Applications & Pathways
A Quantitative Study of Policy-driven Changes and Forecasts in the Development of the Hydrogen Transportation Industry
Feb 2022
Publication
Through data mining and analysis of the word frequency and occurrence position of industrial policy keywords the main policy parameters affecting industrial development are determined and the functional relationship between industrial policy and industrial development is obtained through multi-parameter non-linear regression: Yit−1 (y1 y2 y3 y4 y5) = β1it X1 + β2it ln X2 + β3it ln X3 + β4it X1it ∗ ln X3 + εit . The time series function of the industrial development index: Y (t) = 0.174 ∗ e (0.256∗t) is established and the industrial development under the influence of next year’s policy is predicted. It is concluded from the mathematical expression of the statistical model that there is a certain coupling effect between different policies and that industrial development is influenced by the joint effect on the parent and sub-industries. This ultimately proves that there is a clear correlation between policy and industry development.
Waste Aluminum Application as Energy Valorization for Hydrogen Fuel Cells for Mobile Low Power Machines Applications
Nov 2021
Publication
This article proposes a new model of power supply for mobile low power machines applications between 10 W and 30 W such as radio-controlled (RC) electric cars. This power supply is based on general hydrogen from residual aluminum and water with NaOH so it is proposed energy valorization of aluminum waste. In the present research a theoretical model allows us to predict the requested aluminum surface and the required flow of hydrogen has been developed also considering in addition to the geometry and purity of the material two key variables as the temperature and the molarity of the alkaline solution used in the hydrogen production process. Focusing on hydrogen production isopropyl alcohol plays a key role in the reactor’s fuel cell vehicle as it filters out NaOH particles and maintains a constant flow of hydrogen for the operation of the machine keeping the reactor temperature controlled. Finally a comparison of the theoretical and experimental data has been used to validate the developed model using aluminum sheets from ring cans to generate hydrogen which will be used as a source of hydrogen in a power fuel cell of an RC car. Finally the manuscript shows the parts of the vehicle’s powertrain its behavior and mode of operation.
Import Options for Chemical Energy Carriers from Renewable Sources to Germany
Feb 2024
Publication
Import and export of fossil energy carriers are cornerstones of energy systems world-wide. If energy systems are to become climate neutral and sustainable fossil carriers need to be substituted with carbon neutral alternatives or electrified if possible. We investigate synthetic chemical energy carriers hydrogen methane methanol ammonia and Fischer-Tropsch fuels produced using electricity from Renewable Energy Source (RES) as fossil substitutes. RES potentials are obtained from GIS-analysis and hourly resolved time-series are derived using reanalysis weather data. We model the sourcing of feedstock chemicals synthesis and transport along nine different Energy Supply Chains to Germany and compare import options for seven locations around the world against each other and with domestically sourced alternatives on the basis of their respective cost per unit of hydrogen and energy delivered. We find that for each type of chemical energy carrier there is an import option with lower costs compared to domestic production in Germany. No single exporting country or energy carrier has a unique cost advantage since for each energy carrier and country there are cost-competitive alternatives. This allows exporter and infrastructure decisions to be made based on other criteria than energy and cost. The lowest cost means for importing of energy and hydrogen are by hydrogen pipeline from Denmark Spain and Western Asia and Northern Africa starting at 36 EUR/MWhLHV to 42 EUR/MWhLHV or 1.0 EUR/kgH2 to 1.3 EUR/kgH2 (in 2050 assuming 5% p.a. capital cost). For complex energy carriers derived from hydrogen like methane ammonia methanol or Fischer-Tropsch fuels imports from Argentina by ship to Germany are lower cost than closer exporters in the European Union or Western Asia and Northern Africa. For meeting hydrogen demand direct hydrogen imports are more attractive than indirect routes using methane methanol or ammonia imports and subsequent decomposition to hydrogen because of high capital investment costs and energetic losses of the indirect routes. We make our model and data available under open licenses for adaptation and reuse.
