Applications & Pathways
Hydrogen Blending and the Gas Commercial Framework - Report on Conclusions of NIA study
Sep 2020
Publication
Blending hydrogen into the gas grid could be an important stepping stone during the transition to a sustainable net zero system. In particular it may: provide a significant and reliable source of demand for hydrogen producers supporting the investment case for hydrogen; provide learnings and incremental change towards what could potentially become a 100% hydrogen grid; and immediately decarbonise a portion of the gas flowing through the grid. Technical questions relating to hydrogen blending are being taken forward by the industry (e.g. through the HyDeploy project in relation to the maximum potential blend of hydrogen that can be accommodated without end user appliances needing to be altered or replaced). But if blending is to take place changes to commercial arrangements will be necessary as today these assume a relatively uniform gas quality. In particular the commercial framework will need to ensure that limits on the percentage of hydrogen that can safely be blended (currently expected to be around 20% by volume) are not exceeded. We have been commissioned by Cadent to undertake a Network Innovation Allowance (NIA) project to identify the changes required to the gas commercial framework that will enable hydrogen blending in the GB gas grid and to set out a roadmap for how these can be delivered. This report sets out our recommendations.
Conceptual Study and Development of an Autonomously Operating, Sailing Renewable Energy Conversion System
Jun 2022
Publication
With little time left for humanity to reduce climate change to a tolerable level a highly scalable and rapidly deployable solution is needed that can be implemented by any country. Offshore wind energy in international waters is an underused resource and could even be harnessed by landlocked countries. In this paper the use of sailing wind turbines operating autonomously in high seas to harvest energy is proposed. The electrical energy that is generated by the wind turbine is converted to a renewable fuel and stored onboard. Later the fuel will be transferred to shore or to other destinations of use. The presented idea is explored at the system level where the basic subsystems necessary are identified and defined such as energy conversion and storage as well as propulsion subsystems. Moreover various operating possibilities are investigated including a comparison of different sailing strategies and fuels for storage. Existing ideas are also briefly addressed and an example concept is suggested as well. In this paper the proposed sailing renewable energy conversion system is explored at a higher level of abstraction. Following up on this conceptual study more detailed investigations are necessary to determine whether the development of such a sailing renewable energy conversion system is viable from an engineering economic and environmental point of view.
Everything About Hydrogen Podcast: FCEV's "Down Under"
Dec 2020
Publication
On today's show the EAH team will be joined by Brendan Norman to talk about deployment of sustainable FCEV technologies across many different segments of the transport sector and utility vehicles. Brendan is the CEO of H2X a new vehicle manufacturing company based in Sydney with a manufacturing facility in Port Kembla will deliver its first hydrogen FCEVs to market beginning in 2022 before expanding its vehicle offerings in subsequent years. Brendan joined the EAH team via SquadCast from Kuala Lumpur to talk fuel cells with us and you don't want to miss the excellent discussion that we had on this week's episode.
The podcast can be found on their website
The podcast can be found on their website
Incentive Structures for Power-to-X and E-fuel Pathways for Transport in EU and Member States
Jun 2022
Publication
Though Power-to-X pathways primarily Power-to-Liquids attract interest as solutions for decarbonising parts of the transport sector that are not suitable for electrification the regulatory framework until recently slowed down their implementation. This paper examines the updates in the main aspects of the legal framework in the European Union from 2019 to the beginning of 2022 related to Power-to-X: support schemes specific targets and potential barriers. The results show increasing interest and market entrance of electrolysis and push from the different actors and regulatory parties to establish solutions that will enable faster upscaling. However it is visible from the National Energy and Climate Plans and hydrogen strategies that the most emphasis is still on hydrogen as an end fuel for personal vehicles or power-to-gas. On the other hand few countries have implemented legal frameworks facilitating diverse PtX pathways without focusing solely on hydrogen. Nevertheless revisions of RED II have finally set up specific targets for electrofuels and Fit for 55 has introduced new actions supporting electrofuels in aviation and marine transport.
Wind Power to Methanol: Renewable Methanol Production Using Electricity, Electrolysis of Water and CO2 Air Capture
Feb 2020
Publication
A 100 MW stand-alone wind power to methanol process has been evaluated to determine the capital requirement and power to methanol efficiency. Power available for electrolysis determines the amount of hydrogen produced. The stoichiometric amount of CO2– required for the methanol synthesis – is produced using direct air capture. Integration of utilities for CO2 air capture hydrogen production from co-harvested water and methanol synthesis is incorporated and capital costs for all process steps are estimated. Power to methanol efficiency is determined to be around 50%. The cost of methanol is around 300€ ton−1 excluding and 800€ ton−1 including wind turbine capital cost. Excluding 300 M€ investment cost for 100 MW of wind turbines total plant capital cost is around 200 M€. About 45% of the capital cost is reserved for the electrolysers 50% for the CO2 air capture installation and 5% for the methanol synthesis system. The conceptual design and evaluation shows that renewable methanol produced from air captured CO2 water and renewable electricity is becoming a realistic option at reasonable costs of 750–800 € ton−1.
Everything About Hydrogen Podcast: Can CUTRIC Clean Canada?
Mar 2021
Publication
When the pandemic recedes lockdowns and restrictions are relaxed and eventually eliminated and millions of residents in cities across the world begin to return to their offices and workplaces public transit systems will once again be at the core of billions of commuters' daily activities. Urban transit systems are designed to move huge volumes of people through cities and communities quickly reliably and cost-efficiently (some systems accomplish these goals better than others!). The energy needed to run these networks of cars trains and buses is enormous and today most of it comes from fossil fuels. How can communities - both large and small - redesign their transit systems to eliminate operational carbon emissions in the future?
The podcast can be found on their website
The podcast can be found on their website
Integration of Hydrogen and Synthetic Natural Gas within Legacy Power Generation Facilities
Jun 2022
Publication
Whilst various new technologies for power generation are continuously being evaluated the owners of almost-new facilities such as combined-cycle gas turbine (CCGT) plants remain motivated to adapt these to new circumstances and avoid the balance-sheet financial impairments of underutilization. Not only are the owners reluctant to decommission the legacy CCGT assets but system operators value the inertia and flexibilities they contribute to a system becoming predominated with renewable generation. This analysis therefore focuses on the reinvestment cases for adapting CCGT to hydrogen (H2 ) synthetic natural gas (SNG) and/or retrofitted carbon capture and utilization systems (CCUS). Although H2 either by itself or as part of SNG has been evaluated attractively for longer-term electricity storage the business case for how it can be part of a hybrid legacy CCGT system has not been analyzed in a market context. This work compares the power to synthetic natural gas to power (PSNGP) adaptation with the simpler and less expensive power to hydrogen to power (P2HP) adaptation. Both the P2HP and PSNGP configurations are effective in terms of decarbonizations. The best results of the feasibility analysis for a UK application with low CCGT load factors (around 31%) were obtained for 100% H2 (P2HP) in the lower range of wholesale electricity prices (less than 178 GBP/MWh) but in the higher range of prices it would be preferable to use the PSNGP configuration with a low proportion of SNG (25%). If the CCGT load factor increased to 55% (the medium scenario) the breakeven profitability point between P2HP and PSNGP decreased to a market price of 145 GBP/MWh. Alternatively with the higher load factors (above 77%) satisfactory results were obtained for PSNGP using 50% SNG if with market prices above 185 GBP/MWh.
