Applications & Pathways
Operable Range Extension of Ammonia Direct Injection Spark Ignition Engine by Hydrogen Addition
Feb 2024
Publication
Ammonia is gaining attention as a non-carbon environmental-friendly fuel due to its superior storage capability compared to hydrogen. However its high minimum ignition energy and slow laminar flame speed make it unsuitable for application in combustion-based energy conversion devices. In particular when applied to internal combustion engines issues such as combustion instability and limitations in operational range exist. Therefore the intention is to address these issues by adding hydrogen which has a wider flammable range and a faster laminar flame speed to ammonia. In this study the extension of the operable range of ammonia-fueled spark ignition engine by hydrogen addition was mainly discussed. Ammonia was injected directly in the cylinder and hydrogen was supplied into the intake port. The result showed that operable range of ammonia fueled combustion with hydrogen addition could be extended from 0.2 to 1.4 MPa with relatively stable combustion i.e. CoV of gIMEP
Deploying Green Hydrogen to Decarbonize China's Coal Chemical Sector
Dec 2023
Publication
China’s coal chemical sector uses coal as both a fuel and feedstock and its increasing greenhouse gas (GHG) emissions are hard to abate by electrification alone. Here we explore the GHG mitigation potential and costs for onsite deployment of green H2 and O2 in China’s coal chemical sector using a lifecycle assessment and techno-economic analyses. We estimate that China’s coal chemical production resulted in GHG emissions of 1.1 gigaton CO2 equivalent (GtCO2eq) in 2020 equal to 9% of national emissions. We project GHG emissions from China’s coal chemical production in 2030 to be 1.3 GtCO2eq ~50% of which can be reduced by using solar or wind power-based electrolytic H2 and O2 to replace coal-based H2 and air separation-based O2 at a cost of 10 or 153 Chinese Yuan (CNY)/tCO2eq respectively. We suggest that provincial regions determine whether to use solar or wind power for water electrolysis based on lowest cost options which collectively reduce 53% of the 2030 baseline GHG emissions at a cost of 9 CNY/tCO2eq. Inner Mongolia Shaanxi Ningxia and Xinjiang collectively account for 52% of total GHG mitigation with net cost reductions. These regions are well suited for pilot policies to advance demonstration projects.
Assessing the Potential of Decarbonization Options for Industrial Sectors
Jan 2024
Publication
Industry emits around a quarter of global greenhouse gas (GHG) emissions. This paper presents the first comprehensive review to identify the main decarbonization options for this sector and their abatement potentials. First we identify the important GHG emitting processes and establish a global average baseline for their current emissions intensity and energy use. We then quantify the energy and emissions reduction potential of the most significant abatement options as well as their technology readiness level (TRL). We find that energy-intensive industries have a range of decarbonization technologies available with medium to high TRLs and mature options also exist for decarbonizing low-temperature heat across a wide range of industrial sectors. However electrification and novel process change options to reduce emissions from high-temperature and sector-specific processes have much lower TRLs in comparison. We conclude by highlighting important barriers to the deployment of industrial decarbonization options and identifying future research development and demonstration needs.
Two-stage Optimization of Hydrogen and Storage Coordination for a Multi-region Flexible Intermodal Multi-energy Port System
Jan 2024
Publication
To address the issue of imbalanced electricity and hydrogen supply and demand in the flexible multi-energy port area system a multi-regional operational optimization and energy storage capacity allocation strategy considering the working status of flexible multi-status switches is proposed. Firstly based on the characteristics of the port area system models for system operating costs generation equipment energy storage devices flexible multi-status switches and others are established. Secondly the system is subjected to a first-stage optimization where different regions are optimized individually. The working periods of flexible multi-status switches are determined based on the results of this first-stage optimization targeting the minimization of the overall daily operating costs while ensuring 100% integration of renewable energy in periods with electricity supply-demand imbalances. Subsequently additional constraints are imposed based on the results of the first-stage optimization to optimize the entire system obtaining power allocation during system operation as well as power and capacity requirements for energy storage devices and flexible multi-status switches. Finally the proposed approach is validated through simulation examples demonstrating its advantages in terms of economic efficiency reduced power and capacity requirements for energy storage devices and carbon reduction.
Look-ahead Scheduling of Energy-Water Nexus Integrated with Power2X Conversion Technologies under Multiple Uncertainties
Aug 2023
Publication
Co-optimizing energy and water resources in a microgrid can increase efficiency and improve economic performance. Energy-water storage (EWS) devices are crucial components of a high-efficient energy-water microgrid (EWMG). The state of charge (SoC) at the end of the first day of operation is one of the most significant variables in EWS devices since it is used as a parameter to indicate the starting SoC for the second day which influences the operating cost for the second day. Hence this paper examines the benefits and applicability of a lookahead optimization strategy for an EWMG integrated with multi-type energy conversion technologies and multienergy demand response to supply various energy-water demands related to electric/hydrogen vehicles and commercial/residential buildings with the lowest cost for two consecutive days. In addition a hybrid info-gap/robust optimization technique is applied to cover uncertainties in photovoltaic power and electricity prices as a tri-level optimization framework without generating scenarios and using the probability distribution functions. Duality theory is also used to convert the problem into a single-level MILP so that it can be solved by CPLEX. According to the findings the implemented energy-water storage systems and look-ahead strategy accounted for respectively 4.03% and 0.43% reduction in the total cost.
Capacity Configuration Optimization for Green Hydrogen Generation by Solar-wind Hybrid Power Based on Comprehensive Performance Criteria
Aug 2023
Publication
Green hydrogen generation driven by solar-wind hybrid power is a key strategy for obtaining the low-carbon energy while by considering the fluctuation natures of solar-wind energy resource the system capacity configuration of power generation hydrogen production and essential storage devices need to be comprehensively optimized. In this work a solar-wind hybrid green hydrogen production system is developed by combining the hydrogen storage equipment with the power grid the coordinated operation strategy of solar-wind hybrid hydrogen production is proposed furthermore the NSGA-III algorithm is used to optimize the system capacity configuration with the comprehensive performance criteria of economy environment and energy efficiency. Through the implemented case study with the hydrogen production capacity of 20000 tons/year the abandoned energy power rate will be reduced to 3.32% with the electrolytic cell average load factor of 64.77% and the system achieves the remarkable carbon emission reduction. In addition with the advantage of connect to the power grid the generated surplus solar/wind power can be readily transmitted with addition income when the sale price of produced hydrogen is suggested to 27.80 CNY/kgH2 the internal rate of return of the system reaches to 8% which present the reasonable economic potential. The research provides technical and methodological suggestions and guidance for the development of solar-wind hybrid hydrogen production schemes with favorable comprehensive performance.
Prospective Assessment of Transformation Pathways Toward Low-carbon Steelmaking: Evaluating Economic and Climate Impacts in Germany
Jan 2024
Publication
Due to climate change there is an urgent need to decarbonize high-emission industries. As coal-based operations predominate in primary steelmaking the steel industry offers an exceptionally high potential for reducing greenhouse gas emissions. Alternative processes for almost fully decarbonized primary steelmaking exist but require substantial investments by steelmakers for their implementation while maintaining desired production levels during the transformation periods. In this context the energy carriers required change such that the transformation of the steelmaking processes is deeply intertwined with the transformation of the background system. For the first time we evaluate potential transformation pathways from the steelmakers’ perspective using a prospective life cycle assessment approach. We find that hydrogen may facilitate a reduction of direct emissions by around 96 % compared to conventional steelmaking in 2050. However indirect emissions remain at a high level throughout the transformation period unless the upstream stages of the value chain are transformed accordingly.
A Systematic Review of Predictive, Optimization, and Smart Control Strategies for Hydrogen-based Building Heating Systems
Nov 2024
Publication
The use of energy in the built environment contributes to over one-third of the world’s carbon emissions. To reduce that effect two primary solutions can be adopted i.e. (i) renovation of old buildings and (ii) increasing the renewable energy penetration. This review paper focuses on the latter. Renewable energy sources typically have an intermittent nature. In other words it is not guaranteed that these sources can be harnessed on demand. Thus complement solutions should be considered to use renewable energy sources efficiently. Hydrogen is recognized as a potential solution. It can be used to store excess energy or be directly exploited to generate thermal energy. Throughout this review various research papers focusing on hydrogen-based heating systems were reviewed analyzed and classified from different perspectives. Subsequently articles related to machine learning models optimization algorithms and smart control systems along with their applications in building energy management were reviewed to outline their potential contributions to reducing energy use lowering carbon emissions and improving thermal comfort for occupants. Furthermore research gaps in the use of these smart strategies in residential hydrogen heating systems were thoroughly identified and discussed. The presented findings indicate that the semi-decentralized hydrogen-based heating systems hold significant potential. First these systems can control the thermal demand of neighboring homes through local substations; second they can reduce reliance on power and gas grids. Furthermore the model predictive control and reinforcement learning approaches outperform other control systems ensuring energy comfort and cost-effective energy bills for residential buildings.
Energy Management of Hydrogen Hybrid Electric Vehicles - A Potential Analysis
Jan 2024
Publication
The hydrogen combustion engine (H2 ICE) is known to be able to burn H2 producing no CO2 emissions and extremely low engine-out NOeo emissions. In this work the potential to reduce the NOeo emissions through the implementation of electric hybridization of an H2 ICE-equipped passenger car (H2 -HEV) combined with a dedicated energy management system (EMS) is discussed. Achieving a low H2 consumption and low NOeo emissions are conflicting objectives the trade-off of which depends on the EMS and can be represented as a Pareto front. The dynamic programming algorithm is used to calculate the Pareto-optimal EMS calibrations for various driving missions. Through the utilization of a dedicated energy management calibration H2 -HEVs exhibit the potential to decrease the NOeo x emissions by more than 90% while decreasing the H2 consumption by over 16% compared to a comparable non-hybridized H2 -vehicle. The present paper represents the initial potential analysis suggesting that H2 -HEVs are a viable option towards a CO2 -free mobility with extremely low NOeo emissions.
The Heat Transfer Potential of Compressor Vanes on a Hydrogen Fueled Turbofan Engine
Sep 2023
Publication
Hydrogen is a promising fuel for future aviation due to its CO2-free combustion. In addition its excellent cooling properties as it is heated from cryogenic conditions to the appropriate combustion temperatures provides a multitude of opportunities. This paper investigates the heat transfer potential of stator surfaces in a modern high-speed low-pressure compressor by incorporating cooling channels within the stator vane surfaces where hydrogen is allowed to flow and cool the engine core air. Computational Fluid Dynamics simulations were carried out to assess the aerothermal performance of this cooled compressor and were compared to heat transfer correlations. A core air temperature drop of 9.5 K was observed for this cooling channel design while being relatively insensitive to the thermal conductivity of the vane and cooling channel wall thickness. The thermal resistance was dominated by the air-side convective heat transfer and more surface area on the air-side would therefore be required in order to increase overall heat flow. While good agreement with established heat transfer correlations was found for both turbulent and transitional flow the correlation for the transitional case yielded decent accuracy only as long as the flow remains attached and while transition was dominated by the bypass mode. A system level analysis indicated a limited but favorable impact at engine performance level amounting to a specific fuel consumption improvement of up to 0.8% in cruise and an estimated reduction of 3.6% in cruise NOx. The results clearly show that although it is possible to achieve high heat transfer rate per unit area in compressor vanes the impact on cycle performance is constrained by the limited available wetted area in the low-pressure compressor.
Methanol, a Plugin Marine Fuel for Green House Gas Reduction—A Review
Jan 2024
Publication
The escalating global demand for goods transport via shipping has heightened energy consumption impacting worldwide health and the environment. To mitigate this international organizations aim to achieve complete fuel desulphurization and decarbonization by 50% by 2050. Investigating eco-friendly fuels is crucial particularly those with a reduced carbon and zero sulfur content. Methanol derived mainly from renewable sources and produced by carbon dioxide’s hydrogenation method stands out as an effective solution for GHG reduction. Leveraging its favorable properties global scalability and compatibility with the existing infrastructure especially LNGs methanol proves to be a cost-efficient and minimally disruptive alternative. This review explores methanol’s role as a hybrid maritime fuel emphasizing its ecological production methods advantages and challenges in the shipping industry’s green transition. It discusses the environmental impacts of methanol use and analyzes economic factors positioning methanol not only as an ecofriendly option but also as a financially prudent choice for global shipping. Methanol is efficient and cost-effective and excels over MGO especially in new ships. It is economically advantageous with decreasing investment costs compared to LNG while providing flexibility without specialized pressure tanks. Global marine fuel trends prioritize fuel traits accessibility and environmental considerations incorporating factors like policies emissions bunkering and engine adaptability during transitions.
Environmental Implications and Levelized Cost Analysis of E-fuel Production under Photovoltaic Energy, Direct Air Capture, and Hydrogen
Jan 2024
Publication
The ecological transition in the transport sector is a major challenge to tackle environmental pollution and European legislation will mandate zero-emission new cars from 2035. To reduce the impact of petrol and diesel vehicles much emphasis is being placed on the potential use of synthetic fuels including electrofuels (e-fuels). This research aims to examine a levelised cost (LCO) analysis of e-fuel production where the energy source is renewable. The energy used in the process is expected to come from a photovoltaic plant and the other steps required to produce e-fuel: direct air capture electrolysis and Fischer-Tropsch process. The results showed that the LCOe-fuel in the baseline scenario is around 3.1 €/l and this value is mainly influenced by the energy production component followed by the hydrogen one. Sensitivity scenario and risk analyses are also conducted to evaluate alternative scenarios and it emerges that in 84% of the cases LCOe-fuel ranges between 2.8 €/l and 3.4 €/l. The findings show that the current cost is not competitive with fossil fuels yet the development of e-fuels supports environmental protection. The concept of pragmatic sustainability incentive policies technology development industrial symbiosis economies of scale and learning economies can reduce this cost by supporting the decarbonisation of the transport sector.
Renewable Hydrogen Requirements and Impacts for Network Balancing: A Queensland Cae Study
Dec 2023
Publication
Hydrogen is the gas of the moment: an abundant element that can be created using renewable energy transported in gaseous or liquid form and offering the ability to provide energy with only water vapour as an emission. Hydrogen can also be used in a fuel blend in electricity generation gas turbines providing a low carbon option for providing the peak electricity to cover high demand and firming.<br/>While the electricity grid is itself transforming to decarbonising hard-to-abate industries such as cement and bauxite refineries are slower to reduce emissions constrained by their high temperature process requirements. Hydrogen offers a solution allowing onsite production process heat with waste heat recovery supporting blended gas turbine generation for onsite electricity supply.<br/>This article builds on decarbonisation pathway simulation results from an ANEM model of the electricity grid identifying the amount of peak demand energy required from gas turbines. The research then examines the quantity flow rate storage requirements and emissions reduction if this peak generation were supplied by open cycle hydrogen capable gas turbines.
