Australia
Hydrogen for Australia’s Future
Aug 2018
Publication
The Hydrogen Strategy Group chaired by Australia’s Chief Scientist Dr Alan Finkel has today released a briefing paper on the potential domestic and export opportunities of a hydrogen industry in Australia.
Like natural gas hydrogen can be used to heat buildings and power vehicles. Unlike natural gas or petrol when hydrogen is burned there are no CO2 emissions. The only by-products are water vapour and heat.
Hydrogen is the most abundant element in the universe not freely available as a gas on Earth but bound into many common substances including water and fossil fuels.
Hydrogen was first formally presented as a credible alternative energy source in the early 1970s but never proved competitive at scale as an energy source – until now. We find that the worldwide demand for hydrogen is set to increase substantially over coming decades driven by Japan’s decision to put imported hydrogen at the heart of its economy. Production costs are falling technologies are progressing and the push for non-nuclear low-emissions fuels is building momentum. We conclude that Australia is remarkably well-positioned to benefit from the growth of hydrogen industries and markets.
Like natural gas hydrogen can be used to heat buildings and power vehicles. Unlike natural gas or petrol when hydrogen is burned there are no CO2 emissions. The only by-products are water vapour and heat.
Hydrogen is the most abundant element in the universe not freely available as a gas on Earth but bound into many common substances including water and fossil fuels.
Hydrogen was first formally presented as a credible alternative energy source in the early 1970s but never proved competitive at scale as an energy source – until now. We find that the worldwide demand for hydrogen is set to increase substantially over coming decades driven by Japan’s decision to put imported hydrogen at the heart of its economy. Production costs are falling technologies are progressing and the push for non-nuclear low-emissions fuels is building momentum. We conclude that Australia is remarkably well-positioned to benefit from the growth of hydrogen industries and markets.
Artificial Intelligence/Machine Learning in Energy Management Systems, Control, and Optimization of Hydrogen Fuel Cell Vehicles
Mar 2023
Publication
Environmental emissions global warming and energy-related concerns have accelerated the advancements in conventional vehicles that primarily use internal combustion engines. Among the existing technologies hydrogen fuel cell electric vehicles and fuel cell hybrid electric vehicles may have minimal contributions to greenhouse gas emissions and thus are the prime choices for environmental concerns. However energy management in fuel cell electric vehicles and fuel cell hybrid electric vehicles is a major challenge. Appropriate control strategies should be used for effective energy management in these vehicles. On the other hand there has been significant progress in artificial intelligence machine learning and designing data-driven intelligent controllers. These techniques have found much attention within the community and state-of-the-art energy management technologies have been developed based on them. This manuscript reviews the application of machine learning and intelligent controllers for prediction control energy management and vehicle to everything (V2X) in hydrogen fuel cell vehicles. The effectiveness of data-driven control and optimization systems are investigated to evolve classify and compare and future trends and directions for sustainability are discussed.
Advancements in Hydrogen Production, Storage, Distribution and Refuelling for a Sustainable Transport Sector: Hydrogen Fuel Cell Vehicles
Jul 2023
Publication
Hydrogen is considered as a promising fuel in the 21st century due to zero tailpipe CO2 emissions from hydrogen-powered vehicles. The use of hydrogen as fuel in vehicles can play an important role in decarbonising the transport sector and achieving net-zero emissions targets. However there exist several issues related to hydrogen production efficient hydrogen storage system and transport and refuelling infrastructure where the current research is focussing on. This study critically reviews and analyses the recent technological advancements of hydrogen production storage and distribution technologies along with their cost and associated greenhouse gas emissions. This paper also comprehensively discusses the hydrogen refuelling methods identifies issues associated with fast refuelling and explores the control strategies. Additionally it explains various standard protocols in relation to safe and efficient refuelling analyses economic aspects and presents the recent technological advancements related to refuelling infrastructure. This study suggests that the production cost of hydrogen significantly varies from one technology to others. The current hydrogen production cost from fossil sources using the most established technologies were estimated at about $0.8–$3.5/kg H2 depending on the country of production. The underground storage technology exhibited the lowest storage cost followed by compressed hydrogen and liquid hydrogen storage. The levelised cost of the refuelling station was reported to be about $1.5–$8/kg H2 depending on the station's capacity and country. Using portable refuelling stations were identified as a promising option in many countries for small fleet size low-to-medium duty vehicles. Following the current research progresses this paper in the end identifies knowledge gaps and thereby presents future research directions.
The Hydrogen Economy - Where is the Water?
Jul 2022
Publication
"Green hydrogen” i.e. hydrogen produced by splitting water with a carbon “free” source of electricity via electrolysis is set to become the energy vector enabling a deep decarbonisation of society and a virtuous water based energy cycle. If to date water electrolysis is considered to be a scalable technology the source of water to enable a “green hydrogen” economy at scale is questionable. Countries with the highest renewable energy potential like Australia are also among the driest places on earth. Globally 380000 GL/year of wastewater is available and this is much more than the 34500 GL/year of water required to produce the projected 2.3 Gt of hydrogen of a mature hydrogen economy. Hence the need to assess both technically and economically whether some wastewater treatment effluent are a better source for green hydrogen. Analysis of Sydney Water’s wastewater treatment plants alone shows that these plants have 37.6 ML/day of unused tertiary effluents which if electrolysed would generate 420000 t H2/day or 0.88 Mt H2/year and cover ∼100% of Australia’s estimated production by 2030. Furthermore the production of oxygen as a by-product of the electrolysis process could lead to significant benefits to the water industry not only in reducing the cost of the hydrogen produced for $3/kg (assuming a price of oxygen of $3–4 per kg) but also in improving the environmental footprint of wastewater treatment plants by enabling the onsite re-use of oxygen for the treatment of the wastewater. Compared to desalinated water that requires large investments or stormwater that is unpredictable it is apparent that the water utilities have a critical role to play in managing water assets that are “climate independent” as the next “golden oil” opportunity and in enabling a “responsible” hydrogen industry that sensibly manages its water demands and does not compete with existing water potable water demand.
Life Cycle Greenhouse Gas Emission Assessment for Using Alternative Marine Fuels: A Very Large Crude Carrier (VLCC) Case Study
Dec 2022
Publication
The International Maritime Organization (IMO) has set decarbonisation goals for the shipping industry. As a result shipowners and operators are preparing to use low- or zero-carbon alternative fuels. The greenhouse gas (GHG) emission performances are fundamental for choosing suitable marine fuels. However the current regulations adopt tank-to-wake (TTW) emission assessment methods that could misrepresent the total climate impacts of fuels. To better understand the well-to-wake (WTW) GHG emission performances this work applied the life cycle assessment (LCA) method to a very large crude carrier (VLCC) sailing between the Middle East and China to investigate the emissions. The life cycle GHG emission impacts of using alternative fuels including liquified natural gas (LNG) methanol and ammonia were evaluated and compared with using marine gas oil (MGO). The bunkering site of the VLCC was in Zhoushan port China. The MGO and LNG were imported from overseas while methanol and ammonia were produced in China. Four production pathways for methanol and three production pathways for ammonia were examined. The results showed that compared with MGO using fossil energy-based methanol and ammonia has no positive effect in terms of annual WTW GHG emissions. The emission reduction effects of fuels ranking from highest to lowest were full solar and battery-based methanol full solar and battery-based ammonia and LNG. Because marine ammonia-fuelled engines have not been commercialised laboratory data were used to evaluate the nitrous oxide (N2O) emissions. The GHG emission reduction potential of ammonia can be exploited more effectively if the N2O emitted from engines is captured and disposed of through after-treatment technologies. This paper discussed three scenarios of N2O emission abatement ratios of 30% 50% and 90%. The resulting emission reduction effects showed that using full solar and battery-based ammonia with 90% N2O abatement performs better than using full solar and battery-based methanol. The main innovation of this work is realising the LCA GHG emission assessment for a deep-sea ship.
