Applications & Pathways
Technology Transfer from Fuel Processing for Fuel Cells to Fuel Synthesis from Hydrogen and Carbon Dioxide
Aug 2023
Publication
Improving the energy efficiency of existing technologies such as the on-board power supply of trucks ships and aircraft is an important endeavor for reducing primary energy consumption. The approach consists of using fuel cell technology in conjunction with hydrogen production from liquid fuels. However the energy transition with the goal of complete climate-neutrality requires technological changes in the use of hydrogen produced from renewable energy via electrolysis. Synthetic fuels are an important building block for drive systems that will continue to require liquid energy carriers in the future due to their range. This study addresses the question of whether technical devices that were developed for the generation of hydrogen from liquid fuels for fuel cells to generate electricity are now suitable for the reverse process chain or can play an important role in it. The new process chain produces hydrogen from sustainable electricity combining it with carbon dioxide to create a synthetic liquid fuel.
Energy Consumption and Saved Emissions of a Hydrogen Power System for Ultralight Aviation: A Case Study
Jul 2024
Publication
The growing concern about climate change and the contemporary increase in mobility requirements call for faster cheaper safer and cleaner means of transportation. The retrofitting of fossil-fueled piston engine ultralight aerial vehicles to hydrogen power systems is an option recently proposed in this direction. The goal of this investigation is a comparative analysis of the environmental impact of conventional and hydrogen-based propulsive systems. As a case study a hybrid electric configuration consisting of a fuel cell with a nominal power of about 30 kW a 6 kWh LFP battery and a pressurized hydrogen vessel is proposed to replace a piston prop configuration for an ultralight aerial vehicle. Both power systems are modeled with a backward approach that allows the efficiency of the main components to be evaluated based on the load and altitude at every moment of the flight with a time step of 1 s. A typical 90 min flight mission is considered for the comparative analysis which is performed in terms of direct and indirect emissions of carbon dioxide water and pollutant substances. For the hydrogen-based configuration two possible strategies are adopted for the use of the battery: charge sustaining and charge depleting. Moreover the effect of the altitude on the parasitic power of the fuel cell compressor and consequently on the net efficiency of the fuel cell system is taken into account. The results showed that even if the use of hydrogen confines the direct environmental impact to the emission of water (in a similar quantity to the fossil fuel case) the indirect emissions associated with the production transportation and delivery of hydrogen and electricity compromise the desired achievement of pollutant-free propulsion in terms of equivalent emissions of CO2 and VOCs if hydrogen is obtained from natural gas reforming. However in the case of green hydrogen from electrolysis with wind energy the total (direct and indirect) emissions of CO2 can be reduced up to 1/5 of the fossil fuel case. The proposed configuration has the additional advantage of eliminating the problem of lead which is used as an additive in the AVGAS 100LL.
Design Investigation of Potential Long-Range Hydrogen Combustion Blended Wing Body Aircraft with Future Technologies
Jun 2023
Publication
Present work investigates the potential of a long-range commercial blended wing body configuration powered by hydrogen combustion engines with future airframe and propulsion technologies. Future technologies include advanced materials load alleviation techniques boundary layer ingestion and ultra-high bypass ratio engines. The hydrogen combustion configuration was compared to the configuration powered by kerosene with respect to geometric properties performance characteristics energy demand equivalent CO2 emissions and Direct Operating Costs. In addition technology sensitivity studies were performed to assess the potential influence of each technology on the configuration. A multi-fidelity sizing methodology using low- and mid-fidelity methods for rapid configuration sizing was created to assess the configuration and perform robust analyses and multi-disciplinary optimizations. To assess potential uncertainties of the fidelity of aerodynamic analysis tools high-fidelity aerodynamic analysis and optimization framework MACHAero was used for additional verification. Comparison of hydrogen and kerosene blended wing body aircraft showed a potential reduction of equivalent CO2 emission by 15% and 81% for blue and green hydrogen compared to the kerosene blended wing body and by 44% and 88% with respect to a conventional B777-300ER aircraft. Advancements in future technologies also significantly affect the geometric layout of aircraft. Boundary layer ingestion and ultra-high bypass ratio engines demonstrated the highest potential for fuel reduction although both technologies conflict with each other. However operating costs of hydrogen aircraft could establish a significant problem if pessimistic and base hydrogen price scenarios are achieved for blue and green hydrogen respectively. Finally configurational problems featured by classical blended wing body aircraft are magnified for the hydrogen case due to the significant volume requirements to store hydrogen fuel.
Operating Characteristics Analysis and Capacity Configuration Optimization of Wind-Solar-Hydrogen Hybrid Multi-energy Complementary System
Dec 2023
Publication
Wind and solar energy are the important renewable energy sources while their inherent natures of random and intermittent also exert negative effect on the electrical grid connection. As one of multiple energy complementary route by adopting the electrolysis technology the wind-solar-hydrogen hybrid system contributes to improving green power utilization and reducing its fluctuation. Therefore the moving average method and the hybrid energy storage module are proposed which can smooth the wind-solar power generation and enhance the system energy management. Moreover the optimization of system capacity configuration and the sensitive analysis are implemented by the MATLAB program platform. The results indicate that the 10-min grid-connected volatility is reduced by 38.7% based on the smoothing strategy and the internal investment return rate can reach 13.67% when the electricity price is 0.04 $/kWh. In addition the annual coordinated power and cycle proportion of the hybrid energy storage module are 80.5% and 90% respectively. The developed hybrid energy storage module can well meet the annual coordination requirements and has lower levelized cost of electricity. This method provides reasonable reference for designing and optimizing the wind-solar-hydrogen complementary system.
Split Injection Strategies for a High-pressure Hydrogen Direct Injection in a Small-bore Dual-fuel Diesel Engine
Jan 2024
Publication
Hydrogen-diesel dual direct-injection (H2DDI) engines present a promising pathway towards cleaner and more efficient transportation. In this study hydrogen split injection strategies were explored in an automotive-size single-cylinder compression ignition (CI) engine with a focus on varying the injection timings and energy fractions. The engine was operated at an intermediate load with fixed combustion phasing through adjustments of pilot diesel injection timing. An energy substitution principle guided the variation in energy fraction between the two hydrogen injections and then diesel injection while keeping the total energy input constant. The findings demonstrate that early first hydrogen injection timings lead to characteristics indicative of premixed combustion reflecting a high homogeneity of the hydrogen-air mixture. In contrast hydrogen stratification levels were predominantly influenced by later second injection timings with mixing-controlled combustion behaviour apparent for very late injections near top dead centre or when the second hydrogen injection held high energy fractions which led to decreased nitrogen oxides (NOx: NO and NO2) emissions. The carbon dioxide (CO2) emissions did not show high sensitivity to the hydrogen split injection strategies exhibiting about 77 % reduction compared to the diesel baseline due primarily to increased hydrogen energy fraction of up to 90 %
Green Hydrogen as a Clean Energy Resource and Its Applications as an Engine Fuel
Jan 2024
Publication
The world’s economy heavily depends on the energy resources used by various countries. India is one of the promising developing nations with very low crude reserves actively looking for new renewable energy resources to power its economy. Higher energy consumption and environmental pollution are two big global challenges for our sustainable development. The world is currently facing a dual problem of an energy crisis as well as environmental degradation. So there is a strong need to reduce our dependency on fossil fuels and greenhouse gas emissions. This can be achieved to a great extent by universally adopting clean fuels for all daily life uses like ethanol or liquified natural gas (LNG) as these burn very clean and do not emit many pollutants. Nowadays green hydrogen has emerged as a new clean energy source which is abundantly available and does not pollute much. This article explores the various benefits of green hydrogen with respect to fossil fuels various techniques of producing it and its possible use in different sectors such as industry transport and aviation as well as in day-to-day life. Finally it explores the use of green hydrogen as fuel in automobile engines its blending with CNG gas and its benefits in reducing emissions compared to fossil fuels. On combustion green hydrogen produces only water vapours and is thus a highly clean fuel. Thus it can potentially help humanity preserve the environment due to its ultra-low emissions and can be a consistent and reliable source of energy for generations to come thereby ending the clean energy security debate forever.