Fuelling the Future: An In-depth Review of Recent Trends, Challenges and Opportunities of Hydrogen Fuel Cell for a Sustainable Hydrogen Economy
Sep 2023
Publication
Hydrogen has gained tremendous momentum worldwide as an energy carrier to transit to a net zero emission energy sector. It has been widely adopted as a promising large-scale renewable energy (RE) storage solution to overcome RE resources’ variability and intermittency nature. The fuel cell (FC) technology became in focus within the hydrogen energy landscape as a cost-effective pathway to utilize hydrogen for power generation. Therefore FC technologies’ research and development (R&D) expanded into many pathways such as cost reduction efficiency improvement fixed and mobile applications lifetime safety and regulations etc. Many publications and industrial reports about FC technologies and applications are available. This raised the necessity for a holistic review study to summarize the state-of-the-art range of FC stacks such as manufacturing the balance of plant types technologies applications and R&D opportunities. At the beginning the principal technologies to compare the well known types followed by the FC operating parameters are presented. Then the FC balance of the plant i.e. building components and materials with its functionality and purpose types and applications are critically reviewed with their limitations and improvement opportunities. Subsequently the electrical properties of FCs with their key features including advantages and disadvantages were investigated. Applications of FCs in different sectors are elaborated with their key characteristics current status and future R&D opportunities. Economic attributes of fuel cells with a pathway towards low cost are also presented. Finally this study identifies the research gaps and future avenues to guide researchers and the hydrogen industry.
Thermodynamic Analysis of the Combustion Process in Hydrogen-Fueled Engines with EGR
Jun 2024
Publication
This article presents a novel approach to the analysis of heat release in a hydrogen-fueled internal combustion spark-ignition engine with exhaust gas recirculation (EGR). It also discusses aspects of thermodynamic analysis common to modeling and empirical analysis. This new approach concerns a novel method of calculating the specific heat ratio (cp/cv) and takes into account the reduction in the number of moles during combustion which is characteristic of hydrogen combustion. This reduction in the number of moles was designated as a molar contraction. This is particularly crucial when calculating the average temperature during combustion. Subsequently the outcomes of experimental tests including the heat-release rate the initial combustion phase (denoted CA0- 10) and the main combustion phase (CA10-90) are presented. Furthermore the impact of exhaust gas recirculation on the combustion process in the engine is also discussed. The efficacy of the proposed measures was validated by analyzing the heat-release rate and calculating the mean combustion temperature in the engine. The application of EGR in the range 0-40% resulted in a notable prolongation of both the initial and main combustion phases which consequently influenced the mean combustion temperature.
Uncertainty Quantification in Hydrogen Tank Exchange: Estimating Maintenance Costs for New Aircraft Concepts
Apr 2024
Publication
The increasing demand for sustainable air mobility has led to the development of innovative aircraft designs necessitating a balance between environmental responsibility and profitability. However despite technological advancements there is still limited understanding of the maintenance implications for hydrogen systems in aviation. The aim of this study is to estimate the maintenance costs of replacing the hydrogen storage system in an aircraft as part of its life cycle costs. To achieve this we compared conventional and hydrogenpowered aircraft. As there is insufficient data for new aircraft concepts typical probabilistic methods are not applicable. However by combining global sensitivity analysis with Dempster–Shafer Theory of Evidence and discrete event simulation it is possible to identify key uncertainties that impact maintenance costs and economic efficiency. This innovative framework offers an early estimate of maintenance costs under uncertainty enhancing understanding and assisting in decision-making when integrating hydrogen storage systems and new aviation technologies.
Environmental Assessment of Replacing Fossil Fuels with Hydrogen for Motorised Equipment in the Mining Sector
Nov 2023
Publication
To achieve the European milestone of climate neutrality by 2050 the decarbonisation of energy-intensive industries is essential. In 2022 global energy-related CO2 emissions increased by 0.9% or 321 Mt reaching a peak of over 36.8 Gt. A large amount of these emissions is the result of fossil fuel usage in the motorised equipment used in mining. Heavy diesel vehicles like excavators wheel loaders and dozers are responsible for an estimated annual CO2 emissions of 400 Mt of CO2 accounting for approximately 1.1% of global CO2 emissions. In addition exhaust gases of CO2 and NOx endanger the personnel’s health in all mining operations especially in underground environments. To tackle these environmental concerns and enhance environmental health extractive industries are focusing on replacing fossil fuels with alternative fuels of low or zero CO2 emissions. In mining the International Council on Mining and Metals has committed to achieving net zero emissions by 2050 or earlier. Of the various alternative fuels hydrogen (H2 ) has seen a considerable rise in popularity in recent years as H2 combustion accounts for zero CO2 emissions due to the lack of carbon in the burning process. When combusted with pure oxygen it also accounts for zero NOx formation and near-zero emissions overall. To this end this study aims to examine the overall environmental performance of H2 -powered motorised equipment compared to conventional fossil fuel-powered equipment through Life Cycle Assessment. The assessment was conducted using the commercial software Sphera LCA for Experts following the conventionally used framework established by ISO 14040:2006 and 14044:2006/A1:2018 and the International Life Cycle Data Handbook consisting of (1) the goal and scope definition (2) the Life Cycle Inventory (LCI) preparation (3) the Life Cycle Impact Assessment (LCIA) and (4) the interpretation of the results. The results will offer an overview to support decision-makers in the sector.
Different Strategies in an Integrated Thermal Management System of a Fuel Cell Electric Bus Under Real Driving Cycles in Winter
May 2023
Publication
Due to the climate crisis and the restriction measures taken in the last decade electric buses are gaining popularity in the transport sector. However one of the most significant disadvantages of this type of vehicle is its low autonomy. Many electric buses with proton-exchange membrane fuel cells (PEMFC) systems have been developed to solve this problem in recent years. These have an advantage over battery-electric buses because the autonomy depends on the capacity of the hydrogen tanks. As with batteries thermal management is crucial for fuel cells to achieve good performance and prolong service life. For this reason it is necessary to investigate different strategies or configurations of a fuel cell electric bus’s integral thermal management system (ITMS). In the present work a novel global model of a fuel cell electric bus (FCEB) has been developed which includes the thermal models of the essential components. This model was used to evaluate different strategies in the FCEB integrated thermal management system simulating driving cycles of the public transport system of Valencia Spain under winter weather conditions. The first strategy was to use the heat generated by the fuel cell to heat the vehicle’s cabin achieving savings of up to 7%. The second strategy was to use the waste heat from the fuel cells to preheat the batteries. It was found that under conditions where a high-power demand is placed on the fuel cell it is advisable to use the residual heat to preheat the battery resulting in an energy saving of 4%. Finally a hybrid solution was proposed in which the residual heat from fuel cells is used to heat both the cabin and the battery resulting in an energy saving of 10%.
Path Analysis of Using Hydrogen Energy to Reduce Greenhouse Gas Emissions in Global Aviation
Jul 2024
Publication
The rapid growth of global aviation emissions has significantly impacted the environment leading to an urgent need to use carbon reduction methods. This paper analyzes global aviation’s carbon dioxide (CO2) N2O and CH4 emission changes under different hydrogen energy application paths. The global warming potential over a 100-year period (GWP100) method is used to convert the emissions of N2O and CH4 into CO2-equivalent. Here we report the results: if the global aviation industry begins using hydrogen turbine engines by 2040 it could reduce cumulative CO2-equivalent emissions by 2.217E+10 tons by 2080 which is 2.12% higher than starting hydrogen fuel cell engines in 2045. However adopting hydrogen fuel cell engines 10 years earlier shows greater reduction capabilities than hydrogen turbine engines achieving an accumulated reduction of 3.006E+10 tons of CO2-equivalent emissions. Therefore the timing of adoption notably affects hydrogen fuel cell engines more than hydrogen turbine engines. Delaying adoption makes hydrogen fuel cell engines’ performance lag hydrogen turbine engines.
Life Cycle Analysis of Hydrogen Powered Marine Vessels—Case Ship Comparison Study with Conventional Power System
Aug 2023
Publication
The latest International Maritime Organization strategies aim to reduce 70% of the CO2 emissions and 50% of the Greenhouse Gas (GHG) emissions from maritime activities by 2050 compared to 2008 levels. The EU has set up goals to reduce GHG emissions by at least 55% by 2030 compared to 1990 and achieve net-zero GHG emissions by 2050. The UK aims to achieve more than 68% GHG emission reduction by 2030 and net-zero GHG emissions by 2050. There are many solutions under development to tackle the challenge of meeting the latest decarbonization strategies from the IMO EU and UK among which are hydrogen powered marine vessels. This paper presents a life cycle analysis study for hydrogen fuelled vessels by evaluating their performance in terms of environmental friendliness and economic feasibility. The LCA study will consider the gas emissions and costs during the life stages of the ships including the construction operation maintenance and recycling phases of the selected vessels. The results of the comparisons with the conventional version of the ships (driven by diesel generators) demonstrate the benefits of using hydrogen for marine transportation: over 80% emission reduction and around 60% life cycle cost savings. A sensitivity analysis shows that the prices of fuels and carbon credits can affect the life cycle cost and recommendations for low H2 price and high carbon credit in the future are provided to attract the industry to adopt the new fuel.
Advances in Hospital Energy Systems: Genetic Algorithm Optimization of a Hybrid Solar and Hydrogen Fuel Cell Combined Heat and Power
Sep 2024
Publication
This paper presents an innovative Fuel Cell Combined Heat and Power (FC–CHP) system designed to enhance energy efficiency in hospital settings. The system primarily utilizes solar energy captured through photovoltaic (PV) panels for electricity generation. Excess electricity is directed to an electrolyzer for water electrolysis producing hydrogen which is stored in high-pressure tanks. This hydrogen serves a dual purpose: it fuels a boiler for heating and hot water needs and powers a fuel cell for additional electricity when solar production is low. The system also features an intelligent energy management system that dynamically allocates electrical energy between immediate consumption hydrogen production and storage while also managing hydrogen release for energy production. This study focuses on optimization using genetic algorithms to optimize key components including the peak power of photovoltaic panels the nominal power of the electrolyzer fuel cell and storage tank sizes. The objective function minimizes the sum of investment and electricity costs from the grid considering a penalty coefficient. This approach ensures optimal use of renewable energy sources contributing to energy efficiency and sustainability in healthcare facilities.
Alternative Gaseous Fuels for Marine Vessels towards Zero-Carbon Emissions
Nov 2023
Publication
The maritime industry is recognized as a major pollution source to the environment. The use of low- or zero-carbon marine alternative fuel is a promising measure to reduce emissions of greenhouse gases and toxic pollutants leading to net-zero carbon emissions by 2050. Hydrogen (H2 ) fuel cells particularly proton exchange membrane fuel cell (PEMFC) and ammonia (NH3 ) are screened out to be the feasible marine gaseous alternative fuels. Green hydrogen can reduce the highest carbon emission which might amount to 100% among those 5 types of hydrogen. The main hurdles to the development of H2 as a marine alternative fuel include its robust and energy-consuming cryogenic storage system highly explosive characteristics economic transportation issues etc. It is anticipated that fossil fuel used for 35% of vehicles such as marine vessels automobiles or airplanes will be replaced with hydrogen fuel in Europe by 2040. Combustible NH3 can be either burned directly or blended with H2 or CH4 to form fuel mixtures. In addition ammonia is an excellent H2 carrier to facilitate its production storage transportation and usage. The replacement of promising alternative fuels can move the marine industry toward decarbonization emissions by 2050.
Optimal Sizing of Renewables-to-hydrogen Systems in a Suitable-site-selection Geospatial Framework: The Case Study if Italy and Portugal
Jun 2024
Publication
Growing renewable energy deployment worldwide has sparked a shift in the energy landscape with far-reaching geopolitical ramifications. Hydrogen’s role as an energy carrier is central to this change facilitating global trade and the decarbonisation of hard-to-abate sectors. This analysis offers a new method for optimally sizing solar/wind-to-hydrogen systems in specifically suitable locations. These locations are limited to the onshore and offshore regions of selected countries as determined by a bespoke geospatial analysis developed to be location-agnostic. Furthermore the research focuses on determining the best configurations for such systems that minimise the cost of producing hydrogen with the optimisation algorithm expanding from the detailed computation of the classic levelised cost of hydrogen. One of the study’s main conclusions is that the best hybrid configurations obtained provide up to 70% cost savings in some areas. Such findings represent unprecedented achievements for Italy and Portugal and can be a valuable asset for economic studies of this kind carried out by local and national governments across the globe. These results validate the optimisation model’s initial premise significantly improving the credibility of this work by constructively challenging the standard way of assessing large-scale green hydrogen projects.
Local Energy Community to Support Hydrogen Production and Network Flexibility
Jul 2024
Publication
This paper deals with the optimal scheduling of the resources of a renewable energy community whose coordination is aimed at providing flexibility services to the electrical distribution network. The available resources are renewable generation units battery energy storage systems dispatchable loads and power-to-hydrogen systems. The main purposes behind the proposed strategy are enhancement of self-consumption and hydrogen production from local resources and the maximization of the economic benefits derived from both the selling of hydrogen and the subsidies given to the community for the shared energy. The proposed approach is formulated as an economic problem accounting for the perspectives of both community members and the distribution system operator. In more detail a mixed-integer constrained non-linear optimization problem is formulated. Technical constraints related to the resources and the power flows in the electrical grid are considered. Numerical applications allow for verifying the effectiveness of the procedure. The results show that it is possible to increase self-consumption and the production of green hydrogen while providing flexibility services through the exploitation of community resources in terms of active and reactive power support. More specifically the application of the proposed strategy to different case studies showed that daily revenues of up to EUR 1000 for each MW of renewable energy generation installed can be obtained. This value includes the benefit obtained thanks to the provision of flexibility services which contribute about 58% of the total.
Minimization of Construction and Operation Costs of the Fuel Cell Bus Transportation System
Dec 2024
Publication
This paper took the actual bus transportation system as the object simulated the operating state of the system replaced all the current diesel engine buses with fuel cell buses using electrolysis-produced hydrogen and completed the existing timetable and routes. In the study the numbers of hydrogen production stations and hydrogen storage stations the maximum hydrogen storage capacity of the buses the supplementary hydrogen capacity of the buses and the hydrogen production capacity of the hydrogen storage stations were used as the optimal adjustment parameters for minimizing the ten-year construction and operating costs of the fuel cell bus transportation system by the artificial bee colony algorithm. Two hydrogen supply methods decentralized and centralized hydrogen production were analyzed. This paper used the actual bus timetable to simulate the operation of the buses including 14 transfer stations and 112 routes. The results showed that the use of centralized hydrogen production and partitioned hydrogen production transfer stations could indeed reduce the construction and operating costs of the fuel cell bus transportation system. Compared with the decentralized hydrogen production case the construction and operating costs could be reduced by 6.9% 12.3% and 14.5% with one two and three zones for centralized hydrogen production respectively.
Renewable Electricity and Green Hydrogen Integration for Decarbonization of “Hard-to-Abate” Industrial Sectors
Jul 2024
Publication
This paper investigates hydrogen’s potential to accelerate the energy transition in hardto-abate sectors such as steel petrochemicals glass cement and paper. The goal is to assess how hydrogen produced from renewable sources can foster both industrial decarbonization and the expansion of renewable energy installations especially solar and wind. Hydrogen’s dual role as a fuel and a chemical agent for process innovation is explored with a focus on its ability to enhance energy efficiency and reduce CO2 emissions. Integrating hydrogen with continuous industrial processes minimizes the need for energy storage making it a more efficient solution. Advances in electrolysis achieving efficiencies up to 60% and storage methods consuming about 10% of stored energy for compression are discussed. Specifically in the steel sector hydrogen can replace carbon as a reductant in the direct reduced iron (DRI) process which accounts for around 7% of global steel production. A next-generation DRI plant producing one million tons of steel annually would require approximately 3200 MW of photovoltaic capacity to integrate hydrogen effectively. This study also discusses hydrogen’s role as a co-fuel in steel furnaces. Quantitative analyses show that to support typical industrial plants hydrogen facilities of several hundred to a few thousand MW are necessary. “Virtual” power plants integrating with both the electrical grid and energy-intensive systems are proposed highlighting hydrogen’s critical role in industrial decarbonization and renewable energy growth.
