China, People’s Republic
Highly Selective Production of ‘‘Jadeite Hydrogen” from the Catalytic Decomposition of Diesel
Mar 2025
Publication
Clean hydrogen (H2) is highly desirable for the sustainable development of society in the era of carbon neutrality. However the current capability of water electrolysis and steam methane (CH4) reforming to produce green and blue H2 is very limited mainly due to the high production cost difficult scale-up technology or operational risk. Here we propose the direct catalytic decomposition of diesel using a nano-Fe-based catalyst to produce the so-called ‘‘jadeite H2” while simultaneously fixing the carbon from the diesel in the form of carbon nanotubes (CNTs). Efforts are made to understand the suppression mechanism of the CH4 byproduct such as by tuning the catalyst type space velocity and reaction time. The optimal green index (GI)—that is the molar ratio of H2/carbon in a gaseous state—of the proposed technology exceeds 42 which is far higher than those of any previously reported chemical vapor deposition (CVD) method. Moreover the carbon footprint (CFP) of the proposed technology is far lower than those of grey H2 blue H2 and other dehydrogenation technologies. Compared with most of the technologies mentioned above the energy consumption (per mole of H2) and reactor amplification of the proposed technology validate its high efficiency and great practical feasibility.
Pathways to Environmental Sustainability through Energy Efficiency: A Strategic Next Energy Vision for Sustainable Development by 2050
Oct 2025
Publication
As the global push for carbon neutrality accelerates energy efficiency has become essential for sustainable development especially for nations like Nigeria that face rising energy demands and significant environmental challenges. This study explores how integrating energy efficiency with carbon neutrality can support Nigeria’s strategic energy goals while offering global lessons for other countries facing similar challenges focusing on key sectors including industry transport and power generation. The study systematically examines the impacts of renewable energy (RE) technologies like solar wind and hydropower—alongside policy reforms technological innovations and demand-side management strategies to advance energy efficiency in Nigeria. Key findings include the identification of strategic policy frameworks technological solutions and the transformative role of green hydrogen in decarbonizing hard-to-electrify sectors. The study also emphasizes the importance of international climate finance decentralized RE systems like solar mini-grids for improving energy access and economic opportunities for job creation in the RE sector. Furthermore it highlights the need for behavioral changes community engagement and consistent policy implementation to address infrastructure gaps and drive energy efficiency goals. The novelty of this research lies in its scenario-based analysis of Nigeria’s low-carbon transition detailing both the opportunities and challenges such as policy inconsistencies infrastructure deficits and financial constraints. The findings stress the importance of international collaboration technological advancements and targeted investments to overcome these challenges. By offering actionable insights and strategic recommendations this study provides a roadmap for policymakers industry stakeholders and researchers to drive Nigeria towards a sustainable carbon-neutral future by 2050.
QDQN-ThermoNet: A Quantum-driven Dual Depp Q-network Framework for Intelligent Thermal Regulation in Solid-state and Hydrogen Fuel Cell Systems of Future Electric Vehicles
Oct 2025
Publication
This paper presents QDQN-ThermoNet a novel Quantum-Driven Dual Deep Q-Network framework for intelligent thermal regulation in next-generation electric vehicles with hybrid energy systems. Our approach introduces a dual-agent architecture where a classical DQN governs solid-state battery thermal management while a quantumenhanced DQN regulates proton exchange membrane fuel cell dynamics both sharing a unified quantumenhanced experience replay buffer to facilitate cross-system information transfer. Hardware-in-the-Loop validation across diverse operational scenarios demonstrates significant performance improvements compared to classical methods including enhanced thermal stability (95.1 % vs. 82.3 %) faster thermal response (2.1 s vs. 4.7 s) reduced overheating events (0.3 vs. 3.2) and superior energy efficiency (22.4 % energy savings). The quantum-enhanced components deliver 38.7 % greater sample efficiency and maintain robust performance under sparse data conditions (33.9 % improvement) while material-adaptive control strategies leveraging MXeneenhanced phase change materials achieve a 50.3 % reduction in peak temperature rise during transients. Component lifetime analysis reveals a 33.2 % extension in battery service life through optimized thermal management. These results establish QDQN-ThermoNet as a significant advancement in AI-driven thermal management for future electric vehicle platforms effectively addressing the complex challenges of coordinating thermal regulation across divergent energy sources with different optimal operating temperatures.
A Deep Neural Network-Based Approach for Optimizing Ammonia–Hydrogen Combustion Mechanism
Nov 2025
Publication
Ammonia is a highly promising zero-carbon fuel for engines. However it exhibits high ignition energy slow flame propagation and severe pollutant emissions so it is usually burned in combination with highly reactive fuels such as hydrogen. An accurate understanding and modeling of ammonia–hydrogen combustion is of fundamental and practical significance to its application. Deep Neural Networks (DNNs) demonstrate significant potential in autonomously learning the interactions between high-dimensional inputs. This study proposed a deep neural network-based method for optimizing chemical reaction mechanism parameters producing an optimized mechanism file as the final output. The novelty lies in two aspects: first it systematically compares three DNN structures (Multilayer perceptron (MLP) Convolutional Neural Network and Residual Regression Neural Network (ResNet)) with other machine learning models (generalized linear regression (GLR) support vector machine (SVM) random forest (RF)) to identify the most effective structure for mapping combustion-related variables; second it develops a ResNet-based surrogate model for ammonia–hydrogen mechanism optimization. For the test set (20% of the total dataset) the ResNet outperformed all other ML models and empirical correlations achieving a coefficient of determination (R2 ) of 0.9923 and root mean square error (RMSE) of 135. The surrogate model uses the trained ResNet to optimize mechanism parameters based on a Stagni mechanism by mapping the initial conditions to experimental IDT. The results show that the optimized mechanism improves the prediction accuracy on laminar flame speed (LFS) by approximately 36.6% compared to the original mechanism. This method while initially applied to the optimization of an ammonia–hydrogen combustion mechanism can potentially be adapted to optimize mechanisms for other fuels.
Analysis of Exergy Flow and CCUS Carbon Reduction Potential in Coal Gasification Hydrogen Production Technology in China
Nov 2025
Publication
Coal constitutes China’s most significant resource endowment at present. Utilizing coal resources for hydrogen production represents an early-stage pathway for China’s hydrogen production industry. The analysis of energy quality and carbon emissions in coal gasification-based hydrogen production holds practical significance. This paper integrates the exergy analysis methodology into the traditional LCA framework to evaluate the exergy and carbon emission scales of coal gasification-based hydrogen production in China considering the technical conditions of CCUS. This paper found that the life cycle exergic efficiency of the whole chain of gasification-based hydrogen production in China is accounted to be 38.8%. By analyzing the causes of exergic loss and energy varieties it was found that the temperature difference between the reaction of coal gasification and CO conversion unit and the pressure difference due to the compressor driven by the electricity consumption of the compression process in the variable pressure adsorption unit are the main causes of exergic loss. Corresponding countermeasures were suggested. Regarding decarbonization strategies the CCUS process can reduce CO2 emissions across the life cycle of coal gasification-based hydrogen production by 48%. This study provides an academic basis for medium-to-long-term forecasting and roadmap design of China’s hydrogen production structure.