Hydrogen-electricity Hybrid Energy Pipelines for Railway Transportation: Design and Economic Evaluation
Mar 2024
Publication
With the decarbonization and electrification of modern railway transportation the demand for both the highcapacity electrical energy and hydrogen fuel energy is increasingly high. A novel scheme was proposed from liquid hydrogen production by surplus wind and solar energy to liquid hydrogen-electricity hybrid energy transmission for railway transportation. The 100 MW hybrid energy transmission pipeline was designed with the 10 kA/1.5 kV superconducting DC cable for electricity and cryogenic layers for liquid hydrogen and liquid nitrogen showing strong capability in transmitting “electricity + cold energy + chemical energy” simultaneously. Economic evaluation was performed with respect to the energy equipment capacity and costs with sensitivity and profitability analysis. With the discount rate 8% the dynamic payback period of the hybrid energy pipeline was 7.1 years. Results indicated that the shortest dynamic payback period of the hybrid energy pipeline was 4.8 years with the maximum transmission distance 93 km. Overall this article shows the novel concept and design of liquid hydrogen-electricity hybrid energy pipelines and proves the technical and economic feasibilities for future bulk hybrid energy transmission for railway transportation.
Supporting Hydrogen Technologies Deployment in EU Regions and Member States: The Smart Specialisation Platform on Energy (S3PEnergy)
May 2018
Publication
In order to maximise European national and regional research and innovation potential the European Union is investing in these fields through different funding mechanisms such as the ESIF or H2020 programme. This investment plan is part of the European 2020 strategy where the concept of Smart Specialisation is also included.<br/>Smart Specialisation is an innovation policy concept designed to promote the efficient and effective use of public investment in regional innovation in order to achieve economic growth. The Smart Specialisation Platform was created to support this concept by assisting regions and Member States in developing implementing and reviewing their research and innovation Smart Specialisation strategies.<br/>The Smart Specialisation Platform comprises several thematic platforms. The thematic Smart Specialisation Platform on energy (S3PEnergy) is a joint initiative of three European Commission services: DG REGIO DG ENER and the Joint Research Centre (JRC). The main objective of the S3PEnergy is to support the optimal and effective uptake of the Cohesion Policy funds for energy and to better align energy innovation activities at national local and regional level through the identification of the technologies and innovative solutions that support in the most cost-effective way the EU energy policy priorities.<br/>In the particular case of hydrogen technologies the activities of the platform are mainly focused on supporting the new Fuel Cells and Hydrogen Joint Undertaking (FCH JU) initiative involving regions and cities. To date more than 80 European cities and regions have committed to participate in this initiative through the signature of a Memorandum of Understanding and more participants are expected to join. S3PEnergy is helping in the identification of potential combination of H2020 funding (provided through FCH JU) and ESIF.<br/>To identify potential synergies among these two funding sources a mapping of the different ESIF opportunities has been performed. In order to map these opportunities Operational Programmes (OPs) and research and innovation strategies for Smart Specialisation (RIS3) of the different European regions and Member States were analysed. The results of this mapping and analysis are presented in this paper."
Hydrogen Diffusion and Its Effect on Hydrogen Embrittlement in DP Steels with Different Martensite Content
Dec 2020
Publication
The hydrogen diffusion behavior and hydrogen embrittlement susceptibility of dual phase (DP) steels with different martensite content were investigated using the slow strain-rate tensile test and hydrogen permeation measurement. Results showed that a logarithmic relationship was established between the hydrogen embrittlement index (IHE) and the effective hydrogen diffusion coefficient (Deff). When the martensite content is low ferrite/ martensite interface behaves as the main trap that captures the hydrogen atoms. Also when the Deff decreases IHE increases with increasing martensite content. However when the martensite content reaches approximately 68.3% the martensite grains start to form a continuous network Deff reaches a plateau and IHE continues to increase. This is mainly related to the reduction of carbon content in martensite and the length of ferrite/martensite interface which promotes the diffusion of hydrogen atoms in martensite and the aggregation of hydrogen atoms at the ferrite/martensite interface. Finally a model describing the mechanism of microstructure-driven hydrogen diffusion with different martensite distribution was established.