Sustainable Hydrogen Energy in Aviation - A Narrative Review
Feb 2023
Publication
In the modern world zero-carbon society has become a new buzzword of the era. Many projects have been initiated to develop alternatives not only to the environmental crisis but also to the shortage of fossil fuels. With successful projects in automobile technology hydrogen fuel is now being tested and utilized as a sustainable green fuel in the aviation sector which will lead to zero carbon emission in the future. From the mid-20th century to the early 21st numerous countries and companies have funded multimillion projects to develop hydrogen-fueled aircraft. Empirical data show positive results for various projects. Consequently large companies are investing in various innovations undertaken by researchers under their supervision. Over time the efficiency of hydrogen-fueled aircraft has improved but the lack of refueling stations large production cost and consolidated carbon market share have impeded the path of hydrogen fuel being commercialized. In addition the Unmanned Aerial Vehicle (UAV) is another important element of the Aviation industry Hydrogen started to be commonly used as an alternative fuel for heavy-duty drones using fuel cell technology. The purpose of this paper is to provide an overview of the chronological development of hydrogen-powered aircraft technology and potential aviation applications for hydrogen and fuel cell technology. Furthermore the major barriers to widespread adoption of hydrogen technology in aviation are identified as are future research opportunities.
Biohydrogen Production from Biomass Sources: Metabolic Pathways and Economic Analysis
Sep 2021
Publication
The commercialization of hydrogen as a fuel faces severe technological economic and environmental challenges. As a method to overcome these challenges microalgal biohydrogen production has become the subject of growing research interest. Microalgal biohydrogen can be produced through different metabolic routes the economic considerations of which are largely missing from recent reviews. Thus this review briefly explains the techniques and economics associated with enhancing microalgae-based biohydrogen production. The cost of producing biohydrogen has been estimated to be between $10 GJ-1 and $20 GJ−1 which is not competitive with gasoline ($0.33 GJ−1 ). Even though direct biophotolysis has a sunlight conversion efficiency of over 80% its productivity is sensitive to oxygen and sunlight availability. While the electrochemical processes produce the highest biohydrogen (>90%) fermentation and photobiological processes are more environmentally sustainable. Studies have revealed that the cost of producing biohydrogen is quite high ranging between $2.13 kg−1 and 7.24 kg−1 via direct biophotolysis $1.42kg−1 through indirect biophotolysis and between $7.54 kg−1 and 7.61 kg−1 via fermentation. Therefore low-cost hydrogen production technologies need to be developed to ensure long-term sustainability which requires the optimization of critical experimental parameters microalgal metabolic engineering and genetic modification.
Insights into Decision-making for Offshore Green Hydrogen Infrastructure Developments
Apr 2023
Publication
Green hydrogen is a key element that has the potential to play a critical role in the global pursuit of a resilient and sustainable future. However like other energy production methods hydrogen comes with challenges including high costs and safety concerns across its entire value chain. To overcome these low-cost productions are required along with a promised market. Offshore renewables have an enormous potential to facilitate green hydrogen production on a large scale. Their plummeting cost technological advances and rising cost of carbon pave a pathway where green hydrogen can be cost-competitive against fossil-fuel-based hydrogen. Offshore industries including oil and gas aquaculture and shipping are looking for cleaner energy solutions to decarbonize their systems/operations and can serve as a substantial market. Offshore industrial nexus moreover can assist the production storage and transmission of green hydrogen through infrastructure sharing and logistical support. The development of offshore green hydrogen production facilities is in its infancy and requires a deeper insight into the key elements that govern decision-making during their life-cycle. This includes the parameters that reflect the performance of hydrogen technology with technical socio-political financial and environmental considerations. Therefore this study provides critical insight into the influential factors discovered through a comprehensive analysis that governs the development of an offshore green hydrogen system. Insights are also fed into the requirements for modelling and analysis of these factors considering the synergy of hydrogen production with the offshore industries coastal hydrogen hub and onshore energy demand. The results of this critical review will assist the researchers and developers in establishing and executing an effective framework for offshore site selection in largely uncertain and hazardous ocean environments. Overall the study will facilitate the stakeholders and researchers in developing decision-making tools to ensure sustainable and safe offshore green hydrogen facilities.
Experimental Study for Thermal Methane Cracking Reaction to Generate Very Pur Hydrogen in Small or Medium Scales by Using Regenrative Reactor
Sep 2022
Publication
Non-catalytic thermal methane cracking (TMC) is an alternative for hydrogen manufacturing and traditional commercial processes in small-scale hydrogen generation. Supplying the high-level temperatures (850–1800°C) inside the reactors and reactor blockages are two fundamental challenges for developing this technology on an industrial scale (Mahdi Yousefi and Donne 2021). A regenerative reactor could be a part of a solution to overcome these obstacles. This study conducted an experimental study in a regenerative reactor environment between 850 and 1170°C to collect the conversion data and investigate the reactor efficiency for TMC processes. The results revealed that the storage medium was a bed for carbon deposition and successfully supplied the reaction’s heat with more than 99.7% hydrogen yield (at more than 1150°C). Results also indicated that the reaction rate at the beginning of the reactor is much higher and the temperature dependence in the early stages of the reaction is considerably higher. However after reaching a particular concentration of Hydrogen at each temperature the influence of temperature on the reaction rate decreases and is almost constant. The type of produced carbon in the storage medium and its auto-catalytic effect on the reactions were also investigated. Results showed that carbon black had been mostly formed but in different sizes from 100 to 2000 nm. Increasing the reactor temperature decreased the size of the generated carbon. Pre-produced carbon in the reactor did not affect the production rate and is almost negligible at more than 850°C.
A Review of Hydrogen/rock/brine Interaction: Implications for Hydrogen Geo-storage
Dec 2022
Publication
Hydrogen (H2) is currently considered a clean fuel to decrease anthropogenic greenhouse gas emissions and will play a vital role in climate change mitigation. Nevertheless one of the primary challenges of achieving a complete H2 economy is the large-scale storage of H2 which is unsafe on the surface because H2 is highly compressible volatile and flammable. Hydrogen storage in geological formations could be a potential solution to this problem because of the abundance of such formations and their high storage capacities. Wettability plays a critical role in the displacement of formation water and determines the containment safety storage capacity and amount of trapped H2 (or recovery factor). However no comprehensive review article has been published explaining H2 wettability in geological conditions. Therefore this review focuses on the influence of various parameters such as salinity temperature pressure surface roughness and formation type on wettability and consequently H2 storage. Significant gaps exist in the literature on understanding the effect of organic material on H2 storage capacity. Thus this review summarizes recent advances in rock/H2/brine systems containing organic material in various geological reservoirs. The paper also presents influential parameters affecting H2 storage capacity and containment safety including liquid–gas interfacial tension rock–fluid interfacial tension and adsorption. The paper aims to provide the scientific community with an expert opinion to understand the challenges of H2 storage and identify storage solutions. In addition the essential differences between underground H2 storage (UHS) natural gas storage and carbon dioxide geological storage are discussed and the direction of future research is presented. Therefore this review promotes thorough knowledge of UHS provides guidance on operating large-scale UHS projects encourages climate engineers to focus more on UHS research and provides an overview of advanced technology. This review also inspires researchers in the field of climate change to give more credit to UHS studies.
Explaining Hydrogen Energy Technology Acceptance: A Critical Review
Jan 2022
Publication
The use of hydrogen energy and the associated technologies is expected to increase in the coming years. The success of hydrogen energy technology (HET) is however dependent on public acceptance of the technology. Developing this new industry in a socially responsible way will require an understanding of the psychology factors that may facilitate or impede its public acceptance. This paper reviews 27 quantitative studies that have explored the relationship between psychological factors and HET acceptance. The findings from the review suggest that the perceived effects of the technology (i.e. the perceived benefits costs and risks) and the associated emotions are strong drivers of HET acceptance. This paper does though highlight some limitations with past research that make it difficult to make strong conclusions about the factors that influence HET acceptance. The review also reveals that few studies have investigated acceptance of different types of HET beyond a couple of applications. The paper ends with a discussion about directions for future research and highlights some practical implications for messaging and policy.