Everything About Hydrogen Podcast: Hydrogen in the E-Mobility Sector
Oct 2021
Publication
Quantron AG was created in 2019 as a high-tech spin-off of the well-known Haller GmbH & Co. KG with the vision of paving the way for e-mobility in inner-city and regional passenger and cargo transportation. Quantron AG combines innovative ability and expertise in e-vans e-trucks and e-buses with the long-standing knowledge and experience of Haller GmbH & Co. KG in the commercial vehicle sector. The company's approach to e-Mobility is defined by its commitment to leveraging the most effective zero-emission vehicle technology for the use case which means Quantron is building both hydrogen fuel cell electric vehicles (FCEVs) and battery electric vehicles (BEVs) for its clients.
The podcast can be found on the website
The podcast can be found on the website
Optimized Configuration of Diesel Engine-Fuel Cell-Battery Hybrid Power Systems in a Platform Supply Vessel to Reduce CO2 Emissions
Mar 2022
Publication
The main objective of this paper is to select the optimal configuration of a ship’s power system considering the use of fuel cells and batteries that would achieve the lowest CO2 emissions also taking into consideration the number of battery cycles. The ship analyzed in this work is a Platform Supply Vessel (PSV) used to support oil and gas offshore platforms transporting goods equipment and personnel. The proposed scheme considers the ship’s retrofitting. The ship’s original main generators are maintained and the fuel cell and batteries are installed as complementary sources. Moreover a sensitivity analysis is pursued on the ship’s demand curve. The simulations used to calculate the CO2 emissions for each of the new hybrid configurations were developed using HOMER software. The proposed solutions are auxiliary generators three types of batteries and a protonexchange membrane fuel cell (PEMFC) with different sizes of hydrogen tanks. The PEMFC and batteries were sized as containerized solutions and the sizing of the auxiliary engines was based on previous works. Each configuration consists of a combination of these solutions. The selection of the best configuration is one contribution of this paper. The new configurations are classified according to the reduction of CO2 emitted in comparison to the original system. For different demand levels the results indicate that the configuration classification may vary. Another valuable contribution of this work is the sizing of the battery and hydrogen storage systems. They were installed in 20 ft containers since the installation of batteries fuel cells and hydrogen tanks in containers is widely used for ship retrofit. As a result the most significant reduction of CO2 emissions is 10.69%. This is achieved when the configuration includes main generators auxiliary generators a 3119 kW lithium nickel manganese cobalt (LNMC) battery a 250 kW PEMFC and 581 kg of stored hydrogen.
Porosity and Thickness Effect of Pd–Cu–Si Metallic Glasses on Electrocatalytic Hydrogen Production and Storage
Aug 2021
Publication
This contribution places emphasis on tuning pore architecture and film thickness of mesoporous Pd–Cu–Si thin films sputtered on Si/SiO2 substrates for enhanced electrocatalytic and hydrogen sorption/desorption activity and their comparison with the state-of-the-art thin film electrocatalysts. Small Tafel slope of 43 mV dec–1 for 1250 nm thick coatings with 2 µm diameter pores with 4.2 µm interspacing (H2) electrocatalyst with comparable hydrogen overpotentials to the literature suggests its use for standard fuel cells. The largest hydrogen sorption has been attained for the 250 nm thick electrocatalyst on 5 µm pore diameter and 12 µm interspacing (2189 µC cm–2 per CV cycle) making it possible for rapid storage systems. Moreover the charge transfer resistance described by an equivalent circuit model has an excellent correlation with Tafel slopes. Along with its very low Tafel slope of 42 mV dec–1 10 nm thick H2 pore design electrocatalyst has the highest capacitive response of ∼0.001 S sn cm–2 and is promising to be used as a nano-charger and hydrogen sensor.
The Role of Research and Innovation in Europe for the Decarbonisation of Waterborne Transport
Sep 2021
Publication
Waterborne transport contributes to around 14% of the overall greenhouse gas emissions of transport in the European Union and it is among the most efficient modes of transport. Nonetheless considering the aim of making the European Union carbon-neutral by 2050 and the fundamental role of waterborne transport within the European economy effort is needed to reduce its environmental impact. This paper provides an assessment of research and innovation measures aiming at decreasing waterborne transport’s CO2 emissions by assessing European projects based on the European Commission’s Transport Research and Innovation Monitoring and Information System (TRIMIS). Additionally it provides an outlook of the evolution of scientific publications and intellectual property activity in the area. The review of project findings suggests that there is no single measure which can be considered as a problem solver in the area of the reduction of waterborne CO2 emissions and only the combination of different innovations should enable reaching this goal. The highlighted potential innovations include further development of lightweight composite materials innovative hull repair methods wind assisted propulsion engine efficiency waste heat electrification hydrogen and alternative fuels. The assessment shows prevalence of funding allocated to technological measures; however non-technological ones like improved vessel navigation and allocation systems also show a great potential for the reduction of CO2 emissions and reduction of negative environmental impacts of waterborne transport.
Improvement of Temperature and Humidity Control of Proton Exchange Membrane Fuel Cells
Sep 2021
Publication
Temperature and humidity are two important interconnected factors in the performance of PEMFCs (Proton Exchange Membrane Fuel Cells). The fuel and oxidant humidity and stack temperature in a fuel cell were analyzed in this study. There are many factors that affect the temperature and humidity of the stack. We adopt the fuzzy control method of multi-input and multi-output to control the temperature and humidity of the stack. A model including a driver vehicle transmission motor air feeding electrical network stack hydrogen supply and cooling system was established to study the fuel cell performance. A fuzzy controller is proven to be better in improving the output power of fuel cells. The three control objectives are the fan speed control for regulating temperature the solenoid valve on/off control of the bubble humidifier for humidity variation and the speed of the pump for regulating temperature difference. In addition the results from the PID controller stack model and the fuzzy controller stack model are compared in this research. The fuel cell bench test has been built to validate the effectiveness of the proposed fuzzy control. The maximum temperature of the stack can be reduced by 5 ◦C with the fuzzy control in this paper so the fuel cell output voltage (power) increases by an average of approximately 5.8%.
Application of Hydrogen and Hydrogen-containing Gases in Internal Combustion Engines
Nov 2019
Publication
The results of studies of the influence of hydrogen and hydrogen-containing gas additives on the parameters of various types of internal combustion engines are analyzed and summarized. It made possible to identify the features of the effect on the combustion of fuel during internal combustion engine operation at partial loads. The dependences of reducing the toxicity and fuel consumption of internal combustion engine on the amount of addition of hydrogen and a hydrogen-containing gas to the air-fuel mixture were obtained. It allowed to establish quantitative effects of free hydrogen in particular to quantify the region of small hydrogen additives and the conditions under which hydrogen exhibits the qualities of a chemically active component of the mixture.