Optimizing Green Hydrogen Production from Wind and Solar for Hard-to-abate Industrial Sectors Across Multiple Sites in Europe
Jul 2024
Publication
This article analyzes a power-to-hydrogen system designed to provide high-temperature heat to hard-to-abate industries. We leverage on a geospatial analysis for wind and solar availability and different industrial demand profiles with the aim to identify the ideal sizing of plant components and the resulting Levelized Cost of Hydrogen (LCOH). We assess the carbon intensity of the produced hydrogen especially when grid electricity is utilized. A methodology is developed to size and optimize the PV and wind energy capacity the electrolyzer unit and hybrid storage by combining compressed hydrogen storage with lithium-ion batteries. The hydrogen demand profile is generated synthetically thus allowing different industrial consumption profiles to be investigated. The LCOH in a baseline scenario ranges from 3.5 to 8.9 €/kg with the lowest values in wind-rich climates. Solar PV only plays a role in locations with high PV full-load hours. It was found that optimal hydrogen storage can cover the users’ demand for 2–3 days. Most of the considered scenarios comply with the emission intensity thresholds set by the EU. A sensitivity analysis reveals that a lower variability of the demand profile is associated with cost savings. An ideally constant demand profile results in a cost reduction of approximately 11 %.
An Analysis of Hybrid Renewable Energy-Based Hydrogen Production and Power Supply for Off-Grid Systems
Jun 2024
Publication
Utilizing renewable energy sources to produce hydrogen is essential for promoting cleaner production and improving power utilization especially considering the growing use of fossil fuels and their impact on the environment. Selecting the most efficient method for distributing power and capacity is a critical issue when developing hybrid systems from scratch. The main objective of this study is to determine how a backup system affects the performance of a microgrid system. The study focuses on power and hydrogen production using renewable energy resources particularly solar and wind. Based on photovoltaics (PVs) wind turbines (WTs) and their combinations including battery storage systems (BSSs) and hydrogen technologies two renewable energy systems were examined. The proposed location for this study is the northwestern coast of Saudi Arabia (KSA). To simulate the optimal size of system components and determine their cost-effective configuration the study utilized the Hybrid Optimization Model for Multiple Energy Resources (HOMER) software (Version 3.16.2). The results showed that when considering the minimum cost of energy (COE) the integration of WTs PVs a battery bank an electrolyzer and a hydrogen tank brought the cost of energy to almost 0.60 USD/kWh in the system A. However without a battery bank the COE increased to 0.72 USD/kWh in the same location because of the capital cost of system components. In addition the results showed that the operational life of the fuel cell decreased significantly in system B due to the high hours of operation which will add additional costs. These results imply that long-term energy storage in off-grid energy systems can be economically benefited by using hydrogen with a backup system.
Optimal Multi-layer Economical Schedule for Coordinated Multiple Mode Operation of Wind-solar Microgrids with Hybrid Energy Storage Systems
Nov 2023
Publication
The aim of this paper is the design and implementation of an advanced model predictive control (MPC) strategy for the management of a wind–solar microgrid (MG) both in the islanded and grid-connected modes. The MG includes energy storage systems (ESSs) and interacts with external hydrogen and electricity consumers as an extra feature. The system participates in two different electricity markets i.e. the daily and real-time markets characterized by different time-scales. Thus a high-layer control (HLC) and a low-layer control (LLC) are developed for the daily market and the real-time market respectively. The sporadic characteristics of renewable energy sources and the variations in load demand are also briefly discussed by proposing a controller based on the stochastic MPC approach. Numerical simulations with real wind and solar generation profiles and spot prices show that the proposed controller optimally manages the ESSs even when there is a deviation between the predicted scenario determined at the HLC and the real-time one managed by the LLC. Finally the strategy is tested on a lab-scale MG set up at Khalifa University Abu Dhabi UAE.
Enabling Safe and Sustainable Hydrogen Mobility: Circular Economy-Driven Management of Hydrogen Vehicle Safety
Sep 2023
Publication
Hydrogen vehicles encompassing fuel cell electric vehicles (FCEVs) are pivotal within the UK’s energy landscape as it pursues the goal of net-zero emissions by 2050. By markedly diminishing dependence on fossil fuels FCEVs including hydrogen vehicles wield substantial influence in shaping the circular economy (CE). Their impact extends to optimizing resource utilization enabling zero-emission mobility facilitating the integration of renewable energy sources supplying adaptable energy storage solutions and interconnecting diverse sectors. The widespread adoption of hydrogen vehicles accelerates the UK’s transformative journey towards a sustainable CE. However to fully harness the benefits of this transition a robust investigation and implementation of safety measures concerning hydrogen vehicle (HV) use are indispensable. Therefore this study takes a holistic approach integrating quantitative risk assessment (QRA) and an adaptive decision-making trial and evaluation laboratory (DEMATEL) framework as pragmatic instruments. These methodologies ensure both the secure deployment and operational excellence of HVs. The findings underscore that the root causes of HV failures encompass extreme environments material defects fuel cell damage delivery system impairment and storage system deterioration. Furthermore critical driving factors for effective safety intervention revolve around cultivating a safety culture robust education/training and sound maintenance scheduling. Addressing these factors is pivotal for creating an environment conducive to mitigating safety and risk concerns. Given the intricacies of conducting comprehensive hydrogen QRAs due to the absence of specific reliability data this study dedicates attention to rectifying this gap. A sensitivity analysis encompassing a range of values is meticulously conducted to affirm the strength and reliability of our approach. This robust analysis yields precise dependable outcomes. Consequently decision-makers are equipped to discern pivotal underlying factors precipitating potential HV failures. With this discernment they can tailor safety interventions that lay the groundwork for sustainable resilient and secure HV operations. Our study navigates the intersection of HVs safety and sustainability amplifying their importance within the CE paradigm. Using the careful amalgamation of QRA and DEMATEL methodologies we chart a course towards empowering decision-makers with the insights to steer the hydrogen vehicle domain to safer horizons while ushering in an era of transformative eco-conscious mobility.
A New Path towards Sustainable Energy Transition: Techno-Economic Feasibility of a Complete Hybrid Small Modular Reactor/Hydrogen (SMR/H2) Energy System
Oct 2023
Publication
Small modular reactors (SMRs) are nuclear reactors with a smaller capacity than traditional large-scale nuclear reactors offering advantages such as increased safety flexibility and cost-effectiveness. By producing zero carbon emissions SMRs represent an interesting alternative for the decarbonization of power grids. Additionally they present a promising solution for the production of hydrogen by providing large amounts of energy for the electrolysis of water (pink hydrogen). The above hint at the attractiveness of coupling SMRs with hydrogen production and consumption centers in order to form clusters of applications which use hydrogen as a fuel. This work showcases the techno-economic feasibility of the potential installation of an SMR system coupled with hydrogen production the case study being the island of Crete. The overall aim of this approach is the determination of the optimal technical characteristics of such a system as well as the estimation of the potential environmental benefits in terms of reduction of CO2 emissions. The aforementioned system which is also connected to the grid is designed to serve a portion of the electric load of the island while producing enough hydrogen to satisfy the needs of the nearby industries and hotels. The results of this work could provide an alternative sustainable approach on how a hydrogen economy which would interconnect and decarbonize several industrial sectors could be established on the island of Crete. The proposed systems achieve an LCOE between EUR 0.046/kWh and EUR 0.052/kWh while reducing carbon emissions by more than 5 million tons per year in certain cases.
Optimal Decarbonization Strategies for an Industrial Port Area by Using Hydrogen as Energy Carrier
Jul 2023
Publication
This article discusses possible strategies for decarbonizing the energy systems of an existing port. The approach consists in creating a complete superstructure that includes the use of renewable and fossil energy sources the import or local production of hydrogen vehicles and other equipment powered by Diesel electricity or hydrogen and the associated refuelling and storage units. Two substructures are then identified one including all these options the other considering also the addition of the energy demand of an adjacent steel industry. The goal is to select from each of these two substructures the most cost-effective configurations for 2030 and 2050 that meet the emission targets for those years under different cost scenarios for the energy sources and conversion/storage units obtained from the most reliable forecasts found in the literature. To this end the minimum total cost of all the energy conversion and storage units plus the associated infrastructures is sought by setting up a Mixed Integer Linear Programming optimization problem where integer variables handle the inclusion of the different generation and storage units and their activation in the operational phases. The comprehensive picture of possible solutions set allows identifying which options can most realistically be realized in the years to come in relation to the different assumed cost scenarios. Optimization results related to the scenario projected to 2030 indicate the key role played by Diesel hybrid and electric systems while considering the most stringent or much more stringent scenarios for emissions in 2050 almost all vehicles energy demand and industry hydrogen demand is met by hydrogen imported as ammonia by ship.
Particle Swarm Optimisation for a Hybrid Freight Train Powered by Hydrogen or Ammonia Solid Oxide Fuel Cells
May 2024
Publication
All diesel-only trains in the UK will be phased out by 2040. Hydrogen and ammonia emerge as alternative zerocarbon fuel for greener railway. Solid Oxide Fuel Cells (SOFCs) provide an alternative prime mover option which efficiently convert zero-carbon fuels into electricity without emitting nitrogen oxides (NOx) unlike traditional engines. Superior to Proton Exchange Membrane Fuel Cells (PEMFCs) in efficiency SOFCs fulfil MW-scale power needs and can use ammonia directly. This study investigates innovative strategies for integrating SOFCs into hybrid rail powertrains using hydrogen or ammonia. Utilizing an optimization framework incorporating Particle Swarm Optimization (PSO) the study aims to minimize operational costs while considering capital and replacement expenditures powertrain performance and component sizing. The findings suggest that hybrid powertrains based on ammonia-fueled SOFCs may potentially reduce costs by 30% compared to their hydrogen counterparts albeit requiring additional space for engine compartments. Ammonia-fueled SOFCs trains also exhibit a 5% higher efficiency at End-of-Life (EoL) showing less performance degradation than those powered by hydrogen. The State of Charge (SoC) of the batteries in range of 30–70% for both cases is identified as most costeffective.
Decarbonizing Hard-to-Abate Sectors with Renewable Hydrogen: A Real Case Application to the Ceramics Industry
Jul 2024
Publication
Hydrogen produced from renewable energy sources is a valuable energy carrier for linking growing renewable electricity generation with the hard-to-abate sectors such as cement steel glass chemical and ceramics industries. In this context this paper presents a new model of hydrogen production based on solar photovoltaics and wind energy with application to a real-world ceramics factory. For this task a novel multipurpose profit-maximizing model is implemented using GAMS. The developed model explores hydrogen production with multiple value streams that enable technical and economical informed decisions under specific scenarios. Our results show that it is profitable to sell the hydrogen produced to the gas grid rather than using it for self-consumption for low-gas-price scenarios. On the other hand when the price of gas is significantly high it is more profitable to use as much hydrogen as possible for self-consumption to supply the factory and reduce the internal use of natural gas. The role of electricity self-consumption has proven to be key for the project’s profitability as without this revenue stream the project would not be profitable in any analysed scenario.
How do Variations in Ship Operation Impact the Techno-economic Feasibility and Environmental Performance of Fossil-free Fuels? A Life Cycle Study
Aug 2023
Publication
Identifying an obvious non-fossil fuel solution for all ship types for meeting the greenhouse gas reduction target in shipping is challenging. This paper evaluates the technical viability environmental impacts and economic feasibility of different energy carriers for three case vessels of different ship types: a RoPax ferry a tanker and a service vessel. The energy carriers examined include battery-electric and three electro-fuels (hydrogen methanol and ammonia) which are used in combination with engines and fuel cells. Three methods are used: preliminary ship design feasibility life cycle assessment and life cycle costing. The results showed that battery-electric and compressed hydrogen options are not viable for some ships due to insufficient available onboard space for energy storage needed for the vessel's operational range. The global warming reduction potential is shown to depend on the ship type. This reduction potential of assessed options changes also with changes in the carbon intensity of the electricity mix. Life cycle costing results shows that the use of ammonia and methanol in engines has the lowest life cycle cost for all studied case vessels. However the higher energy conversion losses of these systems make them more vulnerable to fluctuations in the price of electricity. Also these options have higher environmental impacts on categories like human toxicity resource use (minerals and metals) and water use. Fuel cells and batteries are not as cost-competitive for the case vessels because of their higher upfront costs and shorter lifetimes. However these alternatives are less expensive than alternatives with internal combustion engines in the case of higher utilization rates and fuel costs.
Competitive Analysis of Heavy Trucks with Five Types of Fuels under Different Scenarios—A Case Study of China
Aug 2024
Publication
As the country that emits the most carbon in the world China needs significant and urgent changes in carbon emission control in the transportation sector in order to achieve the goals of reaching peak carbon emissions before 2030 and achieving carbon neutrality by 2060. Therefore the promotion of new energy vehicles has become the key factor to achieve these two objectives. For the reason that the comprehensive transportation cost directly affects the end customer’s choice of heavy truck models this work compares the advantages disadvantages and economic feasibility of diesel liquefied natural gas (LNG) electric hydrogen and methanol heavy trucks from a total life cycle cost and end-user perspective under various scenarios. The study results show that when the prices of diesel LNG electricity and methanol fuels are at their highest and the price of hydrogen is 35 CNY/kg the total life cycle cost of the five types of heavy trucks from highest to lowest are hydrogen heavy trucks (HHT) methanol heavy trucks (MHT) diesel heavy trucks (DHT) electric heavy trucks (EHT) and LNG heavy trucks (LNGHT) ignoring the adverse effects of cold environments on car batteries. When the prices of diesel LNG electricity and methanol fuels are at average or lowest levels and the price of hydrogen is 30 CNY/kg or 25 CNY/kg the life cycle cost of the five heavy trucks from highest to lowest are HHT DHT MHT EHT and LNGHT. When considering the impact of cold environments even with lower electricity prices EHT struggle to be economical when LNG prices are low. If the electricity price is above 1 CNY/kWh regardless of the impact of cold environments the economic viability of EHT is lower than that of HHT with a purchase cost of 500000 CNY and a hydrogen price of 25 CNY/kg. Simultaneously an exhaustive competitiveness analysis of heavy trucks powered by diverse energy sources highlights the specific categories of heavy trucks that ought to be prioritized for development during various periods and the challenges they confront. Finally based on the analysis results and future development trends the corresponding policy recommendations are proposed to facilitate high decarbonization in the transportation sector.
The Race Between Hydrogen and Heat Pumps for Space and Water Heating: A Model-based Scenario Analysis
Nov 2023
Publication
This paper analyses different levels and means of the electrification of space and hot water heating using an explorative modelling approach. The analysis provides guidance to the ongoing discussion on favourable pathways for heating buildings and the role of secondary energy carriers such as hydrogen or synthetic fuels. In total 12 different scenarios were modelled with decarbonisation pathways until 2050 which cover all 27 member states of the European Union. Two highly detailed optimisation models were combined to cover the building stock and the upstream energy supply sector. The analysis shows that decarbonisation pathways for space and water heating based on large shares of heat pumps have at least 11% lower system costs in 2050 than pathways with large shares of hydrogen or synthetic fuels. This translates into system cost savings of around €70 bn. Heat pumps are cost-efficient in decentralised systems and in centralised district heating systems. Hence heat pumps should be the favoured option to achieve a cost-optimal solution for heating buildings. Accordingly the paper makes a novel and significant contribution to understanding suitable and cost-efficient decarbonisation pathways for space and hot water heating via electrification. The results of the paper can provide robust guidance for policymakers.