Recent Advances in Sustainable and Safe Marine Engine Operation with Alternative Fuels
Nov 2022
Publication
Pursuing net-zero emission operations in the shipping industry are quintessential for this sector to mitigate the environmental impact caused by hydrocarbon fuel combustion. Significant contributions to this are expected from the substitution of conventional marine fuels by alternative emission-free fuels with lower emission footprints. This study aims to conduct a comprehensive literature review for delineating the main characteristics of the considered alternative fuels specifically focusing on hydrogen methanol and ammonia which have recently attracted attention from both industry and academia. This study comparatively assesses the potential of using these fuels in marine engines and their subsequent performance characteristics as well as the associated environmental benefits. In addition the required storage conditions space as well as the associated costs are reviewed. Special attention is given to the safety characteristics and requirements for each alternative fuel. The results of this study demonstrate that the environmental benefits gained from alternative fuel use are pronounced only when renewable energy is considerably exploited for their production whereas the feasibility of each fuel depends on the vessel type used and pertinent storage constraints. Hydrogen ammonia and methanol are considered best-fit solutions for small scale shipping requiring minimal on-board storage. In addition the need for comparative assessments between diesel and alternative fuels is highlighted and sheds light on marine engines’ operational characteristics. Moreover using combinations of alternative and diesel fuels is identified as a direction towards decarbonisation of the maritime sector; intensifying the need for optimisation studies on marine engine design and operation. This study concludes with recommendations for future research directions thus contributing to fuel research concepts that can facilitate the shipboard use of alternative fuels.
A Multi-energy Multi-microgrid System Planning Model for Decarbonisation and Decontamination of Isolated Systems
May 2023
Publication
Decarbonising and decontaminating remote regions in the world presents several challenges. Many of these regions feature isolation dispersed demand in large areas and a lack of economic resources that impede the development of robust and sustainable networks. Furthermore isolated systems in the developing world are mostly based on diesel generation for electricity and firewood and liquefied petroleum gas for heating as these options do not require a significant infrastructure cost. In this context we present a stochastic multi-energy multi-microgrid system planning model that integrates electricity heat and hydrogen networks in isolated systems. The model is stochastic to capture uncertainty in renewable generation outputs particularly hydro and wind and thus design a multi-energy system proved secured against such uncertainty. The model also features two distinct constraints to limit the emissions of CO2 (for decarbonisation) and particulate matter (for decontamination) and incorporates firewood as a heating source. Moreover given that the focus is on low-voltage networks we introduce a fully linear AC power flow equations set allowing the planning model to remain tractable. The model is applied to a real-world case study to design a multi-energy multi-microgrid system in an isolated region in Chilean Patagonia. In a case with a zero limit over direct CO2 emissions the total system’s cost increases by 34% with respect to an unconstrained case. In a case with a zero limit over particulate matter emissions the total system’s cost increases by 189%. Finally although an absolute zero limit over both particulate matter and direct CO2 emissions leads to a total system’s cost increase of 650% important benefits in terms of decarbonisation and decontamination can be achieved at marginal cost increments.
An Energy Systems Model of a Large Commercial Liquid Hydrogen Aircraft in a Low-carbon Future
Apr 2023
Publication
Liquid hydrogen (LH2) aircraft have the potential to achieve carbon neutrality. However if the hydrogen is produced using electricity grids that utilise fossil fuel they have a non-zero carbon dioxide (CO2) emission associated with their well-to-wing pathway. To assess the potential of LH2 in aviation decarbonisation an energy systems comparison of large commercial LH2 liquified natural gas (LNG) conventional Jet-A and LH2 dual-fuel aircraft is presented. The performance of each aircraft is compared towards 2050 over which three system changes occur: (1) LH2 aircraft technology develops; (2) both world average and region-specific grid electricity which is used to produce the hydrogen decarbonises; and (3) the International Air Transportation Association (IATA) emissions targets which are used to restrict the passenger-range performance of each aircraft tighten. In 2050 the emissions of all aircraft are thus constrained to 0.063 kg-CO2/p-km relative to 0.110 kg-CO2/p-km for the unconstrained Jet A fuelled Boeing 787-8. It is estimated that in this year an LH2 aircraft powered by fuel cells and sourcing world average electricity can travel 6000 km 20% further than the conventional Jet A aircraft that is also constrained to meet the IATA targets but not as far as the LNG aircraft. At its maximum range the LH2 aircraft carries 84% of the Jet A passenger demand. Analysis using region-specific hydrogen indicates that LH2 aircraft can travel further than LNG aircraft in North America only accounting for 17% of the global demand. 1.59 times the current aviation energy consumption is required if all conventional aircraft are replaced with LH2 designs. Under stricter emissions constraints than those outlined by the IATA LH2 outperforms LNG in Europe and the Americas accounting for 41% of the global demand. Also in these regions the range energy consumption and passenger capacity of LH2 aircraft can be improved upon by combining the advantages of LH2 with LNG in dual-fuel aircraft concepts. The use of LH2 is therefore advantageous within several prominent niches of a future decarbonising aviation system.
Impact of Fuel Production Technologies on Energy Consumption and GHG Emissions from Diesel and Electric–Hydrogen Hybrid Buses in Rio de Janeiro, Brazil
Apr 2023
Publication
In view of the GHG reduction targets to be met Brazilian researchers are looking for cleaner alternatives to energy sources. These alternatives are primarily to be applied in the transport sector which presents high energy consumption as well as high CO2 emissions. In this sense this research developed an LCI study considering two bus alternatives for the city of Rio de Janeiro: diesel-powered internal combustion buses (ICEB) and a hydrogen-powered polymer fuel cell hybrid bus (FCHB). For the FCHB three hydrogen production methods were also included: water electrolysis (WE) ethanol steam reforming (ESR) and natural gas steam reforming (NGSR). The research was aimed at estimating energy consumption including the percentage of energy that is renewable as well as CO2 emissions. The results show diesel as the energy source with the highest emissions as well as the highest fossil energy consumption. Regarding the alternatives for hydrogen production water electrolysis stood out with the lowest emissions.
An Integrated Demand Response Dispatch Strategy for Low-carbon Energy Supply Park Considering Electricity-Hydrogen-Carbon Coordination
Apr 2023
Publication
Driven by the goal of ‘carbon peak carbon neutrality’ an integrated demand response strategy for integrated electricity– hydrogen energy systems is proposed for low-carbon energy supply parks considering the multi-level and multi-energy characteristics of campus-based microgrids. Firstly considering the spatial and temporal complementary nature of wind and photovoltaic generation and energy utilization the energy flow framework of the park is built based on the electricity and hydrogen energy carriers. Clean energy is employed as the main energy supply and power heat cooling and gas loads are considered energy consumption. Secondly the operation mechanism of coupled hydrogen storage hydrogen fuel cell and carbon capture equipment is analyzed in the two-stage power-to-gas conversion process. Thirdly considering the operating costs and environmental costs of the park an integrated demand response dispatch model is constructed for the coupled electricity– hydrogen–carbon system while satisfying the system equipment constraints network constraints and energy balance constraints of the park system. Finally Case study in an energy supply park system is implemented. The dispatch results of the integrated demand response with customer participation in the conventional electricity–hydrogen and electricity–hydrogen–carbon modes are compared to verify the effectiveness of the proposed strategy in renewable accommodation environmental protection and economic benefits.
Review of the Planning and Distribution Methodologies to Locate Hydrogen Infrastructure in the Territory
Jan 2024
Publication
The member countries of the European Union (EU) have prioritized the incorporation of hydrogen as a key component of their energy objectives. As the world moves towards reducing its dependence on fossil fuels alternative sources of energy have gained prominence. With the growing development of Fuel Cell Electric Vehicles (FCEVs) the establishment of an infrastructure for hydrogen production and the creation of a network of service stations have become essential. This article’s purpose is to conduct a methodical review of literature regarding the use of green hydrogen for transportation and the planning of imperative infrastructure in the territory of the EU specifically Hydrogen Refueling Stations (HRS). In order to increase the acceptance of fuel cell vehicles a comprehensive network of hydrogen refueling stations (HRS) must be built that enable drivers to refuel their vehicles quickly and easily similar to gasoline or diesel vehicles. The literature review on this topic was conducted using the Web of Science database (WOS) with a variety of search terms proposed to cover all the key components of green hydrogen production and refueling infrastructure. The implementation of HRS powered by renewable energy sources is an important step in the adoption of fuel cell vehicles and overcoming the obstacles that come with their implementation will require cooperation and innovation from governments private businesses and other stakeholders.