Nodal Marginal Price Decomposition Mechanism for the Hydrogen Energy Market Considering Hydrogen Transportation Characteristics
Oct 2025
Publication
With the growing significance of hydrogen in the global energy transition research on its pricing mechanisms has become increasingly crucial. Focusing on hydrogen markets predominantly supplied by electrolytic production this study proposes a nodal marginal hydrogen price decomposition algorithm that explicitly incorporates the time-delay dynamics inherent in hydrogen transmission. A four-dimensional price formation framework is established comprising the energy component network loss component congestion component and time-delay component. To address the nonconvex optimization challenges arising in the market-clearing model an improved second-order cone programming method is introduced. This method effectively reduces computational complexity through the reconstruction of time-coupled constraints and reformulation of the Weymouth equation. On this basis the analytical expression of the nodal marginal hydrogen price is rigorously derived elucidating how transmission dynamics influence each price component. Empirical studies using a modified Belgian 20-node system demonstrate that the proposed pricing mechanism dynamically adapts to load variations with hydrogen prices exhibiting a strong correlation with electricity cost fluctuations. The results validate the efficacy and superiority of the proposed approach in hydrogen energy market applications. This study provides a theoretical foundation for designing efficient and transparent pricing mechanisms in emerging hydrogen markets.
Optimization of Novel Variable-Channel-Width Solid Oxide Electrolysis Cell (SOEC) Design for Enhanced Hydrogen Production
Oct 2025
Publication
This study presents a novel solid oxide electrolysis cell (SOEC) design with variable channel widths to optimize thermal management and electrochemical performance for enhanced hydrogen production. Using high-fidelity computational modeling in COMSOL Multiphysics 6.1 five distinct channel width configurations were analyzed with a baseline model validated against experimental data. The simulations showed that modifying the channel geometry particularly in Scenario 2 significantly improved hydrogen production rates by 6.8% to 29% compared to a uniform channel design with the effect becoming more pronounced at higher voltages. The performance enhancement was found to be primarily due to improved fluid velocity regulation which increased reactant residence time and enhanced mass transport rather than a significant thermal effect as temperature distribution remained largely uniform across the cell. Additionally the inclusion of a dedicated heat transfer channel was shown to improve current density and overall efficiency particularly at lower voltages. While a small increase in voltage raised internal cell pressure the variable-width designs especially those with widening channels led to greater hydrogen output albeit with a corresponding increase in system energy consumption due to higher pressure. Overall the findings demonstrate that strategically designed variable-width channels offer a promising approach to optimizing SOEC performance for industrial-scale hydrogen production.
Effects of Operating Parameters on Combustion Characteristics of Hydrogen-Doped Natural Gas
Oct 2025
Publication
The operational optimization of industrial boilers utilizing hydrogen-enriched natural gas is constrained by two critical gaps: insufficient understanding of the coupled effects of hydrogen blending ratio equivalence ratio and boiler load on combustion performance— compounded by unresolved challenges of combustion instability flashback and elevated NOx emissions—and a lack of systematic investigations combining these parameters in industrial-scale systems (prior studies often focus on single variables like hydrogen fraction). To address this a comprehensive computational fluid dynamics (CFD) analysis was conducted on a 2.1 MW industrial boiler employing the Steady Laminar Flamelet Model (SLFM) with a modified k-ε turbulence model and the GRI-Mech 3.0 mechanism. Simulations covered hydrogen fractions (f(H2) = 0–25%) equivalence ratios (Φ = 0.8–1.2) and load conditions (15–100%). All NOx emissions reported herein are normalized to 3.5% O2 (mg/Nm3 ) for regulatory comparison. Results show that increasing the hydrogen content raises the flame temperature and NOx emissions while reducing CO and unburned hydrocarbons; a higher equivalence ratio elevates temperature and NOx with Φ = 0.8 balancing efficiency and emission control; and reducing load significantly lowers furnace temperature and NO emissions. Notably the boiler’s unique staged-combustion configuration (81% fuel supply to the central rich-combustion nozzle 19% to the concentric lean-combustion nozzle) was found to mitigate NOx formation by 15–20% compared to single-inlet burner designs and its integrated cyclone blades (generating maximum swirling velocity of 14.2 m/s at full load) enhanced fuel–air mixing which became particularly critical for maintaining combustion stability at low loads (≤20%) and high hydrogen blending ratios (≥20%). This study provides quantitative trade-off insights between combustion efficiency and pollutant formation offering actionable guidance for the safe efficient operation of hydrogen-enriched natural gas in industrial boilers.
Application and Research Progress of Mechanical Hydrogen Compressors in Hydrogen Refueling Stations: Structure, Performance, and Challenges
Nov 2025
Publication
The hydrogen energy industry is rapidly developing positioning hydrogen refueling stations (HRSs) as critical infrastructure for hydrogen fuel cell vehicles. Within these stations hydrogen compressors serve as the core equipment whose performance and reliability directly determine the overall system’s economy and safety. This article systematically reviews the working principles structural features and application status of mechanical hydrogen compressors with a focus on three prominent types based on reciprocating motion principles: the diaphragm compressor the hydraulically driven piston compressor and the ionic liquid compressor. The study provides a detailed analysis of performance bottlenecks material challenges thermal management issues and volumetric efficiency loss mechanisms for each compressor type. Furthermore it summarizes recent technical optimizations and innovations. Finally the paper identifies current research gaps particularly in reliability hydrogen embrittlement and intelligent control under high-temperature and high-pressure conditions. It also proposes future technology development pathways and standardization recommendations aiming to serve as a reference for further R&D and the industrialization of hydrogen compression technology.
Addressing Spatiotemporal Mismatch via Hourly Pipeline Scheduling: Regional Hydrogen Energy Supply Optimization
Nov 2025
Publication
The rapid adoption of hydrogen fuel cell vehicles (HFCVs) in the Beijing–Tianjin–Hebei (BTH) hub accentuates the mismatch between renewable-based hydrogen supply in Hebei and concentrated demand in Beijing and Tianjin. We develop a mixed-integer linear model that co-configures a hydrogen pipeline network and optimizes hourly flow schedules to minimize annualized cost and CO2 emissions simultaneously. For 15000 HFCVs expected in 2025 (137 t d−1 demand) the Pareto-optimal design consists of 13 production plants 43 pipelines and 38 refueling stations delivering 50767 t yr−1 at 68% pipeline utilization. Hebei provides 88% of the hydrogen 70% of which is consumed in the two megacities. Hourly profiles reveal that 65% of electrolytic output coincides with local wind–solar peaks whereas refueling surges arise during morning and evening rush hours; the proposed schedule offsets the 4–6 h mismatch without additional storage. Transport distances are 40% < 50 km 35% 50–200 km and 25% > 200 km. Raising the green hydrogen share from 10% to 70% increases total system cost from USD 1.56 bn to USD 2.73 bn but cuts annual CO2 emissions from 142 kt to 51 kt demonstrating the trade-off between cost and decarbonization. The model quantifies the value of sub-day pipeline scheduling in resolving spatial–temporal imbalances for large-scale low-carbon hydrogen supply.
Optimal Dispatch Model for Hybrid Energy Storage in Low-Carbon Integrated Energy Systems
Nov 2025
Publication
Integrated Energy Systems (IESs) which leverage the synergistic coordination of electricity heat and gas networks serve as crucial enablers for a low-carbon transition. Current research predominantly treats energy storage as a subordinate resource in dispatch schemes failing to simultaneously optimise IES economic efficiency and storage operators’ profit maximisation thereby overlooking their potential value as independent market entities. To address these limitations this study establishes an operator-autonomous management framework incorporating electrical thermal and hydrogen storage in IESs. We propose a joint optimal dispatch model for hybrid energy storage systems in low-carbon IES operation. The upper-level model minimises total system operation costs for IES operators while the lower-level model maximises net profits for independent storage operators managing various storage assets. These two levels are interconnected through power price and carbon signals. The effectiveness of the proposed model is verified by setting up multiple scenarios for example analysis.