Shipping Australian Sunshine: Liquid Renewable Green Fuel Export
Dec 2022
Publication
Renewable green fuels (RGF) such as hydrogen are the global energy future. Air pollution is compounded with climate change as the emissions driving both development problems come largely from the same source of fossil fuel burning. As an energy exporter Australian energy export dominates the total energy production and the RGF has become central to the current proposal of Australian government to reach net zero emission. The hydrogen production from solar panels only on 3% of Australia's land area could compensate 10 times of Germany's non-electricity energy consumption. In the unique geographic position Australia's RGF export attracts significant costs for long distance onboard storage and shipping. While the cost reduction of RGF production relies on technological advancement which needs a long time the storage and shipping costs must be minimised for Australia to remain competitive in the global energy market. The present review concentrates on Australian export pathways of lifecycles of liquid renewable green fuels including renewable liquified hydrogen (LH2) liquified methane (LCH4) ammonia (NH3) and methanol (CH3OH) as liquid RGF have the advantages of adopting the existing infrastructure. This review compares the advantages and disadvantages of discussed renewable energy carriers. It is found that the cost of LH2 pathway can be acceptable for shipping distance of up to 7000 km (Asian countries such as Japan) but ammonia (NH3) or methanol (CH3OH) pathways may be more cost effective for shipping distance above 7000 km for European counties such as Germany. These observations suggest the proper fuel forms to fulfill the requirements to different customers and hence will highlight Australia's position as one of major exporters of renewable energy in the future. Detailed techno-economic analysis is worth to be done for supplying more quantitative results.
Large-scale Stationary Hydrogen Storage via Liquid Organic Hydrogen Carriers
Aug 2021
Publication
Large-scale stationary hydrogen storage is critical if hydrogen is to fulfill its promise as a global energy carrier. While densified storage via compressed gas and liquid hydrogen is currently the dominant approach liquid organic molecules have emerged as a favorable storage medium because of their desirable properties such as low cost and compatibility with existing fuel transport infrastructure. This perspective article analytically investigates hydrogenation systems' technical and economic prospects using liquid organic hydrogen carriers (LOHCs) to store hydrogen at a large scale compared to densified storage technologies and circular hydrogen carriers (mainly ammonia and methanol). Our analysis of major system components indicates that the capital cost for liquid hydrogen storage is more than two times that for the gaseous approach and four times that for the LOHC approach. Ammonia and methanol could be attractive options as hydrogen carriers at a large scale because of their compatibility with existing liquid fuel infrastructure. However their synthesis and decomposition are energy and capital intensive compared to LOHCs. Together with other properties such as safety these factors make LOHCs a possible option for large-scale stationary hydrogen storage. In addition hydrogen transportation via various approaches is briefly discussed. We end our discussions by identifying important directions for future research on LOHCs.
Exploring the Australian Public's Response to Hydrogen
Sep 2021
Publication
Over the past three years there has been a rapid increase in discussions across the different levels of Australia's governments about the role that hydrogen might play in helping the world transition to a low carbon future. While those working in the energy industry are aware of the opportunities and challenges that lay ahead the general public is less engaged. However we know from the introduction of previous technologies that public attitudes towards technologies including whether they view them to be safe can severely impact overall acceptance. Understanding how the public perceives hydrogen both for domestic and export use and the potential benefits it brings to Australia is critical for the industry to progress. In this paper we present the initial findings of a national survey of the Australian public conducted in March 2021 which builds on the results of a previous survey conducted in 2018. The 2021 respondents were drawn from all Australian states and territories (n=3020) and quotas were used to ensure adequate representation of age groups and gender. Overall the respondents have favorable views about using hydrogen for energy in Australia with caveats about production-related environmental impacts and issues such as safety. While there has been a slight increase in support for hydrogen as a possible solution for energy and environmental challenges since the 2018 survey the effect size is very small. This suggests that while hydrogen discussions have increased at a policy level little has been done to improve public understanding of hydrogen in communication strategies will be needed as the Australian hydrogen industry continues to develop and gain more widespread media attention.
Stronger Together: Multi-annual Variability of Hydrogen Production Supported by Wind Power in Sweden
Mar 2021
Publication
Hydrogen produced from renewable electricity will play an important role in deep decarbonisation of industry. However adding large electrolyser capacities to a low-carbon electricity system also increases the need for additional electricity generation from variable renewable energies. This will require hydrogen production to be variable unless other sources provide sufficient flexibility. Existing sources of flexibility in hydro-thermal systems are hydropower and thermal generation which are both associated with sustainability concerns. In this work we use a dispatch model for the case of Sweden to assess the power system operation with large-scale electrolysers assuming that additional wind power generation matches the electricity demand of hydrogen production on average. We evaluate different scenarios for restricting the flexibility of hydropower and thermal generation and include 29 different weather years to test the impact of variable weather regimes. We show that (a) in all scenarios electrolyser utilisation is above 60% on average (b) the inter-annual variability of hydrogen production is substantial if thermal power is not dispatched for electrolysis and (c) this problem is aggravated if hydropower flexibility is also restricted. Therefore either long-term storage of hydrogen or backup hydrogen sources may be necessary to guarantee continuous hydrogen flows. Large-scale dispatch of electrolysis capacity supported by wind power makes the system more stable if electrolysers ramp down in rare hours of extreme events with low renewable generation. The need for additional backup capacities in a fully renewable electricity system will thus be reduced if wind power and electrolyser operation are combined in the system.
An Adaptive Renewable Energy Plant (AREP) - To Power Local Premises and Vehicles with 100% Renewables
Aug 2021
Publication
An adaptive response renewable energy plant (AREP) that provides grid balancing services and XeV station fuelling services (where “X” is any type) using renewable energy located in urban centres is described. The AREP has its own primary renewable energy sources and adapts operation in the short term to changing levels of excess or deficient energy on LV and MV electricity grids. The AREP adaptively responds by (1) storing excess energy in batteries for the short term and in hydrogen tanks after energy conversion by electrolysers for the long term; (2) returning power to the grid from either the AREP’s own primary (electron-based) energy sources or batteries and/or from hydrogen via conversion in fuel cells; (3) providing electricity for fast charging BeVs and PHeVs and hydrogen for FCeVs; and (4) exporting excess stored energy as hydrogen to domestic markets. The AREP also adapts over the long term by predictive planning of charging capacity such that the type and capacity of renewable energy equipment is optimised for future operations. A key advantage of this AREP configuration is a flexible “plug and play” capability with modular extension of energy assets. If the AREP footprint is constrained interaction with neighbouring AREPs as a mini-VPP-AREP network can assist in balancing short-term operating requirements. The benefits of this grid balancing and XeV renewable energy filling station or AREP are environmental social and economic through efficient functionality of appropriately sized components. AREPs provide a net zero emissions electricity solution to an existing network with short and long-term storage options as well as a net zero emissions fuel alternative to the transport sector while leveraging existing infrastructure with minimal upfront CAPEX. AREPs can give the flexibility a grid needs to enable high levels of renewable installations while developing green hydrogen production.
A Review of Technical Advances, Barriers, and Solutions in the Power to Hydrogen Roadmap
Oct 2020
Publication
Power to hydrogen (P2H) provides a promising solution to the geographic mismatch between sources of renewable energy and the market due to its technological maturity flexibility and the availability of technical and economic data from a range of active demonstration projects. In this review we aim to provide an overview of the status of P2H analyze its technical barriers and solutions and propose potential opportunities for future research and industrial demonstrations. We specifically focus on the transport of hydrogen via natural gas pipeline networks and end-user purification. Strong evidence shows that an addition of about 10% hydrogen into natural gas pipelines has negligible effects on the pipelines and utilization appliances and may therefore extend the asset value of the pipelines after natural gas is depleted. To obtain pure hydrogen from hydrogen-enriched natural gas (HENG) mixtures end-user separation is inevitable and can be achieved through membranes adsorption and other promising separation technologies. However novel materials with high selectivity and capacity will be the key to the development of industrial processes and an integrated membrane-adsorption process may be considered in order to produce high-purity hydrogen from HENG. It is also worth investigating the feasibility of electrochemical separation (hydrogen pumping) at a large scale and its energy analysis. Cryogenics may only be feasible when liquefied natural gas (LNG) is one of the major products. A range of other technological and operational barriers and opportunities such as water availability byproduct (oxygen) utilization and environmental impacts are also discussed. This review will advance readers’ understanding of P2H and foster the development of the hydrogen economy.