On the Design and Optimization of Distributed Energy Resources for Sustainable Grid-integrated Microgrid in Ethiopia
Apr 2023
Publication
This paper presents a study that focuses on alleviating the impacts of grid outages in Ethiopia. To deal with grid outages most industrial customers utilize backup diesel generators (DG) which are environmentally unfriendly and economically not viable. Grid integration of hybrid renewable energy systems (HRES) might be a possible solution to enhance grid reliability and reduce environmental and economic impacts of utilizing DG. In this study an optimization of grid integrated HRES is carried out for different dispatch and control strategies. The optimal power supply option is determined by performing comparative analysis of the different configurations of grid integrated HRES. The result of the study shows that grid integrated HRES consisting of photovoltaic and wind turbine as renewable energy sources and battery and hydrogen as hybrid energy storage systems is found to be the optimal system to supply the load demand. From the hydrogen produced on-site the FC generator and FCEVs consume 143 620 kg/yr of hydrogen which is equivalent to 394 955 kg/yr gasoline fuel consumption. This corresponds to saving 1 184 865 kg/yr of CO2 emissions and 605 703 $/yr revenue. Besides this system yields 547 035.4 $/yr revenue by injecting excess electricity to the grid. The study clearly shows the economic and environmental viability of this new technology for implementation.
Hydrogen Supply Chain and Refuelling Network Design: Assessment of Alternative Scenarios for the Long-haul Road Freight in the UK
Mar 2023
Publication
Shifting from fossil fuels to clean alternative fuel options such as hydrogen is an essential step in decarbonising the road freight transport sector and facilitating an efficient transition towards zero-emissions goods distribution of the future. Designing an economically viable and competitive Hydrogen Supply Chain (HSC) to support and accelerate the widespread adoption of hydrogen powered Heavy Goods Vehicles (H2-HGVs) is however significantly hindered by the lack of the infrastructure required for producing storing transporting and distributing the required hydrogen. This paper focuses on a bespoke design of a hydrogen supply chain and distribution network for the long-haul road freight transportation in the UK and develops an improved end-to-end and spatially-explicit optimisation tool to perform scenario analysis and provide important first-hand managerial and policy making insights. The proposed methodology improves over existing grid-based methodologies by incorporating spatially-explicit locations of Hydrogen Refuelling Stations (HRSs) and allowing further flexibility and accuracy. Another distinctive feature of the method and the analyses carried out in the paper pertains to the inclusion of bulk geographically agnostic as well as geological underground hydrogen storage options and reporting on significant cost saving opportunities. Finally the curve for H2-HGVs penetration levels safety stock period decisions and the transport mode capacity against hydrogen levelized cost at pump have been generated as important policy making tools to provide decision support and insights into cost resilience and reliability of the HSC.
Low-carbon Planning for Park-level Integrated Energy System Considering Optimal Construction Time Sequence and Hydrogen Energy Facility
Apr 2023
Publication
With the increasing concern about global energy crisis and environmental pollution the integrated renewable energy system has gradually become one of the most important ways to achieve energy transition. In the context of the rapid development of hydrogen energy industry the proportion of hydrogen energy in the energy system has gradually increased. The conversion between various energy sources has also become more complicated which poses challenges to the planning and construction of park-level integrated energy systems (PIES). To solve this problem we propose a bi-level planning model for an integrated energy system with hydrogen energy considering multi-stage investment and carbon trading mechanism. First the mathematical models of each energy source and energy storage in the park are established respectively and the independent operation of the equipment is analyzed. Second considering the operation state of multi-energy coordination a bi-level planning optimization model is established. The upper level is the capacity configuration model considering the variable installation time of energy facilities while the lower level is the operation optimization model considering several typical daily operations. Third considering the coupling relationship between upper and lower models the bi-level model is transformed into a solvable single-level mixed integer linear programming (MILP) model by using Karush–Kuhn–Tucker (KKT) condition and big-M method. Finally the proposed model and solution methods are verified by comprehensive case studies. Simulation results show that the proposed model can reduce the operational cost and carbon emission of PIES in the planning horizon and provide insights for the multi-stage investment of PIES.
Two-Layer Optimization Planning Model for Integrated Energy Systems in Hydrogen Refueling Original Station
May 2023
Publication
With the aggravation of global environmental pollution problems and the need for energy restructuring hydrogen energy as a highly clean resource has gradually become a hot spot for research in countries around the world. Facing the requirement of distributed hydrogen in refueling the original station for hydrogen transportation and other usage this paper proposes a comprehensive energy system planning model for hydrogen refueling stations to obtain the necessary devices construction the devices’ capacity decisions and the optimal operation behaviors of each device. Comparing to traditional single hydrogen producing technics in the traditional planning model the proposed model in this paper integrates both water-electrolysis-based and methanol-based manufacturing technics. A two-level optimization model is designed for this comprehensive system. The result of the numerical study shows that the proposed model can achieve a better optimal solution for distributed hydrogen production. Also it considers the single producing situation when price of one primary resource is sufficient higher than the other.
Influence of Natural Gas and Hydrogen Properties on Internal Combustion Engine Performance, Combustion, and Emissions: A Review
Jan 2024
Publication
This paper provides a comprehensive overview of the physical properties and applications of natural gas (NG) and hydrogen as fuels in internal combustion (IC) engines. The paper also meticulously examines the use of both NG and hydrogen as a fuel in vehicles their production physical characteristics and combustion properties. It reviews the current experimental studies in the literature and investigates the results of using both fuels. It further covers the challenges associated with injectors needle valves lubrication spark plugs and safety requirements for both fuels. Finally the challenges related to the storage production and safety of both fuels are also discussed. The literature review reveals that NG in spark ignition (SI) engines has a clear and direct positive impact on fuel economy and certain emissions notably reducing CO2 and non-methane hydrocarbons. However its effect on other emissions such as unburnt hydrocarbons (UHC) nitrogen oxides (NOx) and carbon monoxide (CO) is less clear. NG which is primarily methane has a lower carbon-to-hydrogen ratio than diesel fuel resulting in lower CO2 emissions per unit of energy released. In contrast hydrogen is particularly well-suited for use in gasoline engines due to its high self-ignition temperature. While increasing the hydrogen content of NG engines reduces torque and power output higher hydrogen input results in reduced fuel consumption and the mitigation of toxic exhaust emissions. Due to its high ignition temperature hydrogen is not inherently suitable for direct use in diesel engines necessitating the exploration of alternative methods for hydrogen introduction into the cylinder. The literature review suggests that hydrogen in diesel engines has shown a reduction in specific exhaust emissions and fuel consumption and an increase in NOx emissions. Overall the paper provides a valuable and informative overview of the challenges and opportunities associated with using hydrogen and NG as fuels in IC engines. It highlights the need for further research and development to address the remaining challenges such as the development of more efficient combustion chambers and the reduction of NOx emissions.
Towards Climate-neutral Aviation: Assessment of Maintenance Requirements for Airborne Hydrogen Storage and Distribution Systems
Apr 2023
Publication
Airlines are faced with the challenge of reducing their environmental footprint in an effort to push for climate-neutral initiatives that comply with international regulations. In the past the aviation industry has followed the approach of incremental improvement of fuel efficiency while simultaneously experiencing significant growth in annual air traffic. With the increase in air traffic negating any reduction in Greenhouse Gas (GHG) emissions more disruptive technologies such as hydrogen-based onboard power generation are required to reduce the environmental impact of airline operations. However despite initial euphoria and first conceptual studies for hydrogen-powered aircraft several decades ago there still has been no mass adoption to this day. Besides the challenges of a suitable ground infrastructure this can partly be attributed to uncertainties with the associated maintenance requirements and the expected operating costs to demonstrate the economic viability of this technology. With this study we address this knowledge gap by estimating changes towards scheduled maintenance activities for an airborne hydrogen storage and distribution system. In particular we develop a detailed system design for a hydrogen-powered fuel-cell-based auxiliary power generation and perform a comparative analysis with an Airbus A320 legacy system. That analysis allows us to (a) identify changes for the expected maintenance effort to enhance subsequent techno-economic assessments (b) identify implications of specific design assumptions with corresponding maintenance activities while ensuring regulatory compliance and (c) describe the impact on the resulting task execution. The thoroughly examined interactions between system design and subsequent maintenance requirements of this study can support practitioners in the development of prospective hydrogen-powered aircraft. In particular it allows the inclusion of maintenance implications in early design stages of corresponding system architectures. Furthermore since the presented methodology is transferable to different design solutions it provides a blueprint for alternative operating concepts such as the complete substitution of kerosene by hydrogen to power the main engines.