Heat Transfer Enhancement in Regenerative Cooling Channels: Numerical Analysis of Single- and Double-row Cylindrical Ribs with Supercritical Hydrogen
Nov 2025
Publication
The thermal protection of rocket engine combustion chambers presents a critical challenge in supersonic flight applications. This study numerically investigates the enhancement of heat transfer and coolant flow characteristics in regenerative cooling channels through cylindrical rib integration employing ANSYS Fluent with SST k-ω turbulence modeling to evaluate single- and double-row configurations (0.75–1.25 mm diameter) under supercritical hydrogen conditions (3 MPa 300 K inlet). Results demonstrate that rib-induced turbulence disrupts thermal boundary layers with a 1.25 mm single-row design achieving a 13.67 % reduction in peak wall temperature compared to smooth channels while double-row arrangements show diminishing returns due to increased flow resistance. The thermal performance factor (η = (Nu/Nu₀)/(f/f₀) 1/3) reveals Case 3′s superiority (21.88 % improvement over the smooth channel configuration) in balancing heat transfer enhancement against pressure drop penalties (9.23–20.93 % for single-row 8.26–18.7 % for double-row). Notably density-driven flow acceleration near heated walls mitigates pressure losses through localized viscosity reduction. Furthermore cylindrical ribs reduce thermal stratification by up to 30 % in single-row configurations with double-row designs providing additional temperature homogenization at the cost of increased flow resistance. These findings offer critical insights for optimizing rib-enhanced cooling systems in high-performance rocket engines achieving simultaneous thermal efficiency and hydraulic performance improvements.
In-situ CO2 Capture by DFMs to Enhance Hydrogen Production and Regeneration Performance of Biomass-H2O Gasification
Nov 2025
Publication
Developing green hydrogen energy can alleviate the problem of CO2 emissions caused by excessive use of fossil fuels. In-situ capture of CO2 for enhanced H2 production in zero-carbon energy biomass-H2O gasification can achieve the dual effects of green H2 production and negative carbon. The study used red mud (RM) to modify CaO and prepare dual-functional materials (DFMs). And the in-situ CO2 capture enhanced H2 production and regeneration cycle performance of DFMs in biomass-H2O gasification were studied and the influence of biomass ash on the H2 production and low-temperature (650 ◦C) regeneration performance of DFMs in the cycle was analyzed. The results are as follows: In DFMs catalyzed biomass-H2O gasification due to the continuous deposition of alkali and alkaline earth metals (AAEMs) in biomass ash with increasing cycle times its catalytic effect increased H2 production by 27 % after twenty cycles and the pore structure degradation and cycle stability of DFMs decreased by 44.71 %. DFMs have demonstrated excellent catalytic performance and cycling stability in the catalytic removal of ash from biomass. After twenty cycles the production of H2 only decreased by 20.59 % and the performance of CaO decreased by 26.67 % demonstrating the enormous potential of DFMs for in-situ CO2 capture and enhanced H2 production.
Thermal Energy Integration and Optimization in a Biomass-fueled Multi-generation System for Power, Hydrogen, and Freshwater Production
Nov 2025
Publication
This work investigates a biomass-driven multi-generation system designed for simultaneous power freshwater and hydrogen production addressing the interlinked energy-waterenvironment nexus. The configuration integrates Brayton supercritical carbon dioxide (SCO2) organic Rankine cycle (ORC) and thermoelectric generator (TEG) subsystems to maximize utilization of biomass-derived syngas. The recovered energy drives a reverse osmosis (RO) desalination unit for freshwater production and an alkaline electrolyzer for hydrogen generation followed by two-stage compression for storage. Under baseline conditions the system generates 1.99 MW of electricity 9.38 kg/h of hydrogen and 88.6 m3 /h of freshwater with an overall exergetic efficiency of 20.25 % emissions intensity of 0.85 kg/kWh and a payback period of 5.87 years. The Brayton cycle accounts for 49.3 % of the total cost rate while the gasifier exhibits the highest exergy destruction at 46 %. Sensitivity analyses show that varying biomass moisture content (10–30 %) and operating temperatures (700–900 ◦C) significantly influence system performance. Using a data-driven optimization framework that combines artificial neural networks (ANN) and a genetic algorithm (GA) the system’s exergetic efficiency improves to 21.76 % freshwater output rises to 90.96 m3 /h and emissions intensity decreases to 0.877 kg/kWh. Additionally optimization reduces the total cost rate by 2.71 % leading to a payback period of 5.4 years and enhances the system’s overall performance by 12.64 %.
Optimal Sizing and Energy Management for Fuel Cell Electric Vehicles with 3D-ordered MEAs: A Pareto Frontier Study
Oct 2025
Publication
Fuel cell electric vehicles (FCEVs) are zero-emission but face cost and power density challenges. To mitigate these limitations a novel 3D-ordered nano-structured self-supporting membrane electrode assembly (MEA) has been developed. This paper investigates the optimal component sizing of the battery and fuel cell in FCEVs equipped with 3D-ordered MEAs integrating the energy management. To explore the trade-offs between component cost operational cost and fuel cell degradation the sizing and energy management problem is formulated into a multi-objective optimisation problem. A Pareto frontier (PF) study is conducted using the decomposed multi-objective evolutionary algorithm (MOEA/D) for a more diverse distribution of feasible solutions. The modular design of fuel cells is derived from a scaled and stressed experiment. After executing MOEA/D across the three aggressive driving cycles power source configurations are selected from the corresponding PFs based on objective trade-offs ensuring robustness of the overall system. The optimisation performance of the MOEA/D is compared with that of the multi-objective Particle Swarm Optimisation. In addition the selected powertrain configurations are evaluated and compared through standard and realworld driving cycles in a simulation environment. This paper also performs a sensitivity analysis to reveal the influence of diverse component unit costs and hydrogen price. The results indicate that the mediumsized configuration consisting of a 63.31 kW fuel cell stack and a 52.15 kWh battery pack delivers the best overall performance. It achieves a 26.71% reduction in component cost and up to 12.76% savings in hydrogen consumption across various driving conditions. These findings provide valuable insights into the design and optimisation of fuel cell systems for FCEVs.
Design of Hydrogen-Powered Mobile Emergency Power Vehicle with Soft Open Point and Appropriate Energy Management Strategy
Oct 2025
Publication
Zhigang Liu,
Wen Chen,
Shi Liu,
Yu Cao and
Yitao Li
Mobile emergency power supply vehicles (MEPSVs) powered by diesel engines or lithiumion batteries (LIBs) have become a viable tool for emergency power supply. However diesel-powered MEPSVs generate noise and environmental pollution while LIB-powered vehicles suffer from limited power supply duration. To overcome these limitations a hydrogen-powered MEPSV incorporating a soft open point (SOP) was developed in this study. We analyzed widely used operating scenarios for the SOP-equipped MEPSV and determined important parameters including vehicle body structure load capacity driving speed and power generation capability for the driving motor hydrogen fuel cell (FC) module auxiliary LIB module and SOP equipment. Subsequently we constructed an energy management strategy for the model for MEPSV which uses multiple energy sources of hydrogen fuel cells and lithium-ion batteries. Through simulations an optimal hydrogen consumption rate in various control strategies was validated using a predefined load curve to optimize the energy consumption minimization strategy and achieve the highest efficiency.