Cross-regional Electricity and Hydrogen Deployment Research Based on Coordinated Optimization: Towards Carbon Neutrality in China
Sep 2022
Publication
In order to achieve carbon neutrality in a few decades the clean energy proportion in power mix of China will significantly rise to over 90%. A consensus has been reached recently that it will be of great significance to promote hydrogen energy that is produced by variable renewable energy power generation as a mainstay energy form in view of its potential value on achieving carbon neutrality. This is because hydrogen energy is capable of complementing the power system and realizing further electrification especially in the section that cannot be easily replaced by electric energy. Power system related planning model is commonly used for mid-term and long-term planning implemented through power installation and interconnection capacity expansion optimization. In consideration of the high importance of hydrogen and its close relationship with electricity an inclusive perspective which contains both kinds of the foresaid energy is required to deal with planning problems. In this study a joint model is established by coupling hydrogen energy model in the chronological operation power planning model to realize coordinated optimization on energy production transportation and storage. By taking the carbon neutrality scenario of China as an example the author applies this joint model to deploy a scheme research on power generation and hydrogen production inter-regional energy transportation capacity and hydrogen storage among various regions. Next by taking the technology progress and cost decrease prediction uncertainty into account the main technical– economic parameters are employed as variables to carry out sensitivity analysis research with a hope that the quantitative calculation and results discussion could provide suggestion and reference to energy-related companies policy-makers and institute researchers in formulating strategies on related energy development.
Sustainable Aviation—Hydrogen Is the Future
Jan 2022
Publication
As the global search for new methods to combat global warming and climate change continues renewable fuels and hydrogen have emerged as saviours for environmentally polluting industries such as aviation. Sustainable aviation is the goal of the aviation industry today. There is increasing interest in achieving carbon-neutral flight to combat global warming. Hydrogen has proven to be a suitable alternative fuel. It is abundant clean and produces no carbon emissions but only water after use which has the potential to cool the environment. This paper traces the historical growth and future of the aviation and aerospace industry. It examines how hydrogen can be used in the air and on the ground to lower the aviation industry’s impact on the environment. In addition while aircraft are an essential part of the aviation industry other support services add to the overall impact on the environment. Hydrogen can be used to fuel the energy needs of these services. However for hydrogen technology to be accepted and implemented other issues such as government policy education and employability must be addressed. Improvement in the performance and emissions of hydrogen as an alternative energy and fuel has grown in the last decade. However other issues such as the storage and cost and the entire value chain require significant work for hydrogen to be implemented. The international community’s alternative renewable energy and hydrogen roadmaps can provide a long-term blueprint for developing the alternative energy industry. This will inform the private and public sectors so that the industry can adjust its plan accordingly.
A Comprehensive Review on the Recent Development of Ammonia as a Renewable Energy Carrier
Jun 2021
Publication
Global energy sources are being transformed from hydrocarbon-based energy sources to renewable and carbon-free energy sources such as wind solar and hydrogen. The biggest challenge with hydrogen as a renewable energy carrier is the storage and delivery system’s complexity. Therefore other media such as ammonia for indirect storage are now being considered. Research has shown that at reasonable pressures ammonia is easily contained as a liquid. In this form energy density is approximately half of that of gasoline and ten times more than batteries. Ammonia can provide effective storage of renewable energy through its existing storage and distribution network. In this article we aimed to analyse the previous studies and the current research on the preparation of ammonia as a next-generation renewable energy carrier. The study focuses on technical advances emerging in ammonia synthesis technologies such as photocatalysis electrocatalysis and plasmacatalysis. Ammonia is now also strongly regarded as fuel in the transport industrial and power sectors and is relatively more versatile in reducing CO2 emissions. Therefore the utilisation of ammonia as a renewable energy carrier plays a significant role in reducing GHG emissions. Finally the simplicity of ammonia processing transport and use makes it an appealing choice for the link between the development of renewable energy and demand.
Delivering an Energy Export Transition: Impact of Conflicting and Competing Informational Contexts on Public Acceptance of Australia's Hydrogen Export Industry
Mar 2024
Publication
This study uses an online quasi-experiment with a national sample from Australia to evaluate public acceptance of hydrogen exports. It explores the complex communications environment that messaging about hydrogen exports is typically encountered in. We find that acceptance of green hydrogen exports is significantly higher than blue or brown hydrogen exports and acceptance of blue hydrogen exports higher than brown hydrogen exports. Additionally results show economic-framed benefit messages are associated with lesser public acceptance when encountered in communication contexts that outline differently-focused environmental downsides (competing contexts) but not same-focused economic downsides (conflicting contexts). In contrast environment-framed benefit messages are associated with lesser public acceptance when presented in communication contexts that outline same-focused environmental downsides (conflicting contexts) but not differentlyfocused economic downsides (competing contexts). Overall the study indicates message framing can impact acceptance of hydrogen exports and that organisations should consider the informational context within which their communications will be received.
Process Reconfiguration and Intensification: An Emerging Opportunity Enabling Efficient Carbon Capture and Low-cost Blue Hydrogen Production
Mar 2023
Publication
Low-carbon hydrogen can play a significant role in decarbonizing the world. Hydrogen is currently mainly produced from fossil sources requiring additional CO2 capture to decarbonize which energy intense and costly. In a recent Green Energy & Environment paper Cheng and Di et al. proposed a novel integration process referred to as SECLRHC to generate high-purity H2 by in-situ separation of H2 and CO without using any additional separation unit. Theoretically the proposed process can essentially achieve the separation of C and H in gaseous fuel via a reconfigured reaction process and thus attaining high-purity hydrogen of ∼99% as well as good carbon and hydrogen utilization rates and economic feasibility. It displays an optimistic prospect that industrial decarbonization is not necessarily expensive as long as a suitable CCS measure can be integrated into the industrial manufacturing process.
Techno-economic Analysis of Hydrogen Electrolysis from Off-Grid Stand-Alone Photovoltaics Incorporating Uncertainty Analysis
Oct 2020
Publication
Solar-driven electrolysis of water to generate hydrogen is emerging as a viable strategy to decarbonize the global energy economy. However this direction is more expensive than traditional fossil fuel generation of hydrogen and effective pathways to lower this cost need to be identified. Here we report a Monte Carlo approach to explore a wide range of input assumptions to identify key cost drivers targets and localized conditions necessary for competitive stand-alone dedicated PV powered hydrogen electrolysis. We determine the levelized cost of hydrogen (LCOH) considering historical weather data for specific locations to model our PV system and optimize its size compared to the electrolyzer. This analysis and its methods show the potential for green hydrogen production using off-grid PV shows the merits of remote systems in areas of high solar resource and provides cost and performance targets for electrolyzer technologies.
How Green Are the National Hydrogen Strategies?
Feb 2022
Publication
Since Japan promulgated the world’s first national hydrogen strategy in 2017 28 national (or regional in the case of the EU) hydrogen strategies have been issued by major world economies. As carbon emissions vary with different types of hydrogen and only green hydrogen produced from renewable energy can be zero-emissions fuel this paper interrogates the commitment of the national hydrogen strategies to achieve decarbonization objectives focusing on the question “how green are the national hydrogen strategies?” We create a typology of regulatory stringency for green hydrogen in national hydrogen strategies analyzing the text of these strategies and their supporting policies and evaluating their regulatory stringency toward decarbonization. Our typology includes four parameters fossil fuel penalties hydrogen certifications innovation enablement and the temporal dimension of coal phasing out. Following the typology we categorize the national hydrogen strategies into three groups: zero regulatory stringency scale first and clean later and green hydrogen now. We find that most national strategies are of the type “scale first and clean later” with one or more regulatory measures in place. This article identifies further challenges to enhancing regulatory stringency for green hydrogen at both national and international levels.
