemical impedance spectroscopy (EIS) was performed and the quality of the recorded spectra was verified by Kramers-Kronig relations. DRT was then applied to the measured spectra and polarization losses were separated on the basis of their typical time constants. The main features of the distribution function were assigned to the cell’s polarization processes by selecting appropriate experimental conditions. DRT can be used to identify individual internal HT-PEMFC fuel cell phenomena without any a-priori knowledge about the physics of the system. This method has the potential to further improve EIS spectra interpretation with either equivalent circuits or physical models.
A Review of Type V Composite Pressure Vessels and Automated Fibre Placement Based Manufacturing
Feb 2023
Publication
Hydrogen is emerging as a promising future energy medium in a wide range of industries. For mobile applica tions it is commonly stored in a gaseous state within high-pressure composite overwrapped pressure vessels (COPVs). The current state of the art pressure vessel technology known as Type V eliminates the internal polymer gas barrier used in Type IV vessels and instead relies on carbon fibre laminate to provide structural properties and prevent gas leakage. Achieving this functionality at high pressure poses several engineering challenges that have thus far prohibited commercial application. Additionally the traditional manufacturing process for COPVs filament winding has several constraints that limit the design space. Automated fibre placement (AFP) a highly flexible robotic composites manufacturing technique has the potential to replace filament winding for composite pressure vessel manufacturing and provide pathways for further vessel optimi sation. A combination of both AFP and Type V technology could provide an avenue for a new generation of highperformance composite pressure vessels. This critical review presents key work on industry-standard Type IV vessels alongside the current state of Type V CPV technology including manufacturing developments challenges cost relevance to commercial standards and future fabrication solutions using AFP. Additionally a novel Type V CPV design concept for a two-piece AFP produced vessel is presented.
Model Complexity and Optimization Trade-offs in the Design and Scheduling of Hybrid Hydrogen-battery Systems
Jul 2025
Publication
The production of hydrogen from renewable sources could play a significant role in supporting the transition toward a decarbonized energy system. This study has involved investigating optimization strategies − mixedinteger linear programming (MILP) a hybrid particle swarm optimization (PSO)-MILP framework and PSO combined with a rule-based energy management strategy (EMS) − applied to a power-to-hydrogen system for industrial applications. The analysis evaluates the levelized cost of hydrogen production (LCOH) carbon emissions and the impact of key factors such as battery degradation electrolyzer efficiency real-time pricing and hydrogen load management. The obtained results indicated that the MILP-based models achieved moderate LCOH values (10.1–10.7 €/kg) but incurred higher CO2 emissions (20.2–24.6 kt/y). Instead the PSO model combined with the rule-based EMS lowered emissions to 14.3 kt/y (a 27–45% reduction) albeit with a higher LCOH (11.6 €/kg). The hybrid PSO-MILP models struck a balance achieving LCOH values of between 9.2 and 9.7 €/kg with CO2 emissions of 19.7–20.3 kt/y as they benefited from the integration of piecewise affine linearization for modeling electrolyzer efficiency and battery degradation. In terms of computational efforts the MILP-based models required more than 48 h to converge while the PSO-MILP models completed within 27–35 h and the PSO model with rule-based EMS achieved results in 1.5 h. These findings offer guidance that can be used to select the most suitable optimization method on the basis of the desired performance targets resource constraints and computational complexity thereby contributing to the design of more sustainable energy systems.