Hydrogen-involved Renewable Energy Base Planning in Desert and Gobi Regions under Electricity-carbon-hydrogen Markets
Nov 2025
Publication
China is developing renewable energy bases (REBs) in the desert and Gobi regions. However the intermittency of renewable energy and the temporal mismatch between peak renewable generation and peak load demand severely disrupt the power supply reliability of these REBs. Hydrogen storage technology characterized by high energy density and long-term storage capability is an effective method for enhancing the power supply reliability. Therefore this paper proposes a REB planning model in the desert and Gobi regions considering seasonal hydrogen storage introduction as well as electricity-carbon-hydrogen markets trading. Furthermore a combination scenario generation method considering extreme scenario optimization is proposed. Among which the extreme scenarios selected through an iterative selection method based on maximizing scenario divergence contain more incremental information providing data support for the proposed model. Finally the simulation was conducted in the desert and Gobi regions of Yinchuan Ningxia Province China primarily verifying that (1) the REB incorporating hydrogen storage can fully leverage hydrogen storage to achieve seasonal and long-term electricity transfer and utilization. The project has a payback period of 10 years with an internal rate of return of 13.30% and a return on investment of 16.34% thus showing significant development potential. (2) Compared to the typical battery-involved REB the hydrogen-involved energy storage facility achieved a 59.39% annual profit a 10.98% internal rate of return a 14.93% return on investment and a 1.51% improvement in power supply reliability by sacrificing a 52.49% increase in construction cost. (3) Compared to REB planning based only on typical scenarios the power supply reliability of REBs based on the proposed combination scenario generation method improved by 8.58%.
A Two-Stage Optimal Dispatch Strategy for Electric-ThermalHydrogen Integrated Energy System Based on IGDT and Fuzzy Chance-Constrained Programming
Nov 2025
Publication
Na Sun,
Hongxu He and
Haiying Dong
To address the economic and reliability challenges of high-penetration renewable energy integration in electricity-heat-hydrogen integrated energy systems and support the dualcarbon strategy this paper proposes an optimal dispatch method integrating Information Gap Decision Theory (IGDT) and Fuzzy Chance-Constrained Programming (FCCP). An IES model coupling multiple energy components was constructed to exploit multi-energy complementarity. A stepped carbon trading mechanism was introduced to quantify emission costs. For interval uncertainties in renewable generation IGDT-based robust and opportunistic dispatch models were established; for fuzzy load uncertainties FCCP transformed them into deterministic equivalents forming a dual-layer “IGDT-FCCP” uncertainty handling framework. Simulation using CPLEX demonstrated that the proposed model dynamically adjusts uncertainty tolerance and confidence levels effectively balancing economy robustness and low-carbon performance under complex uncertainties: reducing total costs by 12.7% cutting carbon emissions by 28.1% and lowering renewable curtailment to 1.8%. This study provides an advanced decision-making paradigm for low-carbon resilient IES.
Joint Optimization Scheduling of Electric Vehicles and Electro–Olefin–Hydrogen Electromagnetic Energy Supply Device for Wind–Solar Integration
Nov 2025
Publication
In northern China the long winter heating period is accompanied by severe wind curtailment. To address this issue a joint optimization scheduling strategy of electric vehicles (EVs) and electro–olefin–hydrogen electromagnetic energy supply device (EHED) is proposed to promote deep wind–solar integration. Firstly the feasibility analysis of EVs participating in scheduling is conducted and the operation models of dispatchable EVs and thermal energy storage EHEDs within the scheduling period are established. Secondly a control strategy for the joint optimization scheduling of wind–solar farms EVs EHEDs and power grid is constructed. Then an economic dispatch model for joint optimization of EVs and EHEDs is established to minimize the system operation cost within the scheduling period and the deep wind–solar integration of the joint optimization model is studied by considering EVs under different demand responses. Finally the proposed model is solved by CPLEX solver. The simulation results show that the established joint optimization economic dispatch model of EV-EHEDs can improve the enthusiasm of dispatchable EVs to participate in deep wind–solar integration reduce wind curtailment power and decrease the overall system operation cost.
An Explainable Fault Diagnosis Algorithm for Proton Exchange Membrane Fuel Cells Integrating Gramian Angular Fields and Gradient-Weighted Class Activation Mapping
Nov 2025
Publication
Reliable operation of proton exchange membrane fuel cells (PEMFCs) is crucial for their widespread commercialization and accurate fault diagnosis is the key to ensuring their long-term stable operation. However traditional fault diagnosis methods not only lack sufficient interpretability making it difficult for users to trust their diagnostic decisions but also one-dimensional (1D) feature extraction methods highly rely on manual experience to design and extract features which are easily affected by noise. This paper proposes a new interpretable fault diagnosis algorithm that integrates Gramian angular field (GAF) transform convolutional neural network (CNN) and gradient-weighted class activation mapping (Grad-CAM) for enhanced fault diagnosis and analysis of proton exchange membrane fuel cells. The algorithm is systematically validated using experimental data to classify three critical health states: normal operation membrane drying and hydrogen leakage. The method first converts the 1D sensor signal into a two-dimensional GAF image to capture the temporal dependency and converts the diagnostic problem into an image recognition task. Then the customized CNN architecture extracts hierarchical spatiotemporal features for fault classification while Grad-CAM provides visual explanations by highlighting the most influential regions in the input signal. The results show that the diagnostic accuracy of the proposed model reaches 99.8% which is 4.18% 9.43% and 2.46% higher than other baseline models (SVM LSTM and CNN) respectively. Furthermore the explainability analysis using Grad-CAM effectively mitigates the “black box” problem by generating visual heatmaps that pinpoint the key feature regions the model relies on to distinguish different health states. This validates the model’s decision-making rationality and significantly enhances the transparency and trustworthiness of the diagnostic process.
Dispersion of High-Pressure Hydrogen Jets in Open-Top and Indoor Environments: Effects of Leak Geometry and Pressure
Nov 2025
Publication
Yang Li,
Shourui Zhang,
Meng Yu,
Yang Wu,
Jiake Wu and
Long Jiang
Hydrogen leakage is a critical safety concern for high-pressure storage systems where orifice geometry significantly influences dispersion and risk. Previous studies on leakage and diffusion have mostly focused on closed or semi-closed environments while thorough exploration has been conducted on open and unshielded environments. This work compares three typical orifice types—circular slit and Y-type—through controlled experiments. Results show that circular orifices generate directional jets with steep gradients but relatively low concentrations with a 1 mm case reaching only 0.725% at the jet core. Slit orifices exhibit more uniform diffusion; at 1 mm concentrations ranged from 2.125% to 2.625%. Y-type orifices presented the highest hazard with 0.5 mm leaks producing 2.9% and 1 mm cases approaching the 4% lower flammability limit within 375 s. Equilibrium times increased with orifice size from 400–800 s for circular and slit leaks to up to 900 s for Y-type leaks some of which failed to stabilize. Response behavior also varied: Y-type leaks achieved rapid multi-point responses (as short as 10 s) while circular and slit leaks responded more slowly away from the jet core. Overall risk ranking was circular < slit < Y-type underscoring the urgent need for geometry-specific monitoring strategies sensor layouts and emergency thresholds to ensure safe hydrogen storage.
Marine Hydrogen Pressure Reducing Valves: A Review on Multi-Physics Coupling, Flow Dynamics, and Structural Optimization for Ship-Borne Storage Systems
Oct 2025
Publication
As a zero-carbon energy carrier hydrogen is playing an increasingly vital role in the decarbonization of maritime transportation. The hydrogen pressure reducing valve (PRV) is a core component of ship-borne hydrogen storage systems directly influencing the safety efficiency and reliability of hydrogen-powered vessels. However the marine environment— characterized by persistent vibrations salt spray corrosion and temperature fluctuations— poses significant challenges to PRV performance including material degradation flow instability and reduced operational lifespan. This review comprehensively summarizes and analyzes recent advances in the study of high-pressure hydrogen PRVs for marine applications with a focus on transient flow dynamics turbulence and compressible flow characteristics multi-stage throttling strategies and valve core geometric optimization. Through a systematic review of theoretical modeling numerical simulations and experimental studies we identify key bottlenecks such as multi-physics coupling effects under extreme conditions and the lack of marine-adapted validation frameworks. Finally we conducted a preliminary discussion on future research directions covering aspects such as the construction of coupled multi-physics field models the development of marine environment simulation experimental platforms the research on new materials resistant to vibration and corrosion and the establishment of a standardized testing system. This review aims to provide fundamental references and technical development ideas for the research and development of high-performance marine hydrogen pressure reducing valves with the expectation of facilitating the safe and efficient application and promotion of hydrogen-powered shipping technology worldwide.