A Numerical Investigation on De-NOx Technology and Abnormal Combustion Control for a Hydrogen Engine with EGR System
Sep 2020
Publication
The combustion emissions of the hydrogen-fueled engines are very clean but the problems of abnormal combustion and high NOx emissions limit their applications. Nowadays hydrogen engines use exhaust gas recirculation (EGR) technology to control the intensity of premixed combustion and reduce the NOx emissions. This study aims at improving the abnormal combustion and decreasing the NOx emissions of the hydrogen engine by applying a three-dimensional (3D) computational fluid dynamics (CFD) model of a single-cylinder hydrogen-fueled engine equipped with an EGR system. The results indicated that peak in-cylinder pressure continuously increased with the increase of the ignition advance angle and was closer to the top dead center (TDC). In addition the mixture was burned violently near the theoretical air–fuel ratio and the combustion duration was shortened. Moreover the NOx emissions the average pressure and the in-cylinder temperature decreased as the EGR ratio increased. Furthermore increasing the EGR ratio led to an increase in the combustion duration and a decrease in the peak heat release rate. EGR system could delay the spontaneous combustion reaction of the end-gas and reduce the probability of knocking. The pressure rise rate was controlled and the in-cylinder hot spots were reduced by the EGR system which could suppress the occurrence of the pre-ignition in the hydrogen engine.
Techno-economic Analysis of High-Pressure Metal Hydride Compression Systems
Jun 2018
Publication
Traditional high-pressure mechanical compressors account for over half of the car station’s cost have insufficient reliability and are not feasible for a large-scale fuel cell market. An alternative technology employing a two-stage hybrid system based on electrochemical and metal hydride compression technologies represents an excellent alternative to conventional compressors. The high-pressure stage operating at 100–875 bar is based on a metal hydride thermal system. A techno-economic analysis of the metal hydride system is presented and discussed. A model of the metal hydride system was developed integrating a lumped parameter mass and energy balance model with an economic model. A novel metal hydride heat exchanger configuration is also presented based on minichannel heat transfer systems allowing for effective high-pressure compression. Several metal hydrides were analyzed and screened demonstrating that one selected material namely (Ti0.97Zr0.03)1.1Cr1.6Mn0.4 is likely the best candidate material to be employed for high-pressure compressors under the specific conditions. System efficiency and costs were assessed based on the properties of currently available materials at industrial levels. Results show that the system can reach pressures on the order of 875 bar with thermal power provided at approximately 150 ◦C. The system cost is comparable with the current mechanical compressors and can be reduced in several ways as discussed in the paper.
Life Cycle Assessment of Waste-to-hydrogen Systems for Fuel Cell Electric Buses in Glasgow, Scotland
Jun 2022
Publication
Waste-to-hydrogen (WtH) technologies are proposed as a dual-purpose method for simultaneous non-fossil-fuel based hydrogen production and sustainable waste management. This work applied the life cycle assessment approach to evaluate the carbon saving potential of two main WtH technologies (gasification and fermentation) in comparison to the conventional hydrogen production method of steam methane reforming (SMR) powering fuel cell electric buses in Glasgow. It was shown that WtH technologies could reduce CO2-eq emissions per kg H2 by 50–69% as compared to SMR. Gasification treating municipal solid waste and waste wood had global warming potentials of 4.99 and 4.11 kg CO2-eq/kg H2 respectively which were lower than dark fermentation treating wet waste at 6.6 kg CO2-eq/kg H2 and combined dark and photo fermentation at 6.4 kg CO2-eq/kg H2. The distance emissions of WtH-based fuel cell electric bus scenarios were 0.33–0.44 kg CO2-eq/km as compared to 0.89 kg CO2-eq/km for the SMR-based scenario.
Everything About Hydrogen Podcast: Digging into the Mining Industry
Jan 2021
Publication
On this episode of Everything About Hydrogen Jan Klawitter Head of International Policy for Anglo American speaks with Andrew Chris and Patrick about Anglo American's strategy for decarbonizing its mining operations and how they plan to use hydrogen and fuel cell technologies as a key part of their approach.
The podcast can be found on their website
The podcast can be found on their website
Repurposing Fischer-Tropsch and Natural Gas as Bridging Technologies for the Energy Revolution
Jun 2022
Publication
Immediate and widespread changes in energy generation and use are critical to safeguard our future on this planet. However while the necessity of renewable electricity generation is clear the aviation transport and mobility chemical and material sectors are challenging to fully electrify. The age-old Fischer-Tropsch process and natural gas industry could be the bridging solution needed to accelerate the energy revolution in these sectors – temporarily powering obsolete vehicles acting as renewable energy’s battery supporting expansion of hydrogen fuel cell technologies and the agricultural and waste sectors as they struggle to keep up with a full switch to biofuels. Natural gas can be converted into hydrogen synthetic natural gas or heat during periods of low electricity demand and converted back to electricity again when needed. Moving methane through existing networks and converting it to hydrogen on-site at tanking stations also overcomes hydrogen distribution storage problems and infrastructure deficiencies. Useful co-products include carbon nanotubes a valuable engineering material that offset emissions in the carbon nanotube and black industries. Finally excess carbon can be converted back into syngas if desired. This flexibility and the compatibility of natural gas with both existing and future technologies provides a unique opportunity to rapidly decarbonise sectors struggling with complex requirements.
Effect of Carbon Monoxide on Polymer Electrolyte Fuel Cell Performance with a Hydrogen Circulation System
Feb 2022
Publication
The effect of carbon monoxide (CO) on the performance of polymer electrolyte fuel cells (PEFCs) with either a hydrogen circulation system or a hydrogen one-way pass system is investigated and compared. The voltage drop induced by adding 0.2 ppm of CO to the PEFC with the hydrogen circulation system was less than one-tenth of that observed in the PEFC with the hydrogen one-way pass system at 1000 mA cm–2 and a cell temperature of 60 °C. Gas analysis results showed that CO concentration in the hydrogen circulation system was lower than the initially supplied CO concentration. In the hydrogen circulation system permeated oxygen from the cathode should enhance CO oxidation. This should lead to decrease the CO concentration and mitigate the voltage drop in the hydrogen circulation system.
Everything About Hydrogen Podcast: High-temperature Fuel Cells at High Altitudes
Jun 2021
Publication
HyPoint led by its CEO and co-founder Alex Ivanenko is at the cutting edge of the industry's efforts to find zero-emissions aircraft propulsion systems that do not sacrifice speed and power in the name of sustainability. HyPoint is a leading producer of high-temperature PEM fuel cells for aviation applications including for logistic drones air taxis electric vertical takeoff and landing vehicles (eVTOLs) and fixed-wing airplanes. On this episode of the EAH podcast the team speaks with Alex about the incredible pace of development and rapid innovation that he and his colleagues are driving in the hydrogen aviation space and how his company is leading the way in a highly complex and competitive race to decarbonize modern air travel.
The podcast can be found on their website
The podcast can be found on their website
Patterned Membranes for Proton Exchange Membrane Fuel Cells Working at Low Humidity
Jun 2021
Publication
High performing proton exchange membrane fuel cells (PEMFCs) that can operate at low relative humidity is a continuing technical challenge for PEMFC developers. In this work micro-patterned membranes are demonstrated at the cathode side by solution casting techniques using stainless steel moulds with laser-imposed periodic surface structures (LIPSS). Three types of patterns lotus lines and sharklet are investigated for their influence on the PEMFC power performance at varying humidity conditions. The experimental results show that the cathode electrolyte pattern in all cases enhances the fuel cell power performance at 100% relative humidity (RH). However only the sharklet pattern exhibits a significant improvement at 25% RH where a peak power density of 450 mW cm−2 is recorded compared with 150 mW cm−2 of the conventional flat membrane. The improvements are explored based on high-frequency resistance electrochemically active surface area (ECSA) and hydrogen crossover by in situ membrane electrode assembly (MEA) testing.