Impact of Climate and Geological Storage Potential on Feasibility of Hydrogen Fuels
Apr 2023
Publication
Electrofuels including hydrogen methane and ammonia have been suggested as one pathway in achieving net-zero greenhouse gas energy systems. They can play a role in providing an energy storage and fuel or feedstock to hard-to-abate sectors. In future energy systems their role is often studied in case studies adhering to specific region. In this study we study their role by defining multiple archetypal energy systems which represent approximations of real systems in different regions. Comparing the role of electrofuels across the cost-optimized systems relying only on renewable energy in power generation we found that hydrogen was a significant energy vector in all systems with its annual quantity approaching the classic electricity demand. The role of renewable methane was very limited. Electrofuel storages were needed in all systems and their capacity was the highest in the northern Hemiboreal system. Absence of cavern storage potential did not hamper the significance of electrofuels but increased the role of ammonia and led to average 5.5 % systemic cost increase. Systems where reservoir hydropower was scarce or level of electricity consumption was high needed more fuel storages. The findings of this study can help for better understanding of what kind of storage and generation technologies will be most useful in future carbon-neutral systems in different types of regions.
Hydrogen Consumption and Durability Assessment of Fuel Cell Vehicles in Realistic Driving
Jan 2024
Publication
This study proposes a predictive equivalent consumption minimization strategy (P-ECMS) that utilizes velocity prediction and considers various dynamic constraints to mitigate fuel cell degradation assessed using a dedicated sub-model. The objective is to reduce fuel consumption in real-world conditions without prior knowledge of the driving mission. The P-ECMS incorporates a velocity prediction layer into the Energy Management System. Comparative evaluations with a conventional adaptive-ECMS (A-ECMS) a standard ECMS with a well-tuned constant equivalence factor and a rule-based strategy (RBS) are conducted across two driving cycles and three fuel cell dynamic restrictions (|∕| ≤ 0.1 0.01 and 0.001 A∕cm2 ). The proposed strategy achieves H2 consumption reductions ranging from 1.4% to 3.0% compared to A-ECMS and fuel consumption reductions of up to 6.1% when compared to RBS. Increasing dynamic limitations lead to increased H2 consumption and durability by up to 200% for all tested strategies.
Analysis of CO2 Emissions Reduction on the Future Hydrogen Supply Chain Network for Dubai Buses
Apr 2023
Publication
There is an impetus to decarbonize transportation sector and mitigate climate change. This study examines the effect of adopting hydrogen (H2) as a fuel for Dubai Buses at different penetration scales on carbon dioxide (CO2) emissions reduction. A H2 supply-chain system dynamics model is developed to conduct life cycle cost and environmental analysis and evaluate the efficacy of different carbon prices and subsidies. Gray green and mixed H2 production scenarios were considered. The results show that gray hydrogen reduces 7.1 million tons of CO2 which is half of green hydrogen buses. Replacing diesel fleet at end of lifetime with mixed hydrogen bus fleet was the optimal approach to promote green hydrogen at pump reaching $4/kg in a decade. This gradual transition reduces 62% of the well-to-wheel CO2 emissions of the new bus fleet and creates mass for economies of scale as carbon prices and subsidies cannot promote green hydrogen alone.
Synthetic Fuels in the German Industry Sector Depending on Climate Protection Level
Aug 2021
Publication
Especially the electrification of the industry sector is highly complex and challenging mainly due to process-specific requirements. In this context there are several industrial processes where the direct and indirect use of electricity is subject to technical restrictions. In order to achieve the national climate goals the fossil energy consumption remaining after the implementation of efficiency and sufficiency measures as well as direct electrification has to be substituted through hydrogen and synthetic gaseous liquid and solid hydrocarbons. As the main research object the role of synthetic fuels in industrial transformation paths is investigated and analyzed by combining individual greenhouse gas abatement measures within the Sector Model Industry. Sector Model Industry is an energy consumption model that performs discrete deterministic energy and emission dynamic calculations with a time horizon up to 2050 at macroeconomic level. The results indicate that the use of synthetic fuels can be expected with a high level of climate protection. The industrial CO2 target in the model makes it necessary to replace CO2 -intensive fossil with renewable fuels. The model uses a total of 163 TWh of synthetic fuels in the climate protection scenario and thus achieves an 88% decrease in CO2 emissions in 2050 compared to 1990. This means that the GHG abatement achieved in industry is within the range of the targeted CO2 mitigation of the overall system in Germany of between 80 and 95% in 2050 compared to 1990. Due to technical restrictions the model mainly uses synthetic methane instead of hydrogen (134 TWh). The results show that despite high costs synthetic fuels are crucial for defossilization as a fall back option in the industrial scenario considering high climate ambition. The scenario does not include hydrogen technologies for heat supply. Accordingly the climate protection scenario uses hydrogen only in the steel industry for the direct reduction of iron (21 TWh). 8 TWh of synthetic oil substitute the same amount of fossil oil in the climate protection scenario. A further analysis conducted on the basis of the model results shows that transformation in the energy system and the use of smart ideas concepts and technologies are a basic prerequisite for enabling the holistic defossilisation of industry. The findings in the research can contribute to the cost-efficient use of synthetic fuels in industry and thus serve as a basis for political decision making. Moreover the results may have a practical relevance not only serving as a solid comparison base for the outcome of other studies but also as input data for further simulation of energy system transformation paths.
The Role of Hydrogen for the Defossilization of the German Chemical Industry
Apr 2023
Publication
Within the European Green Deal the European industry is summoned to transform towards a green and circular economy to reduce CO2-emissions and reach climate goals. Special focus is on the chemical industry to boost recycling processes for plastics exploit resource efficiency potentials and switch to a completely renewable feedstock (defossilization). Despite common understanding that drastic changes have to take place it is yet unknown how the industrial transformation should be accomplished. This work explains how a cost-optimal defossilization of the chemical industry in the context of national greenhouse gas (GHG) mitigation strategies look like. The central part of this investigation is based on a national energy system model to optimize the future energy system design of Germany as a case study for a highly industrialized country. A replacement of fossil-based feedstocks by renewable feedstocks leads to a significant increase in hydrogen demand by þ40% compared to a reference scenario. The resulting demand of hydrogen-based energy carriers including the demand for renewable raw materials must be produced domestically or imported. This leads to cumulative additional costs of the transformation that are 32% higher than those of a reference scenario without defossilization of the industry. Fischer-Tropsch synthesis and the methanol-to-olefins route can be identified as key technologies for the defossilization of the chemical industry.
Low Carbon Optimal Operation of Integrated Energy Systems Considering Air Pollution Emissions
Apr 2023
Publication
To reduce carbon sulfur dioxide (SO2) and nitrogen oxide (NOX) emissions from the integrated energy system (IES) a low carbon optimization strategy for the IES is proposed taking into account carbon SO2 and NOX emissions. Firstly hydrogen production storage and use equipment such as methane reactor electrolysis tank hydrogen fuel cell and hydrogen energy storage are added to the traditional IES to build a multi-energy complementary system of electricity gas cooling thermal and hydrogen. Then this paper introduces a stepped carbon trading mechanism and the model of the emissions of SO2 and NOX. Finally to further reduce its pollutant emissions the model of combined heat and power units and hydrogen fuel cells with adjustable thermoelectric ratio is built. To compare and account for the impact of air pollutant emissions on the optimal low-carbon operation of IES this paper construsted three scenarios with the lowest cost of carbon trading the lowest penalty cost for SO2 and NOX emissions and total operation cost as objective functions respectively The results show that the strategy is effective in reducing air pollutant emissions from integrated energy systems and the outputs of CHP and HFC with adjustable thermoelectric ratios are more flexible and can effectively achieve carbon reduction and pollutant emission reduction.