Toward Design of Synergistically Active Carbon-Based Catalysts for Electrocatalytic Hydrogen Evolution
Apr 2014
Publication
Replacement of precious catalyst with cost-effective alternatives would be significantly beneficial for hydrogen production via electrocatalytic hydrogen evolution reaction (HER). All candidates thus far are exclusively metallic catalysts which suffer inherent corrosion and oxidation susceptibility during acidic proton-exchange membrane electrolysis. Herein based on theoretical predictions we designed and synthesized nitrogen (N) and phosphorus (P) dual-doped graphene as a non-metallic electrocatalyst for sustainable and efficient hydrogen production. The N and Phetero-atoms could coactivate the adjacent C atom in the graphene matrix by affecting its valence orbital energy levels to induce a synergistically enhanced reactivity toward HER. As a result the dual-doped graphene showed higher electrocatalytic HER activity than single-doped ones and comparable performance to some of the traditional metallic catalysts.
Techno-Economic Analysis of the Hybrid Solar PV/H/Fuel Cell Based Supply Scheme for Green Mobile Communication
Nov 2021
Publication
Hydrogen has received tremendous global attention as an energy carrier and an energy storage system. Hydrogen carrier introduces a power to hydrogen (P2H) and power to hydrogen to power (P2H2P) facility to store the excess energy in renewable energy storage systems with the facts of large-scale storage capacity transportability and multiple utilities. This work examines the techno-economic feasibility of hybrid solar photovoltaic (PV)/hydrogen/fuel cell-powered cellular base stations for developing green mobile communication to decrease environmental degradation and mitigate fossil-fuel crises. Extensive simulation is carried out using a hybrid optimization model for electric renewables (HOMER) optimization tool to evaluate the optimal size energy production total production cost per unit energy production cost and emission of carbon footprints subject to different relevant system parameters. In addition the throughput and energy efficiency performance of the wireless network is critically evaluated with the help of MATLAB-based Monte-Carlo simulations taking multipath fading system bandwidth transmission power and inter-cell interference (ICI) into consideration. Results show that a more stable and reliable green solution for the telecommunications sector will be the macro cellular basis stations driven by the recommended hybrid supply system. The hybrid supply system has around 17% surplus electricity and 48.1 h backup capacity that increases the system reliability by maintaining a better quality of service (QoS). To end the outcomes of the suggested system are compared with the other supply scheme and the previously published research work for justifying the validity of the proposed system.
A Review of Hydrogen as a Fuel in Internal Combustion Engines
Sep 2021
Publication
The demand for fossil fuels is increasing because of globalization and rising energy demands. As a result many nations are exploring alternative energy sources and hydrogen is an efficient and practical alternative fuel. In the transportation industry the development of hydrogen-powered cars aims to maximize fuel efficiency and significantly reduce exhaust gas emission and concentration. The impact of using hydrogen as a supplementary fuel for spark ignition (SI) and compression ignition (CI) engines on engine performance and gas emissions was investigated in this study. By adding hydrogen as a fuel in internal combustion engines the torque power and brake thermal efficiency of the engines decrease while their brake-specific fuel consumption increase. This study suggests that using hydrogen will reduce the emissions of CO UHC CO2 and soot; however NOx emission is expected to increase. Due to the reduction of environmental pollutants for most engines and the related environmental benefits hydrogen fuel is a clean and sustainable energy source and its use should be expanded.
Gasification of Solid Fuels (Coal, Biomass and MSW): Overview, Challenges and Mitigation Strategies
Jun 2022
Publication
Currently hydrogen energy is the most promising energy vector while gasification is one of the major routes for its production. However gasification suffers from various issues including slower carbon conversion poor syngas quality lower heating value and higher emissions. Multiple factors affect gasification performance such as the selection of gasifiers feedstock’s physicochemical properties and operating conditions. In this review the status of gasification key gasifier technologies and the effect of solid-fuel (i.e. coal biomass and MSW) properties on gasification performance are reviewed critically. Based on the current review the co-gasification of coal biomass and solid waste along with a partial utilisation of CO2 as a reactant are suggested. Furthermore a technological breakthrough in carbon capture and sequestration is needed to make it industrially viable
Computational Intelligence Approach for Modeling Hydrogen Production: A Review
Mar 2018
Publication
Hydrogen is a clean energy source with a relatively low pollution footprint. However hydrogen does not exist in nature as a separate element but only in compound forms. Hydrogen is produced through a process that dissociates it from its compounds. Several methods are used for hydrogen production which first of all differ in the energy used in this process. Investigating the viability and exact applicability of a method in a specific context requires accurate knowledge of the parameters involved in the method and the interaction between these parameters. This can be done using top-down models relying on complex mathematically driven equations. However with the raise of computational intelligence (CI) and machine learning techniques researchers in hydrology have increasingly been using these methods for this complex task and report promising results. The contribution of this study is to investigate the state of the art CI methods employed in hydrogen production and to identify the CI method(s) that perform better in the prediction assessment and optimization tasks related to different types of Hydrogen production methods. The resulting analysis provides in-depth insight into the different hydrogen production methods modeling technique and the obtained results from various scenarios integrating them within the framework of a common discussion and evaluation paper. The identified methods were benchmarked by a qualitative analysis of the accuracy of CI in modeling hydrogen production providing extensive overview of its usage to empower renewable energy utilization.
Optimal Supply Chains and Power Sector Benefits of Green Hydrogen
Jul 2021
Publication
Green hydrogen can help to decarbonize parts of the transportation sector but its power sector interactions are not well understood so far. It may contribute to integrating variable renewable energy sources if production is sufficiently flexible in time. Using an open-source co-optimization model of the power sector and four options for supplying hydrogen at German filling stations we find a trade-of between energy efficiency and temporal flexibility. For lower shares of renewables and hydrogen more energy-efficient and less flexible small-scale on-site electrolysis is optimal. For higher shares of renewables and/or hydrogen more flexible but less energy-efficient large-scale hydrogen supply chains gain importance as they allow to temporally disentangle hydrogen production from demand via storage. Liquid hydrogen emerges as particularly beneficial followed by liquid organic hydrogen carriers and gaseous hydrogen. Large-scale hydrogen supply chains can deliver substantial power sector benefits mainly through reduced renewable curtailment. Energy modelers and system planners should consider the distinct flexibility characteristics of hydrogen supply chains in more detail when assessing the role of green hydrogen in future energy transition scenarios. We also propose two alternative cost and emission metrics which could be useful in future analyses.
Proton Exchange Membrane Hydrogen Fuel Cell as the Grid Connected Power Generator
Dec 2020
Publication
In this paper a proton exchange membrane fuel cell (PEMFC) is implemented as a grid-connected electrical generator that uses hydrogen gas as fuel and air as an oxidant to produce electricity through electrochemical reactions. Analysis demonstrated that the performance of the PEMFC greatly depends on the rate of fuel supply and air supply pressure. Critical fuel and air supply pressures of the PEMFC are analysed to test its feasibility for the grid connection. Air and fuel supply pressures are varied to observe the effects on the PEMFC characteristics efficiency fuel supply and air consumption over time. The PEMFC model is then implemented into an electrical power system with the aid of power electronics applications. Detailed mathematical modelling of the PEMFC is discussed with justification. The PEMFC functions as an electrical generator that is connected to the local grid through a power converter and a transformer. Modulation of the converter is controlled by means of a proportional-integral controller. The two-axis control methodology is applied to the current control of the system. The output voltage waveform and control actions of the controller on the current and frequency of the proposed system are plotted as well. Simulation results show that the PEMFC performs efficiently under certain air and fuel pressures and it can effectively supply electrical power to the grid.
