Australia
Towards Energy Freedom: Exploring Sustainable Solutions for Energy Independence and Self-sufficiency using Integrated Renewable Energy-driven Hydrogen System
Jan 2024
Publication
n the pursuit of sustainable energy solutions the integration of renewable energy sources and hydrogen technologies has emerged as a promising avenue. This paper introduces the Integrated Renewable Energy-Driven Hydrogen System as a holistic approach to achieve energy independence and self-sufficiency. Seamlessly integrating renewable energy sources hydrogen production storage and utilization this system enables diverse applications across various sectors. By harnessing solar and/or wind energy the Integrated Renewable EnergyDriven Hydrogen System optimizes energy generation distribution and storage. Employing a systematic methodology the paper thoroughly examines the advantages of this integrated system over other alternatives emphasizing its zero greenhouse gas emissions versatility energy resilience and potential for large-scale hydrogen production. Thus the proposed system sets our study apart offering a distinct and efficient alternative compared to conventional approaches. Recent advancements and challenges in hydrogen energy are also discussed highlighting increasing public awareness and technological progress. Findings reveal a payback period ranging from 2.8 to 6.7 years depending on the renewable energy configuration emphasizing the economic attractiveness and potential return on investment. This research significantly contributes to the ongoing discourse on renewable energy integration and underscores the viability of the Integrated Renewable EnergyDriven Hydrogen System as a transformative solution for achieving energy independence. The employed model is innovative and transferable to other contexts.
Dual Fuel-based Multi-Energy System for Australian Renewable Energy Zones at Country Scale
Jul 2025
Publication
This paper aims to optimize dual-fuel facilitated off-/on-grid multi-energy systems (MESs) for different renewable energy zones (REZs) in Australia. The main objective is to develop a novel MES with the main feature of green hydrogen production and blended natural gas utilization for remote households. The proposed optimal system produces green hydrogen of 5343 kg/yr via proton exchange membrane (PEM) electrolyzer and blends it with natural gas. It involves 20 % hydrogen and 80 % natural gas in the overall volume of the blending process. This study contributes by performing optimal sizing of the components economic-energy-environmental and performance analyses to examine the most feasible solution for each REZ. The results indicate that the optimal system in North Queensland REZ has the lowest levelized cost of energy (LCE) of 1.28 A$/kWh and 0.1003 A $/kWh and the net present cost (NPC) of A$0.311 million and A$0.219 million for off-grid and on-grid configurations. The optimal on-grid system has 95.27 % less carbon emissions than the natural gas-fueled combustion energy system.
Recent Progress and Techno-economic Analysis of Liquid Organic Hydrogen Carriers for Australian Renewable Energy Export - A Critical Review
Jan 2024
Publication
Hydrogen as a primary carbon-free energy carrier is confronted by challenges in storage and transportation. However liquid organic hydrogen carriers (LOHCs) present a promising solution for storing and transporting hydrogen at ambient temperature and atmospheric pressure. Unlike circular energy carriers such as methanol ammonia and synthetic natural gas LOHCs do not produce by-products during hydrogen recovery. LOHCs only act as hydrogen carriers and the carriers can also be recycled for reuse. Although there are considerable advantages to LOHCs there are also some drawbacks especially relative to the energy consumption during the dehydrogenation step of the LOHC recycling. This review summarizes the recent progresses in LOHC technologies focusing on catalyst developments process and reactor designs applications and techno-economic assessments (TEA). LOHC technologies can potentially offer significant benefits to Australia especially in terms of hydrogen as an export commodity. LOHCs can help avoid capital costs associated with infrastructure such as transportation vessels while reducing hydrogen loss during transportation such as in the case of liquid hydrogen (LH2). Additionally it minimises CO2 emissions as observed in methane and methanol reforming. Thus it is essential to dedicate more efforts to explore and develop LOHC technologies in the Australian context.
Upcycling of Plastic Wastes for Hydrogen Production: Advances and Perspectives
Feb 2024
Publication
The abundant plastic wastes become an imperative global issue and how to handle these organic wastes gains growing scientific and industrial interest. Recently converting plastic wastes into hydrogen fuel has been investigated and the “waste-to-value” practice accelerates the circular economy. To accelerate the development of plastic-to-hydrogen conversion in this review recent advances in plastic-to-hydrogen conversion via thermochemical photocatalytic and electrocatalytic routes are analyzed. All of the thermo- photo- and electrochemical processes can transform different plastic wastes into hydrogen and the hydrogen production efficiency depends heavily on the selected techniques operating parameters and applied catalysts. The application of rational-designed catalysts can promote the selective production of hydrogen from plastic feedstocks. Further studies on process optimization cost-effective catalyst design and mechanism investigation are needed.
A Review of Port Decarbonisation Options: Identified Opportunities for Deploying Hydrogen Technologies
Apr 2024
Publication
The utilisation of hydrogen is being explored as a viable solution for reducing carbon emissions in port operations with potential applications in cargo handling transportation and shipping vessel operations. To comprehensively list the decarbonisation options in ports this study conducted a Systematic Literature Review to identify and then survey twelve highly cited review papers. Initially a typology approach was used to categorise the decarbonisation options by activities and technologies. Subsequently the study introduced a novel Port Energy Map to reveal the energy system pathways and their interconnections. Each pathway was then converted into a simpler linear sequence of activities shown as a Port Energy System Taxonomy which outlines the energy supply and energy-using activities. By utilising this taxonomy and map the study identified opportunities and research gaps for integrating hydrogen technologies into port energy systems which serves as a valuable tool for assessing port decarbonisation options.
Work Efficiency and Economic Efficiency of Actual Driving Test of Proton Exchange Membrane Fuel Cell Forklift
Aug 2023
Publication
A 3.5 tonne forklift containing proton exchange membrane fuel cells (PEMFCs) and lithium-ion batteries was manufactured and tested in a real factory. The work efficiency and economic applicability of the PEMFC forklift were compared with that of a lithium-ion battery-powered forklift. The results showed that the back-pressure of air was closely related to the power density of the stack whose stability could be improved by a reasonable control strategy and membrane electrode assemblies (MEAs) with high consistency. The PEMFC powered forklift displayed 40.6% higher work efficiency than the lithium-ion battery-powered forklift. Its lower use-cost compared to internal engine-powered forklifts is beneficial to the commercialization of this product.
Underground Hydrogen Storage: Integrated Surface Facilities and Fluid Flow Modelling for Depleted Gas Reservoirs
Aug 2023
Publication
We report a new techno-economic model to assess performance and capital costs for large-scale underground hydrogen storage in depleted gas reservoirs. A simulation toolbox is developed to model surface facilities and to simulate the hydrogen flow in geological formations in an integrated fashion.<br/>Integrated modelling revealed the following key insights: 1) A buffer system is highly desirable to absorb inherent variability in upstream hydrogen production; 2) hydrogen mixing with existing gases in the reservoir together with gravity segregation and diffusion results in a decline in hydrogen purity at the wellhead over time and can require increased purification; 3) the capital cost is dominated by the cost of cushion gas (hydrogen) and the compression system where about 9% of the total energy content of the hydrogen is consumed for compression. The scenarios modelled in our study result in a levelized cost of storage in Australia ranging from 2.3 to 4.29 A$/(kg).
Synergistic Integration of Hydrogen Energy Economy with UK’s Sustainable Development Goals: A Holistic Approach to Enhancing Safety and Risk Mitigation
Oct 2023
Publication
Hydrogen is gaining prominence as a sustainable energy source in the UK aligning with the country’s commitment to advancing sustainable development across diverse sectors. However a rigorous examination of the interplay between the hydrogen economy and the Sustainable Development Goals (SDGs) is imperative. This study addresses this imperative by comprehensively assessing the risks associated with hydrogen production storage transportation and utilization. The overarching aim is to establish a robust framework that ensures the secure deployment and operation of hydrogen-based technologies within the UK’s sustainable development trajectory. Considering the unique characteristics of the UK’s energy landscape infrastructure and policy framework this paper presents practical and viable recommendations to facilitate the safe and effective integration of hydrogen energy into the UK’s SDGs. To facilitate sophisticated decision making it proposes using an advanced Decision-Making Trial and Evaluation Laboratory (DEMATEL) tool incorporating regret theory and a 2-tuple spherical linguistic environment. This tool enables a nuanced decision-making process yielding actionable insights. The analysis reveals that Incident Reporting and Learning Robust Regulatory Framework Safety Standards and Codes are pivotal safety factors. At the same time Clean Energy Access Climate Action and Industry Innovation and Infrastructure are identified as the most influential SDGs. This information provides valuable guidance for policymakers industry stakeholders and regulators. It empowers them to make well-informed strategic decisions and prioritize actions that bolster safety and sustainable development as the UK transitions towards a hydrogen-based energy system. Moreover the findings underscore the varying degrees of prominence among different SDGs. Notably SDG 13 (Climate Action) exhibits relatively lower overall distinction at 0.0066 and a Relation value of 0.0512 albeit with a substantial impact. In contrast SDG 7 (Clean Energy Access) and SDG 9 (Industry Innovation and Infrastructure) demonstrate moderate prominence levels (0.0559 and 0.0498 respectively) each with its unique influence emphasizing their critical roles in the UK’s pursuit of a sustainable hydrogen-based energy future.
Hydrogen-Powered Aircraft at Airports: A Review of the Infrastructure Requirements and Planning Challenges
Nov 2023
Publication
Hydrogen-fueled aircraft are a promising innovation for a sustainable future in aviation. While hydrogen aircraft design has been widely studied research on airport requirements for new infrastructure associated with hydrogen-fueled aircraft and its integration with existing facilities is scarce. This study analyzes the current body of knowledge and identifies the planning challenges which need to be overcome to enable the operation of hydrogen flights at airports. An investigation of the preparation of seven major international airports for hydrogen-powered flights finds that although there is commitment airports are not currently prepared for hydrogen-based flights. Major adjustments are required across airport sites covering land use plans airside development utility infrastructure development and safety security and training. Developments are also required across the wider aviation industry including equipment updates such as for refueling and ground support and supportive policy and regulations for hydrogen-powered aircraft. The next 5–10 years is identified from the review as a critical time period for airports given that the first commercial hydrogen-powered flight is likely to depart in 2026 and that the next generation of short-range hydrogen-powered aircraft is predicted to enter service between 2030 and 2035.
Exploring Hydrogen Storage Potentital in Depleted Western Australian Hydrocarbon Reservoirs: A Petrophysical and Petrographic Analysis
Oct 2023
Publication
Hydrogen recognised as a clean and sustainable energy carrier with excellent transportation fuel properties drives numerous countries towards a hydrogen-based economy due to its high utilisation efficiency and minimal environmental impact. However the gaseous nature of hydrogen necessitates larger storage surface areas. Underground Hydrogen Storage (UHS) has emerged as a promising and efficient method to overcome this challenge. Currently only a handful of UHS locations exist globally due to the novelty of this field. With its abundant depleted hydrocarbon reservoirs boasting significant storage capacity Western Australia presents a suitable region for hydrogen storage. This paper comprehensively analyses petrophysical and petrographic characteristics employing XRD MIP and Micro-CT techniques on sandstone and claystone samples obtained from several fields in Western Australia. The suitability of these samples for hydrogen storage is evaluated based on mineral composition and porosity. The analysis reveals that more than 96% of Quartz is present in the sandstone samples. The claystone samples exhibit a mineral composition comprising Quartz Calcite K-feldspar Kaolinite Pyrite Albite and Muscovite. The study suggests that hydrogen storage in formation rock is favourable due to the low reactivity of hydrogen with silicate minerals but interactions with cap rock minerals should be considered. Micro-CT results indicate the connected porosity in the 17.23–4.67% range. Pore distribution in sandstones ranges from nanometers to millimetres with a substantial proportion of connected pores in the intermediate range which is conducive to hydrogen storage. This is particularly advantageous as the hydrogen-water system is highly water-wet with hydrogen primarily occupying medium and larger pores minimising hydrogen trapping. In claystone most pores were below 3 nm but instrumental constraints limited their quantification. In conclusion the petrophysical and petrographic analysis underscores the potential of Western Australian depleted hydrocarbon reservoirs for hydrogen storage. Understanding the mineralogical reactions with cap rock minerals is crucial while the favourable pore distribution in sandstones further supports the viability of hydrogen storage.
Can the Hydrogen Economy Concept be the Solution to the Future Energy Crisis?
Feb 2022
Publication
The Hydrogen Economy concept is being proposed as a means of reducing and eventually decarbonising the world’s energy use. It looks to hydrogen as being a replacement for methane (natural gas) and generally as a way of removing all fossil fuels from the energy supply. The concept however has at least four flaws as follows: (1) hydrogen has significantly different properties to methane; (2) hydrogen has properties that create significant hazards; (3) hydrogen has a very small initiation (activation) energy; and (4) liquid hydrogen cannot readily replace liquefied natural gas (LNG). Hydrogen’s hazards will prevent it from being accepted in a societal sense. To the question ‘Can the Hydrogen Economy concept be the solution to the future energy crisis?’ the answer is ‘no’. Hydrogen has and will have a role in world energy but that role will be limited to industry. For the future we need an advanced electric economy.
A Review of Hydrogen Technologies and Engineering Solutions for Railway Vehicle Design and Operations
Oct 2021
Publication
Interest in hydrogen-powered rail vehicles has gradually increased worldwide over recent decades due to the global pressure on reduction in greenhouse gas emissions technology availability and multiple options of power supply. In the past research and development have been primarily focusing on light rail and regional trains but the interest in hydrogen-powered freight and heavy haul trains is also growing. The review shows that some technical feasibility has been demonstrated from the research and experiments on proof-of-concept designs. Several rail vehicles powered by hydrogen either are currently operating or are the subject of experimental programmes. The paper identifies that fuel cell technology is well developed and has obvious application in providing electrical traction power while hydrogen combustion in traditional IC engines and gas turbines is not yet well developed. The need for on-board energy storage is discussed along with the benefits of energy management and control systems.
Hydrogen Production from Low-temperature Geothermal Energy - A Review of Opportunities, Challenges, and Mitigating Solutions
Jun 2024
Publication
This study aims to provide a comprehensive review of the potential of geothermal energy for producing hydrogen with a focus on the Australian context where low-temperature geothermal reservoirs particularly hot sedimentary aquifers (HSAs) are prevalent. The work includes an overview of various geothermal technologies and hydrogen production routes and evaluates potential alternatives for hydrogen production in terms of energy and exergy efficiency economic performance and hydrogen production rate. Values for energy efficiency are reported in the literature to range from 3.51 to 47.04% 7.4–67.5% for exergy efficiency a cost ranging from 0.59 to 5.97 USD/kg of hydrogen produced and a hydrogen production rate ranging from 0.11 to 5857 kg/h. In addition the article suggests and evaluates multiple metrics to appraise the feasibility of HSAs geothermal reservoirs with results tailored to Australia but that can be extended to jurisdictions with similar conditions worldwide. Furthermore the performance of various hydrogen production systems is investigated by considering important operating conditions. Lastly the key factors and possible solutions associated with the hydrogeological and financial conditions that must be considered in developing hydrogen production using lowtemperature geothermal energy are summarised. This study shows that low-temperature HSAs (~100 ◦C) can still be used for hydrogen generation via supplying power to conventional electrolysis processes by implementing several improvements in heat source temperature and energy conversion efficiency of Organic Rankine Cycle (ORC) power plants. Geothermal production from depleted or even active oilfields can reduce the capital cost of a hydrogen production system by up to 50% due to the use of pre-existing wellbores under the right operating conditions. Thus the results of this study bring novel insights in terms of both the opportunities and the challenges in producing clean hydrogen from geothermal energy applicable not only to the hydro-geological and socio-economic conditions in Australia but also worldwide exploring the applicability of geothermal energy for clean hydrogen production with similar geothermal potential.