The Fuel Flexibility of Gas Turbines: A Review and Retrospective Outlook
May 2023
Publication
Land-based gas turbines (GTs) are continuous-flow engines that run with permanent flames once started and at stationary pressure temperature and flows at stabilized load. Combustors operate without any moving parts and their substantial air excess enables complete combustion. These features provide significant space for designing efficient and versatile combustion systems. In particular as heavy-duty gas turbines have moderate compression ratios and ample stall margins they can burn not only high- and medium-BTU fuels but also low-BTU ones. As a result these machines have gained remarkable fuel flexibility. Dry Low Emissions combustors which were initially confined to burning standard natural gas have been gradually adapted to an increasing number of alternative gaseous fuels. The paper first delivers essential technical considerations that underlie this important fuel portfolio. It then reviews the spectrum of alternative GT fuels which currently extends from lean gases (coal bed coke oven blast furnace gases . . . ) to rich refinery streams (LPG olefins) and from volatile liquids (naphtha) to heavy hydrocarbons. This “fuel diet” also includes biogenic products (biogas biodiesel and ethanol) and especially blended and pure hydrogen the fuel of the future. The paper also outlines how historically land-based GTs have gradually gained new fuel territories thanks to continuous engineering work lab testing experience extrapolation and validation on the field.
Navigating Turbulence: Hydrogen's Role in the Decarbonization of the Aviation Sector
Jan 2024
Publication
This paper offers a comprehensive analysis of the historical evolution and the current state of the aviation industry with a particular emphasis on the critical need for this sector to decarbonize. It delves into emerging propulsion technologies such as battery electric and hydrogen-based systems assessing their potential impact on sustainability within the aviation sector. Special attention is devoted to the global regulatory framework notably carbon offsetting and emission reduction scheme for international aviation which encapsulates initiatives such as lower carbon aviation fuels and sustainable aviation fuels. Examining the environmental challenges facing aviation the paper underscores the necessity for a balanced and comprehensive strategy that integrates various approaches to achieve sustainable solutions. By addressing both the historical context and contemporary advances the paper aims to provide a nuanced understanding of the complexities surrounding aviation's decarbonization journey acknowledging the industry's strides while recognizing the ongoing challenges in the pursuit of sustainability.
Prediction of Freezing Time During Hydrogen Fueling Using Machine Learning
Nov 2024
Publication
This study presents a method for predicting nozzle surface temperature and the timing of frost formation during hydrogen refueling using machine learning. A continuous refueling system was implemented based on a simulation model that was developed and validated in previous research. Data were collected under various boundary conditions and eight regression models were trained and evaluated for their predictive performance. Hyperparameter optimization was performed using random search to enhance model performance. The final models were validated by applying boundary conditions not used during model development and comparing the predicted values with simulation results. The comparison revealed that the maximum error rate occurred after the second refueling with a value of approximately 4.79%. Currently nitrogen and heating air are used for defrosting and frost reduction which can be costly. The developed machine learning models are expected to enable prediction of both frost formation and defrosting timings potentially allowing for more cost-effective management of defrosting and frost reduction strategies.
Conversion of a Small-Size Passenger Car to Hydrogen Fueling: 0D/1D Simulation of EGR and Related Flow Limitations
Jan 2024
Publication
Hydrogen is seen as a prime choice for complete replacement of gasoline so as to achieve zero-emissions energy and mobility. Combining the use of this alternative fuel with a circular economy approach for giving new life to the existing fleet of passenger cars ensures further benefits in terms of cost competitiveness. Transforming spark ignition (SI) engines to H2 power requires relatively minor changes and limited added components. Within this framework the conversion of a small-size passenger car to hydrogen fueling was evaluated based on 0D/1D simulation. One of the methods to improve efficiency is to apply exhaust gas recirculation (EGR) which also lowers NOx emissions. Therefore the previous version of the quasi-dimensional model was modified to include EGR and its effects on combustion. A dedicated laminar flame speed model was implemented for the specific properties of hydrogen and a purpose-built sub-routine was implemented to correctly model the effects of residual gas at the start of combustion. Simulations were performed in several operating points representative of urban and highway driving. One of the main conclusions was that highpressure recirculation was severely limited by the minimum flow requirements of the compressor. Low-pressure EGR ensured wider applicability and significant improvement of efficiency especially during partial-load operation specific to urban use. Another benefit of recirculation was that pressure rise rates were predicted to be more contained and closer to the values expected for gasoline fueling. This was possible due to the high tolerance of H2 to the presence of residual gas.
Effects of Hydrogen, Methane, and Their Blends on Rapid-Filling Process of High-Pressure Composite Tank
Feb 2024
Publication
Alternative fuels such as hydrogen compressed natural gas and liquefied natural gas are considered as feasible energy carriers. Selected positive factors from the EU climate and energy policy on achieving climate neutrality by 2050 highlighted the need for the gradual expansion of the infrastructure for alternative fuel. In this research continuity equations and the first and second laws of thermodynamics were used to develop a theoretical model to explore the impact of hydrogen and natural gas on both the filling process and the ultimate in-cylinder conditions of a type IV composite cylinder (20 MPa for CNG 35 MPa and 70 MPa for hydrogen). A composite tank was considered an adiabatic system. Within this study based on the GERG-2008 equation of state a thermodynamic model was developed to compare and determine the influence of (i) hydrogen and (ii) natural gas on the selected thermodynamic parameters during the fast-filling process. The obtained results show that the cylinder-filling time depending on the cylinder capacity is approximately 36–37% shorter for pure hydrogen compared to pure methane and the maximum energy stored in the storage tank for pure hydrogen is approximately 28% lower compared to methane whereas the total entropy generation for pure hydrogen is approximately 52% higher compared to pure methane.
The ATHENA Framework: Analysis and Design of a Strategic Hydrogen Refuelling Infrastructure
Apr 2023
Publication
With the pressured timescale in determining effective and viable net zero solutions within the transport sector it is important to understand the extent of implementing a new refuelling infrastructure for alternative fuel such as hydrogen. The proposed ATHENA framework entails three components which encapsulates the demand data analysis an optimisation model in determining the minimal cost hydrogen refuelling infrastructure design and an agent-based model simulating the operational system. As a case study the ATHENA framework is applied to Northern England focusing on the design of a hydrogen refuelling infrastructure for heavy goods vehicles. Analysis is performed in calibrating parameters and investigating different scenarios within the optimisation and agent-based simulation models. For this case study the system optimality is limited by the feasible number of tube trailer deliveries per day which suggests an opportunity for alternative delivery methods.
Low-carbon Economy Dispatching of Integrated Energy System with P2G-HGT Coupling Wind Power Absorption Based on Stepped Carbon Emission Trading
Aug 2023
Publication
To improve the renewable energy consumption capacity of integrated energy system (IES) and reduce the carbon emission level of the system a low-carbon economic dispatch model of IES with coupled power-to-gas (P2G) and hydrogen-doped gas units (HGT) under the stepped carbon trading mechanism is proposed. On the premise of wind power output uncertainty the operating characteristics of the coupled electricity-to-gas equipment in the system are used to improve the wind abandonment problem of IES and increase its renewable energy consumption capacity; HGT is introduced to replace the traditional combustion engine for energy supply and on the basis of refined P2G a part of the volume fraction of hydrogen obtained from the production is extracted and mixed with methane to form a gas mixture for HGT combustion so as to improve the low-carbon economy of the system. The ladder type carbon trading mechanism is introduced into IES to guide the system to control carbon emission behavior and reduce the carbon emission level of IES. Based on this an optimal dispatching strategy is constructed with the economic goal of minimizing the sum of system operation cost wind abandonment cost carbon trading cost and energy purchase cost. After linearization of the established model and comparison analysis by setting different scenarios the wind power utilization rate of the proposed model is increased by 24.5% and the wind abandonment cost and CO2 emission are reduced by 86.3% and 10.5% respectively compared with the traditional IES system which achieves the improvement of renewable energy consumption level and low carbon economy.
A Comparative Environmental Life Cycle Assessment Study of Hydrogen Fuel Electricity and Diesel Fuel for Public Buses
Aug 2023
Publication
Hydrogen fuel and electricity are energy carriers viewed as promising alternatives for the modernization and decarbonization of public bus transportation fleets. In order to choose development pathways that will lead transportation systems toward a sustainable future the authors developed an environmental model based on the Life Cycle Assessment approach. The model tested the impact of energy carrier consumption during driving as well as the electricity origin employed to power electric buses and produce hydrogen. Energy sources such as wind solar waste and grid electricity were investigated. The scope of the study included the life cycles of the energy carrier and the necessary infrastructure. The results were presented from two perspectives: the total environmental impact and global warming potential. In order to create a roadmap an original method for choosing sustainable development pathways was prepared. It was shown that the modernization of conventional bus fleets using hydrogen and electrical pathways can provide significant environmental benefits from both perspectives but especially in terms of global warming potential. It was emphasized that attention should be paid to the use of low- and zero-emission energy sources because their impact often strongly influenced the final environmental judgment. The energy carrier consumption also had a strong impact on the results obtained and that is why efforts should be made to reduce it. In addition it was confirmed that hydrogen and electricity production systems based on electricity generated by a waste-to-energy plant could be an environmentally reasonable dual solution for both sustainable waste management and meeting transport needs.