Techno-Economic Feasibility of Fuel Cell Vehicle-to-Grid Fast Frequency Control in Non-Interconnected Islands
Dec 2024
Publication
This paper presents an innovative approach to fast frequency control in electric grids by leveraging parked fuel cell electric vehicles (FCEVs) especially heavy-duty vehicles such as trucks. Equipped with hydrogen storage tanks and fuel cells these vehicles can be repurposed as dynamic grid-support assets while parked in designated areas. Using an external cable and inverter system FCEVs inject power into the grid by converting DC from fuel cells into AC to be compatible with grid requirements. This functionality addresses sudden power imbalances providing a rapid and efficient solution for frequency stabilization. The system’s external inverter serves as a central control hub monitoring real-time grid frequency and directing FCEVs to supply virtual inertia and primary reserves through droop control as required. Simulation results validate that FCEVs could effectively complement thermal generators preventing unacceptable frequency drops load shedding and network blackouts. A techno-economic analysis demonstrates the economic feasibility of the concept concluding that each FCEV consumes approximately 0.3 kg of hydrogen per day incurring a daily cost of around EUR 1.5. For an island grid with a nominal power of 100 MW maintaining frequency stability requires a fleet of 100 FCEVs resulting in a total daily cost of EUR 150. Compared to a grid-scale battery system offering equivalent frequency response services the proposed solution is up to three times more cost-effective highlighting its economic and technical potential for grid stabilization in renewable-rich non-interconnected power systems.
Implementation of a Decision-making Approach for a Hydrogen-based Multi-energy System Considering EVs and FCEVs Availability
Aug 2024
Publication
Innovative green vehicle concepts have become increasingly prevailing in consumer purchasing habits as technology evolves. The global transition towards sustainable transportation indicates an increase in new-generation vehicles including both fuel-cell electric vehicles (FCEVs) and plug-in electric vehicles (PEVs) that will take on roads in the future. This change requires new-generation stations to support electrification. This study introduced a prominent multi-energy system concept with a hydrogen refueling station. The proposed multi-energy system (MES) consists of green hydrogen production a hydrogen refueling station for FCEVs hydrogen injection into natural gas (NG) and a charging station for PEVs. An on-site renewable system projected at the station and a polymer electrolyte membrane electrolyzer (PEM) to produce hydrogen for two significant consumers support MES. In addition the MES offers the ability to conduct two-way trade with the grid if renewable energy systems are insufficient. This study develops a comprehensive multi-energy system with an economically optimized energy management model using a mixed-integer linear programming (MILP) approach. The determinative datasets of vehicles are generated in a Python environment using Gauss distribution. The fleet of FCEVs and PEVs are currently available on the market. The study includes fleets of the most common models from well-known brands. The results indicate that profits increase when the storage capacity of the hydrogen tank is higher and natural gas injections are limitless. Optimization results for all cases tend to choose higher-priced natural gas injections over hydrogen refueling because of the difference in costs of refueling and injection expenses. The analyses reveal the highest hydrogen sales to the natural gas (NG) grid by consuming 2214.31 kg generating a revenue of $6966 and in contrast the lowest hydrogen sales to the natural gas grid at 1045.38 kg resulting in a revenue of $3286. Regarding electricity the highest sales represent revenue of $7701 and $2375 for distribution system consumption and electric vehicles (EV) respectively. Conversely Cases 1 and 2 have achieved sales to EV of $2286 and $2349 respectively but do not have any sales to distribution system consumption regarding the constraints. Overall the optimization results show that the solution is optimal for a multi-energy system operator to achieve higher profits and that all end-user parties are satisfied.
Techno-economic Analysis of Wind-powered Green Hydrogen Production to Facilitate the Decarbonization of Hard-to-abate Sectors: A Case Study on Steelmaking
Apr 2023
Publication
Green hydrogen is among the most promising energy vectors that may enable the decarbonization of our society. The present study addresses the decarbonization of hard-to-abate sectors via the deployment of sustainable alternatives to current technologies and processes where the complete replacement of fossil fuels is deemed not nearly immediate. In particular the investigated case study tackles the emission reduction potential of steelmaking in the Italian industrial framework via the implementation of dedicated green hydrogen production systems to feed Hydrogen Direct Reduction process the main alternative to the traditional polluting routes towards emissions abatement. Green hydrogen is produced via the coupling of an onshore wind farm with lithium-ion batteries alkaline type electrolyzers and the interaction with the electricity grid. Building on a power generation dataset from a real utility-scale wind farm techno-economic analyses are carried out for a large number of system configurations varying components size and layout to assess its performance on the basis of two main key parameters the levelized cost of hydrogen (LCOH) and the Green Index (GI) the latter presented for the first time in this study. The optimal system design and operation logics are investigated accounting for the necessity of providing a constant mass flow rate of H2 and thus considering the interaction with the electricity network instead of relying solely on RES surplus. In-house-developed models that account for performances degradation over time of different technologies are adapted and used for the case study. The effect of different storage technologies is evaluated via a sensitivity analysis on different components and electricity pricing strategy to understand how to favour green hydrogen penetration in the heavy industry. Furthermore for a better comprehension and contextualization of the proposed solutions their emission-reduction potential is quantified and presented in comparison with the current scenario of EU-27 countries. In the optimal case the emission intensity related to the steel making process can be lowered to 235 kg of CO2 per ton of output steel 88 % less than the traditional route. A higher cost of the process must be accounted resulting in an LCOH of such solutions around 6.5 €/kg.
Hydrogen Refueling Stations: A Review of the Technology Involved from Key Energy Consumption Processes to Related Energy Management Strategies
Sep 2024
Publication
Over the last few years hydrogen has emerged as a promising solution for problems related to energy sources and pollution concerns. The integration of hydrogen in the transport sector is one of the possible various applications and involves the implementation of hydrogen refueling stations (HRSs). A key obstacle for HRS deployment in addition to the need for well-developed technologies is the economic factor since these infrastructures require high capital investments costs and are largely dependent on annual operating costs. In this study we review hydrogen’s application as a fuel summarizing the principal systems involved in HRS from production to the final refueling stage. In addition we also analyze the main equipment involved in the production compression and storage processes of hydrogen. The current work also highlights the main refueling processes that impact energy consumption and the methodologies presented in the literature for energy management strategies in HRSs. With the aim of reducing energy costs due to processes that require high energy consumption most energy management strategies are based on the use of renewable energy sources in addition to the use of the power grid.
Hierarchical Model Predictive Control for Islanded and Grid-connected Microgrids with Wind Generation and Hydrogen Energy Storage Systems
Aug 2023
Publication
This paper presents a novel energy management strategy (EMS) to control a wind-hydrogen microgrid which includes a wind turbine paired with a hydrogen-based energy storage system (HESS) i.e. hydrogen production storage and re-electrification facilities and a local load. This complies with the mini-grid use case as per the IEA-HIA Task 24 Final Report where three different use cases and configurations of wind farms paired with HESS are proposed in order to promote the integration of wind energy into the grid. Hydrogen production surpluses by wind generation are stored and used to provide a demand-side management solution for energy supply to the local and contractual loads both in the grid-islanded and connected modes with corresponding different control objectives. The EMS is based on a hierarchical model predictive control (MPC) in which long-term and short-term operations are addressed. The long-term operations are managed by a high-level MPC in which power production by wind generation and load demand forecasts are considered in combination with day-ahead market participation. Accordingly the hydrogen production and re-electrification are scheduled so as to jointly track the load demand maximize the revenue through electricity market participation and minimize the HESS operating costs. Instead the management of the short-term operations is entrusted to a low-level MPC which compensates for any deviations of the actual conditions from the forecasts and refines the power production so as to address the real-time market participation and the short time-scale equipment dynamics and constraints. Both levels also take into account operation requirements and devices’ operating ranges through appropriate constraints. The mathematical modeling relies on the mixed-logic dynamic (MLD) framework so that the various logic states and corresponding continuous dynamics of the HESS are considered. This results in a mixed-integer linear program which is solved numerically. The effectiveness of the controller is analyzed by simulations which are carried out using wind forecasts and spot prices of a wind farm in center-south of Italy.
The Environmental Impacts of Future Global Sales of Hydrogen Fuel Cell Vehicles
Oct 2024
Publication
During the last decade developing more sustainable transportation modes has become a primary objective for car manufacturers and governments around the world to mitigate environmental issues such as climate change the continuous increase in greenhouse gas (GHG) emissions and energy depletion. The use of hydrogen fuel cell technology as a source of energy in electric vehicles is considered an emerging and promising technology that could contribute significantly to addressing these environmental issues. In this study the effects of Hydrogen Fuel Cell Battery Electric Vehicles (HFCBEVs) on global GHG emissions compared to other technologies such as BEVs were determined based on different relevant factors such as predicted sales for 2050 (the result of the developed prediction model) estimated daily traveling distance estimated future average global electricity emission factors future average Battery Electric Vehicle (BEV) emission factors future global hydrogen production emission factors and future average HFCBEV emission factors. As a result the annual GHG emissions produced by passenger cars that are expected to be sold in 2050 were determined by considering BEV sales in the first scenario and HFCBEV replacement in the second scenario. The results indicate that the environmental benefits of HFCBEVs are expected to increase over time compared to those of BEVs due to the eco-friendly methods that are expected to be used in hydrogen production in the future. For instance in 2021 HFCBEVs could produce more GHG emissions than BEVs by 54.9% per km of travel whereas in 2050 BEVs could produce more GHG emissions than HFCBEVs by 225% per km of travel.
Potentials of Green Hydrogen Production in P2G Systems Based on FPV Installations Deployed on Pit Lakes in Former Mining Sites by 2050 in Poland
Sep 2024
Publication
Green hydrogen production is expected to play a major role in the context of the shift towards sustainable energy stipulated in the Fit for 55 package. Green hydrogen and its derivatives have the capacity to act as effective energy storage vectors while fuel cell-powered vehicles will foster net-zero emission mobility. This study evaluates the potential of green hydrogen production in Power-to-Gas (P2G) systems operated in former mining sites where sand and gravel aggregate has been extracted from lakes and rivers under wet conditions (below the water table). The potential of hydrogen production was assessed for the selected administrative unit in Poland the West Pomerania province. Attention is given to the legal and organisational aspects of operating mining companies to identify the sites suitable for the installation of floating photovoltaic facilities by 2050. The method relies on the use of GIS tools which utilise geospatial data to identify potential sites for investments. Basing on the geospatial model and considering technical and organisational constraints the schedule was developed showing the potential availability of the site over time. Knowing the surface area of the water reservoir the installed power of the floating photovoltaic plant and the production capacity of the power generation facility and electrolysers the capacity of hydrogen production in the P2G system can be evaluated. It appears that by 2050 it should be feasible to produce green fuel in the P2G system to support a fleet of city buses for two of the largest urban agglomerations in the West Pomerania province. Simulations revealed that with a water coverage ratio increase and the planned growth of green hydrogen generation it should be feasible to produce fuel for net-zero emission urban mobility systems to power 200 buses by 2030 550 buses by 2040 and 900 buses by 2050 (for the bus models Maxi (40 seats) and Mega (60 seats)). The results of the research can significantly contribute to the development of projects focused on the production of green hydrogen in a decentralised system. The disclosure of potential and available locations over time can be compared with competitive solutions in terms of spatial planning environmental and societal impact and the economics of the undertaking.
Comparison of Battery Electric Vehicles and Fuel Cell Vehicles
Sep 2023
Publication
In the current context of the ban on fossil fuel vehicles (diesel and petrol) adopted by several European cities the question arises of the development of the infrastructure for the distribution of alternative energies namely hydrogen (for fuel cell electric vehicles) and electricity (for battery electric vehicles). First we compare the main advantages/constraints of the two alternative propulsion modes for the user. The main advantages of hydrogen vehicles are autonomy and fast recharging. The main advantages of battery-powered vehicles are the lower price and the wide availability of the electricity grid. We then review the existing studies on the deployment of new hydrogen distribution networks and compare the deployment costs of hydrogen and electricity distribution networks. Finally we conclude with some personal conclusions on the benefits of developing both modes and ideas for future studies on the subject.
Review of Hydrogen-Driven Power-to-X Technology and Application Status in China
Jul 2024
Publication
Given China’s ambition to realize carbon peak by 2030 and carbon neutralization by 2060 hydrogen is gradually becoming the pivotal energy source for the needs of energy structure optimization and energy system transformation. Thus hydrogen combined with renewable energy has received more and more attention. Nowadays power-to-hydrogen power-to-methanol and power-to-ammonia are regarded as the most promising three hydrogen-driven power-to-X technologies due to the many commercial or demonstration projects in China. In this paper these three hydrogen-driven power-to-X technologies and their application status in China are introduced and discussed. First a general introduction of hydrogen energy policies in China is summarized and then the basic principles technical characteristics trends and challenges of the three hydrogen-driven power-to-X technologies are reviewed. Finally several typical commercial or demonstration projects are selected and discussed in detail to illustrate the development of the power-to-X technologies in China.
Alternative Fuels in Sustainable Logistics—Applications, Challenges, and Solutions
Sep 2024
Publication
Logistics is becoming more cost competitive while customers and regulatory bodies pressure businesses to disclose their carbon footprints creating interest in alternative fuels as a decarbonization strategy. This paper provides a thematic review of the role of alternative fuels in sustainable air land and sea logistics their challenges and potential mitigations. Through an extensive literature survey we determined that biofuels synthetic kerosene natural gas ammonia alcohols hydrogen and electricity are the primary alternative fuels of interest in terms of environmental sustainability and techno-economic feasibility. In air logistics synthetic kerosene from hydrogenated esters and fatty acids is the most promising route due to its high technical maturity although it is limited by biomass sourcing. Electrical vehicles are favorable in road logistics due to cheaper green power and efficient vehicle designs although they are constrained by recharging infrastructure deployment. In sea logistics liquified natural gas is advantageous owing to its supply chain maturity but it is limited by methane slip control and storage requirements. Overall our examination indicates that alternative fuels will play a pivotal role in the logistics networks of the future.
Analysis of a Distributed Green Hydrogen Infrastructure Designed to Support the Sustainable Mobility of a Heavy-duty Fleet
Aug 2023
Publication
Clean hydrogen is a key pillar for the net zero economy which can be deployed by consistent utilization on heavy-duty transport. This study investigates a distributed green hydrogen infrastructure (DHI) for heavy-duty transportation consisting of on-site hydrogen production storage compression and refueling systems in Italy. Two options for energy supply are analyzed: grid connection using green energy via Power Purchasing Agreements (PPAs) and direct connection to the photovoltaic field respectively. Radiation data are representative of the three main Italian areas namely South (Catania) Center (Roma) and North (Milano). The sensitivity analysis varies the PPA value between 50 V/MWh and 200 V/MWh and the water electrolysis capacity factor between 20% and 100%. The study finds that the LCOH ranges from 7.4 V/kgH2 to 67.8 V/kgH2 for the first option and 5.5 V/kgH2 to 27.5 V/kgH2 for the second option with Southern Italy having the lowest LCOH due to higher solar irradiation. The research shows that a DHI can offer economic and technical benefits for heavy-duty mobility. However the performance is highly influenced by external conditions such as hydrogen demand and electricity prices. This study provides valuable insights into designing and operating a DHI for heavy-duty mobility promoting a carbon-free society.