Hydrogen Production Model: A Computational Approach to Optimise Cost Reduction Strategies, Environmental Impact, and Financial Viability
Jul 2025
Publication
This study presents a comprehensive techno-economic and environmental evaluation of hydrogen production from organic waste feedstocks in Bangladesh utilizing an integrated approach through advanced modelling tools. The research combines H2A (Hydrogen Production Cost Analysis) HDSAM (Hydrogen Delivery Scenario Analysis Model) and H2FAST (Hydrogen Financial Assessment Tool) to assess the feasibility of large-scale hydrogen production distribution and storage. H2A is employed to analyze hydrogen production costs considering various feedstocks and production methods while HDSAM evaluates the delivery pathways and logistics of liquid and gaseous hydrogen. H2FAST is used to perform detailed financial modelling focusing on investment risks profitability and financial metrics of hydrogen projects. This integrated methodology provides a comprehensive analysis of the hydrogen value chain addressing key factors such as production costs logistics and financial feasibility. Main results of the study indicate that hydrogen production costs can range from $2.16/kg to $2.18/kg depending on feedstock efficiency and plant utilization. Financial assessments show that larger-scale hydrogen stations (4000 kg/day) benefit from economies of scale with hydrogen costs dropping to approximately $8.51/kg compared to $12.75/kg for smaller stations (400 kg/day). The study concludes incorporates region-specific data for Bangladesh addressing local challenges such as infrastructure limitations financial constraints and energy demands offering a tailored analysis that can inform future hydrogen projects in Bangladesh and similar developing economies.
Green Hydrogen Production in Photoelectrochemical Artificial-leaf Systems with Different Tandem Solar Cells: An Environmental and Economic Assessment of Industrial-scale Production in China
Aug 2025
Publication
Different photoelectrochemical (PEC) artificial-leaf systems have been proposed for green hydrogen production. However their sustainability is not well understood in comparison to conventional hydrogen technologies. To fill this gap this study estimates cradle-to-grave life cycle environmental impacts and costs of PEC hydrogen production in different provinces in China using diverse tandem solar cells: Ge/GaAs/GaInP (Ge-PEC) GaAs/ GaInAs/GaInP (GaAs-PEC) and perovskite/silicon (P-PEC). These systems are benchmarked against conventional hydrogen production technologies − coal gasification (CG) and steam methane reforming (SMR) − across 18 environmental categories life cycle costs and levelised cost of hydrogen (LCOH). P-PEC emerges as the best options with 36–95 % lower impacts than Ge-PEC and GaAs-PEC across the categories including the climate change impact (0.38–0.52 t CO2 eq./t H2) which is 77–79 % lower. Economically P-PEC shows 81–84 % lower LCOH (2.51–3.81 k$/t). Compared to SMR and CG P-PEC reduces the impacts by 23–98 % saving 3.67–38.5 Mt of CO2 eq./yr. While its LCOH is 5 % higher than that of conventional hydrogen it could be economically competitive with both SMR and CG at 10 % higher solar-to-hydrogen efficiency and 25 % lower operating costs. In contrast Ge-PEC and GaAs-PEC while achieving much lower (81–91 %) climate change and some other impacts than the conventional technologies face significant economic challenges. Their LCOH (21.51–32.82 k$/t for Ge-PEC and 16.96–25.89 k$/t for GaAs-PEC) is 7–9 times higher than that of the conventional hydrogen due to the high solar cell costs. Therefore despite their environmental benefits these technologies require substantial cost reductions to become economically viable.
Is Renewable Energy Storage Sustainable? A Review
Jan 2025
Publication
Transformation of energy supply systems into green intensifies the use of renewable energy sources. Renewables cannot continuously supply energy. Therefore energy storage systems are very important in the whole system of generation and distribution. Anyway energy storage systems have many issues in terms of sustainability. This paper classified energy storage and analyzed issues in their sustainability solutions. In addition it determines the key performance indicators that define the sustainability of energy storage systems. This analysis determined many sustainability problems presented by the information for each key performance indicator. The least negative impact is shown for the performance of mechanical energy storage and sensible/latent heat storage. The production of green hydrogen green ammonia and biogas showed some negative impact. The worst sustainability is related to energy storage technologies or electrochemical energy storage technologies.
