Applications & Pathways
A Combined Heat and Green Hydrogen (CHH) Generator Integrated with a Heat Network
Sep 2021
Publication
Combined heat and power (CHP) systems offer high energy efficiencies as they utilise both the electricity generated and any excess heat by co-suppling to local consumers. This work presents the potential of a combined heat and hydrogen (CHH) system a solution where Proton exchange membrane (PEM) electrolysis systems producing hydrogen at 60–70% efficiency also co-supply the excess heat to local heat networks. This work investigates the method of capture and utilisation of the excess heat from electrolysis. The analysed system was able to capture 312 kW of thermal energy per MW of electricity and can deliver it as heated water at either 75 ◦C or 45 ◦C this appropriate for existing district heat networks and lower temperature heat networks respectively. This yields an overall CHH system efficiency of 94.6%. An economic analysis was conducted based on income generated through revenue sales of both hydrogen and heat which resulted in a significant reduction in the Levelized Cost of Hydrogen.
Improved VSG Control Strategy Based on the Combined Power Generation System with Hydrogen Fuel Cells and Super Capacitors
Oct 2021
Publication
Due to their environmental protection and high power generation efficiency the control technology of hydrogen fuel cells (HFCs) connected to the microgrid has become a research hotspot. However when they encounter peak demand or transient events the lack of power cannot be compensated immediately by HFCs which results in sudden changes of the voltage and frequency. The improved virtual synchronous generator (VSG) control strategy based on HFCs and supercapacitors (SCs) combined power generation system is proposed to overcome this shortcoming in this paper. The small-signal model for designing the combined system parameters is provided which are in accordance with the system loop gain phase angle margin and adjustment time requirements. Besides the voltage and current double closed-loop based on sequence control is introduced in the VSG controller. The second-order generalized integrator (SOGI) is utilized to separate the positive and negative sequence components of the output voltage. At the same time a positive and negative sequence voltage outer loop is designed to suppress the negative sequence voltage under unbalanced conditions thereby reducing the unbalance of the output voltage. Finally simulation results in MATLAB/Simulink environment verify that the proposed method has better dynamic characteristics and higher steady-state accuracy compared with the traditional VSG control
The Maritime Sector and Its Problematic Decarbonization: A Systematic Review of the Contribution of Alternative Fuels
May 2022
Publication
The present study seeks to select the most important articles and reviews from the Web of Science database that approached alternative fuels towards the decarbonization of the maritime sector. Through a systematic review methodology a combination of keywords and manual refining found a contribution of 103 works worldwide the European continent accounting for 57% of all publications. Twenty-two types of fuels were cited by the authors liquefied natural gas (LNG) hydrogen and biodiesel contributing to 49% of the mentions. Greenhouse gases sulfur oxide nitrogen oxide and particulate matter reductions are some of the main advantages of cleaner sources if used by the vessels. Nevertheless there is a lack of practical research on new standards engine performance cost and regulations from the academy to direct more stakeholders towards low carbon intensity in the shipping sector.
Modeling the Effects of Implementation of Alternative Ways of Vehicle Powering
Nov 2021
Publication
The trend to replace traditional fossil fuel vehicles is becoming increasingly apparent. The replacement concerns the use of pure biofuels or in blends with traditional fuels the use of hydrogen as an alternative fuel and above all the introduction of electric propulsion. The introduction of new types of vehicle propulsion affects the demand for specific fuels the needs for new infrastructure or the nature of the emissions to the environment generated by fuel production and vehicle operation. The article presents a mathematical model using the difference of two logistic functions the first of which describes the development of the production of a specific type of vehicle and the second the withdrawal of this type of vehicle from traffic after its use. The model makes it possible to forecast both the number of vehicles of each generation as a function of time as well as changes in energy demand from various sources and changes in exhaust emissions. The results of the numerical simulation show replacing classic vehicles with alternative vehicles increases the total energy demand if the generation of the next generation occurs earlier than the decay of the previous generation of vehicles and may decrease in the case of overlapping or delays in the creation of new vehicles compared to the course of the decay function of the previous generation. For electric vehicles carbon dioxide emissions are largely dependent on the emissions from electricity generation. The proposed model can be used to forecast technology development variants as well as analyze the current situation based on the approximation of real data from Vehicle Registration Offices.