Safe Design of a Hydrogen-Powered Ship: CFD Simulation on Hydrogen Leakage in the Fuel Cell Room
Mar 2023
Publication
Adopting proton exchange membrane fuel cells fuelled by hydrogen presents a promising solution for the shipping industry’s deep decarbonisation. However the potential safety risks associated with hydrogen leakage pose a significant challenge to the development of hydrogen-powered ships. This study examines the safe design principles and leakage risks of the hydrogen gas supply system of China’s first newbuilt hydrogen-powered ship. This study utilises the computational fluid dynamics tool FLACS to analyse the hydrogen dispersion behaviour and concentration distributions in the hydrogen fuel cell room based on the ship’s parameters. This study predicts the flammable gas cloud and time points when gas monitoring points first reach the hydrogen volume concentrations of 0.8% and 1.6% in various leakage scenarios including four different diameters (1 3 5 and 10 mm) and five different directions. This study’s findings indicate that smaller hydrogen pipeline diameters contribute to increased hydrogen safety. Specifically in the hydrogen fuel cell room a single-point leakage in a hydrogen pipeline with an inner diameter not exceeding 3 mm eliminates the possibility of flammable gas cloud explosions. Following a 10 mm leakage diameter the hydrogen concentration in nearly all room positions reaches 4.0% within 6 s of leakage. While the leakage diameter does not impact the location of the monitoring point that first activates the hydrogen leak alarm and triggers an emergency hydrogen supply shutdown the presence of obstructions near hydrogen detectors and the leakage direction can affect it. These insights provide guidance on the optimal locations for hydrogen detectors in the fuel cell room and the pipeline diameters on hydrogen gas supply systems which can facilitate the safe design of hydrogen-powered ships.
Selected Aspects of Hydrogen Production via Catalytic Decomposition of Hydrocarbons
Feb 2021
Publication
Owing to the high hydrogen content hydrocarbons are considered as an alternative source for hydrogen energy purposes. Complete decomposition of hydrocarbons results in the formation of gaseous hydrogen and solid carbonaceous by-product. The process is complicated by the methane formation reaction when the released hydrogen interacts with the formed carbon deposits. The present study is focused on the effects of the reaction mixture composition. Variations in the inlet hydrogen and methane concentrations were found to influence the carbon product’s morphology and the hydrogen production efficiency. The catalyst containing NiO (82 wt%) CuO (13 wt%) and Al2O3 (5 wt%) was prepared via a mechanochemical activating procedure. Kinetics of the catalytic process of hydrocarbons decomposition was studied using a reactor equipped with McBain balances. The effects of the process parameters were explored in a tubular quartz reactor with chromatographic analysis of the outlet gaseous products. In the latter case the catalyst was loaded piecemeal. The texture and morphology of the produced carbon deposits were investigated by nitrogen adsorption and electron microscopy techniques.
Labour Implications of the Net-zero Transition and Clean Energy Exports in Australia
Mar 2024
Publication
We examine the employment implications of a domestic net-zero transition and establishment of clean energy export systems for an historically significant energy exporting country through a case study of Australia. The labour impacts of a multi-decadal transition are simulated across both the domestic and export energy systems considering a wide range of energy technologies resources and activities with assessment according to occupation lifecycle stage education and skill requirements. Across all net-zero scenario pathways by mid-century the total gross employment created for the domestic and export sectors comprises 210–490 thousand jobs and 350–510 thousand jobs respectively. This represents a significant expansion of energy sector employment from the current total of 120 thousand across domestic and export sectors an increase from less than 1 % of the total Australian workforce in 2020 to 3–4 % by 2060. The need to build out energy system infrastructure at large-scale over a number of decades results in construction jobs continuing over that timeframe and a subsequent need for a large ongoing operations and maintenance workforce for new energy system assets. Those employed in domestic energy markets work primarily in utility solar PV onshore wind batteries and electricity transmission and distribution activities while export market jobs are dominated by clean hydrogen production and shipping supply chains. Crucially these export jobs are unevenly distributed across the country in regions of highest quality solar resource. All states and territories experience net job growth across each decade to 2060. However in a few sub-state regions net job losses occur in the short-term.
Achieving Net Zero Electricity Sectors in G7 Members
Oct 2021
Publication
Achieving Net Zero Electricity Sectors in G7 Members is a new report by the International Energy Agency that provides a roadmap to driving down CO2 emissions from electricity generation to net zero by 2035 building on analysis in Net Zero by 2050: A Roadmap for the Global Energy Sector.
The new report was requested by the United Kingdom under its G7 Presidency and followed the G7 leaders’ commitment in June 2021 to reach “an overwhelmingly decarbonised” power system in the 2030s and net zero emissions across their economies no later than 2050. It is designed to inform policy makers industry investors and citizens in advance of the COP26 Climate Change Conference in Glasgow that begins at the end of October 2021.
Starting from recent progress and the current state of play of electricity in the G7 the report analyses the steps needed to achieve net zero emissions from electricity and considers the wider implications for energy security employment and affordability. It identifies key milestones emerging challenges and opportunities for innovation.
The report also underscores how G7 members can foster innovation through international collaboration and as first movers lower the cost of technologies for other countries while maintaining electricity security and placing people at the centre of clean energy transitions.
Link to their website
The new report was requested by the United Kingdom under its G7 Presidency and followed the G7 leaders’ commitment in June 2021 to reach “an overwhelmingly decarbonised” power system in the 2030s and net zero emissions across their economies no later than 2050. It is designed to inform policy makers industry investors and citizens in advance of the COP26 Climate Change Conference in Glasgow that begins at the end of October 2021.
Starting from recent progress and the current state of play of electricity in the G7 the report analyses the steps needed to achieve net zero emissions from electricity and considers the wider implications for energy security employment and affordability. It identifies key milestones emerging challenges and opportunities for innovation.
The report also underscores how G7 members can foster innovation through international collaboration and as first movers lower the cost of technologies for other countries while maintaining electricity security and placing people at the centre of clean energy transitions.
Link to their website
Recent Progress in Ammonia Fuel Cells and their Potential Applications
Nov 2020
Publication
Conventional technologies are largely powered by fossil fuel exploitation and have ultimately led to extensive environmental concerns. Hydrogen is an excellent carbon-free energy carrier but its storage and long-distance transportation remain big challenges. Ammonia however is a promising indirect hydrogen storage medium that has well-established storage and transportation links to make it an accessible fuel source. Moreover the notion of ‘green ammonia’ synthesised from renewable energy sources is an emerging topic that may open significant markets and provide a pathway to decarbonise a variety of applications reliant on fossil fuels. Herein a comparative study based on the chosen design working principles advantages and disadvantages of direct ammonia fuel cells is summarised. This work aims to review the most recent advances in ammonia fuel cells and demonstrates how close this technology type is to integration with future applications. At present several challenges such as material selection NOx formation CO2 tolerance limited power densities and long-term stability must still be overcome and are also addressed within the contents of this review
Emerging Electrochemical Energy Conversion and Storage Technologies
Sep 2014
Publication
Electrochemical cells and systems play a key role in a wide range of industry sectors. These devices are critical enabling technologies for renewable energy; energy management conservation and storage; pollution control/monitoring; and greenhouse gas reduction. A large number of electrochemical energy technologies have been developed in the past. These systems continue to be optimized in terms of cost life time and performance leading to their continued expansion into existing and emerging market sectors. The more established technologies such as deep-cycle batteries and sensors are being joined by emerging technologies such as fuel cells large format lithium-ion batteries electrochemical reactors; ion transport membranes and supercapacitors. This growing demand (multi-billion dollars) for electrochemical energy systems along with the increasing maturity of a number of technologies is having a significant effect on the global research and development effort which is increasing in both in size and depth. A number of new technologies which will have substantial impact on the environment and the way we produce and utilize energy are under development. This paper presents an overview of several emerging electrochemical energy technologies along with a discussion some of the key technical challenges.
Safety Assessment of Hydrogen Jet Fire Scenarios within Semi-Confined Spaces
Jan 2023
Publication
Hydrogen fuel cell vehicle (HFCV) technology poses great promise as an alternative to significantly reduce the environmental impact of the transport sector’s emissions. However hydrogen fuel cell technology is relatively new therefore confirmation of the reliability and safety analysis is still required particularly for fire scenarios within confined spaces such as tunnels. This study applied the computational fluid dynamics (CFD) simulations in conjunction with probabilistic calculation methods to determine the associated thermal risk of a hydrogen jet fire in a tunnel and its dependency on scenarios with different tunnel slopes longitudinal and transverse ventilation velocities and fire positions. A large-scale model of 102 m in which the effects of outlined parameter variations on the severity of the fire incident were analysed. It is found that both tunnel ventilation techniques and slope were critical for the effective ejection of accumulated heat. With ventilation playing a primary role in the ejection of heat and gas and slope ensuring the stability of the ejected heat probabilities of thermal burns were found to be reduced by up to approximately 35% with a strong suggestion of critical combinations to further reduce the dangers of hydrogen tunnel fires.