Energy and Exergy-economic Performance Comparison of Wind, Solar Pond, and Ocean Thermal Energy Conversion Systems for Green Hydrogen Production
Jun 2024
Publication
The necessity of energy solutions that are economically viable ecologically sustainable and environmentally friendly has become fundamental to economic and societal advancement of nations. In this context renewable energy sources emerge as the most vital component. Furthermore hydrogen generation systems based on renewable energies are increasingly recognized as the most crucial strategies to mitigate global warming. In the present study a comparative analysis is conducted from an exergy-economic perspective to find the most efficient configuration among three different systems for renewable-based power to hydrogen production. These renewable sources are wind turbine salinity gradient solar pond (SGSP) and ocean thermal energy conversion (OTEC). SGSP and OTEC are coupled with a hydrogen production unit by a trilateral cycle (TLC) to improve the temperature match of the heating process. The heat waste energy within these systems is recovered by a thermoelectric generator (TEG) and a proton exchange membrane electrolyzer (PEME) is used for hydrogen production. Under base case input conditions the net power input of PEME is estimated to be approximately 327.8 kW across all configurations. Additionally the 3E (energy exergy and exergy-economic) performance of the three systems is evaluated by a parametric study and design optimization. The results of the best performance analysis reveal that the best exergy efficiency is achievable with the wind-based system in the range of 5.8–10.47% and for average wind speed of 8–12 m/s. Correspondingly the most favorable total cost rate is attributed to the wind-based system at a wind speed of 8 m/s equating to 66.08 USD/h. Subsequently the unit cost of hydrogen for the SGSP-based system is estimated to be the most economical ranging from 42.78 to 44.31 USD/GJ.
Levelised Cost of Dynamic Green Hydrogen Production: A Case Study for Australia's Hydrogen Hubs
Jun 2024
Publication
This study evaluates the levelised cost of hydrogen (LCOH) dynamically produced using the two dominant electrolysis technologies directly connected to wind turbines or photovoltaic (PV) panels in regions of Australia designated as hydrogen hubs. Hourly data are utilised to size the components required to meet the hydrogen demand. The dynamic efficiency of each electrolysis technology as a function of input power along with its operating characteristics and overload capacity are employed to estimate flexible hydrogen production. A sensitivity analysis is then conducted to capture the behaviour of the LCOH in response to inherent uncertainty in critical financial and technical factors. Additionally the study investigates the trade-offs between carbon cost and lifecycle emissions of green hydrogen. This approach is applied to ascertain the impact of internalising environmental costs on the cost-competitiveness of green hydrogen compared to grey hydrogen. The economic modelling is developed based on the Association for the Advancement of Cost Engineering (AACE) guidelines. The findings indicate that scale-up is key to reducing the LCOH by a meaningful amount. However scale-up alone is insufficient to reach the target value of AUD 3 (USD 2) except for PV-based plant in the Pilbara region. Lowered financial costs from scale-up can make the target value achievable for PV-based plants in Gladstone and Townsville and for wind-based plants in the Eyre Peninsula and Pilbara regions. For other hubs a lower electricity cost is required as it accounts for the largest portion of the LCOH.
A Hydrogen Supply-chain Model Powering Australian Isolated Communities
Oct 2023
Publication
This article proposes a supply chain-based green hydrogen microgrid modelling for a number of remote Australian communities. Green hydrogen can be used as an emissions-free fuel source for electricity generation in places where large-scale renewable energy production is impossible due to land availability population or government regulations. This research focuses on the Torres Strait Island communities in northern Australia where the transition from diesel to renewable electricity generation is difficult due to very limited land availability on most islands. Due to geographical constraints low population and smaller electrical load the green hydrogen needs to be sourced from somewhere else. This research presents a green hydrogen supply chain model that leverages the land availability of one island to produce hydrogen to supply other island communities. In addition this research presents a model of producing and transporting green hydrogen while supplying cheaper electricity to the communities at focus. The study has used a transitional scenario planning approach and the HOMER simulation platform to find the least-cost solution. Based on the results a levelised cost of energy range of AU$0.42 and AU$0.44 was found. With the help of a green hydrogen supply chain CO2 emissions at the selected sites could be cut by 90 %. This study can be used as a guide for small clustered communities that could not support or justify large-scale renewable generation facilities but need more opportunities to install renewable generation.
Techno-Economic Assessment of a Grid-Independent Hybrid Power Plant for Co-Supplying a Remote Micro-Community with Electricity and Hydrogen
Aug 2021
Publication
This study investigates the techno-economic feasibility of an off-grid integrated solar/wind/hydrokinetic plant to co-generate electricity and hydrogen for a remote micro-community. In addition to the techno-economic viability assessment of the proposed system via HOMER (hybrid optimization of multiple energy resources) a sensitivity analysis is conducted to ascertain the impact of ±10% fluctuations in wind speed solar radiation temperature and water velocity on annual electric production unmet electricity load LCOE (levelized cost of electricity) and NPC (net present cost). For this a far-off village with 15 households is selected as the case study. The results reveal that the NPC LCOE and LCOH (levelized cost of hydrogen) of the system are equal to $333074 0.1155 $/kWh and 4.59 $/kg respectively. Technical analysis indicates that the PV system with the rated capacity of 40 kW accounts for 43.7% of total electricity generation. This portion for the wind turbine and the hydrokinetic turbine with nominal capacities of 10 kW and 20 kW equates to 23.6% and 32.6% respectively. Finally the results of sensitivity assessment show that among the four variables only a +10% fluctuation in water velocity causes a 20% decline in NPC and LCOE.
Hydrogen-Enabled Power Systems: Technologies’ Options Overview and Effect on the Balance of Plant
Aug 2025
Publication
Hydrogen-based Power Systems (H2PSs) are gaining accelerating momentum globally to reduce energy costs and dependency on fossil fuels. A H2PS typically comprises three main parts: hydrogen production storage and power generation called packages. A review of the literature and Original Equipment Manufacturers (OEM) datasheets reveals that no single manufacturer supplies all H2PS components posing significant challenges in system design parts integration and safety assurance. Additionally both the literature and H2PS projects’ database highlight a gap in a systematic hydrogen equipment and auxiliary sub-systems technology selection process and how this selection affects the overall H2PS Balance of Plant (BoP). This study addresses that gap by providing a guideline for available technology options and their impact on the H2PS-BoP. The analysis compares packages and auxiliary sub-system technologies to support informed engineering decisions regarding technology and equipment selection. The study finds that each package’s technology influences the selection criteria of the other packages and the associated BoP requirements. Furthermore the choice of technologies across packages significantly affects overall system integrity and BoP. These interdependencies are illustrated using a cause-and-effect matrix. The study’s significance lies in establishing a structured guideline for engineering design and operations enhancing the accuracy of feasibility studies and accelerating the global implementation of H2PS.
Recent Breakthroughs and Future Horizons in Next-generation HT-PEMs for Hydrogen Fuel Cell
Aug 2025
Publication
Aminul Islam,
Mamun Shahriar,
Tarekul Islam,
Md. Tarekul Islam,
Afsana Papia,
Suman Chandra Mohanta,
M. Azizur R. Khan,
Md Aliur Rahman,
Khadiza Tul Kubra,
Md. Munjur Hasan,
Ariyan Islam Rehan,
Mohammed Sohrab Hossain,
Adiba Islam Rasee,
M.A. Shenashen,
Eti Awual,
Md. Chanmiya Sheikh,
Tetsuya Uchida,
R.M. Waliullah,
Md. Shad Salman,
Md. Nazmul Hasan and
Md. Rabiul Awual
High-temperature proton exchange membranes (HT-PEMs) for fuel cells are considered transformative technologies for efficient energy conversion particularly in hydrogen-based transportation owing to their ability to deliver high power density and operational efficiency in harsh environments. However several critical challenges limit their broader adoption notably the limited durability and high costs associated with core components such as membranes and electrocatalysts under elevated temperature conditions. This review systematically addresses these challenges by examining the role of engineered nanomaterials in overcoming performance and stability limitations. The potential of nanomaterials to improve catalytic activity proton conductivity and thermal stability is discussed in detail emphasizing their impact on the optimization of catalyst layer composition including catalysts binders phosphoric acid electrolytes and additives. Recent advancements in nanostructured assemblies and 3D morphologies are explored to enhance fuel cell efficiency through synergistic interactions of these components. Additionally ongoing issues such as catalyst degradation long-term stability and resistance to high-temperature operation are critically analyzed. This manuscript offers a comprehensive overview of current HT-PEMs research and proposes future material design strategies that could bridge the gap between laboratory prototypes and large-scale industrial applications.
Techno-economic Assessment of Hydrogen Production: Comparative Analysis of Electrolyser Technologies in a Hybrid PV/Wind System
Jun 2025
Publication
Green hydrogen is critical for achieving net-zero emissions with water electrolysis offering a CO2-free solution. This study provides a comprehensive comparative financial and economic assessment of a hybrid PV/wind hydrogen production system using three types of electrolysers including Alkaline Electrolyser (AEL) Proton Exchange Membrane Electrolyser (PEMEL) and Solid Oxide Electrolyser (SOEL). Key performance metrics such as net present value (NPV) Internal Rate of Return (IRR) revenues Earnings Before Interest Tax Depreciation and Amortization (EBITDA) Earning Before Taxes (EBT) Debt Service Coverage Ratio (DSCR) and levelized cost of Hydrogen (LCOH) are evaluated to identify the most cost-effective option. The findings reveal that AEL is the most economical solution achieving a higher NPV (503374 k€) and IRR (16.94 % for project IRR) though PEMEL and SOEL remain competitive. Other metrics such as DSCR show that the hydrogen project generates 30 % more cash flow than is required to cover its debt service. Additionally the results of the LCOH analysis demonstrate that a hybrid plant consisting of 10 % PV and 90 % wind is more cost-effective in the studied region than both solar-based or wind-based hydrogen production plants. AEL and PEMEL are approximately 7–6 €/kg less expensive than SOEL but this gap is expected to be narrowed by 2030. The hybrid renewable energy project reduces CO2 emissions by 6786.6 Mt over its lifetime. These findings guide policymakers and investors toward scalable cost-effective green hydrogen deployment emphasizing the synergy of hybrid renewables and mature electrolysis technologies.
The Impact of Acetic Acid Reaction on Microstructural and Mineralogical Changes in Shale Caprock: A Preliminary Study for Underground Hydrogen Storage Integrity
Aug 2025
Publication
Hydrogen storage in depleted gas reservoirs triggers geochemical and microbiological reactions at the caprockreservoir interface yielding significant implications on storage integrity. Acetogenesis is a microbial reaction observed during underground hydrogen storage (UHS) that produces acetate and converts it into acetic acid under protonation potentially impacting the UHS process integrity. For the first time this research explores the impact of the acetic acid + brine + caprock reaction on shale caprock mineralogy microstructure and physicochemical properties where this preliminary study has been conducted under ambient conditions to obtain an initial assessment of the impact. A comprehensive mineralogical and micro-structural characterization including scanning electron microscopy (SEM) energy dispersive X-ray spectroscopy (EDS) X-ray fluorescence (XRF) Xray diffraction (XRD) micro-computed tomography (micro-CT) and inductively coupled plasma mass spectrometry (ICP-MS) have been conducted to assess the mineralogical and microstructural changes in shale specimens saturated with brine solutions with a range of acetic acid percentages (5 % 10 % and 20 %) to find the maximum possible impact. According to the conducted mineralogical analysis (EDS XRF and XRD) there is a significant primary mineral dissolution during the acetic acid interaction where calcite and dolomite are the predominant minerals dissolved evidencing the significant impact of the acetic acid reaction on carbonate-rich caprock systems during UHS. However secondary mineral precipitation happened at high acidic concentrations (20 %). Interestingly other common minerals in reservoir rocks (e.g. mica pyrite) did not demonstrate rapid interactions with acetic acid compared to carbonates. The impact of these mineralogical changes on the caprock microstructure was then investigated through SEM and micro-CT and the results demonstrate substantial enhancements in porosity and microcracks in the rock matrix due to the calcite and dolomite dissolutions despite some microcracks being closed by secondary precipitations. This preliminary study evidences the significant impact of acidification on caprock integrity which may occur during the acetogenesis reaction in UHS environments. These effects should be carefully considered in field UHS projects to eliminate the risks.
Modelling Hydrogen Storage Requirements to Balance the Future Western Australian Grid
Sep 2025
Publication
Increasing renewable energy technology penetration into electrical grids to meet net zero CO2 emission targets is a key challenge in terms of intermittency; one solution is the provision of sufficient energy storage. In the current study we considered future projections of electrical demand and renewable energy (in 2042) for the Southwest Interconnected System grid in Western Australia. Required energy storage considered is a mixture of battery energy storage systems and underground hydrogen storage in a depleted gas reservoir. The Southwest Interconnected System serves as an excellent case study given that it is a comparatively large isolated grid with substantial potential access to renewable energy resources as well as potential underground hydrogen storage sites. This work utilised a dynamic energy model that summates the wind and solar energy resources on an hourly basis. Excess energy utilised battery energy storage systems capacity first followed by underground hydrogen storage. The relative size of the renewables and the storage options is then optimised in terms of minimising wholesale energy production costs. This unique optimisation analysis across the full integrated system clearly indicated that both battery energy storage systems and underground hydrogen storage are required; underground hydrogen storage is predominately necessary to meet seasonal unmet energy demand that amounts to approximately 6% of total demand. Underground hydrogen storage costs were dominated by the required electrolyser requirements. The optimised levelised cost of electricity was found to be US$106/MWh which is approximately 45% larger than current wholesale electricity prices.
Underground Hydrogen Storage in Engineered Lenses
Aug 2025
Publication
Hydrogen can play a significant role in Australian economy and Australia has set an ambitious goal to become a global leader in hydrogen industry as outlined in the National Hydrogen Strategy 2024. Hydrogen is an efficient energy carrier that can be used for both transporting and storing energy. Underground hydrogen storage (UHS) in aquifers depleted gas and oil reservoirs and salt caverns have been considered as a low-cost option for largescale storage of hydrogen. In this study a method for hydrogen storage in engineered (shallow) lenses is proposed where a lens is created in a very low permeability layered formation such as shales via opening the layers by a pressurised fluid. A preliminary overview of the Australian basins is presented focussing on the most suitable/obvious units for the purpose of creating engineered lenses for storage of hydrogen. Major engineering aspects of lenses such as size volume storage capacity storage time and hydrogen loss are reviewed followed by a Techno-Economic Analysis for the proposed hydrogen storage method. Initial modelling shows that up to 250 tonnes of hydrogen can be stored in shallow engineered lenses incurring a capital cost of 35.7 US$/kg and total annual operational cost of 7 US$/kg making the proposed storage method a competitive option against salt and lined rock caverns. Finally Monitoring and Verification (M&V) as part of storage assurance practice has been discussed and successful examples are presented.
Port Energy Models Alignment with Real Port Activities, their Coverage of Hydrogen Technologies, and as Tools for Decarbonisation
Aug 2025
Publication
Ports have significant emissions from using carbon-based electricity and fuels. This paper presents a scoping literature review of port energy models providing interpretations of the models capabilities and limitations in representing activities coverages of hydrogen technologies use as decarbonisation prediction tools and to highlight research directions. Three model categories were assessed. The Conceptual-Driven use a top-down analytical structure for objectives optimisation. Recent publications have increasing coverages of port activities by electrical with hydrogen technologies but limited representation of diesel equipment. The Data-Driven represent entire ports as top-down or focus on electrical mobile equipment in bottom-up data-only abstract structures for algorithm analysis. Both model types omit coverage of hydrogen powered mobile equipment at temporal resolutions representing typical duties and measured emissions for weighting predictions. A HybridDriven model is proposed as a decarbonisation assessment tool for improved representation of diesel mobile equipment duty-profiles referenceable baselines and matching with hydrogen technologies characteristics.
Stakeholder and Techno-Economic Assessment of Iceland’s Green Hydrogen Economy
Mar 2025
Publication
Green hydrogen is a promising energy carrier for the decarbonization of hard-toabate sectors and supporting renewable energy integration aligning with carbon neutrality goals like the European Green Deal. Iceland’s abundant renewable energy and decarbonized electricity system position it as a strong candidate for green hydrogen production. Despite early initiatives its hydrogen economy has yet to significantly expand. This study evaluated Iceland’s hydrogen development through stakeholder interviews and a techno-economic analysis of alkaline and PEM electrolyzers. Stakeholders were driven by decarbonization goals economic opportunities and energy security but faced technological economic and governance challenges. Recommendations include building stakeholder confidence financial incentives and creating hydrogen-based chemicals to boost demand. Currently alkaline electrolyzers are more cost-effective (EUR 1.5–2.8/kg) than PEMs (EUR 2.1–3.6/kg) though the future costs for both could drop below EUR 1.5/kg. Iceland’s low electricity costs and high electrolyzer capacity provide a competitive edge. However this advantage may shrink as solar and wind costs decline globally particularly in regions like Australia. This work’s findings emphasize the need for strategic planning to sustain competitiveness and offer transferable insights for other regions introducing hydrogen into ecosystems lacking infrastructure.