The Global Yet Local Nature of Energy Imaginaries: The Cases of Dutch and Spanish Hydrogen Valleys
Mar 2025
Publication
Hydrogen valleys are envisaged (imagined) integrated industrial systems where hydrogen is produced stored and utilized. Here we show how hydrogen valleys as sociotechnical imaginaries are differentiated in terms of their specific configurations but homogenous in terms of reflecting the interests of large industrial fossil fuel suppliers and consumers. This path dependence is anticipated in sociotechnical transitions theory which emphasises the power of incumbents with vested interests to maintain basic templates or regimes of production and consumption. The simultaneously heterogeneous and homogenous nature of hydrogen valley imaginaries can be thought of as a form of glocalisation for which we draw on Roudometof's theory of glocalisation as involving the local refraction of diffusing global tendencies. To illustrate this we compare two hydrogen valleys one in the north of the Netherlands and one in southern Spain. In the north Netherlands the hydrogen valley imaginary comprises use of offshore windpower to electrolyse hydrogen for transport fuel and as feedstock to heavy industry in proximate regions including northern Germany and Belgium. This is consistent with existing gas distribution networks connecting industrial consumers. In the southern Spanish case the imaginary positions Spain as a major exporter of green hydrogen to the rest of Europe via onshore renewable electrolysis with export including via ocean tankers and chemical refining in existing infrastructure in Rotterdam. Overall the study explores empirically theoretically-informed themes concerning the interrelationship of mutually supportive local and global imaginaries – hence our term glocalised imaginaries.
An Innovative Cryogenic Heat Exchanger Design for Sustainable Aviation
Mar 2025
Publication
Aviation is one of the most important industries in the current global scenario but it has a significant impact on climate change due to the large quantities of carbon dioxide emitted daily from the use of fossil kerosene-based fuels (jet fuels). Although technological advancements in aircraft design have enhanced efficiency and reduced emissions over the years the rapid growth of the aviation industry presents challenges in meeting the environmental targets outlined in the “Flightpath 2050” report. This highlights the urgent need for effective decarbonisation strategies. Hydrogen propulsion via fuel cells or combustion offers a promising solution with the combustion route currently being more practical for a wider range of aircraft due to the limited power density of fuel cells. In this context this paper designs and models a nitrogen–hydrogen heat exchanger architecture for use in an innovative hydrogen-propelled aircraft fuel system where the layout was recently proposed by the same authors to advance sustainable aviation. This system stores hydrogen in liquid form and injects it into the combustion chamber as a gas making the cryogenic heat exchanger essential for its operation. In particular the heat exchanger enables the vaporisation and superheating of liquid hydrogen by recovering heat from turbine exhaust gases and utilising nitrogen as a carrier fluid. A pipe-in-pipe design is employed for this purpose which to the authors’ knowledge is not yet available on the market. Specifically the paper first introduces the proposed heat exchanger architecture then evaluates its feasibility with a detailed thermodynamic model and finally presents the calculation results. By addressing challenges in hydrogen storage and usage this work contributes to advancing sustainable aviation technologies and reducing the environmental footprint of air travel.
Dynamic Modelling of Methanol Steam Reforming to Hydrogen in a Packed Bed Reactor for Shipboard Fuel Cells
Feb 2025
Publication
Hydrogen economy is spreading across the maritime sector in response to increasingly stringent regulations for shipping emissions. The challenging on-board hydrogen logistics are often mitigated with hydrogen carriers such as methanol. Research on methanol reforming to hydrogen for fuel cell feed is conducted mostly in steady state overlooking dynamic reactor operation and its effects on the power production system. Forced reactor operations induce fluctuations of CO content in the reformate potentially harmful to the PEM fuel cell and drops in methanol conversion causing inefficient operation. In present research simulations with a physical 2D unsteady model of a packed bed methanol steam reforming reactor resulted in methanol conversion drop durations of up to a minute. Additionally temporary increases of CO content up to 112% were observed. Throughput ramp ups most notably impact the conversion while ramp downs negatively affect selectivity. The investigation on reactor geometry concludes that larger tube diameters increase transient time and CO spikes while they decrease with reactor length. Amplified unsteady effects are also observed with larger changes in input process variables. The results imply that heat transfer rate to the reactor are most often the detrimental factor for transient effects and durations in practice. Following this work inclusion of realistic heating methods is recommended instead of uniform tube temperatures used in present simulations. Heating system characteristics are necessary for realistic evaluation of the methanol reformer constraint on fuel cell feed demand in fully integrated systems.