Numerical Modeling for Rapid Charging of Hydrogen Gas Vessel in Fuel Cell Vehicle
Feb 2023
Publication
As a fuel for power generation high-pressure hydrogen gas is widely used for transportation and its efficient storage promotes the development of fuel cell vehicles (FCVs). However as the filling process takes such a short time the maximum temperature in the storage tank usually undergoes a rapid increase which has become a thorny problem and poses great technical challenges to the steady operation of hydrogen FCVs. For security reasons SAE J2601/ISO 15869 regulates a maximum temperature limit of 85 ◦C in the specifications for refillable hydrogen tanks. In this paper a two-dimensional axisymmetric and a three-dimensional numerical model for fast charging of Type III 35 MPa and 70 MPa hydrogen vehicle cylinders are proposed in order to effectively evaluate the temperature rise within vehicle tanks. A modified standard k-ε turbulence model is utilized to simulate hydrogen gas charging. The equation of state for hydrogen gas is adopted with the thermodynamic properties taken from the National Institute of Standards and Technology (NIST) database taking into account the impact of hydrogen gas’ compressibility. To validate the numerical model three groups of hydrogen rapid refueling experimental data are chosen. After a detailed comparison it is found that the simulated results calculated by the developed numerical model are in good agreement with the experimental results with average temperature differences at the end time of 2.56 K 4.08 K and 4.3 K. The present study provides a foundation for in-depth investigations on the structural mechanics analysis of hydrogen gas vessels during fast refueling and may supply some technical guidance on the design of charging experiments.
Hydrogen as a Long-Term Large-Scale Energy Storage Solution to Support Renewables
Oct 2018
Publication
This paper presents a case study of using hydrogen for large-scale long-term storage application to support the current electricity generation mix of South Australia state in Australia which primarily includes gas wind and solar. For this purpose two cases of battery energy storage and hybrid battery-hydrogen storage systems to support solar and wind energy inputs were compared from a techno-economical point of view. Hybrid battery-hydrogen storage system was found to be more cost competitive with unit cost of electricity at $0.626/kWh (US dollar) compared to battery-only energy storage systems with a $2.68/kWh unit cost of electricity. This research also found that the excess stored hydrogen can be further utilised to generate extra electricity. Further utilisation of generated electricity can be incorporated to meet the load demand by either decreasing the base load supply from gas in the present scenario or exporting it to neighbouring states to enhance economic viability of the system. The use of excess stored hydrogen to generate extra electricity further reduced the cost to $0.494/kWh.
Sensing Hydrogen Seeps in the Subsurface for Natural Hydrogen Exploration
Jun 2022
Publication
The recent detection of natural hydrogen seeps in sedimentary basin settings has triggered significant interest in the exploration of this promising resource. If large economical resources exist and can be extracted from the sub-surface this would provide an opportunity for natural hydrogen to contribute to the non-carbon-based energy mix. The detection and exploration of hydrogen gas in the sub-surface is a significant challenge that requires costly drilling sophisticated instrumentation and reliable analytical/sampling methods. Here we propose the application of a commercial-based sensor that can be used to detect and monitor low levels of hydrogen gas emissions from geological environments. The sensitivity selectivity (K > 1000) and stability (<1 ppm/day) of the sensor was evaluated under various conditions to determine its suitability for geological field monitoring. Calibration tests showed that the hydrogen readings from the sensor were within ±20% of the expected values. We propose that chemical sensing is a simple and feasible method for understanding natural hydrogen seeps that emanate from geological systems and formations. However we recommend using this sensor as part of a complete geological survey that incorporates an understanding of the geology along with complementary techniques that provide information on the rock properties.
Optimising Renewable Generation Configurations of Off-grid Green Ammonia Production System Considering Haber-Bosch Flexibility
Feb 2023
Publication
Green ammonia has received increasing interest for its potential as an energy carrier in the international trade of renewable power. This paper considers the factors that contribute to producing cost-competitive green ammonia from an exporter’s perspective. These factors include renewable resource quality across potential sites operating modes for off-grid plants and seasonal complementarity with trade buyers. The study applies a mixed-integer programming model and uses Australia as a case study because of its excellent solar and wind resources and the potential for synergy between Southern Hemisphere supply and Northern Hemisphere demand. Although renewable resources are unevenly distributed across Australia and present distinct diurnal and seasonal variability modelling shows that most of the pre-identified hydrogen hubs in each state and territory of Australia can produce cost-competitive green ammonia providing the electrolysis and Haber-Bosch processes are partially flexible to cope with the variability of renewables. Flexible operation reduces energy curtailment and leads to lower storage capacity requirements using batteries or hydrogen storage which would otherwise increase system costs. In addition an optimised combination of wind and solar can reduce the magnitude of storage required. Providing that a partially flexible Haber Bosch plant is commercially available the modelling shows a levelised cost of ammonia (LCOA) of AU$756/tonne and AU$659/tonne in 2025 and 2030 respectively. Based on these results green ammonia would be cost-competitive with grey ammonia in 2030 given a feedstock natural gas price higher than AU$14/MBtu. For green ammonia to be cost-competitive with grey ammonia assuming a lower gas price of AU$6/MBtu a carbon price would need to be in place of at least AU$123/tonne. Given that there is a greater demand for energy in winter concurrent with lower solar power production there may be opportunities for solar-based Southern Hemisphere suppliers to supply the major industrial regions most of which are located in the Northern Hemisphere.
Biohydrogen—A Green Fuel for Sustainable Energy Solutions
Oct 2022
Publication
Energy plays a crucial role in the sustainable development of modern nations. Today hydrogen is considered the most promising alternative fuel as it can be generated from clean and green sources. Moreover it is an efficient energy carrier because hydrogen burning only generates water as a byproduct. Currently it is generated from natural gas. However it can be produced using other methods i.e. physicochemical thermal and biological. The biological method is considered more environmentally friendly and pollution free. This paper aims to provide an updated review of biohydrogen production via photofermentation dark fermentation and microbial electrolysis cells using different waste materials as feedstocks. Besides the role of nanotechnology in enhancing biohydrogen production is examined. Under anaerobic conditions hydrogen is produced during the conversion of organic substrate into organic acids using fermentative bacteria and during the conversion of organic acids into hydrogen and carbon dioxide using photofermentative bacteria. Different factors that enhance the biohydrogen production of these organisms either combined or sequentially using dark and photofermentation processes are examined and the effect of each factor on biohydrogen production efficiency is reported. A comparison of hydrogen production efficiency between dark fermentation photofermentation and two-stage processes is also presented.
Prospect of Green Hydrogen Generation from Hybrid Renewable Energy Sources: A Review
Feb 2023
Publication
Hydrogen is one of the prospective clean energies that could potentially address two pressing areas of global concern namely energy crises and environmental issues. Nowadays fossil‐ based technologies are widely used to produce hydrogen and release higher greenhouse gas emis‐ sions during the process. Decarbonizing the planet has been one of the major goals in the recent decades. To achieve this goal it is necessary to find clean sustainable and reliable hydrogen pro‐ duction technologies with low costs and zero emissions. Therefore this study aims to analyse the hydrogen generation from solar and wind energy sources and observe broad prospects with hybrid renewable energy sources in producing green hydrogen. The study mainly focuses on the critical assessment of solar wind and hybrid‐powered electrolysis technologies in producing hydrogen. Furthermore the key challenges and opportunities associated with commercial‐scale deployment are addressed. Finally the potential applications and their scopes are discussed to analyse the important barriers to the overall commercial development of solar‐wind‐based hydrogen production systems. The study found that the production of hydrogen appears to be the best candidate to be employed for multiple purposes blending the roles of fuel energy carrier and energy storage modality. Further studies are recommended to find technical and sustainable solutions to overcome the current issues that are identified in this study.