Hydrogen Direct Injection: Optical Investigation of Premixed and Jet-guided Combustion Modes
Mar 2024
Publication
The classical approach to use hydrogen as a fuel for Internal Combustion Engines (ICEs) is premixed combustion. In order to avoid knocking and to limit NOx emissions very lean mixtures are employed thus resulting in a high boost pressure demand or low specific engine power. To overcome these limitations the possibility of a diesellike jet-guided combustion of hydrogen is explored. The approach is to ignite a directly injected hydrogen jet at its periphery by means of a conventional spark discharge followed by a diffusion-controlled combustion while injection remains active. An optically accessible Rapid Compression Expansion Machine (RCEM) is used to investigate ignition and combustion of underexpanded hydrogen jets in air by means of simultaneous Schlieren visualization and OH chemiluminescence. Different injection and ignition timing are investigated resulting in premixed partially premixed and diffusion-controlled (jet-guided) combustion conditions. The possibility of ignition and combustion of the hydrogen jets in diffusion-controlled conditions is investigated for different orientations of the incoming fuel jet with respect to spark location. The combustion tests are analyzed in terms of ignition success rate ignition delay reacting surface and heat release rate and an optimal orientation of the jet is assessed. The present study provides insights for optimizing hydrogen direct injection ignition and combustion for later application in ICEs.
Research on Multi-Period Hydrogen Refueling Station Location Model in Jiading District
Sep 2021
Publication
The construction of hydrogen refueling stations is an important part of the promotion of fuel cell vehicles. In this paper a multi-period hydrogen refueling station location model is presented that can be applied to the planning and construction of hydrogen infrastructures. Based on the hydrogen demand of fuel cell passenger cars and commercial vehicles the model calculates the hydrogen demand of each zone by a weighting method according to population economic level and education level. Then the hydrogen demand of each period is calculated using the generalized Bass diffusion model. Finally the set covering model is improved to determine the locations of the stations. The new model is applied to the scientific planning of hydrogen refueling stations in Jiading District Shanghai; the construction location and sequence of hydrogen refueling stations in each period are given and the growth trend of hydrogen demand and the promoting effect of hydrogen refueling stations are analyzed. The model adopted in this model is then compared with the other two kinds of node-based hydrogen refueling station location models that have previously been proposed.
Economic Operation Strategy of Integrated Hydrogen Energy System Considering the Uncertainty of PV Power Output
Jan 2023
Publication
To address the negative influence caused by power randomness of distributed PV output on energy system’s economic operation in this work an economic operation strategy considering the uncertainty features of PV output has been designed and applied on an integrated hydrogen energy system. First the thermal system operation model and the thermoelectric output control model are precisely built for the integrated hydrogen energy system and the hydrogen-based fuel cell respectively. Then referring to the PV output prediction data the uncertainty of light intensity variation is analyzed to correct the PV output prediction curve. Finally a cost–benefit model for the optimal economic operation of the integrated hydrogen energy system including PV hydrogen fuel cell and cogeneration unit is designed with an objective function of achieving an optimal economic operation of the multi-energy coupling devices. The simulation tests validate that considering the influence of PV output uncertainty on hydrogen fuel cell output can make the system operation more reasonable which ensures the economic and reliable operation of hydrogen energy systems.