Competitiveness of Green and Yellow Hydrogen: A Project-level Analysis
Feb 2025
Publication
With the growing global focus on hydrogen as a key solution for achieving decarbonization understanding the most cost-effective and environmentally sustainable production methods is crucial. The objective of this study is to evaluate the economic and environmental performance of different renewable energy sources for hydrogen production while also considering the impact of geographic location system sizing and technological efficiency. This study compares the production of green hydrogen powered by onshorewind offshore-wind and solar PV with that of yellow hydrogen (grid-based hydrogen) in terms of cost and environmental impact for a large sample of publicly announced green hydrogen projects in Europe. Using geographic renewable energy data project-specific details and prevailing technological standards we derive each country’s weighted average cost of capital (WACC) to calculate market-based levelized cost of hydrogen. We find onshore-wind projects to have the lowest average levelized cost of green hydrogen followed by offshore-wind and then by solar PV . The costs for yellow hydrogen depend on the price of electricity. Excluding 2022 yellow hydrogen had lower mean costs than solar PV but higher costs than both types of wind. The environmental impact assessment finds significant decarbonization potential for green hydrogen particularly in regions with substantial renewable resources and carbon-intensive energy mixes. The study aggregates the project data at the country level then clusters the analyzed countries based on economic and environmental metrics to derive specific hydrogen strategies. It concludes that substantial governmental support is essential for the large-scale integration of green hydrogen into the energy system to achieve meaningful decarbonization.
Study of Thermal Behavior on Multi-tank Cascade System for Ship-borne Hydrogen Storage Tank Using a New Design Configuration
Feb 2025
Publication
Hydrogen tanks (HT) with different connection modes are an integral part of the shipborne hydrogen fuel cell system. To ensure the safe and reliable operation of the shipborne multi-tank cascade system this study innovatively develops 3D models of four different connection modes for the shipborne multi-tank cascade system namely Type-22 Type-211 Type-121 and Type-112. Through computational fluid dynamics (CFD) numerical simulation the variations in parameters of different multi-tank cascade systems during the hydrogen storage process are analyzed. The results indicate that the maximum temperature of Type-112 is 271.107K which is 2.220% 4.779% and 3.993% lower than that of Type-22 Type-211 and Type-121 respectively and thus the optimal parameters such as the initial temperature in the tank and pre-cooling temperature are derived. Type-112's maximum temperature is reduced by 14.02% and 16.66% compared to systems connected solely in series or in parallel. The study identifies the optimal structure and reasonable hydrogen storage parameters effectively reducing heat generation during the refueling process while optimizing space utilization thereby strongly ensuring the stability of hydrogen storage and opening up new avenues for addressing related hydrogen storage issues in the future.
Improved Sliding Mode Temperature Control of Hydrogen Fuel Cells for Multirotor Drones
Jan 2025
Publication
This paper investigates the temperature control problem in hydrogen fuel cells based on the improved sliding mode control method specifically within the context of multirotor drone applications. The study focuses on constructing a control-oriented nonlinear thermal model which serves as a foundation for the subsequent development of a practical temperature regulation approach. Initially a novel sliding mode control strategy is proposed which significantly enhances the precision and stability of temperature control by reducing the impact of sensor errors and environmental disturbances. Subsequently the effectiveness and robustness of this control method under various dynamic loads and environmental conditions are demonstrated. The simulation results demonstrate that the improved sliding mode controller is effective in managing and regulating the fuel cell temperature ensuring optimal performance and stability.