Multiphysics Performance Assessment of Hydrogen Fuelled Engines
Sep 2023
Publication
In the quest for decarbonisation alternative clean fuels for propulsion systems are sought. There is definite advantage in retaining the well-established principles of operation of combustion engines at the core of future developments with hydrogen as a fuel. Hydrogen is envisaged as a clean source of energy for propulsion of heavy and off-road vehicles as well as in marine and construction sectors. A source of concern is the unexplored effect of hydrogen combustion on dilution and degradation of engine lubricants and their additives and consequently upon tribology of engine contact conjunctions. These potential problems can adversely affect engine efficiency durability and operational integrity. Use of different fuels and their method of delivery produces distinctive combustion characteristics that can affect the energy losses associated with in-cylinder components and their durability. Therefore detailed predictive analysis should support the developments of such new generation of eco-friendly engines. Different fundamental physics underpin the various aspects of a pertinent detailed analysis. These include thermodynamics of combustion in-cylinder tribological interactions of contacting surfaces and blowby of generated gasses. This paper presents such an integrated multi-physics analysis of internal combustion engines with focus on hydrogen as the fuel. Such an in-depth and computationally efficient analysis has not hitherto been reported in the literature. The results show implications for lubricant degradation due to the use of hydrogen in the performance of in-cylinder components and the underlying physical principles.
Heat Integration of Liquid Hydrogen-Fueled Hybrid Electric Ship Propulsion System
Nov 2023
Publication
This study introduced the methodology for integrating ethylene glycol/water mixture (GW) systems which supply heat energy to the liquid hydrogen (LH2 ) fuel gas supply system (FGSS) and manage the temperature conditions of the battery system. All systems were designed and simulated based on the power demand of a 2 MW class platform supply vessel assumed as the target ship. The LH2 FGSS model is based on Aspen HYSYS V14 and the cell model that makes up the battery system is implemented based on a Thevenin model with four parameters. Through three different simulation cases the integrated GW system significantly reduced electric power consumption for the GW heater during ship operations achieving reductions of 1.38% (Case 1) 16.29% (Case 2) and 27.52% (Case 3). The energy-saving ratio showed decreases of 1.86% (Case 1) 21.01% (Case 2) and 33.80% (Case 3) in overall energy usage within the GW system. Furthermore an examination of the battery system’s thermal management in the integrated GW system demonstrated stable cell temperature control within ±3 K of the target temperature making this integration a viable solution for maintaining normal operating temperatures despite relatively higher fluctuations compared to an independent GW system.
Emission Reduction and Cost-benefit Analysis of the Use of Ammonia and Green Hydrogen as Fuel for Marine Applications
Dec 2023
Publication
Increasingly stringent emission standards have led shippers and port operators to consider alternative energy sources which can reduce emissions while minimizing capital investment. It is essential to understand whether there is a certain economic investment gap for alternative energy. The present work mainly focuses on the simulation study of ships using ammonia and hydrogen fuels arriving at Guangzhou Port to investigate the emission advantages and cost-benefit analysis of ammonia and hydrogen as alternative fuels. By collecting actual data and fuel consumption emissions of ships arriving at Guangzhou Port the present study calculated the pollutant emissions and cost of ammonia and hydrogen fuels substitution. As expected it is shown that with the increase of NH3 in fuel mixed fuels will effectively reduce CO and CO2 emissions. Compared to conventional fuel the injection of NH3 increases the NOx emission. However the cost savings of ammonia fuel for CO2 SOx and PM10 reduction are higher than that for NOx. In terms of pollutants ammonia is less expensive than conventional fuels when applied to the Guangzhou Port. However the cost of fuel supply is still higher than conventional energy as ammonia has not yet formed a complete fuel supply and storage system for ships. On the other hand hydrogen is quite expensive to store and transport resulting in higher overall costs than ammonia and conventional fuels even if no pollutants are produced. At present conventional fuels still have advantage in terms of cost. With the promotion of ammonia fuel technology and application the cost of supply will be reduced. It is predicted that by 2035 ammonia will not only have emission reduction benefits but also will have a lower overall economic cost than conventional fuels. Hydrogen energy will need longer development and technological breakthroughs due to the limitation of storage conditions.
Greenhouse Gas Emissions Performance of Electric, Hydrogen and Fossil-Fuelled Freight Trucks with Uncertainty Estimates Using a Probabilistic Life-Cycle Assessment (pLCA)
Jan 2024
Publication
This research conducted a probabilistic life-cycle assessment (pLCA) into the greenhouse gas (GHG) emissions performance of nine combinations of truck size and powertrain technology for a recent past and a future (largely decarbonised) situation in Australia. This study finds that the relative and absolute life-cycle GHG emissions performance strongly depends on the vehicle class powertrain and year of assessment. Life-cycle emission factor distributions vary substantially in their magnitude range and shape. Diesel trucks had lower life-cycle GHG emissions in 2019 than electric trucks (battery hydrogen fuel cell) mainly due to the high carbon-emission intensity of the Australian electricity grid (mainly coal) and hydrogen production (mainly through steam–methane reforming). The picture is however very different for a more decarbonised situation where battery electric trucks in particular provide deep reductions (about 75–85%) in life-cycle GHG emissions. Fuel-cell electric (hydrogen) trucks also provide substantial reductions (about 50–70%) but not as deep as those for battery electric trucks. Moreover hydrogen trucks exhibit the largest uncertainty in emissions performance which reflects the uncertainty and general lack of information for this technology. They therefore carry an elevated risk of not achieving the expected emission reductions. Battery electric trucks show the smallest (absolute) uncertainty which suggests that these trucks are expected to deliver the deepest and most robust emission reductions. Operational emissions (on-road driving and vehicle maintenance combined) dominate life-cycle emissions for all vehicle classes. Vehicle manufacturing and upstream emissions make a relatively small contribution to life-cycle emissions from diesel trucks (
Comparative Analysis of Marine Alternative Fuels for Offshore Supply Vessels
Nov 2024
Publication
This paper provides an in-depth analysis of alternative fuels including liquefied natural gas (LNG) hydrogen ammonia and biofuels assessing their feasibility based on operational requirements availability safety concerns and the infrastructure needed for large-scale adoption. Moreover it examines hybrid and fully electric propulsion systems considering advancements in battery technology and the integration of renewable energy sources such as wind and solar power to further reduce SOV emissions. Key findings from this research indicate that LNG serves as a viable short- to medium-term solution for reducing GHG emissions in the SOV sector due to its relatively lower carbon content compared to MDO and HFO. This paper finally insists that while LNG presents an immediate opportunity for emission reduction in the SOV sector a combination of hydrogen ammonia and hybrid propulsion systems will be necessary to meet long-term decarbonisation goals. The findings underscore the importance of coordinated industry efforts technological innovation and supportive regulatory frameworks to overcome the technical economic and infrastructural challenges associated with decarbonising the maritime industry.
Batteries or Hydrogen or Both for Grid Electricity Storage Upon Full Electrification of 145 Countries with Wind-Water-Solar?
Jan 2024
Publication
Grids require electricity storage. Two emerging storage technologies are battery storage (BS) and green hydrogen storage (GHS) (hydrogen produced and compressed with clean-renewable electricity stored then returned to electricity with a fuel cell). An important question is whether GHS alone decreases system cost versus BS alone or BS+GHS. Here energy costs are modeled in 145 countries grouped into 24 regions. Existing conventional hydropower (CH) storage is used along with new BS and/or GHS. A method is developed to treat CH for both baseload and peaking power. In four regions only CH is needed. In five CH+BS is lowest cost. Otherwise CH+BS+GHS is lowest cost. CH+GHS is never lowest cost. A metric helps estimate whether combining GHS with BS reduces cost. In most regions merging (versus separating) grid and non-grid hydrogen infrastructure reduces cost. In sum worldwide grid stability may be possible with CH+BS or CH+BS+GHS. Results are subject to uncertainties.
Literature Review on Life Cycle Assessment of Transportation Alternative Fuels
Aug 2023
Publication
Environmental concerns such as global warming and human health damage are intensifying and the transportation sector significantly contributes to carbon and harmful emissions. This review examines the life cycle assessment (LCA) of alternative fuels (AF) evaluating current research on fuel types LCA framework development life cycle inventory (LCI) and impact selection. The objectives of this paper are: (1) to compare various AF LCA frameworks and develop a comprehensive framework for the transportation sector; (2) to identify emission hotspots of different AFs through simulations and real-world cases; (3) to review AF LCA research; (4) to extract valuable information for potential future research directions. The analysis reveals that all stages except for hydrogen use have an environmental impact. LCA boundaries and LCIs vary considerably depending on the raw materials production processes and products involved leading to different emission hotspots. Due to knowledge or data limitations some stages remain uncalculated in the current study emphasizing the need for further refinement of the AF LCI. Future research should also explore the various impacts of widespread adoption of alternative fuels in transportation encompassing social economic and environmental aspects. Lastly the review provides structured recommendations for future research directions.
Comparative Study of Electric and Hydrogen Mobility Infrastructures for Sustainable Public Transport: A PyPSA Optimization for a Remote Island Context
Jul 2024
Publication
Decarbonizing road transportation is vital for addressing climate change given that the sector currently contributes to 16% of global GHG emissions. This paper presents a comparative analysis of electric and hydrogen mobility infrastructures in a remote context i.e. an off-grid island. The assessment includes resource assessment and sizing of renewable energy power plants to facilitate on-site self-production. We introduce a comprehensive methodology for sizing the overall infrastructure and carry out a set of techno-economic simulations to optimize both energy performance and cost-effectiveness. The levelized cost of driving at the hydrogen refueling station is 0.40 e/km i.e. 20% lower than the electric charging station. However when considering the total annualized cost the battery-electric scenario (110 ke/year) is more favorable compared to the hydrogen scenario (170 ke/year). To facilitate informed decision-making we employ a multi-criteria decision-making analysis to navigate through the techno-economic findings. When considering a combination of economic and environmental criteria the hydrogen mobility infrastructure emerges as the preferred solution. However when energy efficiency is taken into account electric mobility proves to be more advantageous.
Toward Green Steel: Modelling and Environmental Economic Analysis of Iron Direct Reduction with Different Reducing Gases
Sep 2023
Publication
The objective of the paper is to simulate the whole steelmaking process cycle based on Direct Reduced Iron and Electric Arc Furnace technologies by modeling for the first time the reduction furnace based on kinetic approach to be used as a basis for the environmental and techno-economic plant analysis by adopting different reducing gases. In addition the impact of carbon capture section is discussed. A complete profitability analysis has been conducted for the first time adopting a Monte Carlo simulation approach.<br/>In detail the use of syngas from methane reforming syngas and hydrogen from gasification of municipal solid waste and green hydrogen from water electrolysis are analyzed. The results show that the Direct Reduced Iron process with methane can reduce CO2 emissions by more than half compared to the blast furnace based-cycle and with the adoption of carbon capture greenhouse gas emissions can be reduced by an additional 40%. The use of carbon capture by amine scrubbing has a limited economic disadvantage compared to the scenario without it becoming profitable once carbon tax is included in the analysis. However it is with the use of green hydrogen from electrolyzer that greenhouse gas emissions can be cut down almost completely. To have an environmental benefit compared with the methane-based Direct Reduced Iron process the green hydrogen plant must operate for at least 5136 h per year (64.2% of the plant's annual operating hours) on renewable energy.<br/>In addition the use of syngas and separated hydrogen from municipal solid waste gasification is evaluated demonstrating its possible use with no negative effects on the quality of produced steel. The results show that hydrogen use from waste gasification is more economic with respect to green hydrogen from electrolysis but from the environmental viewpoint the latter results the best alternative. Comparing the use of hydrogen and syngas from waste gasification it can be stated that the use of the former reducing gas results preferable from both the economic and environmental viewpoint.
Opportunities and Challenges of Hydrogen Ports: An Empirical Study in Australia and Japan
Jul 2024
Publication
This paper investigated the opportunities and challenges of integrating ports into hydrogen (H2 ) supply chains in the context of Australia and Japan because they are leading countries in the field and are potential leaders in the upcoming large-scale H2 trade. Qualitative interviews were conducted in the two countries to identify opportunities for H2 ports necessary infrastructure and facilities key factors for operations and challenges associated with the ports’ development followed by an online survey investigating the readiness levels of H2 export and import ports. The findings reveal that there are significant opportunities for both countries’ H2 ports and their respective regions which encompass business transition processes and decarbonisation. However the ports face challenges in areas including infrastructure training standards and social licence and the sufficiency and readiness levels of port infrastructure and other critical factors are low. Recommendations were proposed to address the challenges and barriers encountered by H2 ports. To optimise logistics operations within H2 ports and facilitate effective integration of H2 applications this paper developed a user-oriented working process framework to provide guidance to ports seeking to engage in the H2 economy. Its findings and recommendations contribute to filling the existing knowledge gap pertaining to H2 ports.
Explainable Prognostics-optimization of Hydrogen Carrier Biogas Engines in an Integrated Energy System using a Hybrid Game-theoretic Approach with XGBoost and Statistical Methods
Jul 2025
Publication
Biogas is a renewable fuel source that helps the circular economy by turning organic waste into energy. This study tackles existing research gaps by exploring the use of biogas as a hydrogen carrier in dual-fuel engine systems. It additionally employs explainable machine learning techniques for predictive modelling and interpretive analysis. The dual-fuel engine was powered with biogas as main fuel while biodiesel-diesel blend was used as pilot fuel. The engine was tested at different Compression Ratios (CR) and Brake Powers (BP). The generated data from testing was used to develop the mathematical models and parametric optimization of engine performance and emissions using Response Surface Methodology (RSM). Desirability-based optimization identified optimal results: a Peak Cylinder Pressure (Pmax) of 54.97 bar and a brake thermal efficiency (BTE) of 24.35 % achieved at a CR of 18.3 and a BP of 3.3 kW. The predictive machine learning approach Extreme Gradient Boosting (XGBoost) was employed to develop predictive models. XGBoost precisely forecasted engine performance and emissions with Coefficient of Determination (R2 ) values (up to 0.9960) and minimal Mean Absolute Percentage Error (MAPE) values (1.47–4.89 %) for all parameters. SHapley Additive exPlanations (SHAP) based analysis identified BP as the predominant feature with a normalized importance score reaching up to 0.9 surpassing that of CR. These findings underscore the potential of biogas as a viable sustainable fuel and highlight the role of explainable prediction–optimization frameworks can play in achieving optimal engine performance and emission control.
Thermal Design of a System for Mobile Powersupply
Sep 2023
Publication
Ever more stringent emission regulations for vehicles encourage increasing numbers of battery electric vehicles on the roads. A drawback of storing electric energy in a battery is the comparable low energy density low driving range and the higher propensity to deplete the energy storage before reaching the destination especially at low ambient temperatures. When the battery is depleted stranded vehicles can either be towed or recharged with a mobile recharging station. Several technologies of mobile recharging stations already exist however most of them use fossil fuels to recharge battery electric vehicles. The proposed novel zero emission solution for mobile charging is a combined high voltage battery and hydrogen fuel cell charging station. Due to the thermal characteristics of the fuel cell and high voltage battery (which allow only comparable low coolant temperatures) the thermal design for this specific application (available heat exchanger area zero vehicle speed air flow direction) becomes challenging and is addressed in this work. Experimental methods were used to obtain reliable thermal and electric power measurement data of a 30 kW fuel cell system which is used in the Mobile Hydrogen Powersupply. Subsequently simulation methods were applied for the thermal design and optimisation of the coolant circuits and heat exchangers. It is shown that an battery electric vehicle charging power of 22 kW requires a heat exchanger area of 1 m2 of which 60 % is used by the fuel cell heat exchanger and the remainder by the battery heat exchanger to achieve steady state operation at the highest possible ambient temperature of 436 °C. Furthermore the simulation showed that when the charging power of 22 kW is solely provided by the high voltage battery the highest possible ambient temperature is 42 °C. When the charging power is decreased operation up to the maximum ambient temperatures of 45 °C can be achieved. The results of maximum charging power and limiting ambient temperature give insights for further system improvements which are: sizing of fuel cell or battery trailer design and heat exchanger area operation strategy of the system (power split between high voltage battery and fuel cell) as well as possible dynamic operation scenarios.