Enhancing the Risk-oriented Participation of Wind Power Plants in Day-ahead Balancing, and Hydrogen Markets with Shared Multi-energy Storage Systems
Dec 2024
Publication
The increasing demand for renewable energy sources (RES) to address environmental concerns and reduce fossil fuel dependency highlights the need for efficient energy storage and balancing mechanisms to manage RES output uncertainty. However providing dedicated storage units to RES owners is often infeasible. Additionally the growing interest in hydrogen utilization complicates optimal decision-making for multi-energy systems. To tackle these challenges this paper presents a novel bidding strategy enabling wind farms to participate in dayahead balancing and hydrogen markets through shared multi-energy storage (SMES) systems. These SMES which include both battery and hydrogen storage offer a cost-effective solution by allowing RES owners to rent storage capacity. By optimizing SMES utilization and wind farm management we propose an integrated strategy for day-ahead electrical and real-time balancing markets and also hydrogen markets. The approach incorporates with uncertainties of wind generation bidding by using conditional value at risk (CVaR) to account for different risk-aversion levels. The Dantzig–Wolfe Decomposition (DWD) method is applied to decentralize the problem reduce the calculation burden and enhance the data privacy. The framework is modeled as a mixed-integer linear program (MILP) and solved using CPLEX solver via GAMS software. The results demonstrate the effectiveness of this strategy offering insights into the risk-oriented market participation of wind power plants with the aid of SMES system supporting a more sustainable and resilient energy system. The numerical results show that by utilizing a SMES with only batteries the revenue can be increased by 17.3% and equipping the SMES with hydrogen storage and participating in both markets leads to 36.9% increment in the revenue of the wind power plant.
Operation Optimization of Regional Integrated Energy Systems with Hydrogen by Considering Demand Response and Green Certificate–Carbon Emission Trading Mechanisms
Jun 2024
Publication
Amidst the growing imperative to address carbon emissions aiming to improve energy utilization efficiency optimize equipment operation flexibility and further reduce costs and carbon emissions of regional integrated energy systems (RIESs) this paper proposes a low-carbon economic operation strategy for RIESs. Firstly on the energy supply side energy conversion devices are utilized to enhance multi-energy complementary capabilities. Then an integrated demand response model is established on the demand side to smooth the load curve. Finally consideration is given to the RIES’s participation in the green certificate–carbon trading market to reduce system carbon emissions. With the objective of minimizing the sum of system operating costs and green certificate–carbon trading costs an integrated energy system optimization model that considers electricity gas heat and cold coupling is established and the CPLEX solver toolbox is used for model solving. The results show that the coordinated optimization of supply and demand sides of regional integrated energy systems while considering multi-energy coupling and complementarity effectively reduces carbon emissions while further enhancing the economic efficiency of system operations.
Robust Control for Techno-economic Efficiency Energy Management of Fuel Cell Hybrid Electric Vehicles
Apr 2022
Publication
The design of an efficient techno-economic autonomous fuel cell hybrid electric vehicle(FCHEV) is a crucial challenge. This paper investigates the design of a near optimal PI controller for an automated FCHEV where autonomy is expressed as efficient and robust tracking of a given reference speed trajectory without driver’s intervention. An impartial comparison is introduced to illustrate the effectiveness of the proposed metaheuristic-based optimal controllers in enhancing the system dynamic performance. The comprehensive optimization performance indicator is considered as a function of the vehicle dynamic characteristics while determining the optimal controller gains. In this paper the proposed effective up-to-date metaheuristic techniques are the grey wolf optimization (GWO) as well as the artificial bee colony (ABC). Using MATLAB TM /Simulink numerical simulations clearly illustrate the efficiency of near-optimal gains in the optimized tuning methodologies and the fixed manual one in realizing adequate velocity tracking. The simulation results demonstrate the superiority of both ABC and GWO rather than the manual controller for driving cycles of high acceleration and deceleration levels. In absence of these latter the manual defined gain controller is considered sufficient. Through a comprehensive sensitivity analysis the robustness of both metaheuristic-based controllers is verified under diverse driving cycles of different operation features and nature. Despite GWO results in better dynamic characteristics the ABC provides more economical feature with about 1.5% compared to manual system in extra urban driving cycle. However manual-controller has the minimum fuel cost under the United States driving cycle developed by the environmental protection agency as a New York city cycle(US EPA NYCC) and urban driving cycle (ECE). Ecologically electric vehicles have an environmentally friendly effect especially when driven with green hydrogen. Autonomous vehicles involving velocity control systems would raise car share and provide more comfort.
Modelling Methodologies to Design and Control Renewables and Hydrogen-Based Telecom Towers Power Supply Systems
Aug 2023
Publication
Proton exchange membrane fuel cell (PEMFCS) and electrolyser (PEMELS) systems together with a hydrogen storage tank (HST) are suitable to be integrated with renewable microgrids to cover intermittency and fully exploit the excess of electrical energy. Such an integration perfectly fits telecom tower power supply needs both in off-grid and grid-connected sites. In this framework a model-based tool enabling both optimal sizing and proper year-through energy management of both the above applications is proposed. Respectively the islanded optimisation is performed considering two economic indices i.e. simple payback (SPB) and levelised cost of energy (LCOE) together with two strategies of hydrogen tank management charge sustaining and depleting and also accounting for the impact of grid extension distance. On the other hand the grid connection is addressed through the dynamic programming method while downsizing PEMELS and HST sizes to improve techno-economic effectiveness thanks to grid contribution towards renewables curtailment issues mitigation. For both the above introduced HST management strategies a reduction of more than 70% of the nominal PEMELS power and 90% of the HST size which will in turn lead to SPB and LCOE being reduced by 80% and 60% in comparison to the islanded case respectively is achieved. Furthermore the charge depleting strategy relying on possible hydrogen purchase interestingly provides an SPB and LCOE of 9% and 7% lower than the charge sustaining one.
Knock Mitigation and Power Enhancement of Hydrogen Spark-Ignition Engine through Ammonia Blending
Jun 2023
Publication
Hydrogen and ammonia are primary carbon-free fuels that have massive production potential. In regard to their flame properties these two fuels largely represent the two extremes among all fuels. The extremely fast flame speed of hydrogen can lead to an easy deflagration-to-detonation transition and cause detonation-type engine knock that limits the global equivalence ratio and consequently the engine power. The very low flame speed and reactivity of ammonia can lead to a low heat release rate and cause difficulty in ignition and ammonia slip. Adding ammonia into hydrogen can effectively modulate flame speed and hence the heat release rate which in turn mitigates engine knock and retains the zero-carbon nature of the system. However a key issue that remains unclear is the blending ratio of NH3 that provides the desired heat release rate emission level and engine power. In the present work a 3D computational combustion study is conducted to search for the optimal hydrogen/ammonia mixture that is knock-free and meanwhile allows sufficient power in a typical spark-ignition engine configuration. Parametric studies with varying global equivalence ratios and hydrogen/ammonia blends are conducted. The results show that with added ammonia engine knock can be avoided even under stoichiometric operating conditions. Due to the increased global equivalence ratio and added ammonia the energy content of trapped charge as well as work output per cycle is increased. About 90% of the work output of a pure gasoline engine under the same conditions can be reached by hydrogen/ammonia blends. The work shows great potential of blended fuel or hydrogen/ammonia dual fuel in high-speed SI engines.
A Rigorous Optimization Method for Long-term Multi-stage Investment Planning: Integration of Hydrogen into a Decentralized Multi-energy System
Dec 2024
Publication
Thoroughly assessing future energy systems requires examining both their end states and the paths leading to them. Employing dynamic investment or multi-stage optimization models is crucial for this analysis. However solving these optimization problems becomes increasingly challenging due to their long time horizons – often spanning several decades – and their dynamic nature. While simplifications like aggregations are often used to expedite solving procedures they introduce higher uncertainty into the results and might lead to suboptimal solutions compared to non-simplified models. Against this background this paper presents a rigorous optimization method tailored for multi-stage optimization problems in long-term energy system planning. By dividing the solution algorithm into a design and operational optimization step the proposed method efficiently finds feasible solutions for the non-simplified optimization problem with simultaneous quality proof. Applied to a real-life energy system of a waste treatment plant in Germany the method significantly outperforms a benchmark solver by reducing the computational time to find the first feasible solution from more than two weeks to less than one hour. Furthermore it exhibits greater robustness compared to a conventional long-term optimization approach and yields solutions closer to the optimum. Overall this method offers decision-makers computationally efficient and reliable information for planning investment decisions in energy systems.