Pieces of a Jigsaw: Opportunities and Challenges in the Nascent Australian Hydrogen Mobility Market
Mar 2023
Publication
Mobility has been a prominent target for proponents of the hydrogen economy. Given the complexities involved in the mobility value chain actors hoping to participate in this nascent market must overcome a range of challenges relating to the availability of vehicles the co-procurement of supporting infrastructure a favourable regulatory environment and a supportive community among others. In this paper we present a state-of-play account of the nascent hydrogen mobility market in Victoria Australia drawing on data from a workshop (N ¼ 15) and follow-up interviews (n ¼ 10). We interpret findings through a socio-technical framework to understand the ways in which fuel cell electric vehicles (FCEVs)dand hydrogen technologies more generallydare conceptualised by different stakeholder groups and how these conceptualisations mediate engagement in this unfolding market. Findings reveal prevailing efforts to make sense of the FCEV market during a period of considerable institutional ambiguity. Discourses embed particular worldviews of FCEV technologies themselves in addition to the envisioned roles the resultant products and services will play in broader environmental and energy transition narratives. Efforts to bring together stakeholders representing different areas of the FCEV market should be seen as important enablers of success for market participants.
Mining Nontraditional Water Sources for a Distributed Hydrogen Economy
Jul 2022
Publication
Securing decarbonized economies for energy and commodities will requireabundant and widely available green H2. Ubiquitous wastewaters and nontraditional watersources could potentially feed water electrolyzers to produce this green hydrogen withoutcompeting with drinking water sources. Herein we show that the energy and costs of treatingnontraditional water sources such as municipal wastewater industrial and resource extractionwastewater and seawater are negligible with respect to those for water electrolysis. We alsoillustrate that the potential hydrogen energy that could be mined from these sources is vast.Based on these findings we evaluate the implications of small-scale distributed waterelectrolysis using disperse nontraditional water sources. Techno-economic analysis and lifecycle analysis reveal that the significant contribution of H2 transportation to costs and CO2emissions results in an optimal levelized cost of hydrogen at small- to moderate-scale waterelectrolyzer size. The implications of utilizing nontraditional water sources and decentralizedor stranded renewable energy for distributed water electrolysis are highlighted for severalhydrogen energy storage and chemical feedstock applications. Finally we discuss challengesand opportunities for mining H2 from nontraditional water sources to achieve resilient and sustainable economies for water andenergy.
Hydrogen Storage Technology, and Its Challenges: A Review
Mar 2025
Publication
This paper aims to present an overview of the current state of hydrogen storage methods and materials assess the potential benefits and challenges of various storage techniques and outline future research directions towards achieving effective economical safe and scalable storage solutions. Hydrogen is recognized as a clean secure and costeffective green energy carrier with zero emissions at the point of use offering significant contributions to reaching carbon neutrality goals by 2050. Hydrogen as an energy vector bridges the gap between fossil fuels which produce greenhouse gas emissions global climate change and negatively impact health and renewable energy sources which are often intermittent and lack sustainability. However widespread acceptance of hydrogen as a fuel source is hindered by storage challenges. Crucially the development of compact lightweight safe and cost-effective storage solutions is vital for realizing a hydrogen economy. Various storage methods including compressed gas liquefied hydrogen cryocompressed storage underground storage and solid-state storage (material-based) each present unique advantages and challenges. Literature suggests that compressed hydrogen storage holds promise for mobile applications. However further optimization is desired to resolve concerns such as low volumetric density safety worries and cost. Cryo-compressed hydrogen storage also is seen as optimal for storing hydrogen onboard and offers notable benefits for storage due to its combination of benefits from compressed gas and liquefied hydrogen storage by tackling issues related to slow refueling boil-off and high energy consumption. Material-based storage methods offer advantages in terms of energy densities safety and weight reduction but challenges remain in achieving optimal stability and capacities. Both physical and material-based storage approaches are being researched in parallel to meet diverse hydrogen application needs. Currently no single storage method is universally efficient robust and economical for every sector especially for transportation to use hydrogen as a fuel with each method having its own advantages and limitations. Moreover future research should focus on developing novel materials and engineering approaches in order to overcome existing limitations provide higher energy density than compressed hydrogen and cryo-compressed hydrogen storage at 70 MPa enhance costeffectiveness and accelerate the deployment of hydrogen as a clean energy vector.