Internal Combustion Engines and Carbon-Neutral Fuels: A Perspective on Emission Neutrality in the European Union
Mar 2024
Publication
Nowadays there is an intense debate in the European Union (EU) regarding the limits to achieve the European Green Deal to make Europe the first climate-neutral continent in the world. In this context there are also different opinions about the role that thermal engines should play. Furhermore there is no clear proposal regarding the possibilities of the use of green hydrogen in the transport decarbonization process even though it should be a key element. Thus there are still no precise guidelines regarding the role of green hydrogen with it being exclusively used as a raw material to produce E-fuels. This review aims to evaluate the possibilities of applying the different alternative technologies available to successfully complete the process already underway to achieve Climate Neutrality by about 2050 depending on the maturity of the technologies currently available and those anticipated to be available in the coming decades.
Energy Management Strategy Based on Reinforcement Learning and Frequency Decoupling for Fuel Cell Hybrid Powertrain
Apr 2024
Publication
This study presents a Two-Layer Deep Deterministic Policy Gradient (TL-DDPG) energy management strategy for Hydrogen fuel cell hybrid train that aims to solve the problem that traditional reinforcement learning strategies require high initial values and are difficult to optimize global variables. Augmenting the optimization capabilities of the inner layer a frequency decoupling algorithm integrates into the outer layer furnishing a fitting initial value for strategy optimization. This addition aims to bolster the stability of fuel cell output thereby enhancing the overall efficiency of the hybrid power system. In comparison with the traditional reinforcement learning algorithm the proposed approach demonstrates notable improvements: a reduction in hydrogen consumption per 100 km by 16.3 kg a 9.7% increase in the output power stability of the fuel cell and a 1.8% enhancement in its efficiency.
Numerical Study on the Use of Ammonia/Hydrogen Fuel Blends for Automotive Sparking-ignition Engines
Jun 2023
Publication
The importance of new alternative fuels has assumed great relevance in the last decades to face the issues of global warming and pollutant emissions from energy production. The scientific community is responsible for developing solutions to achieve the necessary environmental restriction policies. In this context ammonia appears as a potential fuel candidate and energy vector that may solve the technological difficulties of using hydrogen (H2 ) directly in internal combustion engines. Its high hydrogen content per unit mass higher energy density than liquid hydrogen well-developed infrastructure and experience in handling and storage make it suitable to be implemented as a long-term solution. In this work a virtual engine model was developed to perform prospective simulations of different operating conditions using ammonia and H2 -enriched ammonia as fuel in a spark-ignition (SI) engine integrating a chemical kinetics model and empirical correlations for combustion prediction. In addition specific conditions were evaluated to consider and to understand the governing parameters of ammonia combustion using computational fluid dynamics (CFD) simulations. Results revealed similar thermal efficiency than methane fuel with considerable improvements after appropriate H2 - enrichment. Moreover increasing the intake temperature and the turbulence intensity inside the cylinder evinced significant reductions in combustion duration. Finally higher compression ratios ensure efficiency gains with no evidence of abnormal combustion (knocking) even at high compression ratios (above 16:1) and low engine speeds (800 rpm). Numerical simulations showed the direct influence of the flame front surface area and the turbulent combustion velocity on efficiency reflecting the need for optimizing the SI engines design paradigm for ammonia applications.
Environmental-economic Sustainability of Hydrogen and Ammonia Fuels for Short Sea Shipping Operations
Jan 2024
Publication
Alternative fuels of low or zero carbon content can decarbonise the shipping operations. This study aims at assessing the lifetime environmental-economic sustainability of ammonia and hydrogen as alternatives to diesel fuel for short sea shipping cargo vessels. A model is employed to calculate key performance indicators representing the lifetime financial sustainability and environmental footprint of the case ship using a realistic operating profile and considering several scenarios with different diesel substitution rates. Scenarios meeting the carbon emissions reduction targets set by the International Maritime Organisation (IMO) for 2030 are identified whereas policy measures for their implementation including the emissions taxation are discussed. The derived results demonstrate that the future implementation of carbon emissions taxation in the ranges of 136–965 €/t for hydrogen and 356–2647 €/t for ammonia can support these fuels financial sustainability in shipping. This study provides insights for adopting zero-carbon fuels and as such impacts the de-risking of shipping decarbonisation.
Multi-Objective Robust Optimization of Integrated Energy System with Hydrogen Energy Storage
Feb 2024
Publication
A novel multi-objective robust optimization model of an integrated energy system with hydrogen storage (HIES) considering source–load uncertainty is proposed to promote the low-carbon economy operation of the integrated energy system of a park. Firstly the lowest total system cost and carbon emissions are selected as the multi-objective optimization functions. The Pareto front solution set of the objective function is applied by compromise planning and the optimal solution among them is obtained by the maximum–minimum fuzzy method. Furthermore the robust optimization (RO) approach is introduced to cope with the source–load uncertainty effectively. Finally it is demonstrated that the illustrated HIES can significantly reduce the total system cost carbon emissions and abandoned wind and solar power. Meanwhile the effectiveness of the proposed model and solution method is verified by analyzing the influence of multi-objective solutions and a robust coefficient on the Chongli Demonstration Project in Hebei Province.
A Review of the Research Progress and Application of Key Components in the Hydrogen Fuel Cell System
Jan 2024
Publication
The hydrogen cycle system one of the main systems used for hydrogen fuel cells has many advantages. It can improve the efficiency the water capacity and the management of thermal fuel cells. It can also enhance the safety of the system. Therefore it is widely used in hydrogen fuel cell vehicles. We introduce the structure and principles of hydrogen cycle pumps ejectors and steam separators and analyze and summarize the advantages of the components as well as reviewing the latest research progress and industrialization status of hydrogen cycle pumps and ejectors. The technical challenges in hydrogen circulation systems and the development direction of key technologies in the future are discussed. This paper aims to provide a reference for research concerning hydrogen energy storage application technology in hydrogen fuel cell systems.
The Possibility of Using Hydrogen as a Green Alternative to Traditional Marine Fuels on an Offshore Vessel Serving Wind Farms
Nov 2024
Publication
Achieving the required decarbonisation targets by the shipping industry requires a transition to technologies with zero or near-zero greenhouse gas (GHG) emissions. One promising shipping fuel with zero emission of exhaust gases (including CO2) is green hydrogen. This type of fuel recognised as a 100% clean solution is being investigated for feasible use on a service offshore vessel (SOV) working for offshore wind farms. This study aims to examine whether hydrogen may be used on an SOV in terms of the technical and economic challenges associated with the design process and other factors. In the analyses a reference has been made to the current International Maritime Organization (IMO) guidelines and regulations. In this study it was assumed that hydrogen would be directly combusted in a reciprocating internal combustion engine. This engine type was reviewed. In further research hydrogen fuel cell propulsion systems will also be considered. The hydrogen demand was calculated for the assumed data of the SOV and then the volume and number of highpressure tanks were estimated. The analyses revealed that the SOV cannot undertake 14-day missions using hydrogen fuel stored in cylinders on board. These cylinders occupy 66% of the ship’s current volume and their weight including the modular system accounts for 62% of its deadweight. The costs are over 100% higher compared to MDO and LNG fuels and 30% higher than methanol. The actual autonomy of the SOV with hydrogen fuel is 3 days.
Experimental Investigations of the Hydrogen Injectors on the Combustion Characteristics and Performance of a Hydrogen Internal Combustion Engine
Feb 2024
Publication
Hydrogen is regarded as an ideal zero-carbon fuel for an internal combustion engine. However the low mass flow rate of the hydrogen injector and the low volume heat value of the hydrogen strongly restrict the enhancement of the hydrogen engine performance. This experimental study compared the effects of single-injectors and double-injectors on the engine performance combustion pressure heat release rate and the coefficient of variation (CoVIMEP) based on a singlecylinder 0.5 L port fuel injection hydrogen engine. The results indicated that the number of hydrogen injectors significantly influences the engine performance. The maximum brake power is improved from 4.3 kW to 6.12 kW when adding the injector. The test demonstrates that the utilization of the double-injector leads to a reduction in hydrogen obstruction in the intake manifold consequently minimizing the pumping losses. The pump mean effective pressure decreased from −0.049 MPa in the single-injector condition to −0.029 MPa in the double-injector condition with the medium loads. Furthermore the double-injector exhibits excellent performance in reducing the coefficient of variation. The maximum CoVIMEP decreased from 2.18% in the single-injector configuration to 1.92% in the double-injector configuration. This result provides new insights for optimizing hydrogen engine injector design and optimizing the combustion process.
Energy Efficiency Analysis of a Fuel Cell Bus Model Using Real Scenarios Generated by Data Collection
Feb 2024
Publication
Modernizing public transportation is crucial given the ongoing call for sustainable mobility. Growing concerns about climate change and the increasingly stringent emissions standards have compelled public transport operators to embrace alternative propulsion vehicles on a broader scale. For the past years the Battery Electric Buses (BEBs) have been the vehicle of choice for public transportation. However an emerging contender in this sector is the Fuel Cell Electric Bus (FCEB). This paper aims to evaluate the way one such vehicle would perform in terms of energy efficiency while being exploited in an urban scenario generated from collected data.
Comparative Analysis of Solar Cells and Hydrogen Fuels: A Mini Review
Jul 2024
Publication
The aim of this mini-review is to compare the effectiveness and potential of solar cells and hydrogen fuel technologies in clean energy generation. Key aspects such as efficiency scalability environmental footprint and technological maturity are examined. Solar cells are analyzed for their ability to convert sunlight into electricity efficiently and their potential for widespread deployment with minimal environmental impact. Hydrogen fuel technologies are assessed based on their efficiency in hydrogen production scalability and overall environmental footprint from production to end use. The review identifies significant challenges including high costs infrastructure needs and policy requirements as well as opportunities for innovation and market growth. The findings provide insights to guide decision-making towards a sustainable energy future.
Comprehensive Techno-economic Assessment of Power Technologies and Synthetic Fuels under Discussion for Ship Applications
Jun 2023
Publication
The decarbonization of the global ship traffic is one of the industry’s greatest challenges for the next decades and will likely only be achieved with the introduction of synthetic fuels. Until now however not one single best technology solution emerged to ideally fit this task. Instead different energy carriers including hydrogen ammonia methanol methane and synthetic diesel are subject of discussion for usage in either internal combustion engines or fuel cells. In order to drive the selection procedure a case study for the year 2030 with all eligible combinations of power technologies and fuels is conducted. The assessment quantifies the technologies’ economic performances for cost-optimized system designs and in dependence of a ship’s mission characteristics. Thereby the influence of trends for electrofuel prices and shipboard volume opportunity costs are examined. Even if gaseous hydrogen is often considered not suitable for large ship applications due to its low volumetric energy density both the comparatively small fuel price and the high efficiency of fuel cells lead to the overall smallest system costs for passages up to 21 days depending on assumed cost parameters. Only for missions longer than seven days fuel cells operating on methanol or ammonia can compete with gaseous hydrogen economically.
Distributionally Robust Optimal Scheduling of Integrated Energy Systems Including Hydrogen Fuel Cells Considering Uncertainties
Aug 2023
Publication
The economic operation of the integrated energy system faces the problems of coupling between energy production and conversion equipment in the system and the imbalance of various energy demands. Therefore taking system safety as the constraint and minimum economic cost as the objective function including fuel cost operation and maintenance cost this paper proposes the operation dispatching model of the integrated energy system based on hydrogen fuel cell (HFC) including HFC photovoltaic wind turbine electric boiler electric chiller absorption chiller electric energy storage and thermal energy storage equipment. On this basis a distributionally robust optimization (DRO) model is introduced to deal with the uncertainty of wind power and photovoltaic output. In the distributionally robust optimization model Kullback–Leibler (KL) divergence is used to construct an ambiguity set which is mainly used to describe the prediction errors of renewable energy output. Finally the DRO economic dispatching model of the HFC integrated energy system (HFCIES) is established. Besides based on the same load scenario the economic benefits of hybrid energy storage equipment are discussed. The dispatching results show that compared with the scenario of only electric energy storage and only thermal energy storage the economic cost of the scenario of hybrid electric and thermal storage can be reduced by 3.92% and 7.55% respectively and the use of energy supply equipment can be reduced and the stability of the energy storage equipment can be improved.
A Review of Current Advances in Ammonia Combustion from the Fundamentals to Applications in Internal Combustion Engines
Aug 2023
Publication
The energy transition from hydrocarbon-based energy sources to renewable and carbon-free energy sources such as wind solar and hydrogen is facing increasing demands. The decarbonization of global transportation could come true via applying carbon-free fuel such as ammonia especially for internal combustion engines (ICEs). Although ammonia has advantages of high hydrogen content high octane number and safety in storage it is uninflammable with low laminar burning velocity thus limiting its direct usage in ICEs. The purpose of this review paper is to provide previous studies and current research on the current technical advances emerging in assisted combustion of ammonia. The limitation of ammonia utilization in ICEs such as large minimum ignition energy lower flame speed and more NOx emission with unburned NH3 could be solved by oxygen-enriched combustion ammonia–hydrogen mixed combustion and plasma-assisted combustion (PAC). In dual-fuel or oxygen-enriched NH3 combustion accelerated flame propagation speeds are driven by abundant radicals such as H and OH; however NOx emission should be paid special attention. Furthermore dissociating NH3 in situ hydrogen by non-noble metal catalysts or plasma has the potential to replace dual-fuel systems. PAC is able to change classical ignition and extinction S-curves to monotonic stretching which makes low-temperature ignition possible while leading moderate NOx emissions. In this review the underlying fundamental mechanism under these technologies are introduced in detail providing new insight into overcoming the bottleneck of applying ammonia in ICEs. Finally the feasibility of ammonia processing as an ICE power source for transport and usage highlights it as an appealing choice for the link between carbon-free energy and power demand.
Challenges and Solutions of Hydrogen Fuel Cells in Transportation Systems: A Review and Prospects
Jun 2023
Publication
Conventional transportation systems are facing many challenges related to reducing fuel consumption noise and pollutants to satisfy rising environmental and economic criteria. These requirements have prompted many researchers and manufacturers in the transportation sector to look for cleaner more efficient and more sustainable alternatives. Powertrains based on fuel cell systems could partially or completely replace their conventional counterparts used in all modes of transport starting from small ones such as scooters to large mechanisms such as commercial airplanes. Since hydrogen fuel cells (HFCs) emit only water and heat as byproducts and have higher energy conversion efficiency in comparison with other conventional systems it has become tempting for many scholars to explore their potential for resolving the environmental and economic concerns associated with the transportation sector. This paper thoroughly reviews the principles and applications of fuel cell systems for the main transportation schemes including scooters bicycles motorcycles cars buses trains and aerial vehicles. The review showed that fuel cells would soon become the powertrain of choice for most modes of transportation. For commercial long-rage airplanes however employing fuel cells will be limited due to the replacement of the axillary power unit (APU) in the foreseeable future. Using fuel cells to propel such large airplanes would necessitate redesigning the airplane structure to accommodate the required hydrogen tanks which could take a bit more time.