1921–2021: A Century of Renewable Ammonia Synthesis
Apr 2022
Publication
Synthetic ammonia manufactured by the Haber–Bosch process and its variants is the key to securing global food security. Hydrogen is the most important feedstock for all synthetic ammonia processes. Renewable ammonia production relies on hydrogen generated by water electrolysis using electricity generated from hydropower. This was used commercially as early as 1921. In the present work we discuss how renewable ammonia production subsequently emerged in those countries endowed with abundant hydropower and in particular in regions with limited or no oil gas and coal deposits. Thus renewable ammonia played an important role in national food security for countries without fossil fuel resources until after the mid-20th century. For economic reasons renewable ammonia production declined from the 1960s onward in favor of fossil-based ammonia production. However renewable ammonia has recently gained traction again as an energy vector. It is an important component of the rapidly emerging hydrogen economy. Renewable ammonia will probably play a significant role in maintaining national and global energy and food security during the 21st century.
Review of the Hydrogen Permeability of the Liner Material of Type IV On-Board Hydrogen Storage Tank
Aug 2021
Publication
The hydrogen storage tank is a key parameter of the hydrogen storage system in hydrogen fuel cell vehicles (HFCVs) as its safety determines the commercialization of HFCVs. Compared with other types the type IV hydrogen storage tank which consists of a polymer liner has the advantages of low cost lightweight and low storage energy consumption but meanwhile higher hydrogen permeability. A detailed review of the existing research on hydrogen permeability of the liner material of type IV hydrogen storage tanks can improve the understanding of the hydrogen permeation mechanism and provide references for following-up researchers and research on the safety of HFCVs. The process of hydrogen permeation and test methods are firstly discussed in detail. This paper then analyzes the factors that affect the process of hydrogen permeation and the barrier mechanism of the liner material and summarizes the prediction models of gas permeation. In addition to the above analysis and comments future research on the permeability of the liner material of the type IV hydrogen storage tank is prospected.
Hydrogen-powered Aviation and its Reliance on Green Hydrogen Infrastructure - Review and Research Gaps
Oct 2021
Publication
Aircraft powered by green hydrogen (H2) are a lever for the aviation sector to reduce the climate impact. Previous research already focused on evaluations of H2 aircraft technology but analyses on infrastructure related cost factors are rarely undertaken. Therefore this paper aims to provide a holistic overview of previous efforts and introduces an approach to assess the importance of a H2 infrastructure for aviation. A short and a medium-range aircraft are modelled and modified for H2 propulsion. Based on these a detailed cost analysis is used to compare both aircraft and infrastructure related direct operating costs (DOC). Overall it is shown that the economy of H2 aviation highly depends on the availability of low-cost green liquid hydrogen (LH2) supply infrastructure. While total DOC might even slightly decrease in a best LH2 cost case total DOC could also increase between 10 and 70% (short-range) and 15e102% (medium-range) due to LH2 costs alone.
Our Green Print: Future Heat for Everyone
Jul 2021
Publication
Green Print - Future Heat for Everyone draws together technical consumer and economic considerations to create a pioneering plan to transition 22 million UK homes to low carbon heat by 2050.<br/>Our Green Print underlines the scale of the challenge ahead acknowledging that a mosaic of low carbon heating solutions will be required to meet the needs of individual communities and setting out 12 key steps that can be taken now in order to get us there<br/>The Climate Change Committee (CCC) estimates an investment spend of £250bn to upgrade insulation and heating in homes as well as provide the infrastructure to deliver the energy.<br/>This is a task of unprecedented scale the equivalent of retro-fitting 67000 homes every month from now until 2050. In this Report Cadent takes the industry lead in addressing the challenge.
Development and Operation Modes of Hydrogen Fuel Cell Generation System for Remote Consumers’ Power Supply
Aug 2021
Publication
At the present stage of electric power industry development special attention is being paid to the development and research of new efficient energy sources. The use of hydrogen fuel cells is promising for remote autonomous power supply systems. The authors of the paper have developed the structure and determined the optimal composition of a hybrid generation system based on hydrogen fuel cells and battery storage and have conducted studies of its operating modes and for remote consumers’ power supply efficiency. A simulation of the electromagnetic processes was carried out to check the operability of the proposed hybrid generation system structure. The simulation results confirmed the operability of the structure under consideration the calculation of its parameters reliability and the high quality of the output voltage. The electricity cost of a hybrid generation system was estimated according to the LCOE (levelized cost of energy) indicator its value being 1.17 USD/kWh. The factors influencing the electricity cost of a hydrogen generation system have been determined and ways for reducing its cost identified.