How Hydrogen Injection Impacts Reacting Flow in an Ironmaking Blast Furnace: An Industrial-scale CFD-DEM Study
Feb 2025
Publication
Hydrogen injection (HI) is an emerging decarbonisation technology for ironmaking blast furnaces (BFs) yet its impact on the in-furnace phenomenon in the raceway of an industry BF remains unclear. In this study an industrialscale Reactive Computational Fluid Dynamic Discrete Element Method coupling model (rCFD-DEM) is developed to study the impacts of HI on the raceway dynamics and coke combustion inside an industrial-scale BF. To overcome the limit in previous CFD-DEM works this work considers the impact of top loading on the in-raceway reacting flow for the first time. The comparisons show that the raceway size is sensitive to the top loading ratio suggesting that the top loading should be considered in future raceway modelling. Then the quantitative effect of the HI rate is numerically evaluated. It is indicated that when the HI rate increases from zero to 8 kg/tHM the raceway height and depth increase by 95% and 81% respectively under the investigated conditions. The underlying mechanism is explored: the increase in HI rate leads to an increase in inter-phase drag force and interparticle collision and in the convection and radiation heat transfer rates by 33 and 32 times respectively. This study provides a cost-effective tool to understand and optimise HI in industrial-scale BFs for a lower carbon footprint empowering the steel industry with crucial insights.
A Comprehensive Review of Experimental Techniques for Determining Crack Propagation in Caprock during Underground Hydrogen Storage
Aug 2025
Publication
This study comprehensively reviews the state-of-the-art laboratory-scale fracture mechanics testing methods to assess their suitability for investigating stress-induced critical cracks and geochemically induced subcritical cracks in caprock during underground hydrogen storage. Subcritical crack propagation is primarily examined using empirical techniques such as double torsion and constant stress-rate methods. Both methods determine stress intensity factors and crack velocities without requiring crack length measurements. Comparatively the double torsion method provides advantages such as simple sample preparation and pre-cracking process continuous data acquisition and fracture toughness measurements which makes it more reliable for caprockrelated studies. The International Society for Rock Mechanics recommends four standard methods for critical crack propagation to determine fracture toughness values. Chevron-notched specimens including the Chevron Bend specimen Short Rod specimen and Cracked Chevron Notched Brazilian Disk specimen exhibit higher uncertainty in fracture toughness data due to specimen size effects additional fixture requirements and undesirable crack formations. In contrast the Semi-Circular Bend specimen method is frequently employed due to its smaller specimen size simplified testing and well-balanced dynamic forces. Despite these advancements studies on multiple cracking behaviour in caprock under subsurface hydrogen storage conditions remain limited. The conventional methods discussed in this review are primarily designed to function at ambient conditions making it challenging to replicate subsurface geochemical interactions. Future studies should focus more on developing new laboratory techniques and enhancing existing specimen configurations by incorporating specialised apparatus such as high-pressure cells and reaction chambers to implement typical subsurface conditions observed during underground hydrogen storage. Additionally more parametric studies on caprock samples are recommended to generate a comprehensive dataset on subcritical and critical crack propagation and validate the reliability of these testing methods for underground hydrogen storage applications.
Data-driven Strategy for Contact Angle Prediction in Underground Hydrogen Storage Using Machine Learning
Feb 2025
Publication
In response to the surging global demand for clean energy solutions and sustainability hydrogen is increasingly recognized as a key player in the transition towards a low-carbon future necessitating efficient storage and transportation methods. The utilization of natural geological formations for underground storage solutions is gaining prominence ensuring continuous energy supply and enhancing safety measures. However this approach presents challenges in understanding gas-rock interactions. To bridge the gap this study proposes a data-driven strategy for contact angle prediction using machine learning techniques. The research leverages a comprehensive dataset compiled from diverse literature sources comprising 1045 rows and over 5200 data points. Input features such as pressure injection rate temperature salinity rock type and substrate were incorporated. Various artificial intelligence algorithms including Support Vector Machine (SVM) k-Nearest Neighbors (KNN) Feedforward Deep Neural Network (FNN) and Recurrent Deep Neural Network (RNN) were employed to predict contact angle with the FNN algorithm demonstrating superior performance accuracy compared to others. The strengths of the FNN algorithm lie in its ability to model nonlinear relationships scalability to large datasets robustness to noisy inputs generalization to unseen data parallelizable training processes and architectural flexibility. Results show that the FNN algorithm demonstrates higher accuracy (RMSE = 0.9640) than other algorithms (RMSERNN = 1.7452 RMSESVM = 1.8228 RMSEKNN = 1.0582) indicating its efficacy in predicting the contact angle testing subset within the context of underground hydrogen storage. The findings of this research highlight a low-cost and reliable approach with high accuracy for estimating contact angle of water–hydrogen–rock system. This technique also helps determine the contribution and influence of independent factors aiding in the interpretation of absorption tendencies and the ease of hydrogen gas flow through the porous rock space during underground hydrogen storage.
A Risk-based Multi-criteria Decision-making Framework for Offshore Green Hydrogen System Developments: Pathways for Utilizing Existing and New Infrastructure
Mar 2024
Publication
Unlocking the potential of offshore renewables for green hydrogen (GH2) production can be a game-changer empowering economies with their visionary clean energy policies amplifying energy security and promoting economic growth. However their novelty entails uncertainty and risk necessitating a robust framework for facility deployment and infrastructure planning. To optimize offshore GH2 infrastructure placement this work proposes a novel and robust GIS-based multi-criteria decision-making (MCDM) framework. Encompassing thirtytwo techno-socio-economic-safety factors and ocean environmental impact analysis this methodology facilitates informed decision-making for sustainable and safe GH2 development. Utilizing the synergies between offshore wind and solar resources this study investigates the potential of hybrid ocean technologies to enhance space utilization and optimize efficiency. To illustrate the practical application of the proposed framework a case study examining a GH2 system in Australia's marine region and its potential nexus with nearby offshore industries has been conducted. The performed life cycle assessment (LCA) explored various configurations of GH2 production storage and transportation technologies. A Bayesian objective weight integrating technique has been introduced and contrasted statistically with the hybrid CRITIC Entropy MEREC and MARCOS-based MCDM approaches. Various locations are ranked based on the net present value of life cycle cost GH2 production capacity risk availability and environment sustainability factors illustrating their compatibility. A sensitivity analysis is conducted to confirm that a Bayesian approach improves the decision-making outcomes through identifying optimal criteria weights and alternative ranks more effectively. Empowering strategic GH2 decisions globally the proposed approach optimizes system performances cost sustainability and safety excelling in harsh environments.
The Effects of Light Energy Fields on the Molecular and Electrochemical Dynamics During Water Electrolysis
Aug 2025
Publication
Hydrogen will be an integral component for the transition to sustainable energy generation and storage due to its favourable characteristics and versatility in its application. This research provides a greater understanding of the potential light energy has to increase water electrolysis efficiency by examining the effects that light energy fields have on the molecular and electrochemical dynamics during electrolysis. The results indicate that light energy increased efficiency by ~10% while enhancing the molecular dynamics regardless of application. The application of a line laser generated the highest gains in efficiency with a maximum of ~15%. Furthermore the application of a line laser with a linear magnetic field resulted in a synergistic effect which generated higher increases in molecular dynamics as well as an ~18% increase in efficiency and a ~58% increase in hydrogen gas production. As such the application of light energy fields presents a promising method for enhancing water’s molecular dynamics and electrolysis efficiency.
Code of Practice Hydrogen Pipeline Systems: Design, Construction and Operation
May 2025
Publication
The purpose of this Hydrogen Pipeline System COP is to provide guidance based on current knowledge for the design construction and operation of transmission pipeline systems transporting gaseous hydrogen or blends of hydrogen and hydrocarbon fluids.<br/>The objective of the code is to provide guidance for the safe reliable and efficient transportation and storage of hydrogen in transmission pipeline systems that are required to conform to the AS(/NZS) 2885 series. The document also references adoption of other international codes where suitable guidance is available.<br/>This document is intended to be updated with revised design criteria and methods as research and experience improves the understanding of hydrogen service in transmission pipelines. Although the CoP may be further developed into a published standard in the future within the AS(/NSZ) 2885 series framework this current revision of the CoP is not equivalent to a formal published Australian standard. The document also includes expanded commentary and background information as an informative code of practice that is more extensive than is typically covered in a standard.
Upskilling Plumber Gasfitters for Hydrogen: An Empirical Study using the Theory of Planned Behavior
Dec 2023
Publication
Hydrogen has become an important component of the global transition to zero-carbon economies. Low-carbon and green hydrogen gas and fuel cell technology for domestic household use will depend on skilled practi tioners particularly gasfitters to convert install and maintain hydrogen-based appliances. Upskilling gasfitters to work with hydrogen is critical to transitioning from natural gas to hydrogen for heating and cooking. Yet limited research exists on training and upskilling trade practitioners in the context of renewable energy and lowcarbon technologies. This paper makes a novel contribution to research on upskilling for renewable and lowcarbon technologies by drawing on the findings from a survey of 1001 plumbers in Australia. The survey designed using the Theory of Planned Behavior aimed to predict behaviors regarding hydrogen training and ascertain social and structural enablers for such behavior. The results show that plumbers have limited awareness of hydrogen yet have positive attitudes towards upskilling to work with the low-carbon fuel. Perceived benefits to business sustainability customer service and safety underpin the positive attitudes. The research shows that while plumbers are enthusiastic about upskilling for hydrogen upskilling policies and programs must ensure key stakeholders who inform plumbers’ ongoing practice are on board and informed about hydrogen training opportunities.
Energy Management and Sizing of a Stand-alone Hybrid Renewable Energy System for Community Electricity, Fresh Water, and Cooking Gas Demands of a Remote Island
Nov 2023
Publication
Research into the off-grid hybrid energy system to provide reliable electricity to a remote community has extensively been done. However simultaneous meeting electric freshwater and gas demands from the off-grid hybrid energy sources are very scarce in literature. Power- to-X (PtX) is gaining attention in recent days in the energy transition scenarios to generate green hydrogen the primary product of the process as an energy carrier which is deemed to replace conventional fuels to reach absolute carbon neutrality. In this study renew able–based hybrid energy is developed to simultaneously meet the electricity freshwater and gas (cooking gas via methanation process) demands for a remote Island in Bangladesh. In this process an energy management strategy has been developed to use the excess energy to generate both freshwater and the hydrogen where hydrogen is then converted to natural gas via methanation process. The PV wind turbine diesel generator battery and fuel cell have been optimized using non-dominating sorting algorithm-II (NSGA-II) to offer reliable cost-effective solutions of electricity freshwater and cooking gas for the end users. Results reported that the PV/ WT/DG/Batt configuration has been found the most economic configuration with the lowest COE (0.1724 $/kWh) which is 9 % lower than PV/WT/Batt configuration which has the second lowest COE. The cost of water (COW) and cost of gas (COG) of the PV/WT/DG/Batt system are also the lowest among all the four configurations and have been found 1.185 $/m3 and 3.978 $/m3 respectively.
Comparative Electrochemical Performance of Solid Oxide Fuel Cells: Hydrogen vs. Ammonia Fuels—A Mini Review
Apr 2025
Publication
Solid oxide fuel cells (SOFCs) have garnered significant attention as a promising technology for clean and efficient power generation due to their ability to utilise renewable fuels such as hydrogen and ammonia. As carbon-free energy carriers hydrogen and ammonia are expected to play a pivotal role in achieving net-zero emissions. However a critical research question remains: how does the electrochemical performance of SOFCs compare when fuelled by hydrogen vs. ammonia and what are the implications for their practical application in power generation? This mini-review paper is premised on the hypothesis that while hydrogen-fuelled SOFCs currently demonstrate superior stability and performance at low and high temperatures ammonia-fuelled SOFCs offer unique advantages such as higher electrical efficiencies and improved fuel utilisation. These benefits make ammonia a viable alternative fuel source for SOFCs particularly at elevated temperatures. To address this the mini-review paper provides a comprehensive comparative analysis of the electrochemical performance of SOFCs under direct hydrogen and ammonia fuels focusing on key parameters such as open-circuit voltage (OCV) power density electrochemical impedance spectroscopy fuel utilisation stability and electrical efficiency. Recent advances in electrode materials electrolytes fabrication techniques and cell structures are also highlighted. Through an extensive literature survey it is found that hydrogen-fuelled SOFCs exhibit higher stability and are less affected by temperature cycling. In contrast ammonia-fuelled SOFCs achieve higher OCVs (by 7%) and power densities (1880 mW/cm2 vs. 1330 mW/cm2 for hydrogen) at 650 °C along with 6% higher electrical efficiency. Despite these advantages ammonia-fuelled SOFCs face challenges such as NOx emissions nitride formation environmental impact and OCV stabilisation which are discussed alongside potential solutions. This mini review aims to provide insights into the future direction of SOFC research emphasising the need for further exploration of ammonia as a sustainable fuel alternative.
A Review of the Enhancement of Bio-Hydrogen Generation by Chemicals Addition
Apr 2019
Publication
Bio-hydrogen production (BHP) produced from renewable bio-resources is an attractive route for green energy production due to its compelling advantages of relative high efficiency cost-effectiveness and lower ecological impact. This study reviewed different BHP pathways and the most important enzymes involved in these pathways to identify technological gaps and effective approaches for process intensification in industrial applications. Among the various approaches reviewed in this study a particular focus was set on the latest methods of chemicals/metal addition for improving hydrogen generation during dark fermentation (DF) processes; the up-to-date findings of different chemicals/metal addition methods have been quantitatively evaluated and thoroughly compared in this paper. A new efficiency evaluation criterion is also proposed allowing different BHP processes to be compared with greater simplicity and validity
Integrated Design and Construction of a 50 kW Flexible Hybrid Renewable Power Hydrogen System Testbed
Mar 2025
Publication
We report on the first stage of an energy systems integration project to develop hybrid renewable energy generation and storage of hydrogen for subsequent use via research-based low regret system testbeds. This study details the design and construction of a flexible plug-and-play hybrid renewable power and hydrogen system testbed with up to 50 kW capacity aimed at addressing and benchmarking the operational parameters of the system as well as key components when commissioned. The system testbed configuration includes three different solar technologies three different battery technologies two different electrolyser technologies hydrogen storage and a fuel cell for regenerative renewable power. Design constraints include the current limit of an AC microgrid regulations for grid-connected inverters power connection inefficiencies and regulated hazardous area approval. We identify and show the resolution of systems integration challenges encountered during construction that may benefit planning for the emerging pilot or testbed configurations at other sites. These testbed systems offer the opportunity for informed decisions on economic viability for commercial-scale industry applications.
Hydrogen Blending in Gas Pipelines: Fluid-dynamic Insights, Risks, and Recommendations
Mar 2025
Publication
Massive theoretical and applied research is underway worldwide to assess the viability of transporting natural gas-hydrogen blends in pipelines. For the first time this work derives simplified but closed-form equations that describe how changes in gas properties due to hydrogen blending at different volumes map to specific changes in pressure drop compressor power and linepack. These first-of-their-kind equations which are extensively validated against transient gas flow models enabled three unprecedented and unique findings. The first finding which quantifies how a change in demand maps to a change in delay and swing on the supply side reveals that pressure swings increase monotonically with an increase in hydrogen blending volume translating into an increase in pipeline fatigue and risk of failure. The second finding crucially shows that pressure drop does not monotonically increase with an increase in hydrogen blending volume; in fact it is highest at around 85 % hydrogen volume not at 100 %. The third finding shows that the decrease in linepack as a result of an increase in hydrogen volume is not only related to the gross calorific value of the gas mixture but also to the pressure-tocompressibility factor ratio suggesting that smaller parallel pipelines can offset this linepack reduction compared to a single larger pipeline.
Enhancing Disaster Prevention and Structural Resilience of Tunnels: A Study on Liquid Hydrogen Leakage, Diffusion, and Explosion Mitigation
Apr 2025
Publication
The increasing adoption of liquid hydrogen (LH2) as a clean energy carrier presents significant safety challenges particularly in confined underground spaces like tunnels. LH2′s unique properties including high energy density and cryogenic temperatures amplify the risks of leaks and explosions which can lead to catastrophic overpressures and extreme temperatures. This study addresses these challenges by investigating the diffusion and explosion behaviour of LH2 leaks in tunnels providing critical insights into disaster prevention and structural resilience for underground infrastructure. Using advanced numerical simulations validated through theoretical calculations and experimental analogies the study analyses hydrogen diffusion patterns overpressure dynamics and thermal impacts following an LH2 tank rupture. Results show that LH2 explosions generate overpressures exceeding 50 bar and temperatures surpassing 2500 ◦C far exceeding the hazards posed by gaseous hydrogen leaks. Mitigation measures such as suction ventilation and high humidity significantly reduce explosion impacts underscoring their value for tunnel safety. This research advances understanding of hydrogen safety in confined spaces demonstrating the importance of integrating mitigation measures into tunnel design. The findings contribute to disaster prevention strategies offer insights into optimizing safety protocols and support the development of resilient infrastructure capable of accommodating hydrogen technologies in a rapidly evolving energy landscape.