A Review of Hydrogen Direct Injection for Internal Combustion Engines: Towards Carbon-Free Combustion
Nov 2018
Publication
A paradigm shift towards the utilization of carbon-neutral and low emission fuels is necessary in the internal combustion engine industry to fulfil the carbon emission goals and future legislation requirements in many countries. Hydrogen as an energy carrier and main fuel is a promising option due to its carbon-free content wide flammability limits and fast flame speeds. For spark-ignited internal combustion engines utilizing hydrogen direct injection has been proven to achieve high engine power output and efficiency with low emissions. This review provides an overview of the current development and understanding of hydrogen use in internal combustion engines that are usually spark ignited under various engine operation modes and strategies. This paper then proceeds to outline the gaps in current knowledge along with better potential strategies and technologies that could be adopted for hydrogen direct injection in the context of compression-ignition engine applications—topics that have not yet been extensively explored to date with hydrogen but have shown advantages with compressed natural gas.
Integrating a Top-Gas Recycling and CO2 Electrolysis Process for H2-Rich Gas Injection and Reduce CO2 Emissions from an Ironmaking Blast Furnace
Mar 2022
Publication
Introducing CO2 electrochemical conversion technology to the iron-making blast furnace not only reduces CO2 emissions but also produces H2 as a byproduct that can be used as an auxiliary reductant to further decrease carbon consumption and emissions. With adequate H2 supply to the blast furnace the injection of H2 is limited because of the disadvantageous thermodynamic characteristics of the H2 reduction reaction in the blast furnace. This paper presents thermodynamic analysis of H2 behaviour at different stages with the thermal requirement consideration of an iron-making blast furnace. The effect of injecting CO2 lean top gas and CO2 conversion products H2–CO gas through the raceway and/or shaft tuyeres are investigated under different operating conditions. H2 utilisation efficiency and corresponding injection volume are studied by considering different reduction stages. The relationship between H2 injection and coke rate is established. Injecting 7.9–10.9 m3/tHM of H2 saved 1 kg/tHM coke rate depending on injection position. Compared with the traditional blast furnace injecting 80 m3/tHM of H2 with a medium oxygen enrichment rate (9%) and integrating CO2 capture and conversion reduces CO2 emissions from 534 to 278 m3/tHM. However increasing the hydrogen injection amount causes this iron-making process to consume more energy than a traditional blast furnace does.
Net Zero and Geospheric Return: Actions Today for 2030 and Beyond
Sep 2020
Publication
In a report co-authored by Columbia University’s Centre on Global Energy Policy (CGEP) and the Global CCS Institute titled ‘Net Zero and Geospheric Return: Actions today for 2030’ findings reveal that climate finance policies and the development of carbon dioxide removal technologies need to grow rapidly within the next 10 years in order to curb climate change and hit net-zero targets.
The report unveils key climate actions required to avoid climate catastrophe:
With 2020 set to close the hottest decade on record CO2 emissions need to drop by 50% to achieve net-zero climate goals by 2030 The rapid deployment of climate mitigating infrastructure needs to occur including the expansion of CO2 pipelines from the current 8000 km to 43000 km by 2030 Clear climate polices which reduce the financial and regulatory risk of CO2 capture and storage and increase CO2 storage options need to be quickly developed and implemented.
Link to document on Global CCS Institute Website
The report unveils key climate actions required to avoid climate catastrophe:
With 2020 set to close the hottest decade on record CO2 emissions need to drop by 50% to achieve net-zero climate goals by 2030 The rapid deployment of climate mitigating infrastructure needs to occur including the expansion of CO2 pipelines from the current 8000 km to 43000 km by 2030 Clear climate polices which reduce the financial and regulatory risk of CO2 capture and storage and increase CO2 storage options need to be quickly developed and implemented.
Link to document on Global CCS Institute Website
Techno-economic Assessment of a Hydrogen-based Islanded Microgrid in North-east
Feb 2023
Publication
Currently renewable energy-based generators are considered worldwide to achieve net zero targets. However the stochastic nature of renewable energy systems leads to regulation and control challenges for power system operators especially in remote and regional grids with smaller footprints. A hybrid system (i.e. solar wind biomass energy storage) could minimise this issue. Nevertheless the hybrid system is not possible to develop in many islands due to the limited land area geographical conditions and others. Hydrogen as a carrier of clean energy can be used in locations where the installation of extensive or medium-scale renewable energy facilities is not permissible due to population density geographical constraints government policies and regulatory issues. This paper presents a techno-economic assessment of designing a green hydrogen-based microgrid for a remote island in North-east Australia. This research work determines the optimal sizing of microgrid components using green hydrogen technology. Due to the abovementioned constraints the green hydrogen production system and the microgrid proposed in this paper are located on two separate islands. The paper demonstrates three cost-effective scenarios for green hydrogen production transportation and electricity generation. This work has been done using Hybrid Optimisation Model for Multiple Energy Resources or HOMER Pro simulation platform. Simulation results show that the Levelized Cost of Energy using hydrogen technology can vary from AU$0.37/kWh to AU$1.08/kWh depending on the scenarios and the variation of key parameters. This offers the potential to provide lower-cost electricity to the remote community. Furthermore the CO2 emission could be reduced by 1760777 kg/year if the renewable energy system meets 100% of the electricity demand. Additionally the sensitivity analysis in this paper shows that the size of solar PV and wind used for green hydrogen production can further be reduced by 50%. The sensitivity analysis shows that the system could experience AU$0.03/kWh lower levelized cost if the undersea cable is used to transfer the generated electricity between islands instead of hydrogen transportation. However it would require environmental approval and policy changes as the islands are located in the Great Barrier Reef.
Environmental Impact Assessment of Hydrogen Production via Steam Methane Reforming Based on Emissions Data
Oct 2022
Publication
Steam methane reforming (SMR) using natural gas is the most commonly used technology for hydrogen production. Industrial hydrogen production contributes to pollutant emissions which may differ from the theoretical estimates due to process conditions type and state of installed pollution control equipment. The aim of this study was to estimate the impacts of hydrogen production using facilitylevel real emissions data collected from multiple US EPA databases. The study applied the ReCiPe2016 impact assessment method and considered 12 midpoint and 14 endpoint impacts for 33 US SMR hydrogen production facilities. Global warming impacts were mostly driven by CO2 emissions and contributed to 94.6% of the endpoint impacts on human health while global warming impact on terrestrial ecosystems contributed to 98.3% of the total endpoint impacts on ecosystems. The impacts estimated by direct emissions from the 33 facilities were 9.35 kg CO2e/kg H2 which increased to 11.2 kg CO2e/kg H2 when the full life cycle of hydrogen production including upstream emissions was included. The average global warming impact could be reduced by 5.9% and 11.1% with increases in hydrogen production efficiency by 5% and 10% respectively. Potential impact reductions are also found when natural gas hydrogen production feedstock is replaced by renewable sources with the greatest reduction of 78.1% found in hydrogen production via biomass gasification followed by 68.2% reduction in landfill gas and 53.7% reduction in biomethane-derived hydrogen production.
A Review on Ports' Readiness to Facilitate International Hydrogen Trade
Jan 2023
Publication
The existing literature on the hydrogen supply chains has knowledge gaps. Most studies focus on hydrogen production storage transport and utilisation but neglect ports which are nexuses in the supply chains. To fill the gap this paper focuses on ports' readiness for the upcoming hydrogen international trade. Potential hydrogen exporting and importing ports are screened. Ports' readiness for hydrogen export and import are reviewed from perspectives of infrastructure risk management public acceptance regulations and standards and education and training. The main findings are: (1) liquid hydrogen ammonia methanol and LOHCs are suitable forms for hydrogen international trade; (2) twenty ports are identified that could be first movers; among them twelve are exporting ports and eight are importing ports; (3) ports’ readiness for hydrogen international trade is still in its infancy and the infrastructure construction or renovation risk management measures establishment of regulations and standards education and training all require further efforts.
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