Evaluation of Hydrogen Addition on Combustion and Emission Characteristics of Dual-Fuel Diesel Engines with Different Compression Ratios
Sep 2023
Publication
In this paper a computational fluid dynamics (CFD) model was established and verified on the basis of experimental results and then the effect of hydrogenation addition on combustion and emission characteristics of a diesel–hydrogen dual-fuel engine fueled with hydrogenation addition (0% 5% and 10%) under different hydrogenation energy shares (HESs) and compression ratios (CRs) were investigated using CONVERGE3.0 software. And this work assumed that the hydrogen and air were premixed uniformly. The correctness of the simulation model was verified by experimental data. The values of HES are in the range of 0% 5% 10% and 15%. And the values of CR are in the range of 14 16 18 and 20. The results of this study showed that the addition of hydrogen to diesel fuel has a significant effect on the combustion characteristics and the emission characteristics of diesel engines. When the HES was 15% the in-cylinder pressure increased by 10.54%. The in-cylinder temperature increased by 15.11%. When the CR was 20 the in-cylinder pressure and the in-cylinder temperature increased by 66.10% and 13.09% respectively. In all cases HC CO CO2 and soot emissions decreased as the HES increased. But NOx emission increased.
Carbon Footprint Enhancement of an Agricultural Telehandler through the Application of a Fuel Cell Powertrain
Mar 2024
Publication
The growing awareness about climate change and environmental pollution is pushing the industrial and academic world to investigate more sustainable solutions to reduce the impact of anthropic activities. As a consequence a process of electrification is involving all kind of vehicles with a view to gradually substitute traditional powertrains that emit several pollutants in the exhaust due to the combustion process. In this context fuel cell powertrains are a more promising strategy with respect to battery electric alternatives where productivity and endurance are crucial. It is important to replace internal combustion engines in those vehicles such as the those in the sector of NonRoad Mobile Machinery. In the present paper a preliminary analysis of a fuel cell powertrain for a telehandler is proposed. The analysis focused on performance fuel economy durability applicability and environmental impact of the vehicle. Numerical models were built in MATLAB/Simulink and a simple power follower strategy was developed with the aim of reducing components degradation and to guarantee a charge sustaining operation. Simulations were carried out regarding both peak power conditions and a typical real work scenario. The simulations’ results showed that the fuel cell powertrain was able to achieve almost the same performances without excessive stress on its components. Indeed a degradation analysis was conducted showing that the fuel cell system can achieve satisfactory durability. Moreover a Well-to-Wheel approach was adopted to evaluate the benefits in terms of greenhouse gases of adopting the fuel cell system. The results of the analysis demonstrated that even if considering grey hydrogen to feed the fuel cell system the proposed powertrain can reduce the equivalent CO2 emissions of 69%. This reduction can be further enhanced using hydrogen from cleaner production processes. The proposed preliminary analysis demonstrated that fuel cell powertrains can be a feasible solution to substitute traditional systems on off-road vehicles even if a higher investment cost might be required.
The Transition to a Renewable Energy Electric Grid in the Caribbean Island Nation of Antigua and Barbuda
Aug 2023
Publication
The present study describes the development and application of a model of the national electricity system for the Caribbean dual-island nation of Antigua and Barbuda to investigate the cost optimal mix of solar photovoltaics (PVs) wind and in the most novel contribution concentrating solar power (CSP). These technologies together with battery and hydrogen energy storage can enable the aim of achieving 100% renewable electricity and zero carbon emissions. The motivation for this study was that while most nations in the Caribbean rely largely on diesel fuel or heavy fuel oil for grid electricity generation many countries have renewable resources beyond wind and solar energy. Antigua and Barbuda generates 93% of its electricity from diesel-fueled generators and has set the target of becoming a net-zero nation by 2040 as well as having 86% renewable energy generation in the electricity sector by 2030 but the nation has no hydroelectric or geothermal resources. Thus this study aims to demonstrate that CSP is a renewable energy technology that can help assist Antigua and Barbuda in its transition to a renewable energy electric grid while also decreasing electricity generation costs. The modeled optimal mix of renewable energy technologies presented here was found for Antigua and Barbuda by assessing the levelized cost of electricity (LCOE) for systems comprising various combinations of energy technologies and storage. Other factors were also considered such as land use and job creation. It was found that 100% renewable electricity systems are viable and significantly less costly than current power systems and that there is no single defined pathway towards a 100% renewable energy grid but several options are available.
Predictive Maintenance and Reinspection Strategies for Hydrogen Refueling Station Pressure Vessels: A Case Study in South Korea
Jul 2024
Publication
Hydrogen refueling stations rely on pressure vessels capable of withstanding pressures up to 90 MPa while mitigating concerns related to hydrogen embrittlement. However a gap exists in understanding the long-term fatigue behavior of these vessels under real operational conditions. This study focuses on evaluating the safety of SA372 pressure vessels using operational data from a hydrogen refueling station in Pyeongtaek South Korea. A predictive reinspection methodology is proposed based on this evaluation. Parameters including hydrogen-induced stress intensity factor (KIH) initial crack size (a0 c0) and pressure vessel specifications are considered to assess critical crack depth (ac) critical usage cycles (Nc) and allowable usage cycles (Nallowed). Leveraging operational data collected between August and November 2023 fatigue analysis and Rainflow counting inform reinspection schedules. Results indicate a need for mid-bank vessel reinspection within the second year high-bank vessel reinspection every 20 years and low-bank vessel reinspection every 143 years in accordance with safety regulations. Additionally a revised refueling logic is proposed to optimize vehicle charging methods and pressure ranges enhancing operational safety. This study serves as a preliminary investigation highlighting the need for broader data collection and analysis to generalize findings across multiple stations.
Current Status and Economic Analysis of Green Hydrogen Energy Industry Chain
Feb 2024
Publication
Under the background of the power system profoundly reforming hydrogen energy from renewable energy as an important carrier for constructing a clean low-carbon safe and efficient energy system is a necessary way to realize the objectives of carbon peaking and carbon neutrality. As a strategic energy source hydrogen plays a significant role in accelerating the clean energy transition and promoting renewable energy. However the cost and technology are the two main constraints to green hydrogen energy development. Herein the technological development status and economy of the whole industrial chain for green hydrogen energy “production-storage-transportation-use” are discussed and reviewed. After analysis the electricity price and equipment cost are key factors to limiting the development of alkaline and proton exchange membrane hydrogen production technology; the quantity scale and distance of transportation are key to controlling the costs of hydrogen storage and transportation. The application of hydrogen energy is mainly concentrated in the traditional industries. With the gradual upgrading and progress of the top-level design and technology the application of hydrogen energy mainly including traffic transportation industrial engineering energy storage power to gas and microgrid will show a diversified development trend. And the bottleneck problems and development trends of the hydrogen energy industry chain are also summarized and viewed.
Low-carbon Economic Operation of IES Based on Life Cycle Method and Hydrogen Energy Utilization
Aug 2023
Publication
The Integrated Energy System (IES) that coordinates multiple energy sources can effectively improve energy utilization and is of great significance to achieving energy conservation and emission reduction goals. In this context a low-carbon and economic dispatch model for IES is proposed. Firstly a hydrogen energy-based IES (H2-IES) is constructed to refine the utilization process of hydrogen energy. Secondly the carbon emissions of different energy chains throughout their life cycle are analyzed using the life cycle assessment method (LCA) and the carbon emissions of the entire energy supply and demand chain are considered. Finally a staged carbon trading mechanism is adopted to promote energy conservation and emission reduction. Based on this an IES low-carbon and economic dispatch model is constructed with the optimization goal of minimizing the sum of carbon trading costs energy procurement costs and hydrogen sales revenue while considering network constraints and constraints on key equipment. By analyzing the model under different scenarios the introduction of life cycle assessment staged carbon trading and hydrogen energy utilization is shown to promote low-carbon and economic development of the comprehensive energy system.