Incorporating Homeowners' Preferences of Heating Technologies in the UK TIMES Model
Feb 2018
Publication
Hot water and space heating account for about 80% of total energy consumption in the residential sector in the UK. It is thus crucial to decarbonise residential heating to achieve UK's 2050 greenhouse gas reduction targets. However the decarbonisation transitions determined by most techno-economic energy system models might be too optimistic or misleading for relying on cost minimisation alone and not considering households' preferences for different heating technologies. This study thus proposes a novel framework to incorporate heterogeneous households' (HHs) preferences into the modelling process of the UK TIMES model. The incorporated preferences for HHs are based on a nationwide survey on homeowners' choices of heating technologies. Preference constraints are then applied to regulate the HHs' choices of heating technologies to reflect the survey results. Consequently compared to the least cost transition pathway the preference-driven pathway adopts heating technologies gradually without abrupt increases of market shares. Heat pumps and electric heaters are deployed much less than in the cost optimal result. Extensive district heating using low-carbon fuels and conservation measures should thus be deployed to provide flexibility for decarbonisation. The proposed framework can also incorporate preferences for other energy consumption technologies and be applied to other linear programming based energy system models.
Are Scenarios of Hydrogen Vehicle Adoption Optimistic? A Comparison with Historical Analogies
Nov 2015
Publication
There is a large literature exploring possible hydrogen futures using various modelling and scenario approaches. This paper compares the rates of transition depicted in that literature with a set of historical analogies. These analogies are cases in which alternative-fuelled vehicles have penetrated vehicle markets. The paper suggests that the literature has tended to be optimistic about the possible rate at which hydrogen vehicles might replace oil-based transportation. The paper compares 11 historical adoptions of alternative fuel vehicles with 24 scenarios from 20 studies that depict possible hydrogen futures. All but one of the hydrogen scenarios show vehicle adoption faster than has occurred for hybrid electric vehicles in Japan the most successful market for hybrids. Several scenarios depict hydrogen transitions occurring at a rate faster than has occurred in any of the historic examples. The paper concludes that scenarios of alternative vehicle adoption should include more pessimistic scenarios alongside optimistic ones.
Expectations as a Key to Understanding Actor Strategies in the Field of Fuel Cell and Hydrogen Vehicles
Feb 2012
Publication
Due to its environmental impact the mobility system is increasingly under pressure. The challenges to cope with climate change air quality depleting fossil resources imply the need for a transition of the current mobility system towards a more sustainable one. Expectations and visions have been identified as crucial in the guidance of such transitions and more specifically of actor strategies. Still it remained unclear why the actors involved in transition activities appear to change their strategies frequently and suddenly. The empirical analysis of the expectations and strategies of three actors in the field of hydrogen and fuel cell technology indicates that changing actor strategies can be explained by rather volatile expectations related to different levels. Our case studies of the strategies of two large car manufacturers and the German government demonstrate that the car manufacturers refer strongly to expectations about the future regime while expectations related to the socio-technical landscape level appear to be crucial for the strategy of the German government.
Hydrogen Intensified Synthesis Processes to Valorise Process Off-gases in Integrated Steelworks
Jul 2023
Publication
Ismael Matino,
Stefano Dettori,
Amaia Sasiain Conde,
Valentina Colla,
Alice Petrucciani,
Antonella Zaccara,
Vincenzo Iannino,
Claudio Mocci,
Alexander Hauser,
Sebastian Kolb,
Jürgen Karl,
Philipp Wolf-Zoellner,
Stephane Haag,
Michael Bampaou,
Kyriakos Panopoulos,
Eleni Heracleousa,
Nina Kieberger,
Katharina Rechberger,
Leokadia Rog and
Przemyslaw Rompalski
Integrated steelworks off-gases are generally exploited to produce heat and electricity. However further valorization can be achieved by using them as feedstock for the synthesis of valuable products such as methane and methanol with the addition of renewable hydrogen. This was the aim of the recently concluded project entitled “Intelligent and integrated upgrade of carbon sources in steel industries through hydrogen intensified synthesis processes (i3 upgrade)”. Within this project several activities were carried out: from laboratory analyses to simulation investigations from design development and tests of innovative reactor concepts and of advanced process control to detailed economic analyses business models and investigation of implementation cases. The final developed methane production reactors arerespectively an additively manufactured structured fixedbed reactor and a reactor setup using wash-coated honeycomb monoliths as catalyst; both reactors reached almost full COx conversion under slightly over-stoichiometric conditions. A new multi-stage concept of methanol reactor was designed commissioned and extensively tested at pilot-scale; it shows very effective conversion rates near to 100% for CO and slightly lower for CO2 at one-through operation for the methanol synthesis. Online tests proved that developed dispatch controller implements a smooth control strategy in real time with a temporal resolution of 1 min and a forecasting horizon of 2 h. Furthermore both offline simulations and cost analyses highlighted the fundamental role of hydrogen availability and costs for the feasibility of i 3 upgrade solutions and showed that the industrial implementation of the i 3 upgrade solutions can lead to significant environmental and economic benefits for steelworks especially in case green electricity is available at an affordable price.