Levelized Cost of Hydrogen from Offtakers Standpoint: An Overlooked Perspective Via Case Studies in Warrnambool, Australia
Aug 2025
Publication
Green hydrogen is a promising energy vector for replacing fossil fuels in hard-to-abate sectors but its cost hinders widespread deployment. This research develops an exact MILP model to optimize the design of integrated green energy projects minimizing the total annual cost between different power configurations. The model is applied to a case study in regional Victoria Australia which supports a fleet of nine fuel cell electric buses requiring 1160 kg of hydrogen per week. The optimal system includes a 453 kW electrolyzer 212 kg of storage in compressed hydrogen vessels 704 kW of solar PV and 635 kW of wind power firmed with grid electricity. The LCOH is 14.8 A$/kg which is higher than other estimates in the literature for Australia. This is arguably due to the idle capacities resulting from intermittent hydrogen demand. Producing additional hydrogen with surplus or low-priced electricity could reduce LCOH to 12.4 A$/kg. Sensitivity analyzes confirm the robustness of the system to variations in key parameter costs resource availability and estimated energy supply and demand.
Efficient and Stable N-type Sulfide Overall Water Splitting with Separated Hydrogen Production
Aug 2025
Publication
N-type sulfide semiconductors are promising photocatalysts due to their broad visible-light absorption facile synthesis and chemical diversity. However photocorrosion and limited electron transport in one-step excitation and solid-state Z-scheme systems hinder efficient overall water splitting. Liquidphase Z-schemes offer a viable alternative but sluggish mediator kinetics and interfacial side reactions impede their construction. Here we report a stable Z-scheme system integrating n-type CdS and BiVO₄ with a [Fe(CN)₆]³⁻/[Fe(CN)₆]⁴⁻ mediator achieving 10.2% apparent quantum yield at 450 nm with stoichiometric H₂/O₂ evolution. High activity reflects synergies between Pt@CrOx and Co3O4 cocatalysts on CdS and cobalt-directed facet asymmetry in BiVO₄ resulting in matched kinetics for hydrogen and oxygen evolution in a reversible mediator solution. Stability is dramatically improved through coating CdS and BiVO4 with different oxides to inhibit Fe4[Fe(CN)6]3 precipitation and deactivation by a hitherto unrecognized mechanism. Separate hydrogen and oxygen production is also demonstrated in a twocompartment reactor under visible light and ambient conditions. This work unlocks the long-sought potential of n-type sulfides for efficient durable and safe solar-driven hydrogen production.
Ways to Assess Hydrogen Production via Life Cycle Analysis
Apr 2025
Publication
As global energy demand increases and reliance on fossil fuels becomes unsustainable hydrogen presents a promising clean energy alternative due to its high energy density and potential for significant CO2 emission reductions. However current hydrogen production methods largely depend on fossil fuels contributing to considerable CO2 emissions and underscoring the need to transition to renewable energy sources and improved production technologies. Life Cycle Analysis (LCA) is essential for evaluating and optimizing hydrogen production by assessing environmental impacts such as Global Warming Potential (GWP) energy consumption toxicity and water usage. The key findings indicate that energy sources and feedstocks heavily influence the environmental impacts of hydrogen production. Hydrogen production from renewable energy sources particularly wind solar and hydropower demonstrates significantly lower environmental impacts than grid electricity and fossil fuel-based methods. Conversely hydrogen production from grid electricity primarily derived from fossil fuels shows a high GWP. Furthermore challenges related to data accuracy economic analysis integration and measuring mixed gases are discussed. Future research should focus on improving data accuracy assessing the impact of technological advancements and exploring new hydrogen production methods. Harmonizing assessment methodologies across different production pathways and standardizing functional units such as “1 kg of hydrogen produced “ are critical for enabling transparent and consistent sustainability evaluations. Techniques such as stochastic modelling and Monte Carlo simulations can improve uncertainty management and enhance the reliability of LCA results.
Advancement in Hydrogen Production, Application and Strategy Towards Sustainable Energy: Malaysian Case Study
Aug 2025
Publication
Biohydrogen is known for its clean fuel properties with zero emissions. It serves as a reliable alternative to fossil fuel. This paper analyses the status of bio-hydrogen production in Malaysia and the on-going efforts on its advancement. Critical discussions were put forward on biohydrogen production from thermochemical and biological technologies governing associated technological issues and development. Moreover a comprehensive and vital overview has been made on Malaysian and global polices with road maps for the development of biohydrogen and its application in different sectors. This review article provides a framework for researchers on bio-hydrogen production technologies investors and the government to align policies for the biohydrogen based economy. Current biohydrogen energy outlook for production installation units and storage capacity are the key points to be highlighted from global and Malaysia’s perspectives. This critical and comprehensive review provides a strategic route for the researcher to research towards sustainable technology. Current policies related to hydrogen as fuel infrastructure in Malaysia and commercialization are highlighted. Malaysia is also gearing towards clean and decarbonization planning.
A Novel Site Selection Approach for Co-location of Petrol-hydrogen Fuelling Stations Using a Game Theory-based Multi-criteria Decision-making Model
Feb 2025
Publication
Proliferation of co-located petrol-hydrogen fueling stations is an effective solution for widespread deployment of hydrogen as a transportation fuel. Such combined fueling stations largely rely on existing infrastructure hence represent a low-cost option for setting up hydrogen fueling facilities. However optimizing the layout of dual petrol-hydrogen fueling stations and their rational site selection is critical for ensuring the efficient use of re sources. This paper investigates the site selection of combined hydrogen and petrol fueling stations at the ter minus of China’s "West-to-East Hydrogen Pipeline" project. A weighting model based on EWM-CRITIC-Game Theory is developed and the weight coefficients derived from game theory are used to perform the compre hensive ranking of potential sites. The combined evaluation results yield an overall ranking of A9 > A4 > A8 > A26 > A20 > A21 > A11. The effectiveness of this novel method is verified by comparing the results with those obtained from Copeland Borda Average and geometric mean methods. Considering the actual distance con straints the final site ranking is A9 > A4 > A8 > A20 > A21 > A11 > A14. This location offers optimal con ditions for infrastructure integration and hydrogen fueling service coverage. The reliability analysis indicates that the proposed game theory-based method delivers strong performance across various scenarios underscoring its reliability and versatility in consistently delivering accurate results.
An Electron-hole Rich Dual-site Nickel Catalyst for Efficient Photocatalytic Overall Water Splitting
Mar 2023
Publication
Photocatalysis offers an attractive strategy to upgrade H2O to renewable fuel H2. However current photocatalytic hydrogen production technology often relies on additional sacrificial agents and noble metal cocatalysts and there are limited photocatalysts possessing overall water splitting performance on their own. Here we successfully construct an efficient catalytic system to realize overall water splitting where hole-rich nickel phosphides (Ni2P) with polymeric carbon-oxygen semiconductor (PCOS) is the site for oxygen generation and electron-rich Ni2P with nickel sulfide (NiS) serves as the other site for producing H2. The electron-hole rich Ni2P based photocatalyst exhibits fast kinetics and a low thermodynamic energy barrier for overall water splitting with stoichiometric 2:1 hydrogen to oxygen ratio (150.7 μmol h−1 H2 and 70.2 μmol h−1 O2 produced per 100 mg photocatalyst) in a neutral solution. Density functional theory calculations show that the co-loading in Ni2P and its hybridization with PCOS or NiS can effectively regulate the electronic structures of the surface active sites alter the reaction pathway reduce the reaction energy barrier boost the overall water splitting activity. In comparison with reported literatures such photocatalyst represents the excellent performance among all reported transition-metal oxides and/or transition-metal sulfides and is even superior to noble metal catalyst.
Tempering-induced Modulation of Hydrogen Embrittlement in Additvely Manufactured AISI 4340 Steel
Sep 2025
Publication
Recent studies on additive manufacturing (AM) have indicated the necessity of understanding the hydrogen embrittlement (HE) of high-strength steels fabricated by AM due to the different microstructure obtained compared to their conventionally processed counterparts. This study investigated the influence of post-AM tempering (at 205 ◦C 315 ◦C and 425 ◦C) on the HE resistance of AM-fabricated AISI 4340 steel a representative ultrahigh-strength medium-carbon low-alloy steel. The present results show that tempering effectively reduced the HE sensitivity of the steel. When tested in air tempering at a low temperature of 205 ◦C slightly increased both the yield strength (YS) and ultimate tensile strength (UTS) accompanied by a reduction in elongation (EL). This behaviour is attributed to the precipitation of carbides. In contrast higher tempering temperatures of 315 ◦C and 425 ◦C resulted in a progressive decrease in both YS and UTS as anticipated. However when tested in a hydrogen-rich environment although the HE dramatically reduced the ductility and YS could not even be determined for the samples tempered at 205 ◦C and 315 ◦C the tempered samples retained higher UTS and EL compared to the as-AM-fabricated samples because of the increased HE resistance by tempering. Microstructural examination indicated that tempering at 205 ◦C and 315 ◦C retained the bainitic microstructure while promoting the formation of fine carbide precipitates which softened the bainitic ferrite matrix enhancing the hydrogen trapping capacity. Tempering at 425 ◦C promoted recovery of the AM-fabricated steel reducing dislocation density producing a lower subsurface hydrogen concentration and higher hydrogen diffusivity which led to an enhanced HE resistance. As a result testing of the samples tempered at 425 ◦C in hydrogen resulted in a high YS (~1200 MPa) and only a ~5 % reduction in UTS and a 64 % reduction in EL compared with the untempered samples of which the reductions were 31 % in UTS and 79 % in EL. Furthermore this study underscores the critical role of the trap character in governing the HE behaviour offering a pathway toward optimised heat treatment strategies for improved HE resistance of additively manufactured high-strength steels.
Integrated Membrane Distillation-solid Electrolyte-based Alkaline Water Electrolysis for Enhancing Green Hydrogen Production
Jan 2025
Publication
This paper investigates the circularity of green hydrogen and resource recovery from brine using an integrated approach based on alkaline water electrolysis (AWE). Traditional AWE employs highly alkaline electrolytes which can lead to electrode corrosion undesirable side reactions and gas cross-over issues. Conversely indirect brine electrolysis requires pre-treatment steps which negatively impact both techno-economics and environmental sustainability. In response this study proposes an innovative brine electrolysis process utilizing solid electrolytes (SELs). The process includes an on-site brine treatment facility leveraging a self-driven phase transition technique and incorporates a hydrophobic membrane as part of a membrane distillation (MD) system to facilitate the gas pathway. Polyvinyl alcohol (PVA) and tetraethylammonium hydroxide (TEAOH)-based electrolytes combined with potassium hydroxide (KOH) at various concentrations function as a self-wetted electrolyte (SWE). This design partially disperses water vapor while effectively preventing the intrusion of contaminated ions into the SWE and electrode-catalyst interfaces. PVA-TEAOH-KOH-30 wt% SWE demonstrated the highest ion conductivity (112.4 mScm−1) and excellent performance with a current density of 375 mAcm−2. Long-term electrolysis confirmed with a nine-fold brine in volume concentration factor (VCF) demonstrated stable performance without MD membrane wetting. The Cl−/ClO− and Br− concentrations in the SWE were reduced by five orders of magnitude compared to the original brine. This electrolyzer supports the circular use of resources with hydrogen as an energy carrier and concentrated brine and oxygen as valuable by-products aligning with the sustainable development goals (SDGs) and net-zero emissions by 2050.
A Novel Flow Channel Design for Improving Water Splitting in Anion Exchange Membrane Electrolysers
Jul 2025
Publication
Anion exchange membrane (AEM) alkaline water electrolyser s are a promising reactor in large - scale industrial green hydrogen production. However the configurations of electrolysers especially the flow channel are not well optimised. In this work we demonstrate that the several existing flow channel designs e.g. single serpentine parallel pin can significantly affect the AEM electrolysers’ performance. The two -phase flow behaviours associated with the mass transfer of both electrolyte and produced gas bubbles within these flow channels have been simulated and thoroughly studied via a three -dimensional (3D) computational fluid dynamics (CFD) model . A novel flow channel design named Parpentine that combines the features of Parallel and Single serpentine designs is proposed with an optimised balance among the electrolyte flow distribution bubble removal rate and pressure drop. The superiority of the Parpentine flow channel is well verified in practical AEM water electrolyser experiments using commercial Ni foam and self-designed efficient NiFe and NiMo electrodes. At a cell voltage of 2.5 V compared to the benchmark serpentine design a 12.4% ~ 34.8% increase in hydrogen production efficiency can be achieved in both 1 M and 5 M KOH conditions at room temperature. This work discovers a novel design and a new method for highly efficient water electrolysers.
Assessing Cement Durability in Hydrogen-driven Underground Storage Systems
Oct 2025
Publication
As the world shifts towards renewable energy sources the need for reliable large-scale energy storage solutions becomes increasingly critical. Underground Hydrogen Storage (UHS) emerges as a promising option to bridge this gap. However the success of UHS heavily depends on the durability of infrastructure materials particularly cement in wellbores and in unlined rock caverns (URCs) where it serves a dual role in grouting and sealing. This study explores the chemical interactions between hydrogen and cement in these environments exploring how hydrogen might compromise cement integrity over time. We employed advanced thermodynamic analyses kinetic batch tests and 1D reactive transport models to simulate the behaviour of cement when exposed to hydrogen under conditions found in two potential UHS sites: the Haje URC in the Czech Republic and a depleted gas field in the Perth Basin Western Australia. Our results reveal that while certain cement phases are vulnerable to dissolution the overall increase in porosity is minimal suggesting a lower risk of significant degradation. Notably hydrogen was found to penetrate 5 cm of cement within just 4–5 days at both sites. These insights are crucial for enhancing the design and maintenance strategies of UHS facilities. Moreover this study not only advances our understanding of material sciences in the context of hydrogen energy storage but also underscores the importance of sustainable infrastructure in the transition away from fossil fuels.
Zone Negligible Extent: Example of Specific Detailed Risk Assessment for Low Pressure Equipment in a Hydrogen Refuelling Station
Sep 2023
Publication
The MultHyFuel project aims to develop evidence-based guidelines for the safe implementation of Hydrogen Refueling Stations (HRS) in a multi-fuel context. As a part of the generation of good practice guidelines for HRS Hazardous Area Classification (HAC) methodologies were analyzed and applied to case studies representing example configurations of HRS. It has been anticipated that Negligible Extent (NE) classifications might be applicable for sections of the HRS for instance a hydrogen generator. A NE zone requires that an ignition of a flammable cloud would result in negligible consequences. In addition depending on the pressure of the system IEC 60079-10-1:2020 establishes specific requirements in order to classify the hazardous area as being of NE. One such requirement is that a zone of NE shall not be applied for releases from flammable gas systems at pressures above 2000 kPag (20 barg) unless a specific detailed risk assessment is documented. However there is no definition within the standard as to the requirements of the specific detailed risk assessment. In this work an example for a specific detailed risk assessment for the NE classification is presented:<br/>• Firstly the requirements of cloud volume dilution and background concentration for a zone of NE classification from IEC 60079-10-1:2020 are analyzed for hydrogen releases from equipment placed in a mechanically ventilated enclosure.<br/>• Secondly the consequences arising from the ignition of the localized cloud are estimated and compared to acceptable harm criteria in order to assess if negligible consequences are obtained from the scenario.<br/>• In addition a specific qualitative risk assessment for the ignition of the cloud in the enclosure was considered incorporating the estimated consequences and analyzing the available safeguards in the example system.<br/>Recommendations for the specific detailed risk assessment are proposed for this scenario with the intention to support improved definition of the requirement in future revisions of IEC 60079-10-1.