Assessment of a Coupled Electricity and Hydrogen Sector in the Texas Energy System in 2050
Oct 2024
Publication
Due to its ability to reduce emissions in the hard-to-abate sectors hydrogen is expected to play a significant role in future energy systems. This study modifies a sector-coupled dynamic modeling framework for electricity and hydrogen by including policy constraints carbon prices and possible hydrogen pathways and applies it to Texas in 2050. The impact of financial policies including the US clean hydrogen production tax credit on required infrastructure and costs are explored. Due to low natural gas prices financial levers are necessary to promote low-carbon hydrogen production as the optimized solution. The Levelized Costs of Hydrogen are found to be $1.50/kg in the base case (primarily via steam methane reformation production) and lie between $2.10 - 3.10/kg when production is via renewable electrolysis. The supporting infrastructure required to supply those volumes of renewable hydrogen is immense. The hydrogen tax credit was found to be enough to drive production via electrolysis.
Modelling and Operation Strategy Approaches for On-site Hydrogen Refuelling Stations
Aug 2023
Publication
The number of Fuel Cell Electric Vehicles (FCEVs) in circulation has undergone a significant increase in recent years. This trend is foreseen to be stronger in the near future. In correlation with the FCEVs market increase the hydrogen delivery infrastructure must be developed. With this aim many countries have announced ambitious projects. For example Spain has the objective of increasing the number of Hydrogen Refuelling Stations (HRS) with public access from three units in operation currently to about 150 by 2030. HRSs are complex systems with high variability in terms of layout design size of components operational strategy hydrogen generation method or hydrogen generation location. This paper is focused on on-site HRS with electrolysis-based hydrogen production which provides interesting advantages when renewable energy is utilized compared to off-site hydrogen production despite their complexity. To optimize HRS design and operation a simulation model must be implemented. This paper describes a generic on-site HRS with electrolysis-based hydrogen production a cascaded multi-tank storage system with multiple compressors renewable energy sources and multiple types of dispensing formats. A modelling approach of the layout is presented and tested with real-based parameters of an HRS currently under development which is capable of producing 11.34 kg/h of green H2 with irradiation at 1000 W/m2. For the operation an operational strategy is proposed. The modelled system is tested through several simulations. A sensitivity analysis of the effects of hydrogen demand and day-ahead hydrogen production objective on emissions demand satisfaction and variable costs is performed. Simulation results show how the operational strategy has achieved service up to 310 FCEVs refuelling events of heavy duty and light duty FCEVs bringing the total H2 sold up to almost 7200 H2kg in one month of winter. Additionally considering variable costs of the energy from the utility grid the model shows a profit in the range of 21–50 k€ for a daily demand of 60 H2kg/day and 100 H2kg/day respectively. In terms of emissions a year simulation with 60 H2kg/day of demand shows specific emissions in the production of H2 in Spain of 6.26 kgCO2eq/H2kg which represents a greenhouse gas emission intensity of 52.26 kgCO2eq/H2MJ.
Performance Evaluation of a Fuel Cell mCHP System under Different Configurations of Hydrogen Origin and Heat Recovery
Sep 2023
Publication
Motivated by the growing importance of fuel cell systems as the basis for distributed energy generation systems this work considers a micro-combined heat and power (mCHP) generation system based on a fuel cell integrated to satisfy the (power and thermal) energy demands of a residential application. The main objective of this work is to compare the performance of several CHP configurations with a conventional alternative in terms of primary energy consumption greenhouse gas (GHG) emissions and economic viability. For that a simulation tool has been developed to easily estimate the electrical and thermal energy generated by a hydrogen fuel cell and all associated results related to the hydrogen production alternatives: excess or shortfall of electrical and thermal energy CO2 emission factor overall performance operating costs payback period etc. A feasibility study of different configuration possibilities of the micro-CHP generation system has been carried out considering different heat-to-power ratios (HPRs) in the possible demands and analyzing primary energy savings CO2 emissions savings and operating costs. An extensive parametric study has been performed to analyze the effect of the fuel cell’s electric power and number of annual operation hours as parameters. Finally a study of the influence of the configuration parameters on the final results has been carried out. Results show that in general configurations using hydrogen produced from natural gas save more primary energy than configurations with hydrogen production from electricity. Furthermore it is concluded that the best operating points are those in which the generation system and the demand have similar HPR. It has also been estimated that a reduction in renewable hydrogen price is necessary to make these systems profitable. Finally it has been determined that the most influential parameters on the results are the fuel cell electrical efficiencies hydrogen production efficiency and hydrogen cost.
Socio-technical Imaginaries of Climate-neutral Aviation
May 2024
Publication
Limiting global warming to 1.5 ◦C is crucial to prevent the worst effects of climate change. This entails also the decarbonization of the aviation sector which is considered to be a “hard-to-abate” sector and thus requires special attention regarding its sustainability transition. However transition pathways to a potentially climateneutral aviation sector are unclear with different stakeholders having diverse imaginations of the sector's future. This paper aims to analyze socio-technical imaginaries of climate-neutral aviation as different perceptions of various stakeholders on this issue have not been sufficiently explored so far. In that sense this work contributes to the current scientific debate on socio-technical imaginaries of energy transitions for the first time studying the case of the aviation sector. Drawing on six decarbonization reports composed by different interest groups (e.g. industry academia and environmental associations) three imaginaries were explored following the process of a thematic analysis: rethinking travel and behavioral change (travel innovation) radical modernization and technological progress (fleet innovation) and transition to alternative fuels and renewable energy sources (fuel innovation). The results reveal how different and partly conflicting socio-technical imaginaries are co-produced and how the emergence and enforceability of these imaginaries is influenced by the situatedness of their creators indicating that the sustainability transition of aviation also raises political issues. Essentially as socio-technical imaginaries act as a driver for change policymakers should acknowledge the existence of alternative and counter-hegemonic visions created by actors from civil society settings to take an inclusive and equitable approach to implementing pathways towards climate-neutral aviation.
Capacity Expansion Planning of Hydrogen-Enabled Industrial Energy Systems for Carbon Dioxide Peaking
Jul 2024
Publication
As the main contributor of carbon emissions the low-carbon transition of the industrial sector is important for achieving the goal of carbon dioxide peaking. Hydrogen-enabled industrial energy systems (HIESs) are a promising way to achieve the low-carbon transition of industrial energy systems since the hydrogen can be well coordinated with renewable energy sources and satisfy the high and continuous industrial energy demand. In this paper the long-term capacity expansion planning problem of the HIES is formulated from the perspective of industrial parks and the targets of carbon dioxide peaking and the gradual decommissioning of existing equipment are considered as constraints. The results show that the targets of carbon dioxide peaking before different years or with different emission reduction targets can be achieved through the developed method while the economic performance is ensured to some extent. Meanwhile the overall cost of the strategy based on purchasing emission allowance is three times more than the cost of the strategy obtained by the developed method while the emissions of the two strategies are same. In addition long-term carbon reduction policies and optimistic expectations for new energy technologies will help industrial parks build more new energy equipment for clean transformation.
Low-carbon Economic Dispatch of Hydrogen-containing Integrated Energy System Considering Stepped Demand Response
Apr 2024
Publication
Vigorously developing an integrated energy system (IES) centered on the utilization of hydrogen energy is a crucial strategy to achieve the goal of carbon peaking and carbon neutrality. During the energy conversion process a hydrogen storage system releases a large amount of heat. By integrating a heat recovery mechanism we have developed a sophisticated hydrogen energy utilization model that accommodates multiple operational conditions and maximizes heat recovery thereby enhancing the efficiency of energy use on the supply side. To harness the potential of load-side response an integrated demand response (IDR) model accounting for price and incentives is established and a ladder-type subsidy incentive mechanism is proposed to deeply unlock load-side response capacity. Considering system economics and low carbon an IES source-load coordinated optimal scheduling model is proposed optimizing source-load coordinated operation for optimally integrated economy factoring in reward and punishment ladder-type carbon trading. Demonstrations reveal that the proposed methodology not only improves the efficiency of energy utilization but also minimizes wind energy wastage activates consumer engagement and reduces both system costs and carbon emissions thus proving the effectiveness of our optimization approach.
Co-Combustion of Hydrogen with Diesel and Biodiesel (RME) in a Dual-Fuel Compression-Ignition Engine
Jun 2023
Publication
The utilization of hydrogen for reciprocating internal combustion engines remains a subject that necessitates thorough research and careful analysis. This paper presents a study on the co-combustion of hydrogen with diesel fuel and biodiesel (RME) in a compression-ignition piston engine operating at maximum load with a hydrogen content of up to 34%. The research employed engine indication and exhaust emissions measurement to assess the engine’s performance. Engine indication allowed for the determination of key combustion stages including ignition delay combustion time and the angle of 50% heat release. Furthermore important operational parameters such as indicated pressure thermal efficiency and specific energy consumption were determined. The evaluation of dual-fuel engine stability was conducted by analyzing variations in the coefficient of variation in indicated mean effective pressure. The increase in the proportion of hydrogen co-combusted with diesel fuel and biodiesel had a negligible impact on ignition delay and led to a reduction in combustion time. This effect was more pronounced when using biodiesel (RME). In terms of energy efficiency a 12% hydrogen content resulted in the highest efficiency for the dual-fuel engine. However greater efficiency gains were observed when the engine was powered by RME. It should be noted that the hydrogen-powered engine using RME exhibited slightly less stable operation as measured by the COVIMEP value. Regarding emissions hydrogen as a fuel in compression ignition engines demonstrated favorable outcomes for CO CO2 and soot emissions while NO and HC emissions increased.
Technology Pathways, Efficiency Gains and Price Implications of Decarbonising Residential Heat in the UK
Jun 2023
Publication
The UK government’s plans to decarbonise residential heating will mean major changes to the energy system whatever the specific technology pathway chosen driving a range of impacts on users and suppliers. We use an energy system model (UK TIMES) to identify the potential energy system impacts of alternative pathways to low or zero carbon heating. We find that the speed of transitioning can affect the network investment requirements the overall energy use and emissions generated while the primary heating fuel shift will determine which sectors and networks require most investment. Crucially we identify that retail price differences between heating fuels in the UK particularly gas and electricity could erode or eliminate bill savings from switching to more efficient heating systems.
Feasibility Assessment of Alternative Clean Power Systems onboard Passenger Short-Distance Ferry
Sep 2023
Publication
In order to promote low-carbon fuels such as hydrogen to decarbonize the maritime sector it is crucial to promote clean fuels and zero-emission propulsion systems in demonstrative projects and to showcase innovative technologies such as fuel cells in vessels operating in local public transport that could increase general audience acceptability thanks to their showcase potential. In this study a short sea journey ferry used in the port of Genova as a public transport vehicle is analyzed to evaluate a ”zero emission propulsion” retrofitting process. In the paper different types of solutions (batteries proton exchange membrane fuel cell (PEMFC) solid oxide fuel cell (SOFC)) and fuels (hydrogen ammonia natural gas and methanol) are investigated to identify the most feasible technology to be implemented onboard according to different aspects: ferry daily journey and scheduling available volumes and spaces propulsion power needs energy storage/fuel tank capacity needed economics etc. The paper presents a multi-aspect analysis that resulted in the identification of the hydrogen-powered PEMFC as the best clean power system to guarantee for this specific case study a suitable retrofitting of the vessel that could guarantee a zero-emission journey
Feasibility of Green Hydrogen-Based Synthetic Fuel as a Carbon Utilization Option: An Economic Analysis
Sep 2023
Publication
Singapore has committed to achieving net zero emissions by 2050 which requires the pursuit of multiple decarbonization pathways. CO2 utilization methods such as fuel production may provide a fast interim solution for carbon abatement. This paper evaluates the feasibility of green hydrogen-based synthetic fuel (synfuel) production as a method for utilizing captured CO2. We consider several scenarios: a baseline scenario with no changes local production of synfuel with hydrogen imports and overseas production of synfuel with CO2 exports. This paper aims to determine a CO2 price for synfuel production evaluate the economic viability of local versus overseas production and investigate the effect of different cost parameters on economic viability. Using the current literature we estimate the associated production and transport costs under each scenario. We introduce a CO2 utilization price (CUP) that estimates the price of utilizing captured CO2 to produce synfuel and an adjusted CO2 utilization price (CCUP) that takes into account the avoided emissions from crude oil-based fuel production. We find that overseas production is more economically viable compared to local production with the best case CCUP bounds giving a range of 142–148 $/tCO2 in 2050 if CO2 transport and fuel shipping costs are low. This is primarily due to the high cost of hydrogen feedstock especially the transport cost which can offset the combined costs of CO2 transport and fuel shipping. In general we find that any increase in the hydrogen feedstock cost can significantly affect the CCUP for local production. Sensitivity analysis reveals that hydrogen transport cost has a significant impact on the viability of local production and if this cost is reduced significantly local production can be cheaper than overseas production. The same is true if the economies of scale for local production is significantly better than overseas production. A significantly lower carbon capture cost can also the reduce the CCUP significantly.
Techno-economic Modelling of Zero-emission Marine Transport with Hydrogen Fuel and Superconducting Propulsion System: Case Study of a Passenger Ferry
Mar 2023
Publication
This paper proposes a techno-economic model for a high-speed hydrogen ferry. The model can describe the system properties i.e. energy demand weight and daily operating expenses of the ferry. A novel aspect is the consideration of superconductivity as a measure for cost saving in the setting where liquid hydrogen (LH2) can be both coolant and fuel. We survey different scenarios for a high-speed ferry that could carry 300 passengers. The results show that despite higher energy demand compressed hydrogen gas is more economical compared with LH2 for now; however constructing large-scale hydrogen liquefaction plants make it competitive in the future. Moreover compressed hydrogen gas is restricted to a shorter distance while LH2 makes longer distances possible and whenever LH2 is accessible using a superconducting propulsion system has a beneficial impact on both energy and cost savings. These effects strengthen if the operational time or the weight of the ferry increases.
Technology Roadmap for Hydrogen-fuelled Transportation in the UK
Apr 2023
Publication
Transportation is the sector responsible for the largest greenhouse gas emission in the UK. To mitigate its impact on the environment and move towards net-zero emissions by 2050 hydrogen-fuelled transportation has been explored through research and development as well as trials. This article presents an overview of relevant technologies and issues that challenge the supply use and marketability of hydrogen for transportation application in the UK covering on-road aviation maritime and rail transportation modes. The current development statutes of the different transportation modes were reviewed and compared highlighting similarities and differences in fuel cells internal combustion engines storage technologies supply chains and refuelling characteristics. In addition common and specific future research needs in the short to long term for the different transportation modes were suggested. The findings showed the potential of using hydrogen in all transportation modes although each sector faces different challenges and requires future improvements in performance and cost development of innovative designs refuelling stations standards and codes regulations and policies to support the advancement of the use of hydrogen.
Techno-Economic Assessment of Power-to-Liquids (PtL) Fuels Production and Global Trading Based on Hybrid PV-Wind Power Plants
Nov 2016
Publication
This paper introduces a value chain design for transportation fuels and a respective business case taking into account hybrid PV-Wind power plants electrolysis and hydrogen-to-liquids (H2tL) based on hourly resolved full load hours (FLh). The value chain is based on renewable electricity (RE) converted by power-to-liquids (PtL) facilities into synthetic fuels mainly diesel. Results show that the proposed RE-diesel value chains are competitive for crude oil prices within a minimum price range of about 79 - 135 USD/barrel (0.44 – 0.75 €/l of diesel production cost) depending on the chosen specific value chain and assumptions for cost of capital available oxygen sales and CO2 emission costs. A sensitivity analysis indicates that the RE-PtL value chain needs to be located at the best complementing solar and wind sites in the world combined with a de-risking strategy and a special focus on mid to long-term electrolyser and H2tL efficiency improvements. The substitution of fossil fuels by hybrid PV-Wind power plants could create a PV-wind market potential in the order of terawatts.