Hydrogen as a Sustainable Fuel: Transforming Maritime Logistics
Mar 2025
Publication
The marine industry being the backbone of world trade is under tremendous pressure to reduce its environmental impact mainly driven by reliance on fossil fuels and significant greenhouse gas emissions. This paper looks at hydrogen as a transformative energy vector for maritime logistics. It delves into the methods of hydrogen production innovative propulsion technologies and the environmental advantages of adopting hydrogen. The analysis extends to the economic feasibility of this transition and undertakes a comparative evaluation with other alternative fuels to emphasize the distinct strengths and weaknesses of hydrogen. Furthermore based on case studies and pilot projects this study elaborates on how hydrogen can be used in real-world maritime contexts concluding that the combination of ammonia and green hydrogen in hybrid propulsion systems presents increased flexibility with ammonia serving as the primary fuel while hydrogen enhances efficiency and powers auxiliary systems. This approach represents a promising solution for reducing the shipping sector’s carbon footprint enabling the industry to achieve greater sustainability while maintaining the efficiency and scalability essential for global trade. Overall this work bridges the gap between theoretical concepts and actionable solutions therefore offering valuable insights into decarbonization in the maritime sector and achieving global sustainability goals.
Experimental Study of the Influence of Oxygen Enrichment in Hydrogen-enriched Natural Gas Combustion at a Semi-industrial Scale
Aug 2025
Publication
This study investigates the effect of Oxygen-Enriched Combustion on hydrogen-enriched natural gas (H2 -NG) fuel mixtures at a semi-industrial scale (up to 60 kW). The analysis focuses on flame structure temperature distribu tion in the furnace NOx emissions and potential fuel savings. A multi-fuel multi-oxidizer jet burner was used to compare two oxygen enrichment configurations: premixed with air (PM) and air-pure O2 (AO) independent feed. The O2 -enriched flames remained stable across the entire fuel range. OH* chemiluminescence imaging for the H2 -NG fuel mixture delivering 50 concentration kW revealed that higher O2 increases the OH* intensity narrows and elongates the flame transitions from buoyancy- to momentum-driven shape and relocates the reaction zone. At 50 % oxygen enrichment level (OEL) flame shape OH* intensity and temperature profiles resembled pure O combustion. Up to 29 % OEL furnace temperature profiles were similar to those 2 of air-fuel combustion. The power required to maintain 1300 ± 25 ◦C at the reference position decreases with O2 enrichment. Higher OELs resulted in a sharp increase in NOx emissions. The effect of hydrogen enrichment on NOx levels was significantly less pronounced than that of oxygen enrichment. The rise in NOx emissions correlates with increased OH* in tensities. For a 50 % H2 2 blend increasing the O concentration in the oxidizer from 21 % to 50 % resulted in a 27 % reduction in flue gas heat losses. Utilizing O2 co-produced with H2 could be strategic for reducing fuel consumption facilitating the adoption of hydrogen-based energy systems.
Solid Oxide Electrolyzers Process Integration: A Comprehensive Review
Aug 2025
Publication
Solid oxide electrolysis (SOEL) has emerged as a promising technology for efficient hydrogen production. Its main advantages lie in the high operating temperatures which enhance thermodynamic efficiency and in the ability to supply part of the required energy in the form of heat. Nevertheless improving the long-term durability of stack materials remains a key challenge. Thermal energy can be supplied by dedicated integration with different industrial processes where the main challenge lies in the elevated stack operating temperature (700–900 ◦C). This review provides a comprehensive analysis of the integration of solid oxide electrolysis cells (SOECs) into different industrial applications. Main processes cover methanol production methane production Power-to-Hydrogen systems or the use of reversible solid oxide electrolysis cell (rSOEC) stacks that can operate in both electrolysis and fuel cell mode. The potential of co-electrolysis to increase process flexibility and broaden application areas is also analyzed. The aim is to provide a comprehensive analysis of the integration strategies identify the main technical and economic challenges and highlight recent developments and future trends in the field. A detailed comparison assessment of the different processes is being discussed in terms of electrical and thermal efficiencies and operating parameters as well as Key Performance Indicators (KPIs) for each process. Technical-economic challenges that are currently a barrier to their implementation in industry are also analyzed.