Integrating Alkaline Electrolysis with Oxyfuel Combustion for Hydrogen and Electricity Production
Feb 2024
Publication
The present study explores the potential of integrating the NET Zero Cycle (NZC) with hydrogen production by alkaline electrolyzers. To achieve this an Aspen Plus model was developed for the NZC and its accuracy was first confirmed by comparing it with literature data. The creation of a model for an alkaline electrolyzer was achieved using Aspen Custom Modeler and later imported into Aspen Plus. A comprehensive simulation was conducted in Aspen Plus to examine the synergies between the NZC and the alkaline electrolyzer. In this integration the oxygen demand of the NZC is met by a combination of an air separation unit (ASU) and the electrolyzer. The electrolyzer not only partially fulfills the oxygen requirements but also acts as an external heat supplier for the regenerator. Additionally the NZC supplies deionized water to the electrolyzer. A thermodynamic analysis in dicates that the integration of the NZC and alkaline electrolyzers results in a higher efficiency of 56.5 % compared to the stand-alone NZC an improvement of 2.3 %. Assuming that the NZC and alkaline electrolyzer operate at the same power production and input levels the alkaline electrolyzer can generate substantial oxygen to reduce the energy consumption of the ASU significantly. This aspect represents one of the primary reasons for the enhanced efficiency observed in this study. However the ASU still needs to be operated to provide the full oxygen demands of the process. To identify the key parameters influencing the integration of the NZC and alkaline electrolyzers a sensitivity analysis was performed. To enhance the system efficiency a comprehensive investigation was conducted to analyze the influence of key parameters such as combustor outlet temperature (COT) turbine outlet pressure (TOP) and combustor outlet pressure (COP) on the thermodynamic first law efficiency of the cycle. An increase in electrolyzer input power and a reduction in electrolyzer inlet feed were associated with a higher cycle effi ciency. The results also highlight that the TOP COT and the electrolyzer input power have a more significant impact on the cycle thermodynamic first law efficiency within the range of 5.7 4.0 and 2.6 % respectively while COP only causes a 0.4 % change in cycle efficiency. The integrated system demonstrates an impressive system first law thermodynamic efficiency of 62.5 % and exergy efficiency of 60.6 %.
Hydrogen Storage Performance During Underground Hydrogen Storage in Depleted Gas Reservoirs: A Review
Mar 2024
Publication
Hydrogen has emerged as a promising alternative to meet the growing demand for sustainable and renewable energy sources. Underground hydrogen storage (UHS) in depleted gas reservoirs holds significant potential for large-scale energy storage and the seamless integration of intermittent renewable energy sources due to its capacity to address challenges associated with the intermittent nature of renewable energy sources ensuring a steady and reliable energy supply. Leveraging the existing infrastructure and well-characterized geological formations depleted gas reservoirs offer an attractive option for large-scale hydrogen storage implementation. However significant knowledge gaps regarding storage performance hinder the commercialization of UHS operation. Hydrogen deliverability hydrogen trapping and the equation of state are key areas with limited understanding. This literature review critically analyzes and synthesizes existing research on hydrogen storage performance during underground storage in depleted gas reservoirs; it then provides a high-level risk assessment and an overview of the techno-economics of UHS. The significance of this review lies in its consolidation of current knowledge highlighting unresolved issues and proposing areas for future research. Addressing these gaps will advance hydrogen-based energy systems and support the transition to a sustainable energy landscape. Facilitating efficient and safe deployment of UHS in depleted gas reservoirs will assist in unlocking hydrogen’s full potential as a clean and renewable energy carrier. In addition this review aids policymakers and the scientific community in making informed decisions regarding hydrogen storage technologies.
A Review of the Mechanics of Lined Engineered Cavities and their Implications on Hydrogen Storage
Jan 2025
Publication
Large-scale hydrogen storage at scales ranging from gigawatt-hours (GWh) to terawatt-hours (TWh) is currently projected to be an important component of the lowest cost options for a 100% variable renewable energy system driven partly by benefits to the grid from converting variable renewable electricity into hydrogen and partly by the anticipated growing role of hydrogen in a future net-zero energy system. Lined engineered cavities (LEC)s are among the prospective types of underground storage technology because they enable hydrogen storage at highpressure in the gaseous form and are expected to not rely on specific types of rock mass. They fill a niche in moderate storage capacity and cost because of their complementary advantages. An overview of various possible configurations and materials suitable for LECs for storing hydrogen is first reviewed to identify potential cost savings and performance improvements. Amongst the various LEC configurations lined engineered shafts (LES) are identified as having the greatest potential for cost reduction in softer rock masses such as sedimentary formations due to reduced excavation and construction complexity. Despite these advantages significant gaps remain in understanding the long-term behaviour of LES under cyclical loading as revealed through a review of the theoretical and experimental techniques used to study similar LEC configurations. This review paper con cludes with several recommendations for future research in numerical model formulation and material advancement with strong potential to increase the feasibility of LESs for hydrogen storage.
A Study on Hydrogen Embrittlement of a High-strength Pipeline Steel Weldment after Microstructure Manipulation by Targeted Heat Treatments
Dec 2024
Publication
Hydrogen embrittlement (HE) is a major concern when steel pipelines are used for hydrogen transportation and storage. The weldments of steel pipelines are of particular concern because they are reported to have higher HE susceptibility compare to the base metal. In this work targeted heat treatments were used to manipulate the microstructure in a pipeline steel weldment to examine the effects of different microstructural features on HE susceptibility. Complementary analyses of the microstructure mechanical testing and fracture surface identified inclusions and ferrite morphology as the most dominant microstructural features that affect the susceptibility to HE. Specimens with different microstructures but sharing similar Ti-rich inclusions exhibited significant re ductions in elongation to failure after hydrogen charging and showed brittle fracture surfaces decorated with multiple ‘fish-eye’ features. In addition co-existence of bainitic microstructure with Ti-rich inclusions resulted in the highest susceptibility to HE.
An Overview of Hydrogen Storage Technologies - Key Challenges and Opportunities
Jul 2024
Publication
Hydrogen energy has been proposed as a reliable and sustainable source of energy which could play an integral part in demand for foreseeable environmentally friendly energy. Biomass fossil fuels waste products and clean energy sources like solar and wind power can all be employed for producing hydrogen. This comprehensive review paper provides a thorough overview of various hydrogen storage technologies available today along with the benefits and drawbacks of each technology in context with storage capacity efficiency safety and cost. Since safety concerns are among the major barriers to the broad application of H2 as a fuel source special attention has been paid to the safety implications of various H2 storage techniques. In addition this paper highlights the key challenges and opportunities facing the development and commercialization of hydrogen storage technologies including the need for improved materials enhanced system integration increased awareness and acceptance. Finally recommendations for future research and development with a particular focus on advancing these technologies towards commercial viability.
Advancing a Hydrogen Economy in Australia: Public Perceptions and Aspirations
Nov 2023
Publication
Supporters of hydrogen energy urge scaling up technology and reducing costs for competitiveness. This paper explores how hydrogen energy technologies (HET) are perceived by Australia’s general population and considers the way members of the public imagine their role in the implementation of hydrogen energy now and into the future. The study combines a nationally representative survey (n = 403) and semi-structured interviews (n = 30). Results show age and gender relationships with self-reported hydrogen knowledge. Half of the participants obtained hydrogen information from televised media. Strong support was observed for renewable hydrogen while coal (26%) and natural gas (41%) versions had less backing. Participants sought more safety-related information (41% expressed concern). Most felt uncertain about influencing hydrogen decisions and did not necessarily recognise they had agency beyond their front fence. Exploring the link between political identity and agency in energy decision-making is needed with energy democracy a potentially productive direction.
Techno-economic Analysis and Dynamic Operation of Green Hydrogen-integrated Microgrid: An Application Study
Aug 2025
Publication
The shift to renewable energy sources requires systems that are not only environmentally sustainable but also cost-effective and reliable. Mitigating the inherent intermittency of renewable energy optimally managing the hybrid energy storage efficiently integrating the microgrid with the power grid and maximizing the lifespan of system components are the significant challenges that need to be addressed. With this aim the paper proposes an economic viability assessment framework with an optimized dynamic operation approach to determine the most stable cost-effective and environmentally sound system for a specific location and demand. The green integrated hybrid microgrid combines photovoltaic (PV) generation battery storage an electrolyzer a hydrogen tank and a fuel cell tailored for deployment in remote areas with limited access to conventional infrastructure. The study’s control strategy focuses on managing energy flows between the renewable energy resources battery and hydrogen storage systems to maximize autonomy considering real-time changes in weather conditions load variations and the state of charge of both the battery and hydrogen storage units. The core system’s components include the interlinking converter which transfers power between AC and DC grids and the decentralized droop control approach which adjusts the converter’s output to ensure balanced and efficient power sharing particularly during overload conditions. A cloud-based Internet of Things (IoT) platform has been employed allowing continuous monitoring and data analysis of the green integrated microgrid to provide insights into the system's health and performance during the dynamic operation. The results presented in this paper confirmed that the proposed framework enabled the strategic use of energy storage particularly hydrogen systems. The optimal operational control of green hydrogen-integrated microgrid can indeed mitigate voltage and frequency fluctuations caused by variable solar input ensuring stable power delivery without reliance on the main grid or fossil fuel backups.
Hybrid Renewable Multi-generation System Optimization: Attaining Sustainable Development Goals
Jan 2025
Publication
The optimization of hybrid renewable multi-generation systems is crucial for enhancing energy efficiency reducing costs and ensuring sustainable power generation. These factors can be significantly affected by system designs optimization methods climate changes and varying energy demands. The optimization of a stand-alone hybrid renewable energy system (HRES) that integrates various combinations of electricity heating cooling hydrogen and freshwater needs has not been reported in a single comprehensive study. Additionally there has been insufficient attention given to the impact of temporal resolution the recovery of excess energy usage and aligning these efforts with the sustainable development goals (SDGs). This study reviews the recent state-of-theart studies on the stand-alone HRES options for meeting electric heating cooling hydrogen electric vehicles and freshwater demands with various combinations. This study further contributes by examining contemporary literature on sizing optimization reliability analysis sensitivity analysis control techniques detailed modelling and techno-environmental-economic features. It also provides justification for selecting configurations suitable for specific geographical locations along with an analysis of the choice of algorithms and power management systems required to meet the various load demands of a self-sufficient community. By highlighting the im provements and potentials of HRES to achieve various United Nations SDGs this review study aims to bridge existing research gaps.
A Moving Window Method for Time Series Optimisation, with Applications to Energy Storage and Hydrogen Production
Jan 2025
Publication
Temporal decomposition methods aim to solve optimisation problems by converting one problem over a large time series into a series of subproblems over shorter time series. This paper introduces one such method where subproblems are defined over a window that moves back and forth repeatedly over the length of the large time series creating a convergent sequence of solutions and mitigating some of the boundary considerations prevalent in other temporal decomposition methods. To illustrate this moving window method it is applied to two models: an energy storage facility trading electricity in a market; and a hydrogen electrolyser powered by renewable electricity produced and potentially stored onsite. The method is simple to implement and it is found that for large optimisation problems it consistently requires less computation time than the base optimisation algorithm used in this study (by factors up to 100 times). In addition it is analytically demonstrated that decomposition methods in which a minimum is attained for each subproblem need not attain a minimum for the overall problem.
Feasibility of Retrofitting a Conventional Vessel with Hydrogen Power Systems: A Case Study in Australia
Feb 2025
Publication
As the pursuit of greener energy solutions continues industries worldwide are turning away from fossil fuels and exploring the development of sustainable alternatives to meet their energy requirements. As a signatory to the Paris Agreement Australia has committed to reducing greenhouse gas emission by 43% by 2030 and reaching net-zero emissions by 2050. Australia’s domestic maritime sector should align with these targets. This paper aims to contribute to ongoing efforts to achieve these goals by examining the technical and commercial considerations involved in retrofitting conventional vessels with hydrogen power. This includes but is not limited to an analysis of cost risk and performance and compliance with classification society rules international codes and Australian regulations. This study was conducted using a small domestic commercial vessel as a reference to explore the feasibility of implementation of hydrogen-fuelled vessels (HFVs) across Australia. The findings indicate that Australia’s existing hydrogen infrastructure requires significant development for HFVs to meet the cost risk and performance benchmarks of conventional vessels. The case study identifies key determining factors for feasible hydrogen retrofitting and provides recommendations for the success criteria.
Green Hydrogen Credit Subsidized Renewable Energy-hydrogen Business Models for Achieving the Carbon Netural Future
Feb 2024
Publication
The global resurgence of hydrogen as a clean energy source particularly green hydrogen derived from renewable energy is pivotal for achieving a carbon-neutral future. However scalability poses a significant challenge. This research proposes innovative business models leveraging the low-emission property of green hydrogen to reduce its financial costs thereby fostering its widespread adoption. Key components of the business workflow are elaborated mathematical formulations of market parameters are derived and case studies are presented to demonstrate the feasibility and efficiency of these models. Results demonstrate that the substantial costs associated with the current hydrogen industry can be effectively subsidized via the implementation of proposed business models. When the carbon emission price falls within the range of approximately 86–105 USD/ton free access to hydrogen becomes a viable option for end-users. This highlights the significance and promising potential of the proposed business models within the green hydrogen credit framework.
Renewable Hydrogen Requirements and Impacts for Network Balancing: A Queensland Cae Study
Dec 2023
Publication
Hydrogen is the gas of the moment: an abundant element that can be created using renewable energy transported in gaseous or liquid form and offering the ability to provide energy with only water vapour as an emission. Hydrogen can also be used in a fuel blend in electricity generation gas turbines providing a low carbon option for providing the peak electricity to cover high demand and firming.<br/>While the electricity grid is itself transforming to decarbonising hard-to-abate industries such as cement and bauxite refineries are slower to reduce emissions constrained by their high temperature process requirements. Hydrogen offers a solution allowing onsite production process heat with waste heat recovery supporting blended gas turbine generation for onsite electricity supply.<br/>This article builds on decarbonisation pathway simulation results from an ANEM model of the electricity grid identifying the amount of peak demand energy required from gas turbines. The research then examines the quantity flow rate storage requirements and emissions reduction if this peak generation were supplied by open cycle hydrogen capable gas turbines.
Fuelling the Future: An In-depth Review of Recent Trends, Challenges and Opportunities of Hydrogen Fuel Cell for a Sustainable Hydrogen Economy
Sep 2023
Publication
Hydrogen has gained tremendous momentum worldwide as an energy carrier to transit to a net zero emission energy sector. It has been widely adopted as a promising large-scale renewable energy (RE) storage solution to overcome RE resources’ variability and intermittency nature. The fuel cell (FC) technology became in focus within the hydrogen energy landscape as a cost-effective pathway to utilize hydrogen for power generation. Therefore FC technologies’ research and development (R&D) expanded into many pathways such as cost reduction efficiency improvement fixed and mobile applications lifetime safety and regulations etc. Many publications and industrial reports about FC technologies and applications are available. This raised the necessity for a holistic review study to summarize the state-of-the-art range of FC stacks such as manufacturing the balance of plant types technologies applications and R&D opportunities. At the beginning the principal technologies to compare the well known types followed by the FC operating parameters are presented. Then the FC balance of the plant i.e. building components and materials with its functionality and purpose types and applications are critically reviewed with their limitations and improvement opportunities. Subsequently the electrical properties of FCs with their key features including advantages and disadvantages were investigated. Applications of FCs in different sectors are elaborated with their key characteristics current status and future R&D opportunities. Economic attributes of fuel cells with a pathway towards low cost are also presented. Finally this study identifies the research gaps and future avenues to guide researchers and the hydrogen industry.
Comprehensive Review of Development and Applications of Hydrogen Energy Technologies in China for Carbon Neutrality: Technology Advances and Challenges
Jul 2024
Publication
Concerning the transition from a carbon-based energy economy to a renewable energy economy hydrogen is considered an essential energy carrier for efficient and broad energy systems in China in the near future. China aims to gradually replace fossil fuel-based power generation with renewable energy technologies to achieve carbon neutrality by 2060. This ambitious undertaking will involve building an industrial production chain spanning the production storage transportation and utilisation of hydrogen energy by 2030 (when China’s carbon peak will be reached). This review analyses the current status of technological R&D in China’s hydrogen energy industry. Based on published data in the open literature we compared the costs and carbon emissions for grey blue and green hydrogen production. The primary challenges concerning hydrogen transportation and storage are highlighted in this study. Given that primary carbon emissions in China are a result of power generation using fossil fuels we provide an overview of the advances in hydrogen-to-power industry technology R&D including hydrogen-related power generation technology hydrogen fuel cells hydrogen internal combustion engines hydrogen gas turbines and catalytic hydrogen combustion using liquid hydrogen carriers (e.g. ammonia methanol and ethanol).