An Evaluation of Turbocharging and Supercharging Options for High-Efficiency Fuel Cell Electric Vehicles
Dec 2018
Publication
Mass-produced off-the-shelf automotive air compressors cannot be directly used for boosting a fuel cell vehicle (FCV) application in the same way that they are used in internal combustion engines since the requirements are different. These include a high pressure ratio a low mass flow rate a high efficiency requirement and a compact size. From the established fuel cell types the most promising for application in passenger cars or light commercial vehicle applications is the proton exchange membrane fuel cell (PEMFC) operating at around 80 ◦C. In this case an electric-assisted turbocharger (E-turbocharger) and electric supercharger (single or two-stage) are more suitable than screw and scroll compressors. In order to determine which type of these boosting options is the most suitable for FCV application and assess their individual merits a co-simulation of FCV powertrains between GT-SUITE and MATLAB/SIMULINK is realised to compare vehicle performance on the Worldwide Harmonised Light Vehicle Test Procedure (WLTP) driving cycle. The results showed that the vehicle equipped with an E-turbocharger had higher performance than the vehicle equipped with a two-stage compressor in the aspects of electric system efficiency (+1.6%) and driving range (+3.7%); however for the same maximal output power the vehicle’s stack was 12.5% heavier and larger. Then due to the existence of the turbine the E-turbocharger led to higher performance than the single-stage compressor for the same stack size. The solid oxide fuel cell is also promising for transportation application especially for a use as range extender. The results show that a 24-kWh electric vehicle can increase its driving range by 252% due to a 5 kW solid oxide fuel cell (SOFC) stack and a gas turbine recovery system. The WLTP driving range depends on the charge cycle but with a pure hydrogen tank of 6.2 kg the vehicle can reach more than 600 km.
Future of Hydrogen as an Alternative Fuel for Next-Generation Industrial Applications; Challenges and Expected Opportunities
Jun 2022
Publication
A general rise in environmental and anthropogenically induced greenhouse gas emissions has resulted from worldwide population growth and a growing appetite for clean energy industrial outputs and consumer utilization. Furthermore well-established advanced and emerging countries are seeking fossil fuel and petroleum resources to support their aviation electric utilities industrial sectors and consumer processing essentials. There is an increasing tendency to overcome these challenging concerns and achieve the Paris Agreement’s priorities as emerging technological advances in clean energy technologies progress. Hydrogen is expected to be implemented in various production applications as a fundamental fuel in future energy carrier materials development and manufacturing processes. This paper summarizes recent developments and hydrogen technologies in fuel refining hydrocarbon processing materials manufacturing pharmaceuticals aircraft construction electronics and other hydrogen applications. It also highlights the existing industrialization scenario and describes prospective innovations including theoretical scientific advancements green raw materials production potential exploration and renewable resource integration. Moreover this article further discusses some socioeconomic implications of hydrogen as a green resource.
An Overview of Promising Alternative Fuels for Road, Rail, Air, and Inland Waterway Transport in Germany
Feb 2022
Publication
To solve the challenge of decarbonizing the transport sector a broad variety of alternative fuels based on different concepts including Power-to-Gas and Power-to-Liquid and propulsion systems have been developed. The current research landscape is investigating either a selection of fuel options or a selection of criteria a comprehensive overview is missing so far. This study aims to close this gap by providing a holistic analysis of existing fuel and drivetrain options spanning production to utilization. For this purpose a case study for Germany is performed considering different vehicle classes in road rail inland waterway and air transport. The evaluated criteria on the production side include technical maturity costs as well as environmental impacts whereas on the utilization side possible blending with existing fossil fuels and the satisfaction of the required mission ranges are evaluated. Overall the fuels and propulsion systems Methanol-to-Gasoline Fischer–Tropsch diesel and kerosene hydrogen battery-electric propulsion HVO DME and natural gas are identified as promising future options. All of these promising fuels could reach near-zero greenhouse gas emissions bounded to some mandatory preconditions. However the current research landscape is characterized by high insecurity with regard to fuel costs depending on the predicted range and length of value chains.
A Review of the Integrated Renewable Energy Systems for Sustainable Urban Mobility
Aug 2022
Publication
Several challenges have emerged due to the increasing deterioration of urban mobility and its severe impacts on the environment and human health. Primary dependence on internal combustion engines that use petrol or diesel has led to poor air quality time losses noise traffic jams and further environmental pollution. Hence the transitions to using rail and or seaway-based public transportation cleaner fuels and electric vehicles are some of the ultimate goals of urban and national decision-makers. However battery natural gas hybrid and fuel cell vehicles require charging stations to be readily available with a sustainable energy supply within urban regions in different residential and business neighborhoods. This study aims to provide an updated and critical review of the concept and recent examples of urban mobility and transportation modes. It also highlights the adverse impacts of several air pollutants emitted from internal combustion engine vehicles. It also aims to shed light on several possible systems that integrate the electric vehicle stations with renewable energy sources. It was found that using certain components within the integrated system and connecting the charging stations with a grid can possibly provide an uninterrupted power supply to electric vehicles leading to less pollution which would encourage users to use more clean vehicles. In addition the environmental impact assessments as well as several implementation challenges are discussed. To this end the main implementation issues related to consumer incentives infrastructure and recommendations are also reported.