Water Electrolysis and Hydrogen in the European Union - Status Report on Technology Development, Trends, Value Chains & Markets
Jan 2024
Publication
This report is an output of the Clean Energy Technology Observatory (CETO) and is an update of the “Water electrolysis and hydrogen in the European Union” 2023 CETO report. CETO’s objective is to provide an evidencebased analysis feeding the policy making process and hence increasing the effectiveness of R&I policies for clean energy technologies and solutions. It monitors EU research and innovation activities on clean energy technologies needed for the delivery of the European Green Deal; and assesses the competitiveness of the EU clean energy sector and its positioning in the global energy market. CETO is being implemented by the Joint Research Centre for DG Research and Innovation Energy in coordination with DG Energy.
Wastewater as a Resource: Evaluating Light Dependent and Light Independent Methods, Challenges, and Future Directions for Sustainable Hydrogen Generation
Aug 2025
Publication
The increasing need for environmentally friendly energy sources has contributed to the development of innovative technologies that also resolve environmental issues. Hydrogen can be produced in a number of ways including using fossil fuels biomass and renewable energy sources like wind and sun. Using renewable energy for water-based production is the most sustainable method of producing hydrogen. However since fresh water is scarce the main way to address this issue is to use wastewater. Although wastewater is frequently seen as an issue it could additionally be seen as a valuable source of energy as it has the potential to produce bio-hydrogen. The current review emphasizes the key conclusion of studies examining the viability of the generation of hydrogen from wastewater by applying a variety of technologies in order to investigate each method’s potential which effectively removes pollutants from wastewater addressing both environmental challenges of wastewater treatment as well as clean energy production. Hydrogen production from wastewater using sustainable lowenergy methods enhances energy recovery in treatment plants and promotes a circular economy. This lowcarbon hydrogen supports global decarbonization and simultaneously achieving pollutant degradation with advanced systems offers dual benefits over traditional wastewater treatment methods. The essential details of 7 emerging technologies their working mechanisms affecting parameters work advances advantages and disadvantages and their future prospects are taken into consideration in 2 distinct classes- light-independent and light-dependent technologies.
Driving Sustainable Energy Co-Production: Gas Transfer and Pressure Dynamics Regulating Hydrogen and Carboxylic Acid Generation in Anaerobic Systems
Jul 2025
Publication
To achieve energy transition hydrogen and carboxylic acids have attracted much attention due to their cleanliness and renewability. Anaerobic fermentation technology is an effective combination of waste biomass resource utilization and renewable energy development. Therefore the utilization of anaerobic fermentation technology is expected to achieve efficient co-production of hydrogen and carboxylic acids. However this process is fundamentally affected by gas–liquid mass transfer kinetics bubble behaviors and system partial pressure. Moreover the related studies are few and unfocused and no systematic research has been developed yet. This review systematically summarizes and discusses the basic mathematical models used for gas–liquid mass transfer kinetics the relationship between gas solubility and mass transfer and the liquid-phase product composition. The review analyzes the roles of the headspace gas composition and partial pressure of the reaction system in regulating co-production. Additionally we discuss strategies to optimize the metabolic pathways by modulating the gas composition and partial pressure. Finally the feasibility of and prospects for the realization of hydrogen and carboxylic acid co-production in anaerobic fermentation systems are outlined. By exploring information related to gas mass transfer and system pressure this review will surely provide an important reference for promoting cleaner production of sustainable energy.