Co-Optimization of Capacity and Operation for Battery-Hydrogen Hybrid Energy Storage Systems Based on Deep Reinforcement Learning and Mixed Integer Programming
Oct 2025
Publication
The hybrid energy storage system (HESS) that combines battery with hydrogen storage exploits complementary power/energy characteristics but most studies optimize capacity and operation separately leading to suboptimal overall performance. To address this issue this paper proposes a bi-level co-optimization framework that integrates deep reinforcement learning (DRL) and mixed integer programming (MIP). The outer layer employs the TD3 algorithm for capacity configuration while the inner layer uses the Gurobi solver for optimal operation under constraints. On a standalone PV–wind–load-HESS system the method attains near-optimal quality at dramatically lower runtime. Relative to GA + Gurobi and PSO + Gurobi the cost is lower by 4.67% and 1.31% while requiring only 0.52% and 0.58% of their runtime; compared with a direct Gurobi solve the cost remains comparable while runtime decreases to 0.07%. Sensitivity analysis further validates the model’s robustness under various cost parameters and renewable energy penetration levels. These results indicate that the proposed DRL–MIP cooperation achieves near-optimal solutions with orders of magnitude speedups. This study provides a new DRL–MIP paradigm for efficiently solving strongly coupled bi-level optimization problems in energy systems.
Assessment of Regional Hydrogen Refueling Station Layout Planning and Carbon Reduction Benefits Based on Multi-Dimensional Factors of Population, Land, and Demand
Oct 2025
Publication
The urgent global transition toward low-carbon energy systems has highlighted the need for systematic planning of hydrogen refueling stations (HRS) to facilitate clean energy adoption. This study develops an integrated framework for regional HRS layout optimization and carbon emission assessment considering population distribution land area and hydrogen demand. Using Hainan Province as a case study the model estimates regional hydrogen demand determines optimal HRS deployment evaluates spatial coverage and refueling distances and quantifies potential carbon emission reductions under various renewable energy scenarios. Model validation with Haikou demonstrates its reliability and applicability at the regional scale. Results indicate pronounced spatial disparities in hydrogen demand and infrastructure requirements emphasizing that prioritizing station deployment in densely populated urban areas can enhance accessibility and maximize emission reduction. The framework offers a practical data-efficient tool for policymakers and planners to guide early-stage hydrogen infrastructure development and supports strategies for regional decarbonization and sustainable energy transitions.
Degradation Heterogeneity in Active X70 Pipeline Welds Microstructure-Property Coupling Under Multiphysics Environments of Hydrogen-Blended Natural Gas
Oct 2025
Publication
This study investigates the performance degradation of X70 steel weld material in highpressure natural gas pipelines in the Sichuan-Chongqing region and its impact on pipeline safety by investigating their behavior under multiphysics environments including varying gas media (nitrogen methane hydrogen-blended) pressure conditions (0.1–10 MPa) and material regions (base metal vs. weld). A key novelty of this work is the introduction of a “degradation rate” metric to quantitatively assess the deterioration of weld mechanical properties. A key novelty of this work is the explicit introduction of a “degradation rate” metric to quantitatively assess the deterioration of weld mechanical properties. Slow strain rate tensile tests combined with fracture morphology and microstructure analysis reveal that welds exhibit inferior mechanical properties due to microstructural inhomogeneity and residual stresses including a yield stress reduction of 15.2–18.7%. The risk of brittle fracture was highest in the hydrogen-blended environment while nitrogen exhibited the most benign effect. Material region changes were identified as the most significant factor affecting degradation. This research provides crucial data and theoretical support for pipeline safety design and material performance optimization.
Enhanced Performance of TiO2 Composites for Solar Cells and Photocatalytic Hydrogen Production
Oct 2025
Publication
Xue Bai,
Jian Chen,
Shengxi Du and
Yan Xiong
Titanium dioxide (TiO2) is widely used in solar cells and photocatalysts given its excellent photoactivity low cost and high structural electronic and optical stability. Here a novel TiO2 composite was prepared by coating TiO2 inverse opal (IO) with TiO2 nanorods (NRs). With a porous three-dimensional network structure the composite exhibited higher light absorption; enhanced the separation of the electron–hole pairs; deepened the infiltration of the electrolyte; better transported and collected charge carriers; and greatly improved the power conversion efficiency (PCE) of the quantum-dot sensitized solar cells (QDSSCs) based on it while also boosting its own photocatalytic hydrogen generation efficiency. A very high PCE of 12.24% was achieved by QDSSCs utilizing CdS/CdSe sensitizer. Furthermore the TiO2 composite exhibited high photocatalytic activity with a H2 release rate of 1080.2 µ mol h−1 g −1 several times that of bare TiO2 IO or TiO2 NRs.
A Review on Combustion Instability of Hydrogen-Enriched Marine Gas Turbines
Nov 2025
Publication
Hydrogen is widely regarded as a promising carbon-free alternative fuel. However the development of low-emission marine gas turbine combustion systems has been hindered by the associated risks of combustion instability also termed as thermoacoustic oscillations. Although there is sufficient literature on hydrogen fuel and combustion instability systematic reviews addressing the manifestations and mechanisms of these instabilities remain limited. The present study aims to provide a comprehensive review of combustion instabilities in hydrogen-enriched marine gas turbines with a particular focus on elucidating the characteristics and underlying mechanisms. The review begins with a concise overview of recent progress in understanding the fundamental combustion properties of hydrogen and then details various instability phenomena in hydrogen-enriched methane flames. The mechanisms by which hydrogen enrichment affects combustion instabilities are extensively discussed particularly in relation to the feedback loop in thermoacoustic combustion systems. The paper concludes with a summary of the key combustion instability challenges associated with hydrogen addition to methane flames and offers prospects for future research. In summary the review highlights the interaction between hydrogenenriched methane flames and thermoacoustic phenomena providing a foundation for the development of stable low-emission combustion systems in industrial marine applications incorporating hydrogen enrichment.
Benefit Allocation Strategies for Electric–Hydrogen Coupled Virtual Power Plants with Risk–Reward Tradeoffs
Nov 2025
Publication
Driven by carbon neutrality goals electric–hydrogen coupled virtual power plants (EHCVPPs) integrate renewable hydrogen production with power system flexibility resources emerging as a critical technology for large-scale renewable integration. As distributed energy resources (DERs) within EHCVPPs diversify heterogeneous resources generate diversified market values. However inadequate benefit allocation mechanisms risk reducing participation incentives destabilizing cooperation and impairing operational efficiency. To address this benefit allocation must balance fairness and efficiency by incorporating DERs’ regulatory capabilities risk tolerance and revenue contributions. This study proposes a multi-stage benefit allocation framework incorporating risk–reward tradeoffs and an enhanced optimization model to ensure sustainable EHCVPP operations and scalability. The framework elucidates bidirectional risk–reward relationships between DERs and EHCVPPs. An individualized risk-adjusted allocation method and correction mechanism are introduced to address economic-centric inequities while a hierarchical scheme reduces computational complexity from diverse DERs. The results demonstrate that the optimized scheme moderately reduces high-risk participants’ shares increasing operator revenue by 0.69% demand-side gains by 3.56% and reducing generation-side losses by 1.32%. Environmental factors show measurable yet statistically insignificant impacts. The framework meets stakeholders’ satisfaction and minimizes deviation from reference allocations.