What is the Energy Balance of Electrofuels Produced Through Power-to-fuel Integration with Biogas Facilities?
Nov 2021
Publication
The need to reduce the climate impact of the transport sector has led to an increasing interest in the utilisation of alternative fuels. Producing advanced fuels through the integration of anaerobic digestion and power-to-fuel technologies may offer a solution to reduce greenhouse gas emissions from difficult to decarbonise modes of transport such as heavy goods vehicles shipping and commercial aviation while also offering wider system benefits. This paper investigates the energy balance of power-to-fuel (power-to-methane power-to-methanol power-to-Fischer-Tropsch fuels) production integrated with a biogas facility co-digesting grass silage and dairy slurry. Through the integration of power-to-methane with anaerobic digestion an increase in system gross energy of 62.6% was found. Power-to-methanol integration with the biogas system increased the gross energy by 50% while power-to-Fischer-Tropsch fuels increased the gross energy yield by 32%. The parasitic energy demand for hydrogen production was highlighted as the most significant factor for integrated biogas and power-to-fuel facilities. Consuming electricity that would otherwise have been curtailed and optimising the anaerobic digestion process were identified as key to improving the energetic efficiency of all system configurations. However the broad cross-sectoral benefits of the overarching cascading circular economy system such as providing electrical grid stability and utilising waste resources must also be considered for a comprehensive perspective on the integration of anaerobic digestion and power-to-fuel.
Modeling of Fixed Bed Reactor for Coal Tar Hydrogenation via the Kinetic Lumping Approach
Nov 2018
Publication
Hydrogenation technology is an indispensable chemical upgrading process for converting the heavy feedstock into favorable lighter products. In this work a new kinetic model containing four hydrocarbon lumps (feedstock diesel gasoline cracking gas) was developed to describe the coal tar hydrogenation process the Levenberg–Marquardt’s optimization algorithm was used to determine the kinetic parameters by minimizing the sum of square errors between experimental and calculated data the predictions from model validation showed a good agreement with experimental values. Subsequently an adiabatic reactor model based on proposed lumped kinetic model was constructed to further investigate the performance of hydrogenation fixed-bed units the mass balance and energy balance within the phases in the reactor were taken into accounts in the form of ordinary differential equation. An application of the reactor model was performed for simulating the actual bench-scale plant of coal tar hydrogenation the simulated results on the products yields and temperatures distribution along with the reactor are shown to be good consistent with the experimental data.
Transitioning to Hydrogen
Jan 2020
Publication
The UK is investigating supplying hydrogen to homes and businesses instead of natural gas by “repurposing” the gas network. It presents a major engineering challenge which has never been done anywhere else in the world.
In a new report titled ‘Transitioning to hydrogen’ experts from a cross-professional engineering institution (PEI) working group including the IET have assessed the engineering risks and uncertainties and concluded there is no reason why repurposing the gas network to hydrogen cannot be achieved. But there are several engineering risks and uncertainties which need to be addressed.
In a new report titled ‘Transitioning to hydrogen’ experts from a cross-professional engineering institution (PEI) working group including the IET have assessed the engineering risks and uncertainties and concluded there is no reason why repurposing the gas network to hydrogen cannot be achieved. But there are several engineering risks and uncertainties which need to be addressed.