Optimal Planning of Renewable Energy Park for Green Hydrogen Production Using Detailed Cost and Efficiency Curves of PEM Electrolyzer
Jul 2024
Publication
Installing multi-renewable energy (RE) power plants at designated locations known as RE parks is a promising solution to address their intermittent power. This research focuses on optimizing RE parks for three scenarios: photovoltaic (PV)-only wind-only and hybrid PV-wind with the aim of generating green hydrogen in locations with different RE potentials. To ensure rapid response to RE fluctuations a Proton Exchange Membrane (PEM) electrolyzer is employed. Furthermore this research proposes detailed models for manufacturer-provided wind power curves electrolyzer efficiency against its operating power and electrolyzer cost towards its capacity. Two optimization cases are conducted in MATLAB evaluating the optimum sizes of the plants in minimizing levelized cost of hydrogen (LCOH) using classical discrete combinatorial method and determining the ideal PV-to-wind capacity ratio for operating PEM electrolyzer within hybrid PV-wind parks using particle swarm optimization. Numerical simulations show that wind power-based hydrogen production is more cost-effective than PV-only RE parks. The lowest LCOH $4.26/kg H2 and the highest LCOH $14.378/kg H2 are obtained from wind-only and PV-only configurations respectively. Both occurred in Adum-Kirkeby Denmark as it has highest average wind speed and lowest irradiance level. Notably LCOH is reduced with the hybrid PV-wind configuration. The results suggest the optimum PV-to-wind capacity ratio is 65:35 on average and indicate that LCOH is more sensitive to electrolyzer’s cost than to electricity tariff variation. This study highlights two important factors i.e. selecting the suitable location based on the available RE resources and determining the optimum size ratio between the plants within the RE park.
Enabling Safe and Sustainable Hydrogen Mobility: Circular Economy-Driven Management of Hydrogen Vehicle Safety
Sep 2023
Publication
Hydrogen vehicles encompassing fuel cell electric vehicles (FCEVs) are pivotal within the UK’s energy landscape as it pursues the goal of net-zero emissions by 2050. By markedly diminishing dependence on fossil fuels FCEVs including hydrogen vehicles wield substantial influence in shaping the circular economy (CE). Their impact extends to optimizing resource utilization enabling zero-emission mobility facilitating the integration of renewable energy sources supplying adaptable energy storage solutions and interconnecting diverse sectors. The widespread adoption of hydrogen vehicles accelerates the UK’s transformative journey towards a sustainable CE. However to fully harness the benefits of this transition a robust investigation and implementation of safety measures concerning hydrogen vehicle (HV) use are indispensable. Therefore this study takes a holistic approach integrating quantitative risk assessment (QRA) and an adaptive decision-making trial and evaluation laboratory (DEMATEL) framework as pragmatic instruments. These methodologies ensure both the secure deployment and operational excellence of HVs. The findings underscore that the root causes of HV failures encompass extreme environments material defects fuel cell damage delivery system impairment and storage system deterioration. Furthermore critical driving factors for effective safety intervention revolve around cultivating a safety culture robust education/training and sound maintenance scheduling. Addressing these factors is pivotal for creating an environment conducive to mitigating safety and risk concerns. Given the intricacies of conducting comprehensive hydrogen QRAs due to the absence of specific reliability data this study dedicates attention to rectifying this gap. A sensitivity analysis encompassing a range of values is meticulously conducted to affirm the strength and reliability of our approach. This robust analysis yields precise dependable outcomes. Consequently decision-makers are equipped to discern pivotal underlying factors precipitating potential HV failures. With this discernment they can tailor safety interventions that lay the groundwork for sustainable resilient and secure HV operations. Our study navigates the intersection of HVs safety and sustainability amplifying their importance within the CE paradigm. Using the careful amalgamation of QRA and DEMATEL methodologies we chart a course towards empowering decision-makers with the insights to steer the hydrogen vehicle domain to safer horizons while ushering in an era of transformative eco-conscious mobility.
A Review of Gas Phase Inhibition of Gaseous Hydrogen Embrittlement in Pipeline Steels
Feb 2024
Publication
The addition of small amounts of certain gases such as O2 CO and SO2 may mitigate hydrogen embrittlement in high-pressure gas transmission pipelines that transport hydrogen. To practically implement such inhibition in gas transmission pipelines a comprehensive understanding and quantification of this effect are essential. This review examines the impact of various added gases to hydrogen including typical odorants on gaseous hydrogen embrittlement of steels and evaluates their inhibition effectiveness. O2 CO and SO2 were found to be effective inhibitors of hydrogen embrittlement. Yet the results in the literature have not always been consistent partly because of the diverse range of mechanical tests and their parameters. The absence of systematic studies hinders the evaluation of the feasibility of using gas phase inhibitors for controlling gaseous hydrogen embrittlement. A method to quantify the effectiveness of gas phase inhibition is proposed using gas phase permeation studies.
Greenhouse Gas Emissions Performance of Electric, Hydrogen and Fossil-Fuelled Freight Trucks with Uncertainty Estimates Using a Probabilistic Life-Cycle Assessment (pLCA)
Jan 2024
Publication
This research conducted a probabilistic life-cycle assessment (pLCA) into the greenhouse gas (GHG) emissions performance of nine combinations of truck size and powertrain technology for a recent past and a future (largely decarbonised) situation in Australia. This study finds that the relative and absolute life-cycle GHG emissions performance strongly depends on the vehicle class powertrain and year of assessment. Life-cycle emission factor distributions vary substantially in their magnitude range and shape. Diesel trucks had lower life-cycle GHG emissions in 2019 than electric trucks (battery hydrogen fuel cell) mainly due to the high carbon-emission intensity of the Australian electricity grid (mainly coal) and hydrogen production (mainly through steam–methane reforming). The picture is however very different for a more decarbonised situation where battery electric trucks in particular provide deep reductions (about 75–85%) in life-cycle GHG emissions. Fuel-cell electric (hydrogen) trucks also provide substantial reductions (about 50–70%) but not as deep as those for battery electric trucks. Moreover hydrogen trucks exhibit the largest uncertainty in emissions performance which reflects the uncertainty and general lack of information for this technology. They therefore carry an elevated risk of not achieving the expected emission reductions. Battery electric trucks show the smallest (absolute) uncertainty which suggests that these trucks are expected to deliver the deepest and most robust emission reductions. Operational emissions (on-road driving and vehicle maintenance combined) dominate life-cycle emissions for all vehicle classes. Vehicle manufacturing and upstream emissions make a relatively small contribution to life-cycle emissions from diesel trucks (
Opportunities and Challenges of Hydrogen Ports: An Empirical Study in Australia and Japan
Jul 2024
Publication
This paper investigated the opportunities and challenges of integrating ports into hydrogen (H2 ) supply chains in the context of Australia and Japan because they are leading countries in the field and are potential leaders in the upcoming large-scale H2 trade. Qualitative interviews were conducted in the two countries to identify opportunities for H2 ports necessary infrastructure and facilities key factors for operations and challenges associated with the ports’ development followed by an online survey investigating the readiness levels of H2 export and import ports. The findings reveal that there are significant opportunities for both countries’ H2 ports and their respective regions which encompass business transition processes and decarbonisation. However the ports face challenges in areas including infrastructure training standards and social licence and the sufficiency and readiness levels of port infrastructure and other critical factors are low. Recommendations were proposed to address the challenges and barriers encountered by H2 ports. To optimise logistics operations within H2 ports and facilitate effective integration of H2 applications this paper developed a user-oriented working process framework to provide guidance to ports seeking to engage in the H2 economy. Its findings and recommendations contribute to filling the existing knowledge gap pertaining to H2 ports.
Material Challenges and Hydrogen Embrittlement Assessment for Hydrogen Utilisation in Industrial Scale
Sep 2023
Publication
Hydrogen has been studied extensively as a potential enabler of the energy transition from fossil fuels to renewable sources. It promises a feasible decarbonisation route because it can act as an energy carrier a heat source or a chemical reactant in industrial processes. Hydrogen can be produced via renewable energy sources such as solar hydro or geothermic routes and is a more stable energy carrier than intermittent renewable sources. If hydrogen can be stored efficiently it could play a crucial role in decarbonising industries. For hydrogen to be successfully implemented in industrial systems its impact on infrastructure needs to be understood quantified and controlled. If hydrogen technology is to be economically feasible we need to investigate and understand the retrofitting of current industrial infrastructure. Currently there is a lack of comprehensive knowledge regarding alloys and components performance in long-term hydrogen-containing environments at industrial conditions associated with high-temperature hydrogen processing/production. This review summarises insights into the gaps in hydrogen embrittlement (HE) research that apply to high-temperature high-pressure systems in industrial processes and applications. It illustrates why it is still important to develop characterisation techniques and methods for hydrogen interaction with metals and surfaces under these conditions. The review also describes the implications of using hydrogen in large-scale industrial processes.
Impact of Experimentally Measured Relative Permeability Hysteresis on Reservoir-scale Performance of Undergound Hydrogen Storage (UHS)
Jan 2024
Publication
Underground Hydrogen Storage (UHS) is an emerging large-scale energy storage technology. Researchers are investigating its feasibility and performance including its injectivity productivity and storage capacity through numerical simulations. However several ad-hoc relative permeability and capillary pressure functions have been used in the literature with no direct link to the underlying physics of the hydrogen storage and production process. Recent relative permeability measurements for the hydrogen-brine system show very low hydrogen relative permeability and strong liquid phase hysteresis very different to what has been observed for other fluid systems for the same rock type. This raises the concern as to what extend the existing studies in the literature are able to reliably quantify the feasibility of the potential storage projects. In this study we investigate how experimentally measured hydrogen-brine relative permeability hysteresis affects the performance of UHS projects through numerical reservoir simulations. Relative permeability data measured during a hydrogen-water core-flooding experiment within ADMIRE project is used to design a relative permeability hysteresis model. Next numerical simulation for a UHS project in a generic braided-fluvial water-gas reservoir is performed using this hysteresis model. A performance assessment is carried out for several UHS scenarios with different drainage relative permeability curves hysteresis model coefficients and injection/production rates. Our results show that both gas and liquid relative permeability hysteresis play an important role in UHS irrespective of injection/production rate. Ignoring gas hysteresis may cause up to 338% of uncertainty on cumulative hydrogen production as it has negative effects on injectivity and productivity due to the resulting limited variation range of gas saturation and pressure during cyclic operations. In contrast hysteresis in the liquid phase relative permeability resolves this issue to some extent by improving the displacement of the liquid phase. Finally implementing relative permeability curves from other fluid systems during UHS performance assessment will cause uncertainty in terms of gas saturation and up to 141% underestimation on cumulative hydrogen production. These observations illustrate the importance of using relative permeability curves characteristic of hydrogen-brine system for assessing the UHS performances.
Flame Visibility in Hydrogen Appliances
Sep 2023
Publication
One of the benefits of the direct use of hydrogen is its ability to be burned in a similar way to natural gas using appliances with which the community is already familiar. This is particularly true for applications where electrification is neither practicable nor desirable. One common example is domestic cooking stoves where the open flame offers numerous real and perceived benefits to the chef. Similarly many commercial and industrial appliances rely on the unique properties of combustion to achieve a desired purpose that cannot readily be replaced by an alternative to an open flame. Despite the enormous decarbonisation potential of the direct replacement of natural gas with hydrogen there are some operational constraints due to the different burning characteristics of hydrogen. One of the challenges is the low visible light emission from hydrogen flames. The change in visible radiation from the combustion of hydrogen compared with natural gas is a safety concern whereby visual observation of a flame may be difficult. This paper aims to provide clarity on the visual appearance of hydrogen flames via a series of measurements of flame visibility and emission spectra accompanied by the assessment of strategies to improve the safe use of hydrogen.
Large-scale Production of Green Hydrogen from Solar Energy in Australia: Operation and Control of a Multi-unit PEM Electrolyser System
Dec 2024
Publication
Large-scale production of hydrogen using clean electricity from renewable energy sources (RESs) is gaining more momentum in attempts to foster the growth of the nascent hydrogen energy market. However the inherited intermittency of RESs constitutes a significant challenge for the reliable and economic operation of electrolysers and consequently the overall hydrogen production plant. This paper proposes a power allocation control strategy to regulate the operation of a multi-unit electrolyser plant fed by a solar power system for improved efficiency and economic hydrogen production. Proper implementation of the proposed control strategy can decrease the number of switching times increase hydrogen production raise the efficiency and extend the operational lifespan of the utilised electrolyser units. A solar-hydrogen system comprising a 1 MW electrolyser plant and a battery system is designed and implemented in MATLAB/Simulink environment to validate the efficacy of the proposed control strategy in improving the performance and reliability of an Industrial Green Hydrogen Hub (IGHH). The simulation results showed an improvement of 52.85% in the daily production of hydrogen with an increase of 71.088 kg/day a 68.67% improvement in the efficiency and an enhancement of more than 80% in the utilisation factor of the IGHH compared to other control techniques (traditional choppy control).
The Possibility of Powering a Light Aircraft by Releasing the Energy Stored in Hydrogen within a Fuel Cell Stack
Jun 2024
Publication
In this work we examine the possibility of converting a light propeller-driven aircraft powered by a spark-ignition reciprocating piston and internal combustion engine running on AVGAS into one powered by an electric motor driven by a proton exchange membrane fuel cell stack running on hydrogen. Our studies suggest that storing hydrogen cryogenically is a better option than storing hydrogen under pressure. In comparison to cryogenic tanks high-pressure tanks are extremely heavy and unacceptable for light aircraft. We show that the modified aircraft (including batteries) is no heavier than the original and that the layout of the major components results in lower movement of the aircraft center-of-gravity as the aircraft consumes hydrogen. However we acknowledge that our fuel cell aircraft cannot store the same amount of energy as the original running on AVGAS. Therefore despite the fact that the fuel cell stack is markedly more efficient than an internal combustion engine there is a reduction in the range of the fuel cell aircraft. One of our most important findings is that the quantity of energy that we need to dissipate to the surroundings via heat transfer is significantly greater from a fuel cell stack than from an internal combustion engine. This is particularly the case when we attempt to run the fuel cell stack at high current densities. To control this problem our strategy during the cruise phase is to run the fuel cell stack at its maximum efficiency where the current density is low. We size the fuel cell stack to produce at least enough power for cruise and when we require excess power we add the energy stored in batteries to make up the difference.
Hydrogen Storage in Unlined Rock Caverns: An Insight on Opportunities and Challenges
Jun 2024
Publication
Transitioning to a sustainable energy future necessitates innovative storage solutions for renewable energies where hydrogen (H₂) emerges as a pivotal energy carrier for its low emission potential. This paper explores unlined rock caverns (URCs) as a promising alternative for underground hydrogen storage (UHS) overcoming the geographical and technical limitations of UHS methods like salt rock caverns and porous media. Drawing from the experiences of natural gas (NG) and compressed air energy storage (CAES) in URCs we explore the viability of URCs for storing hydrogen at gigawatt-hour scales (>100 GWh). Despite challenges such as potential uplift failures (at a depth of approximately less than 1000 m) and hydrogen reactivity with storage materials at typical conditions (below temperatures of 100◦C and pressures of 15 MPa) URCs present a flexible scalable option closely allied with green hydrogen production from renewable sources. Our comprehensive review identifies critical design considerations including hydraulic containment and the integrity of fracture sealing materials under UHS conditions. Addressing identified knowledge gaps particularly around the design of hydraulic containment systems and the interaction of hydrogen with cavern materials will be crucial for advancing URC technology. The paper underscores the need for further experimental and numerical studies to refine URC suitability for hydrogen storage highlighting the role of URCs in enhancing the compatibility of renewable energy sources with the grid.
Hydrogen Embrittlement Susceptibility of Additively Manufactured High-strength Low-alloy AISI 4340 Steel
Jul 2025
Publication
Hydrogen embrittlement (HE) poses a significant challenge for high-strength steels. Although HE of wrought steels has been extensively studied it remains limited in steels processed by additive manufacturing (AM). The present work (i) compares the HE susceptibility of AISI 4340 ultra-high-strength steel fabricated by selective laser melting (SLM) with its wrought counterpart; (ii) investigates the predominant factors and possible HE mechanisms in the AM-fabricated material; and (iii) correlates microstructures produced with different SLM processing parameters to HE susceptibility of the steel. Generally conventionally processed AISI 4340 steel is used with a tempered martensitic structure to ensure the ultrahigh strength and therefore is susceptible to HE. In contrast SLM-fabricated 4340 exhibits a uniform refined bainitic microstructure. How this change of microstructure influences the HE susceptibility of the steel is unknown and needs investigation. Our results demonstrate that at the same level of strength the SLM-fabricated 4340 steel exhibits significantly lower HE susceptibility than its wrought counterpart. The SLM-fabricated steel showed a higher hydrogen diffusion rate. Furthermore the refined microstructure of the SLM-fabricated steel contributes to enhanced ductility even with hydrogen. These findings indicate that AM of high-strength steels has strong potential to improve HE resistance providing a pathway to solve this long-term problem. This study highlights the critical role of microstructure in influencing HE and offers valuable insights for developing steels for hydrogen applications.