Studies Concerning Electrical Repowering of a Training Airplane Using Hydrogen Fuel Cells
Mar 2024
Publication
The increase in greenhouse gas emissions as well as the risk of fossil fuel depletion has prompted a transition to electric transportation. The European Union aims to substantially reduce pollutant emissions by 2035 through the use of renewable energies. In aviation this transition is particularly challenging mainly due to the weight of onboard equipment. Traditional electric motors with radial magnetic flux have been replaced by axial magnetic flux motors with reduced weight and volume high efficiency power and torque. These motors were initially developed for electric vehicles with in-wheel motors but have been adapted for aviation without modifications. Worldwide there are already companies developing propulsion systems for various aircraft categories using such electric motors. One category of aircraft that could benefit from this electric motor development is traditionally constructed training aircraft with significant remaining flight resource. Electric repowering would allow their continued use for pilot training preparing them for future electrically powered aircraft. This article presents a study on the feasibility of repowering a classic training aircraft with an electric propulsion system. The possibilities of using either a battery or a hybrid source composed of a battery and a fuel cell as an energy source are explored. The goal is to utilize components already in production to eliminate the research phase for specific aircraft components.
Ammonia as Hydrogen Carrier for Transportation; Investigation of the Ammonia Exhaust Gas Fuel Reforming
Jun 2013
Publication
In this paper we show for the first time the feasibility of ammonia exhaust gas reforming as a strategy for hydrogen production used in transportation. The application of the reforming process and the impact of the product on diesel combustion and emissions were evaluated. The research was started with an initial study of ammonia autothermal reforming (NH3 e ATR) that combined selective oxidation of ammonia (into nitrogen and water) and ammonia thermal decomposition over a ruthenium catalyst using air as the oxygen source. The air was later replaced by real diesel engine exhaust gas to provide the oxygen needed for the exothermic reactions to raise the temperature and promote the NH3 decomposition. The main parameters varied in the reforming experiments are O2/NH3 ratios NH3 concentration in feed gas and gas e hourly e space e velocity (GHSV). The O2/NH3 ratio and NH3 concentration were the key factors that dominated both the hydrogen production and the reforming process efficiencies: by applying an O2/NH3 ratio ranged from 0.04 to 0.175 2.5e3.2 l/min of gaseous H2 production was achieved using a fixed NH3 feed flow of 3 l/min. The reforming reactor products at different concentrations (H2 and unconverted NH3) were then added into a diesel engine intake. The addition of considerably small amount of carbon e free reformate i.e. represented by 5% of primary diesel replacement reduced quite effectively the engine carbon emissions including CO2 CO and total hydrocarbons.
Regional Uptake of Direct Reduction Iron Production Using Hydrogen Under Climate Policy
Nov 2022
Publication
The need to reduce CO2 emissions to zero by 2050 has meant an increasing focus on high emitting industrial sectors such as steel. However significant uncertainties remain as to the rate of technology diffusion across steel production pathways in different regions and how this might impact on climate ambition. Informed by empirical analysis of historical transitions this paper presents modelling on the regional deployment of Direction Reduction Iron using hydrogen (DRI-H2). We find that DRI-H2 can play a leading role in the decarbonisation of the sector leading to near-zero emissions by 2070. Regional spillovers from early to late adopting regions can speed up the rate of deployment of DRI-H2 leading to lower cumulative emissions and system costs. Without such effects cumulative emissions are 13% higher than if spillovers are assumed and approximately 15% and 20% higher in China and India respectively. Given the estimates of DRI-H2 cost-effectiveness relative to other primary production technologies we also find that costs increase in the absence of regional spillovers. However other factors can also have impacts on deployment emission reductions and costs including the composition of the early adopter group material efficiency improvements and scrap recycling rates. For the sector to achieve decarbonisation key regions will need to continue to invest in low carbon steel projects recognising their broader global benefit and look to develop and strengthen policy coordination on technologies such as DRI-H2.