Decarbonization in Shipping Industry: A Review of Research, Technology Development, and Innovation Proposals
Apr 2021
Publication
This review paper examines the possible pathways and possible technologies available that will help the shipping sector achieve the International Maritime Organization’s (IMO) deep decarbonization targets by 2050. There has been increased interest from important stakeholders regarding deep decarbonization evidenced by market surveys conducted by Shell and Deloitte. However deep decarbonization will require financial incentives and policies at an international and regional level given the maritime sector’s ~3% contribution to green house gas (GHG) emissions. The review paper based on research articles and grey literature discusses technoeconomic problems and/or benefits for technologies that will help the shipping sector achieve the IMO’s targets. The review presents a discussion on the recent literature regarding alternative fuels (nuclear hydrogen ammonia methanol) renewable energy sources (biofuels wind solar) the maturity of technologies (fuel cells internal combustion engines) as well as technical and operational strategies to reduce fuel consumption for new and existing ships (slow steaming cleaning and coating waste heat recovery hull and propeller design). The IMO’s 2050 targets will be achieved via radical technology shift together with the aid of social pressure financial incentives regulatory and legislative reforms at the local regional and international level.
An Optimal Fuzzy Logic-Based Energy Management Strategy for a Fuel Cell/Battery Hybrid Power Unmanned Aerial Vehicle
Feb 2022
Publication
With the development of high-altitude and long-endurance unmanned aerial vehicles (UAVs) optimization of the coordinated energy dispatch of UAVs’ energy management systems has become a key target in the research of electric UAVs. Several different energy management strategies are proposed herein for improving the overall efficiency and fuel economy of fuel cell/battery hybrid electric power systems (HEPS) of UAVs. A rule-based (RB) energy management strategy is designed as a baseline for comparison with other strategies. An energy management strategy (EMS) based on fuzzy logic (FL) for HEPS is presented. Compared with classical rule-based strategies the fuzzy logic control has better robustness to power fluctuations in the UAV. However the proposed FL strategy has an inherent defect: the optimization performances will be determined by the heuristic method and the past experiences of designers to a great extent rather than a specific cost function of the algorithm itself. Thus the paper puts forward an improved fuzzy logic-based strategy that uses particle swarm optimization (PSO) to track the optimal thresholds of membership functions and the equivalent hydrogen consumption minimization is considered as the objective function. Using a typical 30 min UAV mission profile all the proposed EMS were verified by simulations and rapid controller prototype (RCP) experiments. Comprehensive comparisons and analysis are presented by evaluating hydrogen consumption system efficiency and voltage bus stability. The results show that the PSO-FL algorithm can further improve fuel economy and achieve superior overall dynamic performance when controlling a UAV’s fuel-cell powertrain.
CO2 Emissions Reduction Measures for RO-RO Vessels on Non-Profitable Coastal Liner Passenger Transport
Jun 2021
Publication
Reducing CO2 emissions from ships in unprofitable coastline transport using electricity and hydrogen has potential for island development to improve transport and protect biodiversity and nature. New technologies are a challenge for shipping companies and their introduction should be accompanied by a system of state aid for alternative energy sources. The energy requirements of an electric ferry for a route of up to 6 km were considered as well as the amount of hydrogen needed to generate the electricity required to charge the ferry batteries to enable a state aid scheme. For a daily ferry operation a specific fuel consumption of 60.6 g/kWh of liquid hydrogen is required in the system fuel cell with a total of 342.69 kg of hydrogen. Compared to marine diesel the use of electric ferries leads to a reduction of CO2 emissions by up to 90% including significantly lower NOx Sox and particulate matter (PM) emissions and operating costs by up to 80%.
Potentials of Hydrogen Technologies for Sustainable Factory Systems
Mar 2021
Publication
The industrial sector is the world’s second largest emitter of greenhouse gases hence a methodology for decarbonizing factory systems is crucial for achieving global climate goals. Hydrogen is an important medium for the transition towards carbon neutral factories due to its broad applicability within the factory including its use in electricity and heat generation and as a process gas or fuel. One of the main challenges is the identification of economically and environmentally suitable design scenarios such as for the entire value chain for hydrogen generation and application. For example the infrastructure for renewable electricity hydrogen generation hydrogen conversion (e.g. into synthetic fuels) storage and transport systems as well as application in the factory. Due to the high volatility of energy generation and the related dynamic interdependencies within a factory system a valid technical economic and environmental evaluation of benefits induced by hydrogen technologies can only be achieved using digital factory models. In this paper we present a framework to integrate hydrogen technologies into factory systems. This enables decision makers to identify promising measures according to their expected impact and collect data for appropriate factory modelling. Furthermore a concept for factory modelling and simulation is presented and demonstrated in a case study from the electronics industry assessing the use of hydrogen for decentralized power and heat generation.
Towards a CO2-neutral Steel Industry: Justice Aspects of CO2 Capture and Storage, Biomass- and Green Hydrogen-based Emission Reductions
Apr 2022
Publication
A rapid transition towards a CO2-neutral steel industry is required to limit climate change. Such a transition raises questions of justice as it entails positive and negative impacts unevenly distributed across societal stakeholders. To enable stakeholders to address such concerns this paper assesses the justice implications of three options that reduce emissions: CO2 capture and storage (CCS) on steel (up to 70%) bio-based steelmaking (up to 50%) and green hydrogen-based steel production (up to 100%). We select justice indicators from the energy climate labour and environmental justice literature and assess these indicators qualitatively for each of the technological routes based on literature and desk research. We find context-dependent differences in justness between the different technological routes. The impact on stakeholders varies across regions. There are justice concerns for local communities because of economic dependence on and environmental impact of the industry. Communities elsewhere are impacted through the siting of infrastructure and feedstock production. CCS and bio-based steelmaking routes can help retain industry and associated economic benefits on location while hydrogen-based steelmaking may deal better with environmental concerns. We conclude that besides techno-economic and environmental information transparency on sector-specific justice implications of transforming steel industries is essential for decision-making on technological routes
Deep Decarbonisation Pathways for Scottish Industries: Research Report
Dec 2020
Publication
The following report is a research piece outlining the potential pathways for decarbonisation of Scottish Industries. Two main pathways are considered hydrogen and electrification with both resulting in similar costs and levels of carbon reduction.
Hydrogen for Heating? Decarbonization Options for Households in the United Kingdom in 2050
Dec 2020
Publication
The heating sector makes up 10% of the United Kingdom’s carbon footprint and residential homes account for a majority of demand. At present central heating from a natural gas-fired boiler is the most common system in the UK but low or zero-carbon hydrogen and renewable electricity are the two primary energy replacement options to reduce the carbon footprint. An important consideration is how using either energy source would affect heating costs. This assessment projects the costs for a typical single-family UK household and climate performance in 2050 using low-GHG or GHG-neutral hydrogen renewable electricity or a combination of both. The cost of using boilers or fuel cells in 2050 with two types of hydrogen are assessed: produced via steam-methane reforming (SMR) combined with carbon capture and storage (CCS) and electrolysis using zero-carbon renewable electricity. The costs of heat pumps the most promising heating technology for the direct use of renewable electricity are also assessed in two scenarios: a heat pump only and a hybrid heat pump with an auxiliary hydrogen boiler.