The Role of Hydrogen-based Power Systems in the Energy Transition of the Residential Sector
Sep 2021
Publication
The unsustainable and continuous growth of anthropogenic emissions of greenhouse gases (GHG) has pushed governments private companies and stakeholders to adopt measures and policies to fight against climate change. Within this framework increasing the contribution of renewable energy sources (RES) to final consumed energy plays a key role in the planned energy transition. Regarding the residential sector in Europe 92% of GHG emissions comes from 75% of the building stock that is over 25 years old and highly inefficient. Thus this sector must raise RES penetration from the current 36% to 77% by 2050 to comply with emissions targets. In this regard the hybridization of hydrogen-based technologies and RES represents a reliable and versatile solution to facilitate decarbonization of the residential sector. This study provides an overview and analysis of standalone renewable hydrogen-based systems (RHS) focusing on the residential and buildings sector as well as critical infrastructures like telecom stations data servers etc. For detailed evaluation of RHS several pilot plants and real demonstration plants implemented worldwide are reviewed. To this end a techno-economic assessment of relevant parameters like self-sufficiency ratio levelized cost of energy and hydrogen roundtrip efficiency is provided. Moreover the performance of the different configurations is evaluated by comparing the installed power of each component and their energy contribution to cover the load over a defined period of time. Challenges ahead are identified for the wider deployment of RHS in the residential and buildings sector.
Sustainable Fuel Production Using In-situ Hydrogen Supply via Aqueous Phase Reforming: A Techno-economic and Life-cycle Greenhouse Gas Emissions Assessment
Jul 2023
Publication
Sustainable aviation fuel (SAF) production is one of the strategies to guarantee an environmental-friendly development of the aviation sector. This work evaluates the technical economic and environmental feasibility of obtaining SAFs by hydrogenation of vegetable oils thanks to in-situ hydrogen production via aqueous phase reforming (APR) of glycerol by-product. The novel implementation of APR would avoid the environmental burden of conventional fossil-derived hydrogen production as well as intermittency and storage issues related to the use of RES-based (renewable energy sources) electrolysers. The conceptual design of a conventional and advanced (APR-aided) biorefinery was performed considering a standard plant capacity equal to 180 ktonne/y of palm oil. For the advanced scenario the feed underwent hydrolysis into glycerol and fatty acids; hence the former was subjected to APR to provide hydrogen which was further used in the hydrotreatment reactor where the fatty acids were deoxygenated. The techno-economic results showed that APR implementation led to a slight increase of the fixed capital investment by 6.6% compared to the conventional one while direct manufacturing costs decreased by 22%. In order to get a 10% internal rate of return the minimum fuel selling price was found equal to 1.84 $/kg which is 17% lower than the one derived from conventional configurations (2.20 $/kg). The life-cycle GHG emission assessment showed that the carbon footprint of the advanced scenario was equal to ca. 12 g CO2/MJSAF i.e. 54% lower than the conventional one (considering an energy-based allocation). The sensitivity analysis pointed out that the cost of the feedstock SAF yield and the chosen plant size are keys parameters for the marketability of this biorefinery while the energy price has a negligible impact; moreover the source of hydrogen has significant consequences on the environmental footprint of the plant. Finally possible uncertainties for both scenarios were undertaken via Monte Carlo simulations.
Climate Change Mitigation Potentials of on Grid-connected Power-to-X Fuels and Advanced Biofuels for the European Maritime Transport
Jul 2023
Publication
This study proposes a country-based life-cycle assessment (LCA) of several conversion pathways related 10 to both on grid-connected Power-to-X (PtX) fuels and advanced biofuel production for maritime transport 11 in Europe. We estimate the biomass resource availability (both agricultural and forest residues and 12 second-generation energy crops from abandoned cropland) electricity mix and a future-oriented 13 prospective LCA to assess how future climate change mitigation policies influence the results. Our results 14 indicate that the potential of PtX fuels to achieve well-to-wake greenhouse gas intensities lower than 15 those of fossil fuels is limited to countries with a carbon intensity of the electricity mix below 100 gCO2eq kWh-1 16 . The more ambitious FuelEU Maritime goal could be achieved with PtX only if connected to electricity sources below ca. 17 gCO2eq kWh-1 17 which can become possible for most of the national 18 electricity mix in Europe by 2050 if renewable energy sources will become deployed at large scales. For 19 drop-in and hydrogen-based biofuels biomass residues have a higher potential to reduce emissions than 20 dedicated energy crops. In Europe the potentials of energy supply from all renewable and low-carbon 21 fuels (RLFs) range from 32-149% of the current annual fuel consumption in European maritime transport. 22 The full deployment of RLFs with carbon capture and storage technologies could mitigate up to 184% of 23 the current well-to-wake shipping emissions in Europe. Overall our study highlights how the strategic use 24 of both hydrogen-based biofuels and PtX fuels can contribute to the climate mitigation targetsfor present 25 and future scenarios of European maritime transport.
Investigations on Pressure Dependence of Coriolis Mass Flow Meters Used at Hydrogen Refueling Stations
Sep 2020
Publication
In the framework of the ongoing EMPIR JRP 16ENG01 ‘‘Metrology for Hydrogen Vehicles’’ a main task is to investigate the influence of pressure on the measurement accuracy of Coriolis Mass Flow Meters (CFM) used at Hydrogen Refueling Stations (HRS). At a HRS hydrogen is transferred at very high and changing pressures with simultaneously varying flow rates and temperatures. It is clearly very difficult for CFMs to achieve the current legal requirements with respect to mass flow measurement accuracy at these measurement conditions. As a result of the very dynamic filling process it was observed that the accuracy of mass flow measurement at different pressure ranges is not sufficient. At higher pressures it was found that particularly short refueling times cause significant measurement deviations. On this background it may be concluded that pressure has a great impact on the accuracy of mass flow measurement. To gain a deeper understanding of this matter RISE has built a unique high-pressure test facility. With the aid of this newly developed test rig it is possible to calibrate CFMs over a wide pressure and flow range with water or base oils as test medium. The test rig allows calibration measurements under the conditions prevailing at a 70 MPa HRS regarding mass flows (up to 3.6 kg min−1) and pressures (up to 87.5 MPa).
The Role of Power-to-hydrogen in Carbon Neutral Energy and Industrial Systems: Case Finland
Aug 2023
Publication
To combat climate change decarbonization measures are undertaken across the whole energy sector. Industry and transportation sectors are seen as difficult sectors to decarbonize with green hydrogen being proposed as a solution to achieve decarbonization in these sectors. While many methods of introducing hydrogen to these sectors are present in literature few systemlevel works study the specific impacts of large-scale introduction has on power and heat sectors in an energy system. This contribution examines the effects of introducing hydrogen into a Finnish energy system in 2040 by conducting scenario simulations in EnergyPLAN – software. Primary energy consumption and CO2 emissions of the base scenario and hydrogen scenarios are compared. Additionally the differences between a constant and flexible hydrogen production profile are studied. Introducing hydrogen increases electricity consumption by 31.9 % but reduces CO2 emissions by 71.5 % and fossil energy consumption by 72.6%. The flexible hydrogen profile lowers renewable curtailment and improves energy efficiency but requires economically unfeasible hydrogen storage. Biomass consumption remains high and is not impacted significantly by the introduction of hydrogen. Additional measures in other sectors are needed to ensure carbon neutrality.
Low Platinum Fuel Cell as Enabler for the Hydrogen Fuel Cell Vehicle
Feb 2024
Publication
In this work the design and modeling of a fuel cell vehicle using low-loading platinum catalysts were investigated. Data from single fuel cells with low Pt-loading cathode catalysts were scaled up to fuel cell stacks and systems implemented in a vehicle and then compared to a commercial fuel cell vehicle. The low-loading Pt systems have shown lower efficiency at high loads compared to the commercial systems suggesting less stable materials. However the analysis showed that the vehicle comprising low-loading Pt catalysts achieves similar or higher efficiency compared to the commercial fuel cell vehicle when being scaled up for the same number of cells. When the systems were scaled up for the same maximum power as the commercial fuel cell vehicle all the low-loading Pt fuel cell systems showed higher efficiencies. In this case more cells are needed but still the amount of Pt is significantly reduced compared to the commercial one. The high-efficiency results can be associated with the vehicle’s power range operation that meets the region where the low-loading Pt fuel cells have high performance. The results suggested a positive direction towards the reduction of Pt in commercial fuel cell vehicles supporting a cost-competitive clean energy transition based on hydrogen.
No more items...