Durable Pt-Decorated NiFe-LDH for High-Current-Density Electrocatalytic Water Splitting Under Alkaline Conditions
Nov 2025
Publication
The development of durable and efficient catalysts capable of driving both hydrogen and oxygen evolution reactions is essential for advancing sustainable hydrogen production through overall water electrolysis. In this study we developed a corrosion-mediated approach where Ni ions originate from the self-corrosion of the nickel foam (NF) substrate to construct Pt-modified NiFe layered double hydroxide (Pt-NiFeOxHy@NiFe-LDH) under ambient conditions. The obtained catalyst exhibits a hierarchical architecture with abundant defect sites which favor the uniform distribution of Pt clusters and optimized electronic configuration. The Pt-NiFeOxHy@NiFe-LDH catalyst constructed through the interaction between Pt sites and defective NiFe layered double hydroxide (NiFe-LDH) demonstrates remarkable hydrogen evolution reaction (HER) activity delivering an overpotential as low as 29 mV at a current density of 10 mA·cm−2 and exhibiting a small tafel slope of 34.23 mV·dec−1 in 1 M KOH together with excellent oxygen evolution reaction (OER) performance requiring only 252 mV to reach 100 mA·cm−2 . Moreover the catalyst demonstrates outstanding activity and durability in alkaline seawater maintaining stable operation over long-term tests. The Pt-NiFeOxHy@NiFe-LDH electrode when integrated into a two-electrode system demonstrates operating voltages as low as 1.42 and 1.51 V for current densities of 10 and 100 mA·cm−2 respectively and retains outstanding stability under concentrated alkaline conditions (6 M KOH 70 ◦C). Overall this work establishes a scalable and economically viable pathway toward high-efficiency bifunctional electrocatalysts and deepens the understanding of Pt-LDH interfacial synergy in promoting water-splitting catalysis.
Correlation Development for Para-to-Ortho Hydrogen Catalytic Conversion in Vapor-Cooled Shields of Hydrogen Tanks
Nov 2025
Publication
The cooling effect from the para-ortho hydrogen conversion (POC) combined with a vaporcooled shield (VCS) and multi-layer insulation (MLI) can effectively extend the storage duration of liquid hydrogen in cryogenic tanks. However there is currently no effective and straightforward empirical correlation available for predicting the catalytic POC efficiency in VCS pipelines. This study focuses on the development of correlations for the catalytic conversion of para-hydrogen to ortho-hydrogen in pipelines particularly in the context of cryogenic hydrogen storage systems. A model that incorporates the Langmuir adsorption characteristics of catalysts and introduces the concept of conversion efficiency to quantify the catalytic process’s performance is introduced. Experimental data were obtained in the temperature range of 141.9~229.9 K from a cryogenic hydrogen catalytic conversion facility where the effects of temperature pressure and flow rate on the catalytic conversion efficiency were analyzed. Based on a validation against the experimental data the proposed model offers a reliable method for predicting the cooling effects and optimizing the catalytic conversion process in VCS pipelines which may contribute to the improvement of liquid hydrogen storage systems enhancing both the efficiency and duration of storage.
Coordinated Operation Mechanism of Electric-hydrogen-traffic Coupling System that Considers Carbon Emissions and Uncertainties
Nov 2025
Publication
During the critical period of energy transition the collaborative optimization of the electricity-hydrogentransportation coupling system is of vital importance for achieving efficient energy utilization and sustainable development.This paper proposes a collaborative operation mechanism of Distributed Robust Optimization (DRO) considering carbon emissions. Firstly a Stackelberg game dynamic pricing strategy is constructed for the integrated energy station (IES) and the electricity-hydrogen hybrid charging station (HRS) where the upper-level IES optimizes the electricity price setting strategy and the lower-level HRS dynamically adjusts the electricity purchase-hydrogen production plan. Secondly the Wasserstein distance is used to describe the uncertainties of hydrogen vehicle loads and wind-solar power generation and a bisection algorithm-column constraint generation (BA-C&CG) hybrid algorithm is designed to solve the model. Finally the numerical example verification shows that the daily operation cost of HRS under the proposed mechanism is as low as 1108.53 EUR which is 10.58 % and 7.38 % lower than that of the commonly used stochastic optimization (SO) and robust optimization (RO) respectively. The variance analysis (F = 536.05P < 0.001) confirms that the cost advantage is statistically significant. In terms of carbon emission reduction effect the DRO-Stackelberg game model has the lowest daily carbon cost (6.98EUR). This mechanism effectively balances the economic and robustness of the system and the single dispatch calculation time is only 112.09 s meeting the real-time operation requirements of engineering. It provides technical support for the low-carbon collaborative operation of the electricity-hydrogen-transportation coupling system.
Economic Hydrogen Production by Water Splitting with Different Catalysts and Temperatures under Thermal and Gamma Radiation-thermal Processes
Nov 2025
Publication
This article describes hydrogen production via water splitting because of high green energy demand globally. The amounts of hydrogen produced with zirconium in thermal processes at 473 K and radiation-thermal processes at 473 K and 773K were 1.55 x 1018 2.2 x 1018 and 4.1 x 1018 molecules/g. These amounts on aluminum and stainless steel were 1.05 x 1018 1.95 x 1018 and 3.0 x 1018 molecules/g; and 0.30 x 1018 1.27 x 1018 and 2.6 x 1018 molecules/g. A comparison was carried out and the order of hydrogen production was zirconium > aluminum > stainless steel. The activation energy in radiation-thermal and thermal processes were 14.2 and 65.0 kJ/mol (Zr) 12.05 and 63.1 kJ/mol (Al) and 11.16 and 61.52 kJ/mol (SS). The mechanisms of water splitting were developed and described for future use. The described methods are scalable and can be transferred to a pilot scale.
Reliability and Risk Assessment of Hydrogen-Powered Marine Propulsion Systems Based on the Integrated FAHP-FMECA Framework
Nov 2025
Publication
With the IMO’s 2050 decarbonization target hydrogen is a key zero-carbon fuel for shipping but the lack of systematic risk assessment methods for hydrogen-powered marine propulsion systems (under harsh marine conditions) hinders its large-scale application. To address this gap this study proposes an integrated risk evaluation framework by fusing Failure Mode Effects and Criticality Analysis (FMECA) with the Fuzzy Analytic Hierarchy Process (FAHP)—resolving the limitation of traditional single evaluation tools and adapting to the dynamic complexity of marine environments. Scientific findings from this framework confirm that hydrogen leakage high-pressure storage tank valve leakage and inverter overload are the three most critical failure modes with hydrogen leakage being the primary risk source due to its high severity and detection difficulty. Further hazard matrix analysis reveals two key risk mechanisms: one type of failure (e.g. insufficient hydrogen concentration) features “high severity but low detectability” requiring real-time monitoring; the other (e.g. distribution board tripping) shows “high frequency but controllable impact” calling for optimized operations. This classification provides a theoretical basis for precise risk prevention. Targeted improvement measures (e.g. dual-sealed valves redundant cooling circuits AI-based regulation) are proposed and quantitatively validated reducing the system’s overall risk value from 4.8 (moderate risk) to 1.8 (low risk). This study’s core contribution lies in developing a universally applicable scientific framework for marine hydrogen propulsion system risk assessment. It not only fills the methodological gap in traditional evaluations but also provides a theoretical basis for the safe promotion of hydrogen shipping supporting the scientific realization of the IMO’s decarbonization goal.