You can download this document from the International Council On Clean Transportation website linked here
You can download this document from the International Council On Clean Transportation website linked here
The Influence of Degradation Effects in Proton Exchange Membrane Fuel Cells on Life Cycle Assessment Modelling and Environmental Impact Indicators
Apr 2022
Publication
Although proton exchange membrane fuel cell (PEMFC) systems are expected to have lower environmental impacts in the operational phase compared to conventional energy conversion systems there are still certain economic operational and environmental setbacks. Durability under a wide range of operating conditions presents a challenge because degradation processes affect the PEMFC efficiency. Typically life cycle assessment (LCA) of PEMFC systems do not include performance degradation. Thus a novel semi-empirical PEMFC model is developed which includes degradation effects caused by different operational regimes (dynamic and steady-state). The model is integrated into LCA through life cycle inventory (LCI) to achieve a more realistic and accurate evaluation of environmental impacts. Verification of the model clearly showed that the use of existing LCI models underestimates the environmental impacts. This is especially evident when green hydrogen is used in PEMFC operational phase where manufacturing phase and maintenance (stack replacements) become more influential. Input parameters of the model can be modified to reflect technological improvements (e.g. platinum loading or durability) and evaluate the effects of future scenarios.
Global Energy Transformation: A Roadmap to 2050
Apr 2019
Publication
Dolf Gielen,
Ricardo Gorini,
Nicholas Wagner,
Rodrigo Leme,
Laura Gutierrez,
Gayathri Prakash,
Elisa Asmelash,
Luis Janeiro,
Giacomo Gallina,
Guilia Vale,
Lorenzo Sani,
Xavier Garcia Casals,
Rabia Ferroukhi,
Bishal Parajuli,
Jinlei Feng,
Eva Alexandri,
Unnada Chewpreecha,
Mary Goldman,
Sophie Heald,
Jon Stenning,
Hector Pollitt,
Celia García-Baños and
Michael Renner
Increased use of renewable energy combined with intensified electrification could prove decisive for the world to meet key climate goals by 2050. This study from the International Renewable Energy Agency (IRENA) highlights immediately deployable cost-effective options for countries to fulfil climate commitments and limit the rise of global temperatures. The envisaged energy transformation would also reduce net costs and bring significant socio-economic benefits such as increased economic growth job creation and overall welfare gains.<br/>The report – the second under the Global Energy Transformation banner – expands IRENA’s comprehensive roadmap which examines technology pathways and policy implications to ensure a sustainable energy future. Ramping up electricity to over half of the global energy mix (up from one-fifth currently) in combination with renewables would reduce the use of fossil fuels responsible for most greenhouse-gas emissions.
Scottish Hydrogen Assessment
Dec 2020
Publication
During 2020 the Scottish Government in partnership with Highlands and Islands Enterprise and Scottish Enterprise commissioned Arup and E4Tech to carry out a hydrogen assessment to deepen our evidence base in order to inform our policies on hydrogen going forward. The assessment aims to investigate how and where hydrogen may fit within the evolving energy system technically geographically and economically. To assist in this consideration a key part of the Hydrogen Assessment is the development of distinct viable scenarios for hydrogen deployment in Scotland and the economic assessment of those scenarios.<br/>From our assessment it is clear that hydrogen is not just an energy and emissions reduction opportunity; it could also have an important role in generating new economic opportunities in Scotland. The assessment forms an important part of the evidence base that informed the development of the Hydrogen Policy Statement.
Scottish Offshore Wind to Green Hydrogen Opportunity Assessment
Dec 2020
Publication
Initial assessment of Scotland’s opportunity to produce green hydrogen from offshore wind
Summary of Key Findings
Summary of Key Findings
- Scotland has an abundant offshore wind resource that has the potential to be a vital component in our net zero transition. If used to produce green hydrogen offshore wind can help abate the emissions of historically challenging sectors such as heating transport and industry.
- The production of green hydrogen from offshore wind can help overcome Scotland’s grid constraints and unlock a massive clean power generation resource creating a clean fuel for Scottish industry and households and a highly valuable commodity to supply rapidly growing UK and European markets.
- The primary export markets for Scottish green hydrogen are expected to be in Northern Europe (Germany Netherlands & Belgium). Strong competition to supply these markets is expected to come from green hydrogen produced from solar energy in Southern Europe and North Africa.
- Falling wind and electrolyser costs will enable green hydrogen production to be cost-competitive in the key transport and heat sectors by 2032. Strategic investment in hydrogen transportation and storage is essential to unlocking the economic opportunity for Scotland.
- Xodus’ analysis supports a long-term outlook of LCoH falling towards £2/kg with an estimated reference cost of £2.3 /kg in 2032 for hydrogen delivered to shore.
- Scotland has extensive port and pipeline infrastructure that can be repurposed for hydrogen export to the rest of UK and to Europe. Pipelines from the ‘90s are optimal for this purpose as they are likely to retain acceptable mechanical integrity and have a metallurgy better suited to hydrogen service. A more detailed assessment of export options should be performed to provide a firm foundation for early commercial green hydrogen projects.
- There is considerable hydrogen supply chain overlap with elements of parallel sectors most notably the oil and gas offshore wind and subsea engineering sectors. Scotland already has a mature hydrocarbon supply chain which is engaged in supporting green hydrogen. However a steady pipeline of early projects supported by a clear financeable route to market will be needed to secure this supply chain capability through to widescale commercial deployment.
- There are gaps in the Scottish supply chain in the areas of design manufacture and maintenance of hydrogen production storage and transportation systems. Support including apprenticeships will be needed to develop indigenous skills and capabilities in these areas.
- The development of green hydrogen from offshore wind has the potential to create high value jobs a significant proportion which are likely to be in remote rural/coastal communities located close to offshore wind resources. These can serve as an avenue for workers to redeploy and develop skills learned from oil and gas in line with Just Transition principles.
World Energy Transitions Outlook: 1.5°C Pathway
Mar 2021
Publication
Dolf Gielen,
Ricardo Gorini,
Rodrigo Leme,
Gayathri Prakash,
Nicholas Wagner,
Luis Janeiro,
Sean Collins,
Maisarah Kadir,
Elisa Asmelash,
Rabia Ferroukhi,
Ulrike Lehr,
Xavier Garcia Casals,
Diala Hawila,
Bishal Parajuli,
Elizabeth Press,
Paul Durrant,
Seungwoo Kang,
Martina Lyons,
Carlos Ruiz,
Trish Mkutchwa,
Emanuele Taibi,
Herib Blanco,
Francisco Boshell,
Arina Anise,
Elena Ocenic,
Roland Roesch,
Gabriel Castellanos,
Gayathri Nair,
Barbara Jinks,
Asami Miketa,
Michael Taylor,
Costanza Strinati,
Michael Renner and
Deger Saygin
The World Energy Transitions Outlook preview outlines a pathway for the world to achieve the Paris Agreement goals and halt the pace of climate change by transforming the global energy landscape. This preview presents options to limit global temperature rise to 1.5°C and bring CO2 emissions closer to net zero by mid-century offering high-level insights on technology choices investment needs and the socio-economic contexts of achieving a sustainable resilient and inclusive energy future.