Optimal Design of Electrolysis-based Hydrogen Hubs: Impact of Different Hydrogen Demand Profile Assumptions on System Flexibility and Investment Portfolios
Jul 2025
Publication
Green hydrogen (H2) produced from renewable energy sources (RES) through electrolysis offers a promising solution to decarbonize hard-to-abate sectors paving the way for H2 hubs. The agility of electrolyzers especially proton-exchange membrane (PEM) technology can be leveraged to provide flexibility to future integrated electricity and H2 systems. More flexibility can be unlocked by optimizing the designs of H2 hubs which generally consist of electrolyzers H2 storage tanks H2 liquefiers and battery energy storage systems (BESSs). This paper introduces a generic optimization framework for finding the least-cost designs of H2 hubs that also minimizes system operating costs under arbitrary H2 demand profiles. The proposed electrolyzer model incorporates a variable efficiency to avoid overestimating the power consumption and the true size of electrolyzers. In RES-rich countries like Australia envisaged H2 export demand may constitute a significant source of demand flexibility. The proposed framework is therefore demonstrated on a case study involving the Australian National Electricity Market (NEM) under a future large-scale green H2 export scenario assessing the impact of three different H2 export profile assumptions on H2 hub investment costs system operating costs and system flexibility. These profiles include: (a) a realistic one based on historical liquefied natural gas (LNG) ship schedules and a pilot H2 export project (b) an inflexible constant demand across the year and (c) a flexible monthly target without intraday and interday restrictions. Numerical analysis demonstrates that the optimal H2 hub designs obtained under the more realistic H2 export profile assumptions enjoy the lowest system operating costs and the highest flexibility the latter of which is evidenced by a substantial increase in availability of reserves.
Expert Views on the Legitimacy of Renewable Hydrogen Certification Schemes
Feb 2025
Publication
In this article we draw on findings from a mixed-methods international survey of experts in the energy sector (n = 179) to better understand the role of legitimacy theory in informing the development of renewable hydrogen standards certification and labelling (SCL). The investigation is viewed through two conceptions of legitimacy: the sociological legitimacy of increasing the availability of renewable hydrogen technologies and the normative legitimacy of democratic SCL governance. Results revealed that respondents reacted positively to survey state ments representing sociological legitimacy whereas qualitative data exposed some concerns with pragmatic and cognitive legitimacy such as a lack of immediate benefits and poor comprehensibility stemming from sources including economics and energy strategy. Respondents' ratings of the democratic legitimacy of hydrogen SCLs indicated inputs were perceived to have the most legitimacy followed by throughputs then outputs. The analysis revealed some evidence that features of scheme design and governance may influence experts' evaluations of schemes. Moreover results indicated an opportunity to increase awareness and knowledge of SCLs within the expert community and societally. This study provides evidence to support the premise that hydrogen SCLs would benefit from pursuing diversity in stakeholder participation enhancing process transparency and judging the efficacy of outputs against both decarbonisation and sustainability goals. Attention to these democratic factors among others would enhance the capacity of SCLs to contribute to the sociological legitimation of renewable hydrogen technologies.
Techno-economic Analysis of Hydrogen Production in the Sugarcane Industry by Steam Reforming of Ethanol with Carbon Capture
Feb 2025
Publication
Renewable hydrogen production is a pivotal technology in transitioning to sustainable energy and is essential for global decarbonisation efforts. This study explores the integration of hydrogen production into sugarcane bio refineries which have shifted from traditional sugar production to integrated bioenergy hubs. Specifically steam reforming of ethanol was selected as the process for hydrogen generation. A comprehensive techno-economic analysis was developed to address research gaps and guide future work. A scenario of hydrogen production coupled with carbon capture was analysed illustrating the potential to reduce the carbon footprint and utilise carbon dioxide for producing chemicals. The minimum selling price for hydrogen was determined to be 4.6 US $/kg for the base case scenario and 4.9 US$/kg for the comparison scenario with carbon capture positioning it below the current average market price of 7.2 US$/kg. The capital and operating expenditures were determined to be US$ 273.1 million and 157.8 million for a 42400 t/y hydrogen plant and integrating carbon capture considering 282800 t/y of carbon co-product yield was calculated at US$ 344.1 million and US$ 167.8 million respectively. This dual approach of hydrogen production and carbon capture presents a strategy for imple menting low-carbon processes that future biorefineries may consider. The primary impact highlighted by this integration is the enhancement of the sugarcane biorefineries’ value proposition leveraging undervalued energy sources such as electricity and biogas. This study underscores the economic and environmental benefits of incorporating hydrogen production into sugarcane biorefineries on a large scale offering a framework for future research and technological development.
A Review of Influence of Hydrogen on Fracture Toughness and Mechanical Properties of Gas Transmission Pipeline Steels
Jan 2025
Publication
The existing gas transmission pipeline network can be a convenient and cost-effective way to transport hydrogen. However hydrogen can cause hydrogen embrittlement (HE) of the steels used in pipeline construction. HE is typically manifested as a reduction in fracture toughness and ductility. To ensure structural integrity it is thus important to understand the fracture toughness of pipeline steels in hydrogen gas at pipeline pressures. This paper reviews (i) the influence of hydrogen on the fracture toughness of pipeline steels and (ii) the phenomena that occurs during fracture toughness tests of pipeline steel in air and hydrogen. Also reviewed are (i) the in fluence of hydrogen on tensile properties and (ii) the diffusion and solubility of hydrogen in pipeline steels under conditions relevant to hydrogen transport in gas transmission pipelines.
Performance, Emissions, and Economic Analyses of Hydrogen Fuel Cell Vehicles
May 2024
Publication
The transport sector is considered to be a significant contributor to greenhouse gas emissions as this sector emits about one-fourth of global CO2 emissions. Transport emissions contribute toward climate change and have been linked to adverse health impacts. Therefore alternative and sustainable transport options are urgent for decarbonising the transport sector and mitigating those issues. Hydrogen fuel cell vehicles are a potential alternative to conventional vehicles which can play a significant role in decarbonising the future transport sector. This study critically analyses the recent works related to hydrogen fuel cell integration into vehicles modelling and experimental investigations of hydrogen fuel cell vehicles with various powertrains. This study also reviews and analyses the performance energy management strategies lifecycle cost and emissions of fuel cell vehicles. Previous literature suggested that the fuel consumption and well-to-wheel greenhouse gas emissions of hydrogen fuel cell-powered vehicles are significantly lower than that of conventional internal combustion vehicles. Hydrogen fuel cell vehicles consume about 29–66 % less energy and cause approximately 31–80 % less greenhouse gas emissions than conventional vehicles. Despite this the lifecycle cost of hydrogen fuel cell vehicles has been estimated to be 1.2–12.1 times higher than conventional vehicles. Even though there has been recent progress in energy management in hydrogen fuel cell electric vehicles there are a number of technical and economic challenges to the commercialisation of hydrogen fuel cell vehicles. This study presents current knowledge gaps and details future research directions in relation to the research advancement of hydrogen fuel cell vehicles.
Biohydrogen Production from Biomass Sources: Metabolic Pathways and Economic Analysis
Sep 2021
Publication
The commercialization of hydrogen as a fuel faces severe technological economic and environmental challenges. As a method to overcome these challenges microalgal biohydrogen production has become the subject of growing research interest. Microalgal biohydrogen can be produced through different metabolic routes the economic considerations of which are largely missing from recent reviews. Thus this review briefly explains the techniques and economics associated with enhancing microalgae-based biohydrogen production. The cost of producing biohydrogen has been estimated to be between $10 GJ-1 and $20 GJ−1 which is not competitive with gasoline ($0.33 GJ−1 ). Even though direct biophotolysis has a sunlight conversion efficiency of over 80% its productivity is sensitive to oxygen and sunlight availability. While the electrochemical processes produce the highest biohydrogen (>90%) fermentation and photobiological processes are more environmentally sustainable. Studies have revealed that the cost of producing biohydrogen is quite high ranging between $2.13 kg−1 and 7.24 kg−1 via direct biophotolysis $1.42kg−1 through indirect biophotolysis and between $7.54 kg−1 and 7.61 kg−1 via fermentation. Therefore low-cost hydrogen production technologies need to be developed to ensure long-term sustainability which requires the optimization of critical experimental parameters microalgal metabolic engineering and genetic modification.
Hydrogen Addition to a Commercial Self-aspirating Burner and Assessment of a Practical Burner Modification Strategy to Improve Performance
Jul 2023
Publication
The ability for existing burners to operate safely and efficiently on hydrogen-blended fuels is a primary concern for the many industries looking to adopt hydrogen as an alternative fuel. This study investigates the efficacy of increasing fuel injector diameter as a simple modification strategy to extend the hydrogen-blending limits before flashback. The collateral effects of this modification are quantified with respect to a set of key performance criteria. The results show that the unmodified burner can sustain up to 50 vol% hydrogen addition before flashback. Increasing the fuel injector diameter reduces primary aeration allowing for stable operation on up to 100% hydrogen. The flame length visibility and radiant heat transfer properties are all increased as a result of the reduced air entrainment with a trade-off reported for NOx emissions where in addition to the effects of hydrogen reducing air entrainment further increases NOx emissions.
Advancements in Hydrogen Production, Storage, Distribution and Refuelling for a Sustainable Transport Sector: Hydrogen Fuel Cell Vehicles
Jul 2023
Publication
Hydrogen is considered as a promising fuel in the 21st century due to zero tailpipe CO2 emissions from hydrogen-powered vehicles. The use of hydrogen as fuel in vehicles can play an important role in decarbonising the transport sector and achieving net-zero emissions targets. However there exist several issues related to hydrogen production efficient hydrogen storage system and transport and refuelling infrastructure where the current research is focussing on. This study critically reviews and analyses the recent technological advancements of hydrogen production storage and distribution technologies along with their cost and associated greenhouse gas emissions. This paper also comprehensively discusses the hydrogen refuelling methods identifies issues associated with fast refuelling and explores the control strategies. Additionally it explains various standard protocols in relation to safe and efficient refuelling analyses economic aspects and presents the recent technological advancements related to refuelling infrastructure. This study suggests that the production cost of hydrogen significantly varies from one technology to others. The current hydrogen production cost from fossil sources using the most established technologies were estimated at about $0.8–$3.5/kg H2 depending on the country of production. The underground storage technology exhibited the lowest storage cost followed by compressed hydrogen and liquid hydrogen storage. The levelised cost of the refuelling station was reported to be about $1.5–$8/kg H2 depending on the station's capacity and country. Using portable refuelling stations were identified as a promising option in many countries for small fleet size low-to-medium duty vehicles. Following the current research progresses this paper in the end identifies knowledge gaps and thereby presents future research directions.
Ignore Variability, Overestimate Hydrogen Production - Quantifying the Effects of Electrolyzer Efficiency Curves on Hydrogen Producton from Renewable Energy Sources
May 2024
Publication
This study investigates the impact of including (or neglecting) the variable efficiency of hydrogen electrolyzers as a function of operating power in the modelling of green hydrogen produced from variable renewable energy sources. Results show that neglecting the variable electrolyzer efficiency as is commonly done in studies of green hydrogen leads to significant overestimation of hydrogen production in the range of 5–24%. The effects of the time resolution used in models are also investigated as well as the impact of including the option for the electrolyzer to switch to stand-by mode instead of powering down and electrolyzer ramp rate constraints. Results indicate that these have a minor effect on overall hydrogen production with the use of hour resolution data leading to overestimation in the range of 0.2–2% relative to using 5-min data. This study used data from three solar farms and three wind in Australia from which it is observed that wind farms produced 55% more hydrogen than the solar farms. The results in this study highlight the critical importance of including the variable efficiency of electrolyzers in the modelling of green hydrogen production. As this industry scales continuing to neglect this effect would lead to the overestimation of hydrogen production by tens of megatonnes.
Shorter Message, Stronger Framing Increases Societal Acceptance for Hydrogen
Feb 2024
Publication
With the question of ‘can short messages be effective in increasing public support for a complex new technology (hydrogen)?‘ this study uses a representative national survey in Australia to analyze the differences and variations in subjective support for hydrogen in response to four differently framed short messages. The findings of this study show that short messages can increase social acceptance but the effects depend on how strongly the message is framed in terms of its alignment with either an economic or environmental values framework. Furthermore the effects depend on the social and cultural context of the receiver of the message.
Geomechanics of Hydrogen Storage in a Depleted Gas Field
Feb 2024
Publication
We perform a simulation study of hydrogen injection in a depleted gas reservoir to assess the geomechanical impact of hydrogen storage relative to other commonly injected gases (methane CO2). A key finding is that the differences in hydrogen density compressibility viscosity and thermal properties compared to the other gases result in significantly less thermal perturbation at reservoir level. The risks of fault reactivation and wellbore fractures due to thermally-induced stress changes are significantly lower when storing hydrogen compared to results observed in CO2 scenarios. This implies that hydrogen injection and production has a much smaller geomechanical footprint with benefits for operational safety. We also find that use of nitrogen cushion gas ensures efficient deliverability and phase separation in the reservoir. However in this study a large fraction of cushion gas was back-produced in each cycle demonstrating the need for further studies of the surface processing requirements and economic implications.
Stable Electrolytic Hydrogen Production Using Renewable Energy
Oct 2024
Publication
The inherent intermittency of upstream solar and wind power can result in fluctuating electrolytic hydrogen production which is incompatible with the feedstock requirements of many downstream hydrogen storage and utilisation applications. Suitable backup power or storage (hydrogen or energy) strategies are thus needed in overall system design. This work conducts technoeconomic modelling to design electrolytic production systems featuring stable hydrogen output for various locations across Australia based on hourly weather data and determines the levelised cost of hydrogen (LCOH) emissions intensities and annual electrolyser usage factors. A stable truly green hydrogen supply is consistently achieved by imposing annual usage factor requirements on the system which forces the system modules (i.e. solar wind electrolyser and hydrogen storage) to be oversized in order to achieve the desired usage factor. Whilst the resultant system designs are however very location-specific a design that ensures a 100% usage factor costs approximately 22% more on average than a system design which is optimised for cost alone.
The Impact of Water Injection and Hydrogen Fuel on Performance and Emissions in a Hydrogen/Diesel Dual-Fuel Engine
Nov 2024
Publication
As the need for alternative energy sources and reduced emissions grows proven technologies are often sidelined in favour of emerging solutions that lack the infrastructure for mass adoption. This study explores a transitional approach by modifying existing compression ignition engines to run on a hydrogen/diesel mixture for performance improvement utilising water injection to mitigate the drawbacks associated with hydrogen combustion. This approach can yield favourable results with current technology. In this modelling study ten hydrogen energy ratios (0–90%) and nine water injection rates (0–700 mg/cycle) were tested in a turbocharged Cummins ISBe 220 31 six-cylinder diesel engine. An engine experiment was conducted to validate the model. Key performance indicators such as power mechanical efficiency thermal efficiency indicated mean effective pressure (IMEP) and brake-specific fuel consumption (BSFC) were measured. Both water injection and hydrogen injection led to slight improvements in all performance metrics except BSFC due to hydrogen’s lower energy density. In terms of emissions CO and CO2 levels significantly decreased as hydrogen content increased with reductions of 94% and 96% respectively at 90% hydrogen compared to the baseline diesel. Water injection at peak rates further reduced CO emissions by approximately 40% though it had minimal effect on CO2 . As expected NOx (which is a typical challenge with hydrogen combustion and also with diesel engines in general) increased with hydrogen fuelling resulting in an approximately 70% increase in total NOx emissions over the range of 0–90% hydrogen energy. Similar increases were observed in NO and NO2 e.g. 90% and 57% increases with 90% hydrogen respectively. However water injection reduced NO and NO2 levels by up to 16% and 83% respectively resulting in a net decrease in NOX emissions in many combined cases not only with hydrogen injection but also when compared to baseline diesel.