High‑Entropy Amorphous Catalysts for Water Electrolysis: A New Frontier
Sep 2025
Publication
High‐entropy amorphous catalysts (HEACs) integrate multielement synergy with structural disorder making them promising candidates for water splitting. Their distinctive features—including flexible coordination environments tunable electronic structures abundant unsaturated active sites and dynamic structural reassembly—collectively enhance electrochemical activity and durability under operating conditions. This review summarizes recent advances in HEACs for hydrogen evolution oxygen evolution and overall water splitting highlighting their disorder-driven advantages over crystalline counterparts. Catalytic performance benchmarks are presented and mechanistic insights are discussed focusing on how multimetallic synergy amorphization effect and in‐situ reconstruction cooperatively regulate reaction pathways. These insights provide guidance for the rational design of next‐generation amorphous high‐entropy electrocatalysts with improved efficiency and durability.
Numerical Study of Liquid Hydrogen Internal Flow in Liquid Hydrogen Storage Tank
Oct 2025
Publication
As a key zero-carbon energy carrier the accurate measurement of liquid hydrogen flow in its industrial chain is crucial. However the ultra-low temperature ultra-low density and other properties of liquid hydrogen can introduce calibration errors. To enhance the measurement accuracy and reliability of liquid hydrogen flow this study investigates the heat and mass transfer within a 1 m3 non-vented storage tank during the calibration process of a liquid hydrogen flow standard device that integrates combined dynamic and static gravimetric methods. The vertical tank configuration was selected to minimize the vapor–liquid interface area thereby suppressing boil-off gas generation and enhancing pressure stability which is critical for measurement accuracy. Building upon research on cryogenic flow standard devices as well as tank experiments and simulations this study employs computational fluid dynamics (CFD) with Fluent 2024 software to numerically simulate liquid hydrogen flow within a non-vented tank. The thermophysical properties of hydrogen crucial for the accuracy of the phase-change simulation were implemented using high-fidelity real-fluid data from the NIST Standard Reference Database as the ideal gas law is invalid under the cryogenic conditions studied. Specifically the Lee model was enhanced via User-Defined Functions (UDFs) to accurately simulate the key phasechange processes involving coupled flash evaporation and condensation during liquid hydrogen refueling. The simulation results demonstrated good agreement with NASA experimental data. This study systematically examined the effects of key parameters including inlet flow conditions and inlet liquid temperature on the flow characteristics of liquid hydrogen entering the tank and the subsequent heat and mass transfer behavior within the tank. The results indicated that an increase in mass flow rate elevates tank pressure and reduces filling time. Conversely a decrease in the inlet liquid hydrogen temperature significantly intensifies heat and mass transfer during the initial refueling stage. These findings provide important theoretical support for a deeper understanding of the complex physical mechanisms of liquid hydrogen flow calibration in non-vented tanks and for optimizing calibration accuracy.
Enhancing Regional Integrated Energy Systems Through Seasonal Hydrogen Storage: Insights from a Stackelberg Game Model
Nov 2025
Publication
This study enhances regional integrated energy systems by proposing a Stackelberg planning–operation model with seasonal hydrogen storage addressing source–network separation. An equilibrium algorithm is developed that integrates a competitive search routine with mixed-integer optimization. In the price–energy game framework the hydrogen storage operator is designated as the leader while energy producers load aggregators and storage providers act as followers facilitating a distributed collaborative optimization strategy within the Stackelberg game. Using an industrial park in northern China as a case study the findings reveal that the operator’s initiative results in a revenue increase of 38.60% while producer profits rise by 6.10% and storage-provider profits surge by 108.75%. Additionally renewable accommodation reaches 93.86% reflecting an absolute improvement of 20.60 percentage points. Total net energy imbalance decreases by 55.70% and heat-loss load is reduced by 31.74%. Overall the proposed approach effectively achieves cross-seasonal energy balancing and multi-party gains providing an engineering-oriented reference for addressing energy imbalances in regional integrated energy systems.
Performance Analysis of Natural Gas Centrifugal Compressors Under Hydrogen-Blended Conditions
Nov 2025
Publication
The transport of natural gas blended with hydrogen is a key strategy for the low-carbon energy transition. However the influence mechanism of its thermo-physical property variations on centrifugal compressor performance remains insufficiently understood. This study systematically investigates the effects of the hydrogen blending ratio (HBR 0–30%) inlet temperature and rotational speed on key compressor parameters (pressure ratio polytropic efficiency and outlet temperature) through numerical simulations. In order to evaluate the influence of hydrogen blending on the performance and stability of centrifugal compressors a three-dimensional model of the compressor was established and the simulation conducted was verified with the experimental data. Results indicate that under constant inlet conditions both the pressure ratio and outlet temperature decrease with increasing HBR while polytropic efficiency remains relatively stable. Hydrogen blending significantly expands the surge margin shifting both surge and choke lines downward and consequently reducing the stable operating range by 27.11% when hydrogen content increases from 0% to 30%. This research provides theoretical foundations and practical guidance for optimizing hydrogen-blended natural gas centrifugal compressor design and operational control.
Dual S-Scheme Heterojunction Nanocomposite-chrge Transport for Photocatalytic Green Energy Production and Environmental Implementations - Where to Go?
Sep 2025
Publication
Dating back to more than one century ago the photocatalysis process has demonstrated great promise in addressing environmental problems and the energy crisis. Nevertheless some single or binary composite materials cannot meet the requirements of large-scale implementations owing to their limited photocatalytic efficiencies. Since 2021 dual S-scheme heterojunctionbased nanocomposites have been undertaken as highly efficient photoactive materials for green energy production and environmental applications in order to overcome limitations faced in traditional photocatalysts. Herein state-of-the-art protocols designed for the synthesis of dual S-scheme heterojunctions are described. How the combined three semiconductors in dual S-scheme heterojunctions can benefit from one another to achieve high energy production and efficient oxidative removal of various pollutants is deeply explained. Photocatalytic reaction mechanisms by paying special attention to the creation of Fermi levels (Ef ) and charge carriers transfer between the three semiconductors in dual S-scheme heterojunctions are discussed. An entire section has been dedicated to some examples of preparation and applications of double S-scheme heterojunction-based nanocomposites for several photocatalytic applications such as soluble pollutants photodegradation bacteria disinfection artificial photosynthesis H2 generation H2O2 production CO2 reduction and ammonia synthesis. Lastly the current challenges of dual S-scheme heterojunctions are presented and future research directions are presented. To sum up dual S-scheme heterojunction nanocomposites are promising photocatalytic materials in the pursuit of sustainable energy production and environmental remediation. In the future dual S-scheme heterojunctions are highly recommended for photoreactors engineering instead of single or binary photocatalysts to drive forward photocatalysis processes for practical green energy production and environmental protection.
Sustainable Power System Transition Pathways: Regional Decarbonisation and Resource Conservation Aided by Small Modular Reactors
Oct 2025
Publication
Clean energy technologies offer promising pathways for low-carbon transitions yet their feasibility remains uncertain particularly in rapidly developing regions. This study develops a Factorial Multi-Stochastic Optimization-driven Equilibrium (FMOE) model to assess the economic and environmental impacts of clean power deployment. Using Small Modular Reactors (SMRs) in Guangdong China as a case study the model reveals that SMRs can reduce system costs and alleviate GDP losses supporting provincial-level Nationally Determined Contributions (NDCs). If offshore wind capital costs fall to 40 % of SMRs’ SMR deployment may no longer be necessary after 2030. Otherwise SMRs could supply 22 % of capacity by 2040. The FMOE model provides a robust adaptable framework for evaluating emerging technologies under uncertainty and supports sustainable power planning across diverse regional contexts. This study offers valuable insights into the resource and economic implications of clean energy strategies contributing to global carbon neutrality and efficient energy system design.