High Technical and Temporal Resolution Integrated Energy System Modelling of Industrial Decarbonisation
Aug 2022
Publication
Owing to the complexity of the sector industrial activities are often represented with limited technological resolution in integrated energy system models. In this study we enriched the technological description of industrial activities in the integrated energy system analysis optimisation (IESA-Opt) model a peer-reviewed energy system optimisation model that can simultaneously provide optimal capacity planning for the hourly operation of all integrated sectors. We used this enriched model to analyse the industrial decarbonisation of the Netherlands for four key activities: high-value chemicals hydrocarbons ammonia and steel production. The analyses performed comprised 1) exploring optimality in a reference scenario; 2) exploring the feasibility and implications of four extreme industrial cases with different technological archetypes namely a bio-based industry a hydrogen-based industry a fully electrified industry and retrofitting of current assets into carbon capture utilisation and storage; and 3) performing sensitivity analyses on key topics such as imported biomass hydrogen and natural gas prices carbon storage potentials technological learning and the demand for olefins. The results of this study show that it is feasible for the energy system to have a fully bio-based hydrogen-based fully electrified and retrofitted industry to achieve full decarbonisation while allowing for an optimal technological mix to yield at least a 10% cheaper transition. We also show that owing to the high predominance of the fuel component in the levelled cost of industrial products substantial reductions in overnight investment costs of green technologies have a limited effect on their adoption. Finally we reveal that based on the current (2022) energy prices the energy transition is cost-effective and fossil fuels can be fully displaced from industry and the national mix by 2050
Hydrogen Fuel Cell Vehicle Development in China: An Industry Chain Perspective
Jun 2020
Publication
Hydrogen fuel cell vehicle (FCV) technology has significant implications on energy security and environmental protection. In the past decade China has made great progress in the hydrogen and FCV industry considering both the government’s policy issuances and enterprises’ production. However there are still some technological and cost challenges obstructing the commercialization of FCVs. Herein the status of China’s hydrogen FCV industry is analyzed comprehensively from three perspectives: policy support market application and technology readiness level. The unique characteristics and key issues in each part of the industry chain are emphasized. Furthermore the energy environmental and economic performances of FCV in the life-cycle perspective are reviewed and summarized based on pre-existing literature and reports. The life-cycle analysis of hydrogen and FCV indicates that the energy and environmental impacts of FCVs are highly related to the sources of hydrogen. With the combination of industry status and technology performances it is highlighted that technology advancements in hydrogen production and fuel cells and the optimization of the manufacturing processes for fuel cell systems are equally essential in the development of hydrogen FCVs.
Life Cycle Cost Analysis for Scotland Short-Sea Ferries
Feb 2023
Publication
The pathway to zero carbon emissions passing through carbon emissions reduction is mandatory in the shipping industry. Regarding the various methodologies and technologies reviewed for this purpose Life Cycle Cost Analysis (LCCA) has been used as an excellent tool to determine economic feasibility and sustainability and to present directions. However insufficient commercial applications cause a conflict of opinion on which fuel is the key to decarbonisation. Many LCCA comparison studies about eco-friendly ship propulsion claim different results. In order to overcome this and discover the key factors that affect the overall comparative analysis and results in the maritime field it is necessary to conduct the comparative analysis considering more diverse case ships case routes and various types that combine each system. This study aims to analyse which greener fuels are most economically beneficial for the shipping sector and prove the factors influencing different results in LCCA. This study was conducted on hydrogen ammonia and electric energy which are carbon-free fuels among various alternative fuels that are currently in the limelight. As the power source a PEMFC and battery were used as the main power source and a solar PV system was installed as an auxiliary power source to compare economic feasibility. Several cost data for LCCA were selected from various feasible case studies. As the difficulty caused by the storage and transportation of hydrogen and ammonia should not be underestimated in this study the LCCA considers not only the CapEx and OpEx but also fuel transport costs. As a result fuel cell propulsion systems with hydrogen as fuel proved financial effectiveness for short-distance ferries as they are more inexpensive than ammonia-fuelled PEMFCs and batteries. The fuel cost takes around half of the total life-cycle cost during the life span.
Hydrogen Refueling Process: Theory, Modeling, and In-Force Applications
Mar 2023
Publication
Among the alternative fuels enabling the energy transition hydrogen-based transportation is a sustainable and efficient choice. It finds application both in light-duty and heavy-duty mobility. However hydrogen gas has unique qualities that must be taken into account when employed in such vehicles: high-pressure levels up to 900 bar storage in composite tanks with a temperature limit of 85 ◦C and a negative Joule–Thomson coefficient throughout a wide range of operational parameters. Moreover to perform a refueling procedure that is closer to the driver’s expectations a fast process that requires pre-cooling the gas to −40 ◦C is necessary. The purpose of this work is to examine the major phenomena that occur during the hydrogen refueling process by analyzing the relevant theory and existing modeling methodologies.
No more items...