Performing While Transforming: The Role of Transmission Companies in the Energy Transition
Jun 2020
Publication
As the world prepares to exit from the COVID-19 crisis the pace of the global power revolution is expected to accelerate. A new publication from the World Energy Council in collaboration with PwC underscores the imperative for electricity grid owners and operators to fundamentally transform themselves to secure a role in a more integrated flexible and smarter electricity system in the energy transition to a low carbon future.
“Performing While Transforming: The Role of Transmission Companies in the Energy Transition” is based on in-depth interviews with CEOs and senior leaders from 37 transmission companies representing 35 countries and over 4 million kilometres – near global coverage - of the transmission network. While their roles will evolve transmission companies will remain at the heart of the electricity grid and need to balance the challenges of keeping the lights on while transforming themselves for the future.
The publication explores the various challenges affecting how transmission companies prepare and re-think their operations and business models and leverages the insights from interviewees to highlight four recommendations for transmission companies to consider in their journey:
“Performing While Transforming: The Role of Transmission Companies in the Energy Transition” is based on in-depth interviews with CEOs and senior leaders from 37 transmission companies representing 35 countries and over 4 million kilometres – near global coverage - of the transmission network. While their roles will evolve transmission companies will remain at the heart of the electricity grid and need to balance the challenges of keeping the lights on while transforming themselves for the future.
The publication explores the various challenges affecting how transmission companies prepare and re-think their operations and business models and leverages the insights from interviewees to highlight four recommendations for transmission companies to consider in their journey:
- Focus on the future through enhanced forecasting and scenario planning
- Shape the ecosystem by collaborating with new actors and enhancing interconnectivity
- Embrace automation and technology to optimise processes and ensure digital delivery
- Transform organisation to attract new talent and maintain social licence with consumers
Hydrogen-related Challenges for the Steelmaker: The Search for Proper Testing
Jun 2017
Publication
The modern steelmaker of advanced high-strength steels has always been challenged with the conflicting targets of increased strength while maintaining or improving ductility. These new steels help the transportation sector including the automotive sector to achieve the goals of increased passenger safety and reduced emissions. With increasing tensile strengths certain steels exhibit an increased sensitivity towards hydrogen embrittlement (HE). The ability to characterize the material's sensitivity in an as-delivered condition has been developed and accepted (SEP1970) but the complexity of the stress states that can induce an embrittlement together with the wide range of applications for high-strength steels make the development of a standardized test for HE under in-service conditions extremely challenging. Some proposals for evaluating the material's sensitivity give an advantage to materials with a low starting ductility. Despite this newly developed materials can have a higher original elongation with only a moderate reduction in elongation due to hydrogen. This work presents a characterization of new materials and their sensitivity towards HE.
This article is part of the themed issue ‘The challenges of hydrogen and metals’.
Link to document download on Royal Society Website
This article is part of the themed issue ‘The challenges of hydrogen and metals’.
Link to document download on Royal Society Website
Technology Assessment of Hydrogen Firing of Process Heaters
Apr 2011
Publication
In conjunction with John Zink Co. LLC the Chevron Energy Technology Company conducted a three part study evaluating potential issues with switching refinery process heaters from fuel gas to hydrogen fuel for the purpose of greenhouse gas emissions reduction via CO2 capture and storage.
The focus was on the following areas:
The focus was on the following areas:
- Heater performance
- Burner performance and robustness
- Fuel gas system retrofit requirements
Experimental Research on Low Calorific Value Gas Blended with Hydrogen Engine
Mar 2019
Publication
Experimental research on performance and emissions of engine fuelled with low calorific value gas blended with hydrogen was carried out and indicated thermal efficiency engine torque indicator diagram pressure rise rate and emissions with different hydrogen ratios were also analyzed. Experimental results show that with the increase of hydrogen fraction and CNG fraction in mixtures the indicated thermal efficiency increased. The engine power output is influenced by both low calorific value and hydrogen fractions. With the increase of hydrogen fraction in mixtures HC emissions decrease CO and NOx emissions increase. An engine operating on lean-burn low calorific value gas blended with hydrogen is favourable for getting lower emissions.
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