Coordinated Control Strategy for Island Power Generation System with Photovoltaic, Hydrogen-Fueled Gas Turbine and Hybrid Energy Storage
Oct 2025
Publication
Marine and island power systems usually incorporate various forms of energy supply which poses challenges to the coordinated control of the system under diverse irregular and complex load operation modes. To improve the stability and self-sufficiency of island-isolated microgrids with high penetration of renewable energy this study proposes a coordinated control strategy for an island microgrid with PV HGT and HESS combining primary power allocation via low-pass filtering with a fuzzy logic-based secondary correction. The fuzzy controller dynamically adjusts power distribution based on the states of charge of the battery and supercapacitor following a set of predefined rules. A comprehensive system model is developed in Matlab R2023b integrating PV generation an electrolyzer HGT and a battery–supercapacitor HESS. Simulation results across four operational cases demonstrate that the proposed strategy reduces DC bus voltage fluctuations to a maximum of 4.71% (compared to 5.63% without correction) with stability improvements between 0.96% and 1.55%. The HESS avoids overcharging and over-discharging by initiating priority charging at low SOC levels thereby extending service life. This work provides a scalable control framework for enhancing the resilience of marine and island microgrids with high renewable energy penetration.
Unlocking Hydrogen Carrier Potential of the Yangtze River in China
Oct 2025
Publication
The Yangtze River as the world’s largest clean energy corridor links key economic regions and plays a crucial role in inland waterway transportation. However few studies have comprehensively evaluated the potential of the Yangtze River for cross-regional hydrogen transport. Here we develop a comprehensive integrated power and hydrogen supply chain (IPHSC) optimization model to evaluate the potential of cross-regional hydrogen transport via the Yangtze River. The IPHSC optimization model covers the entire hydrogen production-storage-transportation-utilization chain through cross-sector modeling of energy transportation water scheduling and environmental protection. Results show that in the 2060 carbon neutrality scenario the deployment of 62.2 kilotons of 574 differentiated liquid hydrogen (LH2) carrier ships could enable the transportation of 5018 kilotons (1512 million ton-km) of hydrogen annually meeting nearly 20% of the total electrolytic hydrogen demand across eight riverine provinces. Unlike west-to-east electricity transmission in China the central Yangtze River region is expected to become the main hub for hydrogen exports in the future. Compared with alternative methods such as transmission lines or pipelines LH2 carrier ships offer the lowest energy supply costs at 3 US cents/kWh for electricity and 5 US cents/kWh for hydrogen. Additionally a full-parameter attribution analysis of over 40 factors is conducted to assess variations in supply costs. Our study offers a thorough evaluation of the feasibility and economic benefits of hydrogen transportation via inland waterways providing a comprehensive multi-sectoral coupling assessment framework for regions with well-established inland waterway networks such as Europe and the United States.
Methanol Steam Reforming with Samarium-stabilized Copper Sites for Efficient Hydrogen Production
Nov 2025
Publication
The rational design of Cu-based catalysts with tailored interfacial structures and electronic states remains challenging yet essential for advancing hydrogen production via methanol steam reforming (MSR). Here we developed a samarium-mediated strategy to construct a 30Sm-CuAl catalyst. The introduction of Sm promotes Cu dispersion and induces strong metal-support interactions resulting in the formation of Sm2O3- encapsulated Cu nanoparticles enriched with Cu+ -O-Sm interfaces. The optimized 30Sm-CuAl demonstrates exceptional MSR performance achieving a hydrogen production rate of 1126 mmol gcat− 1 h− 1 at 250◦C. Mechanistic studies revealed that the reaction follows the formate pathway in xSm-CuAl with formate accumulation identified as the primary reason for the deactivation of 30Sm-CuAl. Dynamic regeneration of 30SmCuAl through redox treatment restores its activity thereby enabling cyclic operation. These findings provide insights into rare-earth oxide regulation of Cu-based catalysts and lay the foundation for targeted resolution of formate intermediate accumulation to enhance MSR stability.
Interleaved Parallel VDCM Improves Stability Control of Wind Power-hydrogen Coupled Integrated System
Nov 2025
Publication
Aiming at the problems of poor transient characteristics of converter output DC voltage and large DC current ripple caused by alkaline electrolyzer (AEL) switching operation in the wind power-hydrogen coupled integrated system this paper proposes an interleaved parallel VDCM control method to improve the stable operation of the system. Firstly a refined mathematical-physical model of the wind power-hydrogen coupled integrated system including HD-PMSG interleaved parallel buck and AEL is constructed. Then the VDCM control strategy is introduced into the interleaved parallel buck converter which provides reliable inertia and damping support for the output voltage of the hydrogen production system by simulating the DC motor power regulation characteristics and effectively improving the current ripple of the output current. Meanwhile the influence of rotational inertia and the damping coefficient on the dynamic stability of the system in the control strategy is analyzed based on the small signal method. Finally the proposed method is validated through MATLAB/SIMULINK simulation experiments and RCP + HIL hardware-in-the-loop experiments. The results show that the proposed method can improve the dynamic stability of the wind power-hydrogen coupled integrated system effectively.
Heat Recovery Unit Integrated with Biomass Gasification for Producing Hydrogen/Power/Heat Using a Novel Cascaded ORC with Biphenyl/Diphenyl Oxide Mixture; ML Optimsation and Economic Evaluation
Nov 2025
Publication
This work provides a detailed evaluation of a novel biomass-fueled multigeneration system conceived to contribute to the growing emphasis on sustainable energy solutions. The architecture comprises a biomass gasifier an innovative cascaded organic Rankine cycle (CORC) incorporating a high-temperature mixture in the top cycle a proton exchange membrane electrolyzer (PEME) a Brayton cycle and waste heat utilization units all operating together to deliver electricity hydrogen (H2) and thermal output. A comprehensive thermodynamic modeling framework is established to evaluate the system’s performance across various operational scenarios. The framework emphasizes critical metrics including exergy efficiency levelized total emissions (LTE) and payback period (PP). These indicators ensure a holistic assessment of energy exergy economic and environmental considerations. Parametric studies demonstrate that enhancements in biomass mass flow rate and combustion chamber temperature significantly increase power output and H2 production while reducing the payback period underscoring the system’s flexibility and economic feasibility. Furthermore the study employs sophisticated machine learning optimization methods combining artificial neural networks (ANNs) with genetic algorithms (GA) to determine optimal operating conditions with minimal computational effort and maximum efficiency. When evaluated at nominal parameters the system records an exergy efficiency of 23.72 % achieves a PP of 5.61 years and yields an LTE value of 0.34 ton/GJ. However under optimized conditions these values improve to 35.01 % 3.78 years and 0.241 ton/GJ respectively.
Hybrid-mode Offshore Hydrogen-producing Wind Turbine: Grid-following and Grid-forming Operation Under Variable Grid Conditions
Nov 2025
Publication
This paper proposes a hybrid-mode operation strategy for an offshore hydrogen-producing wind turbine (OHP-WT) capable of grid-following (GFL) and grid-forming (GFM) operation under both normal and low-voltage ride-through (LVRT) conditions. Unlike conventional centralized wind-to-hydrogen (W2H) schemes the proposed turbine-level architecture integrates W2H converters directly into the DC link of a three-level neutral-point-clamped converter. A supervisory power-sharing and mode-switch layer is developed above established GFL and GFM controls to coordinate active and reactive power regulation DC-link balancing and hydrogen-load management according to grid conditions. The proposed strategy is validated through detailed PLECS simulations and real-time hardware-in-the-loop experiments using identical parameters. Results show that the GFL mode achieves accurate power dispatch and shallow-fault LVRT compliance while the GFM mode maintains voltage and frequency stability under weak grid and severe-fault conditions. In all cases maximum-power-point tracking (MPPT) is preserved and hydrogen production continuously absorbs surplus power to stabilize the DC link. The findings demonstrate that the hybrid-mode OHP-WT enables transition between grid support and hydrogen production effectively reducing wind-power curtailment and enhancing offshore grid resilience.
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