Life-cycle Assessment and Cost Analysis of Hydrogen Production via Aluminium-seawater Reactions
Jun 2025
Publication
Presented is an evaluation of the carbon footprint and costs associated with hydrogen production via the aluminum-water reaction (AWR) identifying an optimized scenario that achieves 1.45 kgCO2 equiv per kg of hydrogen produced. U.S.-based data are used to compare results with conventional production methods and to assess hydrogen use in fuel-cell passenger vehicles. In the optimized scenario major contributors include the use of recycled aluminum (0.38 kgCO2 equiv) aluminum processing (0.45 kgCO2 equiv) and alloy activator recovery (0.57 kgCO2 equiv). A cost analysis estimates hydrogen production at $9.2/kg when using scrap aluminum alloy recovery and recycling thermal energy aligning with current green hydrogen prices. Reselling reaction byproducts such as boehmite could generate revenue 5.6 times greater than input costs enhancing economic feasibility. The cradle-to-grave assessment suggests that aluminum fuel as an energy carrier for hydrogen distribution and fuel cell vehicle applications offers a low-emission and economically viable pathway for clean energy deployment.
Mechanisms for the Low-Carbon Transition of Public Transport Energy Systems: Decoupling Emissions and Energy Consumption in Inner Mongolia and the Path to Three-Chain Synergy
Sep 2025
Publication
To achieve deep decarbonization in the transportation sector this study employs life cycle assessment (LCA) and the GREET model to construct baseline and low-carbon scenarios. It simulates the evolution of emissions and energy consumption within Inner Mongolia’s public transportation energy system (including diesel buses (DBs) electric buses (EBs) and hydrogen fuel cell buses (HFCBs)) from 2022 to 2035 while exploring synergistic pathways for its low-carbon transition. Results reveal that under the baseline scenario reliance on industrial by-product hydrogen causes fuel cell bus emissions to increase by 3.64% in 2025 compared to 2022 with system energy savings below 10% and decarbonization potential will be constrained by scale limitations and storage/transportation losses in cold regions. Under the low-carbon scenario deep grid decarbonization vehicle structure optimization and green hydrogen integration reduced system emissions and energy consumption by 66.86% and 40.44% respectively compared to 2022. The study identifies a 15% green hydrogen penetration rate as the critical threshold for resource misallocation and confirms grid decarbonization as the top-priority policy tool yielding marginal benefits 1.43 times greater than standalone hydrogen policies. This study underscores the importance of multipolicy coordination and ‘technology-supply chain’ synergy particularly highlighting the critical threshold of green hydrogen penetration and the primacy of grid decarbonization offering insights for similar coal-dominated cold-region transportation energy transitions.
Synergizing Gas and Electric Systems Using Power-to-Hydrogen: Integrated Solutions for Clean and Sustainable Energy Networks
May 2025
Publication
The rapid growth in natural gas consumption by gas-fired generators and the emergence of power-to-hydrogen (P2H) technology have increased the interdependency of natural gas and power systems presenting new challenges to energy system operators due to the heterogeneous uncertainties associated with power loads renewable energy sources (RESs) and gas loads. These uncertainties can easily spread from one infrastructure to another increasing the risk of cascading outages. Given the erratic nature of RESs P2H technology provides a valuable solution for large-scale energy storage systems crucial for the transition to economic clean and secure energy systems. This paper proposes a new approach for the co-optimized operation of gas and electric power systems aiming to reduce combined operating costs by 10–15% without jeopardizing gas and energy supplies to customers. A mixed integer non-linear programming (MINLP) model is developed for the optimal day-ahead operation of these integrated systems with a case study involving the IEEE 24-bus power system and a 20-node natural gas system. Simulation results demonstrate the model’s effectiveness in minimizing total costs by up to 20% and significantly reducing renewable energy curtailment by over 50%. The proposed approach supports UN Sustainable Development Goals by ensuring sustainable energy (SDG 7) fostering innovation and resilient infrastructure (SDG 9) enhancing energy efficiency for resilient cities (SDG 11) promoting responsible consumption (SDG 12) contributing to climate action (SDG 13) and strengthening partnerships (SDG 17). It promotes clean energy technological innovation resilient infrastructure efficient resource use and climate action supporting the transition to sustainable energy systems.
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