Economics of Renewable Hydrogen Production Using Wind and Solar Energy: A Case Study for Queensland, Australia
Dec 2023
Publication
This study presents a technoeconomic analysis of renewables-based hydrogen production in Queensland Australia under Optimistic Reference and Pessimistic scenarios to address uncertainty in cost predictions. The goal of the work was to ascertain if the target fam-gate cost of AUD 3/kg (approx. USD 2/kg) could be reached. Economies of scale and the learning rate concept were factored into the economic model to account for the effect of scale-up and cost reductions as electrolyser manufacturing capacity grows. The model assumes that small-scale to large-scale wind turbine (WT)-based and photovoltaic (PV)-based power generation plants are directly coupled with an electrolyser array and utilises hourly generation data for the Gladstone hydrogen-hub region. Employing first a commonly used simplified approach the electrolyser array was sized based on the maximum hourly power available for hydrogen production. The initial results indicated that scale-up is very beneficial: the levelised cost of green hydrogen (LCOH) could decrease by 49% from $6.1/kg to $3.1/kg when scaling PV-based plant from 10 MW to 1 GW and for WT-based plant by 36% from $5.8/kg to $3.7/kg. Then impacts on the LCOH of incorporating curtailment of ineffective peak power and electrolyser overload capacity were investigated and shown to be significant. Also significant was the beneficial effect of recognising that electrolyser efficiency depends on input power. The latter two factors have mostly been overlooked in the literature. Incorporating in the model the influence on the LCOH of real-world electrolyser operational characteristics overcomes a shortcoming of the simplified sizing method namely that a large portion of electrolyser capacity is under-utilised leading to unnecessarily high values of the LCOH. It was found that AUD 3/kg is achievable if the electrolyser array is properly sized which should help to incentivise large-scale renewable hydrogen projects in Australia and elsewhere.
Storage Integrity During Underground Hydrogen Storage in Depleted Gas Reservoirs
Nov 2023
Publication
The transition from fossil fuels to renewable energy sources particularly hydrogen has emerged as a central strategy for decarbonization and the pursuit of net-zero carbon emissions. Meeting the demand for large-scale hydrogen storage a crucial component of the hydrogen supply chain has led to the exploration of underground hydrogen storage as an economically viable solution to global energy needs. In contrast to other subsurface storage options such as salt caverns and aquifers which are geographically limited depleted gas reservoirs have garnered increasing attention due to their broader distribution and higher storage capacity. However the safe storage and cycling of hydrogen in depleted gas reservoirs require the preservation of high stability and integrity in the caprock reservoir and wellbore. Nevertheless there exists a significant gap in the current research concerning storage integrity in underground hydrogen storage within depleted gas reservoirs and a systematic approach is lacking. This paper aims to address this gap by reviewing the primary challenges associated with storage integrity including geochemical reactions microbial activities faults and fractures and perspectives on hydrogen cycling. The study comprehensively reviews the processes and impacts such as abiotic and biotic mineral dissolution/precipitation reactivation and propagation of faults and fractures in caprock and host-rock wellbore instability due to cement degradation and casing corrosion and stress changes during hydrogen cycling. To provide a practical solution a technical screening tool has been developed considering controlling variables risks and consequences affecting storage integrity. Finally this paper highlights knowledge gaps and suggests feasible methods and pathways to mitigate these risks facilitating the development of large-scale underground hydrogen storage in depleted gas reservoirs.
Empowering Fuel Cell Electric Vehicles Towards Sustainable Transportation: An Analytical Assessment, Emerging Energy Management, Key Issues, and Future Research Opportunities
Oct 2024
Publication
Fuel cell electric vehicles (FCEVs) have received significant attention in recent times due to various advantageous features such as high energy efficiency zero emissions and extended driving range. However FCEVs have some drawbacks including high production costs; limited hydrogen refueling infrastructure; and the complexity of converters controllers and method execution. To address these challenges smart energy management involving appropriate converters controllers intelligent algorithms and optimizations is essential for enhancing the effectiveness of FCEVs towards sustainable transportation. Therefore this paper presents emerging energy management strategies for FCEVs to improve energy efficiency system reliability and overall performance. In this context a comprehensive analytical assessment is conducted to examine several factors including research trends types of publications citation analysis keyword occurrences collaborations influential authors and the countries conducting research in this area. Moreover emerging energy management schemes are investigated with a focus on intelligent algorithms optimization techniques and control strategies highlighting contributions key findings issues and research gaps. Furthermore the state-of-the-art research domains of FCEVs are thoroughly discussed in order to explore various research domains relevant outcomes and existing challenges. Additionally this paper addresses open issues and challenges and offers valuable future research opportunities for advancing FCEVs emphasizing the importance of suitable algorithms controllers and optimization techniques to enhance their performance. The outcomes and key findings of this review will be helpful for researchers and automotive engineers in developing advanced methods control schemes and optimization strategies for FCEVs towards greener transportation.
Assessment of Wettability and Rock-fluid Interfacial Tension of Caprock: Implications for Hydrogen and Carbon Dioxide Geo-storage
Mar 2022
Publication
Underground hydrogen (H2) storage (UHS) and carbon dioxide (CO2) geo-storage (CGS) are prominent methods of meeting global energy needs and enabling a low-carbon global economy. The pore-scale distribution reservoir-scale storage capacity and containment security of H2 and CO2 are significantly influenced by interfacial properties including the equilibrium contact angle (θE) and solid-liquid and solid-gas interfacial tensions (γSL and γSG). However due to the technical constraints of experimentally determining these parameters they are often calculated based on advancing and receding contact angle values. There is a scarcity of θE γSL and γSG data particularly related to the hydrogen structural sealing potential of caprock which is unavailable in the literature. Young's equation and Neumann's equation of state were combined in this study to theoretically compute these three parameters (θE γSL and γSG) at reservoir conditions for the H2 and CO2 geo-storage potential. Pure mica organic-aged mica and alumina nano-aged mica substrates were investigated to explore the conditions for rock wetting phenomena and the sealing potential of caprock. The results reveal that θE increases while γSG decreases with increasing pressure organic acid concentration and alkyl chain length. However γSG decreases with increasing temperatures for H2 gas and vice versa for CO2. In addition θE and γSL decrease whereas γSG increases with increasing alumina nanofluid concentration from 0.05 to 0.25 wt%. Conversely θE and γSL increase whereas γSG decreases with increasing alumina nanofluid concentration from 0.25 to 0.75 wt%. The hydrogen wettability of mica (a proxy of caprock) was generally less than the CO2 wettability of mica at similar physio-thermal conditions. The interfacial data reported in this study are crucial for predicting caprock wettability alterations and the resulting structural sealing capacity for UHS and CGS.
Numerical Modelling of Hydrogen Release and Dispersion in Under-deck Compressed Hydrogen Storage of Marine Ships
Feb 2024
Publication
There is growing interest in using hydrogen (H2) as a marine fuel. Fire and explosion risks depend on hydrogen release and dispersion characteristics. Based on a validated Computational Fluid Dynamics (CFD) model this study performed hydrogen release and dispersion analysis on an under-deck compressed H2 storage system for a Live-Fish Carrier. A realistic under-deck H2 storage room was modelled based on the ship’s main dimensions and operational profile. Det Norske Veritas (DNV) Rules and Regulations for natural gas storage as a marine fuel were employed as base design guidelines. Case studies were developed to study the effect of two ceiling types (flat and slanted) in terms of flammable cloud formation and dissipation. During the leak’s duration it was found that the recommended ventilation rate was insufficient to dilute the average H2 concentration below 25% of the flammable range as required by DNV (1.2% required against 1.3% slanted and 1.4% flat). However after 35 s of gas extraction the H2 concentration was reduced to 0.5% and 0.6% in the slanted and flat cases respectively. The proposed methodology remains valid to improve the ventilation system and assess mitigation alternatives or other leakage scenarios in confined or semi-confined spaces containing compressed hydrogen gas.
Towards Safer Hydrogen Refuelling Stations: Insights from Computational Fluid Dynamics LH2 Leakage
May 2024
Publication
The transition to a sustainable future with hydrogen as a key energy carrier necessitates a comprehensive understanding of the safety aspects of hydrogen including liquid hydrogen (LH₂). Hence this study presents a detailed computational fluid mechanics analysis to explore accidental LH₂ leakage and dispersion in a hydrogen refuelling station under varied conditions which is essential to prevent fire and explosion. The correlated impact of influential parameters including wind direction wind velocity leak direction and leak rate were analysed. The study shows that hydrogen dispersion is significantly impacted by the combined effect of wind direction and surrounding structures. Additionally the leak rate and leak direction have a significant effect on the development of the flammable cloud volume (FCV) which is critical for estimating the explosion hazards. Increasing wind velocity from 2 to 4 m/s at a constant leak rate of 0.06 kg/s results in an 82% reduction in FCV. The minimum FCV occurs when leak and wind directions oppose at 4 m/s. The most critical situation concerning FCV arises when the leak and wind directions are perpendicular with a leak rate of 0.06 kg/s and a wind velocity of 2 m/s. These findings can aid in the development of optimised sensing and monitoring systems and operational strategies to reduce the risk of catastrophic fire and explosion consequences.
A 500 kW Hydrogen Fuel Cell-powered Vessel: From Concept to Sailing
Sep 2024
Publication
This paper presents the “Three Gorges Hydrogen Boat No. 1” a novel green hydrogen-powered vessel that has been successfully delivered and is currently sailing. This vessel integrated with a hydrogen production and bunkering station at its dedicated dock achieves zero-carbon emissions. It stores 240 kg of 35 MPa gaseous hydrogen and has a fuel cell system rated at 500 kW. We analysed the engineering details of the marine hydrogen system including hydrogen bunkering storage supply fuel cell and the hybrid power system with lithium-ion batteries. In the first bunkering trial the vessel was safely refuelled with 200 kg of gaseous hydrogen in 156 min via a bunkering station 13 m above the water surface. The maximum hydrogen pressure and temperature recorded during bunkering were 35.05 MPa and 39.04 ◦C respectively demonstrating safe and reliable shore-toship bunkering. For the sea trial the marine hydrogen system operated successfully during a 3-h voyage achieving a maximum speed of 28.15 km/h (15.2 knots) at rated propulsion power. The vessel exhibited minimal noise and vibration and its dynamic response met load change requirements. To prevent rapid load changes to the fuel cells 68 s were used to reach 483 kW from startup and 62 s from 480 kW to zero. The successful bunkering and operation of this hydrogen-powered vessel demonstrates the feasibility of zero-carbon emission maritime transport. However four lessons were identified concerning bunkering speed hydrogen cylinder leakage hydrogen pressure regulator malfunctions and fuel cell room space. The novelty of this work lies in the practical demonstration of a fully operational hydrogen-powered maritime vessel achieving zero emissions encompassing its design building operation and lessons learned. These parameters and findings can be used as a baseline for further engineering research.
A Holistic Green System Coupling Hydrogen Production with Wastewater Valorisation
May 2022
Publication
Green hydrogen represents a critical underpinning technology for achievingcarbon neutrality. Although researchers often fixate on its energy inputs atruly ‘green’ hydrogen production process would also be sustainable in termsof water and materials inputs. To address this holistic challenge we demon-strate a new green hydrogen production system which can utilize secondarywastewater as the input (preserving scarce fresh water supplies for drinkingand sanitation). The enabling feature of the proposed system is a self-grownbifunctional CoNi electrode which consists of ultrathin spontaneously depos-ited CoNi nanosheets on a three-dimensional nickel foam. As such a greensynthesis process was developed using an immersion procedure at room-temperature with zero net energy input. Testing revealed that the synthesizedCoNi electrodes can reach a current density of 10 mA cm2 at a small overpo-tential of 197 mV for the hydrogen evolution reaction and 315 mV for the oxy-gen evolution reaction in alkalified wastewater. The values are 16.5%and 6.5% smaller than that from precious catalysts (20 wt% Pt/C and RuO 2 respectively). Importantly this CoNi catalyst offers outstanding durability foroverall wastewater splitting. A prototype solar-energy-powered rooftop waste-water splitting system was constructed and can produce more than 100 Lhydrogen on a sunny day in Sydney Australia. Taken together these resultsindicate that it is promising to unlock holistically green routes for hydrogenproduction by wastewater uplifting with regards to water energy and mate-rials synthesis.
Sustainability Certification for Renewable Hydrogen: An International Survey of Energy Professionals
Jun 2024
Publication
Hydrogen produced from renewable energy is being promoted to decarbonise global energy systems. To support this energy transition standards certification and labelling schemes (SCLs) aim to differentiate hydrogen products based on their system-wide carbon emissions and method of production characteristics. However being certified as low-carbon clean or green hydrogen does not guarantee broader sustainability across economic environmental social or governance dimensions. Through an international survey of energy-sector and sustainability professionals (n = 179) we investigated the desirable sustainability features for renewable hydrogen SCLs and the perceived advantages and disadvantages of sustainability certification. Our mixed-method study revealed general accordance on the feasible inclusion of diverse sustainability criteria in SCLs albeit with varying degrees of perceived essentiality. Within the confines of the data some differences in viewpoints emerged based on respondents’ geographical and supply chain locations which were associated with the sharing of costs and benefits. Qualitatively respondents found the idea of SCL harmonisation attractive but weighed this against the risks of duplication complicated administrative procedures and contradictory regulation. The implications of this research centre on the need for further studies to inform policy recommendations for an overarching SCL sustainability framework that embodies the principles of harmonisation in the context of multistakeholder governance.
Techno-economics of Renewable Hydrogen Export: A Case Study for Australia-Japan
Jul 2024
Publication
The shift from fossil fuels to clean energy carriers such as renewable H2 is imminent. Consequently a global H2 market is taking shape involving countries with limited or insufficient energy resources importing from renewable-rich countries. This study evaluates the techno-economics of renewable hydrogen (H2) export in a globally significant scenario in which Australia exports to Japan. To gain insight into the immediate realisable future the base year was selected as 2030 with a consequently small (in export terms) hydrogen production rate of 100 t/day landed capacity. Electricity was generated by photovoltaic arrays (PV) connected directly to proton exchange membrane (PEM) electrolyser plant allowing for flexible gaseous hydrogen (GH2) production. To enhance the fidelity of the technoeconomic model we incorporated rarely applied but impactful parameters including dynamic efficiency and the overload capacity of PEM electrolysers. The GH2 produced was assumed to be converted into condensed forms suitable for export by sea: liquid hydrogen (LH2) and the chemical carriers liquid ammonia (LNH3) methanol (MeOH) methylcyclohexane (MCH). These were assumed to be reconverted to GH2 at the destination. LNH3 and MCH emerged as promising carriers for export yielding the lowest landed levelised cost of hydrogen (LCOH). LH2 yielded the highest LCOH unless boiloff gas could be managed effectively and cheaply. A sensitivity analysis showed that a lower weighted average cost of capital (WACC) and scale-up can significantly reduce the landed LCOH. Increasing the production rate to 1000 t/day landed capacity very significantly lowered the landed LCOH providing a strong incentive to scale up and optimise the entire supply chain as fast as possible.
Knowledge, Skills, and Attributes Needed for Developing a Hydrogen Engineering Workforce: A Systematic Review of Literature on Hydrogen Engineering Education
May 2024
Publication
Growth in Australia’s demand for engineers is fast outpacing supply. A significant challenge for Australia to achieve high projected low emissions hydrogen export targets by 2030 will be finding engineers with suitable knowledge skills and attributes to deliver hydrogen engineering projects safely and sustainably. This systematic review investigates educational outcomes needed to develop a hydrogen engineering workforce. Sixteen relevant studies published between 2003 and 2023 were identified to explore “What key knowledge skills and attributes support the development of a hydrogen engineering workforce?”. While these studies advocated the need for training and prescribed areas of required knowledge for the low-emissions hydrogen sector there was limited empirical evidence that informed what knowledge skills and attributes are relevant for entry to practice. This finding represents a significant opportunity for researchers to engage with employers and engineering practitioners within emerging low-emissions hydrogen sector capture empirical evidence and inform the design of educational programs.
Renewable Hydrogen Standards, Certifications, and Labels: A State-of-the-art Review from a Sustainability Systems Governance Perspective
Feb 2024
Publication
A range of existing and newly developed hydrogen standards certification and labelling (SCL) schemes aim to promote the role of ‘renewable’ ‘clean’ or ‘green’ hydrogen in decarbonising energy transitions. This paper analyses a sample of these SCLs to assess their role in the scaling up of renewable hydrogen and its derivatives. To analyse these hydrogen SCLs we embellish a novel conceptual framework that brings together Sustainability Systems Thinking and Governance (SSG) literatures. The results reveal noteworthy scheme differences in motivation approach criteria and governance; highlighting the complex interconnected and dynamic reality within which energy systems are embedded. We consider whether the sustainable utilisation of renewable hydrogen is well-served by the proliferation of SCLs and recommend an SSG-informed approach. An SSG approach will better promote collaboration towards an authoritative global multistakeholder compromise on hydrogen certification that balances economic considerations with social and environmental dimensions.
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