Meeting CO2 reduction targets by 2050 will require a combination of: technology and innovation to advance the energy transition and improve carbon management; supportive and proactive policies; associated job creation and socio-economic improvements; and international co-operation to guarantee energy availability and access.
Among key findings:
This preview identifies opportunities to support informed policy and decision making to establish a new global energy system. Following this preview and aligned with the UN High-Level Dialogue process the International Renewable Energy Agency (IRENA) will release the full report which will provide a comprehensive vision and accompanying policy measures for the transition.
Meeting CO2 reduction targets by 2050 will require a combination of: technology and innovation to advance the energy transition and improve carbon management; supportive and proactive policies; associated job creation and socio-economic improvements; and international co-operation to guarantee energy availability and access.
Among key findings:
- Proven technologies for a net-zero energy system already largely exist today. Renewable power green hydrogen and modern bioenergy will dominate the world of energy of the future.
- A combination of technologies is needed to keep us on a 1.5°C climate pathway. These include increasingly efficient energy production to ensure economic growth; decarbonised power systems that are dominated by renewables; increased use of electricity in buildings industry and transport to support decarbonisation; expanded production and use of green hydrogen synthetic fuels and feedstocks; and targeted use of sustainably sourced biomass.
- In anticipation of the coming energy transition financial markets and investors are already directing capital away from fossil fuels and towards other energy technologies including renewables.
- Energy transition investment will have to increase by 30% over planned investment to a total of USD 131 trillion between now and 2050 corresponding to USD 4.4 trillion on average every year.
- National social and economic policies will play fundamental roles in delivering the energy transition at the speed required to restrict global warming to 1.5°C.
This preview identifies opportunities to support informed policy and decision making to establish a new global energy system. Following this preview and aligned with the UN High-Level Dialogue process the International Renewable Energy Agency (IRENA) will release the full report which will provide a comprehensive vision and accompanying policy measures for the transition.
Power-to-liquid via Synthesis of Methanol, DME or Fischer–Tropsch-fuels: A Review
Jul 2020
Publication
The conversion of H2 and CO2 to liquid fuels via Power-to-Liquid (PtL) processes is gaining attention. With their higher energy densities compared to gases the use of synthetic liquid fuels is particularly interesting in hard-to-abate sectors for which decarbonisation is difficult. However PtL poses new challenges for the synthesis: away from syngas-based continuously run large-scale plants towards more flexible small-scale concepts with direct CO2-utilisation. This review provides an overview of state of the art synthesis technologies as well as current developments and pilot plants for the most prominent PtL routes for methanol DME and Fischer–Tropsch-fuels. It should serve as a benchmark for future concepts guide researchers in their process development and allow a technological evaluation of alternative reactor designs. In the case of power-to-methanol and power-to-FT-fuels several pilot plants have been realised and the first commercial scale plants are planned or already in operation. In comparison power-to-DME is much less investigated and in an earlier stage of development. For methanol the direct CO2 hydrogenation offers advantages through less by-product formation and lower heat development. However increased water formation and lower equilibrium conversion necessitate new catalysts and reactor designs. While DME synthesis offers benefits with regards to energy efficiency operational experience from laboratory tests and pilot plants is still missing. Furthermore four major process routes for power-to-DME are possible requiring additional research to determine the optimal concept. In the case of Fischer–Tropsch synthesis catalysts for direct CO2 utilisation are still in an early stage. Consequently today’s Fischer–Tropsch-based PtL requires a shift to syngas benefiting from advances in co-electrolysis and reverse water-gas shift reactor design.
Hydrogen Station Technology Development Review Through Patent Analysis
May 2018
Publication
This study is a review of hydrogen station patents using the Derwent Innovation system and also a secondary screening. This was undertaken by the researchers to better understand and identify hydrogen station trends. The review focuses on analyzing the developing trends of patent technologies associated with a hydrogen station. The results of the review indicated that the countries with the major distribution of patents were Japan China the USA and Europe. Japan is leading the developmental trajectory of hydrogen stations. The results of the analysis found the leading developers of these patented technologies are Kobe Steel Nippon Oil Toyota and Honda. Other active patent developers analyzed include Linde Hyundai and Texaco. The review concludes with a suggestion that using a patent analysis methodology is a good starting point to identify evaluate and measure the trend in hydrogen station commercial development.
Decarbonising Ships, Planes and Trucks: An Analysis of Suitable Low-carbon Fuels for the Maritime, Aviation and Haulage Sectors
Jan 2021
Publication
The high environmental impacts of transport mean that there is an increasing interest in utilising low-carbon alternative energy carriers and powertrains within the sector. While electricity has been mooted as the energy carrier of choice for passenger vehicles as the mass and range of the vehicle increases electrification becomes more difficult. This paper reviews the shipping aviation and haulage sectors and a range of low-carbon energy carriers (electricity biofuels hydrogen and electro fuels) that can be used to decarbonise them. Energy carriers were assessed based on their energy density specific energy cost lifecycle greenhouse gas emissions and land-use. In terms of haulage current battery electric vehicles may be technically feasible however the specific energy of current battery technology reduces the payload capacity and range when compared to diesel. To alleviate these issues biomethane represents a mature technology with potential co-benefits while hydrogen is close to competitiveness but requires significant infrastructure. Energy density issues preclude the use of batteries in shipping which requires energy dense liquids or compressed gaseous fuels that allow for retrofits/current hull designs with methanol being particularly appropriate here. Future shipping may be achieved with ammonia or hydrogen but hull design will need to be changed significantly. Regulations and aircraft design mean that commercial aviation is dependant on drop-in jet fuels for the foreseeable future with power-to-liquid fuels being deemed the most suitable option due to the scales required. Fuel costs and a lack of refuelling infrastructure were identified as key barriers facing the uptake of alternatives with policy and financial incentives required to encourage the uptake of low-carbon fuels.
Polymer Electrolyte Membrane Fuel Cell and Hydrogen Station Networks for Automobiles: Status, Technology, and Perspectives
Feb 2021
Publication
The U.S. transportation sector accounts for 37% of total energy consumption. Automobiles are a primary application of polymer electrolyte membrane (PEM) fuel cells which operate under low temperature and high efficiency to reduce fossil fuel consumption and CO2 emissions. Using hydrogen fuel PEM fuel cells can reach a practical efficiency as high as 65% with water as the only byproduct. Almost all the major automakers are involved in fuel cell electric vehicle (FCEV) development. Toyota and Hyundai introduced FCEVs (the Mirai and NEXO respectively) to consumers in recent years with a driving range between 312 and 402 miles and cold-start capacity from -30 °C. About 50 fuel cell electric buses (FCEB) are operating in California and most of them have achieved the durability target i.e. 25000 h in real-world driving conditions. As of September 2020 over 8573 FCEVs have been sold or leased in the U.S. More than 3521 FCEVs and 22 FCEBs have been sold or leased in Japan as of September 2019. An extensive hydrogen station network is required for the successful deployment of FCEVs and FCEBs. The U.S. currently has over 44 hydrogen fuelling stations (HFSs) nearly all located in California. Europe has over 139 HFSs with ~1500 more stations planned by 2025. This review has three primary objectives: 1) to present the current status of FCEV/FCEB commercialization and HFS development; 2) to describe the PEM fuel cell research/development in automobile applications and the significance of HFS networks; and 3) to outline major challenges and opportunities.