Optimal Operation Strategy of PV-Charging-Hydrogenation Composite Energy Station Considering Demand Response
Apr 2023
Publication
Traditional charging stations have a single function which usually does not consider the construction of energy storage facilities and it is difficult to promote the consumption of new energy. With the gradual increase in the number of new energy vehicles (NEVs) to give full play to the complementary advantages of source-load resources and provide safe efficient and economical energy supply services this paper proposes the optimal operation strategy of a PV-charging-hydrogenation composite energy station (CES) that considers demand response (DR). Firstly the operation mode of the CES is analyzed and the CES model including a photovoltaic power generation system fuel cell hydrogen production hydrogen storage hydrogenation and charging is established. The purpose is to provide energy supply services for electric vehicles (EVs) and hydrogen fuel cell vehicles (HFCVs) at the same time. Secondly according to the travel law of EVs and HFCVs the distribution of charging demand and hydrogenation demand at different periods of the day is simulated by the Monte Carlo method. On this basis the following two demand response models are established: charging load demand response based on the price elasticity matrix and interruptible load demand response based on incentives. Finally a multi-objective optimal operation model considering DR is proposed to minimize the comprehensive operating cost and load fluctuation of CES and the maximum–minimum method and analytic hierarchy process (AHP) are used to transform this into a linearly weighted single-objective function which is solved via an improved moth–flame optimization algorithm (IMFO). Through the simulation examples operation results in four different scenarios are obtained. Compared with a situation not considering DR the operation strategy proposed in this paper can reduce the comprehensive operation cost of CES by CNY 1051.5 and reduce the load fluctuation by 17.8% which verifies the effectiveness of the proposed model. In addition the impact of solar radiation and energy recharge demand changes on operations was also studied and the resulting data show that CES operations were more sensitive to energy recharge demand changes.
Scatter Search for Optimal Sizing of a Hybrid Renewable Energy System for Scheduling Green Hydrogen Production
Dec 2024
Publication
At present energy demands are mainly covered by the use of fossil fuels. The process of fossil fuel production increases pollution from oil extraction transport to processing centers treatment to obtain lighter fractions and delivery and use by the final consumers. Such polluting circumstances are aggravated in the case of accidents involving fossil fuels. They are also linked to speculative markets. As a result the trend is towards the decarbonization of lifestyles in advanced societies. The present paper addresses the problem of the optimal sizing of a hybrid renewable energy system for scheduling green hydrogen production. A local system fully powered by renewable energies is designed to obtain hydrogen from seawater. In order to monetize excess energy the grid connection of the system is considered under realistic energy market constraints designing an hourly purchasing strategy. This crucial problem which has not been taken into account in the literature is solved by the specific dispatch strategy designed. Several optimization methods have been used to solve this problem; however the scatter search method has not previously been employed. In this paper the problem is faced with a novel implementation of this method. The implementation is competitive in terms of performance when compared to on the one hand the genetic algorithm and differential evolution methods which are well-known state-of-the-art evolutionary algorithms and on the other hand the optimal foraging algorithm (OFA) a more recent algorithm. Furthermore scatter search outperformed all other methods in terms of computational cost. This is promising for real-world applications that require quick responses.
Decarbonization with Induced Technical Change: Exploring the Niche Potential of Hydrogen in Heavy Transportation
Jan 2024
Publication
Fuel cells and electric batteries are competing technologies for the energy transition in heavy transportation. We explore the conditions for the survival of a unique technology in the long term. Learning by doing suggests focusing on a single technology while differentiation and decreasing return to scale (cost convexity) favor diversification. Exogenous technical change also plays a role. The interaction between these factors is analyzed in a general model. It is proved that in absence of convexity and exogenous technical change only one technology is used for the whole transition. We then apply this framework to analyze the competition between fuel-cell electric buses (FCEBs) and battery electric buses (BEB) in the European bus sector. There are both learning by doing and exogenous technical change. The model is calibrated and solved. It is shown that the existence of a niche for FCEBs critically depends on the speed at which cost reductions are achieved. The speed depends both on the size of the niche and the rate of learning by doing for FCEBs. Public policies to decentralize the socially optimal trajectory in terms of taxes (carbon) and subsidies (learning by doing) are derived.
Assessing Techno-economic Feasibility of Cogeneration and Power to Hydrogen Plants: A Novel Dynamic Simulation Model
Aug 2023
Publication
Green hydrogen technologies are crucial for decarbonization purposes while cogeneration offers efficient heat and power generation. Integrating green hydrogen and cogeneration brings numerous benefits optimizing energy utilization reducing emissions and supporting the transition to a sustainable future. While there are numerous studies examining the integration of combined heat and power with Power to Gas certain aspects still requires a more detailed analysis especially for internal combustion engines fuelled by natural gas due to their widespread adoption as one of the primary technologies in use. Therefore this paper presents a comprehensive numerical 0-D dynamic simulation model implemented within the TRNSYS environment considering internal combustion engines fuelled by natural gas. Specifically the study focuses on capturing CO2 from exhaust gases and producing green hydrogen from electrolysis. Based on these considerations two configurations are proposed: the first involves the methanation reaction while the second entails the production of a hydromethane mixture. The aim is to evaluate the technical and economic feasibility of these configurations and compare their performance within the Power to Gas framework. Self-sufficiency from the national electricity grid has been almost achieved for the two configurations considering an industrial case. The production of hydromethane allows smaller photovoltaic plant (81 kWp) compared to the production of synthetic methane (670 kWp) where a high quantity of hydrogen is required especially if all the carbon dioxide captured is used in the methanation process. Encouraging economic results with payback times below ten years have been obtained with the use of hydromethane. Moreover hydromethane shows potential residential applications with small required photovoltaic sizes.
The Possibility of Powering a Light Aircraft by Releasing the Energy Stored in Hydrogen within a Fuel Cell Stack
Jun 2024
Publication
In this work we examine the possibility of converting a light propeller-driven aircraft powered by a spark-ignition reciprocating piston and internal combustion engine running on AVGAS into one powered by an electric motor driven by a proton exchange membrane fuel cell stack running on hydrogen. Our studies suggest that storing hydrogen cryogenically is a better option than storing hydrogen under pressure. In comparison to cryogenic tanks high-pressure tanks are extremely heavy and unacceptable for light aircraft. We show that the modified aircraft (including batteries) is no heavier than the original and that the layout of the major components results in lower movement of the aircraft center-of-gravity as the aircraft consumes hydrogen. However we acknowledge that our fuel cell aircraft cannot store the same amount of energy as the original running on AVGAS. Therefore despite the fact that the fuel cell stack is markedly more efficient than an internal combustion engine there is a reduction in the range of the fuel cell aircraft. One of our most important findings is that the quantity of energy that we need to dissipate to the surroundings via heat transfer is significantly greater from a fuel cell stack than from an internal combustion engine. This is particularly the case when we attempt to run the fuel cell stack at high current densities. To control this problem our strategy during the cruise phase is to run the fuel cell stack at its maximum efficiency where the current density is low. We size the fuel cell stack to produce at least enough power for cruise and when we require excess power we add the energy stored in batteries to make up the difference.
Renewable Hydrogen in Industrial Production: A Bibliometric Analysis of Current and Future Applications
Dec 2024
Publication
Renewable hydrogen is widely considered a key technology to achieve net zero emissions in industrial production processes. This paper presents a structured bibliometric analysis examining current and future applications of hydrogen as feedstock and fuel across industries quantifying demand for different industrial processes and identifying greenhouse gas emissions reduction potential against the context of current fossil-based practices. The findings highlight significant focus on hydrogen as feedstock for steel ammonia and methanol production and its use in high-to medium-temperature processes and a general emphasis on techno-economic and technological evaluations of hydrogen applications across industries. However gaps exist in research on hydrogen use in sectors like cement glass waste pulp and paper ceramics and aluminum. Additionally the analysis reveals limited attention in the identified literature to hydrogen supply chain efficiencies including conversion and transportation losses as well as geopolitical and raw material challenges. The analysis underscores the need for comprehensive and transparent data to align hydrogen use with decarbonization goals optimize resource allocation and inform policy and investment decisions for strategic deployment of renewable hydrogen.
The Economic Impact and Carbon Footprint Dependence of Energy Management Strategies in Hydrogen-Based Microgrids
Sep 2023
Publication
This paper presents an economic impact analysis and carbon footprint study of a hydrogenbased microgrid. The economic impact is evaluated with respect to investment costs operation and maintenance (O&M) costs as well as savings taking into account two different energy management strategies (EMSs): a hydrogen-based priority strategy and a battery-based priority strategy. The research was carried out in a real microgrid located at the University of Huelva in southwestern Spain. The results (which can be extrapolated to microgrids with a similar architecture) show that although both strategies have the same initial investment costs (EUR 52339.78) at the end of the microgrid lifespan the hydrogen-based strategy requires higher replacement costs (EUR 74177.4 vs. 17537.88) and operation and maintenance costs (EUR 35254.03 vs. 34877.08) however it provides better annual savings (EUR 36753.05 vs. 36282.58) and a lower carbon footprint (98.15% vs. 95.73% CO2 savings) than the battery-based strategy. Furthermore in a scenario where CO2 emission prices are increasing the hydrogen-based strategy will bring even higher annual cost savings in the coming years.
Energy and Greenhouse Gases Life Cycle Assessment of Electric and Hydrogen Buses: A Real-world Case Study in Bolzano Italy
May 2023
Publication
The transportation sector plays an important role in the current effort towards the control of global warming. Against this backdrop electrification is currently attracting attention as the life cycle environmental performance of different powertrain technologies is critically assessed. In this study a life cycle analysis of the public transportation buses was performed. The scope of the analysis is to compare the energy and global warming performances of the different powertrain technologies in the city fleet: diesel full electric and hydrogen buses. Real world monitored data were used in the analysis for the energy consumptions of the buses and to produce hydrogen in Bolzano. Compared to the traditional diesel buses the electric vehicles showed a 43% reduction of the non-renewable primary energy demand and a 33% of the global warming potential even in the worst consequential scenario considered. The switch to hydrogen buses leads to very different environmental figures: from very positive if it contributes to a further penetration of renewable electricity to hardly any difference if hydrogen from steam-methane reforming is used to clearly negative ones (approximately doubling the impacts) if a predominantly fossil electricity mix is used in the electrolysis.
The Use of Hydrogen as Alternative Fuel for Ship Propulsion: A Case Study of Full and Partial Retrofitting of Roll-on/Roll-off Vessels for Short Distance Routes
Oct 2023
Publication
Roll-on/Roll-Off (Ro-Ro) vessels including those without and with passenger accommodation Roll-on/roll-off passenger (Ro-Pax) can be totally or partially retrofitted to reduce the greenhouse gas (GHG) emissions in maritime transport not only during hoteling operation at the dock but also during service. This study is based on data of the vessel routes connecting the Port of Piombino to the Elba Island in Italy. Three retrofitting scenarios have been considered: replacement of the main and auxiliary engines with fuel cells (FC) (full retrofitting) replacement of the auxiliary engines with FCs (partial retrofitting) and replacement of the auxiliary engines with FCs and hoteling only with auxiliary engines for one specific vessel. The amount of hydrogen the filling time and the energy needed for production compression and pre-cooling of hydrogen have been calculated for the different scenarios.
The Role of Electricity-based Hydrogen in the Emerging Power-to-X Economy
Aug 2023
Publication
As energy system research into high shares of renewables has developed so have the perspectives of the fundamental nature of a highly renewable economy. Early energy system transition research suggested that current fossil fuel energy systems would transition to a ‘Hydrogen Economy’ whereas more recent insights suggest that a ‘Power-to-X Economy’ may be a more appropriate term as renewable electricity will become both the most important primary and final energy carrier through various Power-to-X conversion routes across the energy system. This paper provides a detailed overview on research insights of recent years on the core elements of the Power-to-X Economy and the role of hydrogen based on latest research results. These results suggest that by 2050 upwards of 61737 TWhLHV of hydrogen will be required to fully defossilise the global energy-industry system. Hydrogen therefore emerges as a central intermediate energy carrier and its relevance is driven by significant cost reductions in renewable electricity especially of solar photovoltaics and wind power. Efficiency and cost drivers position direct electrification as the primary solution for defossilisation of the global energy-industry system; however electron-to-molecule routes are essential for the large subset of remaining energy-related demands including chemical production marine and aviation fuels and steelmaking.
Design and Optimization of a Type-C Tank for Liquid Hydrogen Marine Transport
May 2023
Publication
As one of the most promising renewable energy sources hydrogen has the excellent environmental benefit of producing zero emissions. A key technical challenge in using hydrogen across sectors is placed on its storage technology. The storage temperature of liquid hydrogen (20 K or 253 C) is close to absolute zero so the storage materials and the insulation layers are subjected to extremely stringent requirements against the cryogenic behaviour of the medium. In this context this research proposed to design a large liquid hydrogen type-C tank with AISI (American Iron and Steel Institution) type 316 L stainless steel as the metal barrier using Vapor-Cooled Shield (VCS) and Rigid Polyurethane Foams (RPF) as the insulation layer. A parametric study on the design of the insulation layer was carried out by establishing a thermodynamic model. The effects of VCS location on heat ingress to the liquid hydrogen transport tank and insulation temperature distribution were investigated and the optimal location of the VCS in the insulation was identified. Research outcomes finally suggest two optimal design schemes: (1) when the thickness of the insulation layer is determined Self-evaporation Vapor-Cooled Shield (SVCS) and Forcedevaporation Vapor-Cooled Shield (FVCS) can reduce heat transfer by 47.84% and 85.86% respectively; (2) when the liquid hydrogen evaporation capacity is determined SVCS and FVCS can reduce the thickness of the insulation layer by 50% and 67.93% respectively.
A Web-based Decision Support System (DSS) for Hydrogen Refueling Station Location and Supply Chain Optimisation
Jun 2023
Publication
This study presents a novel web-based decision support system (DSS) that optimizes the locations of hydrogen refueling stations (HRSs) and hydrogen supply chains (HSCs). The system is developed with a design science approach that identifies key design requirements and features through interviews and literature reviews. Based on the findings a system architecture and data model were designed incorporating scenario management optimization model visualization and data management components. The DSS provides a two-stage solution model that links demand to HRSs and production facilities to HRSs. A prototype is demonstrated with a plan for 2025 and 2030 in the Republic of Korea where 450 to 660 stations were deployed nationwide and linked to production facilities. User evaluation confirmed the effectiveness of the DSS in solving optimization problems and its potential to assist the government and municipalities in planning hydrogen infrastructure.
Inter-Zone Optimal Scheduling of Rural Wind–Biomass-Hydrogen Integrated Energy System
Aug 2023
Publication
To solve the problems of low utilization of biomass and uncertainty and intermittency of wind power (WP) in rural winter an interval optimization model of a rural integrated energy system with biogas fermentation and electrolytic hydrogen production is constructed in this paper. Firstly a biogas fermentation kinetic model and a biogas hydrogen blending model are developed. Secondly the interval number is used to describe the uncertainty of WP and an interval optimization scheduling model is developed to minimize daily operating cost. Finally a rural integrated energy system in Northeast China is taken as an example and a sensitivity analysis of electricity price gas production and biomass price is conducted. The simulation results show that the proposed strategy can significantly reduce the wind abandonment rate and improve the economy by 3.8–22.3% compared with conventional energy storage under optimal dispatch.
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