The Role of Hydrogen and Fuel Cells in the Global Energy System
Dec 2018
Publication
Hydrogen technologies have experienced cycles of excessive expectations followed by disillusion. Nonetheless a growing body of evidence suggests these technologies form an attractive option for the deep decarbonisation of global energy systems and that recent improvements in their cost and performance point towards economic viability as well. This paper is a comprehensive review of the potential role that hydrogen could play in the provision of electricity heat industry transport and energy storage in a low-carbon energy system and an assessment of the status of hydrogen in being able to fulfil that potential. The picture that emerges is one of qualified promise: hydrogen is well established in certain niches such as forklift trucks while mainstream applications are now forthcoming. Hydrogen vehicles are available commercially in several countries and 225 000 fuel cell home heating systems have been sold. This represents a step change from the situation of only five years ago. This review shows that challenges around cost and performance remain and considerable improvements are still required for hydrogen to become truly competitive. But such competitiveness in the medium-term future no longer seems an unrealistic prospect which fully justifies the growing interest and policy support for these technologies around the world.
Influence of the Gas Injector Configuration on the Temperature Evolution During Refueling of On-board Hydrogen Tanks
Jul 2016
Publication
In this article we show a refuelling strategy analysis using different injector configurations to refuel a 70 MPa composite reinforced type 4 tank. The gas has been injected through single openings of different diameters (3 mm 6 mm and 10 mm) and alternatively through multiple small holes (4 × 3 mm). For each injector configuration slow (12 min) and faster (3 min) fillings have been performed. The gas temperature has been measured at different positions inside the tank as well as the temperatures of the wall materials at various locations: on the external surface and at the interface between the liner and the fiber reinforced composite. In general the larger the injector diameter and the slower the filling the higher the chance that the gas develops vertical temperature gradients (a so-called gas temperature stratification) resulting in higher than average temperatures near the top of the tank and lower than average at its bottom. While the single 3 mm opening injector causes homogeneous gas temperatures for both filling speeds both the 6 mm and 10 mm opening injectors induce gas temperature stratification during the 12 min fillings. The injector with multiple holes has an area comparable to the 6 mm single opening injector: in general this more complex geometry tends to limit the inhomogeneity of gas temperatures during slow fillings. When gas temperature stratification develops the wall materials temperature is also locally affected. This results in a higher than average temperature at the top of the tank and higher the slower the filling.
Trace Level Analysis of Reactive ISO 14687 Impurities in Hydrogen Fuel Using Laser-based Spectroscopic Detection Methods
Oct 2020
Publication
Hydrogen fuelled vehicles can play a key role in the decarbonisation of transport and reducing emissions. To ensure the durability of fuel cells a specification has been developed (ISO 14687) setting upper limits to the amount fraction of a series of impurities. Demonstrating conformity with this standard requires demonstrating by measurement that the actual levels of the impurities are below the thresholds. Currently the industry is unable to do so for measurement standards and sensitive dedicated analytical methods are lacking. In this work we report on the development of such measurement standards and methods for four reactive components: formaldehyde formic acid hydrogen chloride and hydrogen fluoride. The primary measurement standard is based on permeation and the analytical methods on highly sensitive and selective laser-based spectroscopic techniques. Relative expanded uncertainties at the ISO 14687 threshold level in hydrogen of 4% (formaldehyde) 8% (formic acid) 5% (hydrogen chloride) and 8% (hydrogen fluoride) have been achieved.
A Portfolio of Power-Trains for Europe- A Fact Based Analysis
Nov 2010
Publication
This report is prepared by thirty of the largest global car manufacturers oil and gas companies utilities equipment manufacturers NGOs governmental and clean energy organisations with the collaboration of the Fuel Cells and Hydrogen Joint Undertaking.<br/>The analysis compares the economics sustainability and performance of the vehicles and infrastructures needed to reach the 80% decarbonisation goal set by the<br/>European Union and is an unprecedented effort from industry and other stakeholders to analyse the role of the various new car-types in meeting this objective on the basis of proprietary industrial data.
Leakage-type-based Analysis of Accidents Involving Hydrogen Fueling Stations in Japan and USA
Aug 2016
Publication
To identify the safety issues associated with hydrogen fuelling stations incidents at such stations in Japan and the USA were analyzed considering the regulations in these countries. Leakage due to the damage and fracture of main bodies of apparatuses and pipes in Japan and the USA is mainly caused by design error that is poorly planned fatigue. Considering the present incidents in these countries adequate consideration of the usage environment in the design is very important. Leakage from flanges valves and seals in Japan is mainly caused by screw joints. If welded joints are to be used in hydrogen fuelling stations in Japan strength data for welded parts should be obtained and pipe thicknesses should be reduced. Leakage due to other factors e.g. external impact in Japan and the USA is mainly caused by human error. To realize self-serviced hydrogen fuelling stations safety measures should be developed to prevent human error by fuel cell vehicle users.
Clean Growth- Transforming Heating Overview of Current Evidence
Dec 2018
Publication
Government has reviewed the evidence base on options for achieving long term heat decarbonisation. This report provides an overview of the key issues arising from our review and seeks to:
- highlight the different characteristics of the main alternative sources of low carbon heat and the approaches to achieving transformational change
- set out strategically important issues ‘strategic inferences’ which we have drawn from the evidence available to help focus the development of our long term policy framework
- identify areas that require further exploration to inform the development of a new long term policy framework for heat
- better understanding of the different options available for decarbonising heating
- a clearer common agenda across industry academia and the public sector to ensure effort and resources are effectively and efficiently applied to long term heat decarbonisation issues
- the strategic inferences identified
- the priority areas requiring further development
- any important omissions
- the parties best placed to deliver in these areas
- opportunities for enhancing co-ordination
A Study on the Joule-Thomson Effect of During Filling Hydrogen in High Pressure Tank
Dec 2022
Publication
With the development of the hydrogen fuel cell automobile industry higher requirements are put forward for the construction of hydrogen energy infrastructure the matching of parameters and the control strategy of hydrogen filling rate in the hydrogenation process of hydrogenation station. Fuel for hydrogen fuel cell vehicles comes from hydrogen refueling stations. At present the technological difficulty of hydrogenation is mainly reflected in the balanced treatment of reducing the temperature rise of hydrogen and shortening the filling time during the fast filling process. The Joule-Thomson (JT) effect occurs when high-pressure hydrogen gas passes through the valve assembly which may lead to an increase in hydrogen temperature. The JT effect is generally reflected by the JT coefficient. According to the high pressure hydrogen in the pressure reducing valve the corresponding JT coefficients were calculated by using the VDW equation RK equation SRK equation and PR equation and the expression of JT effect temperature rise was deduced which revealed the hydrogen temperature variation law in the process of reducing pressure. Make clear the relationship between charging parameters and temperature rise in the process of decompression; the flow and thermal characteristics of hydrogen in the process of decompression are revealed. This study provides basic support for experts to achieve throttling optimization of related pressure control system in hydrogen industry
Zero-Emission Pathway for the Global Chemical and Petrochemical Sector
Jun 2021
Publication
The chemical and petrochemical sector relies on fossil fuels and feedstocks and is a major source of carbon dioxide (CO2 ) emissions. The techno-economic potential of 20 decarbonisation options is assessed. While previous analyses focus on the production processes this analysis covers the full product life cycle CO2 emissions. The analysis elaborates the carbon accounting complexity that results from the non-energy use of fossil fuels and highlights the importance of strategies that consider the carbon stored in synthetic organic products—an aspect that warrants more attention in long-term energy scenarios and strategies. Average mitigation costs in the sector would amount to 64 United States dollars (USD) per tonne of CO2 for full decarbonisation in 2050. The rapidly declining renewables cost is one main cause for this low-cost estimate. Renewable energy supply solutions in combination with electrification account for 40% of total emissions reductions. Annual biomass use grows to 1.3 gigatonnes; green hydrogen electrolyser capacity grows to 2435 gigawatts and recycling rates increase six-fold while product demand is reduced by a third compared to the reference case. CO2 capture storage and use equals 30% of the total decarbonisation effort (1.49 gigatonnes per year) where about one-third of the captured CO2 is of biogenic origin. Circular economy concepts including recycling account for 16% while energy efficiency accounts for 12% of the decarbonisation needed. Achieving full decarbonisation in this sector will increase energy and feedstock costs by more than 35%. The analysis shows the importance of renewables-based solutions accounting for more than half of the total emissions reduction potential which was higher than previous estimates.
Micro Gas Turbine Role in Distributed Generation with Renewable Energy Sources
Jan 2023
Publication
To become sustainable the production of electricity has been oriented towards the adoption of local and renewable sources. Distributed electric and thermal energy generation is more suitable to avoid any possible waste and the Micro Gas Turbine (MGT) can play a key role in this scenario. Due to the intrinsic properties and the high flexibility of operation of this energy conversion system the exploitation of alternative fuels and the integration of the MGT itself with other energy conversion systems (solar field ORC fuel cells) represent one of the most effective strategies to achieve higher conversion efficiencies and to reduce emissions from power systems. The present work aims to review the results obtained by the researchers in the last years. The different technologies are analyzed in detail both separately and under a more complete view considering two or more solutions embedded in micro-grid configurations.
Energy Management of Heavy-duty Fuel Cell Vehicles in Real-world Driving Scenarios: Robust Design of Strategies to Maximize the Hydrogen Economy and System Lifetime
Feb 2021
Publication
Energy management is a critical issue for the advancement of fuel cell vehicles because it significantly influences their hydrogen economy and lifetime. This paper offers a comprehensive investigation of the energy management of heavy-duty fuel cell vehicles for road freight transportation. An important and unique contribution of this study is the development of an extensive and realistic representation of the vehicle operation which includes 1750 hours of real-world driving data and variable truck loading conditions. This framework is used to analyze the potential benefits and drawbacks of heuristic optimal and predictive energy management strategies to maximize the hydrogen economy and system lifetime of fuel cell vehicles for road freight transportation. In particular the statistical evaluation of the effectiveness and robustness of the simulation results proves that it is necessary to consider numerous and realistic driving scenarios to validate energy management strategies and obtain a robust design. This paper shows that the hydrogen economy can be maximized as an individual target using the available driving information achieving a negligible deviation from the theoretical limit. Furthermore this study establishes that heuristic and optimal strategies can significantly reduce fuel cell transients to improve the system lifetime while retaining high hydrogen economies. Finally this investigation reveals the potential benefits of predictive energy management strategies for the multi-objective optimization of the hydrogen economy and system lifetime.
Modelling and Designing Cryogenic Hydrogen Tanks for Future Aircraft Applications
Jan 2018
Publication
In the near future the challenges to reduce the economic and social dependency on fossil fuels must be faced increasingly. A sustainable and efficient energy supply based on renewable energies enables large-scale applications of electro-fuels for e.g. the transport sector. The high gravimetric energy density makes liquefied hydrogen a reasonable candidate for energy storage in a light-weight application such as aviation. Current aircraft structures are designed to accommodate jet fuel and gas turbines allowing a limited retrofitting only. New designs such as the blended-wing-body enable a more flexible integration of new storage technologies and energy converters e.g. cryogenic hydrogen tanks and fuel cells. Against this background a tank-design model is formulated which considers geometrical mechanical and thermal aspects as well as specific mission profiles while considering a power supply by a fuel cell. This design approach enables the determination of required tank mass and storage density respectively. A new evaluation value is defined including the vented hydrogen mass throughout the flight enabling more transparent insights on mass shares. Subsequently a systematic approach in tank partitioning leads to associated compromises regarding the tank weight. The analysis shows that cryogenic hydrogen tanks are highly competitive with kerosene tanks in terms of overall mass which is further improved by the use of a fuel cell.
Fuel Cell Power Systems for Maritime Applications: Progress and Perspectives
Jan 2021
Publication
Fuel cells as clean power sources are very attractive for the maritime sector which is committed to sustainability and reducing greenhouse gas and atmospheric pollutant emissions from ships. This paper presents a technological review on fuel cell power systems for maritime applications from the past two decades. The available fuels including hydrogen ammonia renewable methane and methanol for fuel cells under the context of sustainable maritime transportation and their pre-processing technologies are analyzed. Proton exchange membrane molten carbonate and solid oxide fuel cells are found to be the most promising options for maritime applications once energy efficiency power capacity and sensitivity to fuel impurities are considered. The types layouts and characteristics of fuel cell modules are summarized based on the existing applications in particular industrial or residential sectors. The various research and demonstration projects of fuel cell power systems in the maritime industry are reviewed and the challenges with regard to power capacity safety reliability durability operability and costs are analyzed. Currently power capacity costs and lifetime of the fuel cell stack are the primary barriers. Coupling with batteries modularization mass production and optimized operating and control strategies are all important pathways to improve the performance of fuel cell power systems.
Ultrasonic-assisted Catalytic Transfer Hydrogenation for Upgrading Pyrolysis-oil
Feb 2021
Publication
Recent interest in biomass-based fuel blendstocks and chemical compounds has stimulated research efforts on conversion and upgrading pathways which are considered as critical commercialization drivers. Existing pre-/post-conversion pathways are energy intense (e.g. pyrolysis and hydrogenation) and economically unsustainable thus more efficient process solutions can result in supporting the renewable fuels and green chemicals industry. This study proposes a process including biomass conversion and bio-oil upgrading using mixed fast and slow pyrolysis conversion pathway as well as sono-catalytic transfer hydrogenation (SCTH) treatment process. The proposed SCTH treatment employs ammonium formate as a hydrogen transfer additive and palladium supported on carbon as the catalyst. Utilizing SCTH bio-oil molecular bonds were broken and restructured via the phenomena of cavitation rarefaction and hydrogenation with the resulting product composition investigated using ultimate analysis and spectroscopy. Additionally an in-line characterization approach is proposed using near-infrared spectroscopy calibrated by multivariate analysis and modelling. The results indicate the potentiality of ultrasonic cavitation catalytic transfer hydrogenation and SCTH for incorporating hydrogen into the organic phase of bio-oil. It is concluded that the integration of pyrolysis with SCTH can improve bio-oil for enabling the production of fuel blendstocks and chemical compounds from lignocellulosic biomass.
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